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Sheahan Diamond Literature Technical Reference Compilation 2018


The Sheahan Diamond Literature Reference Compilation
The Sheahan Diamond Literature Reference Compilation is compiled by Patricia Sheahan who publishes on a monthly basis a list of new scientific articles related to diamonds as well as media coverage and corporate announcementscalled the Sheahan Diamond Literature Service that is distributed as a free pdf to a list of followers. Pat has kindly agreed to allow her work to be made available as an online digital resource at Kaiser Research Online so that a broader community interested in diamonds and related geology can benefit. The references are for personal use information purposes only; when available a link is provided to an online location where the full article can be accessed or purchased directly. Reproduction of this compilation in part or in whole without permission from the Sheahan Diamond Literature Service is strictly prohibited. Return to Diamond Resource Center
Sheahan Diamond Literature Reference Compilation - Scientific Articles by Author for all years
A-An Ao+ B-Bd Be-Bk Bl-Bq Br+ C-Cg Ch-Ck Cl+ D-Dd De-Dn Do+ E F-Fn Fo+ G-Gh Gi-Gq Gr+ H-Hd He-Hn Ho+ I J K-Kg Kh-Kn Ko-Kq Kr+ L-Lh
Li+ M-Maq Mar-Mc Md-Mn Mo+ N O P-Pd Pe-Pn Po+ Q R-Rh Ri-Rn Ro+ S-Sd Se-Sh Si-Sm Sn-Ss St+ T-Th Ti+ U V W-Wg Wh+ X Y Z
Sheahan Diamond Literature Reference Compilation - Media/Corporate References by Name for all years
A B C D-Diam Diamonds Diamr+ E F G H I J K L M N O P Q R S T U V W X Y Z
Tips for Users
Posted/Published Reference CodesThe SDLRC provides 3 types of references identified in the reference code. DS for scientific article, DM for a media article, and DC for a corporate announcement. Consider DS0512-0001. The DS stands for "diamond scientific". 05 stands for 2005, the year the reference was posted. 12 represents the month the reference was posted. For all years prior to 2015 the default month is 12. -0001 is the reference's identifier and it does not mean anything. The number below the refence code, ie 2015, is the year the article was published. Note that the posted year may sometimes be later than the published year.
Sort OrderReferences are sorted by the "author" name and when the reference was posted to the compilation.
Most RecentIf the reference code is highlighted yellow, the reference was made available through the most recent monthly compilation of new literature. Use this to check out new references. When new references are posted, we make it our priority to track down an online link and obtain an abstract. With regard to older references, tracking down an abstract and an online link is a work in progress.
Link to external location of article: If the title has a link, it means we have found a location online where you can either retrieve the full article free, or purchase access to it. The Sheahan Diamond Literature Service is not a technical article procurement service; if you want a restricted article, you must deal directly with the vendor who controls the copyright to the article.
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Monthly Sheahan Diamond Newsletters for 2018
January 2018 May 2018 September 2018
February 2018 June 2018 October 2018
March 2018 July 2018 November 2018
April 2018 August 2018 December 2018
2018 Technical Reference Compilation
Posted/
Published
AuthorTitleSourceRegionKeywords
DS201810-2292
2018
Abbo, A., Avigad, D., Gerdes, A.The lower crust of the Northern broken edge of Gondwana: evidence for sediment subduction and syn-Variscan anorogenic imprint from zircon U-Pb-Hf granulite xenoliths.Gondwana Research, Vol. 64, pp. 84-96.Europesubduction

Abstract: The continental basement in the Eastern Mediterranean represents the northern edge of Gondwana, which has been the site of repeated crustal accretion and has subsequently been modified by consecutive rifting events. We investigated the geologic and thermal history of the North Gondwana lower crust by examining the U-Pb-Hf isotope systematics in zircons within 6 mafic granulite xenoliths from Pliocene lava cone in North Israel. The lava cone protrudes through the platform cover that seals the late Neoproterozoic junction between the Arabian-Nubian basement to the South and the Cadomian basement exposed in the Taurides to the North. The mafic granulite xenoliths are composed of plagioclase + orthopyroxene + clinopyroxene ± garnet ± spinel ± secondary amphibole. U-Pb zircon ages from the granulites vary among the different samples with distinct zircon age populations at 400-1200 Ma, 170-350 Ma, and 3.6-4.2 Ma, attesting the lower crust preserves a prolonged thermal and igneous history. While 400-550 Ma U-Pb ages are interpreted to be the result of Pb loss, the wide scatter of zircon grains aged between 550 and 1200 Ma, alongside their diverse ?Hf(t) values (?25-+10), is an extraordinary evidence for the accretion of Neoproterozoic sediments into the North Gondwana arc root lower crust. The U-Pb-Hf signature of these zircons resembles Cadomian sediments of the Tauride block to the north, indicating southward (present coordinates) subduction under North Gondwana and possible accretion of fore-arc sediments to the lower crust through relamination in the latest Neoproterozoic. One xenolith contained metamorphic-shaped zircons aged 170-350 Ma with positive ?Hf values and Hf-TDM of 0.85 Ga interpreted to reflect Paleozoic recycling of the Neoproterozoic juvenile Arabian basement, which we consider to form a major component of the lower crust in the region. An overwhelming cluster of Carboniferous zircons concentrating at 305 Ma with exclusively negative ?Hf values around ?6, was retrieved from three xenoliths. Some of these zircons portrayed igneous textures and shape. While Carboniferous igneous activity is the hallmark of Western Europe's Variscan orogeny, the latter did not affect the southern rifted edge of Neo-Tethys where our xenoliths were retrieved. The Paleozoic age-Hf composition in our xenoliths is therefore interpreted to result from syn-Variscan recycling of Neoproterozoic sedimentary remains in the lower crust, and some degree of melting in a non-orogenic environment. Rather than with horizontal plate motions and orogeny, the Carboniferous zircon ages in the xenoliths appear to coalesce with significant vertical movements that created continental scale unconformities and a broad basin and swell architecture known to develop over the entire North Gondwana margin at that time. The Carboniferous aged zircons in northern Israel lower crustal xenoliths are therefore a unique gauge of the thermal perturbation that accompanied the large-scale mantle dynamics below the then passive North African margin of Gondwana, while Variscan orogenic accretion occurred on the Eurasian margin. These lower crustal granulites xenoliths therefore contain important information with respect to the nature of the lower crust under Israel, with implications on the geodynamic setting during the Cadomian and Variscan cycles.
DS201812-2771
2018
Abersteiner, A., Kamenetsky, V.S., Goemann, K., Giuliani, A., Howarth, G.H., Castillo-Oliver, M., Thomspon, J., Kamenetsky,M., Cherry, A.Composition and emplacement of the Benfontein kimberlite sill complex ( Kimberley, South Africa): textural, petrographic and melt inclusion constraints.Lithos, doi.org/10.1016 /jlithos.2018 .11.017 32p.Africa, South Africadeposit - Benfontein

Abstract: The Benfontein kimberlite is a renowned example of a sill complex and provides an excellent opportunity to examine the emplacement and evolution of intrusive kimberlite magmas. We have undertaken a detailed petrographic and melt inclusion study of the Benfontein Upper, Middle and Lower sills. These sills range in thickness from 0.25 to 5?m. New perovskite and baddeleyite U/Pb dating produced ages of 85.7?±?4.4?Ma and 86.5?±?2.6?Ma, respectively, which are consistent with previous age determinations and indicate emplacement coeval with other kimberlites of the Kimberley cluster. The Benfontein sills are characterised by large variations in texture (e.g., layering) and mineral modal abundance between different sill levels and within individual samples. The Lower Sill is characterised by carbonate-rich diapirs, which intrude into oxide-rich layers from underlying carbonate-rich levels. The general paucity of xenogenic mantle material in the Benfontein sills is attributed to its separation from the host magma during flow differentiation during lateral spreading. The low viscosity is likely responsible for non-explosive emplacement of the Benfontein sills, while the rhythmic layering is attributed to multiple magma injections. The Benfontein sills are marked by the excellent preservation of olivine and groundmass mineralogy, which is composed of monticellite, spinel, perovskite, baddeleyite, ilmenite, apatite, calcite, dolomite along with secondary serpentine and glagolevite [NaMg6[Si3AlO10](OH,O)8•H2O]. This is the first time glagolevite is reported in kimberlites. Groundmass spinel exhibits atoll-textures and is composed of a magnesian ulvöspinel magnetite (MUM) or chromite core, surrounded by occasional pleonaste and a rim of Mg-Al-magnetite. We suggest that pleonaste crystallised as a magmatic phase, but was resorbed back into the residual host melt and/or removed by alteration. Analyses of secondary inclusions in olivine and primary inclusions in monticellite, spinel, perovskite, apatite and interstitial calcite are largely composed of Ca-Mg carbonates and, to a lesser extent, alkali-carbonates and other phases. These inclusions probably represent the entrapment of variably differentiated parental kimberlite melts, which became progressively more enriched in carbonate, alkalis, halogens and sulphur during crystal fractionation. Carbonate-rich diapirs from the Lower Sill contain more exotic phase assemblages (e.g., Ba-Fe titanate, barite, ancylite, pyrochlore), which probably result from the extreme differentiation of residual kimberlite melts followed by physical separation and isolation from the parental carbonate-rich magma. It is likely that any alkali or halogen rich minerals crystallising in the groundmass were removed from the groundmass during syn?/post-magmatic alteration, or in the case of Na, remobilised to form secondary glagolevite. The Benfontein sill complex therefore provides a unique example of how the composition of kimberlites may be modified after magma emplacement in the upper crust.
DS201811-2552
2018
Abersteiner, A., Kamenetsky, V.S., Golovin, A.V., Kamenetsky, M., Goemann, K.Was crustal contamination involved in the formation of the serpentine-free Udachnaya-East kimberlite? New insights into parental melts, liquids, liquidus assemblage and effects of alteration.Journal of Petrology, Vol. 59, 8, pp. 1467-1492.Russiadeposit - Udachnaya-East

Abstract: The petrologically unique Udachnaya-East kimberlite (Siberia, Russia) is characterised by unserpentinised and H2O-poor volcaniclastic and coherent units that contain fresh olivine, along with abundant alkali-rich carbonates, chlorides, sulphides and sulphates in the groundmass. These mineralogical and geochemical characteristics have led to two divergent models that advocate different origins. It has been suggested that the unserpentinised units from Udachnaya-East are representative of pristine unaltered kimberlite. Conversely, the alkali-chlorine-sulphur enrichment has been attributed to interactions with crustal materials and/or post-emplacement contamination by brines. The mineralogical and geochemical features and the compositions of melt inclusions in unserpentinised and serpentinised Udachnaya-East kimberlite varieties are compared in this study. Both varieties of kimberlite have similar major, compatible and incompatible trace element concentrations and primitive mantle normalised trace element patterns, groundmass textures and silicate, oxide and sulphide mineral compositions. However, these two kimberlite varieties are distinguished by: (i) the presence of unaltered olivine, abundant Na-K-Cl-S-rich minerals (i.e. chlorides, S-bearing alkali-carbonates, sodalite) and the absence of H2O-rich phases (i.e. serpentine, iowaite (Mg4Fe3+(OH)8OCl•3(H2O)) in unserpentinised samples, and (ii) the absence of alkali- and chlorine-enriched phases in the groundmass and characteristic olivine alteration (i.e. replacement by serpentine and/or iowaite) in serpentinised samples. In addition, melt inclusions hosted in olivine, monticellite, spinel and perovskite from unserpentinised and serpentinised kimberlite contain identical daughter phase assemblages that are dominated by alkali-carbonates, chlorides and sulphates/sulphides. This enrichment in alkalis, chlorine and sulphur in melt inclusions demonstrates that these elements were an intrinsic part of the parental magma. The paucity of alkali-carbonates and chlorides in the groundmass of serpentinised Udachnaya-East kimberlite is attributed to their instability and removal during post-emplacement alteration. All evidence previously used in support of crustal and brine contamination of the Udachnaya-East kimberlite is thoroughly evaluated. We demonstrate that ‘contamination models’ are inconsistent with petrographic, geochemical and melt inclusion data. Our combined data suggest that the Udachnaya-East kimberlite crystallised from an essentially H2O-poor, Si-Na-K-Cl-S-bearing carbonate-rich melt.
DS201802-0216
2018
Abersteiner, A., Kamenetsky, V.S., Kamenetsky, M., Goemann, K., Ehrig, K., Rodemann, T.Significance of halogens ( F, Cl) in kimberlite melts: insights from mineralogy and melt inclusions in the Roger pipe ( Ekati, Canada).Chemical Geology, Vol. 478, pp. 148-163.Canada, Northwest Territoriesdeposit - Roger

Abstract: The abundance and distribution of halogens (F, Cl) are rarely recorded in kimberlites and therefore their petrogenetic significance is poorly constrained. Halogens are usually present in kimberlite rocks in the structure of phlogopite and apatite, but their original concentrations are never fully retained due to the effects of alteration. To provide new constraints on the origin and evolution of halogens in kimberlites and their melts, we present a detailed study of the petrography and geochemistry of the late-Cretaceous Group-I (or archetypal) Roger kimberlite (Ekati cluster, Canada). The studied samples contain abundant anhedral-to-euhedral olivine which is set in a crystalline groundmass of monticellite, phlogopite, apatite, spinel (i.e. magnesian ulvöspinel-magnetite (MUM), Mg-magnetite, pleonaste, Cr-spinel), and perovskite along with abundant secondary alteration phases (i.e. serpentine, garnet (andradite-schlorlomite), amakinite ((Fe2 +, Mg, Mn)(OH)2), calcite). The Roger kimberlite is characterised by the highest recorded F-content (up to 2688 ppm) of the Ekati cluster kimberlites, which is reflected by the preservation of F-rich phases, where bultfonteinite (Ca4(Si2O7)(F, OH)2) and fluorite commonly replace olivine. In order to examine the composition and evolution of the kimberlite melt prior to post-magmatic processes, we studied melt inclusions in olivine, Cr-spinel, monticellite and apatite. Primary multiphase melt inclusions in Cr-spinel, monticellite and apatite and secondary inclusions in olivine are shown to contain a diversity of daughter phases and compositions that are dominated by alkali/alkali-earth (Na, K, Ba, Sr)-enriched Ca-Mg-carbonates ± F, Na-K-chlorides and sulphates, phosphates ± REE, spinel, silicates (e.g. olivine, phlogopite, (clino)humite), and sulphides. Although alkali/alkali-earth- and halogen-bearing phases are abundant in melt inclusions, they are generally absent from the kimberlite groundmass, most likely due to ubiquitous effects of syn- and/or post-magmatic alteration (i.e. serpentinisation). Comparisons between halogens and other trace elements of similar compatibility (i.e. F/Nd and Cl/U) in the Roger kimberlite and their respective estimated primitive mantle abundances show that halogens should be a more significant component in kimberlites than typically measured. We propose that fluorine in the Roger kimberlite was magmatic and was redistributed during hydrothermal alteration by Ca-bearing serpentinising fluids to produce the observed bultfonteinite/fluorite assemblages. Based the compositions and daughter mineral assemblages in primary melt inclusions and reconstructed halogen abundances, we suggest that Cr-spinel, monticellite and apatite crystallised from a variably differentiated Si-P-Cl-F-bearing carbonate melt that was enriched in alkalis/alkali-earths and highly incompatible trace elements.
DS201802-0217
2018
Abersteiner, A., Kamenetsky, V.S., Pearson, D.G., Kamenetsky, M., Goemann, K., Ehrig, K., Rodemann, T.Monticellite in group I kimberlites: implications for evolution of parental melts and post emplacement CO2 degassing.Chemical Geology, Vol. 478, pp. 76-88.Canada, Northwest Territories, Europe, Finlanddeposit - Leslie, Pipe 1

Abstract: Monticellite is a magmatic and/or deuteric mineral that is often present, but widely varying in concentrations in Group-I (or archetypal) kimberlites. To provide new constraints on the petrogenesis of monticellite and its potential significance to kimberlite melt evolution, we examine the petrography and geochemistry of the minimally altered hypabyssal monticellite-rich Leslie (Canada) and Pipe 1 (Finland) kimberlites. In these kimberlites, monticellite (Mtc) is abundant (25-45 vol%) and can be classified into two distinct morphological types: discrete and intergrown groundmass grains (Mtc-I), and replacement of olivine (Mtc-II). Primary multiphase melt inclusions in monticellite, perovskite and Mg-magnetite contain assemblages dominated by alkali (Na, K, Ba, Sr)-enriched Ca-Mg-carbonates, chlorides, phosphates, spinel, silicates (e.g. olivine, phlogopite) and sulphides. These melt inclusions probably represent snapshots of a variably differentiated kimberlite melt that evolved in-situ towards carbonatitic and silica-poor compositions. Although unconstrained in their concentration, the presence of alkali-carbonates and chlorides in melt inclusions suggests they are a more significant component of the kimberlite melt than commonly recorded by whole-rock analyses. We present petrographic and textural evidence showing that pseudomorphic Mtc-II resulted from an in-situ reaction between olivine and the carbonate component of the kimberlite melt in the decarbonation reactio. This reaction is supported by the preservation of abundant primary inclusions of periclase and to a lesser extent Fe-Mg-oxides in monticellite, perovskite and Mg-magnetite. Based on the preservation of primary periclase inclusions, we infer that periclase also existed in the groundmass, but was subsequently altered to brucite. We suggest that CO2 degassing in the latter stages of kimberlite emplacement into the crust is largely driven by the observed reaction between olivine and the carbonate melt. For this reaction to proceed, CO2 should be removed (i.e. degassed), which will cause further reaction and additional degassing in response to this chemical system change (Le Chatelier's principle). Our study demonstrates that these proposed decarbonation reactions may be a commonly overlooked process in the crystallisation of monticellite and exsolution of CO2, which may in turn contribute to the explosive eruption and brecciation processes that occur during kimberlite magma emplacement and pipe formation.
DS201801-0001
2017
Ackerman, L., Magna, T., Rapprich, V., Upadhyay, D., Kratky, O., Cejkova, B., Erban, V., Kochergina, Y.V., Hrstka, T.Contrasting petrogenesis of spatially related carbonatites from Samalpatti and Sevattur, Tamil Nadu, India: insights from trace element and isotopic geochemistry.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 31-33.Indiadeposit - Samalpatti, Sevattur

Abstract: The Tamil Nadu region in southern India hosts several carbonatite bodies (e.g., Hogenakal, Samalpatti, Sevattur, Pakkanadu-Mulakkadu) which are closely associated with alkaline silicate rocks such as syenites, pyroxenites or dunites (e.g, Kumar et al., 1998; Schleicher et al., 1998; Srivastava, 1998). This is in contrast to the carbonatite occurrences in north-western India associated with the Deccan Trap basalts (e.g., Amba Dongar) or Proterozoic Newania dolomitic carbonatites. We have studied two, spatially related, Neoproterozoic carbonatite-silico(carbonatite) suites in association with alkaline silicate rocks (e.g., pyroxenite, gabbro) from Sevattur and Samalpatti in terms of petrography, chemistry and radiogenic-stable isotopic compositions in order to provide constraints on their genesis and evolution. In these two bodies, several different carbonatite types have been reported previously with striking differences in their trace element and isotopic compositions (Srivastava, 1998; Viladkar and Subramanian, 1995; Schleicher et al., 1998; Pandit et al., 2002). Collected data for previously poorly studied calcite carbonatites from the Sevattur representing the first carbonatite magmas on this locality, indicate similar geochemical characteristics to those of dolomitic carbonatites, such as high LREE/HREE ratios, very high Sr and Ba contents, large amounts of apatite and magnetite, identical Sr-Nd-C-O isotopic compositions. Thus, they were derived from an enriched mantle source without significant post-emplacement modifications through crustal contamination and hydrothermal overprint, in agreement with previous studies (e.g., Schleicher et al., 1998). Detailed microprobe analyses revealed that high levels of some incompatible elements (e.g., REE, Y, Sr, Ba) cannot be accounted by matrix calcite hosting only significant amounts of SrO (~0.6-1.2 wt.%). On the other hand, abundant micro- to nano-scale exsolution lamellae and/or inclusions of mckelveyite-(Nd) appear to host a significant fraction of LREE in parallel with apatite. Distribution of Sr is most likely influenced also by common but heterogeneously dispersed barite and strontianite. Newly acquired as well as detailed inspection of available geochemical data permits distinguish two different types of carbonatites in Samalpatti: (1) Type I similar to Sevattur carbonatites in terms of mineralogy, trace element and radiogenic-stable isotopic compositions and (2) Type II with remarkably low concentrations of REE and other incompatible trace elements, more radiogenic Sr isotopic compositions and extremely variable C–O isotopic values. The petrogenesis of the Type II seems to be intimately associated with the presence of silicocarbonatites and abundant silicate mineral domains. Instead of liquid immiscible separation from a silicate magma, elevated SiO2 contents observed in silico-carbonatites may have resulted from the interaction of primary carbonatitic melts and crustal rocks prior to and/or during magma emplacement. Arguments for such hypothesis include variable, but radiogenic Sr isotopic compositions correlated with SiO2 and other lithophile elements (e.g., Ti, Y, Zr, REE). Calc-silicate marbles present in the Samalpatti area could represent a possible evolved crustal end member for such process due to the inability of common silicate rocks (pyroxenites, granites, diorites) to comply with radiogenic isotopic constraints. The wide range of C-O isotopic compositions found in Samalpatti carbonatites belong to the highest values ever reported for magmatic carbonates and can be best explained by massive hydrothermal interaction with carbonated fluids. Unusual high-Cr silicocarbonatites were discovered at Samalpatti forming centimetre to decimetre-sized enclaves enclosed in pyroxenites with sharp contacts at hand specimen scale. Detailed microprobe analyses revealed peculiar chemical compositions of the Mgamphibole with predominantly sodic composition embaying and replacing Na-Cr-rich pyroxene (kosmochlor), accompanied by the common presence of Cr-spinel and titanite. Such association have been reported for hydrous metasomatism by Na-rich carbonatitic melts at upper mantle conditions (Ali and Arai, 2013). However, the mineralogy and the mode of occurrence of Samalpatti Mg–-r-rich silicocarbonatites argue against such origin. We explain the petrogenesis of these rocks through the reaction of pyroxenites with enriched mantle-derived alkali-CO2-rich melts, as also evidenced by mantle-like O and Hf isotopic compositions.
DS201803-0431
2017
Afanasyev, A.A., Belyaeva, E.A.The stability of serpentization due to water flow in kimberlite.Journal of Appled Mathematics and Mechanics, Vol. 81, pp. 206-213.Russiadeposit - Mir

Abstract: A linear analysis of the stability of the course of serpentization, that is, of the exothermic hydration reaction, due to the flow of water in a kimberlite pipe is carried out, taking both the heat conduction and the convective heat transfer by the fluid saturating the pipe rocks into account. It is shown that two different serpentization processes exist: a homogeneous process and an inhomogeneous process associated with a loss of stability by the homogeneous process and a non-uniform reaction rate distribution. Dimensionless similarity parameters that determine the course of the reaction are proposed. It is shown that convective heat transfer promotes a stabilization of the flow and the formation of a homogeneous serpentinite distribution. Other conditions being equal, an increase in the convective heat flux leads to an increase in the wavelengths of the unstable perturbations and to a decrease in their amplitude. A critical value of the flow rate exists, and, when this is exceeded, instability does not develop and serpentinization takes place under homogeneous conditions.
DS201812-2772
2018
Agard, P., Plunder, A., Angiboust, S., Bonnet, G., Ruh, J.The subduction plate interface: rock record and mechanical coupling ( from long to short timescales).Lithos, Vol. 320-321, pp. 537-566.Mantlesubduction

Abstract: Short- and long-term processes at or close to the subduction plate interface (e.g.,mineral transformations, fluid release, seismicity and more generally deformation) might be more closely related than previously thought. Increasing evidence from the fossil rock record suggests that some episodes of their long geological evolution match or are close to timescales of the seismic cycle. This contribution uses rocks recovered (episodically) from subduction zones, together with insights from thermomechanical modelling, to provide a new dynamic vision of the nature, structure and properties of the plate interface and to bridge the gap between the mechanical behavior of active subduction zones (e.g.,coupling inferred from geophysical monitoring) and fossil ones (e.g.,coupling required to detach and recover subducted slab fragments). Based on critical observations and an exhaustive compilation of worldwide subducted oceanic units (for which the presence near the plate interface, rock types, pressure, temperature, T/P gradients, thickness and timing of detachment can be assessed), the present study demonstrates how long-term mechanical coupling exerts a key control on detachment from the slab and potential rock recovery. Critical assessment of rock T/P characteristics indicates that these fragments can indeed be used as natural probes and provide reliable information on subduction interface dynamics down to ~2.8?GPa. Rock clusters are identified at depths of 30, 5560 and 80?km, with some differences between rock types. Data also reveal a first-order evolution with subduction cooling (in the first ~5?Myr), which is interpreted as reflecting a systematic trend from strong to weak mechanical coupling, after which subduction is lubricated and mostly inhibits rock recovery. This contribution places bounds on the plate interface constitution, regular thickness (<300?m; i.e. where/when there is no detachment), changing geometry and effective viscosity. The concept of ‘coupled thickness' is used here to capture subduction interface dynamics, notably during episodes of strong mechanical coupling, and to link long- and short-term deformation. Mechanical coupling depends on mantle wedge rheology, viscosity contrasts and initial structures (e.g.,heterogeneous lithosphere, existence of décollement horizons, extent of hydration, asperities) but also on boundary conditions (convergence rates, kinematics), and therefore differs for warm and cold subduction settings. Although most present-day subduction zone segments (both along strike and downdip) are likely below the detachment threshold, we propose that the most favorable location for detachment corresponds to the spatial transition between coupled and decoupled areas. Effective strain localization involves dissolution-precipitation and dislocation creep but also possibly brittle fractures and earthquakes, even at intermediate depths.
DS201808-1722
2018
Agashev, A.M., Nakai, S., Serov, I.V., Tolstov, A.V., Garanin, K.V., Kovalchuk, O.E.Geochemistry and origin of the Mirny field kimberlites, Siberia.Mineralogy and Petrology, doi.org/10.1007/s00710-018-06174 12p.Russia, Siberiadeposit - Mirny

Abstract: Here we present new data from a systematic Sr, Nd, O, C isotope and geochemical study of kimberlites of Devonian age Mirny field that are located in the southernmost part of the Siberian diamondiferous province. Major and trace element compositions of the Mirny field kimberlites show a significant compositional variability both between pipes and within one diatreme. They are enriched in incompatible trace elements with La/Yb ratios in the range of (65-00). Initial Nd isotope ratios calculated back to the time of the Mirny field kimberlite emplacement (t?=?360 ma) are depleted relative to the chondritic uniform reservoir (CHUR) model being 4 up to 6 ?Nd(t) units, suggesting an asthenospheric source for incompatible elements in kimberlites. Initial Sr isotope ratios are significantly variable, being in the range 0.70387-0.70845, indicating a complex source history and a strong influence of post-magmatic alteration. Four samples have almost identical initial Nd and Sr isotope compositions that are similar to the prevalent mantle (PREMA) reservoir. We propose that the source of the proto-kimberlite melt of the Mirny field kimberlites is the same as that for the majority of ocean island basalts (OIB). The source of the Mirny field kimberlites must possess three main features: It should be enriched with incompatible elements, be depleted in the major elements (Si, Al, Fe and Ti) and heavy rare earth elements (REE) and it should retain the asthenospheric Nd isotope composition. A two-stage model of kimberlite melt formation can fulfil those requirements. The intrusion of small bodies of this proto-kimberlite melt into lithospheric mantle forms a veined heterogeneously enriched source through fractional crystallization and metasomatism of adjacent peridotites. Re-melting of this source shortly after it was metasomatically enriched produced the kimberlite melt. The chemistry, mineralogy and diamond grade of each particular kimberlite are strongly dependent on the character of the heterogeneous source part from which they melted and ascended.
DS201807-1477
2018
Agashev, A.M., Pokhilenko, L.N., Pokhilenko, N.P., Shchukina, E.V.Geochemistry of eclogite xenoliths from the Udachnaya kimberlite pipe: section of ancient oceanic crust sampled.Lithos, DOI:10.1016 /j.lithos.2018 .05.027 available 52p.Russiadeposit - Udachnaya

Abstract: A suite of seventeen unique, large, and fresh eclogite xenoliths from the Udachnaya pipe have been studied for their whole-rock and mineral major- and trace-element compositions. Based on their major-element compositions, the Udachnaya eclogites can be subdivided in two groups: high magnesian (Mg# 68.8-81.9) and low magnesian (Mg# 56.8-59). The two eclogite groups are clearly different in the style of correlation between major elements. Positive correlations of FeO and CaO with MgO are observed in the low-magnesian group, whereas these correlations are negative in the high-magnesian group. In terms of trace element composition, the Udachnaya eclogites are enriched over Primitive Mantle, but comparable to mid-ocean-ridge basalt composition, except for significant enrichment in large-ion lithophile elements (LILE; Rb, Ba, K, Sr). Most of the samples show a positive Eu anomaly, irrespective of group. Reconstructed whole-rock composition from clinopyroxene and garnet modal abundances contains much less incompatible elements (LILE, light rare earth elements, high field strength elements) than measured composition. Approximately 60 to 100% of the middle rare earth elements, Zr, and Hf, and nearly 100% of the heavy rare earth elements, Co, V, and Sc of the whole-rock budget are concentrated in Gar and Cpx. Variations in major element compositions cover a full section of the modern and Archaean oceanic crust, from troctolite, through gabbroic rocks, to basalts. The low-Mg# eclogites could have formed from upper oceanic crust protoliths, being a mixture of basalts and gabbro, whereas the high-Mg# eclogites are originated from gabbro-troctolite section of the lower oceanic crust. Concordant variations of Eu anomaly with the Lu/Sr ratio and the V and Ni contents in the eclogite compositions are in agreement with the fractionation of plagioclase, clinopyroxene, and olivine in their low-pressure precursor rocks. Negative correlations of SiO2 and MgO, and a low Nd/YbNMORB ratio, in the low-Mg# eclogites are in agreement with partial melt loss, but the presence of accessory quartz limits the degree of melting to 13%. Major and trace element compositions suggest that the high-Mg# eclogites, and, consequently, the lower oceanic crust, could not have experienced significant melt loss, and subduction in the Archaean may have been essentially dry, compared to the present day.
DS201809-1988
2015
Airo, M.L.Geophysical signatures of mineral deposit types ( mentions diamonds).Finland Geological Survey, http://tupa.gtk.fi /julkaisu/ specialpaper/ sp_058.pdfFinlandgeophysics

Abstract: In this Special Paper volume, the review of physical properties of ore deposit types or mineralization styles is mainly based on published information, in particular on the key note speeches and presentations that were given at two geosciences conferences: Exploration07 held in Toronto in 2007 (proceedings by Milkereit (ed.) 2007), and the SGA meeting held in Uppsala in 2013 (proceedings by Johnsson et al. (eds.) 2013). Diamonds referred to on p. 13.
DS201802-0218
2018
Akaogi, M., Kawahara, A., Kojitani, H., Yoshida, K., Anegawa, Y., Ishii, T.High pressure phase transitions in MgCr2O4 MgSiO4 composition: reactions between olivine and chromite with implications for ultrahigh pressure chromitites.American Mineralogist, Vol. 103, pp. 161-170.Mantlechromites
DS201804-0667
2017
Akishev, A.N., Zyryanov, I.V., Kornilkov, S.V., Kantemirov, V.D.Improving evaluation methods for production capacity and life of open pit diamond mines.Journal of Mining Science, Vol. 53, 1, pp. 71-76.Russiadeposit - Yubileinaya

Abstract: The article reports basic design parameters of open pit mines of ALROSA, as well as criteria and factors that govern the choice of production capacity of an open pit diamond mine under conditions of permafrost. The analytical relations and tables to calculate open pit mine life are presented, and the influence of the rate of the downward advance of an open pit mine on its capacity is demonstrated. The authors formulate key provisions for a paragraph of the national standard of RF enabling systematization of approaches to optimization of open diamond mining parameters.
DS201812-2773
2018
Ali, H., Regier, M.E., Pearson, D.G.Increased recovery of diamonds from eclogite by electrical pulse disaggregation. SELFRAG2018 Yellowknife Geoscience Forum , p. 91-92. abstractAfrica, South Africadeposit - Roberts Victor

Abstract: It is well known that mechanical disaggregation, such as jaw crushing, can cause irreversible damage to valuable gemstones hosted in crystalline rocks. The SELFRAG Lab device uses electrical pulses at high voltages - typically between 150 and 200 kV - to separate material into individual grains along natural boundaries. The purpose of this research is to assess the viability of the SELFRAG as a tool to disaggregate diamond-bearing eclogites, and to assess if this method preserves grains that would otherwise be damaged through mechanical disaggregation. In order to test the applicability of the SELFRAG to diamond recovery from mechanically strong diamond-bearing lithologies, we studied its effects on a diamondiferous eclogite, RV09, from Roberts Victor mine. The Roberts Victor mine is located in South Africa and is renowned for its unusually high abundance of mantle-derived eclogite xenoliths1. Before the eclogite was disaggregated, we bisected the sample and used a CT scan to determine its constituent minerals and the spatial distribution of diamond. One half of the sample was then placed into the SELFRAG, where it was subjected to ~100 shots of 200 kV electrical discharges that segregated the sample into individual grains of similar sizes. The other half was jaw crushed, using a steel jaw crusher which produced non-uniform composite grains and abundant fine material. The varying sizes and aggregate pieces made it difficult to pick diamonds, and after no diamonds were found, the jaw-crushed portion underwent further disaggregation in the SELFRAG. After exerting the same time and effort picking through both portions of the RV09 sample, ten diamonds were recovered from the electronically disaggregated portion, while no diamonds were found in the conventionally disaggregated sample. The diamonds released from the SELFRAG were then imaged with a scanning electron microscope (SEM) to determine the extent to which the diamonds were damaged. Most of the released diamonds showed no evidence of breakage, but a few showed signs of damage that may have occurred prior to kimberlite eruption. The dramatic disparity between the number of diamonds recovered with the SELFRAG and the lack of diamonds in the jaw crushed portion indicates that electrical disaggregation is a superior method compared to the conventional mechanical comminution technique. There are little to no signs of breakage in the SELFRAG-liberated diamonds, whereas, the damage caused by jaw crushing was extensive enough to produce small fragments not readily visible via optical microscopy. The SELFRAG is a promising alternative to conventional disaggregation and offers a practical solution for lessening damage to valuable stones in rocks such as eclogites and kimberlites.
DS201804-0668
2018
Alvaro, M., Nestola, F.Crystallographic approaches to study mineral inclusions in diamonds.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 7-8. abstractTechnologydiamond inclusions
DS201809-1989
2018
Amsellem, E., Moynier, F., Bertrand, H.Origin of carbonatites from Ca stable isotopes. (Oldoinyo Lengai)Goldschmidt Conference, 1p. AbstractAfrica, Tanzaniacarbonatites

Abstract: Carbonatites are rare igneous rocks that have a high content of carbonate minerals and nearly no silica. Carbonatitic magmas are derived from carbonated mantle sources but the origin of the carbonates (recycling of surface material or primary mantle source) is still debated. While mafic igneous rocks present a ?44/40Ca around 0.8-1.2‰ normalised to SRM, surface carbonates have ?44/40Ca ~ 0‰. Ca isotopes are therefore well suited to study the origin of Ca in carbonatites. We analysed the Ca isotopic composition of 25 carbonatites from continental and oceanic locations and from different ages (from 2 Ga to present day). The large majority of the carbonatites are isotopically light (?44/40Ca down to 0.07‰) compared to mantle derived rocks. On the other hand, the natrocarbonatite from Oldoinyo Lengai is isotopically heavier (?44/40Ca =0.82‰), similarly to basalts. Three mechanisms can explain the very light isotopic composition of the calciocarbonatites i) A very low degree of partial melting of the mantle may enrich the melt in light isotopes, yet there is no evidence of such large isotopic fractionation during partial melting. ii) The mantle source for the calciocarbonatites is enriched in light Ca likely due to recycling of surface material. iii) aqueous alteration has enriched the calciocarbonatites in the lighter isotopes. On the other hand, the natrocarbonatite from Oldoinyo Lengai have a MORB-like Ca isotopic composition. The difference of ?44/40Ca between natro- and calcio-carbonatite would then suggest that they either have different mantle sources, were formed from different degree of partial melting and/or that aqueous alteration has modified the Ca isotopic composition of calciocarbonatites.
DS201806-1208
2018
Andersson, M., Malehmir, A.Internal architecture of the Alno alkaline and carbonatite complex (central Sweden) revealed using 3D models of gravity and magnetic data.Tectonophysics, Vol. 740-741, pp. 53-71.Europe, Swedencarbonatite - Alno
DS201803-0432
2018
Andrault, D., Pesce, G., Manthilake, G., Monteux, J., Volfan-Casanova, N., Chantel, J. , Novella, D., Guignot, N., King, A., Itie, J-P., Hennet, L.An archean mushy mantle.Nature Geoscience, Vol. 11, 2, pp. 85-86.Mantlegeodynamics

Abstract: Experimental data reveal that Earth’s mantle melts more readily than previously thought, and may have remained mushy until two to three billion years ago.
DS201804-0669
2018
Angel, R.J., Alvaro, M., Nestola, F.40 years of mineral elasticity: a critical review and a new parameterisation of equations of state for mantle olivines and diamond inclusions.Physics and Chemistry of Minerals, Vol. 45, 2, pp. 95-131.Mantleolivines

Abstract: Elasticity is a key property of materials, not only for predicting volumes and densities of minerals at the pressures and temperatures in the interior of the Earth, but also because it is a major factor in the energetics of structural phase transitions, surface energies, and defects within minerals. Over the 40 years of publication of Physics and Chemistry of Minerals, great progress has been made in the accuracy and precision of the measurements of both volumes and elastic tensors of minerals and in the pressures and temperatures at which the measurements are made. As an illustration of the state of the art, all available single-crystal data that constrain the elastic properties and pressure–volume–temperature equation of state (EoS) of mantle-composition olivine are reviewed. Single-crystal elasticity measurements clearly distinguish the Reuss and Voigt bulk moduli of olivine at all conditions. The consistency of volume and bulk modulus data is tested by fitting them simultaneously. Data collected at ambient pressure and data collected at ambient temperature up to 15 GPa are consistent with a Mie–Grünesien–Debye thermal-pressure EoS in combination with a third-order Birch–Murnaghan (BM) compressional EoS, the parameter V 0 = 43.89 cm3 mol?1, isothermal Reuss bulk modulus KTR,0=126.3(2) GPa, K?TR,0=4.54(6), a Debye temperature ?D=644(9)K, and a Grüneisen parameter ? 0 = 1.044(4), whose volume dependence is described by q = 1.9(2). High-pressure softening of the bulk modulus at room temperature, relative to this EoS, can be fit with a fourth-order BM EoS. However, recent high-P, T Brillouin measurements are incompatible with these EoS and the intrinsic physics implied by it, especially that (?K?TR?T)P>0. We introduce a new parameterisation for isothermal-type EoS that scales both the Reuss isothermal bulk modulus and its pressure derivative at temperature by the volume, KTR(T,P=0)=KTR,0[V0V(T)]?T and K?TR(T,P=0)=K?TR,0[V(T)V0]??, to ensure thermodynamic correctness at low temperatures. This allows the elastic softening implied by the high-P, T Brillouin data for mantle olivine to be fit simultaneously and consistently with the same bulk moduli and pressure derivatives (at room temperature) as the MGD EoS, and with the additional parameters of ? V0 = 2.666(9) × 10?5 K?1, ?E=484(6), ?T = 5.77(8), and ?? = ?3.5(1.1). The effects of the differences between the two EoS on the calculated density, volume, and elastic properties of olivine at mantle conditions and on the calculation of entrapment conditions of olivine inclusions in diamonds are discussed, and approaches to resolve the current uncertainties are proposed.-
DS201802-0219
2018
Anzolini, C., Prencipe, M., Alvaro, M., Romano, C., Vona, A., Lorenzon, S., Smith, E.M., Brenker, F.E., Nestola, F.Depth of formation of super deep diamonds: Raman barometry of CaSiO3 walstromite inclusions.American Mineralogist, Vol. 103, pp. 69-74.Mantlegeobarometry

Abstract: “Super-deep” diamonds are thought to have a sub-lithospheric origin (i.e., below ~300 km depth) because some of the mineral phases entrapped within them as inclusions are considered to be the products of retrograde transformation from lower-mantle or transition-zone precursors. CaSiO3-walstromite, the most abundant Ca-bearing mineral inclusion found in super-deep diamonds, is believed to derive from CaSiO3-perovskite, which is stable only below ~600 km depth, although its real depth of origin is controversial. The remnant pressure (Pinc) retained by an inclusion, combined with the thermoelastic parameters of the mineral inclusion and the diamond host, allows calculation of the entrapment pressure of the diamond-inclusion pair. Raman spectroscopy, together with X-ray diffraction, is the most commonly used method for measuring the Pinc without damaging the diamond host. In the present study we provide, for the first time, a calibration curve to determine the Pinc of a CaSiO3-walstromite inclusion by means of Raman spectroscopy without breaking the diamond. To do so, we performed high-pressure micro-Raman investigations on a CaSiO3-walstromite crystal under hydrostatic stress conditions within a diamond-anvil cell. We additionally calculated the Raman spectrum of CaSiO3-walstromite by ab initio methods both under hydrostatic and non-hydrostatic stress conditions to avoid misinterpretation of the results caused by the possible presence of deviatoric stresses causing anomalous shift of CaSiO3-walstromite Raman peaks. Last, we applied single-inclusion elastic barometry to estimate the minimum entrapment pressure of a CaSiO3-walstromite inclusion trapped in a natural diamond, which is ~9 GPa (~260 km) at 1800 K. These results suggest that the diamond investigated is certainly sub-lithospheric and endorse the hypothesis that the presence of CaSiO3-walstromite is a strong indication of super-deep origin.
DS201810-2293
2017
Arcay, D.Modelling the interplate domain in thermo-mechanical simulations of subduction: critical effects of resolution and rheology, and consequences on wet mantle melting.Physics of the Earth and Planetary Interiors, Vol. 269, 1, pp. 112-132.Mantlesubduction

Abstract: The present study aims at better deciphering the different mechanisms involved in the functioning of the subduction interplate. A 2D thermo-mechanical model is used to simulate a subduction channel, made of oceanic crust, free to evolve. Convergence at constant rate is imposed under a 100 km thick upper plate. Pseudo-brittle and non-Newtonian behaviours are modelled. The influence of the subduction channel strength, parameterized by the difference in activation energy between crust and mantle () is investigated to examine in detail the variations in depth of the subduction plane down-dip extent, . First, simulations show that numerical resolution may be responsible for an artificial and significant shallowing of if the weak crustal layer is not correctly resolved. Second, if the age of the subducting plate is 100 Myr, subduction occurs for any . The stiffer the crust is, that is, the lower is, the shallower is (60 km depth if kJ/mol) and the hotter the fore-arc base is. Conversely, imposing a very weak subduction channel ( J/mol) leads there to an extreme mantle wedge cooling and inhibits mantle melting in wet conditions. Partial kinematic coupling at the fore-arc base occurs if kJ/mol. If the incoming plate is 20 Myr old, subduction can occur under the conditions that the crust is either stiff and denser than the mantle, or weak and buoyant. In the latter condition, cold crust plumes rise from the subduction channel and ascend through the upper lithosphere, triggering (1) partial kinematic coupling under the fore-arc, (2) fore-arc lithosphere cooling, and (3) partial or complete hindrance of wet mantle melting. then ranges from 50 to more than 250 km depth and is time-dependent if crust plumes form. Finally, subduction plane dynamics is intimately linked to the regime of subduction-induced corner flow. Two different intervals of are underlined: 80-120 kJ/mol to reproduce the range of slab surface temperature inferred from geothermometry, and 10-40 kJ/mol to reproduce the shallow hot mantle wedge core inferred from conditions of last equilibration of near-primary arc magmas and seismic tomographies. Therefore, an extra process controlling mantle wedge dynamics is needed to satisfy simultaneously the aforementioned observations. A mantle viscosity reduction, by a factor 4-20, caused by metasomatism in the mantle wedge is proposed. From these results, I conclude that the subduction channel down-dip extent, , should depend on the subduction setting, to be consistent with the observed variability of sub-arc depths of the subducting plate surface.
DS201806-1209
2018
Ardon, T., Ahline, N.Fancy deep brown-orange CVD synthetic diamond. 0.56 ctGems & Gemology, Vol. 54, 1, p. 64Technologysynthetics
DS201804-0670
2018
Armstrong, J.Mining and extracting the world's largest diamonds. Karowe4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 9-10. abstractAfrica, Botswanadeposit - Karowe
DS201809-1990
2018
Arndt, N., Roman, A.Numerical modelling reveals weaknesses in the sagduction model for the formation of Archean continental crust: relevance to the onset of plate tectonics.Goldschmidt Conference, 1p. AbstractMantleplate tectonics

Abstract: Recent studies conclude that plate tectonics started 3 b.y. ago in the mid Archean. A transition from a "presubduction" regime to modern plate tectonics is said to be marked by changes in trace-element or isotopic ratios, the appearance of eclogitic inclusions in diamonds, or an apparent change in upper crust composition. Behind these arguments is the notion that subduction was intermittent or impossible early in Earth history when the mantle was hotter. If so, a mechanism other than subduction must have created granitoids of Archean continental crust. In the sagduction model, the base of thick oceanic crust converts to eclogite, founders, and melts to generate granitic magma. Here we evaluate two crucial constraints on the sagduction process: to generate granitic magma requires that water and basalt is taken deep into the mantle; thick oceanic crust is internally differentiated into uppermost layers of hydrated basalt and lower mafic-ultramafic cumulates. Our numerical modelling shows that any deformation within thick, differentiated crust is restricted to the lower cumulates that lack ingredients essential to generate granitic magma. Emplacement of hot intrusions heats the lower crust which was hot and anhydrous. We conclude that the sagduction model is flawed. Recent re-evaluation gives temperatures in ambient Archean upper mantle only moderately higher than in modern mantle, which deflates arguments that subduction was impossible in the Archean. We conclude that Archean continental crust was generated in subduction zones and that plate tectonics started in the early Archean.
DS201812-2774
2018
Arnould, M., Coltice, N., Flament, N., Seigneur, V., Muller, R.D.On the scales of dynamic topography in whole- mantle convection models.Geochemistry, Geophysics, Geosystems, Vol. 19, 9, pp. 3140-3163.United States, Californiasubduction

Abstract: Mantle convection shapes Earth's surface by generating dynamic topography. Observational constraints and regional convection models suggest that surface topography could be sensitive to mantle flow for wavelengths as short as 1,000 and 250 km, respectively. At these spatial scales, surface processes including sedimentation and relative sea?level change occur on million?year timescales. However, time?dependent global mantle flow models do not predict small?scale dynamic topography yet. Here we present 2?D spherical annulus numerical models of mantle convection with large radial and lateral viscosity contrasts. We first identify the range of Rayleigh number, internal heat production rate and yield stress for which models generate plate?like behavior, surface heat flow, surface velocities, and topography distribution comparable to Earth's. These models produce both whole?mantle convection and small?scale convection in the upper mantle, which results in small?scale (<500 km) to large?scale (>104 km) dynamic topography, with a spectral power for intermediate scales (500 to 104 km) comparable to estimates of present?day residual topography. Timescales of convection and the associated dynamic topography vary from five to several hundreds of millions of years. For a Rayleigh number of 107, we investigate how lithosphere yield stress variations (1050 MPa) and the presence of deep thermochemical heterogeneities favor small?scale (200500 km) and intermediate?scale (500104 km) dynamic topography by controlling the formation of small?scale convection and the number and distribution of subduction zones, respectively. The interplay between mantle convection and lithosphere dynamics generates a complex spatial and temporal pattern of dynamic topography consistent with constraints for Earth.
DS201803-0433
2017
Ashchepekov, I.V., Ntaflos, T., Logvinova, A.M., Spetius, Z.V., Downes, H.Monomineral universal clinopyroxene and garnet barometers for peridotitic, eclogitic and basaltic systems.Geoscience Frontiers, Vol. 8, pp. 775-795.Mantlegeobarometry

Abstract: New versions of the universal Jd-Di exchange clinopyroxene barometer for peridotites, pyroxenites and eclogites, and also garnet barometer for eclogites and peridotites were developed. They were checked using large experimental data sets for eclogitic (?530) and peridotitic systems (>650). The precision of the universal Cpx barometer for peridotites based on Jd-Di exchange is close to Cr-Tschermakite method produced by Nimis and Taylor (2000). Cpx barometer was transformed by the substitution of major multiplier for KD by the equations dependent from Al-Na-Fe. Obtained equation in combination with the thermometer of Nimis and Taylor (2000) allow to reconstruct position of the magma feeder systems of the alkali basaltic magma within the mantle diapirs in modern platforms like in Vitim plateau and other Southern Siberia localities and several localities worldwide showing good agreement of pressure ranges for black and green suites. These equations allow construct PTX diagrams for the kimberlite localities in Siberia and worldwide calculating simultaneously the PT parameters for different groups of mantle rocks. They give very good results for the concentrates from kimberlite lamproites and placers with mantle minerals. They are useful for PT estimates for diamond inclusions. The positions of eclogite groups in mantle sections are similar to those determined with new Gar–Cpx barometer produced by C. Beyer et al. (2015). The Fe rich eclogites commonly trace the boundary between the lower upper parts of subcontinental lithospheric mantle (SCLM) at 3–4 GPa marking pyroxenite eclogites layer. Ca-rich eclogites and especially grospydites in SCLM beneath Precambrian kimberlites occurs near pyroxenite layer but in younger mantle sections they became common in the lower parts. The diamondiferous Mg Cr-less group eclogites referring to the ancient island arc complexes are also common in the middle part of mantle sections and near 5–6 GPa. Commonly eclogites in lower apart of mantle sections are remelted and trace the high temperature convective branch. The Mg- and Fe-rich pyroxenites also show the extending in pressure trends which suggest the anatexic melting under the influence of volatiles or under the interaction with plums.
DS201805-0933
2018
Asthana, D., Kumar, S., Vind, A.K., Zehra, F., Kumar, H., Pophare, A.M.Geochemical fingerprinting of ~2.5 Ga forearc-arc-backarc related magmatic suites in the Bastar Craton, central India.Journal of Asian Earth Sciences, Vol. 157, pp. 218-234.IndiaCraton

Abstract: The Pitepani volcanic suite of the Dongargarh Supergroup, central India comprises of a calc-alkaline suite and a tholeiitic suite, respectively. The rare earth element (REE) patterns, mantle normalized plots and relict clinopyroxene chemistry of the Pitepani calc-alkaline suite are akin to high-Mg andesites (HMA) and reveal remarkable similarity to the Cenozoic Setouchi HMA from Japan. The Pitepani HMAs are geochemically correlated with similar rocks in the Kotri-Dongargarh mobile belt (KDMB) and in the mafic dykes of the Bastar Craton. The rationale behind lithogeochemical correlations are that sanukitic HMAs represent fore-arc volcanism over a very limited period of time, under abnormally high temperature conditions and are excellent regional and tectonic time markers. Furthermore, the tholeiitic suites that are temporally and spatially associated with the HMAs in the KDMB and in the mafic dykes of the Bastar Craton are classified into: (a) a continental back-arc suite that are depleted in incompatible elements, and (b) a continental arc suite that are more depleted in incompatible elements, respectively. The HMA suite, the continental back-arc and continental arc suites are lithogeochemically correlated in the KDMB and in the mafic dykes of the Bastar Craton. The three geochemically distinct Neoarchaean magmatic suites are temporally and spatially related to each other and to an active continental margin. The identification of three active continental margin magmatic suites for the first time, provides a robust conceptual framework to unravel the Neoarchaean geodynamic evolution of the Bastar Craton. We propose an active continental margin along the Neoarchaen KDMB with eastward subduction coupled with slab roll back or preferably, ridge-subduction along the Central Indian Tectonic Zone (CITZ) to account for the three distinct magmatic suites and the Neoarchean geodynamic evolution of the Bastar Craton.
DS201812-2775
2018
Aulbach, S.Cratonic lithosphere discontinuities: dynamics of small volume melting, metacratonization, and a possible role of brines. Chapter from:Lithospheric Discontinuities, AGU Publ., abstract 1p.Mantlecraton

Abstract: Cratons represent modern Earth’s thickest, coldest and most depleted lithospheres. Reintroduction of volatiles led to gradual re-oxidation and refertilisation of initially highly refractory and reducing cratonic mantle, enabling the eventual deposition of carbonates and hydrous minerals, which can cause seismic velocity reductions appearing as mid-lithospheric discontinuities (MLDs). Ubiquitous small-volume potassic magmas erupted since at least the Palaeoproterozoic testify to the presence of such metasomes. Attendant rheological weakening and densification led to reworking up to complete loss of deep cratonic roots, i.e. meta-cratonisation. The depths of meta-cratonic lithosphere-asthenosphere boundaries (LABs),concentrated at ~80 to 150 km, strikingly overlap those of MLDs, which may have provided lithospheric weak zones along which the deep root could be removed during continent collision, flat subduction or rifting. Since most cratonic lithospheres are too cold for melt to be presently stable, some MLDs associated with reduced resistivities may point to a role for mantle brines, which bears further investigation. If small volumes of melt are required to generate the rarely observed seismic discontinuities at the depths of intact cratonic LABs (180-260 km), their presence places lower bounds on the amount of solidus-depressing volatiles in the underlying mantle volume, whereas their absence places upper bounds if temperature can be independently constrained.
DS201805-0934
2018
Aulbach, S., Creaser, R.A., Stachel, T., Kong, J.Diamond ages from Victor ( Superior craton): intra-mantle cycling of volatiles ( C.N.S) during supercontinent reorganisation.Earth Planetary Science Letters, Vol. 490, pp. 77-87.Canada, Ontariodeposit - Victor

Abstract: The central Superior Craton hosts both the diamondiferous 1.1 Ga Kyle Lake and Jurassic Attawapiskat kimberlites. A major thermal event related to the Midcontinent Rift at ca. 1.1 Ga induced an elevated geothermal gradient that largely destroyed an older generation of diamonds, raising the question of when, and how, the diamond inventory beneath Attawapiskat was formed. We determined Re-Os isotope systematics of sulphides included in diamonds from Victor by isotope dilution negative thermal ionisation mass spectrometry in order to obtain insights into the age and nature of the diamond source in the context of regional tectonothermal evolution. Regression of the peridotitic inclusion data (n = 14 of 16) yields a 718 ± 49 Ma age, with an initial 187Os/188Os ratio of 0.1177 ± 0.0016, i.e. depleted at the time of formation (?Os -3.7 ± 1.3). Consequently, Re depletion model ages calculated for these samples are systematically overestimated. Given that reported 187Os/188Os in olivine from Attawapiskat xenoliths varies strongly (0.1012-0.1821), the low and nearly identical initial Os of sulphide inclusions combined with their high 187Re/188Os (median 0.34) suggest metasomatic formation from a mixed source. This was likely facilitated by percolation of amounts of melt sufficient to homogenise Os, (re)crystallise sulphide and (co)precipitate diamond; that is, the sulphide inclusions and their diamond host are synchronous if not syngenetic. The ?720 Ma age corresponds to rifting beyond the northern craton margin during Rodinia break-up. This suggests mobilisation of volatiles (C, N, S) and Os due to attendant mantle stretching and metasomatism by initially oxidising and S-undersaturated melts, which ultimately produced lherzolitic diamonds with high N contents compared to older Kyle Lake diamonds. Thus, some rift-influenced settings are prospective with respect to diamond formation. They are also important sites of hidden, intra-lithospheric volatile redistribution that can be revealed by diamond studies. Later emplacement of the Attawapiskat kimberlites, linking the carbon cycle to the surface, was associated with renewed disturbance during passage of the Great Meteor Hotspot. Lherzolitic diamond formation from oxidising small-volume melts may be the expression of an early and deep stage of the lithospheric conditioning required for the successful eruption of kimberlites, which complements the late and shallow emplacement of volatile-rich metasomes after upward displacement of a redox freezing front.
DS201812-2776
2019
Aulbach, S., Heaman, L.M., Jacob, D.E., Viljoen, K.S.Ages and sources of mantle eclogites: ID-TIMS and in situ MC-ICPMS Pb-Sr isotope sytematics of clinopyroxene.Chemical Geology, Vol. 503, pp. 15-28.Mantleeclogite

Abstract: Strontium and Pb isotopic compositions of clinopyroxene (cpx) in selected samples from three well-characterised eclogite suites with oceanic crustal protoliths (Lace/Kaapvaal craton, Orapa/Zimbabwe craton and Koidu/West African craton) were acquired by high-precision isotope dilution thermal ionisation mass spectrometry (ID-TIMS) and in situ multicollector-laser ablation-inductively-coupled plasma mass spectrometry (MC-LA-ICPMS). The aims of this study are twofold: (1) assess their utility to obtain formation or resetting age constraints and identify elemental signatures that enhance the chances of successful age dating, and (2) to confirm the veracity and utility of results obtained by novel MC-LA-ICPMS techniques. Strontium-Pb isotope systematics of eclogitic cpx measured in this study are decoupled and may reflect addition of unsupported radiogenic Sr during seawater alteration or interaction with oceanic sediments in subduction mélanges, and/or disturbance due to mantle metasomatism, to which the more incompatible Pb is more susceptible. Despite a complex history, subsets of samples yield meaningful model dates. Clinopyroxene fractions from Lace with high Pb contents (36?ppm), unradiogenic Pb isotopic compositions (206Pb/204Pb?=?13.5713.52) and low 238U/204Pb (1.01.5) give single-stage model Pb dates of 2.902.84?Ga. In contrast, samples from Orapa plot to the right of the Geochron and do not yield meaningful Pb model ages. However, these data do define secondary isochrons that can be modelled to yield minimum age constraints on major events affecting the cratonic lithosphere. Within the uncertainties, the resultant 2.18?±?0.45?Ga age obtained for Koidu eclogites reflect disturbance of the Pb isotope system due to subduction beneath the craton linked to the Eburnean orogeny, while they retained their unradiogenic 87Sr/86Sr (0.7016). Similarly, the age for samples from Orapa (2.20?±?0.54?Ga) is interpreted as an overprint age related to Palaeoproterozoic accretion at the western craton margin. Gabbroic eclogites (Eu/Eu*?>?1) with plagioclase-rich protoliths having low time-integrated Rb/Sr and U/Pb retain the least radiogenic Sr and, in part, Pb. High model ? (9.0 to 9.1) for several eclogites from Lace with elevated LREE, Th and Pb abundances reflects ca. 3.0?Ga addition of a sedimentary component, possibly derived from reworking of a high-? basaltic protocrust, as observed on other cratons. We suggest that sample targeting can be usefully guided by fast-throughput in situ LA-ICPMS techniques, which largely yield results identical to ID-TIMS, albeit at lower precision, and which can further help identify kimberlite contamination in the mineral separates used for solution work.
DS201812-2777
2018
Aulbach, S., Heaman, L.M., Stachel, T.Diavik deposit: The diamondiferous mantle root beneath the central Slave craton.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp.319-342.Canada, Northwest Territoriesdeposit - Diavik
DS201809-1991
2017
Aulbach, S., Jacob, D.E., Cartigny, P., Stern, R.A., Simonetti, S.S., Worner, G., Viljoen, K.S.Eclogite xenoliths from Orapa: Ocean crust recycling, mantle metasomatism and carbon cycling at the western Zimbabwe craton margin.Geochimica et Cosmochimica Acta, Vol. 213, 1, pp. 574-592.Africa, Botswanadeposit - Orapa

Abstract: Major- and trace-element compositions of garnet and clinopyroxene, as well as 87Sr/86Sr in clinopyroxene and ?18O in garnet in eclogite and pyroxenite xenoliths from Orapa, at the western margin of the Zimbabwe craton (central Botswana), were investigated in order to trace their origin and evolution in the mantle lithosphere. Two groups of eclogites are distinguished with respect to 87Sr/86Sr: One with moderate ratios (0.7026-0.7046) and another with 87Sr/86Sr >0.7048 to 0.7091. In the former group, heavy ?18O attests to low-temperature alteration on the ocean floor, while 87Sr/86Sr correlates with indices of low-pressure igneous processes (Eu/Eu?, Mg#, Sr/Y). This suggests relatively undisturbed long-term ingrowth of 87Sr at near-igneous Rb/Sr after metamorphism, despite the exposed craton margin setting. The high-87Sr/86Sr group has mainly mantle-like ?18O and is suggested to have interacted with a small-volume melt derived from an aged phlogopite-rich metasome. The overlap of diamondiferous and graphite-bearing eclogites and pyroxenites over a pressure interval of ?3.2 to 4.9 GPa is interpreted as reflecting a mantle parcel beneath Orapa that has moved out of the diamond stability field, due to a change in geotherm and/or decompression. Diamondiferous eclogites record lower median 87Sr/86Sr (0.7039) than graphite-bearing samples (0.7064) and carbon-free samples (0.7051), suggesting that interaction with the - possibly oxidising - metasome-derived melt caused carbon removal in some eclogites, while catalysing the conversion of diamond to graphite in others. This highlights the role of small-volume melts in modulating the lithospheric carbon cycle. Compared to diamondiferous eclogites, eclogitic inclusions in diamonds are restricted to high FeO and low SiO2, CaO and Na2O contents, they record higher equilibrium temperatures and garnets have mostly mantle-like O isotopic composition. We suggest that this signature was imparted by a sublithospheric melt with contributions from a clinopyroxene-rich source, possibly related to the ca. 2.0 Ga Bushveld event.
DS201805-0935
2017
Aulbach, S., Sun, J., Tappe, S., Hofer, H.E., Gerdes, A.Volatile rich metasomatism in the cratonic mantle beneath SW Greenland: link to kimberlites and mid-lithospheric discontinuities.Journal of Petrology, Vol. 58, 12, pp. 2311-2338.Europe, Greenlandkimberlite

Abstract: The cratonic part of Greenland has been a hotspot of scientific investigation since the discovery of some of the oldest crust on Earth and of significant diamond potential in the underlying lithospheric mantle, the characterization of which remains, however, incomplete. We applied a detailed petrographic and in situ analytical approach to a new suite of fresh kimberlite-borne peridotite xenoliths, recovered from the North Atlantic craton in SW Greenland, to unravel the timing and nature of mantle metasomatism, and its link to the formation of low-volume melts (e.g. kimberlites) and to geophysically detectible discontinuities. Two types of mineralogies and metasomatic styles, occurring at two depth intervals, are recognized. The first type comprises lherzolites, harzburgites and dunites, some phlogopite-bearing, which occur from ?100-170?km depth. They form continuous trends towards lower mineral Mg# at increasing TiO2, MnO and Na2O and decreasing NiO contents. These systematics are ascribed to metasomatism by a hydrous silicate melt precursor to c. 150?Ma kimberlites, in the course of rifting, decompression and lithosphere thinning. This metasomatism was accompanied by progressive garnet breakdown, texturally evident by pyroxene-spinel assemblages occupying former coarse grains and compositionally evident by increasing concentrations of elements that are compatible in garnet (Y, Sc, In, heavy rare earth elements) in newly formed clinopyroxene. Concomitant sulphide saturation is indicated by depletion in Cu, Ni and Co. The residual, more silica-undersaturated and potentially more oxidizing melts percolated upwards and metasomatized the shallower lithospheric mantle, which is composed of phlogopite-bearing, texturally equilibrated peridotites, including wehrlites, showing evidence for recent pyroxene-breakdown. This is the second type of lithology, which occurs at ?90-110?km depth and is inferred to have highly depleted protoliths. This type is compositionally distinct from lherzolites, with olivine having higher Ca/Al, but lower Al and V contents. Whereas low Al may in part reflect lower equilibration temperatures, low V is ascribed to a combination of intrinsically more oxidizing mantle at lower pressure and oxidative metasomatism. The intense metasomatism in the shallow cratonic mantle lithosphere contrasts with the strong depletion recorded in the northwestern part of the craton, which at 590-550?Ma extended to >210?km depth, and suggests loss of ?40?km of lithospheric mantle, also recorded in the progressive shallowing of magma sources during the breakup of the North Atlantic craton. The concentration of phlogopite-rich lithologies in a narrow depth interval (?90-110?km) overlaps with a negative seismic velocity gradient that is interpreted as a mid-lithospheric discontinuity beneath western Greenland. This is suggested to be a manifestation of small-volume volatile-rich magmatism, which paved the way for Mesozoic kimberlite, ultramafic lamprophyre, and carbonatite emplacement across the North Atlantic craton.
DS201804-0671
2018
Aurisicchio, C., Conte, A.M., Medeghini, L., Ottolini, L., De Vito, C.Major and trace element geochemistry of emerald from several deposits: implications for genetic models and classification schemes.Ore Geology Reviews, Vol. 94, pp. 351-366.Globalemerald classification

Abstract: In the present work, we report the chemical composition of representative emerald crystals from some of the most important worldwide deposits. Major and trace elements were investigated using Electron Microprobe Analysis (EMPA) and Secondary Ion Mass Spectrometry (SIMS) techniques. Binary, ternary and spider diagrams along with statistical analysis, i.e., Principal Component Analysis (PCA), were used to discriminate each deposit with high reliability. PCA of SiO2, Al2O3, V, Sc, B, Li content identified distinct groups. The use of binary and ternary diagrams contributed to discriminate among emerald crystals from various deposits, which are included in the same clusters of the PCA analysis. In addition, the geochemical features of each group were linked to the geological environment and genetic processes which leaded to emerald formation. In particular, the emeralds related to granitic-pegmatitic intrusions (Type-1) or those occurring in environments controlled by tectonic events (Type-2) were distinguished using the concentrations of major and trace elements. The results of this study can contribute to improve the existing genetic models and classification schemes as well as to identify useful geochemical fingerprints for provenance purposes.-
DS201808-1724
2018
Avice, G., Marty, B., Burgess, R., Hofmann, A., Philippot, P., Zahnle, K., Zakharov, D.Evolution of atmospheric xenon and other noble gases inferred from Archean to Paleoproterozoic rocks.Geochimica et Cosmochimica Acta, Vol. 232, pp. 82-100.Mantlegeochemistry

Abstract: We have analyzed ancient atmospheric gases trapped in fluid inclusions contained in minerals of Archean (3.3?Ga) to Paleozoic (404?Ma) rocks in an attempt to document the evolution of the elemental composition and isotopic signature of the atmosphere with time. Doing so, we aimed at understanding how physical and chemical processes acted over geological time to shape the modern atmosphere. Modern atmospheric xenon is enriched in heavy isotopes by 30-40‰ u?1 relative to Solar or Chondritic xenon. Previous studies demonstrated that, 3.3?Ga ago, atmospheric xenon was isotopically fractionated (enriched in the light isotopes) relative to the modern atmosphere, by 12.9?±?1.2 (1?) ‰ u?1, whereas krypton was isotopically identical to modern atmospheric Kr. Details about the specific and progressive isotopic fractionation of Xe during the Archean, originally proposed by Pujol et al. (2011), are now well established by this work. Xe isotope fractionation has evolved from 21‰ u?1 at 3.5?Ga to 12.9‰ u?1 at 3.3?Ga. The current dataset provides some evidence for stabilization of the Xe fractionation between 3.3 and 2.7?Ga. However, further studies will be needed to confirm this observation. After 2.7?Ga, the composition kept evolving and reach the modern-like atmospheric Xe composition at around 2.1?Ga ago. Xenon may be the second atmospheric element, after sulfur, to show a secular isotope evolution during the Archean that ended shortly after the Archean-Proterozoic transition. Fractionation of xenon indicates that xenon escaped from Earth, probably as an ion, and that Xe escape stopped when the atmosphere became oxygen-rich. We speculate that the Xe escape was enabled by a vigorous hydrogen escape on the early anoxic Earth. Organic hazes, scavenging isotopically heavy Xe, could also have played a role in the evolution of atmospheric Xe. For 3.3?Ga-old samples, Ar-N2 correlations are consistent with a partial pressure of nitrogen (pN2) in the Archean atmosphere similar to, or lower than, the modern one, thus requiring other processes than a high pN2 to keep the Earth's surface warm despite a fainter Sun. The nitrogen isotope composition of the atmosphere at 3.3?Ga was already modern-like, attesting to inefficient nitrogen escape to space since that time.
DS201809-1992
2018
Babinski, M., McGee, B., do Couto Tokashiki, C., Tassinari, C.C.G., Souza Saes, G., Cavalante Pinho, F.E.Comparing two arms of an orogenic belt during Gondwana amalgamation: age and provenance of Cuiaba Group, northern Paraguay, Brazil.South American Earth Sciences, Vol. 85, pp. 6-42.South America, Brazilgeochronology

Abstract: The Cuiabá Group is the basal part of the sequence of passive margin sediments that unconformably overly the Amazonian Craton in central Brazil. Despite these rock's importance in understanding Brazil's path in the supercontinent cycle from Rodinia to Gondwana and their potential record of catastrophic glaciation their internal stratigraphy and relationship to other units is still poorly understood. The timing of deposition and source areas for the subunits of the Cuiabá Group sedimentary rocks are investigated here using integrated U-Pb and Sm-Nd isotope data. We sampled in the northern Paraguay Belt, a range that developed in response to the collision between the Amazonian Craton, the Rio Apa Block, the São Francisco Craton and the Paranapanema Block. 1125 detrital zircon LA-ICPMS U-Pb ages were calculated and 22 whole rock samples were used for Sm-Nd isotope analysis. The U-Pb ages range between Archean and Neoproterozoic and the main source is the Sunsás Province. Moving up stratigraphy there is a subtle increase in slightly younger detritus with the youngest grain showing an age of 652?±?5 Ma, found at the top of the sequence. The age spectra are similar across each of the sampled units and when combined with the Sm-Nd data, indicate that the source of the detritus was mostly similar throughout deposition. This is consistent with the analysis here that indicates sedimentation occurred in a passive margin environment on the southern margin of the Amazonian Craton. The maximum depositional age of 652?±?5 Ma along with the age of the overlying cap carbonate of the Mirassol d’Oeste Formation suggests that part of this section of sediments were deposited in the purportedly global ?636 Ma Marinoan glaciation, although we give no sedimentological evidence for glaciation in the study area. Compared to the southern Paraguay Belt where no direct age constraints exist, the glacial epoch could be either Cryogenian or Ediacaran. In addition, available data in the literature indicates a diachronous evolution between the northern and southern arms of the Paraguay Belt in the final stages of deposition and deformation.
DS201806-1210
2018
Babushkina, M.S., Ugolkov, V.L., Marin, Yu.B., Nikitina, L.P., Goncharov, A.G.Hydrogen and carbon groups in the structures of rock forming minerals of rocks of the lithospheric mantle: FTIR and STA + QMS data. Lherzolites, peridotitesDoklady Earth Sciences, Vol. 479, 2, pp. 456-459.Russia, Siberiadeposit - Udachnaya

Abstract: Using IR-Fourier spectrometry (FTIR) and simultaneous thermal analysis combined with quadrupole mass spectrometry of thermal decomposition products (STA + QMS), olivines and clinopyroxene from xenolites of spinel and garnet lherzolites contained in kimberlites and alkaline basalts were studied to confirm the occurrence of hydrogen and carbon within the structure of the minerals, as well as to specify the forms of H and C. The presence of hydroxyl ions (OH-) and molecules of crystal hydrate water (H2Ocryst) along with CO2, CH, CH2, and CH3 groups was detected, which remained within the structures of mantle minerals up to 1300°C (by the data of both techniques). The total water (OH-and H2Ocryst) was the prevailing component of the C-O-H system.
DS201811-2553
2018
Badredinov, Z.G., Markovsky, B.A., Tararin, I.A., Ekimova, N.I., Chubarov, V.M.Fluid silicate seperation of an ultrabasic melt into high potassium and low potassium fractions: evidence from picrites of the Late Cretaceous ultrabasic volcanic complex, eastern Kamchatka.Russian Journal of Pacific Geology, Vol. 12, 5, pp. 408-418.Russia, Kamchatkapicrites

Abstract: The mineral and chemical compositions of the layered subvolcanic ultrabasic rocks formed through fluid-silicate (liquid) separation of the ultrabasic magma into high-potassium and low-potassium fractions are characterized by the example of the layered picritic sill from the Late Cretaceous ultrabasic volcanic complex of Eastern Kamchatka. It is determined that the main potassium concentrator in the picrites from the high-potassium layers is a residual volcanic glass containing up to 8-9 wt % K2O, which is unique for ultrabasic melts.
DS201802-0220
2017
Baes, M., Sobolev, S.V.Mantle flow as a trigger for subduction initiation: a missing element of the Wilson Cycle concept.Geochemistry, Geophysics, Geosystems, Vol. 18, 12, pp. 4469-4486.Mantlesubduction

Abstract: The classical Wilson Cycle concept, describing repeated opening and closing of ocean basins, hypothesizes spontaneous conversion of passive continental margins into subduction zones. This process, however, is impeded by the high strength of passive margins, and it has never occurred in Cenozoic times. Here using thermomechanical models, we show that additional forcing, provided by mantle flow, which is induced by neighboring subduction zones and midmantle slab remnants, can convert a passive margin into a subduction zone. Models suggest that this is a long-term process, thus explaining the lack of Cenozoic examples. We speculate that new subduction zones may form in the next few tens of millions of years along the Argentine passive margin and the U.S. East Coast. Mantle suction force can similarly trigger subduction initiation along large oceanic fracture zones. We propose that new subduction zones will preferentially originate where subduction zones were active in the past, thus explaining the remarkable colocation of subduction zones during at least the last 400 Myr.
DS201810-2294
2018
Balashova, A., Mattsson, H.B., Hirt, A.M.New tephrostratigraphic data from Lake Emakat ( northern Tanzania): implications for the eruptive history of the Oldoinyo Lengai volcano. ( melilitites)Journal of African Earth Sciences, Vol. 147, pp. 374-382.Africa, Tanzaniadeposit - Oldoinyo Lengai

Abstract: The northern Tanzanian sector of the Gregory Rift is an area of an active continental rifting, in which sedimentation processes are strongly affected by volcanism. Due to limited stratigraphic exposure, the volcanic record of the region is rather sparse, and assigning volcanic centres for the individual eruptions is difficult. This study presents new data on the tephrostratigraphy of the sedimentary sequence of Lake Emakat, Empakaai Crater, northern Tanzania. Seven volcanic ash layers are identified and described from a 1.1-m core of lake sediments. Geochemical, mineralogical, petrographic and magnetic analyses show that: (1) all ash layers are products of highly explosive eruptions of melilite-bearing magmas; (2) most of the eruptions originate from a complex magmatic system; (3) all ash horizons are very well preserved in the lake environment; and (4) there are significant fluctuations of the bulk magnetic susceptibility of the lacustrine sediments which is related to microtephra from additional eruptions, the result of detritus, washed from the shore during periods of strong lake level fluctuations or periods of high erosion rates, or simply by the contamination by the material from the ash layers. Based on geochemistry and mineralogy of the seven identified ash layers in Lake Emakat, combined with the eruption ages from ¹?C datings, we can pinpoint Oldoinyo Lengai volcano as the source of these specific layers. The combination of this new data with existing chronological data from Ryner et al. (2007), retrieved from the same core, provides precise ages of the voluminous highly explosive eruptions in this region of East Africa during the Pleistocene-Holocene transition.
DS201801-0002
2017
Balasubramani, S., Sahoo, P., Bhattacharya, D., Rengarajan, M., Thangavel, S., Bhatt, A.K., Verma, M.B., Nanda, L.K.A note on anomalous concentration of scandium in the Pakkanadu alkaline complex, Salem District, Tamil Nadu, India.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 46.Indiaalkaline rocks

Abstract: Pakkanadu Alkaline complex (PAC) of Neoproterozoic age is located at the southwestern end of Dharmapuri rift/shear zone on the northern part of southern granulitic terrain in Tamil Nadu, India. PAC mainly comprises carbonatite-syenitepyroxenite suite of rocks. Syenite is the predominant rock exposed on the eastern and western part of the explored area with enclaves of pyroxenite and dunite. The carbonatite (sovite) occurs as thin veins/bands and discontinuous lenticular bodies intrusive into highly deformed biotite schist that is considered as the fenitised product of pyroxenite traceable over a strike length of 1.5 km. Petromineralogical study of the biotite schist, pyroxenite containing carbonatite rock and carbonatite indicated presence of monazite, allanite, sphene and betafite as the main radioactive minerals occurring as inclusion within biotite or as discrete mineral grains. Other ore minerals are apatite, thorite, titanite, rutile and barite. Chloritisation, hematitisation, silicification and calcitisation are the main wall rock alteration observed in pyroxenite and syenite. Sub-surface exploration carried out by Atomic Minerals Directorate (AMD) in PAC revealed that biotite schist (n=166) contains anomalously high concentration of Scandium (11-1275 ppm, av.161 ppm), REE (67-58275 ppm, av. 14836 ppm,) and V (5-620 ppm, av. 127 ppm, with carbonatite veins and syenite (n=149) contain scandium (10-462 ppm, av.71 ppm,), REE (18-57510 ppm, av. 4106 ppm) and V (1-285 ppm, av. 48 ppm). In these rocks, LREE (12.5-57670 ppm, av. 9617 ppm, n=315) shows enrichment over HREE (7.1-774 ppm, av. 173 ppm, n=315). The concentration of Scandium (Av. 166 and 71 ppm in biotite schist and syenite respectively) is anomalous as compared to its crustal abundance (22 ppm). Geochemical analyses of the rock indicate that the radioactive biotite schist, pyroxenite containing carbonatite veins generally shows higher Sc and REE concentrations as compared to those of the other rocks (syenite). However, there is no significant correlation between REE and Sc. The higher concentration of scandium in PAC is possibly due to selective partitioning of it into minerals like apatite, pyrochlore, allanite, monazite and other REE bearing phases, apart from its concentration in the ferromagnesian minerals. Scandium rarely concentrates in nature as independent ore mineral. The demand for the metal is very high due to multiple high value commercial uses as an alloy with aluminum, specifically in aerospace and automobile industry, besides, in solid oxide fuel cells (SOFC) in electrical industries. Eight boreholes drilled as part of the preliminary subsurface exploration in PAC, covering an area of 0.05 sq. km, indicated an elevated Scandium content of about 6 times that of the average crustal abundance.
DS201801-0003
2017
Banerjee, A., Chakrabuti, R.Major, trace element compositions and Nd, Sr and stable Ca isotopic compositions of carbonatites and alkaline silicate rocks of the Amba Dongar carbonatite complex, India: role of mantle mineralogy and subducted carbonates.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 18.Indiadeposit - Amba Dongar

Abstract: Carbonatites, with limited spatial but wide temporal occurrences, are unique igneous rocks with more than 50% modal carbonate. Geochemically carbonatites are characterized by high La/Yb(N) and enrichment in the Ba, Sr concentrations and superchondritic whole-rock Nb/Ta (~35) and Zr/Hf ratios (~60). Most of the global carbonatites are associated with the alkaline silicate rocks and their origin is highly debated. To understand the petrogenesis of carbonatites, we present geochemical and isotopic data, including the first ever measurements of Ca stable isotopes in the ~65 Ma old carbonatites and associated silicate rocks occurring in the Amba Dongar carbonatitic complex in Western India We have performed a detail geochemical and isotopic investigation of the carbonatites and associated silicate rocks occurring in the Amba Dongar carbonatitic complex in Western India. The analysed carbonatites are primarily calcitic and ankeritic in nature. The associated silicate rocks can be classified into two groups, the first being highly Krich and alkaline while the second group is tholeiitic in nature. The high La/Yb(N) ratio of carbonatites are suggestive of low degree partial melting while the enrichment in large ion lithophile elements (LILE) of the silicate rocks suggest that these rocks are derived from a LILE enriched upper mantle source. The carbonatites and the associated alkaline silicate rocks from the Amba Dongar carbonatite complex show overlapping Nd-Sr isotopic compositions with the tholeiitic rocks from the Phenai Mata complex, located approximately 16 km NW of Amba Dongar. Variability in ? 44/40Ca in Hawaiian shield stage tholeiites have been interpreted as evidence of subducted ancient marine carbonates, with very low -44/40Ca, into the Hawaiian plume (Huang et al., 2010). Boron isotopic composition of global carbonatites suggests that subducted crustal components contributed to the mantle source of relatively young carbonatites (<300 Ma old) (Hulett et al., 2016), a signature which should potentially be traceable using Ca isotopes. We report -44/40Ca of carbonatites and associated alkaline silicate rocks from the Amba Dongar complex. The samples were analyzed using a 43Ca-48Ca double spike on a Thermo Fischer Triton Plus Thermal Ionization Mass Spectrometer (TIMS) at IISc. ?44/40Ca in these rocks show a significant variation (~0.6 ‰- (w.r.t. SRM 915a), which is much larger than the variation observed in limited analyses of global carbonatites (Amini et al., 2009). Our external reproducibility, estimated from multiple analyses of NIST standards SRM 915a, SRM 915b and seawater (NASS6), is better than 0.1 - (2SD). ?44/40Ca of the ~65 Ma old Amba Dongar carbonatites shows correlations with Nb/Yb, K/Rb as well as with Sr/Nb, Sr/Zr. These variations suggest the role of phlogopite versus amphibole in the mantle source as well sas subducted carbonates in controlling the ?44/40Ca of these carbonatites.
DS201803-0434
2018
Banerjee, S., Kyser, T.K., Mitchell, R.H.Oxygen and hydrogen isotopic composition of phlogopites and amphiboles in diamond bearing kimberlite hosted MARID xenoliths: constraints on fluid-rock interaction and recycled crustal material in the deep continental lithospheric mantle.Chemical Geology, Vol. 479, pp. 272-285.Africa, South Africadeposit - Kimberley

Abstract: MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside) xenoliths are transported from the deep-cratonic lithosphere to the Earth's surface by Cretaceous kimberlites emplaced in the Kimberley area of the Kaapvaal Craton. MARID xenoliths have high modal abundances (70-80?vol%) of mica and amphibole, indicating their origin from a hydrous source. The ?18O values (4.7????18O???6.9‰) of phlogopite micas from 14 MARID samples indicate that these minerals are both 18O-enriched and 18O-depleted with respect to the average upper mantle ?18O value of 5.8?±?0.6‰. The range of ?2H values of phlogopites (?83????2H????53‰, n?=?14) of MARID xenoliths are slightly larger than the average mantle ?2H value (?70?±?10‰). The oxygen (?18Ophlogopites-amphibole?=??0.4 and 0.4‰) and hydrogen (?2Hphlogopite-amphibole?=?14 and 36‰) isotopic disequilibrium recorded from two MARID xenoliths suggests the duration of the last isotopic exchange, possibly just before the kimberlite emplacement, between these minerals and metasomatic fluids was too short to reach isotopic equilibrium. Our model calculation indicates that the phlogopites of MARID xenoliths underwent isotopic exchange with fluids of ?18O?=?5.5 to 10‰, ?2H?=??62 to ?90‰. The range of ?18O value of the calculated metasomatic fluids resembles the oxygen isotopic composition of the primary mantle carbonate (~ 6-9‰) suggesting interaction between carbonatic melt and MARID xenoliths in the continental lithospheric mantle. Furthermore, ?18O values of phlogopites together with previously published nitrogen isotope data (?11 ? ?15N ? 9‰; Banerjee et al., 2015) indicates incorporation of inhomogeneously distributed recycled crustal material from subducted crust within their source magma. Therefore, O-H-N isotope data for MARID xenoliths indicates their crystallization from geochemically heterogeneous magma in the upper continental mantle and subsequent metasomatism with mantle fluids.
DS201806-1211
2018
Baranov, A.A., Bobrov, A.M.Crustal structure and properties of Archean cratons of Gondwanaland: similarity and difference.Russian Geology and Geophysics, Vol. 59, pp. 512-524.Africa, Australia, South America, Indiacraton

Abstract: This is a synopsis of available data the on crustal structure and properties of thirteen Archean cratons of Gondwanaland (the cratons of Africa, Australia, Antarctica, South America, and the Indian subcontinent). The data include estimates of surface area, rock age and lithology, Moho depth, thickness of lithosphere and sediments, as well as elevations, all summarized in a table. The cratons differ in size from 0.05 x 106 km2 (Napier craton) to 4 x 106 km2 (Congo craton) and span almost the entire Archean period from 3.8 to 2.5 Ga. Sediments are mostly thin, though reach 7 km in the Congo and West African cratons. Elevations above sea level are from 0 to 2 km; some relatively highland cratons (Kaapvaal, Zimbabwe, and Tanzanian) rise to more than 1 km. On the basis of regional seismic data, the Moho map for cratons has been improved. The Moho diagrams for each craton are constructed. The analysis of the available new data shows that the average Moho depth varies from 33 to 44 km: Pilbara (33 km), Grunehogna (35 km), Sao Francisco (36 km), Yilgarn (37 km), Dharwar (38 km), Tanzanian (39 km), Zimbabwe (39 km), Kaapvaal (40 km), Gawler (40 km), Napier (40 km), West Africa (40 km), Congo (42 km), and Amazon (44 km) cratons. The Moho depth within the cratons is less uniform than it was assumed before: from 28 to 52 km. The new results differ significantly from the earlier inference of a relatively flat Moho geometry beneath Archean cratons. According to the new data, early and middle Archean undeformed crust is characterized by a shallow Moho depth (28-38 km), while late Archean or deformed crust may be as thick as 52 km.
DS201809-1993
2018
Barnett, W., Stubley, M., Hetman, C., Uken, R., Hrkac, C., McCandless, T.Kelvin and Faraday kimberlite emplacement geometries and implications for subterranean magmatic processes.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0621-8 16p.Canada, Northwest Territoriesdeposit - Kelvin, Faraday

Abstract: The Kennady North Project kimberlites (Northwest Territories of Canada) comprises multiple shallow dipping dykes and several volcaniclastic bodies that have an unusual shallow plunging geometry and complex "pipe" shapes that are termed chonoliths. The detailed exploration of the entire system provides exceptional evidence for subterranean volcanic conduit growth processes. The possible processes leading to the development of the kimberlite bodies are discussed, with emphasis on the importance of the subsurface intrusive system geometry and the local stress tensor. Emplacement into a locally compressive stress regime (i.e. ?1 and ?2 inclined at a low angle to surface) could change the kimberlite emplacement geometries to that observed at Kennady North. Models are proposed for the development of the chonoliths, to emphasize aspects of the growth of kimberlite systems that are not well understood. The conclusions challenge or evolve current emplacement models and should influence kimberlite exploration and resource definition assumptions.
DS201804-0672
2017
Baryshnikov, V.D., Fedyanin, A.S., Pul, E.K., Baryshnikov, D.V.Geomechanical monitoring of open pit bottom reserves in Mir mine, Alrosa: results.Journal of Mining Science, Vol. 53, 1, pp. 34-42.Russiadeposit - Mir

Abstract: The authors propose methods and means to monitor deformation and subsidence of ore crown under mining of open-pit bottom reserves by room-and-pillar system with cemented backfill in Mir Mine, ALROSA. The article describes layout and data of geomechanical monitoring. The mechanism of ore subsidence at the lower boundary of the safety pillar is determined.
DS201809-1994
2018
Bassoo, R., Befus, K.The magmatic origin and provenance of Guyana's diamonds: a first look.Goldschmidt Conference, 1p. AbstractSouth America, Guyanaalluvials

Abstract: Placer diamonds from the Proterozoic and Paleoproterozoic terranes of the Guiana Shield in Guyana, have an enigmatic geochemistry and provenance. Diamonds may be derived from kimberlite intrusions, but no outcrops have been identified in the dense tropical terrain. Alternatively, they may be weathered from 1.79 Ga, NE-SW trending mafic dykes of the Avanavero suite or eroded from 1.95 to 1.78 Ga sandstones and conglomerates of the Roraima Formation into recent alluvial river bed deposits [1]. To resolve these uncertainties, we acquired initial samples of 212 placer diamonds from different locations in Guyana for study. Diamonds range in size from 1.1 mm to 1.7 mm with a mean diameter of 1.3±0.2 mm. Diamonds are primarily dodecahedral to cubic, with lesser octahedral and minor macle forms. The diamonds are colourless to brown and most have a green surface skin. Diamond surfaces show diverse textures, including frosting, edge abrasions, network patterns, and ruts. Dissolution features are common and include point bottom trigons, with a diameter of 21±15 ?m. We measured N concentrations using FTIR (measured at 1282 cm-1). Diamonds are Type IaA-IaB with N concentrations of 55 ppm to 210 ppm. Total N ppm vs %NB ratios indicate mantlederived conditions of 1200 ºC and 4.7 GPa. Calculated Shields Parameter shear stresses of 0.0009 dynes/cm2 to 0.0016 dynes/cm2 suggest diamonds could be transported in bedloads derived from medium to very coarse sandstones or coarse- to pebble-sized kimberlitic lithics. Guyana’s diamonds are dissimilar to those from other regions of the Guiana Shield. To further this comparison, we studied 8 diamonds from Eastern Venezuela and Western Colombia on loan from the Smithsonian Museum of Natural History. Compared to Venezuelan and Colombian diamonds, Guyana’s diamonds are dodecahedral, and have a higher degree of dissolution textures, suggestive of higher ƒO2 conditions during kimberlite magma ascent. We will continue to study Guyana’s diamonds using a combination of electron microprobe, ?XRD, and Raman analyses of inclusions. Taken together we hope to infer the provenance of Guyana’s placer diamonds and the petrology of the mantle rocks from which they were derived.
DS201812-2778
2018
Bataleva, Yu.V., Palyanov, Yu.N., Borzdov, Yu.M., Novoselov, I.D., Bayukov, O.A., Sobolev, N.V.Conditions of formation of iron-carbon melt inclusions in garnet and orthopyroxene under P-T conditions of lithospheric mantle.Petrology, Vol. 26, 6, pp. 565-574.Mantleredox

Abstract: Of great importance in the problem of redox evolution of mantle rocks is the reconstruction of scenarios of alteration of Fe0- or Fe3C-bearing rocks by oxidizing mantle metasomatic agents and the evaluation of stability of these phases under the influence of fluids and melts of different compositions. Original results of high-temperature high-pressure experiments (P = 6.3 GPa, T = 13001500°?) in the carbideoxidecarbonate systems (Fe3CSiO2(Mg,Ca)CO3 and Fe3CSiO2Al2O3(Mg,Ca)CO3) are reported. Conditions of formation of mantle silicates with metallic or metalcarbon melt inclusions are determined and their stability in the presence of CO2-fluid representing the potential mantle oxidizing metasomatic agent are estimated. It is established that garnet or orthopyroxene and CO2-fluid are formed in the carbideoxidecarbonate system through decarbonation, with subsequent redox interaction between CO2 and iron carbide. This results in the formation of assemblage of Fe-rich silicates and graphite. Garnet and orthopyroxene contain inclusions of a FeC melt, as well as graphite, fayalite, and ferrosilite. It is experimentally demonstrated that the presence of CO2-fluid in interstices does not affect on the preservation of metallic inclusions, as well as graphite inclusions in silicates. Selective capture of FeC melt inclusions by mantle silicates is one of the potential scenarios for the conservation of metallic iron in mantle domains altered by mantle oxidizing metasomatic agents.
DS201806-1212
2018
Bataleva, Yu.V., Palyanov, Yu.N., Borzdov, Yu.N., Zdrokov, E.V., Novoselov, I.D., Sobolev, N.V.Formation of the Fe, Mg-silicates, FeO, and graphite ( diamond) assemblage as a result of cohenite oxidation under lithospheric mantle conditions.Doklady Earth Sciences, Vol. 479, 1, pp. 335-338.Mantlegraphite

Abstract: Experimental studies in the Fe3C-SiO2-MgO system (P = 6.3 GPa, T = 1100-1500°C, t = 20-40 h) have been carried out. It has been established that carbide-oxide interaction resulted in the formation of Fe-orthopyroxene, graphite, wustite, and cohenite (1100 and 1200°C), as well as a Fe-C-O melt (1300-1500°C). The main processes occurring in the system at 1100 and 1200°C are the oxidation of cohenite, the extraction of carbon from carbide, and the crystallization of metastable graphite, as well as the formation of ferrosilicates. At T ? 1300°C, graphite crystallization and diamond growth occur as a result of the redox interaction of a predominantly metallic melt (Fe-C-O) with oxides and silicates. The carbide-oxide interaction studied can be considered as the basis for modeling a number of carbon-producing processes in the lithospheric mantle at fO2 values near the iron-wustite buffer.
DS201803-0435
2007
Battilani, G.A., Newton, S.G., Guerra, W.J.The occurrence of microdiamonds in Mesoproterozoic Chapada Diamantin a intrusive rocks: bahia, Brazil.Anais da Academia Brasileira de Ciencas, Vol. 79, pp. 321-332.South America, Brazilmicrodiamonds

Abstract: The origin of diamonds from Serra do Espinhaço in Diamantina region (State of Minas Gerais) and in Chapada Diamantina, Lençóis region (State of Bahia) remains uncertain, even taking into account the ample research carried out during the last decades. The lack of typical satellite minerals in both districts makes a kimberlitic source for these diamonds uncertain. In mid 18th century the occurrence of a metamorphosed igneous rock composed of martite, sericite and tourmaline was described in Diamantina region and named hematitic phyllite, considered by some researchers as a possible diamond source. Similar rocks were found in Lençóis and examined petrographically and their heavy mineral concentration was investigated by means of scanning electron microscopy (SEM). Petrographic analyses indicated an igneous origin for these rocks and SEM analyses showed the discovery of microdiamonds. Geochronological studies using the Ar/Ar technique in muscovites yielded minimum ages of 1515+/-3 Ma, which may correlate with 1710+/-12 Ma from U-Pb method in igneous zircons from the hematitic phyllites. Both rock types also have the same mineral and chemical composition which leads to the conclusion that the intrusive rocks were protolith of the hematitic phyllites. This first discovery of microdiamonds in intrusive rocks opens the possibility of new investigation models for diamond mineralization in Brazilian Proterozoic terrains.
DS201808-1725
2018
Baudouin, C., Parat, F., Michel, T.CO2 rich phonolitic melt and carbonatite immiscibility in early stage of rifting: melt inclusions Hanang volcano, Tanzania.Journal of Volcanology and Geothermal Research, Vol. 358, pp. 262-272.Africa, Tanzaniacarbonatite

Abstract: Hanang volcano is the southern volcano of, the southern area of the east part of the East African Rift (the North Tanzanian Divergence) and represents volcanic activity of the first stage of continental break-up. In this study, we investigate glassy melt inclusions in nepheline phenocrysts to constrain the late stage of Mg-poor nephelinite evolution and the behaviour of volatiles (CO2, H2O, S, F, Cl) during magma storage and ascent during early stage rifting. The melt inclusions have a green silicate glass, a carbonate phase and a shrinkage bubble free of gas phase indicating that carbonatite:silicate (18:82) liquid immiscibility occurred during nephelinite magmatic evolution. The silicate glasses have trachytic composition (Na?+?K/Al?=?1.6-7.2, SiO2?=?54-65.5?wt%) with high CO2 (0.43?wt% CO2), sulfur (0.21-0.92?wt% S) and halogens (0.28-0.84?wt% Cl; 0.35-2.54?wt% F) contents and very low H2O content (<0.1?wt%). The carbonate phase is an anhydrous Ca-Na-K-S carbonate with 33?wt% CaO, 20?wt% Na2O, 3?wt% K2O, and 3?wt% S. The entrapped melt in nepheline corresponds to evolved interstitial CO2-rich phonolitic composition (Na?+?K/Al?=?6.2-6.9) with 6?±?1.5?wt% CO2 at pressure of 800?±?200?MPa after crystallization of cpx (17%), nepheline (40%) garnet (6.5%) and apatite (1.7%) from Mg-rich nephelinitic magma. During ascent, immiscibility in phonolitic melt inclusions leads to Ca-Na carbonate melt with composition within the range of carbonate melt from Oldoinyo Lengai and Kerimasi, in equilibrium with trachytic silicate melt (closed-system, P?
DS201803-0436
2017
Baxter, E.F., Caddick, M.J., Dragovic, B.Garnet: a rock forming mineral petrochronometer.Reviews in Mineralogy & Geochemistry, Vol. 83, Chap. 15, pp. 469-533.Technologygeochronology

Abstract: Garnet could be the ultimate petrochronometer. Not only can you date it directly (with an accuracy and precision that may surprise some), but it is also a common rock-forming and porphyroblast-forming mineral, with wide ranging—yet thermodynamically well understood—solid solution that provides direct and quantitative petrologic context. While accessory phase petrochronology is based largely upon establishing links to the growth or breakdown of key rock-forming pressure–temperature–composition (P–T–X) indicators (e.g., Rubatto 2002; Williams et al. 2007), garnet is one of those key indicator minerals.
DS201809-1995
2018
Beall, A.P., Moresi, L., Cooper, C.M.Formation of cratonic lithosphere during the initiation of plate tectonics.Geology, Vol. 46, 6, pp. 487-490.Mantlecraton

Abstract: Earth’s oldest near-surface material, the cratonic crust, is typically underlain by thick lithosphere (>200 km) of Archean age. This cratonic lithosphere likely thickened in a high-compressional-stress environment, potentially linked to the onset of crustal shortening in the Neoarchean. Mantle convection in the hotter Archean Earth would have imparted relatively low stresses on the lithosphere, whether or not plate tectonics was operating, so a high stress signal from the early Earth is paradoxical. We propose that a rapid transition from heat pipe–mode convection to the onset of plate tectonics generated the high stresses required to thicken the cratonic lithosphere. Numerical calculations are used to demonstrate that an existing buoyant and strong layer, representing depleted continental lithosphere, can thicken and stabilize during a lid-breaking event. The peak compressional stress experienced by the lithosphere is 3×-4× higher than for the stagnant-lid or mobile-lid regimes immediately before and after. It is plausible that the cratonic lithosphere has not been subjected to this high stress state since, explaining its long-term stability. The lid-breaking thickening event reproduces features observed in typical Neoarchean cratons, such as lithospheric seismological reflectors and the formation of thrust faults. Paleoarchean "pre-tectonic" structures can also survive the lid-breaking event, acting as strong rafts that are assembled during the compressive event. Together, the results indicate that the signature of a catastrophic switch from a stagnant-lid Earth to the initiation of plate tectonics has been captured and preserved in the characteristics of cratonic crust and lithosphere.
DS201802-0221
2018
Bedard, J.Stagnant lids and mantle overturns: implications for Archean tectonics, magmagenesis, crust growth, mantle evolution, and the start of plate tectonics.Geoscience Frontiers, Vol. 9, 1, pp. 19-49.Mantleplate tectonics

Abstract: The lower plate is the dominant agent in modern convergent margins characterized by active subduction, as negatively buoyant oceanic lithosphere sinks into the asthenosphere under its own weight. This is a strong plate-driving force because the slab-pull force is transmitted through the stiff sub-oceanic lithospheric mantle. As geological and geochemical data seem inconsistent with the existence of modern-style ridges and arcs in the Archaean, a periodically-destabilized stagnant-lid crust system is proposed instead. Stagnant-lid intervals may correspond to periods of layered mantle convection where efficient cooling was restricted to the upper mantle, perturbing Earth's heat generation/loss balance, eventually triggering mantle overturns. Archaean basalts were derived from fertile mantle in overturn upwelling zones (OUZOs), which were larger and longer-lived than post-Archaean plumes. Early cratons/continents probably formed above OUZOs as large volumes of basalt and komatiite were delivered for protracted periods, allowing basal crustal cannibalism, garnetiferous crustal restite delamination, and coupled development of continental crust and sub-continental lithospheric mantle. Periodic mixing and rehomogenization during overturns retarded development of isotopically depleted MORB (mid-ocean ridge basalt) mantle. Only after the start of true subduction did sequestration of subducted slabs at the core-mantle boundary lead to the development of the depleted MORB mantle source. During Archaean mantle overturns, pre-existing continents located above OUZOs would be strongly reworked; whereas OUZO-distal continents would drift in response to mantle currents. The leading edge of drifting Archaean continents would be convergent margins characterized by terrane accretion, imbrication, subcretion and anatexis of unsubductable oceanic lithosphere. As Earth cooled and the background oceanic lithosphere became denser and stiffer, there would be an increasing probability that oceanic crustal segments could founder in an organized way, producing a gradual evolution of pre-subduction convergent margins into modern-style active subduction systems around 2.5 Ga. Plate tectonics today is constituted of: (1) a continental drift system that started in the Early Archaean, driven by deep mantle currents pressing against the Archaean-age sub-continental lithospheric mantle keels that underlie Archaean cratons; (2) a subduction-driven system that started near the end of the Archaean.
DS201810-2295
2018
Behr, W.M., Becker, T.W.Sediment control on subduction plate speeds.Earth and Planetary Science Letters, Vol. 502, pp. 166-173.Indiasubduction

Abstract: Tectonic plate velocities predominantly result from a balance between the potential energy change of the subducting slab and viscous dissipation in the mantle, bending lithosphere, and slab-upper plate interface. A range of observations suggest that slabs may be weak, implying a more prominent role for plate interface dissipation than previously thought. The shallow thrust interface is commonly assumed to be weak due to an abundance of fluids and near-lithostatic pore fluid pressures, but little attention has been paid to the influence of the deeper, viscous interface. Here we show that the deep interface viscosity in subduction zones is strongly affected by the relative proportions of sedimentary to mafic rocks that are subducted to depth. Where sediments on the down-going plate are sparse, the deep interface is dominated by mafic lithologies that metamorphose to eclogites, which exhibit viscosities 1-2 orders of magnitude higher than the asthenospheric mantle, and reduce subduction plate speeds. In contrast, where sediments are abundant and subducted to depth, the deep interface viscosity is 1-2 orders of magnitude lower than the asthenospheric mantle, thus allowing significantly faster plate velocities. This correlation between subduction plate speed and deep sediment subduction may help explain dramatic accelerations (or decelerations) in convergence rates, such as the acceleration documented for India-Asia convergence during the mid-Cenozoic.
DS201812-2779
2018
Benard, A., Klimm, K., Woodland, A.B., Arculus, R.J., Wilke, M., Botcharnikov, R.E., Shimizu, N., Nebel, O., Rivard, C., Ionov, D.A.Oxidising agents in sub-arc mantle melts link slab devolatillisation and arc magmas.Nature Communications, Vol. 9, 1, doi: 10.1038/s41467-018-05804-2 11p.Mantlemelting

Abstract: Subduction zone magmas are more oxidised on eruption than those at mid-ocean ridges. This is attributed either to oxidising components, derived from subducted lithosphere (slab) and added to the mantle wedge, or to oxidation processes occurring during magma ascent via differentiation. Here we provide direct evidence for contributions of oxidising slab agents to melts trapped in the sub-arc mantle. Measurements of sulfur (S) valence state in sub-arc mantle peridotites identify sulfate, both as crystalline anhydrite (CaSO4) and dissolved SO42? in spinel-hosted glass (formerly melt) inclusions. Copper-rich sulfide precipitates in the inclusions and increased Fe3+/?Fe in spinel record a S6+Fe2+ redox coupling during melt percolation through the sub-arc mantle. Sulfate-rich glass inclusions exhibit high U/Th, Pb/Ce, Sr/Nd and ?34S (+?7 to +?11‰), indicating the involvement of dehydration products of serpentinised slab rocks in their parental melt sources. These observations provide a link between liberated slab components and oxidised arc magmas.
DS201812-2780
2018
Benitez, L.Comparative analysis of two diamond populations of the west of Minas Gerais.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Minas Geraisvaluation
DS201801-0004
2017
Benjamin, F.R., Ghosh, P., Viladkar, S.G.A secular variation of stable isotope record in global carbonatite magma.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p.11.Globalcarbonatites

Abstract: Carbonatites are magmatic rocks, origin of these relates to the involvement of mantle fluid. Thus they provide indirect method to understand the sub-continental upper mantle fluid composition. The first report on carbonatites and the later eruption of the natrocarbonatite paved way for investigating the heterogeneity of the mantle with depth and since then, many other occurrences have been found worldwide, offering suitable samples for probing the mantle. We present record of stable isotopic composition of carbonatites spanning Precambrian, Proterozoic to Phanerozoic to Recent time based on their temporal occurrences and global distribution in the geological record. We consider the various tectonic settings from which carbonatites have been reported, the underlying eruption mechanisms taking into account the tectonic significance of their occurrence and their imprints on surrounding rocks. This account covers carbonatites and associated rocks from different continents with a prime focus on carbon and oxygen isotopes. Carbon and oxygen isotope composition vary significantly within time spans. These variations depend on other factors besides mantle composition i.e. carbonate mineralogy and alteration processes that can cause a shift from original compositions. We envisage the use of stable isotope records to address the secular variation of crustal mixing / contamination process in geological time. Many of these secular variation are abrupt and probably indicate shift in the tectonic forcing - a vital factor responsible for driving the secular trend.
DS201812-2781
2018
Bernardez, F.Five Star diamonds, building a junior diamond mine in Brazil.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazildeposit -
DS201801-0005
2018
Beyer, C., Rosenthal, A., Myhill, R., Crichton, W.A., Yu, T., Frost, D.J.An internally consistent pressure calibration of geobarometers applicable to the Earth's upper mantle using insitu XRD.Geochimica et Cosmochimica Acta, Vol. 222, Feb 1, pp. 421-435.Mantlegeobarometry

Abstract: We have performed an experimental cross calibration of a suite of mineral equilibria within mantle rock bulk compositions that are commonly used in geobarometry to determine the equilibration depths of upper mantle assemblages. Multiple barometers were compared simultaneously in experimental runs, where the pressure was determined using in-situ measurements of the unit cell volumes of MgO, NaCl, Re and h-BN between 3.6 and 10.4?GPa, and 1250 and 1500?°C. The experiments were performed in a large volume press (LVPs) in combination with synchrotron X-ray diffraction. Noble metal capsules drilled with multiple sample chambers were loaded with a range of bulk compositions representative of peridotite, eclogite and pyroxenite lithologies. By this approach, we simultaneously calibrated the geobarometers applicable to different mantle lithologies under identical and well determined pressure and temperature conditions. We identified discrepancies between the calculated and experimental pressures for which we propose simple linear or constant correction factors to some of the previously published barometric equations. As a result, we establish internally-consistent cross-calibrations for a number of garnet-orthopyroxene, garnet-clinopyroxene, Ca-Tschermaks-in-clinopyroxene and majorite geobarometers.
DS201810-2296
2018
Bezzola, M., Hetman, C.M., Garlick, G., Creaser, R., Diering, M., Nowicki, T.Geology and resource development of the Kelvin kimberlite pipe, Northwest Territories, Canada.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0631-6 13p.Canada, Northwest Territoriesdeposit - Kelvin

Abstract: The early Cambrian to late Neoproterozoic Kelvin kimberlite pipe is located in the southeast of the Archean Slave Craton in northern Canada, eight km northeast of the Gahcho Kué diamond mine. Kelvin was first discovered in 2000 by De Beers Canada. Subsequent exploration undertaken by Kennady Diamonds Inc. between 2012 and 2016 resulted in the discovery of significant thicknesses of volcaniclastic kimberlite that had not previously been observed. Through extensive delineation drilling Kelvin has been shown to present an atypical, steep-sided inclined L-shaped pipe-like morphology with an overall dip of 15 to 20°. With a surface expression of only 0.08 ha Kelvin dips towards the northwest before turning north. The body (which remains open at depth) has been constrained to a current overall strike length of 700 m with varying vertical thickness (70 to 200 m) and width (30 to 70 m). Detailed core logging, petrography and microdiamond analysis have shown that the pipe infill comprises several phases of sub-horizontally oriented kimberlite (KIMB1, KIMB2, KIMB3, KIMB4, KIMB7 and KIMB8) resulting from multiple emplacement events. The pipe infill is dominated by Kimberley-type pyroclastic kimberlite or “KPK”, historically referred to as tuffisitic kimberlite breccia or “TKB”, with less common hypabyssal kimberlite (HK) and minor units with textures transitional between these end-members. An extensive HK sheet complex surrounds the pipe. The emplacement of Kelvin is believed to have been initiated by intrusion of this early sheet system. The main pipe-forming event and formation of the dominant KPK pipe infill, KIMB3, was followed by late stage emplacement of additional minor KPK and a hypabyssal to transitional-textured phase along the upper contact of the pipe, cross-cutting the underlying KIMB3. Rb-Sr age dating of phlogopite from a late stage phase has established model ages of 531 ± 8 Ma and 546 ± 8 Ma. Texturally and mineralogically, the Kelvin kimberlite is similar to other KPK systems such as the Gahcho Kué kimberlites and many southern African kimberlites; however, the external morphology, specifically the sub-horizontal inclination of the pipe, is unique. The morphology of Kelvin and the other kimberlites in the Kelvin-Faraday cluster defines a new type of exploration target, one that is likely not unique to the Kennady North Project area. Extensive evaluation work by Kennady Diamonds Inc. has resulted in definition of a maiden Indicated Mineral Resource for Kelvin of 8.5 million tonnes (Mt) of kimberlite at an average grade of 1.6 carats per tonne (cpt) with an average diamond value of US$ 63 per carat (ct).
DS201804-0673
2018
Biller, A.Ya., Logvinova, A.M., Babushkina, S.A., Oleynikov, O.B., Sobolev, N.V.Shrilankite inclusions in garnets from kimberlite bodies and Diamondiferous volcanic-sedimentary rocks of the Yakutian kimberlite province, Russia.Doklady Earth Sciences, Vol. 478, 1, pp. 15-19.Russia, Yakutiadeposit - Yubileinaya

Abstract: Pyrope-almandine garnets (Mg# = 28.3-44.9, Ca# = 15.5-21.3) from a heavy mineral concentrate of diamondiferous kimberlites of the largest diamond deposit, the Yubileinaya pipe, along with kimberlite- like rocks and diamondiferous volcano-sediments of the Laptev Sea coast, have been found to contain polymineral, predominantly acicular inclusions, composed of aggregates of shrilankite (Ti2ZrO6), rutile, ilmenite, clinopyroxene, and apatite. The presence of shrilankite as an inclusion in garnets from assumed garnet-pyroxene rocks of the lower crust, lifted up by diamond-bearing kimberlite, allows it to be considered as an indicator mineral of kimberlite, which expands the possibilities when searching for kimberlite in the Arctic.
DS201806-1213
2018
Birner, S.K., Cottrell, E., Warren, J.M., Kelley, K.A., Davis, F.A.Peridotites and basalts reveal broad congruence between two independent records of mantle f02 desite local redox heterogeneity.Earth and Planetary Science Letters, Vol. 494, pp. 172-189.Mantleperidotites

Abstract: The oxygen fugacity (fO2) of the oceanic upper mantle has fundamental implications for the production of magmas and evolution of the Earth's interior and exterior. Mid-ocean ridge basalts and peridotites sample the oceanic upper mantle, and retain a record of oxygen fugacity. While fO2 has been calculated for mid-ocean ridge basalts worldwide (>200 locations), ridge peridotites have been comparatively less well studied (33 samples from 11 locations), and never in the same geographic location as basalts. In order to determine whether peridotites and basalts from mid-ocean ridges record congruent information about the fO2 of the Earth's interior, we analyzed 31 basalts and 41 peridotites from the Oblique Segment of the Southwest Indian Ridge. By measuring basalts and peridotites from the same ridge segment, we can compare samples with maximally similar petrogenetic histories. We project the composition and oxygen fugacity of each lithology back to source conditions, and evaluate the effects of factors such as subsolidus diffusion in peridotites and fractional crystallization in basalts. We find that, on average, basalts and peridotites from the Oblique Segment both reflect a source mantle very near the quartz-fayalite-magnetite (QFM) buffer. However, peridotites record a significantly wider range of values (nearly 3 orders of magnitude in fO2), with a single dredge recording a range in fO2 greater than that previously reported for mid-ocean ridge peridotites worldwide. This suggests that mantle fO2 may be heterogeneous on relatively short length scales, and that this heterogeneity may be obscured within aggregated basalt melts. We further suggest that the global peridotite fO2 dataset may not provide a representative sample of average basalt-source mantle. Our study motivates further investigation of the fO2 recorded by ridge peridotites, as peridotites record information about the fO2 of the Earth's interior that cannot be gleaned from analysis of basalts alone.
DS201810-2297
2018
Bjorn, H.H., Conrad, C.P., Tronnes, R.G.Stabilizing effect of compositional viscosity contrasts on thermochemical piles.Geophysical Research Letters, Vol. 45, 15, pp. 7523-7532.Mantlebridgemanite

Abstract: Seismic images of the Earth's mantle show two anomalous continent?sized regions close to the core?mantle boundary. The inferred properties of these regions suggest that they have a different composition than the surrounding mantle. Two possible candidate materials have been proposed: accumulated oceanic crust from the Earth's surface or an iron?rich residue remaining from Earth's original magma ocean. Although both materials are denser than the surrounding mantle, it remains unclear whether piles of these chemical heterogeneities can survive at the core?mantle boundary beneath vigorous mantle convection. Numerical models show that the excess density required to preserve these structures is typically larger than indicated by seismological and gravitational observations. In this study, we show that the excess density used in numerical models can be reduced toward the observed values if the pile material is also stiffer than the surrounding mantle. Furthermore, we show that piles must be denser and/or stiffer to avoid destruction during episodes of strong deformation. Because pile formation probably includes vigorous deformation, we expect long?term survival of the piles after their formation is completed.
DS201808-1726
2018
Blom, E.Presentation by World Federation of Diamond Bourses President Ernie Blom.SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 20 ppts.Globaldiamond bourse
DS201802-0222
2017
Bobrov, A.V.Crystal inclusions in diamond - a key to understanding of the Earth's mantle mineralogy. ***IN RUSStarosin, V.I. (ed) Problems of the mineralogy, economic geology and mineral resources. MAKS Press, Moscow *** IN RUS, pp. 175-196.Mantlediamond inclusions
DS201809-1996
2018
Bobrov, A.V., Tamarova, A.P., Sirotkina, E.A., Zhang, G.S., Irifune, T.Interphase partitioning of minor elements in the transition zone and uppermost lower mantle.Goldschmidt Conference, 1p. AbstractMantlediamond inclusions

Abstract: Interphase partitioning of minor elements was studied experimentally upon partial melting of model pyrolite [1] with addition of 2 wt % H2O, 10, and 15 wt % of multicomponent carbonate at 22-24 GPa and 1300-2200°C. The concentrations of minor elements were analyzed on an Agilent 7500a mass spectrometer. Phase associations included quenched melt (L), bridgmanite (Brd), CaSiO3- perovskite (CaPrv), ringwoodite (Rwd), ferropericlase (Fp), and majoritic garnet (Maj). The sequence of phase assemblages in our runs is consistent to that reported in [2] for melting of anhydrous pyrolite at 24 GPa: Fp+L, Fp+Maj+Brd(Rwd)+L, Fp+Maj+Brd(Rwd)+CaPrv. Most of minor elements, except for Sc, Cr, and Ni, are incompatible for Brd and show slight increase in partitioning coefficients from LREEs to HREEs in the H2O-bearing system. Pyrolite with carbonate is characterized by slightly higher LREE partitioning coefficients. Monovalent elements (Li, K, Cs, Rb), as well as Sr and Pb, are strongly incompatible for Brd in all systems. The similar features are observed for Fp enriched in HREEs and depleted in LREEs; all minor elements show redistribution into Fp with pressure. CaPrv is enriched in LREEs and depleted in HREEs. We applied the lattice strain model [3] for interpretation of the analytical data, which allowed us to study the behavior of minor elements as a function of P-T parameters. Our data and some previous results [4] were used for estimation of the composition of melts in equilibrium with inclusions in diamonds from the transition zone and lower mantle.
DS201805-0936
2018
Bocher, M., Fournier, A., Coltice, N.Ensemble Kalman filter for the reconstruction of the Earth's mantle circulation.Nonlinear Processes Geophysics, Vol. 25, pp. 99-123. pdfMantleconvection

Abstract: Recent advances in mantle convection modeling led to the release of a new generation of convection codes, able to self-consistently generate plate-like tectonics at their surface. Those models physically link mantle dynamics to surface tectonics. Combined with plate tectonic reconstructions, they have the potential to produce a new generation of mantle circulation models that use data assimilation methods and where uncertainties in plate tectonic reconstructions are taken into account. We provided a proof of this concept by applying a suboptimal Kalman filter to the reconstruction of mantle circulation (Bocher et al., 2016). Here, we propose to go one step further and apply the ensemble Kalman filter (EnKF) to this problem. The EnKF is a sequential Monte Carlo method particularly adapted to solve high-dimensional data assimilation problems with nonlinear dynamics. We tested the EnKF using synthetic observations consisting of surface velocity and heat flow measurements on a 2-D-spherical annulus model and compared it with the method developed previously. The EnKF performs on average better and is more stable than the former method. Less than 300 ensemble members are sufficient to reconstruct an evolution. We use covariance adaptive inflation and localization to correct for sampling errors. We show that the EnKF results are robust over a wide range of covariance localization parameters. The reconstruction is associated with an estimation of the error, and provides valuable information on where the reconstruction is to be trusted or not.
DS201809-1997
2018
Boehler, R.Surprising" phase behavior of pure carbon: is diamond metastable at high pressures?Goldschmidt Conference, 1p. AbstractMantlemelting

Abstract: Flash laser heating in diamond anvil cells has been performed to melt diamond up to 37.5 GPa and 4500K using three different methods and three different starting materials: graphite, glassy carbon and diamond. In these experiments molten diamonds were confirmed by FIB/SEM images of the quenched samples. The melting slope of diamond is strongly negative, in contrast to all theoretical predictions. This is the first direct measurement of diamond melting temperatures at high pressure supporting early predictions based on analogies in the phase behavior of the group IV elements carbon, silicon and germanium. For diamond, these analogies had been dismissed for over 30 years based on theoretical grounds. The results imply that, at very high pressure, diamond, seemingly stable in all static and shock experiments, must be outside its thermodynamic stability field. This could be comparable to its behavior at ambient pressures, where diamond exhibits remarkable stability when heated to several thousand degrees even though the thermodynamically stable form of carbon is graphite.
DS201811-2554
2018
Bogatikov, O.A., Dokuchaev, A.Ya., Kargin, E.V., Yutkina, E.V., Kondrashov, I.A.Paleoproterozic kimberlites of the Lake Kimozero area, Karelian craton: ore mineralization in kimberlites and fault zones.Doklady Earth Sciences, Vol. 482, 1, pp. 1130-1133.Russiadeposit - Lake Kimozero

Abstract: Syngenetic and epigenetic ore mineralization was studied in Paleoproterozoic metakimberlites in the area of Kimozero Lake. In the Kimozero structure, redeposited ore mineralization is constrained to fracture and shear zones and consists of Fe-vaesite, Fe-Co-polydymite, millerite, Ni-pyrrhotite, pentlandite, chalcopyrite, Zn-bearing copper, galena, and Ni-pyrite. The composition of this mineralization is analogous to that of syngenetic mineralization in pyroclastic and coherent kimberlite, and its likely source was the kimberlite itself.
DS201802-0223
2018
Boldyrev, K.N., Mavrin, B.N., Sherin, P.S., Popova, M.N.Bright luminescence of diamonds with GeV centers.Journal of Luminescence, Vol. 193, pp. 119-124.Technologyluminescence

Abstract: We report on the quantum yield (?) and decay time (?) measurements at room temperature for the bright red-orange (602 nm) luminescence from new germanium-vacancy (Ge-V) centers in nano- and microcrystalline diamonds synthesized at high pressure and high temperature. The values ? = 3 ± 1% and ? = 6.2±0.2 ns were found. The Stokes shift measured as the energy difference between the maxima of the luminescence and luminescence excitation spectra is negligible. The relative intensity of the zero-phonon line constitutes up to 70% from the total intensity of the luminescence. Results of our ab initio DFT calculations for the ground-state electronic and vibrational structure of (Ge-V)? in diamond are presented and discussed.
DS201810-2298
2018
Borghini, G., Fumagalli, P.Subsolidus phase relations in a mantle pyroxenite: an experimental study from 0.7 to 1.5 Gpa.European Journal of Mineralogy, Vol. 30, 2, pp. 333-348.Mantlepyroxenite

Abstract: Pyroxenites are a diffuse heterogeneity in the upper mantle and represent key lithologies in melting processes and mantle deformation. Mantle peridotites exposed in ultramafic massifs are commonly veined by pyroxenites. The latter experienced the same metamorphic evolution as host peridotite and may develop substantially different phase assemblages in response to the different bulk composition. Although several experimental studies focused on melting relations in pyroxenites, subsolidus phase relations are still poorly known. We provide new experimental constraints on phase stability and mineral chemistry for a natural mantle pyroxenite. Piston-cylinder experiments were conducted from 0.7 to 1.5?GPa, 1100-1250?°C. Al-rich spinel, clinopyroxene, orthopyroxene and olivine are ubiquitous phases within the whole pressure range investigated. At 1100?°C, plagioclase is stable up to 0.9?GPa; anorthite content [An?=?Ca/(Ca?+?Na)] decreases as a function of pressure from 0.70 at 0.7?GPa to 0.61 at 0.9?GPa. Maximum plagioclase modal abundance of 14?wt% forms at 0.7?GPa; this amount is more than twice as experimentally determined at the same P-T conditions in fertile lherzolite (5-6?wt%). At intermediate pressure (1.0-1.4?GPa), modal spinel is almost constant (4-5?wt%). A pyrope-rich garnet is stable at 1.5?GPa and its modal abundance increases from 5 to 10 wt% when temperature decreases from 1230?°C to 1150?°C, from 1230?°C to 1150?°C. The Al content in pyroxenes varies significantly across the plagioclase-out and garnet-in transitions and is not pressure-dependent in the spinel-pyroxenite field. At 1100?°C, the plagioclase-out boundary occurs at comparable pressures in the pyroxenite and in fertile lherzolites. On the contrary, the garnet-in curve is located at significantly lower pressure than for mantle peridotites.
DS201801-0006
2017
Borovikov, A.A., Vladykin, N.V., Tretiakova, I.G., Dokuchits, E.Yu.Physicochemical conditions of formation of hydrothermal titanium mineralization on the Murunskiy alkaline massif, western Alden ( Russia).Ore Geology Reviews, in press available, 10p.Russiaalkaline rocks
DS201809-1998
2018
Boshoff, E.T., Morkel, J., Naude, N.Identifying critical parameters in the settling of African kimberlites. SlurriesMineral Processing and Extractive Metallurgy Review, Vol. 39, pp. 136-144.Africa, Angolamineral processing

Abstract: Kimberlite is the host rock of diamonds and varies widely in geological and mineralogical features as well as color, processing capability, and dewatering characteristics. This study investigated the dewatering behavior of problematic Angolan kimberlites. The presence of clay minerals in kimberlite causes difficulties in dewatering due to high flocculant demand, poor supernatant clarity, and low settling rates. Identifying critical parameters governing the settling behavior will assist in managing the settling behavior of different kimberlite slurries. The influence of particle size, pH of the kimberlite slurry, cation exchange capacity, exchangeable sodium percentage, and smectite content of the kimberlite on the settling rate were investigated for 18 different African kimberlite samples. The settling rate and slurry bed compaction during natural settling were also measured for the kimberlite slurries. Seventeen different Angolan clay-rich kimberlites and one South African clay-rich kimberlite were tested, and, except for two kimberlites, colloidal stability was experienced during natural settling. The pH values of the kimberlite slurries ranged between 9 and 11, which is similar to the pH band where colloidal stability was found during earlier research. The results indicate that colloidal stable slurries were experienced with kimberlites that had exchangeable sodium percentages as low as 0.7%. The cation exchange capacity of the various kimberlites differentiated more distinctly between colloidal stability and instability. A new model is proposed whereby clay-rich kimberlites with a cation exchange capacity of more than 10cmol/kg will experience colloidal stability if the pH of the solvent solution is within the prescribed pH range of 9-11.
DS201807-1478
2018
Bournas, N., Prikhodko, A., Plastow, G., Legault, J., Polianichko, V., Treshchev, S.Exploring for kimberlite pipes in the Cuango area, Angola using helicopter-borne EM survey.AEM2018/7th International Workshop on Airborne electromagnetics, Held June 17-20, 4p.Africa, Angolageophysics - TEM
DS201811-2555
2019
Bouyo, M.H., Penaye, J., Mount, H., Toleu, S.F.Eclogite facies metabasites from the Paleoproterozoic Nyong Group, SW Cameroon: mineralogical evidence and implications for a high pressure metamorphism related to a subduction zone at the NW margin of the Archean Congo craton.Journal of African Earth Sciences, Vol. 149, pp. 215-234.Africa, Cameroonsubduction

Abstract: High- to ultrahigh-pressure metamorphic assemblages consisting of garnet-omphacitic clinopyroxene bearing mafic rocks have been identified within the Paleoproterozoic Nyong Group in SW Cameroon, at the northwestern margin of the Archean Congo craton. These rocks were investigated in detail and for the first time evidence for eclogite facies metamorphism at ca 25?kbar and 850?°C is provided. A clockwise P-T path with nearly isothermal decompression (ITD) is deduced from mineral zoning and textural relationships characterized by mineral recrystallization and multi-layered coronitic overgrowths of plagioclase and clinopyroxene surrounding garnet porphyroblasts. These P-T conditions imply a burial depth greater than 90?km, at lower geothermal gradient of ca 10?°C/km. The geochemical signature of ten representative rock samples show that two groups of eclogite facies rocks genetically originate from mostly basaltic and basaltic andesite compositions, with a characteristic upper mantle-derived tholeiitic trend. Moreover, their chondrite and MORB normalized REE and trace element concentrations are characterized by nearly flat REE patterns with very little to no Eu anomaly, (La/Sm)N???1 and Zr/Nb???10, as well as a gradual depletion from LREE to HREE with also very little to no Eu anomaly, but (La/Sm)N < 1, Zr/Nb > 10 and negative anomalies in Th, K, Nb, Ta, Sr, Zr and Ti consistent with mid-ocean ridge basalt (MORB) contaminated by a subduction component or by a crustal component. Previous available geochronological data coupled with our new petrological, mineralogical and geochemical findings clearly indicate that the eclogite facies metabasites from the Eburnean Nyong Group between 2100 and 2000 Ma represent one of the oldest subducted oceanic slab or trace of a suture zone so far recorded within the West Central African Fold Belt (WCAFB). The geodynamic implications of these eclogites suggest a subduction-related process followed by a rapid exhumation of their protoliths, therefore, providing critical information corroborating that plate tectonic processes operated during the Paleoproterozoic.
DS201811-2556
2015
Bowersox, G.The emerald minerals of Panjshir Valley, Afganistan.InColor, December pp. 70-77.Asia, Afghanistanemeralds

Abstract: With the withdrawal of Soviet troops from Afghanistan, villagers in the Pani- & shir Valley are Lurning their attention to the emerald riches of the nearby Hindu Kush Mountains. Large, dark green crystals have been found in the hundreds of tunnels and shafts dug there. Teams of miners use explosives and drills to remove the limestone that hosts the emerald-bearing quartz and onkerite veins. The gemological properties of Panjshir emeralds are consisrent with those of emeralds from other localities; chemically, they are most similar to emeralds from the Muzo mine in Colombia. "Nodules," previously reported only in tourmaline and morganite, have been found in Panjshir emeralds as well. Approximntely $1 0 million in emeralds were produced in 1990; future prospects ore excellent.
DS201809-1999
2018
Boxer, G., Rockett, G.Geology, resources and exploration potential of the Ellendale diamond project, west Kimberley, Western Australia.Government of Western Australia, Record 2018/8. 49p.Australia, Western Australiadeposit - Ellendale
DS201804-0674
2017
Boxer, G.L., Jaques, A.L., Rayner, M.J.Argyle ( AK1) diamond deposit.Australian Ore Deposits, AusIMM Monograph 32, ed. Phillips, N., pp. 527-532.Australiadeposit - Argyle
DS201811-2557
2015
Boyd, W.F., Alferova, M.S.Emeralds in Russia: the geological and gemology of the Malyshev mine.InColor, December pp. 78-87.Russiaemeralds
DS201807-1479
2018
Brabers, P.M.Geophysical alluvial exploration using the Aquares resistivity method. ( mainly ports) two diamond application cases. Luderitz port, Sankura gravels DRC, SA Cape province PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 73-88.Africa, Namibia, Democratic Republic of Congo, South Africageophysics - resistivity
DS201808-1727
2018
Brabers, P.M.Geophysical alluvial exploration using the Aquares resistivity method. SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 18 ppts.Africa, Namibia, Democratic Republic of Congo, South Africageophysics
DS201809-2000
2018
Brahimi, S., Ligeois, J-P., Ghienne, J-F., Munschy, M., Bourmatte, A.The Tuareg shield terranes revisited and extended towards the northern Gondwana margin: magnetic and gravimetric constraints.Earth Science Reviews, Vol. 185, Doi: 10.1016/j.earscirev. 2018.07.002Africa, AlgeriaGondwanaland

Abstract: Kimberlite is the host rock of diamonds and varies widely in geological and mineralogical features as well as color, processing capability, and dewatering characteristics. This study investigated the dewatering behavior of problematic Angolan kimberlites. The presence of clay minerals in kimberlite causes difficulties in dewatering due to high flocculant demand, poor supernatant clarity, and low settling rates. Identifying critical parameters governing the settling behavior will assist in managing the settling behavior of different kimberlite slurries. The influence of particle size, pH of the kimberlite slurry, cation exchange capacity, exchangeable sodium percentage, and smectite content of the kimberlite on the settling rate were investigated for 18 different African kimberlite samples. The settling rate and slurry bed compaction during natural settling were also measured for the kimberlite slurries. Seventeen different Angolan clay-rich kimberlites and one South African clay-rich kimberlite were tested, and, except for two kimberlites, colloidal stability was experienced during natural settling. The pH values of the kimberlite slurries ranged between 9 and 11, which is similar to the pH band where colloidal stability was found during earlier research. The results indicate that colloidal stable slurries were experienced with kimberlites that had exchangeable sodium percentages as low as 0.7%. The cation exchange capacity of the various kimberlites differentiated more distinctly between colloidal stability and instability. A new model is proposed whereby clay-rich kimberlites with a cation exchange capacity of more than 10cmol/kg will experience colloidal stability if the pH of the solvent solution is within the prescribed pH range of 9-11.The Trans-Saharan Belt is one of the most important orogenic systems constitutive of the Pan-African cycle, which, at the end of the Neoproterozoic, led to the formation of the Gondwana Supercontinent. It is marked by the opening and closing of oceanic domains, collision of continental blocks and the deformation of thick synorogenic sedimentary basins. It extends from north to south over a distance of 3000?km in Africa, including the Nigerian Shield and the Tuareg Shield as well as their counterparts beneath the Phanerozoic oil-rich North- and South-Saharan sedimentary basins. In this study, we take advantage of potential field methods (magnetism and gravity) to analyze the crustal-scale structures of the Tuareg Shield terranes and to track these Pan-African structures below the sedimentary basins, offering a new, >1000?km extent. The map interpretations are based on the classical potential field transforms and two-dimensional forward modeling. We have identified geophysical units and first-order bounding lineaments essentially defined owing to magnetic and gravimetric anomaly signatures. In particular, we are able to highlight curved terminations, which in the Trans-Saharan context have been still poorly documented. We provide for the first time a rheological map showing a categorization of contrasted basement units from the south of the Tuareg Shield up to the Atlas Belt. These units highlight the contrasted rheological behavior of the Tuareg tectonostratigraphic terranes during (i) the northerly Pan-African tectonic escape characteristic of the Trans-Saharan Belt and (ii) the North Sahara basin development, especially during intraplate reworking tied to the Variscan event. The discovery of a relatively rigid E-W oriented unit to the south of the Atlas system, and on which the escaping Pan-African terranes were blocked, offers a new perspective on the structural framework of the north-Gondwana margin. It will help to understand how occurred the rendezvous of the N-S oriented Pan-African terranes and the E-W oriented Cadomian peri-Gondwanan terranes.
DS201806-1214
2018
Breeding, C.M., Eaton-Magana, S., Shigley, J.E.Natural color green diamonds: a beautiful conundrum.Gems& Gemology, Vol. 54, 1, spring pp. 2-27.South America, Brazil, Venezuela, Guyanadiamonds - green review

Abstract: Among fancy-color diamonds, natural-color green stones with saturated hues are some of the rarest and most sought after. These diamonds are colored either by simple structural defects produced by radiation exposure or by more complex defects involving nitrogen, hydrogen, or nickel impurities. Most of the world’s current production of fine natural green diamonds comes from South America or Africa. Laboratory irradiation treatments have been used commercially since the late 1940s to create green color in diamond and closely mimic the effects of natural radiation exposure, causing tremendous difficulty in gemological identification. Compounding that problem is a distinct paucity of published information on these diamonds due to their rarity. Four different coloring mechanisms—absorption by GR1 defects due to radiation damage, green luminescence from H3 defects, and absorptions caused by hydrogen- and nickel-related defects—can be identified in green diamonds. Careful microscopic observation, gemological testing, and spectroscopy performed at GIA over the last decade allows an unprecedented characterization of these beautiful natural stones. By leveraging GIA’s vast database of diamond information, we have compiled data representative of tens of thousands of samples to offer a look at natural green diamonds that has never before been possible.
DS201804-0675
2018
Breeding, M.Diamond defects, diamond colour treatment, and its identification.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 11-13. abstractTechnologydiamond -color centers
DS201809-2001
2018
Brenker, F.E., Koch, T.E., Prior, D.J., Lilly, K., Krot, A.N., Bizzarro, M., Frost, D.Fe rich Ferropericlase in super deep diamonds and the stability of high FeO wadsleyite. Implications on the composition and temperature of the Earth's transition zone.Goldschmidt Conference, 1p. AbstractMantlediamond inclusions

Abstract: The high amount of Fe-rich ferropericlase inclusions found in diamonds of a potential super-deep origin questions the bulk chemical model of the Earth [e.g., 1]. Although this might be due to a biased sampling of the lower mantle, it is worth to further address this discrepancy. A limiting factor of the Fe-content of the Earth´s deep mantle (TZ and lower mantle) is a correlation of the depths of the observed main mantle discontinuities with the (Fe,Mg)SiO4 phase diagram. In particular, the 520 kmdiscontinuity is related to the phase transformation of wadsleyite (assuming Fa10) to ringwoodite. The existing phase diagrams suggest a stability limit of wadsleyite ?Fa40 [e.g., 2,3], which limits the Fe-content of the Earth´s transition zone. Here we report on a discovery of Fe-rich wadsleyite grains (up to Fa56) in the high-pressure silicate melt droplets within Fe,Ni-metal in shock veins of the CB (Bencubbin-like) metal-rich carbonaceous chondrite QC 001 [4], which were identified using HR-EDX, nano-EBSD and TEM. Although the existence of such Fe-rich wadsleyite in shock veins may be due to the kinetic reasons, new theoretical and experimental studies of the stability of (Fe,Mg)SiO4 at high temperature (> 1800 K) are clearly needed. This may have significant impact on the temperature and chemical estimates of the Earth´s transition zone.
DS201805-0937
2018
Brett, C.Petrology of the White River Diamondiferous Paleoproterozoic intrusive rocks and constraining the timing of destruction of the southern Superior cratonic rocks.Vancouver Kimberlite Cluster, May 3, 1p. AbstractCanada, OntarioWawa

Abstract: Diamond-bearing kimberlitic rocks have been identified as occurring within the Oskabukuta property,15km west of the town of White River, Northwestern Ontario. These rocks were emplaced within Neo-to-Mesoarchean (2.5 to 3.4 Ga) crystalline rock of the Wawa Subprovince, located within the Superior Province of North America. The emplacement age of the dyke is dated at 1945.3 ± 1.9 Ma (1?) (U-Pb in perovskite). The diamond-bearing, kimberlitic intrusion has been mapped at surface for over a 900 m strike, and is referred to as the Rabbit Foot occurrence. Geothermobarometry of the nearby Proterozoic (2.7 Ga) aged diamondiferous metaconglomerate in Wawa (90 km SE) reported a maximum geothermal gradient range between 39 and 41 mW/m2 corresponding to a minimum lithospheric thickness of the Superior Craton of 190-220 km (Miller et al., 2012). In contrast, the study highlight that younger kimberlite (e.g. ~1.1 Ga Wawa kimberlite) within the Southern Superior record a substantially warmer conductive geotherm (46 mW/m2; Kaminsky et al., 2002) and maximum depth of garnet sampled of 150 km. Miller et al. (2012) interpret the apparent heating of the mantle is likely to have resulted from the Midcontinent Rift, which is broadly coeval with the Wawa kimberlite age. Pressure-Temperature estimates calculated using garnet and clinopyroxene xenocryst mineral compositions extracted from Rabbit Foot Model are consistent with model conductive heat flow of between 38-41 mW-m-2. These data support the interpretation of Miller et al. (2012) and further constrain the presence of a cool and thick Southern Superior keel at 1945 Ma. In fact, several of our garnet compositions support a minimum lithosphere-asthenosphere boundary of 250 km in depth and suggest (along with the presence of diamond) that the Rabbit Foot intrusion transected and sampled a significant portion of depleted and diamond stable lithospheric mantle at ~1945 Ma. A later thermal event, likely related to the Mid-continental rift, has subsequently heated and thinned the Southern Superior Craton, thereby constraining timing of the cessation of diamond fertile sublithospheric mantle in the region.
DS201812-2782
2018
Brett, R.C., Kinakin, Y., Howell, D., Davy, A.T.Diavik deposit: Exploration history and discovery of the Diavik diamond deposits, Northwest Territories, Canada.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 253-266.Canada, Northwest Territoriesdeposit - Diavik
DS201807-1480
2018
Brey, G.P., Shu, Q.The birth, growth and ageing of the Kaapvaal subcratonic mantle.Mineralogy and Petrology, 10.1007/ s00710-018- 0577-8, 19p. Africametasomatism, subduction, geobarometry

Abstract: The Kaapvaal craton and its underlying mantle is probably one of the best studied Archean entity in the world. Despite that, discussion is still vivid on important aspects. A major debate over the last few decades is the depth of melting that generated the mantle nuclei of cratons. Our new evaluation of melting parameters in peridotite residues shows that the Cr2O3/Al2O3 ratio is the most useful pressure sensitive melting barometer. It irrevocably constrains the pressure of melting (melt separation) to less than 2 GPa with olivine (ol), orthopyroxene (opx) and spinel (sp) as residual phases. Garnet (grt) grows at increasing pressure during lithosphere thickening and subduction via the reaction opx?+?sp ? grt?+?ol. The time of partial melting is constrained by Re-depletion model ages (TRD) mainly to the Archean (Pearson and Wittig 2008). However, only 3% of the ages are older than 3.1 Ga while crustal ages lie mainly between 3.1 to 2.8 Ga for the W- and 3.7 to 2.8 Ga for the E-block. Many TRD-ages are probably falsified by metasomatism and the main partial melting period was older than 3.1 Ga. Also, Nd- and Hf- model ages of peridotitic lithologies from the W-block are 3.2 to 3.6 Ga old. The corresponding very negative ?Nd (?40) and ?Hf values (?65) signal the presence of subducted crustal components in these old mantle portions. Subducted components diversify the mantle in its chemistry and thermal structure. Adjustment towards a stable configuration occurs by fluid transfer, metasomatism, partial melting and heat transfer. Ages of metasomatism from the Lu-Hf isotope system are 3.2 Ga (Lace), 2.9 Ga (Roberts Victor) and 2.62 Ga (Finsch) coinciding with the collision of cratonic blocks, the growth of diamonds, metamorphism of eclogites and of Ventersdoorp magmatism. The cratonic lithosphere was stabilized thermally by the end of the Archean and cooled since then with a rate of 0.07 °C/Ma.
DS201810-2299
2018
Broadley, M.W., Barry, P.H., Ballentine, C.J., Taylor, L.A., Burgess, R.End-Permian extinction amplified by plume-induced release of recycled lithospheric volatiles.Nature Geoscience, 10.1038/s41561-018-0215-4 pp. 682-687.Russia, Siberiasubduction

Abstract: Magmatic volatile release to the atmosphere can lead to climatic changes and substantial environmental degradation including the production of acid rain, ocean acidification and ozone depletion, potentially resulting in the collapse of the biosphere. The largest recorded mass extinction in Earth’s history occurred at the end of the Permian, coinciding with the emplacement of the Siberian large igneous province, suggesting that large-scale magmatism is a key driver of global environmental change. However, the source and nature of volatiles in the Siberian large igneous province remain contentious. Here we present halogen compositions of sub-continental lithospheric mantle xenoliths emplaced before and after the eruption of the Siberian flood basalts. We show that the Siberian lithosphere is massively enriched in halogens from the infiltration of subducted seawater-derived volatiles and that a considerable amount (up to 70%) of lithospheric halogens are assimilated into the plume and released to the atmosphere during emplacement. Plume-lithosphere interaction is therefore a key process controlling the volatile content of large igneous provinces and thus the extent of environmental crises, leading to mass extinctions during their emplacement.
DS201812-2783
2018
Broecker, W.CO2: Earth's climate driver.Geochemical Perspectives, Vol. 7, no. 2, pp. 117-196. doi: 10.7185/geochempersp.7.2Mantlecarbon

Abstract: As we struggle to cope with the ongoing buildup of CO2 produced by burning fossil fuels, can we acquire guidance from the geologic record? Although our ability to reconstruct past atmospheric CO2 content reliably is currently confined to the last 800 thousand years, we do have compelling evidence that this greenhouse gas played a key role throughout the Earth’s history. It certainly compensated for the young Sun’s lower luminosity. There is no question that it bailed us out of two snowball episodes or that it led to a brief 5 °C warming at the onset of the Eocene. Less certain is that diminishing atmospheric CO2 content was responsible for the global cooling that began 50 million years ago when the Indian subcontinent collided with Asia. Finally, it colluded with changing seasonality, ocean circulation re-organisation and iron fertilisation to generate the 100 thousand year glacial cycles that dominated the last half-million years.
DS201808-1728
2018
Brunelli, D., Cipriani, A., Bonatti, E.Thermal effects of pyroxenites on mantle melting below mid-ocean ridges.Nature Geoscience, Vol. 11, 7, pp. 520-525.Mantlepyroxenites

Abstract: After travelling in Earth’s interior for up to billions of years, recycled material once injected at subduction zones can reach a subridge melting region as pyroxenite dispersed in the host peridotitic mantle. Here we study genetically related crustal basalts and mantle peridotites sampled along an uplifted lithospheric section created at a segment of the Mid-Atlantic Ridge through a time interval of 26 million years. The arrival of low-solidus material into the melting region forces the elemental and isotopic imprint of the residual peridotites and of the basalts to diverge with time. We show that a pyroxenite-bearing source entering the subridge melting region induces undercooling of the host peridotitic mantle, due to subtraction of latent heat by melting of the low-T-solidus pyroxenite. Mantle undercooling, in turn, lowers the thermal boundary layer, leading to a deeper cessation of melting. A consequence is to decrease the total amount of extracted melt, and hence the magmatic crustal thickness. The degree of melting undergone by a homogeneous peridotitic mantle is higher than the degree of melting of the same peridotite but veined by pyroxenites. This effect, thermodynamically predicted for a marble-cake-type peridotite-pyroxenite mixed source, implies incomplete homogenization of recycled material in the convective mantle.
DS201809-2002
2018
Brunelli, D., Cipriani, A., Bonatti, E.Thermal effects of pyroxenites on mantle melting below mid-ocean ridges.Nature Geoscience, Vol. 11, July, pp. 520-525.Mantle, Oceanmelting

Abstract: After travelling in Earth’s interior for up to billions of years, recycled material once injected at subduction zones can reach a subridge melting region as pyroxenite dispersed in the host peridotitic mantle. Here we study genetically related crustal basalts and mantle peridotites sampled along an uplifted lithospheric section created at a segment of the Mid-Atlantic Ridge through a time interval of 26 million years. The arrival of low-solidus material into the melting region forces the elemental and isotopic imprint of the residual peridotites and of the basalts to diverge with time. We show that a pyroxenite-bearing source entering the subridge melting region induces undercooling of the host peridotitic mantle, due to subtraction of latent heat by melting of the low-T-solidus pyroxenite. Mantle undercooling, in turn, lowers the thermal boundary layer, leading to a deeper cessation of melting. A consequence is to decrease the total amount of extracted melt, and hence the magmatic crustal thickness. The degree of melting undergone by a homogeneous peridotitic mantle is higher than the degree of melting of the same peridotite but veined by pyroxenites. This effect, thermodynamically predicted for a marble-cake-type peridotite–pyroxenite mixed source, implies incomplete homogenization of recycled material in the convective mantle.
DS201805-0938
2018
Buchan, K.L., Ernst, R.E.A giant circumferential dyke swarm associated with the High Arctic Large Igneous Province ( HALIP).Gondwana Research, Vol. 58, pp. 39-57.Canada, Greenlanddykes

Abstract: n this study, we identify a giant circumferential mafic dyke swarm associated with the 135-75 Ma High Arctic Large Igneous Province (HALIP). Previously, a HALIP giant radiating mafic dyke swarm, with portions scattered across the Canadian high Arctic islands, northern Greenland, Svalbard and Franz Josef Land, was recognized in a pre-drift plate tectonic reconstruction of the Arctic region. The radiating swarm has been interpreted to focus above a mantle plume responsible for HALIP magmatism. The newly-recognized HALIP giant circumferential swarm has a centre that is near the focus of the HALIP radiating system, and hence, is likely related to the HALIP plume. Elements of the circumferential swarm are located in each of the four regions where the radiating system is found. The circumferential swarm has a quasi-circular or slightly elliptical geometry, an outer diameter of ~1600 km and an arc of ~220°. It is one of the largest giant circumferential dyke swarms recognized on Earth, and could be linked to the outer edge of the flattening plume head. It is also the first such swarm to have been identified by means of a plate tectonic reconstruction. Although giant circumferential dyke swarms appear to be relatively rare on Earth, possible analogues are common on Venus and are also found on Mars. On Venus giant circular or elliptical tectono-magmatic features, termed coronae, are characterized by an annulus of graben or fissures and prominent topography. Some coronae include a radiating graben-fissure system. Both radiating and circumferential graben may be underlain by dykes. If so, coronae could be analogues for terrestrial giant circumferential dyke swarms such as observed in the case of the HALIP.
DS201809-2003
2018
Buchen, J., Marquardt, H., Speziale, S., Kawazoe, T., Ballaran, T.B., Kumosov, A.High pressure single crystal elasticity of wadlsleyite and the seismic signature of water on the shallow transition zone.Earth and Planetary Science Letters, Vol. 498, pp. 77-87.Mantlegeophysics - seismic

Abstract: Earth's transition zone at depths between 410 km and 660 km plays a key role in Earth's deep water cycle since large amounts of hydrogen can be stored in the nominally anhydrous minerals wadsleyite and ringwoodite, . Previous mineral physics experiments on iron-free wadsleyite proposed low seismic velocities as an indicative feature for hydration in the transition zone. Here we report simultaneous sound wave velocity and density measurements on iron-bearing wadsleyite single crystals with 0.24 wt-% . By comparison with earlier studies, we show that pressure suppresses the velocity reduction caused by higher degrees of hydration in iron-bearing wadsleyite, ultimately leading to a velocity cross-over for both P-waves and S-waves. Modeling based on our experimental results shows that wave speed variations within the transition zone as well as velocity jumps at the 410-km seismic discontinuity, both of which have been used in previous work to detect mantle hydration, are poor water sensors. Instead, the impedance contrast across the 410-km seismic discontinuity that is reduced in the presence of water can serve as a more robust indicator for hydrated parts of the transition zone.
DS201812-2784
2018
Bulanova, G.P., Smith, C.B., Pearson, D.G., Kohn, S.C., Davy, A.T., McKay, A., Marks, A.Murowa deposit: Diamonds from the Murowa kimberlites: formation within extremely depleted and metasomatized Zimbabwean peridotitic subcontinental mantle.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 425-Africa, Zimbabwedeposit - Murowa
DS201812-2785
2018
Bulanova, G.P., Speich, L. Smith, C.B., Gaillou, E., Koln, S.C., Wibberley, E., Chapman, J.G., Howell, D., Davy, A.T.Argyle deposit: The unique nature of Argyle fancy diamonds: internal structure, paragenesis, and reasons for color.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 169-190.Australia, western Australiadeposit - Argyle
DS201812-2786
2018
Bulbuc, K.M., Galarneau, M., Stachel, T., Stern, R.A., Kong, J., Chinn, I.Contrasting growth conditions for sulphide-and garnet-included diamonds from the Victor mine ( Ontario).2018 Yellowknife Geoscience Forum , p. 97-98. abstractCanada, Ontario, Attawapiskatdeposit - Victor

Abstract: The Victor Diamond Mine, located in the Attawapiskat kimberlite field (Superior Craton), is known for its exceptional diamond quality. Here we study the chemical environment of formation of Victor diamonds. We imaged eight sulphide-included diamond plates from Victor using cathodoluminescence (CL). Then, along core-rim transects, we measured nitrogen content and aggregation state utilizing Fourier Transform Infrared (FTIR) spectroscopy, and the stable isotope compositions of carbon (?13C) and nitrogen (?15N), using a multi-collector ion microprobe (MC-SIMS). We compare the internal growth features and chemical characteristics of these sulphide inclusion-bearing diamonds with similar data on garnet inclusion-bearing diamonds from Victor (BSc thesis Galarneau). Using this information, possible fractionation processes during diamond precipitation are considered and inferences on the speciation of the diamond forming fluid(s) are explored. Sulphide inclusion-bearing diamonds show much greater overall complexity in their internal growth features than garnet inclusion-bearing diamonds. Two of the sulphide-included samples have cores that represent an older generation of diamond growth. Compared to garnet inclusion-bearing diamonds, the sulphide-included diamonds show very little intra-sample variation in both carbon and nitrogen isotopic composition; the inter-sample variations in carbon isotopic composition, however, are higher than in garnet included diamonds. For sulphide-included diamonds, ?13C ranges from -3.4 to -17.5 and ?15N ranges from -0.2 to -9.2. Garnet inclusion-bearing diamonds showed ?13C values ranging from -4.6 to -6.0 and ?15N ranging from -2.8 to -10.8. The observation of some 13C depleted samples indicates that, unlike the lherzolitic garnet inclusion-bearing diamonds, the sulphide inclusion-bearing diamonds are likely both peridotitic and eclogitic in origin. The total range in N content across sulphide inclusion-bearing diamonds was 2 to 981 at ppm, similar to the garnet-included samples with a range of 5 to 944 at ppm. The very limited variations in carbon and nitrogen isotopic signatures across growth layers indicate that sulphide-included Victor diamonds grew at comparatively high fluid:rock ratios. This is contrasted by the garnet inclusion-bearing diamonds that commonly show the effects of Rayleigh fractionation and hence grew under fluid-limited conditions.
DS201801-0007
2018
Bunge, H-P., Glasmacher, U.A.Models and observations of vertical motion ( MoveOn) associated with rifting to passive margins. PrefaceGondwana Research, Vol. 53, 1, pp. 1-8.Mantlerifting

Abstract: Two recent co-ordinated research programs - the SAMPLE (South Atlantic Margin Processes and Links with onshore Evolution) program of the German Science Foundation and the French Topo-Africa program - have focused attention on the interaction of the lithosphere with sublithospheric processes. With a main thrust on the West-Gondwana break up and the subsequent post-rift evolution of the South Atlantic passive margins and their hinterlands, SAMPLE and Topo-Africa made concerted efforts to advance models and observations of vertical motions (MoveOn) in the South Atlantic region as a probe into mantle convection/lithosphere interaction. In this special issue of Gondwana Research we assemble a set of contributions that stem from these programs aimed to gain insights on rifting in a geodynamic context with a particular focus on models and observations of the vertical motions of the lithosphere induced by mantle flow. Anderson (1982) suggested that breakup of the supercontinent Gondwana owed to forces in the sublithospheric mantle. However, despite much progress in mantle flow modeling (see Zhong and Liu, 2016 for a recent review), linking mantle convection forces and motion of the lithosphere in quantitative terms has remained elusive. It is generally accepted that plate tectonics is a surface expression of mantle convection and that mantle flow drives horizontal plate motion (Davies, 1999). However, plate tectonic motion reflects a balance of poorly known sublithospheric forces related to mantle flow, and of shallow plate-boundary forces (see Iaffaldano and Bunge, 2015 for a recent review). The latter involve topographic loads from mountain belts and fault friction along convergent plate boundaries (Iaffaldano and Bunge, 2009). Rates of change of plate velocities connect to changes in orogenic topography (Iaffaldano et al., 2006; Austermann and Iaffaldano, 2013) or plate boundary strength (Iaffaldano, 2012), making it possible to reduce some uncertainty on plate boundary forces from the analysis of plate motion changes. But the superposition of sublithospheric forces and shallow plate-boundary forces inhibits interpretations of horizontal plate motions solely in terms of mantle flow related forces. It is also believed that substantial vertical deflections of the earth's surface are induced by viscous stresses from the mantle (e.g., Pekeris, 1935). Such deflections were recognized early on in the sedimentary record through unconformities and missing sections (e.g., Stille, 1919, 1924). Termed ‘Dynamic Topography’ by Hager et al. (1985) > 30 years ago, this topic has received much attention lately (see Braun, 2010 for a recent review). The essential role of dynamic topography in dynamic earth models is well understood, because the mass anomalies associated with surface deflections yield gravity anomalies of comparable amplitude to the flow inducing mantle density variations. Therefore, Geoid interpretations have long been performed with dynamic earth models that account for dynamic topography as well as mantle density heterogeneity (e.g., Ricard et al., 1984; Richards and Hager, 1984; Forte and Mitrovica, 2001). The dynamic topography response of earth models to internal loads (e.g., hot rising plumes or cold sinking slabs) is commonly expressed through kernels (see Colli et al., 2016, for a recent review). They imply that the earth's surface sustains deflections on the order of ± 1 km. For a plume rising through a uniform viscosity mantle the kernels predict the deflections to grow continuously during plume ascend. This is borne out in laboratory models of isoviscous mantle flow (Griffith et al., 1989). However, in the presence of a weak upper mantle much of the surface deflection develops in the final phase of the plume ascend, in a time span of a few million years (Myrs) associated with vertical transit of the plume through the low viscosity upper mantle (Fig. 1). This makes rapid surface uplift events geodynamically plausible.
DS201807-1481
2018
Bureau, H., Remusat, L., Esteve, I., Pinti, D.L., Cartigney, P.The growth of lithospheric diamonds. ( inclusions and carbon isotope fractionation)Science Advances, Vol. 4, 6, doi:10.1126/ sciadv.aat1602Mantlediamond morphology

Abstract: Natural diamonds contain mineral and fluid inclusions that record diamond growth conditions. Replicating the growth of inclusion-bearing diamonds in a laboratory is therefore a novel diagnostic tool to constrain the conditions of diamond formation in Earth’s lithosphere. By determining the carbon isotopic fractionation during diamond growth in fluids or melts, our laboratory experiments revealed that lithospheric monocrystalline and fibrous and coated diamonds grow similarly from redox reactions at isotopic equilibrium in water and carbonate-rich fluids or melts, and not from native carbon. These new results explain why most of the lithospheric diamonds are characterized by a common carbon isotopic fingerprint, inherited from their common parent fluids and not from the mantle assemblage.
DS201812-2787
2018
Buryak, S., Reyes, A.V., Siver, P.A., Li, L., Dufrane, S.A.Bulk organic geochemistry and U-Pb zircon geochronology of the Wombat sedimentary fill.2018 Yellowknife Geoscience Forum , p. 98-99. abstractCanada, Northwest Territoriesdeposit - Wombat

Abstract: The Wombat locality (64.73°N, 110.59°W) is a diamondiferous kimberlite in the Lac de Gras kimberlite field of Northwest Territories. Two drill cores, CH 93-29 and DDH 0-005, intersect the Wombat crater facies and include 195 m of well preserved, undisturbed lake sediment fill. Bulk sediment elemental analysis, C isotope composition, and Rock-Eval pyrolysis, together with inferences from microfossils, are used to characterize conditions of sedimentation and paleoenvironment in the maar lake. Bulk sediment C/N, hydrogen index (HI), and ?13C indicate material derived from C3 land plants dominates the sedimentary organic matter, with a minor algal contribution. The ?13C values range from -25.3 ‰ to -30.2 ‰ (average -26.6 ‰) and are typical for C3 land plants, with fluctuations in ?13C likely related to shifts in the proportions of land-derived material and algal organic matter. An overall trend of higher ?13C towards the top of the core suggests increasing autochthonous organic matter production. 18 samples analyzed by Rock-Eval pyrolysis all plot in the Type III kerogen field for HI vs. Tmax,with average Tmax values ~425 °C indicative of the low thermal maturity of organic matter. Total organic carbon (TOC) averages 3.6 wt.% and average total carbonate content is 14.1 wt.%, indicating bottom water anoxia and substantial carbonate input from weathering of overlying carbonate cover rocks, respectively. Together with well-preserved freshwater microfossils (e.g. diatoms, chrysophytes, synurophytes), the results indicate deposition in a non-marine setting. The age of the Wombat maar lake sediments is determined using MC-LA-ICP-MS U-Pb zircon geochronology from two distal rhyolitic tephra beds found in the core DDH 0-005, yielding a date of 82.97±0.60 Ma (MSWD = 1.7, n=18 of 33 grains analyzed). This minimum age suggests that Wombat kimberlite pipe emplacement occurred during the Late Cretaceous, with sedimentation in the maar beginning shortly thereafter. Though our geochronology is preliminary at this point, our findings from the Wombat pipe post-eruptive lake sediment fill provide direct evidence for a non-marine environment in the Lac De Gras area during the Late Cretaceous. Furthermore, microfossils in the Wombat pipe sediment fill likely include the oldest-known occurrence of freshwater diatoms.
DS201807-1482
2018
Bussweiler, Y., Pearson, D.G., Stachel, T., Kjarsgaard, B.A.Cr-rich megacrysts of clinopyroxene and garnet from Lac de Gras kimberlites, Slave Craton, Canada - implications for the origin of clinopyroxene and garnet in cratonic lherzolites.Mineralogy and Petrology, 10.1007/s00710 -018-0599-2, 14p. Canada, Northwest Territoriesdeposit - Diavik, Ekati

Abstract: Kimberlites from the Diavik and Ekati diamond mines in the Lac de Gras kimberlite field contain abundant large (>1 cm) clinopyroxene (Cr-diopside) and garnet (Cr-pyrope) crystals. We present the first extensive mineral chemical dataset for these megacrysts from Diavik and Ekati and compare their compositions to cratonic peridotites and megacrysts from the Slave and other cratons. The Diavik and Ekati Cr-diopside and Cr-pyrope megacrysts are interpreted to belong to the Cr-rich megacryst suite. Evidence for textural, compositional, and isotopic disequilibrium suggests that they constitute xenocrysts in their host kimberlites. Nevertheless, their formation may be linked to extensive kimberlite magmatism and accompanying mantle metasomatism preceding the eruption of their host kimberlites. It is proposed that the formation of megacrysts may be linked to failed kimberlites. In this scheme, the Cr-rich megacrysts are formed by progressive interaction of percolating melts with the surrounding depleted mantle (originally harzburgite). As these melts percolate outwards, they may contribute to the introduction of clinopyroxene and garnet into the depleted mantle, thereby forming lherzolite. This model hinges on the observation that lherzolitic clinopyroxenes and garnets at Lac de Gras have compositions that are strikingly similar to those of the Cr-rich megacrysts, in terms of major and trace elements, as well as Sr isotopes. As such, the Cr-rich megacrysts may have implications for the origin of clinopyroxene and garnet in cratonic lherzolites worldwide.
DS201804-0676
2017
Butler, J.E., Post, J.E., Wang, W.The Foxfire diamond revisited. Diavik ( using DiamondView phosphoresence)Gems & Gemology Lab Notes, Vol. 53, 4, pp. 479-481.Canada, Northwest Territoriesdiamond notable - Foxfire

Abstract: The largest gem-quality rough diamond found in Canada, reported earlier in Gems & Gemology (Summer 2016 GNI, pp. 188-189), has revealed remarkable responses to excitation with long- and mid-wave UV light. This 187.63 ct diamond (figure 1) was extracted from the Diavik mine in the Canadian Arctic in the spring of 2015. Aptly named for the aurora borealis, the “Foxfire” displays unusual fluorescence and phosphorescence behavior upon exposure to ultraviolet light. As previously reported, this type Ia diamond has a high concentration of nitrogen impurities, a weak hydrogen-related absorption at 3107 cm-1, and typical "cape" absorption lines.
DS201811-2558
2018
Byerly, B.Extraordinary crystals hold secrets of Earth's infancy. ( Barberton area)Nature , Oct 1, 1p.Africa, South Africazircons

Abstract: Geologists have a new window onto the early Earth: zircon crystals from South Africa that could be as much as 4.1 billion years old. Ancient crystals of zircon - a durable mineral found in rock that has been squeezed and heated - from Western Australia have revealed some of the planet’s early secrets, such as clues to the chemistry of its primordial crust. But researchers have had little in the way of other records for this period of Earth’s infancy. Now, Benjamin Byerly at Louisiana State University in Baton Rouge and his colleagues report their discovery of a second rich trove of zircons. The crystals lie east of Pretoria, in a rock formation known as the Barberton greenstone belt. The African zircons are important because they have been subject to less heating and squeezing than the Australian samples. As a result, the African crystals may have richer stories to tell about the chemistry of Earth’s early years.
DS201802-0224
2018
Byrne, K.S., Butler, J.E., Wang, W., Post, J.E.Chameleon diamonds: thermal processes governing luminescence and model for the color change.Diamond & Related Materials, Vol. 81, pp. 45-53.Technologyluminescence

Abstract: To date, the eponymous color-changing behavior of chameleon diamonds lacks an explanation in terms of an identified diamond defect structure or process. Well known, however, is that this color-change is driven by the influence of both light and heat. In this paper, we present observations of how luminescence emission in chameleon diamonds responds to temperature changes and optical pumping. Fluorescence, phosphorescence, and thermoluminescence experiments on a suite of natural chameleon diamonds reveal that a specific emission band, peaking near 550 nm, may be stimulated by several different mechanisms. We have observed thermal quenching of the 550 nm emission band with an activation energy of 0.135 eV. The 550 nm band is also observed in phosphorescence and thermoluminescence. Thermoluminescence spectra suggest the presence of low lying acceptor states at 0.7 eV above the valence band. When excited with 270 nm light, we observe emission of light in two broad spectral bands peaking at 500 and 550 nm. We suggest that the 550 nm emission band results from donor—acceptor pair recombination (DAPR) from low lying acceptor states at ca. 0.7 eV above the valence band and donor states approximately 2.5 to 2.7 eV above the valence band. We do not identify the structure of these defects. We propose a speculative model of the physics of the color change from ‘yellow’ to ‘green’ which results from increased broad-band optical absorption in the near-IR to visible due to transitions from the valence band into un-ionized acceptor states available in the ‘green’ state of the chameleon diamond. We report near-IR absorption spectra confirming the increased absorption of light in the near-IR to visible in the ‘green’ when compared to the ‘yellow’ state with a threshold at ca. 0.65 eV, supporting the proposed model.
DS201804-0677
2018
Caamano-Alegre, M.Drift theory and plate tectonics: a case of embedding in geology.Foundations of Science, Vol. 23, pp. 17-35.Mantleplate tectonics

Abstract: The purpose of this paper is to elucidate the semantic relation between continental drift and plate tectonics. The numerous attempts to account for this case in either Kuhnian or Lakatosian terms have been convincingly dismissed by Rachel Laudan (PSA: Proceedings of the Biennial Meeting of the Philosophy of Science Association. Symposia and Invited Papers, 1978), who nevertheless acknowledged that there was not yet a plausible alternative to explain the so called "geological revolution". Several decades later, the epistemological side of this revolution has received much attention (Ruse in The darwinian paradigm, essays on its history, philosophy and religious implications. London, Routledge, 1981/1989; Thagard in Conceptual revolutions. Princeton University Press, Princeton, 1992; Marvin in Metascience 10:208-217, 2001; Oreskes in Plate tectonics: an insiders’ history of the modern theory of the earth. Westview Press, Boulder, 2003), while the semantic relation between drift theory and plate tectonics has remained mainly unexplored. In studying this case under a new light, the notion of embedding, as distinguished from other sorts of intertheoretical relations (Moulines in Cognitio Humana-Dynamik des Wissens und der Werte. XVII, Institut für Philosophie der Universität Leipzig, Leipzig, 1996, Time, chance, and reduction: philosophical aspects of statistical mechanics. Cambridge University Press, Cambridge, 2010, Metatheoria 1(2):11-27, 2011), will have a particular significance. After formally analyzing the relationship between continental drift and plate tectonics, it will become evident that the models of drift theory are part of the models of plate tectonics, thereby fulfilling the conditions for embedding. All theoretical concepts from drift theory are presupposed in some theoretical concepts from plate tectonics, and all empirical concepts of the former are shared by the latter. Furthermore, all the successful paradigmatic applications of continental drift are also successful applications of plate tectonics. As a consequence, under the label "geological revolution", we actually find a salient historical case of cumulative progress across theory change.
DS201805-0939
2018
Cairncross, B.The where of mineral names: Bultfontein, Bultfontein diamond mine.Rocks & Minerals, Vol. 92, 6, pp. 578-581.Africa, South Africadeposit - Bultfontein
DS201808-1729
2018
Calvert, A.J., Boublier, M.P.Archean continental spreading inferred from seismic images of the Yilgarn Craton.Nature Geoscience, Vol. 11, 7, pp. 526-530.Australiageophysics - seismic

Abstract: On the early Earth, oceanic plateaux similar to present-day Iceland are thought to have evolved into less dense microcontinents as they thickened by continued melt intrusion and crustal fractionation. These earliest continents may have been so weak on a hotter Earth that they collapsed laterally in response to thickening by further magmatic growth or tectonic imbrication. This continental spreading is likely to have resulted in the development of pervasive ductile strain fabrics in the deeper crust, which, if preserved, could generate seismic reflections. Here we present seismic images from the ancient core of the Archaean Yilgarn Craton of Australia that reveal shallowly dipping to horizontal reflections that pervade the middle and lower crust. We interpret these reflective fabrics as the result of widespread lateral crustal flow during the late stage of craton evolution approximately 2.66 to 2.61?billion years ago, which coincided with the widespread intrusion of high-temperature crustal melts, as thickened early continental crust collapsed. The consequent subsidence of large regions of the upper crust, including volcanic and sedimentary greenstone rocks, in the hanging walls of listric mid-lower crustal ductile flow fabrics caused these rocks to drop beneath the granitic melts rising towards the surface, and did not involve Rayleigh-Taylor instabilities within a mostly mobile crust.
DS201809-2004
2018
Calvert, A.J., Doublier, M.P.Archean continental spreading inferred from seismic images of the Yilgarn Craton.Nature Geoscience, Vol. 11, July, pp. 526-530.Australiageophysics - seismic

Abstract: On the early Earth, oceanic plateaux similar to present-day Iceland are thought to have evolved into less dense microcontinents as they thickened by continued melt intrusion and crustal fractionation. These earliest continents may have been so weak on a hotter Earth that they collapsed laterally in response to thickening by further magmatic growth or tectonic imbrication. This continental spreading is likely to have resulted in the development of pervasive ductile strain fabrics in the deeper crust, which, if preserved, could generate seismic reflections. Here we present seismic images from the ancient core of the Archaean Yilgarn Craton of Australia that reveal shallowly dipping to horizontal reflections that pervade the middle and lower crust. We interpret these reflective fabrics as the result of widespread lateral crustal flow during the late stage of craton evolution approximately 2.66 to 2.61?billion years ago, which coincided with the widespread intrusion of high-temperature crustal melts, as thickened early continental crust collapsed. The consequent subsidence of large regions of the upper crust, including volcanic and sedimentary greenstone rocks, in the hanging walls of listric mid-lower crustal ductile flow fabrics caused these rocks to drop beneath the granitic melts rising towards the surface, and did not involve Rayleigh-Taylor instabilities within a mostly mobile crust.
DS201807-1483
2018
Campbell, J.A.H.Keynote address: Financing diamond projects. ( mentions Karowe)SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 137-154.Globalrough production, economics
DS201808-1730
2018
Campbell, J.A.H.Financing diamond projects. PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 35 ppts.Globaleconomics
DS201810-2300
2018
Cartier, L.E., Ali, S.H., Krzemnicki, M.S.Blockchain, chain of custody and trace elements: an overview of tracking and traceability opportunities in the gem industry.The Journal of Gemmology, Vol. 36, 3, pp. 212-227.Globalblockchain terminology
DS201804-0678
2018
Cartigny, P.Stable isotopes and diamonds.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 14-15. abstractTechnologycarbon
DS201809-2005
2017
Cassette, P., Notari, F., Lepy, M-C., Caplan, C., Pierre, S., Hainschwang, T., Fritsch, E.Residual radioactivity of treated green diamonds.Applied Radiation and Isotopes, Vol. 126, 1, pp. 66-72.Globaldiamond - green

Abstract: Treated green diamonds can show residual radioactivity, generally due to immersion in radium salts. We report various activity measurements on two radioactive diamonds. The activity was characterized by alpha and gamma ray spectrometry, and the radon emanation was measured by alpha counting of a frozen source. Even when no residual radium contamination can be identified, measurable alpha and high-energy beta emissions could be detected. The potential health impact of radioactive diamonds and their status with regard to the regulatory policy for radioactive products are discussed.
DS201809-2006
2018
Castillo-Oliver, M., Giuliani, A., Griffin, W.L., O'Reilly, S.Y.Characterisation of primary and secondary carbonates in hypabyssal kimberlites: an integrated compositional and Sr-isotopic approach. Mineralogy and Petrology, doi.org/10.1007/s00710-018-0626-3 13p.Africa, South Africa, Australia, Europe, Finland, Canada, Northwest Territoriesdeposit - Wesselton, De Beers, Bultfontein, Benfontein, Jagersfontein, Cullinan, Melita, Pipe 1, Grizzley, Koala

Abstract: Carbonates in fresh hypabyssal kimberlites worldwide have been studied to understand their origin [i.e. primary magmatic (high T) versus deuteric (‘low T’) versus hydrothermal/alteration (‘low T’)] and identify optimal strategies for petrogenetic studies of kimberlitic carbonates. The approach presented here integrates detailed textural characterisation, cathodoluminescence (CL) imaging, in situ major- and trace-element analysis, as well as in situ Sr-isotope analysis. The results reveal a wide textural diversity. Calcite occurs as fine-grained groundmass, larger laths, segregations, veins or as a late crystallising phase, replacing olivine or early carbonates. Different generations of carbonates commonly coexist in the same kimberlite, each one defined by a characteristic texture, CL response and composition (e.g., variable Sr and Ba concentrations). In situ Sr isotope analysis revealed a magmatic signature for most of the carbonates, based on comparable 87Sr/86Sr values between these carbonates and the coexisting perovskite, a robust magmatic phase. However, this study also shows that in situ Sr isotope analysis not always allow distinction between primary (i.e., magmatic) and texturally secondary carbonates within the same sample. Carbonates with a clear secondary origin (e.g., late-stage veins) occasionally show the same moderately depleted 87Sr/86Sr ratios of primary carbonates and coexisting perovskite (e.g., calcite laths-shaped crystals with 87Sr/86Sr values identical within uncertainty to those of vein calcite in the De Beers kimberlite). This complexity emphasises the necessity of integrating detailed petrography, geochemical and in situ Sr isotopic analyses for an accurate interpretation of carbonate petrogenesis in kimberlites. Therefore, the complex petrogenesis of carbonates demonstrated here not only highlights the compositional variability of kimberlites, but also raises concerns about the use of bulk-carbonate C-O isotope studies to characterise the parental melt compositions. Conversely, our integrated textural and in situ study successfully identifies the most appropriate (i.e. primary) carbonates for providing constraints on the isotopic parameters of parental kimberlite magmas.
DS201812-2788
2018
Cawood, P.A., Hawkesworth, C.J.Continental crustal volume, thickness and area, and their geodynamic implications.Gondwana Research, doi.org/10.1016 /j.gr.2018.11.001 37p.Mantlegeodynamics

Abstract: Models of the volume of continental crust through Earth history vary significantly due to a range of assumptions and data sets; estimates for 3?Ga range from <10% to >120% of present day volume. We argue that continental area and thickness varied independently and increased at different rates and over different periods, in response to different tectonic processes, through Earth history. Crustal area increased steadily on a pre-plate tectonic Earth, prior to ca. 3?Ga. By 3?Ga the area of continental crust appears to have reached a dynamic equilibrium of around 40% of the Earth's surface, and this was maintained in the plate tectonic world throughout the last 3?billion?years. New continental crust was relatively thin and mafic from ca. 4-3?Ga but started to increase substantially with the inferred onset of plate tectonics at ca. 3?Ga, which also led to the sustained development of Earth's bimodal hypsometry. Integration of thickness and area data suggests continental volume increased from 4.5?Ga to 1.8?Ga, and that it remained relatively constant through Earth's middle age (1.8-0.8?Ga). Since the Neoproterozoic, the estimated crustal thickness, and by implication the volume of the continental crust, appears to have decreased by as much as 15%. This decrease indicates that crust was destroyed more rapidly than it was generated. This is perhaps associated with the commencement of cold subduction, represented by low dT/dP metamorphic assemblages, resulting in higher rates of destruction of the continental crust through increased sediment subduction and subduction erosion.
DS201812-2789
2018
Cawood, P.A., Hawkesworth, C.J., Pisarevsky, S.A., Dhuime, B., Capitanio, F.A., Nebel, O.Geological archive of the onset of plate tectonics.Philosphical Transactions of the Royal Society, rsta.royalsociety publishing.org 30p. AvailableMantletectonics, geochemistry

Abstract: Plate tectonics, involving a globally linked system of lateral motion of rigid surface plates, is a characteristic feature of our planet, but estimates of how long it has been the modus operandi of lithospheric formation and interactions range from the Hadean to the Neoproterozoic. In this paper, we review sedimentary, igneous and metamorphic proxies along with palaeomagnetic data to infer both the development of rigid lithospheric plates and their independent relative motion, and conclude that significant changes in Earth behaviour occurred in the mid- to late Archaean, between 3.2?Ga and 2.5?Ga. These data include: sedimentary rock associations inferred to have accumulated in passive continental margin settings, marking the onset of sea-floor spreading; the oldest foreland basin deposits associated with lithospheric convergence; a change from thin, new continental crust of mafic composition to thicker crust of intermediate composition, increased crustal reworking and the emplacement of potassic and peraluminous granites, indicating stabilization of the lithosphere; replacement of dome and keel structures in granite-greenstone terranes, which relate to vertical tectonics, by linear thrust imbricated belts; the commencement of temporally paired systems of intermediate and high dT/dP gradients, with the former interpreted to represent subduction to collisional settings and the latter representing possible hinterland back-arc settings or ocean plateau environments. Palaeomagnetic data from the Kaapvaal and Pilbara cratons for the interval 2780-2710?Ma and from the Superior, Kaapvaal and Kola-Karelia cratons for 2700-2440?Ma suggest significant relative movements. We consider these changes in the behaviour and character of the lithosphere to be consistent with a gestational transition from a non-plate tectonic mode, arguably with localized subduction, to the onset of sustained plate tectonics.
DS201809-2007
2018
Chakrabarty, A., Mitchell, R.H., Ren, M., Sen, A.K., Supriyo, P., Supratim, P.Nb Zr REE re-mobilization and implications for transitional agpaitic rock formation: insights from the Sushin a Hill complex, India.Petrology, doi: 10.1093/petrology/egy084Indianepheline syenite

Abstract: The formation of transitional agpaitic rocks is not a well understood process as there are few studies of miaskitic to agpaitic transitions. The Mesoproterozoic Sushina Hill complex (India) provides a suitable site to investigate these "transitions" as this complex hosts diverse miaskitic and agpaitic nepheline syenites, together with syenites containing exotic mineral assemblages. In this study, we have used mineralogical and geochemical data to describe the evolution of the transitional agpaitic rocks occurring at Sushina Hill. In common with other occurrences, high field strength elements (HFSE) in miaskitic nepheline syenites are mainly sequestered by primary zircon and magnetite. In contrast, the major HFSE carriers in agpaitic nepheline syenites (agpaitic unit-I) are late-magmatic eudialyte and rinkite-(Ce) - nacareniobsite-(Ce), formed at T between 825° - 784ºC and aSiO2 in the range of 0.41 - 0.44. With decreasing temperature (? 575ºC) and aSiO2(0.30), coupled with an increase in aH2O, this assemblage has undergone extensive subsolidus alteration leading to the decomposition of late-magmatic eudialyte to wöhlerite - marianoite, alkali-zirconosilicates (catapleiite/gaidonnyaite, hilairite), and pectolite - serandite. Decomposition of late-magmatic eudialyte resulted in a more alkaline fluid by increasing the a(Na+)/a(Cl-) ratio, facilitating crystallization of hydrothermal eudialyte replacing late-magmatic eudialyte. Crystallization of hydrothermal eudialyte leads to evolving fluids which are less alkaline, resulting in the crystallization of a transitional agpaitic assemblage of pyrochlore + zircon + niobokupletskite + wadeite in agpaitic unit-II in the temperature range 547º - 455ºC with aSiO2 in the range 0.27 - 0.25. Regional scale deformation contemporaneous with the subsolidus alteration stage leads to separation of the evolving fluid from the system, resulting in extensive albitization, with superposition of a new miaskitic-like assemblage in syenite I in the form of late-stage zircon - magnetite - xenotime - monazite-(Ce) upon the early assemblage of primary zircon and magnetite. During deformation, syenite unit-II composed of eudialyte - albite - aegirine was also formed and considered as a later stage pegmatitic offshoot of agpaitic unit I. The mineralogical changes are also complemented by variations in the bulk-rock composition in which the total REE, Nb, U and Th concentrations increase in order from: miaskitic unit ? agpaitic unit I ? syenite unit II, -I ? agpaitic unit II at constant Zr concentration. This suggests that the REE-Nb are mainly mobilized in agpaitic unit-II during the agpaitic - to - transitional agpaitic assemblage transformation in a relatively less alkaline environment.
DS201803-0437
2018
Chandra, J., Paul, D., Viladar, S.G., Sensarma, S.Origin of Amba Dongar carbonatite complex, India and its possible linkage with the Deccan Large Igneous Province.Geological Society of London Special Publication, No. 463, pp. 137-169.Indiacarbonatite

Abstract: The genetic connection between Large Igneous Province (LIP) and carbonatite is controversial. Here, we present new major and trace element data for carbonatites, nephelinites and Deccan basalts from Amba Dongar in western India, and probe the linkage between carbonatite and the Deccan LIP. Carbonatites are classified into calciocarbonatite (CaO, 39.5-55.9 wt%; BaO, 0.02-3.41 wt%; ?REE, 1025-12 317 ppm) and ferrocarbonatite (CaO, 15.6-31 wt%; BaO, 0.3-7 wt%; ?REE, 6839-31 117 ppm). Primitive-mantle-normalized trace element patterns of carbonatites show distinct negative Ti, Zr-Hf, Pb, K and U anomalies, similar to that observed in carbonatites globally. Chondrite-normalized REE patterns reveal high LREE/HREE fractionation; average (La/Yb)N values of 175 in carbonatites and approximately 50 in nephelinites suggest very-low-degree melting of the source. Trace element modelling indicates the possibility of primary carbonatite melt generated from a subcontinental lithospheric mantle (SCLM) source, although it does not explain the entire range of trace element enrichment observed in the Amba Dongar carbonatites. We suggest that CO2-rich fluids and heat from the Deccan plume contributed towards metasomatism of the SCLM source. Melting of this SCLM generated primary carbonated silicate magma that underwent liquid immiscibility at crustal depths, forming two compositionally distinct carbonatite and nephelinite magmas.
DS201804-0679
2017
Chanturia, V.A., Ryazantseva, M.V., Dvoichenkova, G.P., Minenko, V.G., Koporulina, E.V.Surface modification of rock forming minerals of diamond bearing kimberlites under interaction with wastewater and electrochemically treated water.Journal of Mining Science, Vol. 53, 1, pp. 126-132.Russiadeposit - Mir

Abstract: The structural and chemical surface transformation of basic kimberlite-forming minerals (calcite, olivine, serpentine) under the contact with natural and waste mineralized water and products of electrochemical treatment of the water are studied using X-ray photoelectronic spectroscopy, scanning electron microscopy and X-ray spectral micro-analysis, and atomic force microscopy. It is found that contact with kimberlite extract and recycling water induces chemical modification of calcite surface, which consists in adsorption of hydrocarbon impurities, and chlorine- and silica-bearing compounds, majority of which are removed during interaction with the product of electrochemical treatment of recycling water. The change in the structural and chemical surface properties of rock-forming silicates, aside from adsorption-desorption of organic compound, is also connected with the distortion of nano-size layer structure after leaching of Mg, Fe and Si, and with the carbonatization of the surface.
DS201809-2008
2018
Chapman, J., Dejanin, B.An overview of synthetic diamond detection - methods and instruments.The Australian Gemmologist, Vol. 26, 9-10, pp. 209-216.Globalsynthetics
DS201805-0940
2018
Chasse, M., Griffin, W.L., Alard, O., O'Reilly, S.Y., Calas, G.Insights into the mantle geochemistry of scandium from a meta-analysis of garnet data. GEOROC databaseLithos, in press available 47p.Mantlemetasomatism

Abstract: he meta-analysis of about 13,000 analyses of scandium content in garnet grains shows that, below the spinel-garnet transition, this phase carries about three-quarters of the Sc budget of the mantle, indicating its control on Sc mobility. The Sc content of garnets in mafic rocks is low, due to a dilution effect resulting from their high modal content in garnet. Garnets from ultramafic rocks exhibit a wider range of Sc concentrations. We assess the relative influence of thermobarometry, crystal chemistry and fluid-related events on the distribution of Sc in garnet from such rocks to improve the tracking of geochemical processes in the mantle. Pressure and temperature of equilibration in the mantle are second-order factors influencing the Sc content of garnet, while crystal-chemistry, in particular and , is the main parameter controlling the compatibility of Sc. Scandium is incorporated in both X and Y sites of Cr-Ca-rich garnets, resulting in a behaviour intermediate between rare-earth elements, incorporated in the X site, and trivalent transition elements, occupying the Y site. This affinity for both sites results in a mild compatibility of Sc in the garnet stability field of the mantle; hence Sc concentration in garnet increases with melt extraction and can be reduced by silicate-melt metasomatism. In contrast, metasomatism by volatile-rich fluids increases the Sc concentration in garnet. The control of garnet on the compatibility of Sc in deep lithospheric rocks demonstrates the potential of using Sc to track the conditions of formation of magmas and their residual rocks, as well as the origin and nature of metasomatic fluids.
DS201810-2301
2018
Chayka, I.F., Izokh, A.E., Sobolev, A.V., Batanova, V.G.Low titanium lamproites of the Ryabinoviy Massif ( Aldan shield): crystallization conditions and lithospheric source.Doklady Earth Sciences, Vol. 481, 2, pp. 1008-1012.Russia, Aldan shieldlamproite

Abstract: Obtained data shows that high-potassic dyke rocks of the Ryabinoviy massif (Central Aldan) belong to low-titanium lamproite series (Mediterranean type) and are distinct with “classic” high-titanium lamproites. Based on Al-in-olivine thermometer, temperature of olivine-chrome-spinel pair crystallization varies in range between 1100 and 1250°C. This suggests lithospheric mantle source for the parental melt and makes role of mantle plume insignificant. High-precision data on olivine composition and bulk rock traceelement composition imply mixed source for the parental melt, consisted of depleted peridotite and enriched domains, originated during ancient subduction.
DS201802-0225
2018
Chen, N., Ma, H., Chen, L., Yan, B., Fang, C., Liu, X., Li, Y., Guo, L., Chen, L., Jia, X.Effects of S on the synthesis of type 1b diamond under high pressure and high temperature.International Journal of Refractory Metals & Hard Materials, Vol. 71, pp. 141-146.Technologysynthetic diamonds
DS201809-2009
2018
Chen, W., Lu, J., Jiang, S-Y., Ying, Y-C., Liu. Y-S.Radiogenic Pb reservoir contributes to the rare earth element (REE) enrichment in South Qinling carbonatites.Chemical Geology, Vol. 494, pp. 80-95.Chinacarbonatites

Abstract: Carbonatite and related alkaline silicate rocks contain one of the most significant rare earth element (REE) reserves in the world. It is well-known that these REE deposits are characterized by a strong light REE enrichment with a steep fractionation from La to Lu in the chondrite-normalized diagram. However, the origin of their REE enrichment remains debatable. The Shaxiongdong (SXD) carbonatite in the South Qinling orogenic belt hosts one of the most important REE deposits in central China. In this study, in situ chemical and isotopic data have been obtained for carbonate minerals from the complex. Our results show that calcite has variable trace element abundances, especially REEs. In situ Pb isotope data for calcite reveal extreme variations of 206Pb/204Pb (18.05-31.71) and 207Pb/204Pb (15.49-16.36) ratios. Interestingly, Pb isotope variations display positive correlations with REE enrichments [i.e., (La/Yb)N and (La/Nd)N]. Calcite with extreme radiogenic Pb isotopic compositions displays upper mantle C and O isotopic compositions (?13Cavg?=??5.74‰, ?18Oavg?=?7.13‰) and depleted 87Sr/86Sr isotopic ratios (~0.7030). The observed various REE enrichments accompanying the variable Pb isotopic composition within SXD calcite possibly result from a closed-system metasomatic event. The U-bearing mineral (i.e., pyrochlore) accumulating abundant uranogenic lead since their Silurian formation serves as the radiogenic Pb and LREE source for the metasomatism. Alternatively, the chemical and isotopic composition observed might suggest involvement of two mantle sources (PREMA and the distinct radiogenic Pb mantle reservoir).
DS201810-2302
2018
Chen, Y., Gu, Y.J., Hung, S-H.A new appraisal of lithospheric structures of the Cordillera craton boundary region in western Canada.Tectonics, Aug. 28, 10.1029/ 2018TC004956Canada, Alberta, Saskatchewancraton

Abstract: The Western Canada Sedimentary Basin marks a boundary zone between the Precambrian North American craton and the Phanerozoic Cordillera. Its crystalline basement has documented more than 3 billion years of evolution history of western Laurentia. Here we conduct a high?resolution survey of the mantle P and S wave velocities using finite?frequency tomography. Our models show pronounced eastward increases of 4% P and 6% S wave velocities beneath the foreland region, which define a sharp seismic Cordillera?Craton boundary. In the cratonic region, distinctive high? (>2%) velocity anomalies representing depleted mantle lithospheres are well correlated with major Precambrian crustal domains. The largest lithosphere thickness contrast coincides with the Snowbird Tectonic Zone, where the Hearne province extends down to ~300 km, nearly 100 km deeper than the Proterozoic terranes in northern Alberta. In the latter region, a pronounced cylindrical negative velocity anomaly extends subvertically from 75 to ~300?km depth, which potentially results from significant tectonothermal modifications during subduction and/or plume activities. At the basin scale, mantle velocities show no apparent correlations with surface heat flux, suggesting a minimum mantle contribution to the regional thermal variability. Furthermore, the long?wavelength isostatic gravity correlates negatively with the velocities, which confirms that the melt extraction from Precambrian cratons is responsible for the formation of highly depleted mantle lithospheres. Moreover, our model reveals the increased concentrations of kimberlites and lamproites near the zones of high horizontal velocity gradients. The distinct spatial pattern may reflect either preferential formation or eruption of potentially diamondiferous rocks at lithospheric weak zones near the western margin of Laurentia.
DS201809-2010
2018
Chen, Y., Yang, J., Xu, Z., Tian, Y., Shengmin, L.Diamonds and other unusual minerals from peridotites of the Myitkyin a ophiolite, Myanmar.Journal of Asian Earth Sciences, Vol. 164, pp. 179-193.Asia, Myanmarperidotites

Abstract: Peridotites from the Myitkyina ophiolite are mainly composed of lherzolite and harzburgite. The lherzolites have relatively fertile compositions, with 39.40-43.40?wt% MgO, 1.90-3.17?wt% Al2O3 and 1.75-2.84?wt% CaO. They contain spinel and olivine with lower Cr# (12.6-18.2) and Fo values (88.7-91.6) than those of the harzburgites (24.5-59.7 and 89.6-91.6 respectively). The harzburgites have more refractory compositions, containing 42.40-46.23?wt% MgO, 0.50-1.64?wt% Al2O3 and 0.40-1.92?wt% CaO. PGE contents of the peridotites show an affinity to the residual mantle. Evaluation of petrological and geochemical characteristics of these peridotites suggests that the lherzolites and harzburgites represent residual mantle after low to moderate degrees of partial melting, respectively, in the spinel stability field. The U-shaped, primitive mantle-normalized REE patterns and strong positive Ta and Pb anomalies of the harzburgites suggest melt/fluid refertilization in either a MOR or SSZ setting after their formation at a MOR. Mineral separation of the peridotites has yield a range of exotic minerals, including diamond, moissanite, native Si, rutile and zircon, a collection similar to that reported for ophiolites of Tibet and the Polar Urals. The discovery of these exotic minerals in the Myitkyina ophiolite supports the view that they occur widely in the upper oceanic mantle.
DS201810-2303
2018
Cheng, Q.Extrapolations of secular trends in magmatic intensity and mantle cooling: implications for future evolution of plate tectonics.Gondwana Research, Vol. 63, pp. 268-273.Mantlemagmatism, geochonology

Abstract: The beginning of plate tectonics on Earth remains the subject of fundamental debate. Also, future evolution of plate tectonics has not yet been addressed adequately in the literature. Here I develop models to extrapolate secular trends of plate tectonics closely associated with mantle potential temperature; intensity of magmatic activities to estimate the lifetime of plate tectonics. First a fractal model is utilized to analyze global igneous and detrital zircon U-Pb age datasets to characterize nonlinear intensity and periodicity of peaks in magmatic activities associated with deep-seated avalanche-type events (slab break off, lithospheric root detachments and mantle plumes). The results show descending trends of both nonlinear intensity and duration of peaks in magmatism observed from 3?Ga to the present day, suggesting a general trend of mantle cooling. This relation when extrapolated yields 1.45?Gyr of time for when nonlinear intensity of major magmatic activity would vanish. Further it is demonstrated by an independent polynomial model fitted to the relation between mantle potential temperature and future age of the earth that this result conforms to the time estimated for when mantle potential temperature is reduced to mantle solidus temperature.
DS201810-2304
2018
Cheng, Z., Zhang, Z., Aibai, A., Kong, W., Holtz, F.The role of magmatic and post-magmatic hydrothermal processes on rare earth element mineralization: a study of the Bachu carbonatites from the Tarim Large Igneous Province, NW China.Lithos, Vol. 314-315, pp. 71-87.Chinacarbonatite

Abstract: The contribution of magmatic and hydrothermal processes to rare earth element (REE) mineralization of carbonatites remains an area of considerable interest. With the aim of better understanding REE mineralization mechanisms, we conducted a detailed study on the petrology, mineralogy and C-O isotopes of the Bachu carbonatites, NW China. The Bachu carbonatites are composed predominantly of magnesiocarbonatite with minor calciocarbonatite. The two types of carbonatite have primarily holocrystalline textures dominated by dolomite and calcite, respectively. Monazite-(Ce) and bastnäsite-(Ce), the major REE minerals, occur as euhedral grains and interstitial phases in the carbonatites. Melt inclusions in the dolomite partially rehomogenize at temperatures above 800?°C, and those in apatite have homogenization temperatures (Th) ranging from 645 to 785?°C. Oxygen isotope ratios of the calciocarbonatite intrusions (?18OV-SMOW?=?6.4‰ to 8.3‰), similar to the magnesiocarbonatites, indicate the parental magma is mantle-derived, and that they may derive from a more evolved stage of carbonatite fractionation. The magnesiocarbonatites are slightly enriched in LREE whereas calciocarbonatites have higher HREE concentrations. Both dolomite and calcite have low total REE (TREE) contents ranging from 112 to 436?ppm and 88 to 336?ppm, respectively, much lower than the bulk rock composition of the carbonatites (371 to 36,965?ppm). Hence, the fractional crystallization of carbonates is expected to elevate REE concentrations in the residual magma. Rocks from the Bachu deposit with the highest TREE concentration (up to 20?wt%) occur as small size (2?mm to 3 cm) red rare earth-rich veins (RRV) with barite + celestine + fluorapatite + monazite-(Ce) associations. These rocks are interpreted to have a hydrothermal origin, confirmed by the fluid inclusions in barite with Th in the range 198-267?°C. Hydrothermal processes may also explain the existence of interstitial textures in the carbonatites with similar mineral assemblages. The C-O isotopic compositions of the RRV (?13CV-PDB?=??3.6 to ?4.3‰, ?18OV-SMOW?=?7.6 to 9.8‰) are consistent with an origin resulting from fluid exsolution at the end of the high temperature fractionation trend. A two-stage model involving fractional crystallization and hydrothermal fluids is proposed for the mineralization of the Bachu REE deposit.
DS201805-0941
2018
Chenin, P., Picazo, S., Jammes, S., Manatschal, G., Muntener, O., Karner, G.Potential role of lithospheric mantle composition in the Wilson cycle: a North American perspective.Geological Society of London, Special Publication, Vol. 470, doi:10.1144 /SP470.10Mantlewilson cycle

Abstract: Although the Wilson cycle is usually considered in terms of wide oceans floored with normal oceanic crust, numerous orogens result from the closure of embryonic oceans. We discuss how orogenic and post-orogenic processes may be controlled by the size/maturity of the inverted basin. We focus on the role of lithospheric mantle in controlling deformation and the magmatic budget. We describe the physical properties (composition, density, rheology) of three types of mantle: inherited, fertilized and depleted oceanic mantle. By comparing these, we highlight that fertilized mantle underlying embryonic oceans is mechanically weaker, less dense and more fertile than other types of mantle. We suggest that orogens resulting from the closure of a narrow, immature extensional system are essentially controlled by mechanical processes without significant thermal and lithological modification. The underlying mantle is fertile and thus has a high potential for magma generation during subsequent tectonic events. Conversely, the thermal state and lithology of orogens resulting from the closure of a wide, mature ocean are largely modified by subduction-related arc magmatism. The underlying mantle wedge is depleted, which may inhibit magma generation during post-orogenic extension. These end-member considerations are supported by observations derived from the Western Europe-North Atlantic region.
DS201803-0438
2018
Chepurov, A., Dereppe, J-M., Turkin, A., Lin, V.From subcalcic pyropes to uvarovites: experimental crystalllization of Cr-rich garnets in ultramafic systems with presence of Ca bearing hydrous fluid.Neues Jahrbuch fur Mineralogie - abhandlungen, Vol. 195, 1, pp. 65-78.Technologygarnets
DS201809-2011
2018
Chepurov, A.A., Sonin, V.M., Chepurov, A.I., Tomilenko, A.A.The effects of the concentration of olivine xenocrysts on the viscosity of kimberlite melts: experimental evidence.Journal of Volcanology and Seismology, Vol. 12, 2, pp. 140-149.Russiadeposit- Nyurbinskaya

Abstract: The study of viscosity in sub-liquidus heterogeneous media, which includes kimberlite magma at the pressures and temperatures that prevail in the mantle, is an urgent task. We have conducted experiments in the serpentine-olivine, serpentine-CaCO3?olivine, and native kimberlite-olivine systems at a pressure of 4 GPa and temperatures of 1400?1600°? in a BARS high-pressure device using the technique of a falling Pt pellet. The samples were examined after experiments to find fine-grained chilled mass of crystals where the Pt pellet was observed at the time of chilling. The concentration of the solid phase was varied in the experiments between 10 and 50 wt %. We showed that when 50 wt % of olivine grains has been introduced, it was not possible to detect the motion of the Pt pellet, while when the concentration of olivine xenocrysts reached 10 wt %, the Pt pellet very rapidly descended to the bottom of the reaction volume. Viscosity was calculated using the Stokes method. We found that the viscosity of a homogeneous kimberlite melt at 4 GPa and 1600°? is below 2 Pa s, with the viscosity of a melt that contained up to 10 wt % of the solid phase being approximately constant. A kimberlite melt that contained 30 wt % of the solid phase had a viscosity on the order of 100 Pa s, while with 50 wt % of the solid phase the relative viscosity of an ultrabasic system increased to reach values over 1000 Pa s.
DS201806-1215
2018
Cherniak, D.J., Watson, E.B., Meunier, V., Kharche, N.Diffusion of helium, hydrogen and deuterium in diamonds: experiment, theory and geochemical applications.Geochimica et Cosmochimica Acta, Vol. 232 pp. 206-224.Technologydiamond - inclusions DFT

Abstract: Diffusivities of helium, deuterium and hydrogen have been characterized in diamond. Polished CVD diamond was implanted with either 3He, 2H, or 1H. Implanted samples were sealed under vacuum in silica glass capsules, and annealed in 1-atm furnaces. 3He, 2H and 1H distributions were measured with Nuclear Reaction Analysis. We obtain these Arrhenius relations: DHe = 4.00?×?10?15 exp(?138?±?14?kJ?mol?1/RT) m2?s?1. D2H = 1.02?×?10?4 exp(?262?±?17?kJ?mol?1/RT) m2?s?1. D1H = 2.60?×?10?4 exp(?267?±?15?kJ?mol?1/RT) m2?s?1. Diffusivities of 1H and 2H agree within experimental uncertainties, indicating little diffusive mass fractionation of hydrogen in diamond. To complement the experimental measurements, we performed calculations using a first-principles quantum mechanical description of diffusion in diamond within the Density Functional Theory (DFT). Differences in 1H and 2H diffusivities from calculations are found to be ?4.5%, reflected in differences in the pre-exponential factor. This small difference in diffusivities, despite the large relative mass difference between these isotopes, is due to the fact that the atomistic process involved in the transition along the diffusion pathway is dictated by local changes to the diamond structures rather than to vibrations involving 1H/2H. This finding is consistent with the experimental results given experimental uncertainties. In contrast, calculations for helium diffusion in diamond indicate a difference of 15% between diffusivities of 3He and 4He. Calculations of diffusion distances for hydrogen using our data yield a distance of 50??m in diamond in 300,000?years at 500?°C and ?30?min at 1400?°C. Diffusion distances for He in diamond are shorter than for H at all temperatures above ?350?°C, but differences increase dramatically with temperature because of the higher activation energy for H diffusion. For example, a 50??m diffusion distance for He would be attained in ?40 Myr at 500?°C and 400?yr at 1400?°C. For comparison, a 50??m diffusion distance for N in diamond would require nearly 1 billion years at 1400?°C. The experimental data indicate that diamonds equilibrate with ambient H and He in the mantle on timescales brief relative to most geological processes and events. However, He diffusion in diamond is slower than in any other mineral measured to date, including other kimberlite-hosted minerals. Under some circumstances, diamond may provide information about mantle He not recoverable from other minerals. One possibility is diamonds entrained in kimberlites. Since the ascent of kimberlite from the mantle to near-surface is very rapid, entrained diamonds may retain most or all of the H and He acquired in mantle environments. Calculations using reasonable ascent rates and T-t paths indicate that He diffusive loss from kimberlite-hosted diamonds is negligible for grains of 1.0-0.2?mm radius, with fractional losses <0.15% for all ascent rates considered. If the host kimberlite magma is effectively quenched in the near-surface (or is erupted), diamonds should contain a faithful record of [He] and He isotopes from the mantle source region. Preservation of H in kimberlite-hosted diamonds is less clear-cut, with model outcomes depending critically upon rates of ascent and cooling.
DS201804-0680
2018
Chertova, M.V., Spakman, W., Steinberger, B.Mantle flow influence on subduction evolution.Earth and Planteray Science Letters, Vol. 489, pp. 258-266.Mantlesubduction

Abstract: The impact of remotely forced mantle flow on regional subduction evolution is largely unexplored. Here we investigate this by means of 3D thermo-mechanical numerical modeling using a regional modeling domain. We start with simplified models consisting of a 600 km (or 1400 km) wide subducting plate surrounded by other plates. Mantle inflow of ?3 cm/yr is prescribed during 25 Myr of slab evolution on a subset of the domain boundaries while the other side boundaries are open. Our experiments show that the influence of imposed mantle flow on subduction evolution is the least for trench-perpendicular mantle inflow from either the back or front of the slab leading to 10-50 km changes in slab morphology and trench position while no strong slab dip changes were observed, as compared to a reference model with no imposed mantle inflow. In experiments with trench-oblique mantle inflow we notice larger effects of slab bending and slab translation of the order of 100-200 km. Lastly, we investigate how subduction in the western Mediterranean region is influenced by remotely excited mantle flow that is computed by back-advection of a temperature and density model scaled from a global seismic tomography model. After 35 Myr of subduction evolution we find 10-50 km changes in slab position and slab morphology and a slight change in overall slab tilt. Our study shows that remotely forced mantle flow leads to secondary effects on slab evolution as compared to slab buoyancy and plate motion. Still these secondary effects occur on scales, 10-50 km, typical for the large-scale deformation of the overlying crust and thus may still be of large importance for understanding geological evolution.
DS201811-2559
2018
Chin, E.J.Deep crustal cumulates reflect patterns of continental rift volcanism beneath Tanzania.Contributions to Mineralogy and Petrology, Vol. 173, 22p. Doi.org/10.1007/s00410-018-1512-zAfrica, Tanzaniamagmatism

Abstract: Magmatism on Earth is most abundantly expressed by surface volcanic activity, but all volcanism has roots deep in the crust, lithosphere, and mantle. Intraplate magmatism, in particular, has remained enigmatic as the plate tectonic paradigm cannot easily explain phenomena such as large flood basalt provinces and lithospheric rupture within continental interiors. Here, I explore the role of deep crustal magmatic processes and their connection to continental rift volcanism as recorded in deep crustal xenoliths from northern Tanzania. The xenoliths are interpreted as magmatic cumulates related to Cenozoic rift volcanism, based on their undeformed, cumulate textures and whole-rock compositions distinct from melt-reacted peridotites. The cumulates define linear trends in terms of whole-rock major elements and mineralogically, can be represented as mixtures of olivine?+?clinopyroxene. AlphaMELTS modeling of geologically plausible parental melts shows that the end-member cumulates, clinopyroxenite and Fe-rich dunite, require fractionation from two distinct melts: a strongly diopside-normative melt and a fractionated picritic melt, respectively. The former can be linked to the earliest, strongly silica-undersaturated rift lavas sourced from melting of metasomatized lithosphere, whereas the latter is linked to the increasing contribution from the upwelling asthenospheric plume beneath East Africa. Thus, deep crustal cumulate systematics reflect temporal and compositional trends in rift volcanism, and show that mixing, required by the geochemistry of many rift lava suites, is also mirrored in the lavas’ cumulates.
DS201808-1732
2018
Chinn, I.L, Perritt, S.H.The art and science of diamond analysis, and what the results can tell usSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 18 ppts.Globalpopulation, economics
DS201807-1484
2018
Chinn, I.L., Perritt, S.H.The art and science of diamond analysis, and what the results can tell us. PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 155-160.GlobalDiamond analyses, populations, economics
DS201806-1216
2018
Chinn, I.L., Perritt, S.H., Stiefenhofer, J., Stern, R.A.Diamonds from Orapa mine show a clear subduction signature in SIMS stable isotope data.Mineralogy and Petrology, in press available, 11p.Africa, Botswanadeposit - Orapa

Abstract: Spatially resolved analyses reveal considerable isotopic heterogeneity within and among diamonds ranging in size from 0.15 to 4.75 mm from the Orapa Mine, Botswana. The isotopic data are interpreted in conjunction with nitrogen aggregation state data and growth zone relationships from cathodoluminescence images. The integrated information confirms that a distinct diamond growth event (with low IaAB nitrogen aggregation states, moderately high nitrogen contents and ?13C and ?15N values compatible with average mantle values) is younger than the dominant population(s) of Type IaAB diamonds and cores of composite diamonds with more negative and positive ?13C and ?15N values, respectively. A significant proportion of the older diamond generation has high nitrogen contents, well outside the limit sector relationship, and these diamonds are likely to reflect derivation from subducted organic matter. Diamonds with low ?13C values combined with high nitrogen contents and positive ?15N values have not been previously widely recognised, even in studies of diamonds from Orapa. This may have been caused by prior analytical bias towards inclusion-bearing diamonds that are not necessarily representative of the entire range of diamond populations, and because of average measurements from heterogeneous diamonds measured by bulk combustion methods. Two distinct low nitrogen/Type II microdiamond populations were recognised that do not appear to continue into the macrodiamond sizes in the samples studied. Other populations, e.g. those containing residual singly-substituted nitrogen defects, range in size from small microdiamonds to large macrodiamonds. The total diamond content of the Orapa kimberlite thus reflects a complex assortment of multiple diamond populations.
DS201808-1733
2018
Choudary, G.Investigating a fake rough. Mentions cubic zirconium, topaz as diamond octahedrons on. P. 28.Gems & Jewellery, Vol. 27, 2, pp. 26-29.Technologydiamond - fake
DS201810-2305
2018
Chukanov, N.V., Rastsvetaeva, R.K., Kruszewski, L., Akensov, S.M., Rusakov, V., Britvin, S.N., Vozchikova, S.A.Siudaite, Na8(Mn2+2Na) Ca6Fe3+3Zr3NbSi25O74(OH)2Cl.5H20: a new eudialyte group mineral from the Khibiny alkaline massif, Kola Peninsula.Physics and Chemistry of Minerals, Vol. 45, pp. 745-758.Russia, Kola Peninsulaalkaline

Abstract: The new eudialyte-group mineral siudaite, ideally Na8(Mn2+2Na)Ca6Fe3+3Zr3NbSi25O74(OH)2Cl•5H2O, was discovered in a peralkaline pegmatite situated at the Eveslogchorr Mt., Khibiny alkaline massif, Kola Peninsula, Russia. The associated minerals are aegirine, albite, microcline, nepheline, astrophyllite, and loparite-(Ce). Siudaite forms yellow to brownish-yellow equant anhedral grains up to 1.5 cm across. Its lustre is vitreous, and the streak is white. Cleavage is none observed. The Mohs’ hardness is 4½. Density measured by hydrostatic weighing is 2.96(1) g/cm3. Density calculated using the empirical formula is equal to 2.973 g/cm3. Siudaite is nonpleochroic, optically uniaxial, negative, with ??=?1.635(1) and ??=?1.626(1) (??=?589 nm). The IR spectrum is given. The chemical composition of siudaite is (wt%; electron microprobe, H2O determined by HCN analysis): Na2O 8.40, K2O 0.62, CaO 9.81, La2O3 1.03, Ce2O3 1.62, Pr2O3 0.21, Nd2O3 0.29, MnO 6.45, Fe2O3 4.51. TiO2 0.54, ZrO2 11.67, HfO2 0.29, Nb2O5 2.76, SiO2 47.20, Cl 0.54, H2O 3.5, -O?=?Cl ??0.12, total 99.32. According to Mössbauer spectroscopy data, all iron is trivalent. The empirical formula (based on 24.5 Si atoms pfu, in accordance with structural data) is [Na7.57(H2O)1.43]?9(Mn1.11Na0.88Ce0.31La0.20Nd0.05Pr0.04K0.41)?3(H2O)1.8(C a5.46Mn0.54)?6(Fe3+1.76Mn2+1.19)?2.95Nb0.65(T i0.20Si0.50)?0.71(Zr2.95Hf0.04Ti0.01)?3Si24.00Cl0.47O70(OH)2Cl0.47•1.2H2O. The crystal structure was determined using single-crystal X-ray diffraction data. The new mineral is trigonal, space group R3m, with a?=?14.1885(26) Å, c?=?29.831(7) Å, V?=?5200.8(23) Å3 and Z?=?3. Siudaite is chemically related to georgbarsanovite and is its analogue with Fe3+-dominant M2 site. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 6.38 (60) (-114), 4.29 (55) (-225), 3.389 (47) (131), 3.191 (63) (-228). 2.963 (100) (4-15), 2.843 (99) (-444), 2.577 (49) (3-39). Siudaite is named after the Polish mineralogist and geochemist Rafa? Siuda (b. 1975).
DS201802-0226
2017
Chust, T.C., Steinle Neumann, G., Dolejs, D., Schuberth, B.S., Bunge, H.P.A computational framework for mineralogical thermodynamics. MMA-EoSJournal of Geophysical Research, Vol. 122, 10.1002/2017JB014501Mantlethermodynamics

Abstract: We present a newly developed software framework, MMA-EoS, that evaluates phase equilibria and thermodynamic properties of multicomponent systems by Gibbs energy minimization, with application to mantle petrology. The code is versatile in terms of the equation-of-state and mixing properties and allows for the computation of properties of single phases, solution phases, and multiphase aggregates. Currently, the open program distribution contains equation-of-state formulations widely used, that is, Caloric-Murnaghan, Caloric-Modified-Tait, and Birch-Murnaghan-Mie-Grüneisen-Debye models, with published databases included. Through its modular design and easily scripted database, MMA-EoS can readily be extended with new formulations of equations-of-state and changes or extensions to thermodynamic data sets. We demonstrate the application of the program by reproducing and comparing physical properties of mantle phases and assemblages with previously published work and experimental data, successively increasing complexity, up to computing phase equilibria of six-component compositions. Chemically complex systems allow us to trace the budget of minor chemical components in order to explore whether they lead to the formation of new phases or extend stability fields of existing ones. Self-consistently computed thermophysical properties for a homogeneous mantle and a mechanical mixture of slab lithologies show no discernible differences that require a heterogeneous mantle structure as has been suggested previously. Such examples illustrate how thermodynamics of mantle mineralogy can advance the study of Earth's interior.
DS201812-2790
2018
Cimen, O., Kuebler, C., Monaco, B., Simonetti, S.S., Corcoran, L., Chen, W., Simonatti, A.Boron, carbon, oxygen and radiogenic isotope investigation of carbonatite from the Miaoya complex, central China: evidences for late stage REE hydrothermal event and mantle source heterogeneity.Lithos, Vol. 322, pp. 225-237.Chinadeposit - Miaoya

Abstract: The Miaoya carbonatite complex (MCC) is located within the southern edge of the Qinling orogenic belt in central China, and is associated with significant rare earth element (REE) and Nb mineralization. The MCC consists of syenite and carbonatite that were emplaced within Neo- to Mesoproterozoic-aged supracrustal units. The carbonatite intruded the associated syenite as stocks and dikes, and is mainly composed of medium- to fine-grained calcite and abundant REE-bearing minerals. Carbonatite melt generation and emplacement within the MCC occurred during the Silurian (at ~440?Ma), and was subsequently impacted by a late-stage hydrothermal event (~232?Ma) involving REE-rich fluids/melt. This study reports trace element and stable (B, C, and O) and radiogenic (Nd, Pb, and Sr) isotope data for the MCC carbonatite, and these have been subdivided into three groups that represent different REE contents, interpreted as varying degrees of hydrothermal interaction. Overall, the group of carbonatites with the lowest enrichment in LREEs (i.e., least affected by hydrothermal event) is characterized by ?11B values that vary between ?7 (typical asthenospheric mantle) and?+?4‰; ?11B values and B abundances (~0.2 to ~1?ppm) do not correlate with LREE contents. The Sm-Nd and Pb-Pb isotope systems have both been perturbed by the late-stage, REE-rich hydrothermal activity and corroborate open-system behavior. Contrarily, initial 87Sr/86Sr ratios (vary between ~0.70355 and 0.70385) do not correlate significantly with both LREEs and Sr abundances, nor with initial 143Nd/144Nd ratios. The late-stage hydrothermal event overprinted the Nd and Pb isotope compositions for most of the carbonatite samples examined here, whereas a majority of the samples preserve their variable B and Sr isotope values inherited from their mantle source. The B and Sr isotope data for carbonatites exhibiting the least LREE enrichment correlate positively and suggest carbonatite melt generation from a heterogenous upper mantle source that records the input of recycled crustal material. This finding is consistent with those previously reported for young (<300?Ma old) carbonatites worldwide.
DS201811-2560
2018
Claesson, S., Artemenko, G.V., Bogdanova, S.V., Shumlyanskyy, L.Archean crustal evolution in the Ukrainian shield.Earth's Oldest Rocks, Springer , Chapter 33, pp. 872-889.Europe, Ukrainetectonics
DS201807-1485
2018
Clarke, J.E.The future of diamond liberation and recovery? DWIK, EPDSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 127-136.Africamining - milling
DS201808-1734
2018
Clarke, J.E.The future of diamond liberation and recovery? PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 22 ppts.Globalmining - milling
DS201801-0008
2018
Clerc, C., Ringenbach, J-C., Jolivet, L., Ballard, J-F.Rifted margins: ductile deformation, boudinage, continentward-dipping normal faults and the role of the weak crust.Gondwana Research, Vol. 53, 1, pp. 20-40.Mantlerifting

Abstract: The stunningly increased resolution of the deep crustal levels in recent industrial seismic profiles acquired along most of the world's rifted margins leads to the unraveling of an unexpected variety of structures. It provides unprecedented access to the processes occurring in the middle and lower continental crust. We present a series of so far unreleased profiles that allows the identification of various rift-related geological processes such as crustal boudinage, ductile shear and low-angle detachment faulting, and a rifting history that differs from the classical models of oceanward-dipping normal faults. The lower crust in rifted margins appears much more intensely deformed than usually represented. At the foot of both magma-rich and magma-poor margins, we observe clear indications of ductile deformation of the deep continental crust along large-scale shallow dipping shear zones. These shear zones generally show a top-to-the-continent sense of shear consistent with the activity of Continentward Dipping Normal Faults (CDNF) observed in the upper crust. This pattern is responsible for a migration of the deformation and associated sedimentation and/or volcanic activity toward the ocean. We discuss the origin of these CDNF and investigate their implications and the effect of sediment thermal blanketing on crustal rheology. In some cases, low-angle shear zones define an anastomosed pattern that delineates boudin-like structures. The maximum deformation is localized in the inter-boudin areas. The upper crust is intensely boudinaged and the highly deformed lower crust fills the inter-boudins underneath. The boudinage pattern controls the position and dip of upper crustal normal faults. We present some of the most striking examples from the margins of Uruguay, West Africa, South China Sea and Barents Sea, and discuss their implications for the time-temperature history of the margins.
DS201809-2012
2018
Clerc, F., Behn, M.D., Parmentier, E.M., Hirth, G.Predicting rates and distribution of carbonate melting in oceanic upper mantle: implications for seismic structure and global carbon cycling.Geophysical Research Letters, doi.org/10.1029/2018GL078142Mantlemelting

Abstract: Despite support from indirect observations, the existence of a layer of carbon?rich, partially molten rock (~60 km) below oceanic crust, made possible by the presence of CO2, remains uncertain. In particular, abrupt decreases in the velocity that seismic waves propagate at depths of 40-90 and 80-180 km beneath the ocean basins remain unexplained. In this study, we test whether these seismic discontinuities can be attributed to the presence of a layer of carbon?rich melt. Melt generation occurs only where the mantle is upwelling; thus, we predict the locations of carbonate?enhanced melting using a mantle convection model and compare the resulting melt distribution with the seismic observations. We find that the shallower seismic discontinuities (at 40? to 90?km depth) are not associated with regions of predicted melting but that the deeper discontinuities (80-180 km) occur preferentially in areas of greater mantle upwelling—suggesting that these deep observations may reflect the presence of localized melt accumulation at depth. Finally, we show that carbonate melting far from mid?ocean ridges produces an additional CO2 flux previously overlooked in deep carbon cycle estimates, roughly equivalent to the flux of CO2 due to seafloor volcanism.
DS201804-0681
2018
Cline, C.J. II, Faul, U.H., David, E.C., Berry, A.J., Jackson, I.Redox influenced seismic properties of upper mantle olivine.Nature, Vol. 555, March 15, pp. 255-258.Mantlegeophysics - seismics

Abstract: Lateral variations of seismic wave speeds and attenuation (dissipation of strain energy) in the Earth’s upper mantle have the potential to map key characteristics such as temperature, major-element composition, melt fraction and water content1,2,3. The inversion of these data into meaningful representations of physical properties requires a robust understanding of the micromechanical processes that affect the propagation of seismic waves2,3. Structurally bound water (hydroxyl) is believed to affect seismic properties2,3 but this has yet to be experimentally quantified. Here we present a comprehensive low-frequency forced-oscillation assessment of the seismic properties of olivine as a function of water content within the under-saturated regime that is relevant to the Earth’s interior. Our results demonstrate that wave speeds and attenuation are in fact strikingly insensitive to water content. Rather, the redox conditions imposed by the choice of metal sleeving, and the associated defect chemistry, appear to have a substantial influence on the seismic properties. These findings suggest that elevated water contents are not responsible for low-velocity or high-attenuation structures in the upper mantle. Instead, the high attenuation observed in hydrous and oxidized regions of the upper mantle (such as above subduction zones) may reflect the prevailing oxygen fugacity. In addition, these data provide no support for the hypothesis whereby a sharp lithosphere-asthenosphere boundary is explained by enhanced grain boundary sliding in the presence of water.
DS201804-0682
2017
Collett, B., Bassias, Y.Guiana shield tectonics influence hydrocarbon bearing compartments.Oil & Gas Journal, Oct. 2, pp. 42-45.South America, Guyanatectonics

Abstract: Interpretations of magnetic anomolies, fracture-zone geometry, and continental-oceanic crust transitions frame the debate surrounding the tectonic opening of the Equatorial and South Atlantic Ocean. Misinterpretations of movement in this region lead to misalignments and misunderstanding of the depositional environments at the margins. This article presents further evidence of the Guiana Shield's role during the initial separation between the American and African plates. Research suggests that the structure of the larger Guiana basin was controlled by the reactivation of Paleozoic and early Mesozoic faults, inherited from older orogenic belts. The same river paths fed the basin with clastic deposits for several tens to hundreds of millions of years. A network of NNW-SSE and NNE-SSW lineaments along the Atlantic margin coast and their onshore continuity at the edge of the Guiana Shield denote relics of deep faulting associated with the early rifting of the central Atlantic Ocean during early Jurassic, between 190 and 170 million years (Ma) (Fig. 1). These older faults were reactivated during Cretaceous E-W drift, a fact that created a favorable Tertiary-to-present structural and depositional environment for southward-shoreward hydrocarbon migration in the South American-Central Equatorial Atlantic margin (OGJ, Jan. 4, 2016, p. 42).
DS201801-0009
2017
Coltice, N., Larrouturou, G., Debayle, E., Garnero, E.J.Interactions of scales of convection in the Earth's mantle.Tectonophysics, in press available, 9p.Mantleplate tectonics, geophysics - seismics

Abstract: The existence of undulations of the geoid, gravity and bathymetry in ocean basins, as well as anomalies in heat flow, point to the existence of small scale convection beneath tectonic plates. The instabilities that could develop at the base of the lithosphere are sufficiently small scale (< 500 km) that they remain mostly elusive from seismic detection. We take advantage of 3D spherical numerical geodynamic models displaying plate-like behavior to study the interaction between large-scale flow and small-scale convection. We find that finger-shaped instabilities develop at seafloor ages > 60 Ma. They form networks that are shaped by the plate evolution, slabs, plumes and the geometry of continental boundaries. Plumes impacting the boundary layer from below have a particular influence through rejuvenating the thermal lithosphere. They create a wake in which new instabilities form downstream. These wakes form channels that are about 1000 km wide, and thus are possibly detectable by seismic tomography. Beneath fast plates, cold sinking instabilities are tilted in the direction opposite to plate motion, while they sink vertically for slow plates. These instabilities are too small to be detected by usual seismic methods, since they are about 200 km in lateral scale. However, this preferred orientation of instabilities below fast plates could produce a pattern of large-scale azimuthal anisotropy consistent with both plate motions and the large scale organisation of azimuthal anisotropy obtained from recent surface wave models.
DS201802-0227
2018
Condie, K.C.A planet in transition: the onset of plate tectonics on Earth between 3 and 2 Ga?Geoscience Frontiers, Vol. 9, 1, pp. 51-60.Mantleplate tectonics

Abstract: Many geological and geochemical changes are recorded on Earth between 3 and 2 Ga. Among the more important of these are the following: (1) increasing proportion of basalts with “arc-like” mantle sources; (2) an increasing abundance of basalts derived from enriched (EM) and depleted (DM) mantle sources; (3) onset of a Great Thermal Divergence in the mantle; (4) a decrease in degree of melting of the mantle; (5) beginning of large lateral plate motions; (6) appearance of eclogite inclusions in diamonds; (7) appearance and rapid increase in frequency of collisional orogens; (8) rapid increase in the production rate of continental crust as recorded by zircon age peaks; (9) appearance of ophiolites in the geologic record, and (10) appearance of global LIP (large igneous province) events some of which correlate with global zircon age peaks. All of these changes may be tied directly or indirectly to cooling of Earth's mantle and corresponding changes in convective style and the strength of the lithosphere, and they may record the gradual onset and propagation of plate tectonics around the planet. To further understand the changes that occurred between 3 and 2 Ga, it is necessary to compare rocks, rock associations, tectonics and geochemistry during and between zircon age peaks. Geochemistry of peak and inter-peak basalts and TTGs needs to be evaluated in terms of geodynamic models that predict the existence of an episodic thermal regime between stagnant-lid and plate tectonic regimes in early planetary evolution.
DS201806-1217
2018
Condie, K.C., Puetz, S.J., Davaille, A.Episodic crustal production before 2.7 Ga.Precambrian Research, Vol. 312, pp. 16-22.Mantlegeochronology - zircon

Abstract: Before 2.7?Ga, 14 igneous and detrital zircon age peaks and 9 large igneous province (LIP) age peaks are robust and statistically significant. Correlation analysis indicates a synchronous association among these peaks and power spectral analysis shows 91, 114-127 and 182-Myr cycles. These age cycles may be related to mantle plume or mantle overturn events, and to the time it takes to reach threshold temperature gradients for thermo-chemical destabilization in the lowermost mantle. Most zircon age peaks are transferred into younger detrital sediments, which does not favor an origin of the peaks by selective erosion. Correlation of eight pre-2.7-Ga LIP age peaks with zircon age peaks is consistent with a genetic relationship between mantle melting events and felsic crustal production and supports an interpretation of pre-2.7-Ga age peaks as growth rather than preservation peaks produced during craton collisions. Also consistent with the growth peak interpretation is the apparent absence of collisional orogens older than 2.7?Ga. An increasing number of geographic age peak sites from 4 to 2.8?Ga suggests production and survival of only small volumes of continental crust during this time and supports an episodic model for continental crustal growth.
DS201801-0010
2017
Cook, T.Probing the grain scale processes that drive plate tectonics.Eos, Vol. 98, publ. Dec. 8, 2p.Mantletectonics

Abstract: The theory of plate tectonics, which posits that Earth’s lithosphere is broken into a series of rigid plates that are propelled by currents of heat circulating through the taffy-like rocks below, underpins modern geological sciences. Yet the localized weakening mechanisms that form the plate boundaries remain poorly understood. Because of the presence of regions of very fine grained deformed rocks at many tectonic margins, scientists have argued that a reduction in grain size is a critical step in concentrating deformation into narrow shear zones. Because the grains in these zones are much smaller—and hence weaker—than those in the surrounding material, they appear to provide a pathway for localizing deformation in the lithosphere. But the role the grains’ composition may play in shaping shear zones has been the subject of ongoing debate. To further our understanding of grain-scale weakening processes in different materials, Tasaka et al. conducted a series of torsion laboratory experiments to examine how mixtures of two minerals commonly found in Earth’s mantle, olivine and pyroxene, respond to increasing strain. The results of the first study indicate that at low strain, the mixture responded in the same way as samples of pure olivine but that at higher strain the mixture’s behavior varied, suggesting this deformation occurred via a different grain-reducing mechanism that operates only in samples containing pyroxene. According to the results of the companion study, which analyzed changes in the mixed samples’ microstructures, this mechanism is the nucleation of small grains of olivine and pyroxene along each other’s mineral boundaries. As the new crystals begin to form at moderate strain, argue the authors, they restrict one another’s dimensions, effectively reducing the samples’ average grain size. By permanently inhibiting grain growth, this process eventually creates zones of fine-grained material that remain weak over geologic timescales. These papers provide important insights into the processes that control grain-scale weakening and provide crucial experimental data necessary to test numerical geodynamic models. The mechanism proposed by the researchers may potentially be responsible for forming and perpetuating shear zones and hence the formation of plate boundaries.
DS201812-2791
2018
Cookenboo, H.Diamond project - eclogitic garnets point to eclogitic diamond potential. Vantage 7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazileclogites
DS201803-0439
2006
Correia Eugenio, A., Laiginhas-Fernando, A.T.P.Garnets from the Camafuca Camazambo kimberlite.Anais da Academia Brasileira de Ciencas, Vol. 78, 2, pp. 309-315.Africa, Angoladeposit - Camafuca

Abstract: This work presents a geochemical study of a set of garnets, selected by their colors, from the Camafuca-Camazambo kimberlite, located on northeast Angola. Mantle-derived garnets were classified according to the scheme proposed by Grütter et al. (2004) and belong to the G1, G4, G9 and G10 groups. Both sub-calcic (G10) and Ca-saturated (G9) garnets, typical, respectively, of harzburgites and lherzolites, were identified. The solubility limit of knorringite molecule in G10D garnets suggests they have crystallized at a minimum pressure of about 40 to 45 kbar (4-4.5 GPa). The occurrence of diamond stability field garnets (G10D) is a clear indicator of the potential of this kimberlite for diamond. The chemistry of the garnets suggests that the source for the kimberlite was a lherzolite that has suffered a partial melting that formed basaltic magma, leaving a harzburgite as a residue.
DS201802-0228
2018
Corti, G., Molin, P., Sembroni, A., Bastow, I.D., Keir, D.Control of pre-rift lithospheric structure on the architecture and evolution of continental rifts: insights from the Main Ethiopian Rift, East Africa.Tectonics, Africa, Ethiopiatectonics

Abstract: We investigate the along-axis variations in architecture, segmentation and evolution of the Main Ethiopian Rift (MER), East Africa, and relate these characteristics to the regional geology, lithospheric structure and surface processes. We first illustrate significant along-axis variations in basin architecture through analysis of simplified geological cross-sections in different rift sectors. We then integrate this information with a new analysis of Ethiopian topography and hydrography to illustrate how rift architecture (basin symmetry/asymmetry) is reflected in the margin topography and has been likely amplified by a positive feedback between tectonics (flexural uplift) and surface processes (fluvial erosion, unloading). This analysis shows that ~70% of the 500 km-long MER is asymmetric, with most of the asymmetric rift sectors being characterized by a master fault system on the eastern margin. We finally relate rift architecture and segmentation to the regional geology and geophysical constraints on the lithosphere. We provide strong evidence that rift architecture is controlled by the contrasting nature of the lithosphere beneath the homogeneous, strong Somalian Plateau and the weaker, more heterogeneous Ethiopian Plateau, differences originating from the presence of pre-rift zones of weakness on the Ethiopian Plateau and likely amplified by surface processes. The data provided by this integrated analysis suggest that asymmetric rifts may directly progress to focused axial tectonic-magmatic activity, without transitioning into a symmetric rifting stage. These observations have important implications for the asymmetry of continental rifts and conjugate passive margins worldwide.
DS201812-2792
2018
Costa Cavalcante, L.F.Diamond prospecting and exploration developed by CBPM in Bahia State.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Bahiaprospecting
DS201806-1218
2018
Cowing, M.Let there be light: diamond optics, ray tracing and light performances with insights.Gems&Jewellery www.gem-a-com, Spring, pp. 24-27.Technologydiamond cutting
DS201811-2561
2018
Cox, M.A., Cavosie, A.J., Bland, P.A., Miljkovic, K., Wingate, M.T.D.Microstructural dynamics of central uplifts: reidite offset by zircon twins at the Woodleigh impact structure, Australia.Geology, doi.org/10.1130/G45127.1 4p.Australiacrater

Abstract: Impact cratering is a dynamic process that is violent and fast. Quantifying processes that accommodate deformation at different scales during central uplift formation in complex impact structures is therefore a challenging task. The ability to correlate mineral deformation at the microscale with macroscale processes provides a critical link in helping to constrain extreme crustal behavior during meteorite impact. Here we describe the first high-pressure-phase-calibrated chronology of shock progression in zircon from a central uplift. We report both shock twins and reidite, the high-pressure ZrSiO4 polymorph, in zircon from shocked granitic gneiss drilled from the center of the >60-km-diameter Woodleigh impact structure in Western Australia. The key observation is that in zircon grains that contain reidite, which forms at >30 GPa during the crater compression stage, the reidite domains are systematically offset by later-formed shock deformation twins (?20 GPa) along extensional planar microstructures. The {112} twins are interpreted to record crustal extension and uplift caused by the rarefaction wave during crater excavation. These results provide the first physical evidence that relates the formation sequence of both a high-pressure phase and a diagnostic shock microstructure in zircon to different cratering stages with unique stress regimes that are predicted by theoretical and numerical models. These microstructural observations thus provide new insight into central uplift formation, one of the least-understood processes during complex impact crater formation, which can produce many kilometers of vertically uplifted bedrock in seconds.
DS201811-2562
2018
Craddock, J., Malone, D., Schmitz, M.D., Gifford, J.N.Strain variations across the Proterozoic Penokean Orogen, USA and Canada. Sudbury impact Precambrian Research, Vol. 318, pp. 25-69.United States, Canadaorogeny

Abstract: Strata in the Huron (2.5-2.0 Ga) and Animikie (2.2-1.85 Ga) basins were deposited on the southern margin of the Archean Superior province. These rocks were deformed during the Penokean orogeny (?1850 Ma) followed by subsequent accretionary orogens to the south at 1750 Ma (Yavapai) and 1630 Ma (Mazatzal). Strain patterns are unique to each orogenic belt with no far-field effect: Archean Wawa terrane rocks in the Penokean foreland preserve deformation associated with Archean accretion with no younger Penokean, Yavapai or Mazatzal strain overprint. The Penokean orogeny deformed Huron-Animikie basin sediments into a north-vergent fold-and-thrust belt with no Yavapai or Mazatzal strain overprint. Yavapai orogen strains (SW-NE margin-parallel shortening) are unique when compared to the younger Mazatzal shortening (N20°W) shortening, with no strain overprint. Penokean deformation is characterized by shortening from the south including uplifted Archean gneisses and a northerly thin-skinned fold-and-thrust belt, with north-vergent nappes and a gently-dipping foreland. Our study of finite and calcite twinning strains (n=60) along (?1500 km) and across (?200 km) the Penokean belt indicate that this orogeny was collisional as layer-parallel shortening axes are parallel across the belt, or parallel to the tectonic transport direction (?N-S). Penokean nappe burial near the margin resulted in vertical shortening strain overprints, some of which are layer-normal. The Sudbury impact layer (1850 Ma) is found across the Animikie basin and provides a widespread deformation marker with many local, unique strain observations. We also report new geochronology (U-Pb zircon and apatite) for the gneiss-mafic dike rocks at Wissota (Chippewa Falls, WI) and Arbutus (Black River Falls, WI) dams, respectively, which bears on Penokean-Yavapai deformation in the Archean Marshfield terrane which was accreted during the Penokean orogen. Pseudotachylite formation was common in the Superior province Archean basement rocks, especially along terrane boundaries reactivated by contemporaneous Penokean, Trans-Hudson, Cape Smith and New Quebec deformation. In the hinterland (south), the younger Yavapai orogen (1750 Ma; n=8) deformation is preserved as margin-parallel horizontal shortening (?SW-NE) in Yavapai crust and up to 200 km to the north in the Penokean thrust belt as a strain and Barrovian metamorphic overprint. Mazatzal deformation (1630 Ma; n=16) is preserved in quartzites on Yavapai and Penokean crust with layer-parallel and layer-normal shortening strains oriented N20°W.
DS201812-2793
2018
Creighton, S., Hunt, L.The utility of clinopyroxene in diamond exploration.2018 Yellowknife Geoscience Forum , p. 13. abstractGlobalthermobarometry

Abstract: Clinopyroxene single-crystal thermo-barometry is an essential tool in the identification and evaluation of prospective kimberlites. The paleogeothermal gradient preserved by clinopyroxene xenocrysts elucidates the thermal structure of the underlying lithospheric mantle; indicates the depth to and thickness of the “diamond window”. The widely used clinopyroxene thermometer-barometer of Nimis and Taylor (2000) requires that clinopyroxene equilibrated with both garnet and orthopyroxene. With the rare exception of wehrlites, equilibration with orthopyroxene is nearly a given for the majority of chrome-diopside clinopyroxene xenocrysts. Demonstrating equilibration with garnet, however, is a major obstacle for clinopyroxene-based thermobarometry. The most commonly used method for clinopyroxene discrimination is an Al2O3-Cr2O3 diagram proposed by Ramsay and Thompkins in 1994 supplemented with an additional MgO-Al2O3 from Nimis (1998) and an additional 1-dimensional filter based on chemical composition. Despite the aggressiveness of the filtering method, single-clinopyroxene pressure-temperature results have large scatter that can obscure the true paleogeothermal gradient. This is especially true of areas where the lithospheric mantle has undergone chemical modification by melt/fluid influx. Using a database of clinopyroxenes derived from kimberlite-borne mantle-derived lherzolites, we have developed a simple and effective discrimination plot that identifies clinopyroxene from garnet lherzolites and simultaneously removes clinopyroxene from metaosomatised peridotites. Calculated paleogeothermal gradients from clinopyroxene xenocrysts cut across model conductive geotherms which can complicate the interpretation of thermobarometry data. Grütter (2009) presented a solution to the problem by way of relative reference geotherms. He used xenocryst data from three Canadian locations with different thermal structures as references in comparison to the dataset under investigation. Taking a cue from this earlier work, we have developed a new set of relative reference geotherms that are based on single-clinopyroxene thermobarometry data for xenoliths from well-characterized regions - Somerset Island, Kaapvaal on-craton, and the Central Slave. A simple linear fit through the data produces sub-parallel clinopyroxene reference geotherms that are simpler to use and easier to visualize compared to the xenocrysts reference geotherms. Using these two new and simple tools will greatly help maximize the utility of clinopyroxene data in large exploration databases.
DS201811-2563
2018
Creus, P.K., Basson, I.J., Stoch, B., Mogorosi, O., Gabanakgosi, K., Ramsden, F., Gaegopolwe, P.Structural analysis and implicit 3D modelling of Jwaneng mine: insights into deformation of the Transvaal Supergroup in SE Botswana.Journal of African Earth Sciences, Vol. 137, pp. 9-21.Africa, Botswanadeposit - Jwaneng

Abstract: Country rock at Jwaneng Diamond Mine provides a rare insight into the deformational history of the Transvaal Supergroup in southern Botswana. The ca. 235 Ma kimberlite diatremes intruded into late Archaean to Early Proterozoic, mixed, siliciclastic-carbonate sediments, that were subjected to at least three deformational events. The first deformational event (D1), caused by NW-SE directed compression, is responsible for NE-trending, open folds (F1) with associated diverging, fanning, axial planar cleavage. The second deformational event (D2) is probably progressive, involving a clockwise rotation of the principal stress to NE-SW trends. Early D2, which was N-S directed, involved left-lateral, oblique shearing along cleavage planes that developed around F1 folds, along with the development of antithetic structures. Progressive clockwise rotation of far-field forces saw the development of NW-trending folds (F2) and its associated, weak, axial planar cleavage. D3 is an extensional event in which normal faulting, along pre-existing cleavage planes, created a series of rhomboid-shaped, fault-bounded blocks. Normal faults, which bound these blocks, are the dominant structures at Jwaneng Mine. Combined with block rotation and NW-dipping bedding, a horst-like structure on the northwestern limb of a broad, gentle, NE-trending anticline is indicated. The early compressional and subsequent extensional events are consistent throughout the Jwaneng-Ramotswa-Lobatse-Thabazimbi area, suggesting that a large area records the same fault geometry and, consequently, deformational history. It is proposed that Jwaneng Mine is at or near the northernmost limit of the initial, northwards-directed compressional event.
DS201807-1486
2018
Cronwright, H., Campbell, J.A.H.Application of the microdiamond technique in assisting diamond mining juniors to make rapid technical and economic decisions. Zebedelia clusterSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 233-246.Africa, South Africadeposit - Frischgewaacht, Klipspringer
DS201808-1735
2018
Cronwright, H., Campbell, J.A.H.Application of the microdiamond technique in assisting diamond mining juniors to make rapid technical and economic decisions. PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 32 ppts.Globalmicrodiamond
DS201812-2794
2018
Crosta, A.P., Reimold, W.V., Vasconcelos, M.A.R., Hauser, N., Oliveira, G.J.G., Maziviero, M.V., Goes, A.M.Impact cratering: the South American record. Part 2.Chemie der Erde, doi.org/10.1016/j ,chemer.2018.09.002 30MBSouth America, Brazilmeteorite

Abstract: In the first part of this review of the impact record of South America, we have presented an up-to-date introduction to impact processes and to the criteria to identify/confirm an impact structure and related deposits, as well as a comprehensive examination of Brazilian impact structures. The current paper complements the previous one, by reviewing the impact record of other countries of South America and providing current information on a number of proposed impact structures. Here, we also review those structures that have already been discarded as not being formed by meteorite impact. In addition, current information on impact-related deposits is presented, focusing on impact glasses and tektites known from this continent, as well as on the rare K-Pg boundary occurrences revealed to date and on reports of possible large airbursts. We expect that this article will not only provide systematic and up-to-date information on the subject, but also encourage members of the South American geoscientific community to be aware of the importance of impact cratering and make use of the criteria and tools to identify impact structures and impact deposits, thus potentially contributing to expansion and improvement of the South American impact record.
DS201802-0229
2017
Crust. T.C., Steinle-Neumann, G., Dolejs, D., Schuberth, B.S., Bunge, H.P.MMA-EoS: a computational framework for mineralogical thermodynamics.Journal of Geophysical Research, 122, https://doi.org/10.1002/2017JB014501Technologyprogram - MMA-EoS
DS201810-2307
2018
Cruz-Uribe, A.M., Feineman, M.D., Zack, T., Jacob, D.E.Asssessing trace element (dis) equilibrium and the application of single element thermometers in metamorphic rocks.Lithos, Vol. 314-315, pp. 1-15.Globalthermobarometry

Abstract: Empirical and experimental calibration of single element solubility thermometers, such as Zr-in-rutile, Zr-in-titanite, Ti-in-zircon, and Ti-in-quartz, within the past 13 years has greatly expanded our ability to assess the pressure and temperature conditions of individual minerals associated with specific textures in metamorphic rocks. Combined with advances in in situ techniques for analyzing trace concentrations, this has led to an increase in the combined use of single element thermometers, geochronometers, and isotope ratios, often simultaneously, in metamorphic minerals. Here we review the calibration and application of single element thermometers at the pressure and temperature conditions of interest in metamorphic rocks. We discuss to what extent accessory phase equilibrium and trace element equilibrium are attained in metamorphic systems, and the thermodynamic and kinetic framework within which trace element equilibrium is assessed. As an example, we present a comprehensive study of trace element distribution during rutile replacement by titanite in rocks that experienced high-temperature amphibolite-facies overprinting and those that underwent low-temperature blueschist-facies overprinting from a variety of subduction-related terranes worldwide. We find that trace element distributions approach equilibrium partition coefficients in rocks from amphibolite-facies overprinted terranes, whereas trace element distributions do not approach equilibrium in rocks that experienced blueschist-facies overprinting. We caution that single element thermometers that rely upon slow-diffusing high field strength elements should not be applied to rocks equilibrated at <600 °C unless attainment of trace element equilibrium can be demonstrated.
DS201805-0942
2018
Cruz-Uribe, A.M., Marschall, H.R., Gaetani, G.A., Le Roux, V.Generation of alkaline magmas in subduction zones by partial melting of melange diapirs - an experimental study.Geology, Vol. 48, 4, pp. 343-346.Technologysubduction

Abstract: Alkaline lavas occur globally in subduction-related volcanic arcs. Conventional models for the origin of these lavas typically invoke a multi-stage process in which mantle wedge peridotite, enriched in phlogopite and/or amphibole due to prior metasomatism, partially melts during infiltration by fluids and melts derived from subducted oceanic lithosphere. However, geochemical systematics in the majority of subduction-related alkaline lavas require physical mixing of subducted components and peridotite prior to partial melting. This can be explained by the mélange diapir model, which predicts the generation of arc magmas during advection of buoyant material from the slab-wedge interface into the mantle wedge below arcs. Here we report results from experiments in which natural mélange materials were partially melted at upper mantle conditions to produce alkaline magmas. Partial melts produced in our experiments have trace-element abundance patterns that are typical of alkaline arc lavas, such as enrichment in large ion lithophile elements (LILEs) and depletion in Nb and Ta. These results favor generation of alkaline magmas in the arc and backarc regions of subduction zones by partial melting of mélange materials rather than previously metasomatized peridotite.
DS201811-2564
2018
Cundari, R., Smyk, M., Campbell, D., Puumala, M., Woodruff, L.G.Possible emplacement controls on diamond bearing rocks North of Lake Superior.Proceedings and Abstracts - Institite on Lake Superior Geology, Vol. 64, pt. 1, pp. 19-20.Canada, Ontariodiamond genesis
DS201812-2795
2018
Czas, J.The quandry of the Sask Craton: origin and evolution of the lithospheric mantle beneath the Sask craton. ( FALC Star and rion South)Thesis, Phd. University of Alberta, 245p. Pdf availableCanada, Saskatchewan deposit - Fort a la Corne
DS201812-2796
2017
D'Agrella-Filho, M.S., Cordani, U.G.The paleomagnetic record of the Sao Francisco-Congo craton.Heilbron et al. eds. Sao Francisco Craton, eastern Brazil, Chapter 16, 17p. ResearchgateSouth America, Brazilgeochronology

Abstract: This chapter, based on paleomagnetic and geologic-geochronological evidence, discusses the position of the São Francisco craton and other South American and African cratonic blocks within paleo-continents, since the formation of Columbia supercontinent in the Paleoproterozoic up to the fragmentation of Pangea in the Mesozoic. In Paleoproterozoic times, between ca. 2.0 and 1.8 Ga, two large independent landmasses were formed. The first one involved several cratonic blocks that were leading to the formation of Laurentia. Later, Laurentia, proto-Amazonia, West Africa and Baltica amalgamated to form the nucleus of the supercontinent Columbia at about 1.78 Ga. The second landmass encompassed the São Francisco-Congo, Kalahari, Rio de la Plata and Borborema-Trans-Sahara, forming the Central African block. For the São Francisco-Congo and Kalahari cratons, two robust Paleoproterozoic poles are available. One is from the Jequié charnockites of Bahia (São Francisco Craton), and the other from the Limpopo high-grade metamorphics in South Africa (Kalahari Craton). They support the possible link between these two cratonic blocks at ca. 2.0 Ga. Columbia may have remained united until 1.25 Ga, when Baltica and Amazonia/West Africa broke apart. Their paleomagnetic record seems to indicate that both executed clockwise rotations, until they collided with Laurentia along the Grenville belt at ca. 1.0 Ga., culminating with the formation of Rodinia. For the Central African block, however, there are no reliable paleomagnetic poles available between 1.78 and 1.27 MA. Nevertheless, during this time interval, the geological-geochronological evidence indicates that no continental collisional episodes affected the São Francisco-Congo craton, where important intra-plate tectonic episodes occurred. Most probably, this large continental block drifted alone since the end of the Paleoproterozoic and did not take part of Columbia or Rodinia. At the end of the Mesoproterozoic, ca. 1100 MA, the robust Umkondo pole of the Kalahari craton, as part of the Central African block, and the equally robust Keweenawan pole of Laurentia at the center of Rodinia, indicated that these landmasses were very far apart. At that time a large oceanic realm, the Goiás-Pharusian Ocean, was indeed separating Amazonia-West Africa from the Central African block. This ocean closed by a continued subduction process that started at ca. 900 MA and ended in a collisional belt with Himalayan-type mountains at ca. 615 MA, as part of the few continental collisions which formed Gondwana. However, the age of the final convergence is still a matter of debate, because paleomagnetic measurements for the Araras Group, which occurs within the Paraguay belt at the eastern margin of the Amazonian craton, would indicate that a large ocean was still in existence between it and São Francisco craton close to the Ediacaran/Cambrian boundary. Consensus about this matter awaits for further paleomagnetic data. Gondwana collided with Laurasia during the late Paleozoic, at about 300 Ma, originating Pangea, which not much later started splitting apart, near the Permian/Triassic boundary. As part of this present-time plate tectonic regime, the São Francisco Craton (in South America) started separation from the Congo craton (in Africa) in Jurassic times, giving rise of the present-day oceanic lithosphere of the Atlantic Ocean.
DS201806-1219
2018
Dai, L., Li, S., Li, Z-H., Somerville, I., Santosh, M.Dynamics of exhumation and deformation of HP-UHP orogens in double subduction collision systems: numerical modeling and implications for the Western Dabie Orogen.Earth Science Reviews, Vol. 182, pp. 68-84.ChinaUHP

Abstract: The dynamics of formation and exhumation of high-pressure (HP) and ultra-high pressure (UHP) metamorphic orogens in double subduction-collision zones remain enigmatic. Here we employ two-dimensional thermo-mechanical numerical models to gain insights on the exhumation of HP-UHP metamorphic rocks, as well as their deformation during the collision of a micro-continent with pro- and retro-continental margins along two subduction zones. A three-stage collisional process with different convergence velocities is tested. In the initial collisional stage, a fold-and-thrust belt and locally rootless superimposed folds are developed in the micro-continent and subduction channel, respectively. In the second (exhumation) stage of HP-UHP rocks, a faster convergence model results in upwelling of the asthenosphere, which further leads to a detachment between the crust and lithospheric mantle of the micro-continent. A slower convergence model results in rapid exhumation of HP-UHP rocks along the north subduction channel and a typical piggy-back thrusting structure in the micro-continent. A non-convergence model produces a slab tear-off, leading to the rebound of residual lithosphere of the micro-continent. In the third and final stage, a series of back and ramp thrusts are formed in the micro-continent with the pro-continent re-subducted. Based on an analogy of our numerical results with the Western Dabie Orogen (WDO), we suggest that: (1) slab tear-off results in a rebound of residual lithosphere, which controls the two-stage syn-collisional exhumation process of HP-UHP rocks in the WDO; and (2) in contrast to the single subduction-collision system, the exhumation range of the partially molten rocks with lower viscosity and density is restricted to a specific region of the micro-continent by the Mianlue and Shangdan subduction zones, which generated the complex deformation features in the WDO.
DS201801-0011
2017
Dalou, C., Hirschmann, M.M., von der Handt, A., Mosenfelder, J., Armstrong, L.S.Nitrogen and carbon fractionation during core-mantle differentiation at shallow depth.Earth and Planetary Science Letters, Vol. 458, 1, pp. 141-151.Mantlecarbon

Abstract: One of the most remarkable observations regarding volatile elements in the solar system is the depletion of N in the bulk silicate Earth (BSE) relative to chondrites, leading to a particularly high and non-chondritic C:N ratio. The N depletion may reflect large-scale differentiation events such as sequestration in Earth's core or massive blow off of Earth's early atmosphere, or alternatively the characteristics of a late-added volatile-rich veneer. As the behavior of N during early planetary differentiation processes is poorly constrained, we determined together the partitioning of N and C between Fe–N–C metal alloy and two different silicate melts (a terrestrial and a martian basalt). Conditions spanned a range of fO2 from ?IW?0.4 to ?IW?3.5 at 1.2 to 3 GPa, and 1400?°C or 1600?°C, where ?IW is the logarithmic difference between experimental fO2 and that imposed by the coexistence of crystalline Fe and wüstite. N partitioning ( ) depends chiefly on fO2, decreasing from to with decreasing fO2. also decreases with increasing temperature and pressure at similar fO2, though the effect is subordinate. In contrast, C partition coefficients () show no evidence of a pressure dependence but diminish with temperature. At 1400?°C, partition coefficients increase linearly with decreasing fO2 from to At 1600?°C, however, they increase from ?IW?0.7 to ?IW?2 ( to ) and decrease from ?IW?2 to ?IW?3.3 . Enhanced C in melts at high temperatures under reduced conditions may reflect stabilization of C–H species (most likely CH4). No significant compositional dependence for either N or C partitioning is evident, perhaps owing to the comparatively similar basalts investigated. At modestly reduced conditions (?IW?0.4 to ?2.2), N is more compatible in core-forming metal than in molten silicate ( ), while at more reduced conditions (?IW?2.2 to ?IW?3.5), N becomes more compatible in the magma ocean than in the metal phase. In contrast, C is highly siderophile at all conditions investigated (). Therefore, sequestration of volatiles in the core affects C more than N, and lowers the C:N ratio of the BSE. Consequently, the N depletion and the high C:N ratio of the BSE cannot be explained by core formation. Mass balance modeling suggests that core formation combined with atmosphere blow-off also cannot produce a non-metallic Earth with a C:N ratio similar to the BSE, but that the accretion of a C-rich late veneer can account for the observed high BSE C:N ratio.
DS201807-1487
2018
Danoczi, J.E.The importance of grease technology in diamond recovery. Eg. CullinanSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 161-172.Globalgrease details, water
DS201808-1736
2018
Danoczi, J.E.The importance of grease technology in diamond recovery. CullinanSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 21 ppts.Africa, South Africamining
DS201809-2013
2018
Dapper, F.A., Cottrell, E.Experimental investigation and peridotite oxybarometers: implications for spinel thermodynamic models and Fe3+ compatibility during generation of upper mantle melts.American Mineralogist, Vol. 103, pp. 1056-1067.Mantlemelting
DS201812-2797
2018
Das, H., Kobussen, A.F., Webb, K.J., Phillips, D., Maas, R., Soltys, A., Rayner, M.J., Howell, D.Bunder deposit: The Bunder diamond project, India: geology, geochemistry, and age of Saptarshi lamproite pipes.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 201-222.Indiadeposit - Bunder
DS201811-2565
2018
Dasgupta, R., Van Tongeren, J.A., Watson, E.B., Ghiorso, M.Volatile bearing partial melts beneath oceans and continents; where, how much, and of what composition.American Journal of Science, Vol. 318, 1, pp. 141-165.Mantlemelting

Abstract: Besides depth and temperature, CO2 and H2O, are the two most important variables in stabilizing partial melts in the Earth's mantle. However, despite decades of experimental studies on the roles of these two volatile species in affecting mantle melting, ambiguity remains in terms of the stability, composition, and proportion of volatile-bearing partial melts at depths. Furthermore, the difference in the influence of H2O versus CO2 in production of mantle melts is often inadequately discussed. Here I first discuss how as a function of depth and concentration of volatiles, the peridotite + H2O versus peridotite + CO2 near-solidus melting conditions differ - discussing specifically the concepts of saturation of volatile-bearing phases and how the mode of storage of ‘water’ and carbon affects the near solidus melting relations. This analysis shows that for the Earth's mantle beneath oceans and continents, deep, volatile-induced melting is influenced mostly by carbon, with water-bearing carbonated silicate melt being the key agent. A quantitative framework that uses the existing experimental data, allows calculation of the loci, extent of melting, and major element compositions of volatile-bearing partial melts beneath oceans and continents. How the domains of volatile-bearing melt stability are affected when possible oxygen fugacity variation at depths in the mantle is taken into account is also discussed. I show that trace amount hydrous carbonated silicate melt is likely stabilized at two or more distinct depths in the continental lithospheric mantle, at depths ranges similar to where mid-lithospheric discontinuity (MLD) and lithosphere-asthenosphere boundary (LAB) have been estimated from seismology. Whereas beneath oceans, hydrous carbonated silicate melt likely remain continuously stable from the base of the thermal boundary layer to at least 200 km or deeper depending on the prevailing oxygen fugacity at depths. Hotter mantles, such as those beneath oceans, prevent sampling strongly silica-undersaturated, carbonated melts such as kimberlites as shallower basaltic melt generation dominates. Thick thermal boundary layers, such as those in cratonic regions, on the other hand allow production of kimberlitic to carbonatitic melt only. Therefore, the increasing frequency of occurrence of kimberlites starting at the Proterozoic may be causally linked to cooling and growth of sub-continental mantles through time.
DS201809-2014
2018
Daver, L., Bureau, H., Gaillou, E., Ferraris, C., Bouillard, J-C., Cartigny, P., Pinti, D.L.In situ analysis of inclusions in diamonds from collections.Goldschmidt Conference, 1p. AbstractGlobaldiamond inclusions

Abstract: Diamonds represent one of the few witnesses of our planet interior. They are mainly formed in the first 200 km of the lithospheric mantle, and, more rarely from the transition zone to 700 km deep. Diamonds contain a lot of information about global evolution, however their mode of formation remains poorly understood. Recent studies in high-pressure mineralogy suggest that diamonds precipitate from oxidized metasomatic fluids. The study of inclusions trapped in diamonds may provide precise information on composition, pressure, temperature and redox conditions. The aim of this study is to use the inclusions trapped in diamond as probes of the deep cycling of volatiles (C, H, halogens). Therefore, we investigate inclusions in diamonds with a systematic study of diamonds from collections. We selected 73 diamonds from three museums: National Museum of Natural History, School of Mines and Sorbonne University. The selected diamonds are studied with the help of a large range of in situ methods: RAMAN and FTIR spectrometry and X-Ray Diffraction. These analyses allow us to identify the nature of the different inclusions without damaging the gems. First results indicate silicate minerals inclusions as pyrope garnet, olivine and enstatite pyroxene. This assemblage is typical of peridotitic-type diamonds in the lithosphere.
DS201810-2308
2018
Davies, G.R., van den Heuvel, Q., Matveev, S., Drury, M.R., Chinn, I.L., Gress, M.U.A combined catholuminescence and electron backscatter diffraction examination of the growth relationships between Jwaneng diamonds and their eclogitic inclusions.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0634-3 12p.Africa, Botswanadeposit - Jwaneng

Abstract: To fully understand the implications of the compositional information recorded by inclusions in diamond it is vital to know if their growth was syn- or protogenetic and the extent to which they have equilibrated with diamond forming agents. The current paradigm is that the majority of inclusions in diamond are syngenetic but recently this assumption has been questioned. This study presents an integrated cathodoluminescence (CL) and electron backscatter diffraction (EBSD) study of 8 diamonds containing eclogitic inclusions: 19 pyrope-almandine garnets, 12 omphacitic clinopyroxenes, 4 sulphides, 1 coesite and 1 rutile from the Jwaneng diamond mine, Botswana. Diamond plates were sequentially polished to expose inclusions at different levels and CL imaging and EBSD were performed to constrain the relationship between diamond and inclusion growth. Despite complex growth and resorption, individual diamonds are single crystals with a homogeneous crystallographic orientation. All individual inclusions have homogeneous crystallographic orientation and no resolvable compositional zonation. The combined CL and EBSD data suggest that epitaxial inclusion-diamond growth is rare (none of 24 inclusions) and that the imposition of cubo-octahedral faces on inclusions does not necessarily result in epitaxy. Individual diamonds contain inclusions that record evidence of both syngentic and protogenetic relationships with the host diamond and in one case an inclusion appears syngenetic to the diamond core but protogenetic to the growth zone that surrounds 70% of the inclusion. These findings emphasise that inclusions in diamonds have multiple modes of origin and that in order to validate the significance of geochronological studies, further work is needed to establish that there is rapid chemical equilibration of protogenetic inclusions with diamond forming agents at mantle temperatures.
DS201812-2798
2018
Davies, R., Davies, A.W.Alteration of Mn ilmentite in Horton area of Lena West.2018 Yellowknife Geoscience Forum , p. 102-103. abstractCanada, Northwest Territoriesdeposit - Lena West

Abstract: Mn-ilmenite was recognized as a kimberlite indicator mineral (KIM) in the Lena West diamond region of the Northwest Territories by Darnley Bay, Talmora and Sanatana. It includes compositions that match those found as inclusions in type IIa diamonds from Brazil and Venezuela that formed in the lower mantle. The recent determination that large, high value type IIa diamonds like the Cullinan, Koh-I-Nor, etc. also formed in the lower mantle increases the importance of Mn-ilmenites not only as a KIM resistant to tropical weathering but as a possible indicator of large high value stones. The Mn-ilmenite alteration products, pseudorutile (Fe2Ti3O9) and ferropseudobrookite (FeTi2O5) may also be used as KIMs and provide useful additional information. Mn-ilmenites found as inclusions in diamonds range from 51 wt.% TiO2 (total wt.% 100) to 56 wt.% TiO2 (total wt.% 95). The shortfall in wt.% of the high TiO2 grains was ascribed by Kaminsky and Belasouva (2009) to some element not included in the analysis. The shortfall may also occur when some ferric iron is calculated as ferrous iron? As most Lena West Mn-ilmenite analyses have high totals those with totals less than 96 wt.% have been considered an alteration product (“pseudorutile”). “Pseudorutile” is produced by the oxidation of FeO in ilmenite to Fe2O3 which results in an apparent loss of total weight percent when Fe is calculated as ferrous iron. A range of values approximating “ferropseudobrookite” with totals close to 100 wt.% is another alteration product of ilmenite with a loss of iron but without its oxidation to ferric iron. The Horton area consists of a cluster of magnetic anomalies averaging ~ 200 m diameter east of a very large magnetic anomaly beneath Seahorse Lake. The Seahorse anomaly is at the focus of a train of kimberlite pathfinder elements coincident with a NNW trending KIM train characterised by Mn-ilmenite, picro-ilmenite and chromite. A parallel train of similar KIMs is focused Mn-ilmenite was recognized as a kimberlite indicator mineral (KIM) in the Lena West diamond region of the Northwest Territories by Darnley Bay, Talmora and Sanatana. It includes compositions that match those found as inclusions in type IIa diamonds from Brazil and Venezuela that formed in the lower mantle. The recent determination that large, high value type IIa diamonds like the Cullinan, Koh-I-Nor, etc. also formed in the lower mantle increases the importance of Mn-ilmenites not only as a KIM resistant to tropical weathering but as a possible indicator of large high value stones. The Mn-ilmenite alteration products, pseudorutile (Fe2Ti3O9) and ferropseudobrookite (FeTi2O5) may also be used as KIMs and provide useful additional information. Mn-ilmenites found as inclusions in diamonds range from 51 wt.% TiO2 (total wt.% 100) to 56 wt.% TiO2 (total wt.% 95). The shortfall in wt.% of the high TiO2 grains was ascribed by Kaminsky and Belasouva (2009) to some element not included in the analysis. The shortfall may also occur when some ferric iron is calculated as ferrous iron? As most Lena West Mn-ilmenite analyses have high totals those with totals less than 96 wt.% have been considered an alteration product (“pseudorutile”). “Pseudorutile” is produced by the oxidation of FeO in ilmenite to Fe2O3 which results in an apparent loss of total weight percent when Fe is calculated as ferrous iron. A range of values approximating “ferropseudobrookite” with totals close to 100 wt.% is another alteration product of ilmenite with a loss of iron but without its oxidation to ferric iron. The Horton area consists of a cluster of magnetic anomalies averaging ~ 200 m diameter east of a very large magnetic anomaly beneath Seahorse Lake. The Seahorse anomaly is at the focus of a train of kimberlite pathfinder elements coincident with a NNW trending KIM train characterised by Mn-ilmenite, picro-ilmenite and chromite. A parallel train of similar KIMs is focused on the cluster of smaller anomalies to the east. “Pseudorutile” is found over the cluster of anomalies that lie within the Horton River drainage and in the area north towards Darnley Bay. It was especially abundant with some unaltered Mn-ilmenite grains in the cuttings of a Packsack drill hole that penetrated a few feet of rusty coloured clay coincident with one of the anomalies. It does not appear to travel far. “Ferropseudobrookite” is found mostly west of the Horton River drainage, about 100 kilometers down-ice in the trains coming off the Seahorse anomaly and the cluster of smaller anomalies respectively. It represents the weathering of Mn-ilmenite in the upper part of anomalies that was carried furthest by glaciation indicating a resistance to mechanical wear. Mn-ilmenite is a useful KIM in areas of tropical weathering and is also an indicator of rare large high value diamonds. The distribution of pseudorutile and ferropseudobrookite suggests that the initial alteration of Mn-ilmenite is to pseudorutile and then ferropseudobrookite. The presence of one or the other is therefore a measure of the distance to the source.
DS201808-1737
2018
Davis, F.A., Cottrell, E.Experimental investigation of basalt and peridotite oxybarometers: implications for spinel thermodynamic models and Fe 3+ compatibility during generation of upper mantle melts.American Mineralogist, Vol. 103, pp. 1056-1067.Mantleperidotite

Abstract: Peridotites dredged from mid-ocean ridges and glassy mid-ocean ridge basalts (MORB) transmit information about the oxygen fugacity (fO2) of Earth's convecting upper mantle to the surface. Equilibrium assemblages of olivine+orthopyroxene+spinel in abyssal peridotites and Fe3+/?Fe ratios in MORB glasses measured by X-ray absorption near-edge structure (XANES) provide independent estimates of MORB source region fO2, with the former recording fO2 approximately 0.8 log units lower than the latter relative to the quartz-fayalite-magnetite (QFM) buffer. To test cross-compatibility of these oxybarometers and examine the compositional effects of changing fO2 on a peridotite plus melt system over a range of Earth-relevant fO2, we performed a series of experiments at 0.1 MPa and fO2 controlled by CO-CO2 gas mixes between QFM-1.87 and QFM+2.23 in a system containing basaltic andesite melt saturated in olivine, orthopyroxene, and spinel. Oxygen fugacities recorded by each method are in agreement with each other and with the fO2 measured in the furnace. Measurements of fO2 from the two oxybarometers agree to within 1? in all experiments. These results demonstrate that the two methods are directly comparable and differences between fO2 measured in abyssal peridotites and MORB result from geographic sampling bias, petrological processes that change fO2 in these samples after separation of melts and residues, or abyssal peridotites may not be residues of MORB melting. As fO2 increases, spinel Fe3+ concentrations increase only at the expense of Cr from QFM-1.87 to QFM-0.11. Above QFM, Al is also diluted in spinel as the cation proportion of Fe3+ increases. None of the three spinel models tested, MELTS (Ghiorso and Sack 1995), SPINMELT (Ariskin and Nikolaev 1996), and MELT_CHROMITE (Poustovetov and Roeder 2001), describe these compositional effects, and we demonstrate that MELTS predicts residues that are too oxidized by >1 log unit to have equilibrated with the coexisting liquid phase. Spinels generated in this study can be used to improve future thermodynamic models needed to predict compositional changes in spinels caused by partial melting of peridotites in the mantle or by metamorphic reactions as peridotites cool in the lithosphere. In our experimental series, where the ratio of Fe2O3/FeO in the melt varies while other melt compositional parameters remain nearly constant, experimental melt fraction remains constant, and Fe3+ becomes increasingly compatible in spinel as fO2 increases. Instead of promoting melting, increasing the bulk Fe3+/?Fe ratio in peridotite drives reactions analogous to the fayalite-ferrosilite-magnetite reaction. This may partly explain the absence of correlation between Na2O and Fe2O3 in fractionation-corrected MORB.
DS201812-2799
2018
Davy, A.T., Smith, C.B., Helmstaedt, H., Jaques, A.L.PrefaceSociety of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, p. ixAustralia, India, Canada, Northwest Territories, Africa, Zimbabwedeposits - Argyle, Bunder, Diavik, Murowa
DS201802-0230
2018
De Carvallo, L.D.V., Schnellrath, J., de Medeiros, S.G.Mineral inclusions in diamonds from Chapada Diamantina, Bahia, Brazil: a raman spectroscopic characterization, REM ****IN PORTInternational Engineering Journal, Ouro Preto *** IN: PORT, Vol. 71, 1, pp. 27-35.South America, Brazildeposit - Chapada

Abstract: The Chapada Diamantina, located in the central region of the State of Bahia, is of important historical significance due to its diamond occurrences. Discovered in the nineteenth century, comprehensive research about the regional diamonds and their origins are still limited, demanding more investigation in the matter. Looking for insights about their genesis, mineral inclusions in 23 alluvial diamonds from 4 garimpos located in the Chapada Diamantina were analyzed through the use of Raman micro spectroscopy. Additionally, the characteristics of nitrogen aggregation of the host diamonds were measured using Fourier-transform infrared spectroscopy (FTIR). The diamonds from Chapada Diamantina consist mainly of well-formed crystals, with dominant dodecahedral habits, characterized by faint to very light yellow body colors, typically with green and brown radiation spots on their surface. The main surface textures observed are related to processes that took place in the late stage resorption and during the residence of the diamonds in placer environments. The diamonds are predominantly type IaAB, with a significant occurrence of poorly aggregated nitrogen (Type IaA diamond). The main mineral assemblages of the studied peridotitic inclusions refer to a harzburgitic paragenesis.
DS201812-2800
2018
de Sousa do Amaral Miranda, N.Modernization introduced by the Kimberley Process Certification.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, BrazilKP
DS201803-0440
2018
De Wit, M.C.Prospecting history leading to the discovery of Botswana's diamond mines: from artefacts to Lesedi La Rona.Mineralogy and Petrology, in press available, 16p.Africa, Botswanadiamond exploration

Abstract: Bechuanaland/Botswana has a long and colourful history in exploration and mining. Here these activities are subdivided into three phases: pre-historic, historic and modern. Quarrying stone in Botswana was ongoing 500,000 years ago during the Early Stone Age (ESA). Actual mining of stones probably only started during the Middle Stone Age (MSA) i.e. post 250,000 BP, and the first prehistoric hard rock mining of specularite and limonite, likely started during the Late Stone Age (LSA) 20,000 to 2,000 BP. In east Botswana iron and copper were mined from AD 800 onwards; the mining of gold started in the thirteenth century. Historic mining started with the re-discovery of gold close to Francistown in 1865 and lasted until the 1950s. Rumours of diamonds in Bechuanaland had already surfaced in the 1880s, and it was Ngamiland, in the northwest, that was first explored systematically for diamonds and gold between 1896 and 1899. A joint initiative between Anglo American and De Beers started serious prospecting parts of eastern Bechuanaland between 1932 and 1938; and in 1938 the first diamond finds in Bechuanaland were reported. Modern mining and exploration started with the signing of an agreement in 1959, allowing Consolidated African Selection Trust Ltd. (CAST) into the Bamangwato Tribal Reserve. CAST found a few diamonds in the Motloutse River, but concluded that these were reworked and dropped the exploration rights. De Beers believed that these diamonds had come from west of the Motloutse headwaters, across the watershed in the Kalahari. This ultimately led to the discovery of the Orapa kimberlite field in 1967, a year after Botswana became independent. This discovery triggered a major exploration boom across Botswana adding important diamond-bearing kimberlites such as at Letlhakane (1968), Jwaneng (1973), Gope (1981) and Lerala (1991).
DS201808-1738
2017
Deb, M., Sarkar, S.C.Minerals and allied natural resources and their sustainable development. Principles, perspectives with emphasis on the Indian scenario. Detailed Book reviewSpringer Nature , book review in Mineralium Deposita diamonds mentioned p. 6-7. of reviewIndiadiamonds

Abstract: Nonrenewable natural resources - metallic and non-metallic minerals, industrial rocks and energy resources (both organic and inorganic), have been treated in a holistic manner in this book, including two important resources (soil and water), not commonly covered in most books on this topic. For the uninitiated reader, an introductory chapter looks into some basic definitions as well as nature and characteristics of mineral deposits followed by a chapter on the different crustal processes that produce the various ore deposits in the endogenous and exogenous environments. The strength of the book lies in its critical treatment of the genetic processes of the mineral deposits, their classification and the geodynamic context of metallogeny, and coverage of sustainable development of mineral deposits with special reference to various socio-economic as well as regulatory and environmental issues that face the Indian mining industry today. The text is punctuated with examples of Indian deposits, balanced with classical deposits around the world, to cater to the interests of Indian students and the international readership. This is a book for advanced undergraduate and post-graduate students of Geology, Environmental Sciences and Natural Resource Management.
DS201806-1220
2018
DeLaunay, A., Fritsch, E.Type IIa diamond with extraordinary etch channels.Gems & Gemology, Vol. 54, 1, p. 66.Technologydiamond inclusions
DS201804-0683
2017
Devriese, S.G.R., Davis, K., Oldenburg, D.W.Inversion of airborne geophysics over the DO-27/DO18 kimberlites. Part 1. Potential fields.Society of Exploration Geophysicists, Interpretation, August T 299, 13p.Canada, Northwest Territoriesdeposit - Tli Kwi Cho

Abstract: The Tli Kwi Cho (TKC) kimberlite complex contains two pipes, called DO-27 and DO-18, which were discovered during the Canadian diamond exploration rush in the 1990s. The complex has been used as a testbed for ground and airborne geophysics, and an abundance of data currently exist over the area. We have evaluated the historical and geologic background of the complex, the physical properties of interest for kimberlite exploration, and the geophysical surveys. We have carried out 3D inversion and joint interpretation of the potential field data. The magnetic data indicate high susceptibility at DO-18, and the magnetic inversion maps the horizontal extent of the pipe. DO-27 is more complicated. The northern part is highly magnetic and is contaminated with remanent magnetization; other parts of DO-27 have a low susceptibility. Low densities, obtained from the gravity and gravity gradiometry data, map the horizontal extents of DO-27 and DO-18. We combine the 3D density contrast and susceptibility models into a single geologic model that identifies three distinct kimberlite rock units that agree with drilling data. In further research, our density and magnetic susceptibility models are combined with information from electromagnetic data to provide a multigeophysical interpretation of the TKC kimberlite complex.
DS201804-0684
2018
D'Haenens-Johansson, U.Synthesis of man-made gem diamonds and their detection.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., p. 16. abstractTechnologysynthetics
DS201812-2801
2017
Dhuime, B., Hawkesworth, C.J., Delavault, H., Cawood, P.A.Rates of generation and destruction of the continental crust: implications for continental growth.Philosphical Transactions of the Royal Society, http://dx.doi.org/ 10.1098/rsta .2017.0403 12p. AvailableMantleplate tectonics

Abstract: Less than 25% of the volume of the juvenile continental crust preserved today is older than 3?Ga, there are no known rocks older than approximately 4?Ga, and yet a number of recent models of continental growth suggest that at least 60-80% of the present volume of the continental crust had been generated by 3?Ga. Such models require that large volumes of pre-3?Ga crust were destroyed and replaced by younger crust since the late Archaean. To address this issue, we evaluate the influence on the rock record of changing the rates of generation and destruction of the continental crust at different times in Earth's history. We adopted a box model approach in a numerical model constrained by the estimated volumes of continental crust at 3?Ga and the present day, and by the distribution of crust formation ages in the present-day crust. The data generated by the model suggest that new continental crust was generated continuously, but with a marked decrease in the net growth rate at approximately 3?Ga resulting in a temporary reduction in the volume of continental crust at that time. Destruction rates increased dramatically around 3 billion years ago, which may be linked to the widespread development of subduction zones. The volume of continental crust may have exceeded its present value by the mid/late Proterozoic. In this model, about 2.6-2.3 times of the present volume of continental crust has been generated since Earth's formation, and approximately 1.6-1.3 times of this volume has been destroyed and recycled back into the mantle.
DS201809-2015
2018
Di Massa, D., Fedi, M., Florio, G., Vitale, A., Viezzoli, A., Kaminski, V.Joint interpretation of AEM and aeromagnetic dat a acquired over the Drybones kimberlite, NWT ( Canada).Journal of Applied Physics, Vol. 158, pp. 48-56.Canada, Northwest Territoriesdeposit - Drybones

Abstract: We present the joint interpretation of airborne electromagnetic and aeromagnetic data, acquired to study kimberlite pipes. We analyse the data surveyed in 2005 over Drybones Bay, Archean Slave Province of the Northwest Territories, northern Canada. This area hosts a recently discovered kimberlite province with >150 kimberlite pipes. Magnetic and electromagnetic data were each one modelled by 1D inversion. For magnetic data we inverted vertical soundings built through upward continuations of the measured data at various altitudes. The validity of the method was prior verified by tests on synthetic data. Electromagnetic data were processed and inverted using the modified AarhusINV code, with Cole-Cole modelling, in order to take into account induced polarization effects, consisting in negative voltages and otherwise skewed transients. The integrated study of the two kinds of data has led to a better understanding of the structures at depth, even though the comparison between the magnetic and the electromagnetic models shows the different sensitivity of the two methods with respect to the geological structure at Drybones Bay.
DS201803-0441
2017
Diallo, P.Social insecurity, stability and the politics in West Africa: a case study of artisanal and small scale diamond mining in Guinea, 1958-2008.The Extractive Industries and Society, Vol. 4, pp. 489-496.Africa, Guineaartisanal mining

Abstract: The period of protracted conflict in Sierra Leone and Liberia brought the politics of alluvial diamond mining in West Africa to the forefront of academic and policy-oriented discussions. Using social contract theory, this paper moves away from discussions on how minerals have perpetuated conflict in the region, and interrogates how the governance of diamond mining in Guinea impacts regime stability and social insecurity. More importantly, it attempts to illustrate how artisanal diamond mining contributes to stability. The paper situates this discussion within the broad spectrum of the social contract between state and citizens and an analysis of how these are at play in diamond mining areas. It illustrates how artisanal diamond mining enables specific social contracts to emerge and how this in turn contributes to stability in the regions where they are extracted.
DS201808-1739
2018
Diamond Buyers InternationalCompletely new types of diamonds found in Kamchatka lava. Tolbachikdiamondbuyers intl.com, July 5, 1p.Russia, Kamchatkadeposit - Tolbachik

Abstract: discovered a unique type of diamond in the Tolbachik volcano frozen lava- in the Kamchatka Peninsula of far East Russia. Scientists from all over the world are quite impressed with these findings and they now classify the gemstones as completely new & unique types of diamonds. The new types of diamonds are named after the place they were found- Tolbachik Diamonds. According to geologists, the Tolbachik diamonds were born under a very peculiar natural formation where the gemstones crystalized under the direct influence of the electric discharge of lightning and the pressure from the volcanic gases. Geologists also agree that several decades ago experts wanted to create a synthetic type of diamond where the result would have been exactly the one now created naturally in the Tolbachik diamonds. In the early 60s the French wanted to create a synthetic diamond where they would use gas as primary substance and then using electric discharge for the crystallization of the gemstone. At a closer look, the Tolbachik diamonds are similar to the synthetic diamonds found on today’s market. However, the main mineralogical and geological structure of the diamond is unlike any other type of precious stone discovered until now. These diamonds are particularly large in size (200 and up to 700 microns!). According to scientists, this is actually the first time when they discovered lava rocks that show such very dense diamond content. This discovery actually gave way to very intense disputes among specialists regarding if the Lab Grown diamonds should be regarded as ‘synthetic’ any longer. The Tolbachik diamonds resemble almost in every aspect the structure of the lab grown diamonds and they are naturally formed in lava. Therefore, the Lab Grown diamonds should be more highly regarded just as the naturally mined diamonds are. Another important fact to keep in mind is that only a true expert is actually able to tell the difference between the Tolbachik diamonds created naturally and the lab grown diamonds. Someone who is not an expert would simply regard the Tolbachik diamonds as synthetic diamonds, given their different structure from the regular diamonds formed in magmatic melt. Experts found an extremely high quantity of diamonds (several hundreds of pieces) in only a small sample of frozen lava in the Kamchatka Lava in Russia. When or how these gemstones will enter the fascinating diamond industry, and if the price of jewelry featuring Tolbachik diamonds will be more budget friendly is yet to be settled…
DS201811-2566
2018
Dijkstra, A.H., Hatch, C.Mapping a hidden terrane boundary in the mantle lithosphere with lamprophyres. ( Amorica)Nature Communications, Vol. 9, p. 3770.Europe, Englandgeochronology

Abstract: Lamprophyres represent hydrous alkaline mantle melts that are a unique source of information about the composition of continental lithosphere. Throughout southwest Britain, post-Variscan lamprophyres are (ultra)potassic with strong incompatible element enrichments. Here we show that they form two distinct groups in terms of their Sr and Nd isotopic compositions, occurring on either side of a postulated, hitherto unrecognized terrane boundary. Lamprophyres emplaced north of the boundary fall on the mantle array with ?Nd ?1 to +1.6. Those south of the boundary are enriched in radiogenic Sr, have initial ?Nd values of ?0.3 to ?3.5, and are isotopically indistinguishable from similar-aged lamprophyres in Armorican massifs in Europe. We conclude that an Armorican terrane was juxtaposed against Avalonia well before the closure of the Variscan oceans and the formation of Pangea. The giant Cornubian Tin-Tungsten Ore Province and associated batholith can be accounted for by the fertility of Armorican lower crust and mantle lithosphere.
DS201804-0685
2018
Dilek, Y., Yang, J.Ophiolites, diamonds, and ultrahigh pressure minerals: new discoveries and concepts on upper mantle petrogenesis.Lithosphere, Vol. 10, 1, pp. 3-13.MantleUHP - metasomatism

Abstract: Ophiolitic peridotites represent variously depleted residues of the primitive mantle after multiple episodes of partial melting, melt extraction, and melt-rock interactions. They display a wide range of compositional and geochemical heterogeneities at different scales, and their incompatible bulk-rock compositions and mineral chemistries are commonly inconsistent with their evolution through simple partial melting processes at shallow mantle depths. Approaching these issues from different perspectives, the papers in this volume concentrate on (1) melt evolution and magmatic construction of ophiolites in various tectonic settings, and (2) the occurrence of microdiamonds, ultrahigh-pressure (UHP) minerals, and crustal material as inclusions in ophiolitic chromitites and peridotites. Crustal and mantle rock units exposed in different ophiolites show that the mantle melt sources of ophiolitic magmas undergo progressive melting, depletion, and enrichment events, constantly modifying the melt compositions and the mineralogical and chemical makeup of residual peridotites. Formation and incorporation of microdiamonds and UHP minerals into chromite grains occurs at depths of 350-660 km in highly reducing conditions of the mantle transition zone. Carbon for microdiamonds and crustal minerals are derived from subduction-driven recycling of surface material. Host peridotites with their UHP mineral and diamond inclusions are transported into shallow mantle depths by asthenospheric upwelling, associated with either slab rollback-induced channel flow or superplumes. Decompression melting of transported mantle rocks beneath oceanic spreading centers and their subsequent flux melting in mantle wedges result in late-stage formation of podiform chromitites during the upper mantle petrogenesis of ophiolites. Future studies should demonstrate whether diamonds and UHP minerals also occur in peridotites and chromitites of nonsubduction-related ophiolites.
DS201811-2567
2018
Dipple, G.Optimizing carbon capture and storage in kimberlite tailings for environmental benefit and operational efficiency.Vancouver Kimberlite Cluster, Nov. 6, 1p. AbstractGlobalcarbon

Abstract: Ultramafic mine tailings, including those from kimberlite-hosted diamond mines, offer potential operational and environmental benefit through reaction with carbon dioxide from air and power plant flue gas. The carbon dioxide is sequestered from the environment through the precipitation of carbonate minerals, thus reducing or offsetting the greenhouse gas emissions associated with mining. Additional benefits can include tailings stabilization, dust reduction, acid mine drainage prevention, and toxic metal encapsulation. In this talk I will present an overview of the processes and controls on carbonation reactions within tailings at active mines with a focus on acceleration of carbon sequestration within kimberlite tailings. Carbonation reactions can be limited by transport (rate of CO2 supply) and by reaction kinetics (mineral dissolution or mineral precipitation). Field studies of accidental passive carbonation within tailings at operating mines supplemented with laboratory experiment and reactive transport modelling has been key to identifying the rate limits to carbon sequestration at each mine site. With these limits identified, acceleration approaches can be tailored to the local climate, gangue mineralogy, and mine design, all of which can exert a primary control on carbon sequestration rates. The result is a methodology for evaluating the carbon sequestration potential of a mine site and a toolbox of acceleration strategies which together allow for site selection and project design. In the coming years, these systems will be deployed on site at active mines to further test and advance the technology. I will end with a perspective on the role that mining of ultramafic-hosted deposits can play in achieving net negative CO2 emissions as is projected to be required by the end of this century if we are to avoid net global warming in excess of two degrees centigrade.
DS201808-1740
2018
Dira, T. A., Daniels, L. R.M. The significance of termites on the future of kimberlite exploration in Botswana.Mineralogy and Petrology, 10.1007/s00710-018-0608-5 8p. Africa, Botswanaindicator minerals

Abstract: The majority of the diamond mines in Botswana were discovered as a direct consequence of soil sampling for indicator minerals such as garnet and picroilmenite. Over the past 60 years the application of soil sampling for indicator minerals as a primary exploration tool has declined while aeromagnetic surveys have increased in popularity. The rate of kimberlite discovery in Botswana has declined significantly. The obvious magnetic kimberlites have been discovered. The future of new kimberlite discoveries is once again dependent on soil sampling for kimberlite indicator minerals. It is essential to have an in depth understanding of the transport mechanism of kimberlite indicator minerals from the kimberlite to the modern day surface of the Kalahari Formation, which is solely via termite bioturbation. Field observations indicate that the concentration of indicator minerals at surface is directly dependent on the physical characteristics and capabilities as well as behavioural patterns of the particular termite species dominant in the exploration area. The discovery of future diamond mines in Botswana will be closely associated with an in depth understanding of the relationship between size and concentration of kimberlite indicator minerals in surface soils and the seasonal behaviour, depth penetration capabilities, earthmoving efficiencies and mandible size of the dominant termite species within the exploration area. Large areas in Botswana, where kimberlite indicator minerals recovered from soil samples have been described as distal from source or background, will require re-evaluation. Without detailed termite studies the rate of discovery will continue to decline.
DS201803-0442
2018
Dira, T., Daniels, L.Contrasting termite transported indicator mineral concentrations in the Kgalafadi of central district Botswana: Macrotermes micaelseni vs Hodotermes mossambicus.Vancouver Kimberlite Cluster, March 9, 1p. AbstractAfrica, Botswanatermite and indiactor minerals
DS201808-1741
2018
Dira, T., Daniels, L.The role of Hodtermes mossambicus termites and background kimberlite indicators in the Kgalagadi. PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 38 ppts.Africa, Botswanaindicator minerals
DS201807-1488
2018
Dira, T.A., Daniels, L.R.M.The role of Hodotermes mossambicus termites and background kimberlite indicators in the Kgalagadi .Malatswe areaSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 1-8.Africa, BotswanaIndicator minerals
DS201805-0943
2018
Dobrzhinetskaya, L., Mukhin, P., wang, Q., Wirth, R., O'Bannon, E., Zhao, W., Eppelbaum, L., Sokhonchuk, T.Moissanite ( SiC) with metal silicide and silicon inclusions from tuff of Israel: raman spectroscopy and electron microscope studies.Lithos, in press available 58p.Europe, Israelmoissanite

Abstract: Here, we present studies of natural SiC that occurs in situ in tuff related to the Miocene alkaline basalt formation deposited in northern part of Israel. Raman spectroscopy, SEM and FIB-assisted TEM studies revealed that SiC is primarily hexagonal polytypes 4H-SiC and 6H-SiC, and that the 4H-SiC polytype is the predominant phase. Both SiC polytypes contain crystalline inclusions of silicon (Sio) and inclusions of metal-silicide with varying compositions (e.g. Si58V25Ti12Cr3Fe2, Si41Fe24Ti20Ni7V5Zr3, and Si43Fe40Ni17). The silicides crystal structure parameters match Si2TiV5 (Pm-3 m space group, cubic), FeSi2Ti (Pbam space group, orthorhombic), and FeSi2 (Cmca space group, orthorhombic) respectively. We hypothesize that SiC was formed in a local ultra-reduced environment at respectively shallow depths (60-100 km), through a "desilification" reaction of SiO2 with highly reducing fluids (H2O-CH4-H2-C2H6) arisen from the mantle "hot spot" and passing through alkaline basalt magma reservoir. SiO2 (melt) interacting with the fluids may originate from the walls of the crustal rocks surrounding this magmatic reservoir. The "desilification" process led to the formation of SiC and the reduction of metal-oxides to native metals, alloys, and silicides. The latter were trapped by SiC during its growth. Hence, interplate "hot spot" alkali basalt volcanism can now be included as a geological environment where SiC, silicon, and silicides can be found.
DS201812-2802
2018
Donati-Filho, J.P.A new geological model, facies recognition and terminology of the Brauna kimberlite field, Bahia - Brazil.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Bahiadeposit - Brauna
DS201804-0686
2018
Dorfman, S.M., Badro, J., Nabiel, F., Prakapenka, V.B., Cantoni, M., Gillet, P.Carbonate stability in the reduced lower mantle.Earth and Planteray Science Letters, Vol. 489, pp. 84-91.Mantlecarbonate

Abstract: Carbonate minerals are important hosts of carbon in the crust and mantle with a key role in the transport and storage of carbon in Earth's deep interior over the history of the planet. Whether subducted carbonates efficiently melt and break down due to interactions with reduced phases or are preserved to great depths and ultimately reach the core-mantle boundary remains controversial. In this study, experiments in the laser-heated diamond anvil cell (LHDAC) on layered samples of dolomite (Mg,?Ca)CO3 and iron at pressure and temperature conditions reaching those of the deep lower mantle show that carbon-iron redox interactions destabilize the MgCO3 component, producing a mixture of diamond, Fe7C3, and (Mg,?Fe)O. However, CaCO3 is preserved, supporting its relative stability in carbonate-rich lithologies under reducing lower mantle conditions. These results constrain the thermodynamic stability of redox-driven breakdown of carbonates and demonstrate progress towards multiphase mantle petrology in the LHDAC at conditions of the lowermost mantle.
DS201803-0443
2018
Doroshkevich< A.G., Prokopyev, I.R., Izokh, A.E., Klemd, R., Ponomarchuk, A.V., Nikolaeva, I.V., Vladykin, N.V.Isotopic and trace element geochemistry of the Seligdar magnesiocarbonatites ( South Yakutia, Russia): insights regarding the mantle evolution beneath the Aldan Stanovoy shield.Journal of Asian Earth Sciences, Vol. 154, pp. 354-368.Russia, Yakutiacarbonatite -Seligdar

Abstract: The Paleoproterozoic Seligdar magnesiocarbonatite intrusion of the Aldan-Stanovoy shield in Russia underwent extensive postmagmatic hydrothermal alteration and metamorphic events. This study comprises new isotopic (Sr, Nd, C and O) data, whole-rock major and trace element compositions and trace element characteristics of the major minerals to gain a better understanding of the source and the formation process of the carbonatites. The Seligdar carbonatites have high concentrations of P2O5 (up to 18?wt%) and low concentrations of Na, K, Sr and Ba. The chondrite-normalized REE patterns of these carbonatites display significant enrichments of LREE relative to HREE with an average La/Ybcn ratio of 95. Hydrothermal and metamorphic overprints changed the trace element characteristics of the carbonatites and their minerals. These alteration processes were responsible for Sr loss and the shifting of the Sr isotopic compositions towards more radiogenic values. The altered carbonatites are further characterized by distinct 18O- and 13C-enrichments compared to the primary igneous carbonatites. The alteration most likely resulted from both the percolation of crustal-derived hydrothermal fluids and subsequent metamorphic processes accompanied by interaction with limestone-derived CO2. The narrow range of negative ?Nd(T) values indicates that the Seligdar carbonatites are dominated by a homogenous enriched mantle source component that was separated from the depleted mantle during the Archean.
DS201802-0231
2017
Dowman, E., Wall, F., Treloar, P.J., Rankin, A.H.Rare earth mobility as a result of multiple phases of fluid activity in fenite around the Chilwa Island carbonatite, Malawi.Mineralogical Magazine, Vol. 81, 6, pp. 1367-1395.Africa, Malawicarbonatite - Chilwa

Abstract: Carbonatites are enriched in critical raw materials such as the rare earth elements (REE), niobium, fluorspar and phosphate. A better understanding of their fluid regimes will improve our knowledge of how to target and exploit economic deposits. This study shows that multiple fluid phases penetrated the surrounding fenite aureole during carbonatite emplacement at Chilwa Island, Malawi. The first alkaline fluids formed the main fenite assemblage and later microscopic vein networks contain the minerals of potential economic interest such as pyrochlore in high-grade fenite and RE minerals throughout the aureole. Seventeen samples of fenite rock from the metasomatic aureole around the Chilwa Island carbonatite complex were chosen for study (Natural History Museum, London collection BM1968 P37). In addition to the main fenite assemblage of feldspar and aegirine ± arfvedsonite, riebeckite and richterite, the fenite contains micro-mineral assemblages including apatite, ilmenite, rutile, magnetite, zircon, RE minerals and pyrochlore in vein networks. Petrography using SEM-EDX showed that the RE minerals (monazite, bastnäsite and parisite) formed later than the fenite feldspar, aegirine and apatite and provide evidence of REE mobility into all grades of fenite. Fenite apatite has a distinct negative Eu anomaly (determined by LA-ICP-MS) that is rare in carbonatite-associated rocks and interpreted as related to pre-crystallisation of plagioclase and co-crystallisation with K-feldspar in the fenite. The fenite minerals have consistently higher mid REE/light REE ratios (La/Sm = ~1.3 monazite, ~1.9 bastnäsite, ~1.2 parisite) than their counterparts in the carbonatites (La/Sm = ~2.5 monazite, ~4.2 bastnäsite, ~3.4 parisite). Quartz in the low- and medium-grade fenite hosts fluid inclusions, typically a few µm in diameter, secondary and extremely heterogeneous. Single phase, 2- and 3-phase, single solid and multi solid-bearing examples are present, with 2-phase the most abundant. Calcite, nahcolite, burbankite and barite were found in the inclusions. Decrepitation of inclusions occurred at around 200?C before homogenisation but melting temperature data indicate that the inclusions contain relatively pure CO2. A minimum salinity of around 24 wt.% NaCl equivalent was determined. Among the trace elements in whole rock analyses, enrichment in Ba, Mo, Nb, Pb, Sr, Th and Y and depletion in Co, Hf and V are common to carbonatite and fenite but enrichment in carbonatitic type elements (Ba, Nb, Sr, Th, Y, and REE) generally increases towards the inner parts of the aureole. A schematic model contains multiple fluid events, related to first and second boiling of the magma, accompanying intrusion of the carbonatites at Chilwa Island, each contributing to the mineralogy and chemistry of the fenite. The presence of distinct RE mineral micro-assemblages in fenite at some distance from carbonatite could be developed as an exploration indicator of REE enrichment.
DS201803-0444
2017
Dowman, E., Wall, F., Treloar, P.J., Rankin, A.H.Rare earth mobility as a result of multiple phases of fluid activity in fenite around the Chilwa Island carbonatite, Malawi.Mineralogical Magazine, Vol. 81, 6, pp. 1367-1395.Africa, Malawicarbonatite

Abstract: Carbonatites are enriched in critical raw materials such as the rare earth elements (REE), niobium, fluorspar and phosphate. A better understanding of their fluid regimes will improve our knowledge of how to target and exploit economic deposits. This study shows that multiple fluid phases penetrated the surrounding fenite aureole during carbonatite emplacement at Chilwa Island, Malawi. The first alkaline fluids formed the main fenite assemblage and later microscopic vein networks contain the minerals of potential economic interest such as pyrochlore in high-grade fenite and RE minerals throughout the aureole. Seventeen samples of fenite rock from the metasomatic aureole around the Chilwa Island carbonatite complex were chosen for study (Natural History Museum, London collection BM1968 P37). In addition to the main fenite assemblage of feldspar and aegirine ± arfvedsonite, riebeckite and richterite, the fenite contains micro-mineral assemblages including apatite, ilmenite, rutile, magnetite, zircon, RE minerals and pyrochlore in vein networks. Petrography using SEM-EDX showed that the RE minerals (monazite, bastnäsite and parisite) formed later than the fenite feldspar, aegirine and apatite and provide evidence of REE mobility into all grades of fenite. Fenite apatite has a distinct negative Eu anomaly (determined by LA-ICP-MS) that is rare in carbonatite-associated rocks and interpreted as related to pre-crystallisation of plagioclase and co-crystallisation with K-feldspar in the fenite. The fenite minerals have consistently higher mid REE/light REE ratios (La/Sm = ~1.3 monazite, ~1.9 bastnäsite, ~1.2 parisite) than their counterparts in the carbonatites (La/Sm = ~2.5 monazite, ~4.2 bastnäsite, ~3.4 parisite). Quartz in the low- and medium-grade fenite hosts fluid inclusions, typically a few µm in diameter, secondary and extremely heterogeneous. Single phase, 2- and 3-phase, single solid and multi solid-bearing examples are present, with 2-phase the most abundant. Calcite, nahcolite, burbankite and barite were found in the inclusions. Decrepitation of inclusions occurred at around 200?C before homogenisation but melting temperature data indicate that the inclusions contain relatively pure CO2. A minimum salinity of around 24 wt.% NaCl equivalent was determined. Among the trace elements in whole rock analyses, enrichment in Ba, Mo, Nb, Pb, Sr, Th and Y and depletion in Co, Hf and V are common to carbonatite and fenite but enrichment in carbonatitic type elements (Ba, Nb, Sr, Th, Y, and REE) generally increases towards the inner parts of the aureole. A schematic model contains multiple fluid events, related to first and second boiling of the magma, accompanying intrusion of the carbonatites at Chilwa Island, each contributing to the mineralogy and chemistry of the fenite. The presence of distinct RE mineral micro-assemblages in fenite at some distance from carbonatite could be developed as an exploration indicator of REE enrichment.
DS201812-2803
2018
Doyle, M.Perspectives on diamond exploration and evaluation strategies.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazilvaluation
DS201812-2804
2018
Driscol, P.What goes on deep inside Earth's magnetic dynamo?dtm.carnegiescience.edu, 6p. PdfMantlegeodynamics

Abstract: Earth's global magnetic field shields us from the dangers of space, including harmful levels of Solar radiation. This shield is one of the major reasons why life has survived on Earth, and it all starts in the core, where the geomagnetic field is generated by the turbulent motion of liquid iron deep inside the planet. It's the so-called geodynamo. Scientists like DTM's Peter Driscoll devote their career to understanding the nature of such planetary dynamics. In 2016, Driscoll's research suggested that in ancient times Earth may have been significantly different, with prolonged periods of weak field intensity and strange multipolar geometry with many poles in contrast to the modern north-and-south pole orientation. Now, in a recent paper co-authored with DTM's Cian Wilson, Driscoll finds that geologic evidence for such a complex magnetic field will be very difficult to identify. In preparation for his Neighborhood Lecture on November 8, 2018, Driscoll answers some questions about his latest research and why studying the geodynamo is critical to understanding the history of our planet.
DS201809-2016
2018
Duan, Yunfei, Sun, Ningyu, Wang, Siheng, Li, Xinyang, Guo, Xuan, Ni.Phase stability and thermal equation of state of delta -AIOOH: implication for water transportation in the deep lower mantle.Earth and Planetary Science Letters, Vol. 494, 1, pp. 92-98.Mantlewater

Abstract: In this study, we present new experimental constraints on the phase stability and thermal equation of state of an important hydrous phase, ?-AlOOH, using synchrotron X-ray diffraction up to 142 GPa and 2500 K. Our experimental results have shown that ?-AlOOH remains stable at the whole mantle pressure-temperature conditions above the D? layer yet will decompose at the core-mantle boundary because of a dramatic increase in temperature from the silicate mantle to the metallic outer core. At the bottom transition zone and top lower mantle, the formation of ?-AlOOH by the decomposition of phase Egg is associated with a ?2.1-2.5% increase in density (?) and a ?19.7-20.4% increase in bulk sound velocity (V?). The increase in ? across the phase Egg to ?-AlOOH phase transition can facilitate the subduction of ?-AlOOH to the lower mantle. Compared to major lower-mantle phases, ?-AlOOH has the lowest ? but greatest V?, leading to an anomalous low ? /V? ratio which can help to identify the potential presence of ?-AlOOH in the region. More importantly, water released from the breakdown of ?-AlOOH at the core-mantle boundary could lower the solidus of the pyrolitic mantle to cause partial melting and/or react with Fe in the region to form the low-velocity FeO2Hx phase. The presence of partial melting and/or the accumulation of FeO2Hx phase at the CMB could be the cause for the ultra-low velocity zone. ?-AlOOH is thus an important phase to transport water to the lowermost mantle and helps to understand the origin of the ultra-low velocity zone.
DS201801-0012
2017
Duraiswami, R.A.Textural evidences of late stage carbonate dissolution precipitation and stable isotope exchange re-equilibration in the Kangankunde carbonatite complex, Malawi.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 39-40.Africa, Malawideposit - Kangankunde

Abstract: The Kangankunde carbonatite complex, southern Malawi is an eroded remnant of a carbonatite depocentre belonging to the Lower Cretaceous Chilwa Alkaline Province (Garson and Campbell-Smith, 1965; Karmalkar et al., 2010). The carbonatite complex consists of fenites, carbonated agglomeratic breccias and ankeritic-ferron dolomite carbonatite with sporadic patches of REE minerals. Coarse pegmatitic siderite and ankeritic carbonatite hosts exotic cavities and vugs that contain RE minerals like monazite, synchysite, bastnasite, and florencite-goyazite along with barite and strontianite. Bright green monazite occurs with thick quartz veins and as disseminations within host carbonatites (Garson and Campbell-Smith, 1965; Holt, 1965). Texturally, the host carbonatite exhibits euhedral to subhedral rhombohedra of ankerite-calcite and dolomite set in a fine groundmass. However samples close to mineralized zones show streaky textures, streaming effects and patterns that resemble remobilization and fluidization. Textural evidences such as presence of pseudomorphs containing the REE mineral assemblage, veinlets and drusy cavities indicate that REE mineralization replaced earlier formed carbonates (Wall et al. 1994). SEM micromorphology of such carbonatites show several dissolution-precipitation features indicating that there was a pervasive fluid interaction with the host subsequent to cooling and crystallization. Within cavities and vugs, the precipitation is closely associated with monazite veins and formation of minerals like collinsite, synchysite and rare aragonite (Duraiswami and Shaikh, 2010). Carbon and oxygen isotope ratios were determined on 8 bulk carbonatite powders from Kangankunde using Thermo Fisher Scientific GasBench II, equipped with autosampler (CTC Analytics AG, Zwingen, Switzerland), and coupled to a Delta Plus XP Mass Spectrometer at NGRI, Hyderabad. International Standards NBS-19-1 and NBS-18-1 plus internal standards were used. The internal precision (1s) measured for raw d18O and d13C was 0.04–0.08‰ and 0.03 to 0.06 respectively. The ?13C VS V-PDB show restricted range (-0.31 to -2.76) but ?18O VS V-SMOW values vary widely (8.22 to 24.5). The samples analysed in the present study plot outside the Primary Igneous Carbonatite field (Demény et al., 2004) and are related either to carbo-hydrothermal fluids or alteration of dolomite by a later, cooling, deuteric fluid (Fendley et al., 2017). This study provides conclusive textural evidences (pseudomorphic replacements, atolls, iron-oxide exsolution fringes from dolomite/ankerite, coloform banding, secondary veinlets, etc.) to supports geochemical and stable isotopic inferences about the role of late stage hydrothermal fluids and subsequent alterations in the Kangankunde carbonatite complex (Wall and Mariano, 1996, Wall et al., 1994, Doroshkevich et al., 2009, Fendley et al., 2017).
DS201806-1221
2018
Eaton-Magana, S.Five CVD synthetics greater than three carats: quality factorsGems & Gemology, Vol. 54, 1, p. 63.Technologysynthetics
DS201809-2017
2018
Eaton-Magana, S., Breeding, C.M., Shigley, J.E.Natural color blue, gray, and violet diamonds: allure of the deep.Gems & Gemology, Vol. 54, 2, pp. 112-131.Africa, South Africa, Australiadiamond - colour

Abstract: Natural-color blue diamonds are among the rarest and most valuable gemstones. Gray and violet diamonds are also included here, as these diamonds can coexist on a color continuum with blue diamonds. More so than most other fancy colors, many diamonds in this color range are sourced from specific locations-the Cullinan mine in South Africa and the Argyle mine in Australia. Although blue color is often associated with boron impurities, the color of diamonds in this range (including gray and violet) also originates from simple structural defects produced by radiation exposure or from more complex defects involving hydrogen. These different mechanisms can be characterized by absorption and luminescence spectroscopy. A fourth mechanism-micro-inclusions of grayish clouds or tiny graphite particles in gray diamonds-can be distinguished through microscopy. In this article, we summarize prior research as well as collected data such as color and carat weight on more than 15,000 naturally colored blue/gray/violet diamonds from the GIA database (along with an analysis of spectroscopic data on a subset of 500 randomly selected samples) to provide an unprecedented description of these beautiful gemstones.
DS201802-0232
2017
Ebinger, C.J., Keir, D., Bastow, I.D., Whaler, K., Hammond, J.O.S., Miller, A.A., Tiberi, M.S., Hautot, S.Crustal structure of active deformation zones in Africa: implications for global crustal processes.Tectonics, Vol. 36, 10.1002/2017TC004526Africatectonics

Abstract: The Cenozoic East African rift (EAR), Cameroon Volcanic Line (CVL), and Atlas Mountains formed on the slow-moving African continent, which last experienced orogeny during the Pan-African. We synthesize primarily geophysical data to evaluate the role of magmatism in shaping Africa's crust. In young magmatic rift zones, melt and volatiles migrate from the asthenosphere to gas-rich magma reservoirs at the Moho, altering crustal composition and reducing strength. Within the southernmost Eastern rift, the crust comprises ~20% new magmatic material ponded in the lower crust and intruded as sills and dikes at shallower depths. In the Main Ethiopian Rift, intrusions comprise 30% of the crust below axial zones of dike-dominated extension. In the incipient rupture zones of the Afar rift, magma intrusions fed from crustal magma chambers beneath segment centers create new columns of mafic crust, as along slow-spreading ridges. Our comparisons suggest that transitional crust, including seaward dipping sequences, is created as progressively smaller screens of continental crust are heated and weakened by magma intrusion into 15-20 km thick crust. In the 30 Ma Recent CVL, which lacks a hot spot age progression, extensional forces are small, inhibiting the creation and rise of magma into the crust. In the Atlas orogen, localized magmatism follows the strike of the Atlas Mountains from the Canary Islands hot spot toward the Alboran Sea. CVL and Atlas magmatism has had minimal impact on crustal structure. Our syntheses show that magma and volatiles are migrating from the asthenosphere through the plates, modifying rheology, and contributing significantly to global carbon and water fluxes.
DS201808-1742
2018
Edahbi, M., Plante, B., Benzaazoua, M., Kormos, L., Pelletier, M.Rare earth elements ( La, Ce, Pr, Nd, and Sm) from a carbonatite deposit: mineralogical characterization and geochemical behavior. MontvielMinerals, Vol. 8, pp. 55-74.Canada, Quebeccarbonatite

Abstract: Geochemical characterization including mineralogical measurements and kinetic testing was completed on samples from the Montviel carbonatite deposit, located in Quebec (Canada). Three main lithological units representing both waste and ore grades were sampled from drill core. A rare earth element (REE) concentrate was produced through a combination of gravity and magnetic separation. All samples were characterized using different mineralogical techniques (i.e., quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN), X-ray diffraction (XRD), and scanning electron microscopy with X-ray microanalysis (SEM-EDS)) in order to quantify modal mineralogy, liberation, REE deportment and composition of REE-bearing phases. The REE concentrate was then submitted for kinetic testing (weathering cell) in order to investigate the REE leaching potential. The mineralogical results indicate that: (i) the main REE-bearing minerals in all samples are burbankite, kukharenkoite-Ce, monazite, and apatite; (ii) the samples are dominated by REE-free carbonates (i.e., calcite, ankerite, and siderite); and (iii) LREE is more abundant than HREE. Grades of REE minerals, sulfides and oxides are richer in the concentrate than in the host lithologies. The geochemical test results show that low concentrations of light REE are leached under kinetic testing conditions (8.8-139.6 ?g/L total light REE). These results are explained by a low reactivity of the REE-bearing carbonates in the kinetic testing conditions, low amounts of REE in solids, and by precipitation of secondary REE minerals.
DS201805-0944
2018
Eeken, T., Goes, S., Pedersen, H.A., Arndt, N.T., Bouilhol, P.Seismic evidence for depth dependent metasomatism in cratons.Earth Planetary Science Letters, Vol. 491, pp. 148-159.Africa, Australia, Canada, Europegeothermometry

Abstract: The long-term stability of cratons has been attributed to low temperatures and depletion in iron and water, which decrease density and increase viscosity. However, steady-state thermal models based on heat flow and xenolith constraints systematically overpredict the seismic velocity-depth gradients in cratonic lithospheric mantle. Here we invert for the 1-D thermal structure and a depth distribution of metasomatic minerals that fit average Rayleigh-wave dispersion curves for the Archean Kaapvaal, Yilgarn and Slave cratons and the Proterozoic Baltic Shield below Finland. To match the seismic profiles, we need a significant amount of hydrous and/or carbonate minerals in the shallow lithospheric mantle, starting between the Moho and 70 km depth and extending down to at least 100-150 km. The metasomatic component can consist of 0.5-1 wt% water bound in amphibole, antigorite and chlorite, ?0.2 wt% water plus potassium to form phlogopite, or ?5 wt% CO2 plus Ca for carbonate, or a combination of these. Lithospheric temperatures that fit the seismic data are consistent with heat flow constraints, but most are lower than those inferred from xenolith geothermobarometry. The dispersion data require differences in Moho heat flux between individual cratons, and sublithospheric mantle temperatures that are 100-200?°C less beneath Yilgarn, Slave and Finland than beneath Kaapvaal. Significant upward-increasing metasomatism by water and CO2-rich fluids is not only a plausible mechanism to explain the average seismic structure of cratonic lithosphere but such metasomatism may also lead to the formation of mid-lithospheric discontinuities and would contribute to the positive chemical buoyancy of cratonic roots.
DS201811-2568
2018
Eguchi, J., Dasgupta, R.A CO2 solubility model for silicate melts from fluid saturation to graphite or diamond saturation.Chemical Geology, Vol. 487, 1, pp. 23-38.Mantlediamond genesis

Abstract: A model based on a thermodynamic framework for CO2 concentrations and speciation in natural silicate melts at graphite/diamond-saturated to fluid-saturated conditions is presented. The model is simultaneously calibrated with graphite-saturated and fluid-saturated conditions allowing for consistent model predictions across the CCO buffer. The model was calibrated using water-poor (?1?wt% H2O) silicate melts from graphite- to CO2-fluid-saturation over a range of pressure (P?=?0.05-3?GPa), temperature (T?=?950-1600?°C), composition (foidite-rhyolite; NBO?=?0.02-0.92; wt% SiO2?~?39-77, TiO2?~?0.1-5.8, Al2O3?~?7.5-18, FeO?~?0.2-24 MgO?~?0.1-24, CaO?~?0.3-14, Na2O~1-5, K2O?~?0-6), and fO2 (~QFM +1.5 to ~QFM ?6). The model can predict CO2 concentrations for a wide range of silicate melt compositions from ultramafic to rhyolitic compositions, i.e., melts that dissolve carbon only as carbonate anions CO32- and those that dissolve carbon both as CO32- and as molecular CO2mol as a function of pressure, temperature, and oxygen fugacity. The model also does a reasonable job in capturing CO2 solubility in hydrous silicate melts with ?2-3?wt% H2O. New CO2 solubility experiments at pressures >3?GPa suggest that the newly developed CO2 solubility model can be satisfactorily extrapolated to ~4-5?GPa. Above 5?GPa the model poorly reproduces experimental data, likely owing to structural change in silicate melt at pressures above 5?GPa. An Excel spreadsheet and a Matlab function are provided as online supplementary materials for implementing the new CO2 solubility model presented here.
DS201811-2569
2018
Ekimov, E.A., Sidorov, V.A., Maslakov, K.I., Sirotinkin, B.P., Krotova, M.D., Pleskov, Yu.V.Influence of growth medium composition on the incorporation of boron in HPHT diamond.Diamond & Related Materials, Vol. 89, pp. 101-107.Mantleboron

Abstract: Influence of growth medium composition on the efficiency of boron doping of carbonado-like diamond at 8-9 GPa was studied by diluting the C-B growth system with metallic solvents of carbon, Co and Ni. Addition of these metals to the original system leads to a decrease in the synthesis temperature, degree of doping with boron and suppression of superconductivity in diamond. According to XPS analysis, content of substitutional boron is equal to 0.07, 0.16 and 0.39 at.% in diamonds obtained in Co-C-B, Ni-C-B and C-B growth systems, respectively. Metallic behavior at normal temperatures and superconductivity below 5 K in diamond, synthesized in C-B system, change to semiconducting character of conductivity down to 2 K in diamonds obtained in the diluted systems; a faint hint of superconducting transition at 2 K was detected in the case of diamond grown in Ni-C-B system. By comparing phase composition of the inclusions and the doping efficiency of the diamonds, we are able to suggest that high chemical affinity of boron to boride-forming metals hinders the boron doping of diamond. The heavily boron-doped carbonado-like diamond compacts demonstrate high electrochemical activity in aqueous solutions and can be used as miniature electrodes in electrosynthesis and electroanalysis.
DS201812-2805
2018
Ekimov, E.A., Sidorov, V.A., Maslakov, K.I., Sirotinkin, B.P., Krotova, M.D., Pleskov, Yu.V.Influence of growth medium composition on the incorporation of boron in HPHT diamond.Diamond & Related Materials, Vol. 89, pp. 101-107.Mantlecarbonado
DS201809-2018
2018
Elazar, O., Kessel, R., Huang, J-X., Navon, O.Silicic fluid Micro inclusions in a metasomatised eclogite from Roberts Victor.Goldschmidt Conference, 1p. AbstractAfrica, South AfricaDeposit - Roberts Victor

Abstract: We report preliminary results of a systematic search for fluid/melt microinclusions in mantle minerals. “Dusty” garnets from xenolith XRV6 [1], a heavily metasomatised Type I eclogite from Roberts Victor mine, SA, carry many microinclusions (<1 ?m). FTIR analyses of "dusty" zones indicate the presence of molecular water in the inclusions and hydroxyl groups in the garnet. EPMA analysis of 136 microinclusions constrains the bulk composition of the microinclusions. Compared to the host garnet, they are enriched in TiO2, FeO, CaO, Na2O and K2O and depleted in Al2O3 and MgO. The silica contents seem to be similar to that of the host garnet. Figure 1: a. Backscatter image of the microinclusions in XRV6 garnet. b. K2O vs. MgO of the clear garnet (red) and the microinclusions (+ their surrounding garnet, blue). Most of the elements form compositional mixing arrays of microinclusion+garnet (Fig. 1b). The arrays trend away from the compositions of large melt pools or secondary minerals found in the xenolith. They point towards the array of silicic to low-Mg carbonatitic high density fluids (HDFs) trapped in diamonds, indicating the role of such fluids in mantle metasomatism.
DS201812-2806
2018
Elliott, B.Diamond potential of the Dehcho region. Horn Plateau2018 Yellowknife Geoscience Forum , p. 104. abstractCanada, Northwest Territoriesgeochemistry

Abstract: Our knowledge of the diamond potential in the Dehcho region has progressed significantly in the past decade. We now recognize that the central Dehcho represents a world class diamond exploration district. Continued scientific and industry work in the area have clearly shown that the diamond potential of this area may be of the same magnitude as the Lac de Gras region, which hosts active diamond mines. The evidence for high diamond potential in the Dehcho, includes abundant Kimberlite Indicator Minerals (KIM) from stream sediment sampling work, a diamond found in a stream sediment sample, 39 drilled kimberlites, some of which are diamondiferous, and numerous untested kimberlite-like geophysical anomalies from both government and industry data. Recent work at the University of Alberta has shown that deep Earth conditions in the area of the Horn Plateau may be as favorable for diamond generation and preservation as the Lac de Gras region and that there that there may be multiple generations of kimberlites present in the region. Given the relative paucity of exploration work and geoscience data in the Dehcho region, the available evidence is strongly suggestive of the possibility of the presence of diamond deposits.
DS201802-0233
2018
Elliott, H.A.L., Wall, F., Chakmouradian, A.R., Siegfried, P.R., Dahlgren, S., Weatherley, S., Finch, A.A., Marks, M.A.W., Dowman, E., Deady, E.Fenites associated with carbonatite complexes: a review.Ore Geology Reviews, Vol. 92, pp. 38-59.Globalcarbonatites

Abstract: Carbonatites and alkaline-silicate rocks are the most important sources of rare earth elements (REE) and niobium (Nb), both of which are metals imperative to technological advancement and associated with high risks of supply interruption. Cooling and crystallizing carbonatitic and alkaline melts expel multiple pulses of alkali-rich aqueous fluids which metasomatize the surrounding country rocks, forming fenites during a process called fenitization. These alkalis and volatiles are original constituents of the magma that are not recorded in the carbonatite rock, and therefore fenites should not be dismissed during the description of a carbonatite system. This paper reviews the existing literature, focusing on 17 worldwide carbonatite complexes whose attributes are used to discuss the main features and processes of fenitization. Although many attempts have been made in the literature to categorize and name fenites, it is recommended that the IUGS metamorphic nomenclature be used to describe predominant mineralogy and textures. Complexing anions greatly enhance the solubility of REE and Nb in these fenitizing fluids, mobilizing them into the surrounding country rock, and precipitating REE- and Nb-enriched micro-mineral assemblages. As such, fenites have significant potential to be used as an exploration tool to find mineralized intrusions in a similar way alteration patterns are used in other ore systems, such as porphyry copper deposits. Strong trends have been identified between the presence of more complex veining textures, mineralogy and brecciation in fenites with intermediate stage Nb-enriched and later stage REE-enriched magmas. However, compiling this evidence has also highlighted large gaps in the literature relating to fenitization. These need to be addressed before fenite can be used as a comprehensive and effective exploration tool.
DS201806-1222
2018
Engi, M., Giuntoli, F., Lanari, P., Burn, M., Kunz, B., Bouvier, A.S.Pervasive eclogization due to brittle deformation and rehydration of subducted basement: effects on continental recycling?Geochemistry, Geophysics, Geosystems, Vol. 19, 3, pp. 865-881.Mantlesubduction

Abstract: The buoyancy of continental crust opposes its subduction to mantle depths, except where mineral reactions substantially increase rock density. Sluggish kinetics limit such densification, especially in dry rocks, unless deformation and hydrous fluids intervene. Here we document how hydrous fluids in the subduction channel invaded lower crustal granulites at 50-60 km depth through a dense network of probably seismically induced fractures. We combine analyses of textures and mineral composition with thermodynamic modeling to reconstruct repeated stages of interaction, with pulses of high-pressure (HP) fluid at 650-6708C, rehydrating the initially dry rocks to micaschists. SIMS oxygen isotopic data of quartz indicate fluids of crustal composition. HP growth rims in allanite and zircon show uniform U-Th-Pb ages of 65 Ma and indicate that hydration occurred during subduction, at eclogite facies conditions. Based on this case study in the Sesia Zone (Western Italian Alps), we conclude that continental crust, and in particular deep basement fragments, during subduction can behave as substantial fluid sinks, not sources. Density modeling indicates a bifurcation in continental recycling: Chiefly mafic crust, once it is eclogitized to >60%, are prone to end up in a subduction graveyard, such as is tomographically evident beneath the Alps at 550 km depth. By contrast, dominantly felsic HP fragments and mafic granulites remain positively buoyant and tend be incorporated into an orogen and be exhumed with it. Felsic and intermediate lithotypes remain positively buoyant even where deformation and fluid percolation allowed them to equilibrate at HP.
DS201803-0446
2017
Engi, M., Lanari, P., Jokn, M.J.Significant ages - an introduction to petrochronology.Reviews in Mineralogy & Geochemistry, Vol. 83, Chap. 1, pp. 1-12.Technologygeochronology

Abstract: Question: Why "Petrochronology"? Why add another term to an already cluttered scientific lexicon? Answer: Because petrologists and geochronologists need a term that describes the unique, distinctive way in which they apply geochronology to the study of igneous and metamorphic processes. Other terms just won’t do.
DS201809-2019
2012
Eppelbaum, L.V.Mineral deposits of Israel.Chapter 1, Researchgate, 45p. PdfEurope, Israelgemstones

Abstract: For many years, Israel was considered to be an unlikely area for discovering commercially exploitable minerals. Studies only reported phosphorites, which are processed at the Dead Sea Works into plant fertilizer, building materials and chemicals for the cosmetic industry. However, a contemporary look at Israel’s economic mineral deposits suggests that this view needs substantial revision. This chapter provides an overview of all the economic deposits in Israel and then presents the second author's investigations in more detail. Aside from estimates of the industrial value of these deposits, methods for further probes are provided. Examples of the ways in which descriptions of geological formations, mineralogical analyses and geophysical methods can be applied to estimates of economic value and types of investigations are discussed along with the specific physical-geological profiles of the region. Since water reserves are crucially related to mineral rich deposits, new work around the Sea of Galilee is discussed.
DS201810-2309
2017
Eppelbaum, L.V.Satellite gravimetry ( BIG DATA): a powerful tool for regional tectonic examination and reconstructions.IN: Horizons in Earth Science Research, Chapter 4, pp. 115-147. researchgateMantlegeophysics - gravity

Abstract: Satellite gravimetry is recognized now as a powerful and reliable tool for regional tectono-geodynamic zonation. Regular observation grid and comparatively high accuracy (1-1.5 mGal) of satellite gravity data retracked to the Earth’s surface (together with other kinds of gravity observations) makes these data indispensable instrument for examination of deep geological-geophysical features (mainly, Earth crust and upper mantle). Accomplished satellite derived gravity measurements (tens and hundreds of millions of observations) may be considered as ‘big data’ because of their volume and variety. For comprehensive analysis of these data, different methodologies can be applied: entropial and information transformations, computing of various derivatives, coherence features and multistatistical characteristics, inverse probability and advanced downward continuation, etc. Effectiveness of the satellite regional gravity analysis is demonstrated on numerous examples from the Eastern Mediterranean, South Caspian Sea and African-Arabian region. It was proposed that increasing satellite derived gravity data accuracy during nearest five years will allow to extend the circle of solvable physical-geological problems.
DS201810-2310
2017
Eppelbaum, L.V., Katz, Y., Klokocnik, J., Kostelecky, J., Zheludev, V., Ben-Avraham, Z.Tectonic insights into the Arabian African region inferred from a comprehensive examination of satellite gravity big data.Global and Planetary Change, doi.org/j.gloplacha.2017.10.011 24p.Africageodynamics

Abstract: Modern satellite gravimetry is now considered one of the most powerful and effective instrument for regional tectono-geodynamic zonation. Satellite gravity observations clearly fit the definition of 'big data' because of their volume and variety. The Arabian - NE African region discussed in this article has intricate geodynamic features including active rift zones, high seismic activity and collision processes, a rich structural pattern made up of the mosaic block system of continental and oceanic crusts of different ages, as well as several of the greatest gravity anomalies and complex magnetic anomaly mosaics. This region also has the world's main hydrocarbon resources and a vast number of other economic deposits. A comprehensive analysis of these satellite derived gravity data were used to construct a series of new maps that localize the key properties of the lithosphere of the region. A careful examination of numerous geological sources and their combined inspection with satellite derived gravity and other geophysical data resulted in this new integrated tectonic map of the Arabian-African region. An analysis of the series of gravity map transformations and certain geological indicators document the significant geodynamic features of the region.
DS201811-2570
2018
Ernst, R.E., Davies, D.R., Jowitt, S.M., Campbell, I.H.When do mantle plumes destroy diamonds? ( review )Earth and Planetary Science Letters, Vol. 502, pp. 244-252.Russia, Canada, Ontario, Attawapiskatkimberlite, core boundary

Abstract: Mantle plumes are hot buoyant upwellings that rise from Earth's core-mantle-boundary to its surface where they can produce large igneous provinces (LIPs) and volcanic tracks, such as the Siberian Traps and the Hawaiian Emperor chain, respectively. We show that flattened mantle plume heads, which can have radii of >1200 km in the uppermost mantle, can heat the overlying lithospheric mantle to temperatures above the diamond stability field. As a consequence, they can destroy diamonds within the roots of Archean cratons, the principal source of diamonds in kimberlites. We quantitatively demonstrate that there is a ‘sour spot’ for this effect that occurs when lithospheric thicknesses are 165-185 km and the plume has a temperature of >150?°C above background mantle. Our model explains why the kimberlites associated with the 370 Ma Yakutsk-Vilyui plume in the Siberian craton are diamondiferous whilst those associated with the younger 250 Ma Siberian Traps plume are barren. We also show that the time required to restore the pre-plume thermal structure of the lithosphere is ca. 75-120 Myr, and that destroyed diamonds may regrow once the plume's thermal effect dissipates. The 1100 Ma Kyle Lake and adjacent 180-150 Ma Attawapiskat kimberlites in the southern Superior craton exemplify this, where the older kimberlites are associated with a narrower diamond window (<30 km) in comparison with the ca. 85 km diamond window of the younger Attawapiskat field.
DS201812-2807
2018
Esteve, C., Schaeffer, A.J., Audet, P.Upper mantle structure underlying the diamondiferous Slave craton from teleseismic body-wave tomography.2018 Yellowknife Geoscience Forum , p.104-105. abstractCanada, Northwest Territoriestomography

Abstract: Cratons are, by definition, the most tectonically stable and oldest parts of the continental lithosphere on Earth. The Archean Slave craton is located in the northwestern part of the Canadian Shield. The propensity of diamondiferous kimberlite pipes in the central Slave craton raises many questions regarding their structural environment and source. Here, we provide the most robust teleseismic P and S body wave tomography models over the Slave craton region based on 20,547 P-wave delay times, 6,140 direct S-wave delay times and 3,381 SKS delay times. The P-wave model reveals an alternating pattern of relative positive and negative anomalies over a fine broad scale region within the central Slave craton. Furthermore, the P-wave model revealed two fine structures located in the lithosphere beneath the Lac de Gras kimberlite cluster, with relatively slow anomalies (B - C) that extend from 75 km to 350 km depths with an apparent dip to the north. These relatively slow P- and S-wave anomalies are associated with metasomatised regions within the lithosphere. The S-wave model displays a slow S-wave anomaly lying from 300 km depth to the transition zone beneath the central Slave craton. This anomaly is located beneath the Lac de Gras kimberlite cluster. We suggest that this anomaly is not the cause of the actual kimberlites at the surface since last eruption occurred 75-45 Ma ago but may be related to a potential kimberlite magma ascent in the asthenosphere.
DS201812-2808
2018
Farahbakhsh, E., Chandra, R., Olierook, H.K.H., Scalzo, R., Clark, C., Reddy, S.M., Muller, R.D.Computer vision based framework for extracting geological lineaments from optical remote sensing data.researchgate.com, arXiv:1810.02320v1 17p. Oct 4.Globallineaments

Abstract: The extraction of geological lineaments from digital satellite data is a fundamental application in remote sensing. The location of geological lineaments such as faults and dykes are of interest for a range of applications, particularly because of their association with hydrothermal mineralization. Although a wide range of applications have utilized computer vision techniques, a standard workflow for application of these techniques to mineral exploration is lacking. We present a framework for extracting geological lineaments using computer vision techniques which is a combination of edge detection and line extraction algorithms for extracting geological lineaments using optical remote sensing data. It features ancillary computer vision techniques for reducing data dimensionality, removing noise and enhancing the expression of lineaments. We test the proposed framework on Landsat 8 data of a mineral-rich portion of the Gascoyne Province in Western Australia using different dimension reduction techniques and convolutional filters. To validate the results, the extracted lineaments are compared to our manual photointerpretation and geologically mapped structures by the Geological Survey of Western Australia (GSWA). The results show that the best correlation between our extracted geological lineaments and the GSWA geological lineament map is achieved by applying a minimum noise fraction transformation and a Laplacian filter. Application of a directional filter instead shows a stronger correlation with the output of our manual photointerpretation and known sites of hydrothermal mineralization. Hence, our framework using either filter can be used for mineral prospectivity mapping in other regions where faults are exposed and observable in optical remote sensing data.
DS201807-1489
2018
Farr, H., Phillips, D., Maas, R., de Wit, M.Petrography, Sr isotope geochemistry and geochronology of the Nxau-Nxau kimberlites, north west Botswana.Mineralogy and Petrology, June 14, DOI:10.1007/ s00710-018- 0593-8, 14p.Africa, Botswanadeposit - Nxau

Abstract: The Nxau Nxau kimberlites in northwest Botswana belong to the Xaudum kimberlite province that also includes the Sikereti, Kaudom and Gura kimberlite clusters in north-east Namibia. The Nxau Nxau kimberlites lie on the southernmost extension of the Congo Craton, which incorporates part of the Damara Orogenic Belt on its margin. The Xaudum kimberlite province is geographically isolated from other known clusters but occurs within the limits of the NW-SE oriented, Karoo-aged Okavango Dyke Swarm and near NE-SW faults interpreted as the early stages of the East African Rift System. Petrographic, geochronological and isotopic studies were undertaken to characterise the nature of these kimberlites and the timing of their emplacement. The Nxau Nxau kimberlites exhibit groundmass textures, mineral phases and Sr-isotope compositions (87Sr/86Sri of 0.7036?±?0.0002; 2?) that are characteristic of archetypal (Group I) kimberlites. U-Pb perovskite, 40Ar/39Ar phlogopite and Rb-Sr phlogopite ages indicate that the kimberlites were emplaced in the Cretaceous, with perovskite from four samples yielding a preferred weighted average U-Pb age of 84?±?4 Ma (2?). This age is typical of many kimberlites in southern Africa, indicating that the Xaudum occurrences form part of this widespread Late Cretaceous kimberlite magmatic province. This time marks a significant period of tectonic stress reorganisation that could have provided the trigger for kimberlite magmatism. In this regard, the Nxau Nxau kimberlites may form part of a NE-SW oriented trend such as the Lucapa corridor, with implications for further undiscovered kimberlites along this corridor.
DS201810-2311
2018
Faryad, S.W., Jedlicka, R., Hauzenberger, C., Racek, M.High pressure crystallization vs. recrystallization origin of garnet pyroxenite-eclogite within subduction related lithologies. Bohemian MassifMineralogy and Petrology, Vol. 112, 5, pp. 603-616.Europe, Austriasubduction

Abstract: Mafic layers displaying transition between clinopyroxenite and eclogite within peridotite from felsic granulite in the Bohemian Massif (Lower Austria) have been investigated. The mafic-ultramafic bodies shared a common granulite facies metamorphism with its hosting felsic rocks, but they still preserve evidence of eclogite facies metamorphism. The selected mafic layer for this study is represented by garnet with omphacite in the core of coarse-grained clinopyroxene, while fine-grained clinopyroxene in the matrix is diopside. In addition, garnet contains inclusions of omphacite, alkali feldspars, hydrous and other phases with halogens and/or CO2. Textural relations along with compositional zoning in garnet from the clinopyroxenite-eclogite layers favour solid-state recrystallization of the precursor minerals in the inclusions and formation of garnet and omphacite during subduction. Textures and major and trace element distribution in garnet indicate two stages of garnet growth that record eclogite facies and subsequent granulite facies overprint. The possible model explaining the textural and compositional changes of minerals is that the granulite facies overprint occurred after formation and exhumation of the eclogite facies rocks.
DS201804-0687
2018
Fedortchouk, Y.Dissolution features on diamond surfaces: what can they tell us?Vancouver Kimberlite Cluster talk, 1p. AbstractMantlediamond morphology

Abstract: Diamonds are valued for their brilliance achieved by faceting of diamond crystals into the cut shapes that most efficiently reflect the light. However, diamond cut removes the long history of diamond growth and dissolution recorded in the surface features on rough diamonds. Growth features on diamond surfaces reflect the conditions of diamond-forming events in the mantle but are rarely preserved on natural diamonds due to their partial dissolution. The majority of natural diamonds show surface features resulted from dissolution both in the mantle source due to metasomatism and in the kimberlite magma during the ascent to the Earth’s surfaces. Mantle-derived resorption features can be preserved on diamonds enclosed in mantle xenoliths and protected from the interaction with the kimberlite magma during the ascent. The diamonds exposed to the reaction with the kimberlite magma develop kimberlite-induced dissolution features. This talk will discuss the large diversity of surface dissolution features on diamonds recovered from kimberlites. It will examine how the shape, size, and orientation of certain features can be used to deduce the conditions of kimberlite emplacement using the results of diamond dissolution experiments and observations on natural diamonds. The talk will discuss what we can learn about the behavior of volatiles and exsolution of fluid in kimberlite magma and how this supports or contradicts to what we know about kimberlitic fluid. The results of experiments conducted at mantle conditions are used to examine the kind of dissolution surfaces developed by diamonds during mantle metasomatism in fluids, in aqueous silicate melts and in carbonatitic melts. Comparison to the features of natural diamonds will assess what media dissolves diamond in the mantle, the prevalent diamond-destructive metasomatic agent, and will try to explain the repetitive cycles of growth and dissolution events recorded in single diamond crystals.
DS201809-2020
2018
Fedortchouk, Y., Chinn, I., Liebske, C., McCammon, C.Mantle metasomatism as recorded in diamond dissolution features.Goldschmidt Conference, 1p. AbstractAfrica, Botswanadeposit - Orapa

Abstract: Roots of continental cratons keep a long record of multiple metasomatic events, but their trace is complicated due to the mixed signals left by these events in the composition of mantle silicate minerals. Simple composition helps diamonds to provide a more robust record of the latest metasomatic events which they witnessed. Growth and dissolution features on the diamond surface are sensitive to the composition of the reacting media. In this study we use mantle-derived resorption features on natural diamonds to examine the nature of metasomatic events in diamondiferous mantle lithologies. We use experiments at mantle conditions to examine how the composition of fluids and melts affect diamond resorption. We then compare these results to the features of natural diamonds to determine which of the tested compositions could have acted as metasomatic agents in Earth’s cratonic roots. Diamond dissolution experiments conducted at 6 GPa, 1200 - 1500oC using synthetic MgO-CaO-SiO2-CO2-H2O system examined the effect of CHO fluid, silica-saturated CHO fluid, aqueous and “dry” silica-carbonate and carbonate melts. Results show that the main control of diamond resorption morphology is the state of the reacting media: fluid vs. melt. We compared the experimental results to diamonds with mantle-derived resorption features from two kimberlites from the Orapa kimberlite cluster (Botswana). We identified twelve mantle-derived resorption types, none of which resembled the products of resorption in fluids. Most of the observed resorption types could be produced by dissolution in mantle melts with variable proportions of carbonate and silicate components and in the range of temperatures. The most abundant resorption type resembles the product of diamond dissolution in carbonate melts at temperatures above 1450oC. Our results suggest that fluid-metasomatism is not destructive for diamonds while melt-metasomatism is. The lower hydrous carbonated solidus of lherzolite compared to harzburgite can result in the shift the process from diamond growth in fluids to diamond dissolution in melts due to metasomatic transformation of harzburgite into lherzolite.
DS201810-2312
2009
Fedortchouk, Y., Matveev, S.Surface features on diamonds and water content of olivine from kimberlite as indicators of fluid systems in kimberlite magma. EkatiAtlantic Geology, Vol. 45, p. 28. 1p. AbstractCanada, Northwest Territoriesmagmatism
DS201810-2313
2018
Finkelstein, G.J., Jackson, J.M., Said, A., Alatas, A., Leu, B.M., Sturhahn, W., Toellner, T.S.Strongly anisotropic magnesiowustite in Earth's lower mantle. Journal of Geophysical Research Solid Earth, doi.org/10.1029/ 2017JB015349Mantlecore mantle boundary

Abstract: The juxtaposition of a liquid iron?dominant alloy against a mixture of silicate and oxide minerals at Earth's core?mantle boundary is associated with a wide range of complex seismological features. One category of observed structures is ultralow?velocity zones, which are thought to correspond to either aggregates of partially molten material or solid, iron?enriched assemblages. We measured the phonon dispersion relations of (Mg,Fe) O magnesiowüstite containing 76 mol % FeO, a candidate ultralow?velocity zone phase, at high pressures using high?energy resolution inelastic X?ray scattering. From these measurements, we find that magnesiowüstite becomes strongly elastically anisotropic with increasing pressure, potentially contributing to a significant proportion of seismic anisotropy detected near the base of the mantle.
DS201810-2314
2018
Finkelstein, Y.Breaking diamonds. The Australian Gemmologist, Vol. 26, 9-10, pp. 240-243.Africa, Sierra Leonedeposit - Zimni
DS201801-0013
2017
Fischer, R.A., Campbell, A.J., Ciesla, F.J.Sensitivities of Earth's core and mantle compositions to accretion and differentiation processes.Earth and Planetary Science Letters, Vol. 458, 1, pp. 252-262.Mantlegeochemistry

Abstract: The Earth and other terrestrial planets formed through the accretion of smaller bodies, with their core and mantle compositions primarily set by metal -silicate interactions during accretion. The conditions of these interactions are poorly understood, but could provide insight into the mechanisms of planetary core formation and the composition of Earth's core. Here we present modeling of Earth's core formation, combining results of 100 N-body accretion simulations with high pressure -temperature metal -silicate partitioning experiments. We explored how various aspects of accretion and core formation influence the resulting core and mantle chemistry: depth of equilibration, amounts of metal and silicate that equilibrate, initial distribution of oxidation states in the disk, temperature distribution in the planet, and target:impactor ratio of equilibrating silicate. Virtually all sets of model parameters that are able to reproduce the Earth's mantle composition result in at least several weight percent of both silicon and oxygen in the core, with more silicon than oxygen. This implies that the core's light element budget may be dominated by these elements, and is consistent with ?1 -2 wt% of other light elements. Reproducing geochemical and geophysical constraints requires that Earth formed from reduced materials that equilibrated at temperatures near or slightly above the mantle liquidus during accretion. The results indicate a strong tradeoff between the compositional effects of the depth of equilibration and the amounts of metal and silicate that equilibrate, so these aspects should be targeted in future studies aiming to better understand core formation conditions. Over the range of allowed parameter space, core and mantle compositions are most sensitive to these factors as well as stochastic variations in what the planet accreted as a function of time, so tighter constraints on these parameters will lead to an improved understanding of Earth's core composition.
DS201810-2315
2018
Fitzpayne, A., Giuliani, A., Hergt, J., Phillips, D., Janney, P.New geochemical constraints on the origins of MARID and PIC rocks: implications for mantle metasomatism and mantle -derived potassic magmatism.Lithos, Vol. 318-319, pp. 478-493.Mantlemetasomatism
DS201812-2809
2018
Fitzpayne, A., Giuliani, A., Hergt, J., Phillips, D., Janney, P.New geochemical constraints on the origins of MARID and PIC rocks: implications for mantle metasomatism and mantle derived potassic magmatism. ( kimberlite)Lithos, Vol. 318-319, pp. 478-493.Globallamproites

Abstract: MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside) and PIC (Phlogopite-Ilmenite-Clinopyroxene) rocks are unusual mantle samples entrained by kimberlites and other alkaline volcanic rocks. The formation of MARID rocks remains hotly debated. Although the incompatible element (for example, large ion lithophile element) enrichment in these rocks suggests that they formed by mantle metasomatism, the layered textures of some MARID samples (and MARID veins in composite xenoliths) are more indicative of formation by magmatic processes. MARID lithologies have also been implicated as an important source component in the genesis of intraplate ultramafic potassic magmas (e.g., lamproites, orangeites, ultramafic lamprophyres), due to similarities in their geochemical and isotopic signatures. To determine the origins of MARID and PIC xenoliths and to understand how they relate to alkaline magmatism, this study presents new mineral major and trace element data and bulk-rock reconstructions for 26 MARID and PIC samples from the Kimberley-Barkly West area in South Africa. Similarities between compositions of PIC minerals and corresponding phases in metasomatised mantle peridotites are indicative of PIC formation by pervasive metasomatic alteration of peridotites. MARID genesis remains a complicated issue, with no definitive evidence precluding either the magmatic or metasomatic model. MARID minerals exhibit broad ranges in Mg# (e.g., clinopyroxene Mg# from 82 to 91), which may be indicative of fractionation processes occurring in the MARID-forming fluid/melt. Finally, two quantitative modelling approaches were used to determine the compositions of theoretical melts in equilibrium with MARID rocks. Both models indicate that MARID-derived melts have trace element patterns resembling mantle-derived potassic magma compositions (e.g., lamproites, orangeites, ultramafic lamprophyres), supporting inferences that these magmas may originate from MARID-rich mantle sources.
DS201806-1223
2018
Fitzpayne, A., Giuliani, A., Phillips, D., Wu, N.Kimberlite related metasomatism recorded in Marid and PIC mantle xenoliths. Kimberlites and orangeitesMineralogy and Petrology, in press available, 14p.Africa, South Africadeposit - Bultfontein

Abstract: MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside) and PIC (Phlogopite-Ilmenite-Clinopyroxene) xenoliths are thought to be formed by intense Bprimary^ mantle metasomatism. These rocks also display secondary features, such as cross-cutting veins and geochemical zonation of matrix minerals, which probably reflect latermetasomatic events. To investigate the nature and origin(s) of these secondary features, 28 MARID and PIC xenoliths from southern African kimberlites and orangeites have been studied. MARID-hosted veins contain both carbonate and Ti-rich phases (e.g., titanite, phlogopite), suggesting that they formed by the infiltration of a carbonated silicate melt. Elevated TiO2 contents in MARID matrix mineral rims are spatially associated with carbonate-dominated veins, suggesting a genetic relationship between vein formation and geochemical zonation. Spongy rims around primaryMARID and PIC clinopyroxene are depleted in Na2O andAl2O3 relative to their cores, possibly reflecting mineral dissolution in the xenoliths during ascent and emplacement of the entraining kimberlite. The preservation of compositional differences between primary and secondary phases in MARID and PIC xenoliths indicates that metasomatism occurred shortly before, or broadly coeval with, kimberlite/orangeite magmatism; otherwise, at typical mantle temperatures, such features would have quickly re-equilibrated. Increased Na2O in some mineral rims (e.g., K-richterite) may therefore reflect equilibration with a more Na-enriched primitive kimberlite melt composition than is commonly suggested. Vein-hosted clinopyroxene 87Sr/86Sri (0.70539 ± 0.00079) in one MARID sample is intermediate between primary clinopyroxene in the sample (0.70814 ± 0.00002) and the host Bultfontein kimberlite (0.70432 ± 0.00005), suggesting that vein minerals are derived from interactions between primary MARID phases and kimberlite-related melts/fluids. Sulfur isotope compositions of barite (?34SVCDT = +4.69 ‰) and sulfides (?34SVCDT = ?0.69 ‰) in carbonate veins reflect equilibration at temperatures of 850-900 °C, consistent with sulfurrich melt/fluid infiltration in the lithospheric mantle. In contrast, vein carbonate C-O isotope systematics (?13CVPDB = ?9.18 ‰ ?18OVSMOW = +17.22‰) are not typical of kimberlites or other mantle carbonates (?13CVPDB = ?3 to ?8‰ ?18OVSMOW = 6 to 9 ), and may represent post-emplacement hydrothermal interactions of the cooling kimberlite with crustal fluids. These constraints suggest protracted metasomatism of MARID rocks shortly before and during entrainment by the host kimberlite.
DS201809-2021
2018
Fletcher, A.W., Abdelsalam, M.G., Emishaw, L., Atekwana, E.A., Lao-Davila, D.A., Ismail, A.Lithospheric controls on the rifting of the Tanzanian Craton at the Eyasi Basin, eastern branch of the East African Rift system.Tectonics, Aug 14, doi: 10.1029/2018 TC005065Africa, Tanzaniacraton

Abstract: Continental rifts most often nucleate within orogenic belts. However, some studies in the East African Rift System (EARS) have shown that continental rifts can also develop withincratons. This work investigated the ~1.5 Ma Eyasibasin,which propagates in a WSW direction into the Tanzanian craton. The basin is located where the Eastern Branch of the EARS transitions from a narrow rift (~70 km wide) thewider(~300 km wide) North Tanzanian Divergence. Unlike the rest of the Eastern Branch segments, the Eyasibasindoes not follow the Mozambique orogenic belt located on the eastern margin of the Tanzanian craton. This work generatedlithospheric?scale sections across the basinusing: (1) Digital Elevation Model to map surface rift?related brittle structures; (2) Aeromagnetic data to determine the depth to the Precambrian basement;and (3) World Gravity Model 2012 to estimatecrustal and lithospheric thickness by applying the two?dimensional(2D) radially?averaged power spectral analysis and 2D forward gravity modeling. These cross?sectionsshow that the Eyasibasinnucleates within a previously unidentified suture zone within the Tanzanian cratonand that this suture zone is characterized by thinner lithospherethat can be as thin as ~95 km. This zone ofthinner lithosphere is offset southeastwardfrom the surface expression of the Eyasibasinand might have facilitated the formation of other basins further south. Furthermore, the lithospheric thickness map indicates that the Tanzanian craton is heterogeneous and possibly composed of multiplesmaller cratonic fragments.
DS201807-1490
2018
Fofana, M., Steyn, T.Monitoring the performance of DMS circuits using RhoVol technology.SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 113-126.Africa, South Africadeposit - Venetia
DS201801-0014
2017
Foley, S.F., Fischer, T.P.An essential role for continental rifts and lithosphere in the deep carbon cycle.Nature Geoscience, Vol. 10, 12, pp. 897-902.Mantlecarbon

Abstract: The continental lithosphere is a vast store for carbon. The carbon has been added and reactivated by episodic freezing and re-melting throughout geological history. Carbon remobilization can lead to significant variations in CO2 outgassing and release in the form of magmas from the continental lithosphere over geological timescales. Here we use calculations of continental lithospheric carbon storage, enrichment and remobilization to demonstrate that the role for continental lithosphere and rifts in Earth’s deep carbon budget has been severely underestimated. We estimate that cratonic lithosphere, which formed 2 to 3 billion years ago, originally contained about 0.25 Mt C km -3. A further 14 to 28 Mt C km -3 is added over time from the convecting mantle and about 43 Mt C km -3 is added by plume activity. Re-melting focuses carbon beneath rifts, creating zones with about 150 to 240 Mt C km -3, explaining the well-known association of carbonate-rich magmatic rocks with rifts. Reactivation of these zones can release 28 to 34 Mt of carbon per year for the 40 million year lifetime of a continental rift. During past episodes of supercontinent breakup, the greater abundance of continental rifts could have led to short-term carbon release of at least 142 to 170 Mt of carbon per year, and may have contributed to the high atmospheric CO2 at several times in Earth's history.
DS201804-0688
2017
Forster, B., Aulbach, S., Symes, C., Gerdes, A., Hofer, H.E., Chacko, T.A reconnaissance study of Ti minerals in cratonic granulite xenoliths and their potential as recorders of lower crust formation and evolution.Journal of Petrology, Vol. 58, 10, pp. 2007-2034.Canada, Northwest Territoriesdeposit - Diavik

Abstract: A comprehensive petrographic and in situ major and trace element study of rutile, ilmenite and Ti-magnetite was undertaken in six lower crustal xenoliths of metabasaltic (?underplate) and metasedimentary (subduction) origin from the Diavik kimberlites (central Slave Craton, Canada). The aims of the study were to improve our understanding of trace element incorporation into these Ti-minerals, and to use these systematics to obtain insights into lower continental crust formation and evolution. Abundant (oxy)exsolution of titanomagnetite lamellae, blocky rutile, as well as minor pleonaste and zircon in ilmenite from metabasaltic granulites are proposed to reflect cooling from magmatic or metamorphic temperatures and subsequent secular mantle cooling. This explains the large spread in Zr-in-rutile temperatures (>200°C) and may partly be responsible for the substantial heterogeneity of other trace element concentrations in rutile and ilmenite. Even after accounting for trace element heterogeneity and modal uncertainties, mass-balance calculations indicate that both Ti and Nb in lower crustal granulites are largely controlled by rutile and ilmenite. Rutile U-Pb data define discordia arrays that yield upper intercept ages broadly coincident with the 1•27 Ga giant Mackenzie dike swarm event, suggesting reheating of the lower crust above the rutile U-Pb closure temperature, whereas lower intercept ages roughly correspond to the age of Cretaceous to Eocene kimberlite magmatism. Subsequent cooling led to partial resetting and data spread along the concordia. Closer inspection reveals that inter-grain concentrations of elements that are compatible in rutile (Nb, Ta, W, U), but highly incompatible in the abundant silicate minerals (in equilibrium with melt), are heterogeneous and contrast with the more homogeneous concentrations of the transition metals (NiO, V). This may indicate that local reaction partners for diffusive homogenization of these element concentrations were absent. Nb/Ta is also highly variable at the sample scale. This may be explained by prograde growth from high-Nb/Ta mineral precursors (e.g. biotite) in the metasedimentary granulites and crystallization of the protoliths to the metabasaltic granulites from a mafic magma that had experienced fractionation of ilmenite with low Nb/Ta in a crustal magma chamber. Thus, (Fe)-Ti minerals represent high field strength element ‘islands’ in the granulite silicate matrix. The lack of homogenization and persistence of high-energy grain boundaries, such as exsolution lamellae, further indicate that the lower continental crust remained essentially dry and did not recrystallize, possibly since Neoarchaean metamorphism.
DS201804-0689
2018
Forster, M.W., Prelevic, D., Schmuck, H.R., Buhre, S., Marschall, H.R., Mertz-Kraus, R., Jacob, D.E.Melting phologopite rich MARID: lamproites and the role of alkalis in olivine liquid Ni partioning.Chemical Geology, Vol. 476, 1, pp. 429-440.Technologylamproites

Abstract: In this study, we show how veined lithospheric mantle is involved in the genesis of ultrapotassic magmatism in cratonic settings. We conducted high pressure experiments to simulate vein + wall rock melting within the Earth's lithospheric mantle by reacting assemblages of harzburgite and phlogopite-rich hydrous mantle xenoliths. These comprised a mica-, amphibole-, rutile-, ilmenite-, diopside (MARID) assemblage at 3-5 GPa and 1325-1450 °C. Melting of the MARID assemblages results in infiltration of melt through the harzburgite, leading to its chemical alteration. At 3 and 4 GPa, melts are high in K2O (> 9 wt%) with K2O/Na2O > > 2 comparable to anorogenic lamproites. Higher pressures and temperatures (5 GPa/1450 °C) lead to increasing MgO contents of the melt and to some extent lower K2O contents (5-7 wt%) at equally high K2O/Na2O ratios. Our experiments provide insights into the role of alkalis in nickel-partitioning (DNi) between olivine and ultrapotassic melt. We observe that the high contents of Na, K, and Al are indicative of high DNi values, implying that the melt polymerization is the dominant factor influencing the olivine/melt nickel partitioning. The change of DNi as a function of melt composition results in a pressure independent, empirical geothermometer: Element oxides represent the composition of the glass (in wt%), and DNi is the liquid/olivine Ni-partitioning coefficient. We propose that this geothermometer is applicable to all natural silicate melts that crystallized olivine in a temperature interval between 1000 and 1600 °C. Application to glass-olivine pairs from calc-alkaline settings (Mexico), MORB (East Pacific Rise), and OIB (Hawaii) yielded reasonable values of 996-1199 °C, 1265 °C, and 1330 °C, respectively.
DS201804-0690
2017
Fournier, D., Kang, S., Mmillan, M.S., Oldenburg, D.W.Inversion of airborne geophysics over the DO-27/DO18 kimberlites. Part 2. Electromagnetics.Society of Exploration Geophysicists, Interpretation, August T 313, 13p.Canada, Northwest Territoriesdeposit - Tli Kwi Cho

Abstract: We focus on the task of finding a 3D conductivity structure for the DO-18 and DO-27 kimberlites, historically known as the Tli Kwi Cho (TKC) kimberlite complex in the Northwest Territories, Canada. Two airborne electromagnetic (EM) surveys are analyzed: a frequency-domain DIGHEM and a time-domain VTEM survey. Airborne time-domain data at TKC are particularly challenging because of the negative values that exist even at the earliest time channels. Heretofore, such data have not been inverted in three dimensions. In our analysis, we start by inverting frequency-domain data and positive VTEM data with a laterally constrained 1D inversion. This is important for assessing the noise levels associated with the data and for estimating the general conductivity structure. The analysis is then extended to a 3D inversion with our most recent optimized and parallelized inversion codes. We first address the issue about whether the conductivity anomaly is due to a shallow flat-lying conductor (associated with the lake bottom) or a vertical conductive pipe; we conclude that it is the latter. Both data sets are then cooperatively inverted to obtain a consistent 3D conductivity model for TKC that can be used for geologic interpretation. The conductivity model is then jointly interpreted with the density and magnetic susceptibility models from a previous paper. The addition of conductivity enriches the interpretation made with the potential fields in characterizing several distinct petrophysical kimberlite units. The final conductivity model also helps better define the lateral extent and upper boundary of the kimberlite pipes. This conductivity model is a crucial component of the follow-up paper in which our colleagues invert the airborne EM data to recover the time-dependent chargeability that further advances our geologic interpretation.
DS201803-0447
2017
Fraga, L.M., Cordani, U., Reis, N., Nadeau, S., Camara Maurer, V.U Pb shrimp and La ICPMS new dat a for different A type granites of the Orocaima igneous belt, central Guyana shield, northern Amazonian craton. ( Project Geology of the Guiana Shield)Anais Do 15 Simposio Geologia da Amazonia, Belem , Dec. 5p. Abstract pdfSouth America, Guianacraton

Abstract: The Orocaima Igneous Belt (OIB) is a huge plutono-volcanic belt at the central part of Guiana Shield, consisting mainly of 1.99-1.96 Ga volcano-plutonic rocks with high-K calc-alkaline, A-type and shosho-nitic geochemical signatures. Three A-type granitic bodies from the central part of the OIB have been dated using U-Pb SHRIMP and LA-ICPMS methods. A 1985±11 Ma age was calculated for the Macucal Mountain Granite of the Saracura Suite (Brazil) and ages of 1977±3.9 Ma and 1975±5 were calculated for the alkaline riebeckite granites respectively of the Lontra (Brazil) and Makarapan (Guyana) bodies. These ages are in the same range of those reported for the Aricamã A-type granitoids and the results indicate that different A-type magmatism took place in the 1.993-1.975 Ma interval along the OIB, coeval to high-K calc-alkaline and shoshonitic magmatism. This scenario fits well to a post-collisional setting.
DS201810-2316
2018
Friedrich, A.M.Palaeogeological hiatus surface mapping: a tool to visualize vertical motion of the continents.Geological Magazine, doi. 10.1017/ S0016756818000560 12p.Mantlegeodynamics

Abstract: Dynamic topography is a well-established consequence of global geodynamic models of mantle convection with horizontal dimensions of >1000 km and amplitudes up to 2 km. Such physical models guide the interpretation of geological records on equal dimensions. Continent-scale geological maps therefore serve as reference frames of choice to visualize erosion/non-deposition as a proxy for long-wavelength, low-amplitude vertical surface motion. At a resolution of systems or series, such maps display conformable and unconformable time boundaries traceable over hundreds to thousands of kilometres. Unconformable contact surfaces define the shape and size of time gap (hiatus) in millions of years based on the duration of time represented by the missing systems or series. Hiatus for a single system or series base datum diminishes laterally to locations (anchor points) where it is conformable at the mapped resolution; it is highly dependent upon scale. A comparison of hiatus area between two successive system or series boundaries yields changes in location, shape, size and duration, indicative of the transient nature of vertical surface motion. As a single-step technique, it serves as a quantitative proxy for palaeotopography that can be calibrated using other geological data. The tool magnifies the need for geological mapping at the temporal resolution of stages, matching process rates. The method has no resolving power within conformable regions (basins) but connects around them. When applied to marine seismic sections that relate to rock record, not to time, biostratigraphic and radiometric data from deep wells are needed before hiatus areas - that relate to time - can be mapped.
DS201801-0015
2018
Friedrich, A.M., Bunge, H-P., Rieger, S.M., Ghelichkhan, S., Nerlich, R.Stratigraphic framework for the plume mode of mantle convection and the analysis of inter regional unconformities on geological maps.Gondwana Research, Vol. 53, 1, pp. 159-188.Mantleconvection

Abstract: Mantle convection is a fundamental planetary process. Its plate mode is established and expressed by plate tectonics. Its plume mode also is established and expressed by interregional geological patterns. We developed both an event-based stratigraphic framework to illustrate the surface effects predicted by the plume model of Griffiths et al. (1989) and Griffiths and Campbell (1990) and a methodology to analyze continent-scale geological maps based on unconformities and hiatuses. The surface expression of ascending plumes lasts for tens-of-millions-of-years and rates vary over a few million years. As the plume ascends, its surface expression narrows, but increases in amplitude, leaving distinct geological and stratigraphic patterns in the geologic record, not only above the plume-head center, but also above its margins and in distal regions a few thousands-of-kilometers from the center. To visualize these patterns, we constructed sequential geological maps, chronostratigraphic sections, and hiatus diagrams. Dome-uplift with erosion (?engör, 2001) and the flood basalts (Duncan and Richards, 1991; Ernst and Buchan, 2001a) are diagnostic starting points for plume-stratigraphic analyses. Mechanical collapse of the dome results in narrow rifting (Burke and Dewey, 1973), drainage-network reorganization (Cox, 1989), and flood-basalt eruption. In the marginal region, patterns of vertical movement, deformation and surface response are transient and complex. At first, the plume margin is uplifted together with the central region, but then it subsides as the plume ascents farther; With plume-head flattening, the plume margin experiences renewed outward-migrating surface uplift, erosion, broad crustal faulting, and drainage reorganization. Knickpoint migration occurs first inward-directed at ½ the rate of plume ascent and later outward-directed at the rate of asthenospheric flow. Interregional-scale unconformity-bounded stratigraphic successions document the two inversions. The distal regions, which did not experience any plume-related uplift, yield complete sedimentary records of the event; Event-related time gaps (hiatuses) in the sedimentary record increase towards the center, but the event horizon is best preserved in the distal region; it may be recognized by tracing its contacts from the center outwards. We extracted system- and series-hiatuses from interregional geological maps and built hiatus maps as proxies for paleo-dynamic topography and as a basis for comparison with results from numerical models. Interregional-scale geological maps are well suited to visualize plume-related geological records of dynamic topography in continental regions. However, geological records and hiatus information at the resolution of stages will be needed at interregional scales. The plume-stratigraphic framework is event-based, interregional, but not global, with time-dependent amplitudes that are significantly larger than those of global eustatic sea-level fluctuations. Global stratigraphic syntheses require integration of plate- and plume-stratigraphic frameworks before eustatic contributions may be assessed.
DS201809-2022
2018
Frigo, C., Stalder, R., Ludwig, T.OH defects in coesite and stishovite during ultrahigh-pressure metamorphism of continental crust. Dora Maira, Kochetav massifsPhysics and Chemistry of Minerals, dor.org/10.1007/ d00269-018-0987-5 13p.Russia, Kazakhstan, Alpscoesite, UHP

Abstract: The high-pressure silica polymorphs coesite and stishovite were synthesized under water-saturated conditions from a natural granitic composition doped with Li and B. Experiments were performed in a Multi-Anvil apparatus between 4 and 9.1 GPa and 900 and 950 °C, based on the conditions of a subducting continental crust as realistic for the ultrahigh-pressure metamorphic units Dora Maira and Kochetav massifs. Run products consisted of coesite/stishovite?+?kyanite?±?phengite?±?omphacite, and quench material. The synthesized silica polymorphs were successively analyzed by infrared spectroscopy, electron microprobe, and Secondary-Ion Mass Spectrometry (SIMS). No hydrous defects were observed in coesite synthesized at 4 GPa and 900 °C, whereas coesite grown at higher pressures revealed a triplet of infrared absorptions bands at 3575, 3523, and 3459 cm??1, two minor bands at 3535 and 3502 cm??1, and a small band at 3300 cm??1 that was only visible at 7.7 GPa. The total amount of Al was charge-balanced by H and the other monovalent cations. However, the band triplet could not be associated with AlOH defects, while the band doublet was inferred to BOH defects and the small band probably corresponded to interstitial H. Stishovite displayed one dominant band at 3116 cm??1 with a shoulder at 3170 cm??1, and a minor band at 2665 cm??1, probably all associated with AlOH defects. BOH defects were not observed in stishovite, and LiOH defects were neither observed in coesite nor stishovite, probably because of preferentially partition of Li in other phases such as omphacite. The total amount of defect protons increased with pressure and with metal impurity concentrations. The general increase in OH defects in silica polymorphs with increasing pressure (this study) contrasted the negative pressure trend of OH in quartz observed previously from the same starting material, and revealed an incorporation minimum of OH in silica polymorphs around the quartz/coesite phase transition.
DS201808-1743
2018
Fritsch, E., Delaunay, A.What truly characterises a Chameleon diamond? An example of an Atypical 25.85 ct stone. ( Diamondvision)Journal of Gemmology, Vol. 36, 2, pp. 142-151.Technologydiamond - morphology

Abstract: We document an exceptionally large, 25.85 ct diamond that shows a slight colour change but exhibits some atypical properties for chameleon diamonds, including white luminescence to long- and short-wave UV radiation, as well as a network-like pattern seen in most orientations with the DiamondView. In considering whether to call this a chameleon diamond, we undertook a review of available data to compile the properties that are commonly exhibited by these gems. We found that, in addition to their defining photochromic and thermochromic behaviour, nine characteristics all must be present: long-lasting yellow phosphorescence, a zoned DiamondView growth pattern showing yellow-green/blue/inert areas, the presence of dominant A aggregates and also some hydrogen in the infrared spectrum, a continuum of absorption in the visible range related to a very weak type Ib character, a 480 nm absorption band that is possibly related to trace amounts of oxygen, a 425 nm absorption band, a weaker absorption band in the red to near-infrared region consistent with hydrogen-related defects, and traces of nickel detected with photoluminescence spectroscopy.
DS201802-0234
2018
From, R.E., Camacho, A., Pearson, D.G., Luo, Y.U-Pb and Lu-Hf isotopes of the Archean orthogneiss complex on eastern Hall Peninsula, southern Baffin Island, Nunavut: identification of exotic Paleo to Mesoarchean crust beneath eastern Hall Peninsula.Precambrian Research, Vol. 305, pp. 341-357.Canada, Nunavut, Hall Peninsulageochronology

Abstract: Eastern Hall Peninsula on southeastern Baffin Island, lies at the junction of a complex Paleoproterozoic collision between the Rae craton, Meta Incognita microcontinent and the North Atlantic craton from ca. 1.88 to 1.80?Ga. Several different interpretations of crustal correlations and the location of intervening sutures have been proposed based on reconnaissance-scale geologic investigation. Therefore, in this study, complex zircon grains from Archean orthogneiss units on eastern Hall Peninsula were analyzed in-situ to elucidate the detailed magmatic history of the region and assess crustal provenance. Magmatic zircons yielded U-Pb crystallization ages between ca. 2976 and 2720?Ma and metamorphic zircons record tectonothermal disturbances between ca. 2740 and 2700?Ma, a period coinciding with metamorphism documented in adjacent crustal blocks (e.g., west Greenland and northern Labrador). Magmatic rocks older than ca. 2740?Ma generally have positive ?Hf(t) signatures between 0 and 7 (±2) and depleted mantle model ages of ca. 3.1-3.0?Ga indicating the time that protolith melt was extracted from the mantle. The oldest, granodioritic crust crystallized at ca. 2976?Ma and was then reworked periodically at ca. 2.93, 2.84-2.81 and 2.77-2.69?Ma. Zircons from two orthogneiss samples, with U-Pb crystallization ages younger than ca. 2740?Ma, yielded negative ?Hf(t) values ranging from ?4 to ?12 and mean depleted mantle model ages of ca. 3.4 and 3.3?Ga respectively, indicating derivation from an older, potentially exotic, crustal source yet to be identified in outcrop on Hall Peninsula. Synthesizing regional U-Pb data we propose a new regional correlation model that retains the essentials of previous models and incorporates new data from eastern Hall Peninsula and other recent studies. This new tectonic correlation model groups eastern Hall Peninsula, southern Cumberland Peninsula and the Aasiaat domain into a “Core zone” that shared a geologic history prior to 1.90?Ga and potentially prior to 2.75?Ga.
DS201808-1744
2018
Fu, S., Yang, J., Zhang, Y., Okuschi, T., McCammon, C., Kim, H-I., Lee, S.K., Lin, J-F.Abnormal elasticity of Fe bearing bridgmanite in the Earth's lower mantle.Geophysical Research Letters, Vol. 45, 10, pp. 4725-4732.Mantlebridgmanite

Abstract: Seismic heterogeneities in the Earth's lower mantle have been attributed to thermal and/or chemical variations of constituent minerals. Bridgmanite is the most abundant lower?mantle mineral and contains Fe and Al in its structure. Knowing the effect of Fe on compressional and shear wave velocities (VP, VS) and density of bridgmanite at relevant pressure?temperature conditions can help to understand seismic heterogeneities in the region. However, experimental studies on both VP and VS of Fe?bearing bridgmanite have been limited to pressures below 40 GPa. In this study, VP and VS of Fe?bearing bridgmanite were measured up to 70 GPa in the diamond anvil cell. We observed drastic softening of VP by ~6(±1)% at 42.6-58 GPa and increased VS at pressures above 40 GPa. We interpret these observations as due to a spin transition of Fe3+. These observations are different to previous views on the effect of Fe on seismic velocities of bridgmanite. We propose that the abnormal sound velocities of Fe?bearing bridgmanite could help to explain the seismically observed low correlation between VP and VS in the mid?lower mantle. Our results challenge existing models of Fe enrichment to explain the origin of Large Low Shear Velocity provinces in the lowermost mantle.
DS201809-2023
2018
Fukuyama, K., Kagi, H., Inoue, T., Shinmei, T., Kakizawa, S., Takahata, N., Sano, Y.in corporation of nitrogen into lower mantle minerals under high pressure and high temperature.Goldschmidt Conference, 1p. AbstractMantlenitrogen

Abstract: Nitrogen occupies about 80% of the Earth 's atmosphere and had an impact on the climate in the early Earth. However, the behavior of nitrogen especially in the deep Earth is still unclear. Nitrogen is depleted compared to other volatile elements in deep mantle (Marty et al., 2012). "Missing" nitrogen is an important subject in earth science. In this study, we compared nitrogen incorporation into lower-mantle minerals (bridgmanite, periclase and stishovite) from high-temperature high-pressure experiment using multianvil apparatus installed at Geodynamics Research Center, Ehime University under the conditions of 27 GPa and 1600°C-1900°C. In these experiments, we used Fe-FeO buffer in order to reproduce the redox state of the lower mantle. Two types of starting materials: a powder mixture of SiO2 and MgO and a powder mixture of SiO2, MgO, Al2O3 and Mg(OH)2 were used for starting materials. Nitrogen in recovered samples was analyzed using NanoSIMS installed at Atmosphere and Ocean Research Institute. A series of experimental results revealed that stishovite and periclase can incorporate more nitrogen than bridgmanite. This suggests that periclase, the major mineral in the lower mantle, may be a nitrogen reservoir. Furthermore, the results suggest that stishovite, which is formed by the transition of the SiO2-rich oceanic crustal sedimentary rocks transported to the lower mantle via subducting slabs, can incorporate more nitrogen than bridgmanite (20 ppm nitrogen solubility reported by Yoshioka et al. (2018)). Our study suggests that nitrogen would continue to be supplied to the lower mantle via subducting slabs since approximate 4 billion years ago when the plate tectonics had begun, forming a "Hidden" nitrogen reservoir in the lower mantle.
DS201802-0235
2017
Fullea, J.On joint modelling of electrical conductivity and other geophysical and petrological observables to infer the structure of the lithosphere and underlying upper mantle.Surveys in Geophysics, Vol. 38, 5, pp. 963-1004.Mantlegeophysics

Abstract: This review paper focuses on joint modelling and interpretation of electromagnetic data and other geophysical and petrological observables. In particular, integrated geophysical-petrological modelling approaches, where the electrical conductivity and other physical properties of rocks are required to be linked by the common subsurface thermochemical conditions within a self-consistent thermodynamic framework, are reviewed. The paper gives an overview of the main geophysical electromagnetic techniques/data sets employed in lithospheric and mantle imaging including recent advances using satellite data, and an up-to-date summary of the most relevant laboratory experiments regarding the electrical conductivity of upper mantle minerals for various temperature-pressure-water conditions. The sensitivity of electrical conductivity and other geophysical parameters (density, seismic velocities) of mantle rocks to changes in temperature and composition are presented based on a Monte Carlo method parameter exploration. Finally, a case study in Central Tibet is presented where both seismological (long-period surface wave phase velocities) and electromagnetic (magnetotelluric) data—simultaneously including the constraints offered by topography, surface heat flow and mantle xenoliths—have been integrated. The modelling is based on a self-consistent petrological-geophysical thermodynamic framework where mantle properties are calculated as a function of temperature, pressure, and composition. The Tibetan case study offers an excellent opportunity to illustrate the different and complementary sensitivities of the various data sets used and to show how integrated thermochemical models of the lithosphere can help understand settings with a complex tectonic evolution.
DS201806-1224
2018
Galmiche, A.Is space our next diamond resource?Gems&Jewellery www.gem-a-com, Spring, pp. 32-35.Technologyasteroids
DS201810-2317
2018
Ganne, J., Feng, X.Magmatism: a crustal and geodynamic perspective.Journal of Structual Geology, Vol. 11, pp. 329-335.Mantlemagmatism

Abstract: The Earth's continental crust constitutes a major interface between the inner and outer envelops of the planet, controlling the differentiation of magmas produced in the mantle and their transfer to the surface. This close link facilitates the use of different chemical proxies to qualitatively unravel the crustal thickness related to fossil magmatic systems based on the message carried by magmas. This paper aims to bridge different results of statistical petrology, recently obtained at different scales of observation, in a global geodynamic model. Statistical analyses applied to a large multidimensional database of magmatic rocks show that crustal thickness could actually exert a first-order control on the composition of magmas, which become more calc-alkaline and comparatively less tholeiitic with increasing crustal thickness. Using this correlation, we document the progressive build-up of a thick (>40?km) Jurassic to Cretaceous accretionary belt along the Circum-Pacific Orogenic Belts (CPOB) that bounded the Panthalassa Ocean. The destruction of this thick belt started at ca. 125 Ma and was initially recorded by the thinnest magmatic systems hosting amphibole-bearing magma. Thinning of the CPOB became widespread in the northern regions of western America and in the western Pacific after ca. 75 Ma, possibly in response to oceanic plate segmentation, which triggered slab rollback and overriding plate extension. This chemical evolution is superimposed on a more global evolution of magma controlled by the temperature of the mantle that has gradually decreased since 200 Ma. Although the relative contribution of crust vs mantle cooling in the chemical signature of magmatic rocks should be further explored in the future, our results offer a new global perspective of the magmatic history of Pangea, the last supercontinent.
DS201802-0236
2017
Garanin, K.V.Polygenesis and discrete character - fundamental basis for the natural diamond genesis. *** IN RUSStarosin, V.I. (ed) Problems of the mineralogy, economic geology and mineral resources. MAKS Press, Moscow *** IN RUS, pp. 88-127.Technologydiamond morphology
DS201802-0237
2017
Garanin, K.V., Serov, I.V., Nikiforova, A.Yu., Grakhanov, O.S.The ALROSA geological prospecting complex and the analysis of the base for the diamond mining in Russian Federation to 2030. *** IN RUSStarosin, V.I. (ed) Problems of the mineralogy, economic geology and mineral resources. MAKS Press, Moscow *** IN RUS, pp. 22-40.Russiatechnology
DS201809-2024
2018
Garber, J.M., Maurya, S., Hernandez, J.A., Duncan, M.S., Zeng, L., Zhang, H.L.Multidisciplanary constraints on the abundance of diamond and eclogite in the cratonic lithosphere.Geochemistry, Geophysics, Geosystems, Vol. 19, 7, pp. 2062-2086. doi.org/10/1029/ 2018GC007534Mantlegeophysics - seismics

Abstract: Some seismic models derived from tomographic studies indicate elevated shear?wave velocities (?4.7 km/s) around 120-150 km depth in cratonic lithospheric mantle. These velocities are higher than those of cratonic peridotites, even assuming a cold cratonic geotherm (i.e., 35 mW/m2 surface heat flux) and accounting for compositional heterogeneity in cratonic peridotite xenoliths and the effects of anelasticity. We reviewed various geophysical and petrologic constraints on the nature of cratonic roots (seismic velocities, lithology/mineralogy, electrical conductivity, and gravity) and explored a range of permissible rock and mineral assemblages that can explain the high seismic velocities. These constraints suggest that diamond and eclogite are the most likely high?Vs candidates to explain the observed velocities, but matching the high shear?wave velocities requires either a large proportion of eclogite (>50 vol.%) or the presence of up to 3 vol.% diamond, with the exact values depending on peridotite and eclogite compositions and the geotherm. Both of these estimates are higher than predicted by observations made on natural samples from kimberlites. However, a combination of ?20 vol.% eclogite and ~2 vol.% diamond may account for high shear?wave velocities, in proportions consistent with multiple geophysical observables, data from natural samples, and within mass balance constraints for global carbon. Our results further show that cratonic thermal structure need not be significantly cooler than determined from xenolith thermobarometry.
DS201808-1745
2018
Garber, J.M., Maurya, S., Hernandez, J-A., Duncan, M.S., Zeng, L., Zhang, H.L., Faul, U., McCammon, C., Montagner, J-P., Moresi, L., Romanowicz, B.A., Rudnick, R.L., Stixrude, L.Multidisciplinary constraints on the abundance of diamond and eclogite in the cratonic lithosphere.G3 Geochemistry, Geophysics, Geosystems, http:/orchid.org/0000-0001-5313-0982Mantleeclogite
DS201807-1491
2018
Garber, J.M., Maurya, S., Hernandez, J-A., Duncan, M.S., Zeng, Li., Zhang, H.L., Faul, U., McCammon, C., Montagner, J-P., Moresi, L., Romanowicz, B.A., Rudnick, R.L., Stixrude, L.Multidisciplinary constraints on the abundance of diamond and eclogite in the cratonic lithosphere. Mentions Jericho and Roberts VictorGeochemistry, Geophysics, Geosystems, https://doi.org/10.1029/2018GCC007534Globalthermobarometry

Abstract: Some seismic models derived from tomographic studies indicate elevated shear?wave velocities (?4.7 km/s) around 120?150 km depth in cratonic lithospheric mantle. These velocities are higher than those of cratonic peridotites, even assuming a cold cratonic geotherm (i.e., 35 mW/m2 surface heat flux) and accounting for compositional heterogeneity in cratonic peridotite xenoliths and the effects of anelasticity. We reviewed various geophysical and petrologic constraints on the nature of cratonic roots (seismic velocities, lithology/mineralogy, electrical conductivity, and gravity) and explored a range of permissible rock and mineral assemblages that can explain the high seismic velocities. These constraints suggest that diamond and eclogite are the most likely high?Vs candidates to explain the observed velocities, but matching the high shear?wave velocities requires either a large proportion of eclogite (>50 vol.%) or the presence of up to 3 vol.% diamond, with the exact values depending on peridotite and eclogite compositions and the geotherm. Both of these estimates are higher than predicted by observations made on natural samples from kimberlites. However, a combination of ?20 vol.% eclogite and ~2 vol.% diamond may account for high shear?wave velocities, in proportions consistent with multiple geophysical observables, data from natural samples, and within mass balance constraints for global carbon. Our results further show that cratonic thermal structure need not be significantly cooler than determined from xenolith thermobarometry.
DS201810-2318
2018
Gardiner, N.J., Searle, M.P., Morley, C.K., Robb, L.J., Whitehouse, M.J., Roberts, N.M.W., Kirkland, C.L., Spencer, C.J.The crustal architecture of Myanmar imaged through zircon U-Pb, Lu-Hf and O isotopes: tectonic and metallogenic implications. ReviewGondwana Research, Vol. 62, pp. 27-60.Asia, Myanmartectonics

Abstract: The Tethys margin in central and eastern Asia is comprised of continental terranes separated by suture zones, some of which remain cryptic. Determining the crustal architecture, and therefore the geological history, of the Eastern Tethyan margin remains challenging. Sited in the heart of this region, Myanmar is a highly prospective but poorly explored minerals jurisdiction. A better understanding of Myanmar's mineralization can only be realized through a better understanding of its tectonic history, itself reflected in at least four major magmatic belts. The Eastern and the Main Range Provinces are associated with the Late Permian to Early Triassic closure of Palaeo-Tethys. The Mogok-Mandalay-Mergui Belt and Wuntho-Popa Arc are a response to the Eocene closure of Neo-Tethys. However, magmatic ages outside these two orogenic events are also recorded. We present new zircon U-Pb, Lu-Hf and O isotope data from magmatic rocks across Myanmar, which we append to the existing dataset to isotopically characterize Myanmar's magmatic belts. Eastern Province Permian I-type magmatism has evolved eHf (-10.9 to -6.4), whilst Main Range Province Triassic S-type magmatism also records evolved eHf (-13.5 to -8.8). The Mogok-Mandalay-Mergui Belt is here divided into the Tin Province and the Mogok Metamorphic Belt. The Tin Province hosts ca. 77-50 Ma magmatism with evolved eHf (-1.2 to -15.2), and d 18 O of 5.6-8.3‰. The Mogok Metamorphic Belt exhibits a more complex magmatic and metamorphic history, and granitoids record Jurassic, Late Cretaceous, and Eocene to Miocene phases of magmatism, all of which exhibit evolved eHf values between -4.6 and -17.6, and d 18 O between 6.3 and 9.2‰. From the Tagaung-Myitkyina Belt, we report a magmatic age of 172 Ma and eHf of 18.1 to 10.8. To accommodate the geological evidence, we propose a tectonic model for Myanmar involving a greater Sibumasu - where the documented zircon isotopic variations reflect compositional variations in magmatic source - and invoke the role of a Tengchong Block. The Baoshan Block and Greater Sibumasu were likely assembled on or before the Triassic, a former Andean margin and suture which may lie across the Northern Shan Plateau, and reflected in isotopic differences between the northern and southern parts of the Mogok Metamorphic Belt. This contiguous Sibumasu-Baoshan Block then sutured onto the Indochina margin in the Late Triassic. We propose that a Tengchong Block within Myanmar provides for a southerly termination of the Meso-Tethys suture immediately north of the Mogok area. A discrete Tengchong Block may explain a discontinuous arc of Late Triassic to Jurassic I-type magmatism in central Myanmar, representing an Andean-type margin sited above a subducting Meso-Tethys on the margin of Sibumasu. The Tengchong Block sutured onto Greater Sibumasu before the Late Cretaceous, after which subduction of Neo-Tethys drove the magmatism of the Wuntho-Popa Arc and ultimately that of the Tin Province. The metallogenic character of granite belts in Myanmar reflects the crustal architecture of the region, which is remarkable for its prolific endowment of granite-hosted Sn-W mineralization in two quite distinct granite belts related to sequential Indosinian and Himalayan orogenesis.
DS201802-0238
2018
Garzanti, E., Dinis, P., Vermeesch, P., Ando, S., Hahn, A., Huvi, J., Limonta, M., Padoan, M., Resentini, A., Rittner, M., Vezzoli, G.Sedimentary processes controlling ultralong cells of littoral transport: placer formation and termination of the Orange sand highway in southern Angola.Sedimentology, Vol. 65, 2, pp. 431-460.Africa, Angolaplacers, alluvials

Abstract: This study focuses on the causes, modalities and obstacles of sediment transfer in the longest cell of littoral sand drift documented on Earth so far. Sand derived from the Orange River is dragged by swell waves and persistent southerly winds to accumulate in four successive dunefields in coastal Namibia to Angola. All four dunefields are terminated by river valleys, where aeolian sand is flushed back to the ocean; and yet sediment transport continues at sea, tracing an 1800 km long submarine sand highway. Sand drift would extend northward to beyond the Congo if the shelf did not become progressively narrower in southern Angola, where drifting sand is funnelled towards oceanic depths via canyon heads connected to river mouths. Garnet-magnetite placers are widespread along this coastal stretch, indicating systematic loss of the low-density feldspatho-quartzose fraction to the deep ocean. More than half of Moçamedes Desert sand is derived from the Orange River, and the rest in similar proportions from the Cunene River and from the Swakop and other rivers draining the Damara Orogen in Namibia. The Orange fingerprint, characterized by basaltic rock fragments, clinopyroxene grains and bimodal zircon-age spectra with peaks at ca 0•5 Ga and ca 1•0 Ga, is lost abruptly at Namibe, and beach sands further north have abundant feldspar, amphibole-epidote suites and unimodal zircon-age spectra with a peak at ca 2•0 Ga, documenting local provenance from Palaeoproterozoic basement. Along with this oblique-rifted continental margin, beach placers are dominated by Fe-Ti-Cr oxides with more monazite than garnet and thus have a geochemical signature sharply different from beach placers found all the way along the Orange littoral cell. High-resolution mineralogical studies allow us to trace sediment dispersal over distances of thousands of kilometres, providing essential information for the correct reconstruction of ‘source to sink’ relationships in hydrocarbon exploration and to predict the long-term impact of man-made infrastructures on coastal sediment budgets.
DS201810-2319
2018
Gaudet, M., Kopylova, M., Muntener, C., Zhuk, V., Nathwani, C.Geology of the Renard 65 kimberlite pipe, Quebec, Canada.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0633-4 13p.Canada, Quebecdeposit - Renard

Abstract: Renard 65, a diamondiferous pipe in the Neoproterozoic Renard kimberlite cluster (Québec, Canada), is a steeply-dipping and downward-tapering diatreme comprised of three pipe-filling units: kimb65a, kimb65b, and kimb65d. The pipe is surrounded by a marginal and variably-brecciated country rock aureole and is crosscut by numerous hypabyssal dykes: kimb65c. Extensive petrographic and mineralogical characterization of over 700 m of drill core from four separate drill holes, suggests that Renard 65 is a Group I kimberlite, mineralogically classified as phlogopite kimberlite and serpentine-phlogopite kimberlite. Kimb65a is a massive volcaniclastic kimberlite dominated by lithic clasts, magmaclasts, and discrete olivine macrocrysts, hosted within a fine-grained diopside and serpentine-rich matrix. Kimb65b is massive, macrocrystic, coherent kimberlite with a groundmass assemblage of phlogopite, spinel, perovskite, apatite, calcite, serpentine and rare monticellite. Kimb65c is a massive, macrocrystic, hypabyssal kimberlite with a groundmass assemblage of phlogopite, serpentine, calcite, perovskite, spinel, and apatite. Kimb65d is massive volcaniclastic kimberlite with localized textures that are intermediate between volcaniclastic and coherent, with tightly packed magmaclasts separated by a diopside- and serpentine-rich matrix. Lithic clasts of granite-gneiss in kimb65a are weakly reacted, with partial melting of feldspars and crystallization of richterite and actinolite. Lithic clasts in kimb65b and kimb65d are entirely recrystallized to calcite + serpentine/chlorite + pectolite and display inner coronas of diopside-aegirine and an outer corona of phlogopite. Compositions are reported for all minerals in the groundmass of coherent kimberlites, magmaclasts, interclast matrices, and reacted lithic clasts. The Renard 65 rocks are texturally classified as Kimberley-type pyroclastic kimberlites and display transitional textures. The kimberlite units are interpreted to have formed in three melt batches based on their distinct spinel chemistry: kimb65a, kimb65b and kimb65d. We note a strong correlation between the modal abundances of lithic clasts and the textures of the kimberlites, where increasing modal abundances of granite/gneiss are observed in kimberlites with increasingly fragmental textures.
DS201801-0016
2017
Gautam, I., Bhutani, R., Balakrishnan, S., Chatterjee, A., George, B.G., Ray, J.S.142Nd/144Nd of alkaline magmas in Phenai Mat a complex, Chhota Udaipur, Deccan flood basalt province.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 14.Indiaalkaline rocks

Abstract: The 65 million year old alkaline plug at Phenai Mata Complex, in Chota Udaipur sub province, is often linked to the last pulse of the Deccan volcanism. However, many believe that the Deccan-Reunion mantle plume that was responsible for the generation of flood basalts might not have been the source of Phenai Mata. It, however, could have acted as a heat source for these magmas derived from the subcontinentallithospheric- mantle (SCLM). Since the SCLM is generally considered to be a nonconvective mantle domain it has the potential to preserve some of the geochemical evidence of the early silicate Earth differentiation, e.g., 142Nd anomaly. In search of such signatures we analysed alkali basalts from the complex for their 142Nd/144Nd using high precision thermal ionization mass spectrometry. Whereas the geochemical characterization of these samples confirmed the lithospheric origin of their source magmas, their ? 142Nd compositions are found to be normal with respect to terrestrial standards. We infer that either the mantle source of Phenai Mata does not represent a true non-convective mantle or it is too young to retain any evidence of 146Sm decay.
DS201810-2320
2018
Gem NotesReduced phosphorescence of type II HPHT grown synthetic diamonds after electron beam irradiation.The Journal of Gemmology, Vol. 36, 3, pp. 208-210.Globalsynthetics
DS201804-0691
2017
Gems & GemologySynthetic moissanite.Gems & Gemology Lab Notes, Vol. 53, 4, p. 462.Technologymoissanite
DS201809-2025
2018
Gems & GemologyChart: Features of synthetic diamond chart in colour.Gems & Gemology, Vol. 54, 2, p. 150.Globalsynthetics
DS201808-1746
2018
Gems & JewelleryFocus: Looking for the light. Fluorescence in gemstones.Gems & Jewellery, Vol. 27, 2, pp. 12-14.Technologyfluorescence
DS201808-1747
2018
Gems & JewelleryOnly a matter of time: Argyle, a sparkling history.Gems & Jewellery, Vol. 27, 2, 20-21.Australiadeposit - Argyle
DS201811-2571
2018
Gems & JewelleryWaiting for the lift…. Photograph only of miners down to Bultfontein, Dutoitspan mines.Gems & Jewellery, Autumn p. 8-9.Africa, South Africamining
DS201804-0692
2018
Geological Society of South AfricaSAMREC/SAMVAL Compliance and JSE reporting meetings… program T. Marshallgssaconferences.co.za /compliance -jse-reporting, June 28,29 thAfrica, South Africadiamond resource and reserve reporting

Abstract: This two-day Workshop (28th and 29th June 2018) comprises an introduction to the SAMREC and SAMVAL Codes, and JSE Reporting. This course is aimed at geologists, mining engineers and other technical specialists, who include sign-off as Competent Persons ("CPs") or Competent Valuators ("CVs") in their job description. Day one focuses on the basics of the SAMREC and SAMVAL Codes, and concentrates on the requirements for CPs who compile documents, specifically Competent Persons Reports and Integrated Annual Reports, for companies listed on the Johannesburg Stock Exchange (applicable primarily to Solid Minerals). Day two focuses on the Section 12 Listing rules applicable to both the Main Board and the Alt-X as well as the requirements of SAMREC and SAMVAL, highlighting some of the issues experienced by CPs over the years as well as some of the updated requirements as a result of the implementation of the 2016 SAMREC/SAMVAL Codes. An introduction to the JSE Readers Panel and a discussion of some of the on-going compliance issues identified by the panel.
DS201803-0448
2018
Geological Survey of Western AustraliaDiamond exploration and prospectivity of Western Australia.Geological Survey of Western Australia, digital data packageAustraliareview - exploration
DS201803-0449
2018
Geological Survey of Western AustraliaFrogtech Geoscience 2017, Canning Basin SEEBASE study and GIS dat a package.Geological Survey of Western Australia, Report 182, 297p.Australiadeposit - Ellendale area

Abstract: In 2005, Frogtech Geoscience completed OZ SEEBASE - a continental-scale depth-to-basement grid which shows the distribution of Phanerozoic basins across Australia. OZ SEEBASE is an open-file study that has been downloaded 1000s of times by industry, government and academia. This was followed in 2006 by the Proterozoic OZ SEEBASE interpretation including the main Proterozoic basins of Australia. The 2005 and 2006 OZ SEEBASE incorporated results from the Canning Basin Project completed by SRK Consulting for Shell during 1998-99.
DS201811-2572
2018
get-diamondsThe oval diamond cut - history of polishing technique. Lazare Kaplanget-diamonds.com, Oct. 3p.Globaldiamond polishing
DS201810-2321
2018
Ghobadi, M., Gerdes, A., Kogarko, L., Hoefer, H., Brey, G.In situ LA-ICPMS isotopic and geochronological studies on carbonatites and phoscorites from the Guli Massif, Maymecha-Kotuy, polar Siberia.Geochemistry International, Vol. 56, 8, pp. 766-783.Russia, Siberiacarbonatite

Abstract: In this study we present a fresh isotopic data, as well as U-Pb ages from different REE-minerals in carbonatites and phoscorites of Guli massif using in situ LA-ICPMS technique. The analyses were conducted on apatites and perovskites from calcio-carbonatite and phoscorite units, as well as on pyrochlores and baddeleyites from the carbonatites. The 87Sr/86Sr ratios obtained from apatites and perovskites from the phoscorites are 0.70308-0.70314 and 0.70306-0.70313, respectively; and 0.70310-0.70325 and 0.70314-0.70327, for the pyrochlores and apatites from the carbonatites, respectively. Furthermore, the in situ laser ablation analyses of apatites and perovskites from the phoscorite yield ?Nd from 3.6 (±1) to 5.1 (±0.5) and from 3.8 (±0.5) to 4.9 (±0.5), respectively; ?Nd of apatites, perovskites and pyrochlores from carbonatite ranges from 3.2 (±0.7) to 4.9 (±0.9), 3.9 (±0.6) to 4.5 (±0.8) and 3.2 (±0.4) to 4.4 (±0.8), respectively. Laser ablation analyses of baddeleyites yielded an eHf(t)d of +8.5 (± 0.18); prior to this study Hf isotopic characteristic of Guli massif was not known. Our new in situ ?Nd, 87Sr/86Sr and eHf data on minerals in the Guli carbonatites imply a depleted source with a long time integrated high Lu/Hf, Sm/Nd, Sr/Rb ratios. In situ U-Pb age determination was performed on perovskites from the carbonatites and phoscorites and also on pyrochlores and baddeleyites from carbonatites. The co-existing pyrochlores, perovskites and baddeleyites in carbonatites yielded ages of 252.3 ± 1.9, 252.5 ± 1.5 and 250.8 ± 1.4 Ma, respectively. The perovskites from the phoscorites yielded an age of 253.8 ± 1.9 Ma. The obtained age for Guli carbonatites and phoscorites lies within the range of ages previously reported for the Siberian Flood Basalts and suggest essentially synchronous emplacement with the Permian-Triassic boundary.
DS201807-1492
2018
GIADr. D. Twitchen ( CVD Element Six) discussion using magnetic resonance and optical techniques to study how defects in diamond affect colour and electrical conductivity. Keynote speakerGIA Symposium , Oct. 7-9, Carlsbad CA United States, Californiasynthetics
DS201809-2026
2018
Gibson, S.A., Richards, M.A.Delivery of deep sourced, volatile rich plume material to the global ridge system.Earth and Planetary Science Letters, Vol. 499, pp. 205-218.Oceanplumes, hotspots

Abstract: The global mid-ocean ridge (MOR) system represents a major site for outgassing of volatiles from Earth's mantle. The amount of H2O released via eruption of mid-ocean ridge basalts varies along the global ridge system and greatest at sites of interaction with mantle plumes. These deep-sourced thermal anomalies affect approximately one-third of all MORs - as reflected in enrichment of incompatible trace elements, isotope signatures and elevated ridge topography (excess melting) - but the physical mechanisms involved are controversial. The “standard model” involves solid-state flow interaction, wherein an actively upwelling plume influences the divergent upwelling generated by a mid-ocean ridge so that melting occurs at higher pressures and in greater amounts than at a normal spreading ridge. This model does not explain, however, certain enigmatic features including linear volcanic ridges radiating from the active plume to the nearby MOR. Examples of these are the Wolf-Darwin lineament (Galápagos), Rodrigues Ridge (La Réunion), Discovery Ridge (Discovery), and numerous smaller ridge-like structures associated with the Azores and Easter-Salas y Gómez hot spots. An important observation from our study is that fractionation-corrected MORB with exceptionally-high H2O contents (up to 1.3 wt.%) are found in close proximity to intersections of long-lived plume-related volcanic lineaments with spreading centres. New algorithms in the rare-earth element inversion melting (INVMEL) program allow us to simulate plume-ridge interactions by mixing the compositions of volatile-bearing melts generated during both active upwelling and passively-driven corner-flow. Our findings from these empirical models suggest that at sites of plume-ridge interaction, moderately-enriched MORBs (with 0.2-0.4 wt.% H2O) result from mixing of melts formed by: (i) active upwelling of plume material to minimum depths of ?35 km; and (ii) those generated by passive melting at shallower depths beneath the ridge. The most volatile-rich MORB (0.4-1.3 wt.% H2O) may form by the further addition of up to 25% of “deep” small-fraction plume stem melts that contain >3 wt.% H2O. We propose that these volatile-rich melts are transported directly to nearby MOR segments via pressure-induced, highly-channelised flow embedded within a broader “puddle” of mostly solid-state plume material, spreading beneath the plate as a gravity flow. This accounts for the short wavelength variability (over 10s of km) in geochemistry and bathymetry that is superimposed on the much larger (many 100s of km) “waist width” of plume-influenced ridge. Melt channels may constitute a primary delivery mechanism for volatiles from plume stems to nearby MORs and, in some instances, be expressed at the surface as volcanic lineaments and ridges. The delivery of small-fraction hydrous melts from plume stems to ridges via a two-phase (melt-matrix) regime implies that a parallel, bimodal transport system is involved at sites of plume-ridge interaction. We estimate that the rate of emplacement of deep-sourced volatile-rich melts in channels beneath the volcanic lineaments is high and involves 10s of thousands of km3/Ma. Since mantle plumes account for more than half of the melt production at MORs our findings have important implications for our understanding of deep Earth volatile cycling.
DS201812-2810
2019
Giebel, R.J., Marks, M.A.W., Gauert, C.D.K., Markl, G.A model for the formation of carbonatite-phoscorite assemblages based on the compositional variations of mica and apatite from the Palabora carbonatite complex, South Africa.Lithos, Vol. 324-325, pp. 89-104.Africa, South Africadeposit - Palabora

Abstract: A detailed electron microprobe study has been carried out on the compositional variations of mica and apatite from carbonatites, phoscorites and associated pyroxenites (and fenites) of the Loolekop deposit, Palabora Carbonatite Complex (South Africa). Mica in pyroxenites and fenites is Mg-rich biotite, whilst micas in carbonatites and phoscorites are compositionally diverse including phlogopite, Ba-rich phlogopite (up to 30% kinoshitalite component), IVAl-rich phlogopite (up to 30% eastonite component) and tetraferriphlogopite. The various types of phlogopites are interpreted as orthomagmatic phases, whereas tetraferriphlogopite precipitation was a late-magmatic to hydrothermal process that additionally introduced REE into the system. Orthomagmatic apatite is generally REE- and Sr-poor fluorapatite and does not show large compositional differences between rock types. Apatite associated with the late-stage tetraferriphlogopite mineralization reaches higher levels of REE (up to 4.9?wt%), Si (up to 1.5?wt% SiO2), Sr (up to 2.6?wt% SrO) and Na (up to 1.0?wt% Na2O). The compositional variation of micas and apatites, which is affiliated with distinct rock types, reflects the multi-stage evolution of the Loolekop deposit and provides detailed insight into the relationships of the carbonatite-phoscorite assemblage. The obtained data support the separation of phoscorite and carbonatite by immiscibility from a common parental magma, which may happen due to a decrease of temperature and/or pressure during the ascent of the magma. This results in a density contrast between the carbonatitic and phoscoritic components that will lead to descending phoscorite accumulations at the outer zones of the magma channel and a jet-like ascent (further promoted by its extremely low viscosity) of the carbonatite magma. The genetic model deduced here explains the peculiar association of carbonatites, phoscorites and silicate rocks in many alkaline complexes worldwide.
DS201809-2027
2018
Gifford, J.N., Mueller, P.A., Foster, D.A., Mogk, D.W.Extending the realm of Archean crust in the Great Falls tectonic zone: evidence from the Little Rocky Mountains, Montana.Precambrian Research, Vol. 315, pp. 264-281.United States, Montanacraton

Abstract: Two prominent features separate the Archean Wyoming and Hearne cratons: the Paleoproterozoic Great Falls tectonic zone (GFTZ) and the Medicine Hat block (MHB), neither of which is well defined spatially because of Phanerozoic sedimentary cover. Based on limited data, the MHB is thought to be a structurally complex mix of Archean (2.6-3.1?Ga) and Proterozoic (1.75?Ga) crust, but is recognized primarily by its geophysical signature, and its influence on the geochemistry of younger igneous rocks. Similarly, the GFTZ was recognized on the basis of broad differences in geophysical patterns, isopachs of Paleozoic sedimentary sections, and lineaments; however, juvenile arc rocks in the Little Belt Mountains (LBM) and strongly overprinted Archean rocks in southwestern Montana show it to be a dominantly Paleoproterozoic feature. The Little Rocky Mountains (LRM) of Montana provide access to exposures of the northeastern-most Precambrian crust in the MHB-GFTZ region. U/Pb ages of zircons from Precambrian rocks of the LRM range from 2.4 to 3.3?Ga, with most ages between 2.6 and 2.8?Ga. Whole-rock analyses yield Sm-Nd TDM from 3.1 to 4.0?Ga and initial ?Nd(T) values calculated at U-Pb zircon crystallization ages range from ?0.9 to ?10.5, indicating significant contributions from older Archean crust. The high proportion of 2.6-2.8?Ga U/Pb ages differentiates LRM crust from arc-related Paleoproterozoic magmatic rocks exposed in the LBM to the southwest. The age and isotopic composition of the LRM gneisses are similar to crust in the northern Wyoming Province (2.8-2.9?Ga), but Paleoproterozoic K-Ar cooling ages suggest crust in the LRM experienced the Paleoproterozoic metamorphism and deformation that characterizes the GFTZ. Consequently, its history differs markedly from the adjacent Beartooth-Bighorn magmatic zone of the northern Wyoming Province, which does not record Paleoproterozoic tectonism, but has a strong correlation with the Montana metasedimentary terrane that was strongly overprinted during the Paleoproterozoic Great Falls orogeny that defines the GFTZ. The LRM, therefore, likely provides a unique, and perhaps the only, opportunity to characterize Archean crust of the MHB.
DS201804-0693
2018
Gifillan, S.M.V., Ballentine, C.J.He, Ne and Ar 'snapshot' of the subcontinental lithospheric mantle from CO2 well gas.Chemical Geology, Vol. 480, pp. 116-127.Mantlechemistry

Abstract: The subcontinental lithospheric mantle (SCLM) constitutes a significant portion of the upper mantle sourcing magmatic volatiles to the continents above, yet its geochemical signature and evolution remain poorly constrained. Here we present new interpretation of noble gas datasets from two magmatic CO2 fields in the SW US, namely Bravo Dome and Sheep Mountain, which provide a unique insight into the volatile character of the SCLM sourcing the Cenozoic volcanism in the region. We identify that reduction of 3He/4Hemantle ratio within the Sheep Mountain CO2 field can be attributed to radiogenic production within the SCLM. Using a Reduced Chi-Squared minimisation on the variation of derived 4He/21Necrust ratios within samples from the Sheep Mountain field, combined with a radiogenically raised 21Ne/22Nemantle end member, we resolve 3He/4Hemantle ratios of 2.59 ± 0.15 to 3.00 ± 0.18 Ra. These values correspond with a 21Ne/22Nemantle value of 0.136. Using these 3He/4Hemantle end member values with 21Nemantle resolved from Ne three component analysis, we derive the elemental 3He/22Nemantle of 2.80 ± 0.16 and radiogenic 4He/21Ne*mantle range of 1.11 ± 0.11 to 1.30 ± 0.14. A second Reduced Chi-Squared minimisation performed on the variation of 21Ne/40Arcrust ratios has allowed us to also determine both the 4He/40Armantle range of 0.78 to 1.21 and 21Ne/40Armantle of 7.66 ± 1.62 to 7.70 ± 1.54 within the field. Combining these ratios with the known mantle production ranges for 4He/21Ne and 4He/40Ar allows resolution of the radiogenic He/Ne and He/Ar ratios corresponding to the radiogenically lowered 3He/4Hemantle ratios. Comparing these values with those resolved from the Bravo Dome field allows identification of a clear and coherent depletion of He to Ne and He to Ar in both datasets. This depletion can only be explained by partial degassing of small melt fractions of asthenospheric melts that have been emplaced into the SCLM. This is the first time that it has been possible to resolve and account for both the mantle He/Ne and He/Ar ratios within a SCLM source. The data additionally rule out the involvement of a plume component in the mantle source of the two gas fields and hence any plume influence on the Colorado Plateau Uplift event.
DS201810-2322
2018
Giordano, D., Russell, J.K.Towards a structural model for the viscosity of geological melts.Earth and Planetary Science Letters, Vol. 501, pp. 202-212.Mantlemelting

Abstract: The viscosity of silicate melts is the most important physical property governing magma transport and eruption dynamics. This macroscopic property is controlled by composition and temperature but ultimately reflects the structural organization of the melt operating at the microscale. At present, there is no explicit relationship connecting viscosity to silicate melt structure and vice versa. Here, we use a single Raman spectroscopic parameter, indicative of melt structure, to accurately forecast the viscosity of natural, multicomponent silicate melts from spectroscopic measurements on glasses preserved on Earth and other planets. The Raman parameter is taken as the ratio of low and high frequency vibrational bands from the silicate glass by employing a green source laser wavelength of 514.5 nm (R514.5). Our model is based on an empirical linkage between R514.5 and coefficients in the Vogel-Fulcher-Tammann function for the temperature dependence of melt viscosity. The calibration of the Raman-based model for melt viscosity is based on 413 high-temperature measurements of viscosity on 23 melt compositions for which published Raman spectra are available. The empirical model obviates the need for chemical measurement of glass compositions, thereby, providing new opportunities for tracking physical and thermochemical properties of melts during igneous processes (e.g., differentiation, mixing, assimilation). Furthermore, our model serves as a milepost for the future use of Raman spectral data for predicting transport (and calorimetric) properties of natural melts at geological conditions (e.g., volatiles and pressure) and production.
DS201812-2811
2018
Giordano, D., Russell, J.K.Towards a structural model for the viscosity of geological melts.Earth and Planetary Science Letters, Vol. 501, pp. 202-212.Mantlemelting

Abstract: The viscosity of silicate melts is the most important physical property governing magma transport and eruption dynamics. This macroscopic property is controlled by composition and temperature but ultimately reflects the structural organization of the melt operating at the microscale. At present, there is no explicit relationship connecting viscosity to silicate melt structure and vice versa. Here, we use a single Raman spectroscopic parameter, indicative of melt structure, to accurately forecast the viscosity of natural, multicomponent silicate melts from spectroscopic measurements on glasses preserved on Earth and other planets. The Raman parameter is taken as the ratio of low and high frequency vibrational bands from the silicate glass by employing a green source laser wavelength of 514.5 nm (R514.5). Our model is based on an empirical linkage between R514.5 and coefficients in the Vogel-Fulcher-Tammann function for the temperature dependence of melt viscosity. The calibration of the Raman-based model for melt viscosity is based on 413 high-temperature measurements of viscosity on 23 melt compositions for which published Raman spectra are available. The empirical model obviates the need for chemical measurement of glass compositions, thereby, providing new opportunities for tracking physical and thermochemical properties of melts during igneous processes (e.g., differentiation, mixing, assimilation). Furthermore, our model serves as a milepost for the future use of Raman spectral data for predicting transport (and calorimetric) properties of natural melts at geological conditions (e.g., volatiles and pressure) and production.
DS201805-0945
2018
Girnis, A.V., Brey, G.P., Bulatov, V.K., Hofer, H.E., Woodland, A.B.Graphite to diamond transformation during sediment-peridotite interaction at 7.5 and 10.5 Gpa.Lithos, in press available 42p.Mantleperidotites

Abstract: Diamond nucleation and growth were investigated experimentally at 7.5 and 10.5?GPa and temperatures up to 1500?°C. Samples consisted of two layers: i) H2O- and CO2-bearing model sediment and ii) graphite-bearing garnet harzburgite comprising natural minerals. Two experimental series were conducted, one under a controlled temperature gradient with the sedimentary layer usually in the cold zone and the other under isothermal conditions. In the latter case, diamond seeds were added to the sedimentary mixture. During the experiments, the sedimentary layer partially or completely melted, with the melt percolating and interacting with the adjacent harzburgite. The graphite-to-diamond transition in the peridotite was observed above 1300?°C at 7.5?GPa and 1200?°C at 10.5?GPa in the temperature-gradient experiments, and at temperatures ~100?°C lower in the isothermal experiments with diamond seeds. Newly formed diamond occurs mostly as individual grains up to 10??m in size and is separate from graphite aggregates. In some cases, an association of diamond with magnesite was observed. Diamond nucleation occurs in hydrous and CO2-bearing silicate melt following graphite dissolution and recrystallization. In the case of the diamond-magnesite association, diamond was probably formed through carbonate reduction coupled with graphite oxidation. The composition of the melts ranged from “carbonatitic” with ~10?wt% SiO2 and?>?50?wt% volatiles to hydrous silicate with ~40?wt% SiO2 and?
DS201801-0017
2017
Giuliani, A., Campeny, M., Kamenetsky, V.S., Afonso, J.C., Maas, R., Melgarejo, J.C., Kohn, B.P., Matchen, E.L., Mangas, J., Goncalves, A.O., Manuel, J.Southwestern Africa on the burner: Pleistocene carbonatite volcanism linked to deep mantle upwelling in Angola.Geology, Vol. 45, 11, pp. 971=974.Africa, Angolacarbonatite - Catanda

Abstract: The origin of intraplate carbonatitic to alkaline volcanism in Africa is controversial. A tectonic control, i.e., decompression melting associated with far-field stress, is suggested by correlation with lithospheric sutures, repeated magmatic cycles in the same areas over several million years, synchronicity across the plate, and lack of clear age progression patterns. Conversely, a dominant role for mantle convection is supported by the coincidence of Cenozoic volcanism with regions of lithospheric uplift, positive free-air gravity anomalies, and slow seismic velocities. To improve constraints on the genesis of African volcanism, here we report the first radiometric and isotopic results for the Catanda complex, which hosts the only extrusive carbonatites in Angola. Apatite (U-Th-Sm)/He and phlogopite 40Ar/39Ar ages of Catanda aillikite lavas indicate eruption at ca. 500-800 ka, more than 100 m.y. after emplacement of abundant kimberlites and carbonatites in this region. The lavas share similar high-? (HIMU)-like Sr-Nd-Pb-Hf isotope compositions with other young mantle-derived volcanics from Africa (e.g., Northern Kenya Rift; Cameroon Line). The position of the Catanda complex in the Lucapa corridor, a long-lived extensional structure, suggests a possible tectonic control for the volcanism. The complex is also located on the Bié Dome, a broad region of fast Pleistocene uplift attributed to mantle upwelling. Seismic tomography models indicate convection of deep hot material beneath regions of active volcanism in Africa, including a large area encompassing Angola and northern Namibia. This is strong evidence that intraplate late Cenozoic volcanism, including the Catanda complex, resulted from the interplay between mantle convection and preexisting lithospheric heterogeneities.
DS201803-0450
2014
Giuliani, A., Phillips, D., Maas, R., Woodhead, J.D., Kendrick, M.A., Greig, A., Armstrong, R.A., Chew, D., Kamenetsky, V.S., Fiorentini, M.L.LIMA U-Pb ages link lithospheric mantle metasomatism to Karoo magmatism beneath the Kimberley region, South Africa.Earth and Planetary Science Letters, Vol. 401, pp. 132-147.Africa, South Africametasomatism

Abstract: The Karoo igneous rocks (174-185 Ma) of southern Africa represent one of the largest continental flood basalt provinces on Earth. Available evidence indicates that Karoo magmas either originated in the asthenosphere and were extensively modified by interaction with the lithospheric mantle prior to emplacement in the upper crust; or were produced by partial melting of enriched mantle lithosphere. However, no direct evidence of interaction by Karoo melts (or their precursors) with lithospheric mantle rocks has yet been identified in the suites of mantle xenoliths sampled by post-Karoo kimberlites in southern Africa. Here we report U-Pb ages for lindsleyite-mathiasite (LIMA) titanate minerals (crichtonite series) from three metasomatised, phlogopite and clinopyroxene-rich peridotite xenoliths from the ?84 Ma Bultfontein kimberlite (Kimberley, South Africa), located in the southern part of the Karoo magmatic province. The LIMA minerals appear to have formed during metasomatism of the lithospheric mantle by fluids enriched in HFSE (Ti, Zr, Hf, Nb), LILE (K, Ba, Ca, Sr) and LREE. LIMA U-Pb elemental and isotopic compositions were measured in situ by LA-ICP-MS methods, and potential matrix effects were evaluated by solution-mode analysis of mineral separates. LIMA minerals from the three samples yielded apparent U-Pb ages of , and (). A single zircon grain extracted from the ?190 Ma LIMA-bearing sample produced a similar U-Pb age of , within uncertainty of the LIMA ages. These data provide the first robust evidence of fluid enrichment in the lithospheric mantle beneath the Kimberley region at ?180-190 Ma, and suggest causation of mantle metasomatism by Karoo melts or their precursor(s). The results further indicate that U-Pb dating of LIMA minerals provides a new, accurate tool for dating metasomatic events in the lithospheric mantle.
DS201803-0451
2018
Giuliani, A., Woodhead, J.D., Phillips, D., Maas, R., Davies, G.R.Titanates of the lindsleyite mathiasite ( LIMA) group reveal isotope disequilibrium associated with metasomatism in the mantle beneath Kimberley ( South Africa).Earth and Planetary Science Letters, Vol. 482, pp. 253-264.Africa, South Africametasomatism

Abstract: Radiogenic isotope variations unrelated to radiogenic ingrowth are common between minerals found in metasomatised mantle xenoliths entrained in kimberlite, basalts and related magmas. As the metasomatic minerals are assumed to have been in isotopic equilibrium originally, such variations are typically attributed to contamination by the magma host and/or interaction with mantle fluids during or before xenolith transport to surface. However, the increasing evidence of metasomatism by multiple, compositionally distinct fluids permeating the lithospheric mantle, coeval with specific magmatic events, suggests that isotopic disequilibrium might be a consequence of discrete, though complex, metasomatic events. Here we provide clear evidence of elemental and Sr isotope heterogeneity between coeval Ti-rich LIMA (lindsleyite–mathiasite) minerals at the time of their formation in the mantle. LIMA minerals occur in close textural association with clinopyroxene and phlogopite in low-temperature (?800–900?°C), strongly metasomatised mantle xenoliths from the ?84 Ma Bultfontein kimberlite (South Africa). Previous U/Pb dating of the LIMA phases was used to argue that each xenolith recorded a single event of LIMA crystallisation at ?180–190 Ma, coeval with the emplacement of Karoo magmas. SEM imaging reveals that up to four types of LIMA phases coexist in each xenolith, and occasionally in a single LIMA grain. Major element and in situ Sr isotope analyses of the different LIMA types show that each phase has a distinct elemental composition and initial 87Sr/86Sr ratio (e.g., 0.7068–0.7086 and 0.7115–0.7129 for two LIMA types in a single xenolith; 0.7053-0.7131 across the entire sample suite). These combined age and isotopic constraints require that multiple fluids metasomatised these rocks at broadly the same time (i.e. within a few thousands to millions of years), and produced similar mineralogical features. Elemental and isotopic variations between different LIMA types could be due to interaction between one (or more) Karoo-related Ti-rich silicate melts and previously metasomatised, phlogopite-rich lithospheric mantle. This study demonstrates that mantle metasomatic assemblages seemingly generated in a single event may instead result from the infiltration of broadly coeval fluids with variable compositions. This in turn implies that the isotopic variations recorded in mantle rocks may be an inherent feature of metasomatism, and that hot fluids infiltrating a rock do not necessarily cause equilibration at the cm scale, as has been assumed previously. Simple modelling of solid-state diffusion in mantle minerals shows that isotopic disequilibrium may be preserved for up to hundreds of Myr at mantle lithosphere temperatures (?1100–1200?°C), unless subsequently affected by transient heating and/or fluid infiltration events. Radiogenic isotope disequilibrium associated with mantle metasomatism may therefore be a common feature of mantle xenoliths.
DS201811-2573
2015
Giuliani, G., Branquet, Y., Fallick, A.E., Groat, L.A., Marshall, D.Emerald deposits around the world, their similarities and differences.InColor, December pp. 56-69.Globalemeralds
DS201803-0452
2018
Glassley, W.E.Epiphanies of the edgelands. Book: A wilder time: notes from a geologist at the edge of the Greenland ice.Nature, Vol. 554, Feb 8, p. 166.Europe, Greenlandgeomorphology
DS201802-0239
2018
Glikson, A.Structure and origin of Australian ring and dome features with reference to the search for asteroid impact events.Tectonophysics, Vol. 722, pp. 175-196.Australiaring structures

Abstract: Ring, dome and crater features on the Australian continent and shelf include (A) 38 structures of confirmed or probable asteroid and meteorite impact origin and (B) numerous buried and exposed ring, dome and crater features of undefined origin. A large number of the latter include structural and geophysical elements consistent with impact structures, pending test by field investigations and/or drilling. This paper documents and briefly describes 43 ring and dome features with the aim of appraising their similarities and differences from those of impact structures. Discrimination between impact structures and igneous plugs, volcanic caldera and salt domes require field work and/or drilling. Where crater-like morphological patterns intersect pre-existing linear structural features and contain central morphological highs and unique thrust and fault patterns an impact connection needs to tested in the field. Hints of potential buried impact structures may be furnished by single or multi-ring TMI patterns, circular TMI quiet zones, corresponding gravity patterns, low velocity and non-reflective seismic zones. A) Examples of crater-form and dome-form features containing elements consistent with an impact origin, though unproven, include Auvergne, Delamere, Fiery Creek, Monte Christo, Mount Moffatt, Tanami East, Youngerina, and Tingha. B) Examples of buried multi-ring features of possible to probable impact origin include Augathella, Balfour Downs, Calvert Hills, Camooweal, Green Swamp Well, Herbert, Ikybon River, Ilkurka, Lennis, McLarty Hills, Mount Davies, Mulkara; Neale; Sheridan Creek, Oodjuongari and Renehan. C) Examples of igneous plugs unrelated to impacts include the Monto gabbro and numerous circular granitoid plugs such as Windinie Hills granite and Yataga granodiorite. D) Large circular structures such as Mount Ashmore and Gnargoo are considered to have convincing structural deformation features warranting classification as probable impact structures. The origin of very large circular TMI and gravity patterns such as of the Diamantina River drainage feature, Coonamona anomaly and the multiple TMI ring pattern of the Deniliquin-Booligal remain unresolved. The advent of ~ 40 m TMI grid coverage promises to further uncover ring and dome features, such as the McLarty Hills multi-ring feature, potentially increasing the inventory of ring structures on the Australian continent. Compared with frequency distribution patterns of extra-terrestrial impact structures worldwide, the Australian record displays a relatively common occurrence of large impact structures and relative depletion in small impact structures and craters. This is explained by the better preservation of large structures at deep crustal zones as compared to the erosion of small craters.
DS201805-0946
2018
Golovin, A.V., Sharygin, I.S., Kamenetsky, V.S., Korsakov, A.V., Yaxley, G.M.Alkali-carbonate melts from the base of cratonic lithospheric mantle: links to kimberlites.Chemical Geology, Vol. 483, pp. 261-274.Russiadeposit - Udachnaya

Abstract: Identification of the primary compositions of mantle-derived melts is crucial for understanding mantle compositions and physical conditions of mantle melting. However, these melts rarely reach the Earth's surface unmodified because of contamination, crystal fractionation and degassing, processes that occur almost ubiquitously after melt generation. Here we report snapshots of the melts preserved in sheared peridotite xenoliths from the Udachnaya-East kimberlite pipe, in the central part of the Siberian craton. These xenoliths are among the deepest mantle samples and were delivered by kimberlite magma from 180-230?km depth interval, i.e. from the base of the cratonic lithosphere. The olivine grains of the sheared peridotites contain secondary inclusions of the crystallized melt with bulk molar (Na?+?K)/Ca?~?3.4. Various Na-K-Ca-, Na-Ca-, Na-Mg-, Ca-Mg- and Ca-carbonates, Na-Mg-carbonates with additional anions, alkali sulphates and halides are predominant among the daughter minerals in secondary melt inclusions, whereas silicates, oxides, sulphides and phosphates are subordinate. These inclusions can be considered as Cl-S-bearing alkali-carbonate melts. The presence of aragonite, a high-pressure polymorph of CaCO3, among the daughter minerals suggests a mantle origin for these melt inclusions. The secondary melt inclusions in olivine from the sheared peridotite xenoliths and the melt inclusions in phenocrystic olivines from the host kimberlites demonstrate similarities, in daughter minerals assemblages and trace-element compositions. Moreover, alkali-rich minerals (carbonates, halides, sulphates and sulphides) identified in the studied melt inclusions are also present in the groundmass of the host kimberlites. These data suggests a genetic link between melt enclosed in olivine from the sheared peridotites and melt parental to the Udachnaya-East kimberlites. We suggest that the melt inclusions in olivine from mantle xenoliths may represent near primary, kimberlite melts. These results are new evidence in support of the alkali?carbonate composition of kimberlite melts in their source regions, prior to the kimberlite emplacement into the crust, and are in stark contrast to the generally accepted ultramafic silicate nature of parental kimberlite liquids.
DS201809-2028
2018
Gong, Z., Xu, X., Evans, D.A.D., Hoffman, P.F., Mitchell, R.N., Bleeker, W.Paleomagnetism and rock magnetism of the ca. 1.87 Ga Pearson Formation, Northwest Territories, Canada: a test of vertical axis rotation within the Great Slave Basin.Precambrian Research , Vol. 305C, pp. 295-309.Canada, Northwest Territoriesgeophysics

Abstract: A geometrically quantitative plate-kinematic model, based on paleomagnetism, for the initial assembly of Laurentia has taken form in the past few decades. Within this framework, there remains but one problematic interval of data predominantly from the Slave craton, which is the 1.96-1.87?Ga Coronation apparent polar wander path (APWP). The Coronation APWP shows large (?110°) back-and-forth oscillations that are difficult to explain in terms of plate motion. Nonetheless, poles from the Coronation APWP have been incorporated in various paleogeographic reconstructions of Laurentia and the supercontinent Nuna, pointing to the importance of testing its veracity. In this study, we conducted a detailed paleomagnetic and rock magnetic study of the ca. 1.87?Ga Pearson Formation, East Arm of Great Slave Lake, Northwest Territories, Canada. Our results show that Pearson Formation yields a characteristic remanent magnetization carried by single-domain or small pseudo-single-domain magnetite. The age of the magnetization is constrained to be older than Paleoproterozoic deformation and is interpreted as primary. Paleomagnetic declinations reveal a one-to-one correlation with local structural attitudes, indicating that some small blocks in the fold belt likely experienced significant (?60°) vertical-axis rotations, presumably related to large dextral displacements along the McDonald Fault system. Alternative explanations, such as true polar wander or a non-dipole magnetic field, are considered less parsimonious for the data presented here. It is suspected that some existing Christie Bay Group poles (the Stark and Tochatwi Formations), which were sampled in areas with anomalous structural attitudes and differ from time-equivalent poles obtained from areas of the Slave craton far from major transcurrent faults, may similarly suffer from vertical-axis rotation. We suggest further study before using possibly rotated Christie Bay Group poles for paleogeographic reconstructions.
DS201809-2029
2018
Gonzalez-Garcia, D., Petrelli, M., Behrens, H., Vetere, F., Fischer, L.A., Morgavi, D., Perugini, D.Diffusive exchange of trace elements between alkaline melts: implications for element fractionation and timescale estimations during magma mixing.Geochimica et Cosmochimica Acta, Vol. 233, pp. 95-114.Europe, Italyshoshonites

Abstract: The diffusive exchange of 30 trace elements (Cs, Rb, Ba, Sr, Co, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ta, V, Cr, Pb, Th, U, Zr, Hf, Sn and Nb) during the interaction of natural mafic and silicic alkaline melts was experimentally studied at conditions relevant to shallow magmatic systems. In detail, a set of 12 diffusion couple experiments have been performed between natural shoshonitic and rhyolitic melts from the Vulcano Island (Aeolian archipelago, Italy) at a temperature of 1200?°C, pressures from 50 to 500?MPa, and water contents ranging from nominally dry to ca. 2 wt.%. Concentration-distance profiles, measured by Laser Ablation ICP-MS, highlight different behaviours, and trace elements were divided into two groups: (1) elements with normal diffusion profiles (13 elements, mainly low field strength and transition elements), and (2) elements showing uphill diffusion (17 elements including Y, Zr, Nb, Pb and rare earth elements, except Eu). For the elements showing normal diffusion profiles, chemical diffusion coefficients were estimated using a concentration-dependent evaluation method, and values are given at four intermediate compositions (SiO2 equal to 58, 62, 66 and 70 wt.%, respectively). A general coupling of diffusion coefficients to silica diffusivity is observed, and variations in systematics are observed between mafic and silicic compositions. Results show that water plays a decisive role on diffusive rates in the studied conditions, producing an enhancement between 0.4 and 0.7 log units per 1 wt.% of added H2O. Particularly notable is the behaviour of the trivalent-only REEs (La to Nd and Gd to Lu), with strong uphill diffusion minima, diminishing from light to heavy REEs. Modelling of REE profiles by a modified effective binary diffusion model indicates that activity gradients induced by the SiO2 concentration contrast are responsible for their development, inducing a transient partitioning of REEs towards the shoshonitic melt. These results indicate that diffusive fractionation of trace elements is possible during magma mixing events, especially in the more silicic melts, and that the presence of water in such events can lead to enhanced chemical diffusive mixing efficiency, affecting also the estimation of mixing to eruption timescales.
DS201801-0019
2017
Gorczyk, W., Mole, D.R., Barnes, S.J.Plume lithosphere interaction at craton margins throughout Earth history.Tectonophysics, in press available, 17p.Mantleplume

Abstract: Intraplate continental magmatism represents a fundamental mechanism in Earth's magmatic, thermal, chemical and environmental evolution. It is a process intimately linked with crustal development, large-igneous provinces, metallogeny and major global environmental catastrophes. As a result, understanding the interactions of continental magmas through time is vital in understanding their effect on the planet. The interaction of mantle plumes with the lithosphere has been shown to significantly affect the location and form of continental magmatism, but only at modern mantle conditions. In this study, we perform numerical modelling for Late Archean (1600 °C), Paleoproterozoic (1550 °C), Meso-Neoproteroic (1500 °C) and Phanerozoic (1450 °C) mantle potential temperatures (Tp) to assess the time-space magmatic effects of ambient-mantle- and plume- lithosphere interaction over Earth's thermal history. Within these experiments, we impinge a mantle plume, with a time-appropriate Tp, onto a ‘step-like’ lithosphere, to evaluate the effect of craton margins on continental magmatism through time. The results of this modelling demonstrate that lithospheric architecture controls the volume and location of continental magmatism throughout Earth history, irrespective of ambient mantle or plume Tp. In all plume models, mantle starting plumes (diameter 300 km) impinge on the base of the lithosphere, and spread laterally over > 1600 km, flowing into the shallowest mantle, and producing the highest volume magmas. In ambient-mantle only models, Archean and Paleoproterozoic Tp values yield significant sub-lithospheric melt volumes, resulting in ‘passive’ geodynamic emplacement of basaltic magmatic provinces, whereas no melts are extracted at > 100 km for Meso-Neoproterozoic and Phanerozoic Tp. This indicates a major transition in non-subduction related continental magmatism from plume and ambient mantle to a plume-dominated source around the Mesoproterozoic. While the experiments presented here show the variation in plume-lithosphere interaction through time, the consistency in melt localisation indicates the lithosphere has been a first-order control on continental magmatism since its establishment in the Mesoarchean.
DS201805-0947
2018
Gordienko, V.Deep seated processes and diamond bearing rocks.New Concepts in Global Tectonics Journal, Vol. 6, no. 1, pp. 4-20. pdfMantlemagmatism, UHP
DS201807-1493
2013
Gorkovets, V.Ya., Rudashevskii, N.S., Rudashevsky, V.N., Popov, M.G., Antonov, A.A.Indicator minerals in the lamproitic diatreme, Kostomuksha region, Karelia. Doklady Earth Sciences , Vol. 450, 1, pp. 79-90.Russialamproite

Abstract: The mineralogy of a new lamproitic diatreme 200-250 m in diameter and 3 ga in area is studied in detail. The chemical and 3-D mineralogical analysis identify the diatreme rocks as strongly altered olivine lamproites with a large volume (50-60%) of xenoliths of strongly altered spinel (garnet) lherzolites and harzburgites-dunites. Numerous grains-xenocrysts of indicator minerals of diamond have been extracted from the heavy concentrates (the weight of the initial product is 742 g and the size is 100-500 ?m) as a result of hydroseparation: (1) subcalcium (CaOav. 2.6 wt %) high-Cr (Cr2O3 av. 5.3 wt %) pyrope (50 grains); (2) chrome diopside (7 and 8 mol % of kosmochlor and jadeite components, respectively, >40 grains); (3) high-Cr chromite (Cr2O3 > 62 wt %); and (4) picroilmenite (MgO 12-13.8 wt %) and Cr-rutile (Cr2O3 1.1 wt %). Xenocrysts prove the mantle endogene (the level of garnet lherzolites) source of the magmatic center of lamproites and forecast the diamond potential of the new diatreme in the Kostomuksha ore district.
DS201807-1494
2018
Gose, J., Schmadicke, E.Water in corporation in garnet: coesite versus quartz ecologite from Erzgebirge and Fichtelbirge.Journal of Petrology, Vol. 59, 2, pp. 207-232.Europe, Germanycoesite
DS201804-0694
2017
Gouiza, M., Bertotti, G., Andriessen, P.A.M.Mesozoic and Cenozoic thermal history of the Western Reguibat Shield ( West African Craton).Terra Nova, pp. 135-145.Africa, Moroccogeothermometry

Abstract: Using low?temperature thermochronology on apatite and zircon crystals, we show that the western Reguibat Shield, located in the northern part of the West African Craton, experienced significant cooling and heating events between Jurassic and present times. The obtained apatite fission track ages range between 49 and 102 Ma with mean track lengths varying between 11.6 and 13.3 ?m and Dpar values between 1.69 and 3.08 ?m. Zircon fission track analysis yielded two ages of 159 and 118 Ma. Apatite (U-Th)/He uncorrected single?grain ages range between 76 and 95 Ma. Thermal inverse modelling indicates that the Reguibat Shield was exhumed during the Early Cretaceous, Late Cretaceous, Palaeocene-Eocene and Quaternary. These exhumation events were coeval with regional tectonic and geodynamic events, and were probably driven by a combined effect of plate tectonics and mantle dynamics.
DS201812-2812
2018
Goussi Ngalamo, J.F., Sobh, M., Bisso, D., Abdelsalam, M.G., Atekwana, E., Ekodeck, G.E.Lithospheric structure beneath the central Africa orogenic belt in Cameroon from the analysis of satellite gravity and passive seismic data.Tectonophysics, Vol. 745, pp. 326-337.Africa, Cameroongeophysics - seismics

Abstract: We present original results that contribute to the understanding of lithospheric structures modification of regions that have witnessed superimposition of multiple tectonic events throughout their geological history. We analyze satellite gravity data through two-dimensional radially-averaged power spectral analysis as well as passive seismic data through thermal modeling to image the depth to the Moho and the lithosphere - asthenosphere boundary (LAB beneath the Central Africa Orogenic Belt (CAOB). The CAOB is an ENE-trending deformation belt extending from Cameroon in the west to Sudan in the east. In Cameroon, it is found on the northern edge of the Congo craton represented by the Oubanguides orogenic belt (the Western Cameroon, the Adamawa - Yade, and the Yaoundé domains). It coincides with the Adamawa plateau and the Benue Trough, and it is spotted by the Cenozoic Cameroon Volcanic Line (CVL). The CAOB was formed during the Precambrian Greater Gondwana assembly but was reactivated during the Mesozoic as a result of Gondwana breakup. We find deeper Moho and LAB) beneath Congo craton and the Yaoundé domain reaching ~50?km and ~200?km, respectively. We map shallower Moho and LAB beneath the CAOB (together with the Adamawa plateau and the Benue trough) reaching ~25?km and ~70?km, respectively. We interpret the shallower LAB beneath the CAOB as due to zonal sub-continental lithospheric mantle (SCLM) delamination along the northern edge of the Congo craton that occurred in association with collisional assembly of Greater Gondwana. This allowed for channelization of mantle flow during the Cenozoic resulting in the formation of the CVL and the uplift of the Adamawa plateau. Our approach can be used to understand the modification of lithospheric structures beneath other terrains that have long tectonic history.
DS201808-1748
2018
Greaves, J.S., Scaife, A.M.M., Frayer, D.T., Green, D.A., Mason, B.S., Smith, A.M.S.Anomalous microwave emission from spinning nanodiamonds around stars.Nature Astronomy, doi.org/10.1038/s41550-018-0495-zGlobalnanodiamonds

Abstract: Several interstellar environments produce 'anomalous microwave emission', with brightness-peaks at tens-of-gigahertz frequencies. The emission's origins are uncertain - rapidly-spinning nano-particles could emit electric-dipole radiation, but polycyclic aromatic hydrocarbons proposed as the carrier are now found not to correlate with Galactic signals. The difficulty is to identify co-spatial sources over long lines of sight. Here we identify anomalous microwave emission in three proto-planetary discs. These are the only known systems that host hydrogenated nano-diamonds, in contrast to very common detection of polycyclic aromatic hydrocarbons. Spectroscopy locates the nano-diamonds close to the host-stars, at physically-constrained temperatures. Developing disc models, we reproduce the emission with diamonds 0.75-1.1 nanometres in radius, holding less than or equal to 1-2 per cent of the carbon budget. The microwave-emission:stellar-luminosity ratios are approximately constant, allowing nano-diamonds to be ubiquitous but emitting below detection thresholds in many star-systems. This can unify the findings with similar-sized diamonds found within solar system meteorites. As nano-diamond spectral absorption is seen in interstellar sightlines, these particles are also a candidate for generating galaxy-scale anomalous microwave emission.
DS201809-2030
2018
Green, C.The pursuit of colour. Part 1. The rise to prominence of fancy coloured diamonds post 1970.The Australian Gemmologist, Vol. 26, 9-10, pp. 226-239.Globaldiamond - colour
DS201805-0948
2018
Greenough, J.D., McDivitt, J.A.Earth's evolving subcontinental lithospheric mantle: inferences from LIP continental flood basalt geochemistry.International Journal of Earth Sciences, Vol. 107, 3, pp. 787-810.Mantlegeochemistry

Abstract: Archean and Proterozoic subcontinental lithospheric mantle (SLM) is compared using 83 similarly incompatible element ratios (SIER; minimally affected by % melting or differentiation, e.g., Rb/Ba, Nb/Pb, Ti/Y) for >3700 basalts from ten continental flood basalt (CFB) provinces representing nine large igneous provinces (LIPs). Nine transition metals (TM; Fe, Mn, Sc, V, Cr, Co, Ni, Cu, Zn) in 102 primitive basalts (Mg# = 0.69-0.72) from nine provinces yield additional SLM information. An iterative evaluation of SIER values indicates that, regardless of age, CFB transecting Archean lithosphere are enriched in Rb, K, Pb, Th and heavy REE(?); whereas P, Ti, Nb, Ta and light REE(?) are higher in Proterozoic-and-younger SLM sources. This suggests efficient transfer of alkali metals and Pb to the continental lithosphere perhaps in association with melting of subducted ocean floor to form Archean tonalite-trondhjemite-granodiorite terranes. Titanium, Nb and Ta were not efficiently transferred, perhaps due to the stabilization of oxide phases (e.g., rutile or ilmenite) in down-going Archean slabs. CFB transecting Archean lithosphere have EM1-like SIER that are more extreme than seen in oceanic island basalts (OIB) suggesting an Archean SLM origin for OIB-enriched mantle 1 (EM1). In contrast, OIB high U/Pb (HIMU) sources have more extreme SIER than seen in CFB provinces. HIMU may represent subduction-processed ocean floor recycled directly to the convecting mantle, but to avoid convective homogenization and produce its unique Pb isotopic signature may require long-term isolation and incubation in SLM. Based on all TM, CFB transecting Proterozoic lithosphere are distinct from those cutting Archean lithosphere. There is a tendency for lower Sc, Cr, Ni and Cu, and higher Zn, in the sources for Archean-cutting CFB and EM1 OIB, than Proterozoic-cutting CFB and HIMU OIB. All CFB have SiO2 (pressure proxy)-Nb/Y (% melting proxy) relationships supporting low pressure, high % melting resembling OIB tholeiites, but TM concentrations do not correlate with % melting. Thus, the association of layered intrusion (plutonic CFB) TM deposits with Archean terranes does not appear related to higher metal concentrations or higher percentages of melting in Archean SLM. Other characteristics of these EM1-like magmas (e.g., S2 or O2 fugacity) may lead to element scavenging and concentration during differentiation to form ore deposits.
DS201807-1495
2018
Gress, M.U., Pearson, D.G., Chinn, I.L., Koornneef, J.M., Pals, A.S.M., Van der Valk, E.A.S., Davies, G.R.Episodic eclogitic diamond genesis at Jwaneng diamond mine, Botswana.Goldschmidt2018, abstract 1p.Africa, Botswanadeposit - Jwaneng

Abstract: The diamondiferous Jwaneng kimberlite cluster (~240 Ma) is located on the NW rim of the Archaean Kaapvaal Craton in central Botswana. Previous studies report eclogitic diamond formation in the late Archean (2.9 Ga) and in the Middle Proterozoic (1.5 Ga) involving different mantle and sedimentary components [1;2;3]. Here we report newly acquired Sm- Nd ages of individual eclogitic pyrope-almandine and omphacite inclusions along with their major element data and nitrogen data from the diamond hosts to re-examine Jwaneng’s diamond formation ages. The Sm-Nd isotope analyses were performed via TIMS using 1013? resistors [4]. An initial suite of three pyropealmandine and 14 omphacite inclusions yield 143Nd/144Nd from 0.51102±7 to 0.5155±5. 147Sm/144Nd vary from 0.024 to 0.469. Major element data defines two inclusion populations: (1) seven omphacites with high Mg#, high Cr# and one pyropealmandine with low-Ca define an isochron age of 1.93±0.16 Ga with ?Ndi= +3.5; (2) seven omphacites with low Mg#, low Cr# and two pyrope-almandines with low-Ca define an isochron age of 0.82±0.06 Ga with ?Ndi= +3.7. Nitrogen contents of corresponding diamond host growth zones in Group (1) are ? 50 at.ppm whereas Group (2) range between 50 to 700 at.ppm with N-aggregation > 70 %B. Additional data used to define “co-genetic” inclusion suites include Sr-isotopes and trace elements of the inclusions and carbon isotopes of the diamond hosts. Re-Os data of coexisting sulphide inclusions from the same silicate-bearing diamonds further validates the ages and indicates more periods of diamond formation at Jwaneng than previously assumed. The integrated data indicate the possibility of an extensive Paleoproterozoic diamond-forming event in southern Africa.
DS201810-2323
2018
Griffin, W.L., Gain, S.E.M., Huang, J.X., Belousova, E.A., Toledo, V., O'Reilly, S.Y.Permian to quaternary magmatism beneath the Mt. Carmel area, Israel: zircons from volcanic rocks and associated alluvial deposits.Lithos, Vol. 314-315, pp. 307-322.Europe, Israel zircons

Abstract: Xenocrystic zircons from Cretaceous pyroclastic vents on Mt. Carmel, N. Israel, document two major periods of earlier mafic magmatism: Permo-Triassic (285-220?Ma) and Jurassic (200-160?Ma). Related alluvial deposits also contain these zircon populations. However, most alluvial zircons are Cretaceous (118-80?Ma) or younger, derived from Miocene to Pliocene volcanic episodes. The Permo-Triassic-Jurassic zircons are typically large and glassy; they have irregular shapes and a wide variety of internal zoning patterns. They appear to have grown in the interstitial spaces of coarse-grained rocks; many show evidence of recrystallization, including brecciation and rehealing by chemically similar zircon. Grains with relict igneous zoning have mantle-like ?18O (5.5?±?1.0‰), but brecciation leads to lower values (mean 4.8‰, down to 3.1‰). Hf-isotope compositions lie midway between the Chondritic Uniform Reservoir (CHUR) and Depleted Mantle (DM) reservoirs; Hf model ages suggest that the source region separated from DM in Neoproterozoic time (1500-1000?Ma). Most Cretaceous zircons have 176Hf/177Hf similar to those of the older zircons, suggesting recrystallization and/or Pb loss from older zircons in the Cretaceous thermal event. The Permo-Jurassic zircons show trace-element characteristics similar to those crystallized from plume-related magmas (Iceland, Hawaii). Calculated melts in equilibrium with them are characterized by strong depletion in LREE and P, large positive Ce anomalies, variable Ti anomalies, and high and variable Nb, Ta, Th and U, consistent with the fractionation of monazite, zircon, apatite and Ti-bearing phases. We suggest that these coarse-grained zircons crystallized from late differentiates of mafic magmas, ponded near the crust-mantle boundary (ca 30?km depth), and were reworked repeatedly by successively younger igneous/metasomatic fluids. The zircon data support a published model that locates a fossil Neoproterozoic plume head beneath much of the Arabia-Levant region, which has been intermittently melted to generate the volcanic rocks of the region. The Cretaceous magmas carry mantle xenoliths derived from depths up to 90?km, providing a minimum depth for the possible plume head. Post-Cretaceous magmatism, as recorded in detrital zircons, shows distinct peaks at 30?Ma, 13?Ma, 11.4?±?0.1?Ma (a major peak; n?=?15), 9-10?Ma and 4?Ma, representing the Lower and Cover Basalts in the area. Some of these younger magmas tapped the same mantle source as the Permian-Jurassic magmatism, but many young zircons have Hf-isotope compositions extending up to DM values, suggesting derivation of magmas from deeper, more juvenile sources.
DS201810-2324
2018
Griffin, W.L., Howell, D., Gonzalez-Jimenez, J.M., Xiong, Q.., O'Reilly, S.Y.Comment: Ultra high pressure and ultra reduced minerals in ophiolites may form by lightning strikes. Super Reduced Minerals SURGeochemical Perspectives Letters, Vol. 7, pp. 1-2.Mantlemoissanite

Abstract: Ballhaus et al. (2017) use electric-discharge experiments to argue that lightning strikes could produce ultra-high pressure (UHP) and super-reduced (SuR) phases "identical to those found in 'high-pressure' ophiolites" and that thus there is "not sufficient evidence to challenge long-established models of ophiolite genesis", specifically for the UHP processing of Tibetan ophiolites. However, the authors produced no evidence for UHP phases in their experiments. There are pertinent observations, relevant to the authors’ assertions, in the literature regarding the relationship between the UHP and SuR assemblages in the Tibetan peridotites. Their conclusions are not consistent with this evidence.
DS201806-1225
2018
Griffin, W.L., Huang, J-X., Thomassot, E., Gain, S.E.M., Toledo, V., O'Reilley, S.Y.Super reducing conditions in ancient and modern volcanic systems: sources and behaviour of carbon-rich fluids in the lithospheric mantle. Mt. Carmel moissaniteMineralogy and Petrology, in press available, 14p.Europe, Israelmetasomatism

Abstract: Oxygen fugacity (fO2) is a key parameter of Earth’s mantle, because it controls the speciation of the fluids migrating at depth; a major question is whether the sublithospheric mantle is metal-saturated, keeping fO2 near the Iron-Wustite (IW) buffer reaction. Cretaceous basaltic pyroclastic rocks on Mt. Carmel, Israel erupted in an intraplate environment with a thin, hot lithosphere. They contain abundant aggregates of hopper-shaped crystals of Ti-rich corundum, which have trapped melts with phenocryst assemblages (Ti2O3, SiC, TiC, silicides, native V) requiring extremely low fO2. These assemblages are interpreted to reflect interaction between basaltic melts and mantle-derived fluids dominated by CH4 + H2. Similar highly reduced assemblages are found associated with volcanism in a range of tectonic situations including subduction zones, major continental collisions, intraplate settings, craton margins and the cratons sampled by kimberlites. This distribution, and the worldwide similarity of ?13C in mantle-derived SiC and associated diamonds, suggest a widespread process, involving similar sources and independent of tectonic setting. We suggest that the common factor is the ascent of abiotic (CH4 + H2) fluids from the sublithospheric mantle; this would imply that much of the mantle is metal-saturated, consistent with observations of metallic inclusions in sublithospheric diamonds (e.g. Smith et al. 2016). Such fluids, perhaps carried in rapidly ascending deep-seated magmas, could penetrate high up into a depleted cratonic root, establishing the observed trend of decreasing fO2 with depth (e.g. Yaxley et al. in Lithos 140:142-151, 2012). However, repeated metasomatism (associated with the intrusion of silicate melts) will raise the FeO content near the base of the craton over time, developing a carapace of oxidizing material that would prevent the rise of CH4-rich fluids into higher levels of the subcontinental lithospheric mantle (SCLM). Oxidation of these fluids would release CO2 and H2O to drive metasomatism and low-degree melting both in the carapace and higher in the SCLM. This model can explain the genesis of cratonic diamonds from both reduced and oxidized fluids, the existence of SiC as inclusions in diamonds, and the abundance of SiC in some kimberlites. It should encourage further study of the fine fractions of heavy-mineral concentrates from all types of explosive volcanism.
DS201808-1749
2018
Griffin, W.L., Huang, J-X., Thomassot, E., Gain, S.E.M., Toledo, V., O'Reilly, S.Y.Super-reducing conditions in ancient and modern volcanic systems: sources and behaviour of carbon-rich fluids in the lithospheric mantle ( Mt. Carmel).Mineralogy and Petrology, doi.org/10.1007/s00710-018-0575-x 14p.Mantlemoissanite
DS201810-2325
2018
Gromilov, S.A., Afanasiev, V.P., Poikhilenko. N.P.Moissanites of the Popigai astrobleme.Doklady Earth Sciences, Vol. 481, 2, pp. 997-999.Russiamoissanite

Abstract: Moissanites were found in tagamites of the Popigai meteorite crater along with impact diamonds. We have studied 55 samples including 49 individual polytypes and six intergrowths. The numbers of 6H, 15R, 4H, 6H/15R, and 6H/4H polytypes are 82, 7, 5, 4, and 2%, respectively. By the assemblage of polytypes, the moissanites of the Popigai astrobleme are distinct from kimberlite moissanites, as well as from synthetic SiC, which is characterized by the absence of the 4H polytype and the presence of more diverse inclusions (including Fe-bearing). The Popigai astrobleme is one of few objects with reliable natural moissanite. Technogenic contamination is excluded, since any researcher can find this mineral in tagamites.
DS201812-2813
2018
Gruber, B.H., Chacko, T., Pearson, D.G.The thermochemical conditions of the Diavik lower crust: a kimberlite-hosted xenolith study.2018 Yellowknife Geoscience Forum , p. 25-26. abstractCanada, Northwest Territoriesdeposit - Diavik

Abstract: Thermochemical variables such as lower crustal heat production and Moho temperatures in cratonic regions offer critical insight in constraining the thermal and geodynamic evolution of the lithosphere. In this study, 15 lower crustal granulite xenoliths erupted via the A154N kimberlite at the Diavik mine in the NWT, Canada were studied to quantify the thermal properties of the local Moho and the effects of different heat production models on geotherm models. We quantitatively constrain the thermal properties of the local Moho and the effects of different heat production models on ancient Moho temperatures, the effects of crustal thickness on Moho temperatures, and potential lower crustal compositions. We evaluate the effect of these parameters on total lithospheric thickness estimates. In order to test the accuracy of deep crust thermal calculations, we estimated the ambient temperature of the lower crust at the time of kimberlite eruption through garnet-biotite Fe-Mg exchange geothermometry (Ferry & Spear, 1978). Rim compositions from touching garnet-biotite pairs were used in the calculations and yielded temperatures of 524 ± 77°C (n=20). These represent a maximum estimate of the ambient lower crustal temperature as the closure temperature of garnet-biotite Fe-Mg exchange between garnet and biotite may be higher than the ambient temperature. The primary objective of this study is to quantify lower crustal heat production and its effects on the thermal architecture of cratons. The concentrations of the main heat-producing elements (HPEs) U, Th, and K were quantified via LA-ICP-MS and EPMA in multiple mineral phases per xenolith. By combining these measurements with mineral modes, we derived reconstructed bulk-rock HPE concentrations that were utilized to calculate a range of lower crustal heat production values. This method is preferred over whole-rock analyses as 1) kimberlite is generally enriched in HPEs (Tappe et al. 2013) and can bias trace-element data for their xenoliths and 2) data on individual minerals allows for theoretical lower crustal compositions to be calculated on an idealized basis. A lower crust comprising exclusively mafic granulite (garnet, plagioclase, clinopyroxene ± orthopyroxene) provides a lower bound to heat production (0.07 ± 0.04 W/m3) whereas a lower crust made exclusively of high-grade metasedimentary rocks yields an upper bound (0.42 ± 0.08 W/m3). Both endmembers are present as xenoliths in the A154N kimberlite but mafic granulites predominate following the worldwide trend (Rudnick, 1992). We model the lower crust comprising 20% metasedimentary granulites and 80 % depleted mafic granulites, in accordance with the present xenolith collection. Using this preferred crustal model, we calculate an average heat production of 0.12 ± 0.05 W/m3) for the lower crust beneath Lac de Gras. Utilizing heat flow measurements (Russell et thickness estimates (Mareschal et al. 2004) in conjunction with these HPE determinations, the Moho temperature underlying A-154N can be calculated to be 502 ± 10°C. Using these values along with available mantle xenolith thermobaromtetry (Hasterok & Chapman, 2011) the geotherm is extrapolated to present a mantle potential temperature of 1365°C, at 200 km (FITPLOT, Mather et al, 2011).
DS201804-0695
2018
Grutter, H.Pyroxene thermobarometry: a xenocryst - based approach.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 17-18. abstractTechnologythermobarometry
DS201804-0696
2018
Grutter, H.Microdiamond SFD's and practical use in macrograde forecasting.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 19-20. abstractTechnologymicrodiamonds
DS201807-1496
2018
Grutter, H.S., Pell, J.A., Fitzgerald, C.E.Use of a simplified Mahalanobis distance approach to constrain the dispersion and provenance of Cr-pyrope populations at the Chidliak kimberlite province, Nunavut, Canada.Mineralogy and Petrology, June 14, DOI:10.1007/ s0710-018 -0578-7, 12p.Canada, Nunavutdeposit - Chidliak

Abstract: Exploration for diamond-bearing kimberlites in the Chidliak project area by Peregrine Diamonds has generated a grid-like till sampling pattern across four discrete areas of interest totalling 402 km2 that is densely populated with research-grade compositional data for 10,743 mantle-derived Cr-pyrope garnets. The available dataset is well suited to statistical analysis, in part due to the relatively unbiased spatial coverage. Previous workers showed empirically that the TiO2 and Mn thermometry (Ti-TMn) attributes of Cr-pyrope populations at the Chidliak project may serve as source-specific “fingerprints”. In this work, we employ a simplified version of the multivariate Mahalanobis distance technique to formally examine the variability of, and differences between, Ti-TMn attributes of Cr-pyrope subpopulations recovered from a Laurentide-age glaciated terrain that also contains 30 known kimberlites within the four areas of interest. We show the simplified Mahalanobis distance approach enables accurate discrimination of Cr-pyrope subpopulations with subtly to distinctly different Ti-TMn attributes, and permits proper demarcation of their respective kimberlite source(s), specifically in areas with straightforward glacial histories. Redistribution and blending of Cr-pyrope subpopulations from known kimberlite sources is also observed, and typifies areas at Chidliak with complex late-glacial histories. Our results support <1 km horizontal scale subtle to obvious variability in the proportions of TiO2-rich and high-temperature (> 1100 °C) Cr-pyropes between closely spaced kimberlite source(s) and also between physically adjacent magma batches within single kimberlite pipes. The local scale variability is attributed to protokimberlite fluid or melt interacting with, and metasomatizing discrete conduits within, the ambient diamond-facies peridotitic mantle at times closely preceding eruption of kimberlite magma batches at Chidliak.
DS201804-0697
2018
Grutzner, T., Klemme, S., Rohrbach, A., Gerbasoni, F., Berndt, J.The effect of fluorine on the stability of wadsleyite: implications for the nature and depths of the transition zone in the Earth's mantle.Earth and Planteray Science Letters, Vol. 482, pp. 236-244.Mantletransition zone

Abstract: The Earth's mantle contains significant amounts of volatile elements, such as hydrogen (H), carbon (C) and the halogens fluorine (F), chlorine (Cl) and bromine (Br) and iodine (I). There is a wealth of knowledge about the global cycling of H and C, but there is only scant data on the concentrations of halogens in different Earth reservoirs and on the behavior of halogens during recycling in subduction zones. Here we focus on the storage potential of F in deeper parts of the Earth's mantle. The transition zone is a region in the Earth's mantle (410-660 km) known for its high water storage capacity, as the high pressure polymorphs of olivine, wadsleyite and ringwoodite are known to be able to incorporate several per-cent of water. In order to assess potential fractionation between water and F in the transition zone of the Earth's mantle, we set out to investigate the storage capacity of the halogen F in wadsleyite and olivine at transition zone conditions. Experiments were performed in a simplified mantle composition at temperatures from 1400?°C to 1900?°C and pressures from 17 up to 21 GPa in a multi anvil apparatus. The results show that F can shift the olivine-wadsleyite transition towards higher pressure. We find that F has an opposing effect to water, the latter of which extends the transition zone towards lower pressure. Moreover, the F storage capacity of wadsleyite is significantly lower than previously anticipated. F concentrations in wadsleyite range from to independent of temperature or pressure. The F storage capacity in wadsleyite is even lower than the F storage capacity of forsterite under transition zone conditions, and the latter can incorporate F under these conditions. Based on our data we find that the transition zone cannot be a reservoir for F as it is assumed to be for water. Furthermore, we argue that during subduction of a volatile-bearing slab, fractionation of water from F will occur, where water enters preferentially the transition zone and F remains in the peridotite of the lowermost upper mantle.
DS201811-2574
2018
Gu, T., Wang, W.Optical defects in milky type I aB diamonds.Diamond & Related Materials, Vol. 89, pp. 322-329.Russia, Indiadeposit - Mir, Panna

Abstract: The optical features of milky type IaB diamonds were studied systematically by non-destructive approaches including FTIR, photoluminescence (PL), and cathodoluminescence (CL) spectroscopy. From 97 type IaB diamonds ranging from 0.2?ct to ~100?ct submitted to GIA's New York laboratory for screening, we found that all the milky type IaB diamonds consistently displayed the hydrogen-related defect with an absorption line at 3107?cm?1, and ~96% of them were accompanied by a weaker line at 3085.4?cm?1, which is undetectable in most non-milky diamonds. Most of the diamond samples display no platelet defect or a very tiny residual platelet peak with a position at larger wavenumber in milky diamonds than in non-milky counterparts. “Amber center” with a weak but sharp absorption line at 4168.8?cm?1 has been observed in ~73% of the milky diamonds and ~24% of the non-milky ones. Photoluminescence (PL) results reveal that several defects with ZPLs at 490.7, 536, 575.9 and 612.4?nm are more common in milky type IaB diamonds than non-milky ones. A zero-phonon line (ZPL) at 536?nm has been confirmed by PL mapping and CL spectra as a product of plastic deformation, and it might be linked with the H4 center (N4V2 defect). A ZPL at 490.7?nm could be related to a nitrogen-vacancy complex. The defects present more often in milky IaB diamonds are generally associated with plastic deformation. The presence of a hydrogen-related peak at 3085.4?cm?1 and a 536?nm center would help effectively distinguish IaB diamonds with subtle milky areas from their non-milky counterparts.
DS201812-2814
2018
Gu, T., Wang, W.Optical defects in milky type IaB diamonds.Diamond & Related Materials, Vol. 89, pp. 322-329.Russia, India, South America, Brazilphotoluminesence spectroscopy
DS201802-0240
2018
Gu, X., Ingrin, J., Deloule, E., France, L., Xia, Q.Metasomatism in the sub-continental lithospheric mantle beneath the south French Massif Central: constraints from trace elements, Li and H in peridotite minerals.Chemical Geology, Vol. 478, pp. 2-17.Europe, Franceperidotite

Abstract: Mantle metasomatism by percolating melts/fluids can significantly modify the geochemical and mineralogical compositions of the sub-continental lithospheric mantle (SCLM). We present a detailed study of water contents and Li concentrations and isotopic compositions in mantle minerals from a suite of peridotite xenoliths entrained by a Cenozoic Strombolian volcano in the southern French Massif Central (FMC). Wide ranging clinopyroxene trace element distributions (e.g., (La/Yb)N from 0.25 to 22.21; Ti/Eu ratios from 453 to 4892) suggest that the SCLM has undergone metasomatism by carbonatitic melts/fluids or melts/fluids related to subducted materials. Two amphibole-bearing samples exhibit depletion of light rare earth elements (LREE; (La/Yb)N = 0.26 and 0.30, respectively) in amphiboles, similar to that in co-existing clinopyroxenes; these samples indicate that amphiboles grew during a separate modally metasomatic event predating the cryptic metasomatism accounting for LREE enrichment and negative HFSE anomalies in other samples. Mineral Li concentrations are similar to those in the normal mantle, with inter-mineral Li partitioning nearly equilibrated and intragranular Li distributions nearly homogeneous. However, negative ?7Li values of pyroxenes in some samples (as low as ? 8.8‰ in clinopyroxene of sample MC38) can be attributed to diffusive exchange with a small-volume melt of moderate Li concentration and light Li isotopic composition, originally associated with a recycled component. Preservation of the currently observed large inter-mineral Li isotopic variations indicates that melt percolation occurred shortly before entrainment of the peridotite xenoliths by the host magma. Mineral water contents vary from 41 to 428 ppm in clinopyroxenes and from 28 to 152 ppm in orthopyroxenes, and their roughly negative co-variation with coexisting olivine Fo contents imply that partial melting was the main control over mineral water content variations in most samples. Varied water contents in LREE-enriched metasomatized samples indicate the involvement of metasomatic agents of different origins. The aqueous agent responsible for generation of amphiboles in two samples did not produce a notable increase in the water contents of coexisting nominally anhydrous minerals.
DS201801-0020
2018
Guillocheau, F., Simon, B., Baby, G., Bessin, P., Robin, C., Dauteuil, O.Planation surfaces as a record of mantle dynamics: the case of Africa.Gondwana Research, Vol. 53, 1, pp. 82-98.Africageodynamics

Abstract: There are two types of emerged relief on the Earth: high elevation areas (mountain belts and rift shoulders) in active tectonic settings and low elevation domains (anorogenic plateaus and plains) characteristic of the interior of the continents i.e. 70% of the Earth emerged relief. Both plateaus and plains are characterized by large erosional surfaces, called planation surfaces that display undulations with middle (several tens of kilometres) to very long (several thousands of kilometres) wavelengths, i.e. characteristic of lithospheric and mantle deformations respectively. Our objective is here (1) to present a new method of characterization of the very long and long wavelength deformations using planation surfaces with an application to Central Africa and (2) to reconstruct the growth of the very long wavelength relief since 40 Ma, as a record of past mantle dynamics below Central Africa. (i) The African relief results from two major types of planation surfaces, etchplains (weathering surfaces by laterites) and pediplains/pediments. These planation surfaces are stepped along plateaus with different elevations. This stepping of landforms records a local base level fall due to a local tectonic uplift. (ii) Central Africa is an extensive etchplain-type weathering surface - called the African Surface - from the uppermost Cretaceous (70 Ma) to the Middle Eocene (45 Ma) with a paroxysm around the Early Eocene Climatic Optimum. Restoration of this surface in Central Africa suggests very low-elevation planation surfaces adjusted to the Atlantic Ocean and Indian Ocean with a divide located around the present-day eastern branch of the East African Rift. (iii) The present-day topography of Central Africa is younger than 40 -30 Ma and records very long wavelength deformations (1000 -2000 km) with (1) the growth of the Cameroon Dome and East African Dome since 34 Ma, (2) the Angola Mountains since 15 -12 Ma increasing up to Pleistocene times and (3) the uplift of the low-elevation (300 m) Congo Basin since 10 -3 Ma. Some long wavelength deformations (several 100 km) also occurred with (1) the low-elevation Central African Rise since 34 Ma and (2) the Atlantic Bulge since 20 -16 Ma. These very long wavelength deformations record mantle dynamics, with a sharp increase of mantle upwelling around 34 Ma and an increase of the wavelength of the deformation and then of mantle convection around 10 -3 Ma.
DS201809-2032
2018
Gunn, A.G., Dorbor, J.K., Mankelow, J.M., Lusty, P.A.J., Deady, E.A., Shaw, R.A.A review of the mineral potential of Liberia.Ore Geology Reviews, Vol. 101, pp. 413-431.Africa, Liberiadiamonds

Abstract: The Republic of Liberia in West Africa is underlain mostly by Precambrian rocks of Archaean (Liberian) age in the west and of Proterozoic (Eburnean) age in the east. By analogy with similar terranes elsewhere in the world, and in West Africa in particular, the geology of Liberia is favourable for the occurrence of deposits of a wide range of metals and industrial minerals, including gold, iron ore, diamonds, base metals, bauxite, manganese, fluorspar, kyanite and phosphate. Known gold deposits, mostly orogenic in style, occur widely and are commonly associated with north-east-trending regional shear zones. Gold mining commenced at the New Liberty deposit in western Liberia in 2015, while significant gold resources have also been identified at several other sites in both Archaean and Proterozoic terranes. Liberia has large resources of itabirite-type iron ores, most of which are located in the Liberian terrane, and was the largest producer in Africa prior to the onset of civil war in 1989. Production of iron ore is currently restricted to a single mine, Yekepa, in the Nimba Range. Other important deposits, some of them previously mined, include Bong, the Western Cluster, Putu and Goe Fantro. There is a long history of alluvial diamond production in western and central Liberia, together with more than 160 known occurrences of kimberlite. Most of the known kimberlites occur in three clusters of small pipes and abundant dykes, located at Kumgbor, Mano Godua and Weasua, close to the border with Sierra Leone. Many of these are considered to be part of a single province that includes Jurassic age diamondiferous kimberlites in Sierra Leone and Guinea. Deposits and occurrences of a wide range of other metals and industrial minerals are also known. Several of these have been worked on a small scale in the past, mainly by artisanal miners, but most are poorly known in detail with sub-surface information available at only a few localities. By comparison with most other countries in West Africa, the geology of Liberia is poorly known and there has been very little systematic exploration carried out for most commodities other than gold, iron ore and diamonds since the 1960s and 1970s. Further detailed field and laboratory investigations using modern techniques are required to properly evaluate the potential for the occurrence of economic deposits of many minerals and metals in a variety of geological settings. Digital geological, geochemical, geophysical and mineral occurrence datasets, including new national airborne geophysical survey data, provide a sound basis for the identification of new exploration targets, but in almost every part of the country there is a need for new and more detailed geological surveys to underpin mineral exploration.
DS201811-2575
2018
Guotana, J.M., Morishita, T., Yamaguchi, R., Nishio, I., Tamura, A., Harigane, Y., Szilas, K., Pearson, G.Contrasting textural and chemical signatures of chromitites in the Mesoarchean Ulamertoq peridotite body, southern West Greenland.Geosciences, Vol. 8, no. 9, p. 328-Europe, Greenlandperidotite

Abstract: Peridotites occur as lensoid bodies within the Mesoarchaean orthogneiss in the Akia terrane of Southern West Greenland. The Ulamertoq peridotite body is the largest of these peridotites hosted within the regional orthogneiss. It consists mainly of olivine, orthopyroxene, and amphibole-rich ultramafic rocks exhibiting metamorphic textural and chemical features. Chromitite layers from different localities in Ulamertoq show contrasting characteristics. In one locality, zoned chromites are hosted in orthopyroxene-amphibole peridotites. Compositional zonation in chromites is evident with decreasing Cr and Fe content from core to rim, while Al and Mg increase. Homogeneous chromites from another locality are fairly uniform and Fe-rich. The mineral chemistry of the major and accessory phases shows metamorphic signatures. Inferred temperature conditions suggest that the zoned chromites, homogeneous chromites, and their hosts are equilibrated at different metamorphic conditions. In this paper, various mechanisms during the cumulus to subsolidus stages are explored in order to understand the origin of the two contrasting types of chromites.
DS201810-2326
2018
Guotana, J.M., Morishita, T., Yamaguchi, R., Nishio, I., Tamura, A., Tani, K., Harigane, Y., Szilas, K., Pearson, D.G.Contrasting textural and chemical signatures of chromitites in the Mesoarchean Ulamertoq peridotite body, southern West Greenland.MDPI Geosciences, Researchgate 19p.Europe, Greenlandperidotite

Abstract: Peridotites occur as lensoid bodies within the Mesoarchaean orthogneiss in the Akia terrane of Southern West Greenland. The Ulamertoq peridotite body is the largest of these peridotites hosted within the regional orthogneiss. It consists mainly of olivine, orthopyroxene, and amphibole-rich ultramafic rocks exhibiting metamorphic textural and chemical features. Chromitite layers from different localities in Ulamertoq show contrasting characteristics. In one locality, zoned chromites are hosted in orthopyroxene-amphibole peridotites. Compositional zonation in chromites is evident with decreasing Cr and Fe content from core to rim, while Al and Mg increase. Homogeneous chromites from another locality are fairly uniform and Fe-rich. The mineral chemistry of the major and accessory phases shows metamorphic signatures. Inferred temperature conditions suggest that the zoned chromites, homogeneous chromites, and their hosts are equilibrated at different metamorphic conditions. In this paper, various mechanisms during the cumulus to subsolidus stages are explored in order to understand the origin of the two contrasting types of chromites.
DS201805-0949
2018
Gupta, T.Carbon: the Black, the Gray and the Transparent.Springer Publication, Cost 129.00Technologycarbon

Abstract: All living things contain carbon in some form, as it is the primary component of macromolecules including proteins, lipids, nucleic acids (RNA and DNA), and carbohydrates. As a matter of fact, it is the backbone of all organic (chemistry) compounds forming different kinds of bonds. Carbon: The Black, the Gray and the Transparent is not a complete scientific history of the material, but a book that describes key discoveries about this old faithful element while encouraging broader perspectives and approaches to its research due to its vast applications. All allotropes of carbon are described in this book, along with their properties, uses, and methods of procurement or manufacturing. Black carbon is represented by coal, gray carbon is represented by graphite, and transparent carbon is represented by diamond.
DS201811-2576
2018
Gura, C., Kempton, P.D., Datta, S.Geochemistry in the critical zone; limestone shale and kimberlite weathering in the Flint Hills, Kansas. USA.Geological Society of America Annual Meeting, Vol. 50, 4, 1p. AbstractUnited States, Kansaskimberlite

Abstract: The Critical Zone is the realm where rocks meet life. This study examines the physicochemical interactions that occur when interbedded limestone-shale systems and kimberlitc eruptive materials weather to form soils. Fast weathering with extensive soil loss has been a major environmental concern in the Flint Hills. Knowledge of soil formation processes, rates of formation and loss and understanding how these processes differ in different systems are critical for managing soil as a resource. The kimberlites of Riley County, KS, are CO2-rich igneous rocks that are high in Mg and Fe; they are compositionally distinct from the Paleozoic limestones and shales found throughout the rest of the region. Bulk composition and mineralogy of the soils overlying these different bedrock types have been analyzed using X-Ray Fluorescence (XRF), X-Ray diffraction of <2mm soil fraction and <2µm soil clay fraction, bulk elemental extraction, and particle size analyses. Results show that the kimberlitic soils have higher concentrations of Fe, Mg, Ca, K and some trace elements (e.g. Ti, Ni, Cu). The weathering products differ mineralogically as well, e.g. lizardite is abundant in kimberlitic soils and absent from the limestone terrane. As a result, kimberlite-sourced soils have significantly different physical properties than the thin limestone-sourced soils surrounding them. Particle size analysis shows that the limestone-shale soils have a higher proportion of silt-sized particles whereas the kimberlitic soils have more clay (10.55% vs. 8.06%) and significantly more sand (36.12% vs. 14.83%). Mineralogy was determined for all <2mm fractions and for some <2µm soil clay fraction to understand the association and mobility of these major and trace elements in the respective soils. Interestingly some of the similarities between the kimberlite and limestone-shale soils suggests that loess/wind-blown sediment is making a significant contribution to the soil profile. Kimberlite-sourced and limestone-shale-sourced soils produce different weathering products and could potentially have agricultural significance in terms of ionic and nutrient mobility.
DS201811-2577
2018
Gurenko, A.A., Sobolev, A.V.Can orthopyroxene be present in the source of Toro-Ankole, East African Rift, kamafugites?Journal of Petrology, Vol. 59, 8, pp. 1517-1550.Africa, Ugandakamafugites

Abstract: We have studied mineral-hosted melt, crystal and fluid inclusions from two ugandite, one mafurite and two katungite samples from the Toro-Ankole volcanic province in the East African Rift, which is the archetypal location for kamafugitic rocks. A main finding of our study is the presence of orthopyroxene as inclusions in an early generation of olivine from all three types of kamafugites, suggesting interaction of a carbonate-rich metasomatic agent with lithospheric peridotite mantle that may have caused almost complete dissolution of orthopyroxene. This process was preceded, accompanied or followed by the formation of phlogopite-clinopyroxene veins resulting from interaction of F-rich and low H2O/CO2 metasomatic fluids with the mantle rocks, which then became the source of the Toro-Ankole kamafugites. Pressure-temperature (P-T) estimates suggest that the parental kamafugitic melts last equilibrated with their source rocks at ?16?±?8?kbar and ?1160?±?130°C. This implies that they could have originated significantly below the solidus of dry, carbonated peridotite, but above the solidus of phlogopite-bearing clinopyroxenite. We conclude that the Toro-Ankole kamafugites originated by very low degrees of partial melting at moderately oxidized conditions (?FMQ = +2•2?±?0•4?atm log units, where FMQ is fayalite-magnetite-quartz buffer) under a high geothermal gradient of 60-80?mW?m?2, in response to lithospheric extension and probable association with an adjacent mantle plume. We estimate that differentiation of parental ugandite, mafurite and katungite magmas could have occurred at depths <12?km in the T range 1150-850°C. Laboratory-heated, homogenized melt inclusions trapped by a second generation of olivine and clinopyroxene are characterized by remarkable silica-undersaturation, compared with mid-ocean ridge basalt and ocean island basalt magmas, with high concentrations of alkalis, Ti, Ba, Sr and Zr, but varying to very low concentrations of Al and Ca. Such alkali-rich, strongly evolved melts might have resulted from extreme (>95%) fractional crystallization of the parental magmas, assuming their chemical compositions to be similar to those of the respective lavas. However, this estimate is about three times higher than the modal amount of phenocrysts in the lavas that could be reinforced by the presence of excess cognate crystals and/or xenocrysts in the lavas. Strong oxidation from FMQ?+?2 to FMQ?+?4 to +?5•2?atm log units of the evolved mafuritic magmas at ?900-1000°C has occurred during the final stage of magma evolution at very shallow crustal depths or possibly directly in the lava flow.
DS201804-0698
2017
Haggerty, S.E.Majorite-indicative ultradeep ( >300 km) xenoliths with spinel associations from the Jagersfontein kimberlite, South Africa.South African Journal of Geology, Vol. 120, 1, pp. 1-20.Africa, South Africadeposit - Jagersfontein

Abstract: Our earlier studies continued in a diligent search for rare ultradeep xenoliths in the kimberlite diatreme at Jagersfontein. The search has met with moderate success insofar as 20 majorite-bearing (decomposed to *gt + lamellar px) xenoliths are identified. Discrete gts (1 to 2 cm), gt-rich layers (2 to 3 cm) in lherzolites, and rare megacrystic gts (>3 cm) from xenoliths characterize the ultradeep suite. Pyroxene lamellae are crystallographically controlled along {111} gt planes, but px may also be prismatic, lensoidal, coarsely graphic, or annular to gt; jigsaw, rather than 120° dihedral textures, are typical. Gt ranges from Pyr68-74 mole% and CaO - Cr2O3 relations, with two exceptions, are distinctly lherzolitic. Cpx = Wo37-46 mole%, Jd3-19 mole%, with 0.4 to 2.4 wt% Cr2O3; opx = 92 to 95 mole% en, and ol averages 92.5 mole% with maximum wt% 0.1 CaO, 0.4 NiO, and 0.1 Cr2O3. A new class of 10 ultradeep xenoliths has lamellar spinel (Cr/Cr + Al = 0.74; Mg/Mg + Fe = 0.58) in addition to cpx with gt >3wt% Cr2O3 (c.f. 0.5 to 1.5 for sp-free types). Five samples are texturally linked but are compositional outliers to the central body of data: two are sp hosts (Cr# 0.69, Mg# 0.76) and (Cr# 0.74, Mg# 0.57) to gt (Pyr72) + cpx (Jd14); one is a gt megacryst (Pyr80) with sp (Cr# 57, Mg# 69); and the remaining two are unusually rich in chromium with gt = 7.3 to 8.2 wt% Cr2O3, rimmed by cpx (2.3 to 3-3 wt% Cr2O3). In addition, there are 17 xenoliths with compositional affinities to the ultradeep suite but lacking the texturally diagnostic lamellar intergrowths of cpx in gt are possibly completely equilibrated to gt + irregular cpx. Results from the new collection substantiate our earlier conclusions that the mantle was sampled by thejagersfontein kimberlite from the lower lithosphere (250 to 350 km) and the transition zone (435 km) with diagnostic high P-T majorite in lherzolite that decomposed to gt + px at one or more interruptive stations (e.g. lithosphere-asthenosphere boundary), and at one or another time, en route to the surface. Homogeneous majorite occurs as diamond inclusions at Jagersfontein but these are eclogitic, leading to the proposition that the source region in the asthenosphere was an unassimilated mixture of lherzolite and eclogite in the Mid-Cretaceous at the time of kimberlite sampling. Important questions arise: Is majorite primordial; did majorite form exclusively from the transition of pyroxene; or did subsequent dissolution into coexisting garnet take place? Why has majorite not been identified in eclogite, nor diamonds of lherzolitic affinity? Does the formation of majorite and the crystallization of encapsulating diamond imply distinct high P-T events?
DS201811-2578
2015
Hainschwang, T., Notari, F.Standards and protocols for emerald analysis in gem testing laboratories.InColor, December pp. 106-114.Globalemeralds
DS201812-2815
2018
Haley, W.Diavik diamond mine update.2018 Yellowknife Geoscience Forum , p. 27-28.Canada, Northwest Territoriesdeposit - Diavik

Abstract: Over the past year, the Diavik Diamond Mine continued to make significant contributions through its mining operation on Lac de Gras, NWT. The mine is the second largest diamond mine in the NWT (and in Canada), but the largest producer of Canadian rough diamonds. Production has been augmented in 2018 with the official opening and start of mining from a new ore body called A-21.
DS201811-2579
2019
Hamzeh, A., Mehramuz, M.The depth estimation of subsurface anomalies using probability tomography imaging method from airborne vertical gravity gradient. ( Not specific to diamonds).Journal of African Earth Sciences, Vol. 149, pp. 207-214.Globalgeophysics - gravity

Abstract: In this article, the probability tomography imaging method is applied to airborne vertical gravity gradient data to detect anomalies and estimate their depths and locations. First, the subsurface is divided into a 3D regular grid. Then, the probability tomography function is calculated at each grid node, and the obtained grid values are plotted. The zones of the highest values are the most probable areas for the buried bodies. It is noted that the results fall in the range [-1, +1] that represents the mass excess or mass deficit of density relative to the density of the host volume. The approach is applied to a sphere model and a cube model at certain flight altitudes. The results demonstrate that the approximate mass distribution and depth estimation derived from the approach are reliable up to a certain flight altitude.
DS201809-2033
2018
Hansen, R.F., Rennie, L.J.The first Australian diamond.The Australian Gemmologist, Vol. 26, 9-10, pp. 205-208.Australia, New South Wales diamond - Ophir

Abstract: This article describes the first Australian diamond to reach the shores of Britain. Originally donated to the Museum of Practical Geology, it now resides in the Natural History Museum, London. The diamond came from the gold-mining district of Ophir, near Bathurst in New South Wales, and is possibly the earliest found and recognised as a diamond in Australia.
DS201802-0241
2018
Hardman, M.F., Pearson, D.G., Stachel, T., Sweeney, R.J.Statistical approaches to the discrimination of crust and mantle derived low Cr garnet - Major element based methods and their application to diamond exploration.Journal of Geochemical Exploration, Vol. 186, pp. 24-35.Mantlegarnet diamond exploration

Abstract: In diamond exploration, the accurate distinction between garnets from the crust or mantle, or from those having a cognate origin with kimberlite (low-Cr megacrysts), is important for the assessment of indicator mineral samples; misclassifications potentially result in costly misdirection of exploration efforts. Existing literature databases and graphical classification schemes for garnets suffer from a paucity of craton-derived, lower-crustal garnets that - as shown here - are among the most difficult to distinguish from garnets of mantle origin. To improve this situation, a large database of new and literature garnet major element analyses has been compiled. Using this dataset, it is shown that the conventionally used Mg# (Mg/(Mg + Fe)) vs. Ca# (Ca/(Mg + Ca)) plot (Schulze, 2003) for discrimination of crust and mantle garnets results in significant overlap (39.2% crustal failure rate using our dataset). We propose a new graphical classification scheme that uses the parameters ln(Ti/Si) and ln(Mg/Fe) to discriminate low-Cr garnets of crust origin from those of a mantle eclogite-pyroxenite origin with an error rate of 10.1 ± 2.1% at the 95% confidence level (assessed via K-fold cross-validation with ten random test datasets), significantly lower than existing methods. Multivariate statistical solutions, which incorporate a wide selection of geochemical variables, represent additional possibilities for discrimination. Using our new database, logistic regression (LR) and linear discriminant analysis (LDA) approaches are evaluated and new crust-mantle garnet discrimination schemes derived. The resulting solutions, using a wide variety of cations in garnet, provide lower misclassification rates than existing literature schemes. Both LR and LDA are successful discrimination techniques with error rates for the discrimination of crust from mantle eclogite-pyroxenite of 7.5 ± 1.9% and 8.2 ± 2.3%, respectively. LR, however, involves fewer stipulations about the distribution of training data (i.e., it is more "robust") and can return an estimate for probability of classification certainty for single garnets. New data from diamond exploration programs can be readily classified using these new graphical and statistical methods. As the discrimination of low-Cr megacrysts from mantle eclogite-pyroxenite is not the focus of this study, we recommend the method of Schulze (2003) or Grütter et al. (2004) for low-Cr megacryst discrimination to identify megacrysts in the "mantle" suite. Runstreams for our LDA and LR approaches using the freeware "R" are provided for quick implementation.
DS201808-1750
2018
Hardman, M.F., Pearson, D.G., Stachel, T., Sweeney, R.J.Statistical approaches to the discrimination of mantle - and crust derived low Cr garnets using major and trace element data.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0622-7 10p.Technologygarnet classification
DS201801-0021
2017
Harmer, R.E.The Bulhoek carbonatite complex, South Africa: evidence for magmatic crystallization of dolomite at low pressures and the petogenetic implications.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 5-7.Africa, South Africadeposit - Bulhoek

Abstract: In many plutonic carbonatite complexes the dominant carbonatite type is calcitic and there is a tendency to assume that dolomitic carbonatites are insignificant relative to calcitic types. While calcitic carbonatites dominate in regions of rifting, e.g. the East African Rift System, dolomitic carbonatites are more abundant in the Archaean Kaapvaal and Zimbabwean Cratons of southern Africa and the Archaean parts of the Canadian Shield (Harmer and Gittins, 1997). The ~1.4Ga Newania carbonatite, the only dolomite carbonatite complex described from India, is located within the Archaean Aravalli Craton (Ray et al., 2013). Increased exploration activity on carbonatites in response to the short-lived 2009-2012 REE boom has highlighted the importance of dolomitic carbonatites as targets for REE (and P) deposits: for example, of the 10 advanced African REE projects (i.e. deposits with a defined resource) associated with carbonatites, 7 are hosted within dolomite carbonatites (Harmer and Nex, 2016). This study reports a detailed petrological study of the Bulhoek Carbonatite Complex, one of a number of carbonatite and alkaline igneous complexes that were emplaced into the central Kaapvaal Craton at 1.4 Ma (Hanson et al., 2006). The Bulhoek Complex comprises three centres of intrusion of magnesian carbonatite into granitic and granophyric components of the 2.05Ga Bushveld Complex over a linear 20 km long zone. At all three centres, areas of fenitised granite enclose sheeted intrusions of dolomitic carbonatite of similar composition and intrusive style. No alkaline silicate magmatic rocks have been in the vicinity of the intrusive centres. Carbonatites were emplaced in three discrete intrusive episodes: initial intrusion was accompanied by significant shattering of the country rocks and produced a sequence of medium-grained, flow foliated dolomite carbonatites (C1) containing clasts of fenitised country rock granites along with xenoliths of fenitised ferrogabbro and magnetite transported from Bushveld Upper Zone cumulates underlying the granites. A second intrusive pulse produced cross-cutting sheets of medium- to coarse-grained dolomitic carbonatite free of xenoliths (C2) that make up the bulk of the carbonatite at each intrusive centre. Evidence that both C1 and C2 carbonatites intruded as crystal-rich mushes include strongly developed sub-vertical foliations, deflection of foliations around large fenite xenoliths and the common occurrence of folded foliations through drag effects at contacts with country rock and in C2 intrusions along contacts with C1 carbonatites.
DS201808-1751
2018
Harris, G.A., Pearson, D.G., Liu, J., Hardman, M.F., Snyder, D.B., Kelsch, D.Mantle composition, age and geotherm beneath the Darby kimberlite field, west central Rae craton.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0609-4 14p.Canada, Northwest Territoriesdeposit - Darby

Abstract: New geological and geophysical research on Canada’s Rae craton are providing an increasingly good baseline for diamond exploration. This study uses mantle xenoliths and xenocrysts from the Darby property, located ~200 km southwest of the community of Kugaaruk, Nunavut, to provide new information on the lithospheric mantle and diamond potential of the western portion of the central Rae. Peridotite xenoliths containing enough fresh olivine have a median Mg# value of 92.5, indistinguishable from the median value of 92.6 typical of cratonic peridotites world-wide. Only of the 14 peridotitic xenoliths contain fresh garnet. Of these, garnet in one sample is classified as harzburgitic (G10), giving a minimum pressure of 4.7 GPa using the P38 geobarometer (38 mW/m2 model geothermal gradient), while garnets from three peridotites are classified as lherzolitic (G9). 52 garnets picked from concentrate have lherzolitic affinities. Lherzolitic diopsides from kimberlite heavy mineral concentrate yield a lithospheric thickness of ~ 200 km. The four garnet peridotite xenoliths and 49 peridotitic garnets from concentrate yield two distinct modes in mantle sampling depths using Ni thermometry, when projected to the Cpx geotherm. A cluster of samples from the higher Ca/Cr lherzolitic garnets equilibrated at 765 to 920 °C with a group of peridotitic garnets (50 % of xenoliths and 28 % of concentrate) from the lower Ca/Cr lherzolitic garnets with anomalously high Ti concentrations yielding super-adiabatic TNi values The aluminum-in-olivine thermometer applied to olivines filtered to be “garnet facies yielded a mantle sampling portion of the mantle cargo from the diamond stability field. A suite of pyroxenitic xenoliths are a feature of each Darby kimberlite target. New screening techniques indicate that these rocks likely originate close to the crust mantle boundary. Osmium isotope analyses of the Darby peridotites reveal whole-rock Re-depletion ages ranging from Mesoarchean to Paleoproterozoic. The pyroxenite xenoliths have very radiogenic Os isotope compositions and provide the first age information from pyroxenites/“eclogites” beneath the Rae craton. Their resulting Archean whole rock TMA ages are consistent with a Mesoarchean age of the western Central Rae lithosphere older than the lithosphere beneath the Repulse Bay block in the East section of the Rae craton (Liu et al., 2016. Precambrian Research 272). The highly depleted olivine compositions, thick cold lithosphere, and Archean ages of the Darby peridotite xenoliths clearly indicate the presence of 200 km thick cold cratonic lithospheric mantle beneath the western segment of the central Rae craton circa 540 Ma. The Archean model ages of most of the pyroxenites support this, notwithstanding the fact that some of these rocks could be sampling either crust or mantle lithologies very close to the crust-mantle boundary. Mantle sampling took place well into the diamond stability field at Darby.
DS201804-0699
2018
Harris, J.W.A history of diamond.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 21-24. abstractGlobalhistory
DS201811-2580
2018
Hawkesworth, C.J., Brown, M.Earth dynamics and the development of plate tectonics.Philosophical Transactions Royal Society A, Vol. A376: doi://dx.doi.org/10.1098/rsta.2018.0228 5p.Mantleplate tectonics

Abstract: "Why does Earth have plate tectonics?" stands among the top research questions in the Earth Sciences. Plate tectonics developed in the last 4 billion years. This meeting will explore the evidence for the development of plate tectonics, contrast the terrestrial record with those from neighbouring planets, evaluate the conditions required for plate tectonics, and discuss implications for environmental conditions and development of the biosphere.
DS201809-2034
2018
He, L., Zhang, L.Thermal evolution of cratons in China. ReviewJournal of Asian Earth Sciences, Vol. 164, pp. 237-247.Chinageothermometry
DS201801-0022
2017
Hecht, H., Oguchi, T.Global evalusation of erosion rates in relation to tectonics. Progress in Earth and Planetary Science, 7p. PdfGlobaltectonics

Abstract: Understanding the mechanisms and controlling factors of erosion rates is essential in order to sufficiently comprehend bigger processes such as landscape evolution. For decades, scientists have been researching erosion rates where one of the main objectives was to find the controlling factors. A variety of parameters have been suggested ranging from climate-related, basin morphometry and the tectonic setting of an area. This study focuses on the latter. We use previously published erosion rate data obtained mainly using 10Be and sediment yield and sediment yield data published by the United States Geological Survey. We correlate these data to tectonic-related factors, i.e., distance to tectonic plate boundary, peak ground acceleration (PGA), and fault distribution. We also examine the relationship between erosion rate and mean basin slope and find significant correlations of erosion rates with distance to tectonic plate boundary, PGA, and slope. The data are binned into high, medium, and low values of each of these parameters and grouped in all combinations. We find that groups with a combination of high PGA (>?0.2.86 g) and long distance (>?1118.69 km) or low PGA (
DS201812-2816
2018
Helmstaedt, H.Tectonic and structural controls on diamondiferous kimberlite and lamproite and their bearing on area selection for diamond exploration.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 1-48.Globaltechnology - diamond exploration
DS201805-0950
2018
Heron, P.J., Pysklywec, R.N., Stephenson, R.Exploring the theory of plate tectonics: the role of mantle lithosphere structure.Geological Society of London, Special Publication, Vol. 470, doi:10.1144 /SP470.7Mantletectonics

Abstract: This review of the role of the mantle lithosphere in plate tectonic processes collates a wide range of recent studies from seismology and numerical modelling. A continually growing catalogue of deep geophysical imaging has illuminated the mantle lithosphere and generated new interpretations of how the lithosphere evolves. We review current ideas about the role of continental mantle lithosphere in plate tectonic processes. Evidence seems to be growing that scarring in the continental mantle lithosphere is ubiquitous, which implies a reassessment of the widely held view that it is the inheritance of crustal structure only (rather than the lithosphere as a whole) that is most important in the conventional theory of plate tectonics (e.g. the Wilson cycle). Recent studies have interpreted mantle lithosphere heterogeneities to be pre-existing structures and, as such, linked to the Wilson cycle and inheritance. We consider the current fundamental questions in the role of the mantle lithosphere in causing tectonic deformation, reviewing recent results and highlighting the potential of the deep lithosphere in infiltrating every aspect of plate tectonics processes.
DS201812-2817
2018
Heron, P.J., Pysklywec, R.N., Stephenson, R.Exploring the theory of plate tectonics: the role of mantle lithosphere structure.http://sp.lyellcollection.org, doi.org/10.1144/ SP470.7Mantleplate tectonics

Abstract: This review of the role of the mantle lithosphere in plate tectonic processes collates a wide range of recent studies from seismology and numerical modelling. A continually growing catalogue of deep geophysical imaging has illuminated the mantle lithosphere and generated new interpretations of how the lithosphere evolves. We review current ideas about the role of continental mantle lithosphere in plate tectonic processes. Evidence seems to be growing that scarring in the continental mantle lithosphere is ubiquitous, which implies a reassessment of the widely held view that it is the inheritance of crustal structure only (rather than the lithosphere as a whole) that is most important in the conventional theory of plate tectonics (e.g. the Wilson cycle). Recent studies have interpreted mantle lithosphere heterogeneities to be pre-existing structures and, as such, linked to the Wilson cycle and inheritance. We consider the current fundamental questions in the role of the mantle lithosphere in causing tectonic deformation, reviewing recent results and highlighting the potential of the deep lithosphere in infiltrating every aspect of plate tectonics processes.
DS201806-1226
2018
Hoare, M.Bring on blockchain?Gems&Jewellery www.gem-a-com, Spring, pp. 38-39.Technologyblockchain
DS201810-2327
2018
Holloway, G.What size does that diamond look like? Carat weight patent pending "Looks Like Size".The Australian Gemmologist, Vol. 26, 9-10, pp. 240-248.Globaldiamond morphology
DS201809-2035
2018
Holtstam, D., Camara, F., Skogby, H., Karlsson, A., Langhof, J.Description and recognition of potassic richterite, an amphibole supergroup mineral from the Pajsberg ore field, Varmland, Sweden.Mineralogy and Petrology, doi.org/101007/ s00710-018-0623-6 10p.Europe, Swedenalkaline

Abstract: Potassic-richterite, ideally AKB(NaCa)CMg5TSi8O22W(OH)2, is recognized as a valid member of the amphibole supergroup (IMA-CNMNC 2017-102). Type material is from the Pajsberg Mn-Fe ore field, Filipstad, Värmland, Sweden, where the mineral occurs in a Mn-rich skarn, closely associated with mainly phlogopite, jacobsite and tephroite. The megascopic colour is straw yellow to grayish brown and the luster vitreous. The nearly anhedral crystals, up to 4 mm in length, are pale yellow (non-pleochroic) in thin section and optically biaxial (?), with ??=?1.615(5), ??=?1.625(5), ??=?1.635(5). The calculated density is 3.07 g•cm?1. VHN100 is in the range 610-946. Cleavage is perfect along {110}. EPMA analysis in combination with Mössbauer and infrared spectroscopy yields the empirical formula (K0.61Na0.30Pb0.02)?0.93(Na1.14Ca0.79Mn0.07)?2(Mg4.31Mn0.47Fe3+0.20)?5(Si7.95Al0.04Fe3+0.01)?8O22(OH1.82F0.18)?2 for a fragment used for collection of single-crystal X-ray diffraction data. The infra-red spectra show absorption bands at 3672 cm?1 and 3736 cm?1 for the ? direction. The crystal structure was refined in space group C2/m to R1?=?3.6% [I >?2?(I)], with resulting cell parameters a?=?9.9977(3) Å, b?=?18.0409(4) Å, c?=?5.2794(2) Å, ??=?104.465(4)°, V?=?922.05(5) Å3 and Z?=?2. The A and M(4) sites split into A(m) (K+), A(2/m) (Na+), A(2) (Pb2+), and M(4?) (Mn2+) subsites, respectively. The remaining Mn2+ is strongly ordered at the octahedrally coordinated M(2) site, possibly together with most of Fe3+. The skarn bearing potassic-richterite formed at peak metamorphism, under conditions of low SiO2 and Al2O3 activities and relatively high oxygen fugacities.
DS201807-1497
2018
Holtzhausen, C., Moodley, T.Practical roadmapping of technology and digital transformation in mining.SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 65-72.Technologydigital solutions
DS201806-1227
2018
Homrighausen, S., Hoernle, K., Hauff, J., Geldmacher, J., Garbe-Schonberg, D.Global distribution of the HIMU end member: formation through Archean plume lid tectonics.Earth Science Reviews, Vol. 182, pp. 85-101.Globaltectonics

Abstract: Oceanic basalts reflect the heterogeneities in the earth's mantle, which can be explained by five mantle end members. The HIMU end member, characterized by high time-integrated ? (238U/204Pb), is defined by the composition of lavas from the ocean islands of St. Helena, South Atlantic Ocean and Mangaia and Tubuai (Cook-Austral Islands), South Pacific Ocean. It is widely considered to be derived from a mantle reservoir that is rarely sampled and not generally involved in mixing with the other mantle components. On the other hand, the FOZO end member, located at the FOcal ZOne of oceanic volcanic rock arrays on isotope diagrams, is considered to be a widespread common component with slightly less radiogenic 206Pb/204Pb and intermediate Sr-Nd-Hf isotopic compositions. Here we present new major and trace element, Sr-Nd-Pb-Hf isotope and geochronological data from the Walvis Ridge and Richardson Seamount in the South Atlantic Ocean and the Manihiki Plateau and Eastern Chatham Rise in the southwest Pacific Ocean. Our new data, combined with literature data, document a more widespread (nearly global) distribution of the HIMU end member than previously postulated. Our survey shows that HIMU is generally associated with low-volume alkaline, carbonatitic and/or kimberlitic intraplate volcanism, consistent with derivation from low degrees of melting of CO2-rich sources. The majority of end member HIMU locations can be directly related to hotspot settings. The restricted trace element and isotopic composition (St. Helena type HIMU), but near-global distribution, point to a deep-seated, widespread reservoir, which most likely formed in the Archean. In this context we re-evaluate the origin of a widespread HIMU reservoir in an Archean geodynamic setting. We point out that the classic ocean crust recycling model cannot be applied in a plume-lid dominated tectonic setting, and instead propose that delamination of carbonatite-metasomatized subcontinental lithospheric mantle could be a suitable HIMU source.
DS201809-2036
2018
Hoover, D.B., Karfunkel, J., Walde, D., Moraes, R.A.V., Michelfelder, G., Henger, F.E., Ribeira, L.C., Krambock, K.The Alto Paranaiba region, Brazil: a continuing source for pink diamonds?The Australian Gemmologist, Vol. 26, 9-10, pp. 196-204.South America, Brazildeposit - Alto Paranaiba
DS201801-0023
2017
Hopp, J., Viladkar, S.G.Noble gas composition of Indian carbonatites ( Amba Dongar, Siriwasan): implications on mantle source compositions and late stage hydrothermal processes.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 10.Indiadeposit - Amba Dongar, Siriwasan

Abstract: Within a stepwise crushing study we determined the noble gas composition of several calcite separates, one aegirine and one pyrochlore-aegirine separate of the carbonatite ring dyke complex of Amba Dongar and carbonatite sill complex of Siriwasan, India. Both carbonatites are related to the waning stages of volcanic activity of the Deccan Igneous Province ca. 65 Ma ago. Major observations are a clear radiogenic 4He* and nucleogenic 21Ne* imprint related to insitu production from U and Th in mineral impurities, most likely minute apatite grains. However, in first crushing steps of most calcites from Amba Dongar a well-resolvable mantle neon signal is observed, with lowest air-corrected mantle 21Ne/22Ne-compositions equivalent to the Réunion hotspot mantle source. In case of the aegirine separate from Siriwasan we found a neon composition similar to the Loihi hotspot mantle source. We conclude that previously derived models of a lithospheric mantle source containing recycled components in generation of the carbonatitic magmas from Amba Dongar are obsolete. Instead, the mantle source of both investigated carbonatite complexes is related to a primitive mantle plume source that we tentatively ascribe to the postulated Deccan mantle plume. If, as is commonly suggested, the present location of the Deccan mantle plume source is below Réunion Island, the currently observed more nucleogenic neon isotopic composition of the Réunion hotspot might be obliterated by significant upper mantle contributions, similar to Kilauea Volcano, Hawai’i. In addition, compared with other carbonatite complexes worldwide a rather significant contribution of atmospheric noble gases is observed. This is documented in cut-off 20Ne/22Ne-ratios of ca. 10.2 (Amba Dongar) and 10.45 (Siriwasan) and cut-off 40Ar/36Ar-ratios of about 1500. This atmospheric component likely had been added at shallow levels during the emplacement process. However, understanding the late-stage interaction between atmospheric gases and magmatic mantle fluids still requires further investigation.
DS201805-0951
2018
Hopp, J., Viladkar, S.G.Noble gas composition of Indian carbonatites ( Amba Dongar, Siriwasan): implications on mantle source compositions and late stage hydrothermal processes.Earth Planetary Science Letters, Vol. 492, pp. 186-196.Indiacarbonatite

Abstract: Within a stepwise crushing study we determined the noble gas composition of several calcite separates, one aegirine and one pyrochlore-aegirine separate of the carbonatite ring dyke complex of Amba Dongar and carbonatite sill complex of Siriwasan, India. Both carbonatites are related to the waning stages of volcanic activity of the Deccan Igneous Province ca. 65 Ma ago. Major observations are a clear radiogenic 4He and nucleogenic 21Ne imprint related to in situ production from U and Th in mineral impurities, most likely minute apatite grains, or late incorporation of crustal fluids. However, in first crushing steps of most calcites from Amba Dongar a well-resolvable mantle neon signal is observed, with lowest air-corrected mantle 21Ne/22Ne-compositions equivalent to the Réunion hotspot mantle source. In case of the aegirine separate from Siriwasan we found a neon composition similar to the Loihi hotspot mantle source. This transition from a mantle plume signal in first crushing step to a more nucleogenic signature with progressive crushing indicates the presence of an external (crustal) or in situ nucleogenic component unrelated and superposed to the initial mantle neon component whose composition is best approximated by results of first crushing step(s). This contradicts previous models of a lithospheric mantle source of the carbonatitic magmas from Amba Dongar containing recycled crustal components which base on nucleogenic neon compositions. Instead, the mantle source of both investigated carbonatite complexes is related to a primitive mantle plume source that we tentatively ascribe to the postulated Deccan mantle plume. If, as is commonly suggested, the present location of the Deccan mantle plume source is below Réunion Island, the currently observed more nucleogenic neon isotopic composition of the Réunion hotspot might be obliterated by significant upper mantle contributions. In addition, compared with other carbonatite complexes worldwide a rather significant contribution of atmospheric noble gases is observed. This is documented in cut-off 20Ne/22Ne-ratios of ca. 10.2 (Amba Dongar) and 10.45 (Siriwasan) and cut-off 40Ar/36Ar-ratios of about 1500. This atmospheric component had been added at shallow levels during the emplacement process or later during hydrothermal alteration. However, understanding the late-stage interaction between atmospheric gases and magmatic mantle fluids still requires further investigation.
DS201809-2037
2018
Hopp, T., Kleine, T.Nature of late accretion to Earth inferred from mass dependent Ru isotopic compositions of chondites and mantle peridotites.Earth and Planetary Science Letters, Vol. 494, 1, pp. 50-59.Mantleperidotites

Abstract: Elevated abundances of highly siderophile elements in Earth's mantle are thought to reflect the late accretion of primitive material after the cessation of core formation, but the origin of this material, and whether or not it can be linked to specific types of meteorites remain debated. Here, mass-dependent Ru isotopic data for chondrites and terrestrial peridotites are reported to evaluate the chemical nature and type of the late-accreted material. After correction for nucleosynthetic Ru isotope anomalies, enstatite, ordinary and carbonaceous chondrites all have indistinguishable mass-dependent Ru isotopic compositions. Thus, neither distinct formation conditions in the solar nebula nor parent body processes resulted in significant mass-dependent Ru isotope fractionation. All five terrestrial peridotites analyzed have mass-dependent Ru isotopic compositions that are indistinguishable from each other and from the composition of chondrites. The chondritic mass-dependent Ru isotopic composition of Earth's mantle is difficult to reconcile with prior suggestions that the late accretionary assemblage was a mixture of chondrites with a chemically evolved metal component. Although this mixture can reproduce the suprachondritic Ru/Ir inferred for Earth's mantle, it consistently predicts a heavy Ru isotopic composition of Earth's mantle with respect to chondrites. This is because metal components with elevated Ru/Ir are also enriched in heavy Ru isotopes, resulting from isotope fractionation during core crystallization. Thus, if late accretion involved impacts of differentiated protoplanetary bodies, then the projectile cores must have been either homogenized upon impact, or added to Earth's mantle completely, because otherwise Earth's mantle would have inherited a non-chondritic mass-dependent Ru isotopic composition from the unrepresentative sampling of core material.
DS201810-2328
2018
Hopper, E., Fischer, K.M.The changing face of the lithosphere, asthenosphere boundary: imaging continental scale patterns in upper mantle structure across the contiguous U.S. with Sp converted waves.Geochemistry, Geophysics, Geosystems, Vol. 19, 8, pp. 2593-2614.United Statesgeophysics - seismic

Abstract: Juxtaposed terranes of highly varied tectonic history make up the contiguous U.S.: the tectonically active western U.S., the largely quiescent Archean and Proterozoic cratons of the central U.S., and the Phanerozoic orogen and rifted margin of the eastern U.S. The transitions between these regions are clearly observed with Sp converted wave images of the uppermost mantle. We use common conversion point stacked Sp waves recorded by EarthScope's Transportable Array and other permanent and temporary broadband stations to image the transition from a strong velocity decrease at the lithosphere?asthenosphere boundary (or LAB) beneath the western U.S. to deeper, less continuous features moving east that largely lie within the lithosphere. Only sparse, localized, weak phases are seen at LAB depths beneath the cratonic interior. Instead, we observe structures within the cratonic lithosphere that are most prominent within the Archean lithosphere of the Superior Craton. The transition from west to east is clearly revealed by cluster analysis, which also shows eastern U.S. mantle velocity gradients as more similar to the western U.S. than the ancient interior, particularly beneath New England and Virginia. In the western U.S., the observed strong LAB indicates a large enough velocity gradient (an average velocity drop of 10?±?4.5% distributed over 30?±?15 km) to imply that melt has ponded beneath the lithosphere.
DS201808-1752
2018
Hosseini, K., Mathews, K.J., Sigloch, K., Shephard, G.E., Domeier, M., Tsekhmistrenko, M.SubMachine: web based tools for exploring seismic tomography and other models of Earth's deep interior.Geochemistry, Geophysics, Geosystems, Vol. 19, 5, pp. 1464-1483.Mantlegeophysics - seismic

Abstract: SubMachine is a collection of web-based tools for the interactive visualisation, analysis, and quantitative comparison of global-scale, volumetric (3-D) data sets of the subsurface, with supporting tools for interacting with other, complementary models and data sets as listed below. In short, SubMachine is a computational engine (Machine) to visualize models and datasets of the sub-surface (Sub).
DS201807-1498
2018
Houlton, B.Z., Morford, S.L., Dahlgren, R.A.Convergent evidence for Wide spread rock nitrogen sources in Earth's surface environment.Science, Vol. 360, pp. 58-62.Mantlenitrogen

Abstract: Nitrogen availability is a pivotal control on terrestrial carbon sequestration and global climate change. Historical and contemporary views assume that nitrogen enters Earth’s land-surface ecosystems from the atmosphere. Here we demonstrate that bedrock is a nitrogen source that rivals atmospheric nitrogen inputs across major sectors of the global terrestrial environment. Evidence drawn from the planet’s nitrogen balance, geochemical proxies, and our spatial weathering model reveal that ~19 to 31 teragrams of nitrogen are mobilized from near-surface rocks annually. About 11 to 18 teragrams of this nitrogen are chemically weathered in situ, thereby increasing the unmanaged (preindustrial) terrestrial nitrogen balance from 8 to 26%. These findings provide a global perspective to reconcile Earth’s nitrogen budget, with implications for nutrient-driven controls over the terrestrial carbon sink.
DS201810-2329
2018
Howarth, G.H.Olivine megacryst chemistry, Monastery kimberlite: constraints on the mineralogy of the HIMU mantle reservoir in southern Africa.Lithos, Vol. 314-315, pp. 658-668.Africa, South Africadeposit - Monastery

Abstract: Olivine phenocryst chemistry is a useful tracer of mantle source lithology as olivine is typically the first mineral to crystallize in a range of mafic to alkaline magma types and contains geochemical information about the primary parent magma composition. It is particularly useful in discriminating between pyroxenite (i.e.,recycled crustal component) and peridotite mantle source lithologies. Radiogenic isotope studies of HIMU basalts have shown the important role of a recycled crustal component in the source. However, olivine chemistry of HIMU basalts suggests a dominantly peridotitic mantle source with a subduction-derived metasomatic carbonate component. To further investigate how olivine chemistry can be used to understand the source of HIMU magmas, I present major and trace element data for olivine megacrysts related to the 89?Ma Cr-poor megacryst suite from the Monastery kimberlite (South Africa), which have previously been interpreted to crystallize at high P-T conditions of ~1400?°C and ~5?GPa from a magma sourced from a HIMU reservoir. Olivine megacrysts have high-Ni concentrations at a given Fo (forsterite) content, overlapping ocean island basalts (OIB) interpreted to have formed from pyroxenite-dominated sources but are distinct from typical olivine in HIMU basalts. However, they have low 100*Mn/Fe (0.8-1.1) and no correlation is observed between Ni and trace elements indicative of recycled components such as Co, Li, or Zn. The olivine megacryst chemistry is similar to that of aillikite olivine interpreted to be controlled by phlogopite in the source rather than pyroxenite. Comparison with olivine chemistry from orangeites/Group II kimberlites (sourced from phlogopite-rich mantle lithologies) supports a phlogopite controlon low 100*Mn/Fe in olivine. Further comparison with olivine phenocryst chemistry of HIMU melilitites (76-58?Ma) in southern Africa suggests a mineralogically heterogeneous HIMU reservoir formed by metasomatic modification of the lithospheric mantle in southern Africa. Thus, olivine megacryst chemistry supports interpretations for the recycled component of the HIMU reservoir as mineralogically complex metasomatic lithologies formed by the infiltration of subduction-derived melts into the base of the lithospheric mantle. In addition to carbonate-richHIMU mantle lithologies in southern Africa and worldwide, Monastery kimberlite olivine megacrysts and olivine in melilitites suggest that a phlogopite-richHIMU lithology is present in southern Africa. An important question arising from this study is in reconciling the homogenous isotopic ratios of HIMU basalts worldwide with an apparent heterogeneous lithological source indicated by olivine chemistry.
DS201804-0700
2018
Howell, D.Fourier transform Infrared ( FTIR) spectroscopy of diamonds.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 25-27. abstractTechnologyspectroscopy
DS201809-2038
2018
Howell, D., Stachel, T., Pearson, D.G., Stern, R.A., Nestola, F., Shirey, S.B., Harris, J.W.Deep carbon through time: the diamond record.Goldschmidt Conference, 1p. AbstractAfrica, Australia, Russia, Canadadeposit - Argyle, De Beers Pool, Jwaneng, Orapa, Udachnaya, Venetia, Wawa, Diavik

Abstract: Earth’s mantle is by far the largest silicate-hosted reservoir of carbon. Diamonds are unrivalled in their ability to record the cycle of mantle carbon and other volatiles over a vast portion of the Earth’s history. They are the product of ascending, cooling, carbon-saturated, metasomatic fluidsmelts and/or redox reactions, predominantly within peridotitic and eclogitic domains in the mantle lithosphere. This paper reports the results of a major secondary ion mass spectrometry (SIMS) carbon isotope study, carried out on 127 diamond samples, spanning a large range of geological time. Detailed transects across the incremental growth zones within each diamond were measured for C isotopes, N abundances and, for samples with N >~200 at.ppm, N isotopes. Given that all of the samples are fragments, recovered when the original crystals were broken to liberate their inclusions, 81 of the analytical traverses have confirmed growth direction context. 98 samples are from studies that have confirmed the dates of the individual diamonds through analysis of their silicate or sulphide inclusions, from source localities including Argyle, De Beers Pool, Jwaneng, Orapa, Udachnaya & Venetia. Additional samples come from Wawa (a minimum age) and Diavik where the samples are tied via inclusion paragenesis to published ages. The peridotitic dataset covers the age range of ~3.3 - 2.0 Ga, with the eclogitic data from 2.9 - 1.0 Ga. In total, 751 carbon isotope and nitrogen concentration measurements have been obtained (425 on peridotitic diamonds, and 326 on eclogitic diamonds) with 470 nitrogen isotope measurements (190 P, 280 E). We attempt to constrain the diamond carbon isotope record through time and its implications for (i) the mantle carbon reservoir, (ii) its oxygen fugacity, (iii) the fluid / melt growth environment of diamonds, (iv) fractionation trends recorded in individual diamonds, and (v) diamond population studies using bulk combustion carbon isotope analysis.
DS201804-0701
2018
Huguet, L., Van Oman, J.A., Hauck, S.A., Willard, M.A.Earth's inner core nucleation paradox.Earth and Planteray Science Letters, Vol. 487, pp. 1-17.MantleCore

Abstract: The conventional view of Earth's inner core is that it began to crystallize at Earth's center when the temperature dropped below the melting point of the iron alloy and has grown steadily since that time as the core continued to cool. However, this model neglects the energy barrier to the formation of the first stable crystal nucleus, which is commonly represented in terms of the critical supercooling required to overcome the barrier. Using constraints from experiments, simulations, and theory, we show that spontaneous crystallization in a homogeneous liquid iron alloy at Earth's core pressures requires a critical supercooling of order 1000 K, which is too large to be a plausible mechanism for the origin of Earth's inner core. We consider mechanisms that can lower the nucleation barrier substantially. Each has caveats, yet the inner core exists: this is the nucleation paradox. Heterogeneous nucleation on a solid metallic substrate tends to have a low energy barrier and offers the most straightforward solution to the paradox, but solid metal would probably have to be delivered from the mantle and such events are unlikely to have been common. A delay in nucleation, whether due to a substantial nucleation energy barrier, or late introduction of a low energy substrate, would lead to an initial phase of rapid inner core growth from a supercooled state. Such rapid growth may lead to distinctive crystallization texturing that might be observable seismically. It would also generate a spike in chemical and thermal buoyancy that could affect the geomagnetic field significantly. Solid metal introduced to Earth's center before it reached saturation could also provide a nucleation substrate, if large enough to escape complete dissolution. Inner core growth, in this case, could begin earlier and start more slowly than standard thermal models predict.
DS201812-2818
2018
Hunt, L., Stachel, T., Stern, R.A., Creighton, S.Diavik deposit: Diamonds from the Diavik mine: from formation through mantle residence to emplacement.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 343-358.Canada, Northwest Territoriesdeposit - Diavik
DS201810-2330
2018
Hurt, S.M., Wolf, A.S.Thermodynamic properties of CaC03-SrC03-BaC03 liquids: a molecular dynamics study using new empirical atomic potentials for alkaline earth carbonates.Physics and Chemistry of Minerals, doi.org/10.1007/s00269-018-0995-5 16p.Mantlecarbonatite

Abstract: Thermodynamic modeling offers a powerful framework for studying melting reactions of carbonated mantle systems across a wide range of compositions, pressures, and temperatures. Such modeling requires knowledge of the standard state thermodynamic properties of the pure alkaline earth carbonate liquid components, which are difficult to determine experimentally due to their instability at 1 bar. Atomistic simulations offer a solution to these experimental difficulties by providing access to metastable states and supplying constraints on thermodynamic properties. We developed an empirically-derived potential model for the simulation of alkaline earth carbonates (MgCO3, CaCO3, SrCO3 and BaCO3), emphasizing the accurate simulation of the standard state thermodynamic properties of carbonate liquids. Molecular dynamics (MD) simulations of liquids in the CaCO3-SrCO3-BaCO3 system are performed over a geologically relevant temperature-pressure range (1100-3400 K and 0-43 GPa). Simulation data for each of these three components (up to a maximum of 2300 K and 30 GPa) are fitted to a temperature-dependent third-order Birch-Murnaghan equation-of-state to estimate their standard state thermodynamic properties. With a few exceptions, calculated properties agree well with available estimates from experiments and/or first-principles MD simulations. Exploration of binary mixtures supports ideal mixing of volumes, heat capacities, and compressibilities, reflecting the common liquid structure and pressure-temperature evolution for these three components. The success of this new model for CaCO3-SrCO3-BaCO3 liquids suggests that it can accurately predict the properties of MgCO3-bearing liquids, where experimental data are unavailable.
DS201803-0453
2018
Hutchison, M.T.Diamond exploration and prospectivity of Western Australia.Geological Survey of Western Australia, Report 179, 70p.Australiareview - exploration

Abstract: Western Australia (WA) hosts 696 000 km2 of exposed, onshore, exclusively Archean rocks and 439 000 km2 of Paleoproterozoic rocks. In total, pre-1.6 Ga rocks comprise around 45% of the onshore area of the State, constituting the West Australian Craton (WAC; Yilgarn and the Pilbara Cratons) and the western part of the North Australian Craton (NAC). Seimic tomography demonstrates that considerable remaining portions of the State are also underlain by thick mantle lithosphere (Kennett et al., 2013), hosting the conditions under which diamonds form. Subsequently, most of the State is prospective for diamonds and numerous diamondiferous lamproite and kimberlite fields are known. Emplacement of diamond-bearing rocks spans much of geological time, from the c. 1868 Ma Brockman Creek kimberlite in the Pilbara (White, 2000) to the c. 17 Ma Walgidee Hills lamproite, Noonkanbah field, West Kimberley (Phillips et al, 2012). According to Kimberley Process statistics, Australia is estimated to have produced approximately 11% of global rough diamond production by weight in 2015, ranking it fourth in the world after the Russian Federation, Botswana and the Democratic Republic of Congo. These production figures are accounted for by two mines, both in WA. However, due to the closure of the Ellendale mine in 2015, responsible for a large proportion of the world’s fancy yellow production, only one currently producing mine remains in Australia (at the AK1 olivine lamproite at Argyle, NAC). In order to assess the effectiveness of prior exploration and draw attention to under-explored prospective areas, a thorough compilation and interpretation of WA diamond exploration data has been conducted.
DS201803-0454
2018
Hutchison, M.T.Dat a methodologies applied in the Western Australia diamond exploration package.Geological Survey of Western Australia, Report 2017/16, 24p.Australiareview - exploration

Abstract: The Geological Survey of Western Australia’s Diamond exploration and prospectivity data package compiles over 40 years of diamond exploration data. In addition to samples derived from Western Australia’s established diamond mining areas at Ellendale and Argyle, a wide coverage of regional exploration data extending to the boundaries of the State is included. The database follows a similar methodology of attribution and has a compatible structure to the Diamond Exploration Database of the Northern Territory, allowing direct comparison of data throughout the North Australian Craton. The diamond exploration and prospectivity data package is the first of its kind to collate diamond exploration data statewide in a publicly accessible fashion. It incorporates the locations of over 88 000 diamond exploration samples. Associated with these samples are over 30 000 good-quality chemical analyses of mineral separate grains integrated into a standardized framework presented herein. In total, 524 discrete in situ bodies, which in principle have diamond potential (kimberlites, lamproites, ultramafic lamprophyres, and carbonatites) have also been compiled in the diamond exploration and prospectivity data package. With 114 confirmed to be diamondiferous, this part of the database considerably expands upon previous compilations of relevant Western Australian rocks, including the Geological Survey of Western Australia’s MINEDEX database and Bulletin 132. As a companion, 127 emplacement age determinations from 63 bodies are reported, encompassing most of the geographic extent of Western Australia’s known rocks with diamond potential. Analyses of the Western Australian data allow for an understanding of the exploration history in areas of known occurrences and identification of considerable gaps in the exploration coverage within areas of diamond potential. The Diamond exploration and prospectivity data package stands as a means to support and encourage future diamond exploration in the State in addition to providing a rigorous framework suitable for the establishment of diamond exploration databases elsewhere.
DS201807-1499
2018
Hutchison, M.T.Diamond exploration and regional prospectivity of Western Australia. Kimberlite and lamproiteMineralogy and Petrology, 10.1007/ s00710-018- 0579-6, 17p.AustraliaIndicator minerals

Abstract: Pre-1.6 Ga rocks comprise around 45% of the onshore area of Western Australia (WA), constituting the West Australian Craton (WAC) (including the Archean Yilgarn and Pilbara Cratons) and the western part of the North Australian Craton (NAC). These areas provide the conditions suitable for diamond formation at depth, and numerous diamondiferous lamproite and kimberlite fields are known. As emplacement ages span close to 2500 Ma, there are significant opportunities for diamond-affinity rocks being present near-surface in much of the State, including amongst Phanerozoic rocks. WA’s size, terrain, infrastructure and climate, mean that many areas remain underexplored. However, continuous diamond exploration since the 1970s has resulted in abundant data. In order to advance future exploration, a comprehensive database of results of diamond exploration sampling (Geological Survey of Western Australia 2018) has been assessed. The Yilgarn and Pilbara Cratons have spinel indicators almost exclusively dominated by chromite (>90% of grains), whereas (Mg,Fe,Ti)-bearing Al-chromites account for more of the indicator spinels in the NAC, up to 50% of grains at the Northern Territory (NT) border. Increasing dominance of Al in chromites is interpreted as a sign of weathering or a shallower source than Al-depleted Mg-chromites. Garnet compositions across the State also correlate with geological subdivisions, with lherzolitic garnets showing more prospective compositions (Ca-depleted) in WAC samples compared to the NAC. WAC samples also show a much broader scatter into strongly diamond-prospective G10 and G10D compositions. Ilmenites from the NAC show Mg-enriched compositions (consistent with kimberlites), over and above those present in NT data. However, ilmenites from the WAC again show the most diamond-prospective trends. Numerous indicator mineral concentrations throughout the State have unknown sources. Due in part to the presence of diamondiferous lamproites, it is cautioned that some accepted indicator mineral criteria do not apply in parts of WA. For example Ca-depleted garnets, Mg-depleted ilmenites and Cr-depleted and Al-absent clinopyroxenes are all sometimes associated with strongly diamondiferous localities. Quantitative prospectivity analysis has also been carried out based on the extent and results of sampling, age of surface rocks relative to ages of diamond-prospective rocks, and the underlying mantle structure. Results show that locations within the NAC and with proximity to WA’s diamond mines score well. However, results point to parts of the WAC being more prospective, consistent with mineral chemical data. Most notable are the Hamersley Basin, Eastern Goldfields Superterrane and the Goodin Inlier of the Yilgarn Craton. Despite prolific diamond exploration, WA is considerably underexplored and the ageing Argyle mine and recent closure of operations at Ellendale warrant a re-evaluation of diamond potential. Results of mineral chemistry and prospectivity analysis make a compelling case for renewed exploration.
DS201809-2039
2018
Hutchison, M.T., Faithfull, J.W., Barfod, D.N., Hughes, J.W., Upton, B.G.J.The mantle of Scotland viewed through the Glen Gollaidh aillikite.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0610-y 18p.Europe, Scotlandaillikite

Abstract: The Glen Gollaidh aillikite dyke (58.36741°N 4.69751°W), N.W. Scotland, occurs within the Neoproterozoic sedimentary rocks of the Moine Supergroup ~4 km east of the Moine Thrust. Phlogopite 40Ar/36Ar measurements give a late Devonian maximum emplacement age of 360.3?±?4.9 (2?) Ma. This age occurs in a quiet period of Scottish magmatic history c. 30 Ma after the closure of the Iapetus and before the start of intra-plate alkali magmatism which affected southern Scotland for ~60 My from c. 350 Ma. Abundant chromites and Cr-diopsides and a few unaltered olivines, reflecting a mantle provenance, were recovered from heavy mineral concentrates. The North Atlantic Craton, exposed in Lewisian gneisses west of the Moine thrust, is therefore inferred to extend east at depth under Glen Gollaidh, presenting an opportunity to investigate the thickness and composition of the cratonic margin in the Devonian. The aillikite was found to be barren of diamond and no picro-ilmenites or garnets were definitively identified. However, mineral chemistry suggests that a proportion of Glen Gollaidh xenocrysts crystallised in equilibrium with garnet. Most spinels are Mg, Al chromites, with some Mg chromite present. All fall within the garnet peridotite field based on Ti and Cr but with insufficient Cr2O3 (up to 47.2 wt%) to be consistent with the diamond stability field. Amongst Cr-diopsides 30% of grains have Cr and Al contents consistent with derivation from garnet peridotite. The majority of clinopyroxenes also show a marked depletion in heavy compared to light rare-earth elements, again consistent with equilibration with garnet. The opx-cpx solvus thermometer demonstrates that average Cr-diopside compositions require at least 37 kbar to give a temperature (979 °C) lying even on a relatively warm 40 mWm?2 geotherm (Hasterok and Chapman Earth Planet Sc Lett 307:59-70, 2011). Large variations in the chemistry of mantle minerals reflect a complex history of metasomatism akin to constituents of alkali igneous rocks elsewhere in the Hebridean and Northern Highlands Terranes. Fertilised mantle provided the conditions for generation of aillikite melts, probably triggered by break-off of the advancing Avalonia slab. The cratonic root underlying the Glen Gollaidh aillikite during the late Devonian was apparently too thin to lie within the diamond stability field, consistent with xenoliths from alkali basalts further south. Nonetheless, sufficient geophysical and mineral chemical evidence supports Glen Gollaidh aillikite sitting close to the edge of diamond-prospective mantle therefore suggesting diamond potential a short distance to the west within the Lewisian and what is now East Greenland.
DS201812-2819
2018
Hwang, S.L., Shen, P., Yui, T.F., Chu, H.T., Logvinova, A.M., Sobolev, N.V.Low energy phase boundary pairs and preferred crystallographic orientations of olivines in nanometer-sized ultrapotassic fluid inclusions of Aykhal diamond.Lithos, Vol. 322, pp. 392-404.Russiadeposit - Aykhal

Abstract: The healed internal conjugated cleavages at the core of Aykhal octahedral diamond sample AH2 were decorated with {111}dia-facetted ultrapotassic fluid/melt inclusion pockets containing nanosized graphite, phlogopite and olivine (Fo92) inclusions. These olivines are either rounded in pockets with ample fluid, or facetted by the {111}dia mold in the pockets with a fluid film. Transmission electron microscopy revealed two distinct crystallographic characteristics of olivine inclusions: (1) pronounced crystallographic texture of olivines grouped in specific diamond domain, and (2) frequent parallelism or sub-parallelism of specific low-energy faces of the two phases, mainly (010)ol, {120}ol, (001)ol and {111}dia, {110}dia, {100}dia in the order of decreasing preference, forming prominent (010)ol/{111}dia, (010)ol/{110}dia, (001)ol/{110}dia, {120}ol/{111}dia, and {120}ol/{110}dia low-energy phase boundaries with thin liquid film of 1-2?nm in between. These findings not only testify to the extremely low adhesion energies of olivine-diamond boundary pairs, but also imply that, in the presence of a fluid phase, the interfacial energetics and the energetically favored crystallographic orientations of olivine inclusions in diamond can be controlled simply by the settlement/attachment of low-energy facets of olivine crystals precipitating from the parental fluid upon the low-energy {111}dia or {110}dia surfaces of diamond. Such interfacial energetics control and the resultant low-energy boundary pairs are characteristically distinct from the common topotaxy or epitaxy between oxide/silicate mineral pairs, but are in a sense like the Van der Waals heteroepitaxy in artificial systems.
DS201811-2581
2013
Iddon, C., Hettihewa, S., Wright, C.S.Junior mining sector capital raising: the effects of information asymmetry and uncertainty issues.Journal of Applied Business and Economics, Vol. 15, 3, 12p. PdfGlobaleconomics

Abstract: While prospecting by junior mining companies (JMCs) is a vital contributor to modern wealth creation, attributes of the junior mining sector (JMS) limit JMC-fund raisings to external equity (shares). In considering responses by JMC principals to deep discounting and other JMC-investor strategies, potential responses were found to: increase returns to principals, increase JMS moral-hazard issues, and further deepen price discounts on JMC share offerings, especially IPOs. It is suggested that the attractiveness and moral-hazard consequences of these potential responses can be greatly diminished if mining-tenement fees are raised and JMC prospecting costs are allowed as an offset against those fees.
DS201809-2040
2018
Ignatov, P.A., Novikov, K.V., Shmonov, A.M., Zaripov, N.R., Khodnya, M.S., Razumov, A.N., Kilishekov, O.K., Kryazhev, S.G., Kovalchuk, O.E.Zoning of faults and secondary mineralization of host rocks of kimberlites of the Maiscoe diamond deposit, Nakyn field, Yakutia.Geology of Ore Deposits, Vol. 60, 3, pp. 201-209.Russiadeposit - Maiscoe
DS201805-0952
2017
Ikenne, M., Lahna, A.A., Soderlund, U., Tassinar, C.C.G., Ernst, R.E., Pin, Ch., Youbi, N., El Aouli, EH., Hafid, A., Admou, H., Mata, J., Bouougri, EH., Boumehdi, M.A.New Mesoproterozoic age constraints for the Taghdout Group, Anti-Atlas ( Morocco): toward a new lithostratigra[hic framework for the Precambrian in the NW margin of the West African Craton.The First West African Craton and Margins International Workshop WACMA, Held Apr. 24-29. 1p. AbstractAfrica, Moroccogeochronology
DS201801-0024
2017
Ionov, D.A., Doucet, L.S., Pogge von Strandmann, P.A.E., Golovin, A.V., Korsakov, A.V.Links between deformation, chemical enrichments and Li-isotope compositions in the lithospheric mantle of the central Siberian craton.Chemical Geology, Vol. 475, pp. 105-121.Russiadeposit - Udachnaya

Abstract: We report the concentrations ([Li]) and isotopic compositions of Li in mineral separates and bulk rocks obtained by MC-ICPMS for 14 previously studied garnet and spinel peridotite xenoliths from the Udachnaya kimberlite in the central Siberian craton as well as major and trace element compositions for a new suite of 13 deformed garnet peridotites. The deformed Udachnaya peridotites occur at > 5 GPa; they are metasomatized residues of melt extraction, which as a group experienced greater modal and chemical enrichments than coarse peridotites. We identify two sub-groups of the deformed peridotites: (a) mainly cryptically metasomatized (similar to coarse peridotites) with relatively low modal cpx (< 6%) and garnet (< 7%), low Ca and high Mg#, sinusoidal REE patterns in garnet, and chemically unequilibrated garnet and cpx; (b) modally metasomatized with more cpx and garnet, higher Ca, Fe and Ti, and equilibrated garnet and cpx. The chemical enrichments are not proportional to deformation degrees. The deformation in the lower lithosphere is caused by a combination of localized stress, heating and fluid ingress from the pathways of ascending proto-kimberlite melts, with metasomatic media evolving due to reactions with wall rocks. Mg-rich olivine in spinel and coarse garnet Udachnaya peridotites has 1.2-1.9 ppm Li and ?7Li of 1.2-5.0‰, i.e. close to olivine in equilibrated fertile to depleted off-craton mantle peridotites from literature data, whereas olivine from the deformed peridotites has higher [Li] (2.4-7.5 ppm) and a broader range of ?7Li (1.8-11.6‰), which we attribute to pre-eruption metasomatism. [Li] in opx is higher than in coexisting olivine while ?7LiOl-Opx (?7LiOl ? ?7LiOpx) ranges from ? 6.6 to 7.8‰, indicating disequilibrium inter-mineral [Li] and Li-isotope partitioning. We relate these Li systematics to interaction of lithospheric peridotites with fluids or melts that are either precursors of kimberlite magmatism or products of their fractionation and/or reaction with host mantle. The melts rich in Na and carbonates infiltrated, heated and weakened wall-rock peridotites to facilitate their deformation as well as produce high [Li] and variable, but mainly high, ?7Li in olivine. The carbonate-rich melts preferentially reacted with the opx without achieving inter-mineral equilibrium because opx is consumed by such melts, and because of small volumes and uneven distribution of the metasomatic media, as well as short time spans between the melt infiltration and the capture of the wall-rock fragments by incoming portions of ascending kimberlite magma as xenoliths. Trapped interstitial liquid solidified as cryptic components responsible for high [Li] and the lack of ?7Li balance between olivine and opx, and bulk rocks. Unaltered ?26Mg values (0.20-0.26‰) measured in several olivine separates show no effects of the metasomatism on Mg-isotopes, apparently due to high Mg in the peridotites.
DS201802-0242
2018
Ionov, D.A., Doucet, L.S., Xu, Y., Golovin, A.V., Oleinikov, O.B.Reworking of Archean mantle in the NE Siberian craton by carbonatite and silicate melt metasomatism: evidence from a carbonate bearing, dunite to web sterite xenolith suite from the Obnazhennaya kimberlite.Geochimica et Cosmochimica Acta, in press available, 46p.Russia, Siberiadeposit - Obnazhennaya

Abstract: The Obnazhennaya kimberlite in the NE Siberian craton hosts a most unusual cratonic xenolith suite, with common rocks rich in pyroxenes and garnet, and no sheared peridotites. We report petrographic and chemical data for whole rocks (WR) and minerals of 20 spinel and garnet peridotites from Obnazhennaya with Re-depletion Os isotope ages of 1.8-2.9 Ga (Ionov et al., 2015a) as well as 2 pyroxenites. The garnet-bearing rocks equilibrated at 1.6-2.8 GPa and 710-1050°C. Some xenoliths contain vermicular spinel-pyroxene aggregates with REE patterns in clinopyroxene mimicking those of garnet. The peridotites show significant scatter of Mg# (0.888-0.924), Cr2O3 (0.2-1.4 wt.%) and high NiO (0.3-0.4 wt.%). None are pristine melting residues. Low-CaO-Al2O3 (?0.9 wt.%) dunites and harzburgites are melt-channel materials. Peridotites with low to moderate Al2O3 (0.4-1.8 wt.%) usually have CaO > Al2O3, and some have pockets of calcite texturally equilibrated with olivine and garnet. Such carbonates, exceptional in mantle xenoliths and reported here for the first time for the Siberian mantle, provide direct evidence for modal makeover and Ca and LREE enrichments by ephemeral carbonate-rich melts. Peridotites rich in CaO and Al2O3 (2.7-8.0 wt.%) formed by reaction with silicate melts. We infer that the mantle lithosphere beneath Obnazhennaya, initially formed in the Mesoarchean, has been profoundly modified. Pervasive inter-granular percolation of highly mobile and reactive carbonate-rich liquids may have reduced the strength of the mantle lithosphere leading the way for reworking by silicate melts. The latest events before the kimberlite eruption were the formation of the carbonate-phlogopite pockets, fine-grained pyroxenite veins and spinel-pyroxene symplectites. The reworked lithospheric sections are preserved at Obnazhennaya, but similar processes could erode lithospheric roots in the SE Siberian craton (Tok) and the North China craton, where ancient melting residues and reworked garnet-bearing peridotites are absent.The modal, chemical and Os-isotope compositions of the Obnazhennaya xenoliths produced by reaction of refractory peridotites with melts are very particular (high Ca/Al, no Mg#-Al correlations, highly variable Cr, low 187Os/188Os, continuous modal range from olivine-rich to low-olivine peridotites, wehrlites and websterites) and distinct from those of fertile lherzolites in off-craton xenoliths and peridotite massifs. These features argue against the concept of ‘refertilization’ of cratonic and other refractory peridotites by mantle-derived melts as a major mechanism to form fertile to moderately depleted lherzolites in continental lithosphere. The Obnazhennaya xenoliths represent a natural rock series produced by ‘refertilization’, but include no rocks equivalent in modal, major and trace element to the fertile lherzolites. This study shows that ‘refertilization’ yields broad, continuous ranges of modal and chemical compositions with common wehrlites and websterites that are rare among off-craton xenoliths.
DS201804-0702
2018
Irifune, T., Ohuchi, T.Oxidation softens mantle rocks. Nature, Vol. 555, March 15, pp. 314-315.Mantlegeophysics - seismics

Abstract: Seismic waves that propagate through a layer of Earth’s upper mantle are highly attenuated. Contrary to general thinking, this attenuation seems to be strongly affected by oxidation conditions, rather than by water content.
DS201809-2041
2018
Iskrina, A.V., Bobrov, A.V., Kriulina, G.Y., Zedgenizov, D.A., Garanin, V.K.Melt/fluid inclusions in diamonds from the Lomonosov deposit ( Arkangelsk kimberlite province).Goldschmidt Conference, 1p. AbstractRussia, Kola Peninsuladeposit - Lomonosov

Abstract: Melt/fluid inclusions in diamonds provide important evidence for mantle diamond-forming fluids or melts. By now, the major characteristics of the composition of microinclusions have been analyzed in diamonds from several kimberlite provinces and pipes worldwide [1-4]. Here we report the first data on the composition of parent diamondforming melts for diamonds from the Arkhangelsk kimberlite province. After the study of morphology, specialty of the internal structure, and distribution of microinclusions in diamonds, 10 single crystals were selected from the 31 diamonds of the representative collection. The studied crystals may be divided into two groups: cuboids and coated diamonds. The crystals have grayish yellow or dark gray colors and are almost nontransparent due to the high content of microinclusions. Polished slices of these diamonds were studied by IR-spectroscopy, which allowed us to calculate the content of nitrogen defects, as well as the content of water and carbonates in microinclusions. X-ray spectral analyses allowed to study the composition of fluid/melt microinclusions and showed that they were essentially carbonate-silicate with significant variations between these two end-members. All inclusions contain water, with the highest H2O/CO2 in highly siliceous inclusions. Unlike diamonds from Canada and South Africa [1, 2], the studied inclusions in diamionds from the Arkhangelsk province are almost free of chlorides. Comparison of the data obtained with the database on fliud/melt inclusions in diamonds worldwide shows similar of Arkhangelsk diamonds to some diamonds from Yakutia [3, 4], and the data obtained are the most similar to the composition of microinclusions in diamonds from the Internatsionalnaya pipe (Yakutia).
DS201812-2820
2018
Iulianella Phillips, B.P., Simister, R.L., Cayer, E.M., Winterburn, P.A., Crowe, S.A.Direct discovery of concealed kimberlites with microbial community fingerprinting. 2018 Yellowknife Geoscience Forum , p. 36. abstractCanada, Northwest Territoriesmineral chemistry

Abstract: Mineral exploration in Canada is becoming increasingly complex as the majority of undiscovered commodities are likely deeply buried beneath significant glacial overburden and bedrock, reducing the effectiveness of many existing tools. The development of innovative exploration protocols and techniques is imperative to the continuation of discovery success. Preliminary experimentation has demonstrated the potential viability of microbial fingerprinting through genetic sequencing to directly identify the projected subcrop of mineralization in addition to the more distal entrained geochemical signatures in till. With the advent of inexpensive modern sequencing technology and big-data techniques, microbiological approaches to exploration are becoming more quantitative, cost effective, and efficient. The integration of microbial community information with soil chemistry, mineralogy and landscape development coupled with geology and geophysics propagates the development of an improved decision process in mineral exploration. Soils over porphyry, kimberlite, and VMS deposits have undergone microbial community profiling. These community-genome derived datasets have been integrated with trace metal chemistry, mineralogy, surface geology and other environmental variables including Eh and pH. Analyses of two kimberlites in the Northwest Territories show significant microbial community shifts that are correlated with subsurface mineralization, with distinctive microbial community profiles present directly above the kimberlite. The relationship between microbial profiles and mineralization leads to the use of microbial fingerprinting as a method for more accurately delineating ore deposits in glacially covered terrain. As databases are developed, there is potential for application as a field based technique, as sequencing technology is progressively developed into portable platforms.
DS201801-0025
2018
Ivanov, A.V., Demonterova, E.I., Savatenkov, V.M., Perepelov, A.B., Ryabov, V.V., Shevko, A.Y.Late Triassic (Carnian) lamproites from Norilsk, polar Siberia: evidence for melting of the recycled Archean crust and the question of lamproite source for some placer diamond deposits of the Siberian craton.Lithos, Vol. 296-299, pp. 67-78.Russia, Siberialamproites

Abstract: Two typical lamproitic dykes were found in Noril'sk region of the north-western Siberian Craton, which according to mineralogical, geochemical and isotopic criteria belong to anorogenic, non-diamondiferous type of lamproites. According to the geologic relationships, they cut through the Noril'sk-1 intrusion of the Siberian flood basalt province and thus are younger than ~251 Ma. 40Ar/39Ar dating of the two dykes yielded ages of 235.24 ± 0.19 Ma and 233.96 ± 0.19 Ma, showing that they were emplaced in Carnian of the Late Triassic, about 16 Ma after the flood basalt event. There are some indications that there were multiple lamproitic dyke emplacements, including probably emplacement of diamondiferous lamproites, which produced Carnian-age diamond-rich placer deposits in other parts of the Siberian Craton and in adjacent regions. Lead isotope modelling shows that the source of the studied lamproites was formed with participation of recycled crust, which underwent modification of its U/Pb ratio as early as 2.5 Ga. However, the exactmechanismof the recycling cannot be deciphered now. It could be either through delamination of the cratonic crust or subduction of amix of ancient terrigenous sediments into the mantle transition zone.
DS201805-0953
2018
Ivanov, A.V., Mukasa, S.B., Kamenetsky, V.S., Ackerman, M., Demonterova, E.I., Pokrovsky, B.G., Vladykin, N.V., Kolesnichenko, M.V., Litasov, K.D., Zedgenizov, D.A.Origin of high-Mg melts by volatile fluxing without significant excess of temperature.Chemical Geology, https://doi.org/ 10.1016/j .chemgeo. 2018.03.11Russiameimechites
DS201809-2043
2018
Ivarsson, M., Skogby, H., Bengtson, S., Siljestrom, S., Ounchanum, P., Boonsoong, A., Kruachanta, M., Marone, F., Belivanova, V., Holstrom, S.Intricate tunnels in garnets from soils and river sediments in Thailand - possible endolithic microborings.PluS One, Vol. 13, 8, doi:10.1371/journal.pone.0200351Asia, Thailandgarnets

Abstract: Garnets from disparate geographical environments and origins such as oxidized soils and river sediments in Thailand host intricate systems of microsized tunnels that significantly decrease the quality and value of the garnets as gems. The origin of such tunneling has previously been attributed to abiotic processes. Here we present physical and chemical remains of endolithic microorganisms within the tunnels and discuss a probable biological origin of the tunnels. Extensive investigations with synchrotron-radiation X-ray tomographic microscopy (SRXTM) reveal morphological indications of biogenicity that further support a euendolithic interpretation. We suggest that the production of the tunnels was initiated by a combination of abiotic and biological processes, and that at later stages biological processes came to dominate. In environments such as river sediments and oxidized soils garnets are among the few remaining sources of bio-available Fe2+, thus it is likely that microbially mediated boring of the garnets has trophic reasons. Whatever the reason for garnet boring, the tunnel system represents a new endolithic habitat in a hard silicate mineral otherwise known to be resistant to abrasion and chemical attack.
DS201810-2331
2018
Jackson, C.G., Gibson, S.A.Preservation of systematic Ni and Cr heterogeneity in otherwise homogeneous mantle olivine: implications for timescales of post-metasomatism re-equilibration.Lithos, Vol. 318-319. pp. 448-463.Africa, South Africadeposit - Bultfontein

Abstract: The flux of elements into Earth's sub-continental lithospheric mantle is facilitated by the passage of small-fraction melts that either crystallise new phases or react with pre-existing minerals.Metasomatised peridotite records the end product of this exchange but rarely captures the process in the act due to subsolidus re-equilibration. We present the results of a systematic investigation of a metasomatic melt channel preserved in a mantle peridotite from the Late Cretaceous Bultfontein kimberlite (Kaapvaal craton) that shows rare direct evidence of the melt-rock reaction processes. We show that the metasomatic proto-kimberlite melt underwent variable crystallisation of clinopyroxene, sulfides, phlogopite, spinel and zircon together with interaction and diffusive exchange with the surrounding olivine-rich mantle. Element profiles across large olivine porphyroclasts (Fo88) show significant core-to-rim variations in Ni (NiO?=?0.18-0.32?wt%) and Cr (Cr?=?35-60?ppm), while concentrations of all other elements (e.g. Mg, Fe, Mn, Co, V)are remarkably homogeneous. Electron backscatter diffraction analysis shows that the disequilibrium of Ni and Cr is greatest where the crystal contains large components of the [100] and [010] axes. The disequilibrium is preserved in certain orientations because diffusion of Ni and Cr in olivine is more anisotropic than Fe-Mg and Mn, and slower in the [100] and [010] directions. We present the first observations of Ni and Cr decoupling from other elements in mantle olivine and suggest that this is a consequence of: (i)changing mineral-melt concentration gradients associated with the reactive percolation of a precursory kimberlite melt; and (ii) late-stage sulfide and spinel precipitation. We use the diffusion limited re-equilibration of Ni in olivine to quantify the timing of metasomatism prior to xenolith entrainment by the host kimberlite. Our modelling indicates that reactive percolation occurred on the order of 103-105?years prior to entrainment; this provides an additional line of support for the hypothesis that a period of metasomatism by proto-kimberlite melts precedes the final kimberlite ascent to the surface. The broader implication of our finding of variable rates of minor element diffusion in natural olivine is that it highlights the importance of anisotropy and the impact of changing local concentration gradients during subsolidus re-equilibration.
DS201812-2821
2018
Jackson, C.G., Gibson, S.A.Preservation of systematic Ni and Cr heterogeneity in otherwise homogeneous mantle olivine: implications for timescales of post-metasomatism re-equilibrium.Lithos, Vol. 318-319, pp. 448-463.Africa, South Africadeposit - Bultfontein

Abstract: The flux of elements into Earth’s sub-continental lithospheric mantle is facilitated by the passage of small-fraction melts that either crystallise new phases or react with pre-existing minerals. Metasomatised peridotite records the end product of this exchange but rarely captures the process in the act due to subsolidus re-equilibration. We present the results of a systematic investigation of a metasomatic melt channel preserved in a mantle peridotite from the Late Cretaceous Bultfontein kimberlite (Kaapvaal craton) that shows rare direct evidence of the melt-rock reaction processes. We show that the metasomatic proto-kimberlite melt underwent variable crystallisation of clinopyroxene, sulfides, phlogopite, spinel and zircon together with interaction and diffusive exchange with the surrounding olivine-rich mantle. Element profiles across large olivine porphyroclasts (Fo88) show significant core-to-rim variations in Ni (NiO = 0.18-0.32 wt.%) and Cr (Cr = 35-60 ppm), while concentrations of all other elements (e.g. Mg, Fe, Mn, Co, V) are remarkably homogeneous. Electron backscatter diffraction analysis shows that the disequilibrium of Ni and Cr is greatest where the crystal contains large components of the [100] and [010] axes. The disequilibrium is preserved in certain orientations because diffusion of Ni and Cr in olivine is more anisotropic than Fe-Mg and Mn, and slower in the [100] and [010] directions. We present the first observations of Ni and Cr decoupling from other elements in mantle olivine and suggest that this is a consequence of: (i) changing mineral-melt concentration gradients associated with the reactive percolation of a precursory kimberlite melt; and (ii) late-stage sulfide and spinel precipitation. We use the diffusion limited re-equilibration of Ni in olivine to quantify the timing of metasomatism prior to xenolith entrainment by the host kimberlite. Our modelling indicates that reactive percolation occurred on the order of 103-105 years prior to entrainment; this provides an additional line of support for the hypothesis that a period of metasomatism by proto-kimberlite melts precedes the final kimberlite ascent to the surface. The broader implication of our finding of variable rates of minor element diffusion in natural olivine is that it highlights the importance of anisotropy and the impact of changing local concentration gradients during subsolidus re-equilibration.
DS201803-0455
2018
Jackson, C.R., Bennett, N.R., Du, Z., Cottrell, E., Fei, Y.Early episodes of high pressure core formation preserved in plume mantle.Nature , Vol. 553, 7689, pp. 491-495.Mantleplumes

Abstract: The decay of short-lived iodine (I) and plutonium (Pu) results in xenon (Xe) isotopic anomalies in the mantle that record Earth’s earliest stages of formation1,2,3,4,5,6,7,8. Xe isotopic anomalies have been linked to degassing during accretion2,3,4, but degassing alone cannot account for the co-occurrence of Xe and tungsten (W) isotopic heterogeneity in plume-derived basalts9,10 and their long-term preservation in the mantle. Here we describe measurements of I partitioning between liquid Fe alloys and liquid silicates at high pressure and temperature and propose that Xe isotopic anomalies found in modern plume rocks (that is, rocks with elevated 3He/4He ratios) result from I/Pu fractionations during early, high-pressure episodes of core formation. Our measurements demonstrate that I becomes progressively more siderophile as pressure increases, so that portions of mantle that experienced high-pressure core formation will have large I/Pu depletions not related to volatility. These portions of mantle could be the source of Xe and W anomalies observed in modern plume-derived basalts2,3,4,9,10. Portions of mantle involved in early high-pressure core formation would also be rich in FeO11,12, and hence denser than ambient mantle. This would aid the long-term preservation of these mantle portions, and potentially points to their modern manifestation within seismically slow, deep mantle reservoirs13 with high 3He/4He ratios.
DS201809-2044
2018
Jacob, D.E., Stern, R.A., Stachel, T., Piazolo, S.Polycrystalline diamonds and their mantle derived mineral and fluid intergrowths. (Aggregates, framesites, boart, diamondite)Goldschmidt Conference, 1p. AbstractAfrica, South Africadeposit - Venetia

Abstract: Polycrystalline diamond aggregates (framesites, boart, diamondite) are an understudied variety of mantle diamond, but can make up 20% of the production in some Group I kimberlites. Their polycrystalline nature indicates rapid precipitation from carbon-oversaturated fluids and individual PDAs often contain a chemically heterogeneous suite of websteritic and pyroxenitic inclusions and minerals intimately intergrown with the diamond crystals. Geochemical and microstructural evidence suggests that fluid-driven redox reactions with lithospheric material occurring episodically over millions of years play a major role in freezing carbon in the subcratonic lithosphere (Jacob et al., 2000; 2016; Mikhail et al., 2014). A suite of 39 samples from the Venetia kimberlite pipe in South Africa allows a more detailed look at the diamondforming fluids. 13C values in the diamonds measured by secondary ion mass spectrometry range from +2 to -28 and cover the entire range for PDA from the literature. Nitrogen concentrations are mostly very low (less than 100 at ppm), but reach up to 2660 at ppm in individual samples. These high nitrogen concentrations in concert with mostly positive 15N values of up to +17 and some very negative 3C values suggest crustal material as the source of the nitrogen and the carbon. However, detailed analysis of the sample provides evidence for a more complex growth history followed by alteration. Individual diamond crystals show complex growth zonations by cathodoluminescence imaging that can be related with the carbon and nitrogen isotopic compositions and points to growth incorporating several pulses of carbon-nitrogen fluid with distinct isotopic compositions. Most of these growth events show decoupled carbon and nitrogen systematics. In addition, EBSD identifies deformation and recrystallization and nitrogen aggregation states range from pure IaA to pure IaB, supporting a heterogeneous and episodic growth history.
DS201804-0704
2018
Jacoby, M.Carbonate mineral forms diamond on its own. New geological mechanism involving carbonate suggests Earth's lower mantle may be rich in diamond.cen.acs.org, Mar. 5, 1p.Mantlemeteorite

Abstract: When a meteorite slammed into Earth some 50,000 years ago, forming the bowl-shaped Xiuyan crater in northeast China, it left a treasure trove of geochemical research goodies. By applying microscopy and spectroscopy methods to analyze carbonate minerals found there, researchers have uncovered samples of diamond and a new mechanism for its formation.
DS201801-0026
2017
Jadhav, G.N., Viladkar, S.G., Goswami, R., Badhe, K.Fluid melt inclusions petrography of primary calcites from carbonatites of Amba Dongar, Gujarat India.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 15.Indiadeposit - Amba Dongar

Abstract: The Amba Dongar Carbonatite complex consists of sovites which are dominantly composed of calcite along with pyrochlore, phlogopite, apatite, barite, ankerite and haematite and minor opaques such as magnetite, chalcopyrite and pyrite. Two distinct types of texture are present in these carbonatites- a mosaic of equigranular calcite crystals and porphyritic texture. Silicate melt inclusions are observed in primary minerals viz. apatite and calcites. These are small droplets of silicate melt entrapped during the growth of the minerals. In this case carbonatite-alkaline silicate melt inclusions are entrapped predominantly in calcite crystals. Dominantly these calcite host minerals are predominantly containing fluid inclusions along with halite, sylvite and minor nahcolite as daughter crystals. The presence of calcite with nahcolite indicates the coexistence of a Ca-rich, alkali-bearing carbonatite melt phase. The melt inclusions are heated upto 1100 °C and the carbonate melt inclusions appear to be homogenized around 950 °C. This fall within the range of melting temperature of a carbonatite melt. In addition to these, three types of fluid inclusions were also observed in host calcite they are i) monophase, ii) biphase and iii) polyphase types of fluid inclusions. The fluid inclusions contain CO2 gas, Li-K carbonate phases and fergusonite based on Micro-Laser- Raman. Carbon dioxide is the dominant gas phase in most of the fluid inclusions, indicating high temperature and deep mantle source(?). The fluid inclusions have formed from a primary mother liquor that has separated out from the early formed carbonatitic melt. This fluid was either formed just after the formation of melt inclusions or during simultaneous crystallization from a carbonatitic or to be more precise carbonatiticpegmatite melt(?).The presence of both melt and fluid inclusions in these primary calcite host minerals indicates the presence of a carbonatitic-pegmatitic fluid, which must have got separated out from the early formed carbonatite-alkaline silicate magma.
DS201809-2045
2018
Janse, A.J.A. BramEssential books on diamond. List by author and overview of each technical book biased to diamond.The Australian Gemmologist, Vol. 26, 9-10, pp. 217-225.Globalgemstones - diamond

Abstract: I have been asked several times in the past to provide a list of books on diamond that are essential to "the interested layperson" and the gemmologist who is just starting out – either a student or a lover of gems. These books I would class as essential reading for persons wanting to know more about diamonds, including their physical properties, crystal forms, beauty in cut and polished shapes, exploration, mining and trade. I have presented here a list of books based on three levels of understanding – initial, intermediate and advanced. Many of the books quoted are out of print, but a diligent search on Amazon, Book Depository, Booktopia, Fish Pond Australia or Abe Books will find these books for sale, either new or second hand. For the first, initial level there are four essential books. After reading and digesting these, one could be seen as a knowledgeable person, not an expert, as this takes more time and study. The books do not require scientific education at university level, instead a general knowledge of science, a good mind and common sense are all that is needed to enjoy these books. The first book listed was published to accompany the wonderful exhibition of the ‘World of Diamonds’ organised by the American Museum of Natural History in New York in 1998. The exhibition travelled to a few other venues in the next two years, but very high insurance costs restricted this effort. Not to be outdone, the Muséum National d’Histoire Naturelle in Paris organised a similar wonderful exhibition in 2001, based more on diamond jewellery than on diamonds themselves. This exhibition only travelled to Rome, again high insurance prevented further travel. The second book, published in a French and an English edition, was issued to accompany and describe the French exhibition. [The exhibition in the Natural History Museum in London in 2005 unfortunately was closed after only a few weeks in 2005 because of the threat of a robbery. This raised the cost of insurance to unacceptable levels for entrance fees. The exhibition was described in a slim booklet by Dixon which I have listed for completeness, as well as the volume on the diamond jubilee exhibition in Buckingham Palace in 2012, but it is not essential reading]. The third book is dedicated to diamonds as jewels. It portrays about one hundred famous and notable cut and polished diamonds, and has gone to its fifth edition by now. The fourth book is a primer on diamond geology and mineralogy written for the general reader interested in diamonds.
DS201808-1754
2018
Jaques, A.L., Foley, S.F.Insights into the petrogenesis of the West Kimberley lamproites from trace elements in olivine.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0612-9 19p.Australialamproites

Abstract: The Miocene lamproites of the West Kimberley region, Western Australia include olivine-leucite lamproites (?10 wt% MgO) containing olivine and leucite microphenocrysts, and diamondiferous olivine lamproites (20-30 wt% MgO) containing olivine phenocrysts and larger (1-10 mm) olivine as mantle xenocrysts and dunite micro-xenoliths. Olivine phenocrysts and thin (<100 ?m) magmatic rims define trends of decreasing Cr and Ni, and increasing Ca and Mn, with decreasing olivine Mg#, consistent with fractional crystallisation of olivine (and minor chromite). Many phenocrysts are zoned, and those with cores of similar Mg# and trace element abundances to the mantle xenocrysts may be xenocrysts overgrown by later olivine crystallised from the lamproite magma. Magmatic olivines Mg#91-92 are estimated to have been in equilibrium with olivine lamproite magma(s) containing ~22-24 wt% MgO. The xenocrystic mantle olivines Mg90-92.5 in the olivine lamproites are inferred from trace element abundances to be mostly derived from garnet peridotite with equilibration temperatures estimated from the Al-in-olivine thermometer (Bussweiler et al. 2017) to be ~1000-1270 °C at depths of 115-190 km. Olivines from the deeper lithosphere are less depleted (lower Mg#, higher Na, Al, P, Ti, Zr etc) than those at shallower depths, a feature suggested to reflect the combined effects of metasomatic re-enrichment of the craton roots (Ti, Fe, Zr etc) and increasing temperature with depth of origin (Na, Al, Ca). The West Kimberley lamproite olivines are not enriched in Li, as might be expected if their source regions contained continental sedimentary material as has been previously inferred from lamproite large-ion-lithophile trace elements, and Sr and Pb isotopes.
DS201812-2822
2018
Jaques, A.L., Luguet, A., Smith, C.B., Pearson, D.G., Yaxley, G.M., Kobussen, A.F.Argyle deposit: Nature of the mantle beneath the Argyle AK1 lamproite pipe: constraints from mantle xenoliths, diamonds, and lamproite geochemistry.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 119-144.Australia, western Australiadeposit - Argyle
DS201806-1229
2018
Jayananda, M., Santosh, M., Aadhiseshan, K.R.Formation of Archean (3600-2500 Ma) continental crust in the Dharwar craton, southern India.Earth Science Reviews, Vol. 181, pp. 12-42.Indiageodynamics

Abstract: The generation, preservation and destruction of continental crust on Earth is of wide interest in understanding the formation of continents, cratons and supercontinents as well as related mineral deposits. In this contribution, we integrate the available field, petrographic, geochronologic, elemental Nd-Hf-Pb isotope data for greenstones, TTG gneisses, sanukitoids and anatectic granites from the Dharwar Craton (southern India). This review allows us to evaluate the accretionary processes of juvenile crust, mechanisms of continental growth, and secular evolution of geodynamic processes through the 3600-2500?Ma window, hence providing important insights into building of continents in the Early Earth. The Dharwar Craton formed by assembly of micro-blocks with independent thermal records and accretionary histories. The craton can be divided into three crustal blocks (western, central and eastern) separated by major shear zones. The western block contains some of the oldest basement rocks with two generations of volcano-sedimentary greenstone sequences and discrete potassic plutons whereas the central block consist of older migmatitic TTGs, abundant younger transitional TTGs, remnants of ancient high grade supracrustal rocks, linear volcanic-dominated greenstone belts, voluminous calc-alkaline granitoids of sanukitoid affinity and anatectic granites. In contrast, the eastern block comprises younger transitional TTGs, abundant diatexites, thin volcanic-sedimentary greenstone belts and calc-alkaline plutons. Published geochronologic data show five major periods of felsic crust formation at ca. 3450-3300?Ma, 3230-3150?Ma, 3000-2960?Ma, 2700-2600?Ma, and 2560-2520?Ma which are sub-contemporaneous with the episodes of greenstone volcanism. U-Pb ages of inherited zircons in TTGs, as well as detrital zircons together with Nd-Pb-Hf isotope data, reveal continental records of 3800-3600?Ma. The U-Pb zircon data suggest at least four major reworking events during ca. 3200?Ma, 3000?Ma, 2620-2600?Ma, and 2530-2500?Ma corresponding to lower crustal melting and spatially linked high grade metamorphic events. The TTGs are sub-divided into the older (3450-3000?Ma) TTGs and the younger (2700-2600?Ma) transitional TTGs. The older TTGs can be further sub-divided into low-Al and high-Al groups. Elemental and isotopic data suggest that the low-Al type formed by melting of oceanic island arc crust within plagioclase stability field. In contrast, the elemental and isotopic features for the high-Al group suggest derivation of their magmatic precursor by melting of oceanic arc crust at deeper levels (55-65?km) with variable garnet and ilmenite in residue. The transitional TTGs likely formed by melting of composite sources involving both enriched oceanic arc crust and sub-arc mantle with minor contamination of ancient crustal components. The geochemical and isotopic compositions of granitoids with sanukitoid affinity suggest derivation from enriched mantle reservoirs. Finally, anatectic granites were produced by reworking of crustal sources with different histories. In the light of the data reviewed in this contribution, we propose the following scenario for the tectonic evolution of the Dharwar Craton. During 3450-3000?Ma, TTGs sources (oceanic arc crust) formed by melting of down going slabs and subsequent melting of such newly formed crust at different depths resulted in TTG magmas. On the contrary, by 2700?Ma the depth of slab melting increased. Melting of slab at greater depth alongside the detritus results in enriched melts partly modified the overlying mantle wedge. Subsequent melting of such newly formed enriched oceanic arc crust and surrounding arc-mantle generated the magmatic precursor to transitional TTGs. Finally at ca. 2600-2560?Ma, eventual breakoff of down going slab caused mantle upwelling which induced low degree (10-15%) melting of overlying enriched mantle at different depths, thereby, generating the sanukitoid magmas which upon emplacement into the crust caused high temperature metamorphism, reworking and final cratonization.
DS201812-2823
2018
Jerram, D.A., Sharp, T.H., Torsvik, T.H., Poulson, R., Watton, T.H., Freitag, U., Halton, A., Sherlock, S.C., Malley, J.A.S., Finley, A., Roberge, J., Swart, R., Fabregas, P., Ferreira, C.H., Machado, V.Volcanic constraints on the unzipping of Africa from South America: insights from new geochronological controls alone the Angola margin.Tectonophysics, doi.org/10.1016/ j.tecto.2018.07.027 33p.Africa, Angola, South Americageochronology

Abstract: The breakup of Africa from South America is associated with the emplacement of the Paraná-Etendeka flood basalt province from around 134 Ma and the Tristan da Cunha plume. Yet many additional volcanic events occur that are younger than the main pulse of the Paraná-Etendeka and straddle the rift to drift phases of the main breakup. This contribution reports on new geochronological constraints from the Angolan part of the African Margin. Three coastal and one inland section have been sampled stretching across some 400 Km, with 39Ar/40Ar, U-Pb and Palaeontology used to provide age constraints. Ages from the new data range from ~100 to 81 Ma, with three main events (cr. 100, 91 and 82-81 Ma). Volcanic events are occurring within the Early to Late Cretaceous, along this part of the margin with a general younging towards Namibia. With the constraints of additional age information both onshore and offshore Angola, a clear younging trend at the early stages of rift to drift is recorded in the volcanic events that unzip from North to South. Similar age volcanic events are reported from the Brazilian side of the conjugate margin, and highlight the need to fully incorporate these relatively low volume volcanic pulses into the plate tectonic breakup models of the South Atlantic Margin.
DS201803-0456
2018
Joel, L.Erasing a billion years of geologic time across the globe.Eos, doi.org/10.1029/2018E0092065Mantlethermochronology

Abstract: The Great Unconformity "a huge time gap in the rock record" may have been triggered by the uplift of an ancient supercontinent, say researchers using a novel method for dating rocks.
DS201807-1500
2018
Joel, L.Ancient Earth froze over in a geologic instant. Snowball Earth and mentions NWT glaciationSciencemag.org, doi:10.1126/ science.aau4137Mantlegeomorphology
DS201810-2332
2018
Johnson, B.W., Goldblatt, C.The new Earth system nitrogen model. EarthNGeochemistry, Geophysics, Geosystems, Vol. 19, 8, pp. 2516-2542.Mantlenitrogen

Abstract: The amount of nitrogen in the atmosphere, oceans, crust, and mantle have important ramifications for Earth's biologic and geologic history. Despite this importance, the history and cycling of nitrogen in the Earth system is poorly constrained over time. For example, various models and proxies contrastingly support atmospheric mass stasis, net outgassing, or net ingassing over time. In addition, the amount available to and processing of nitrogen by organisms is intricately linked with and provides feedbacks on oxygen and nutrient cycles. To investigate the Earth system nitrogen cycle over geologic history, we have constructed a new nitrogen cycle model: EarthN. This model is driven by mantle cooling, links biologic nitrogen cycling to phosphate and oxygen, and incorporates geologic and biologic fluxes. Model output is consistent with large (2-4x) changes in atmospheric mass over time, typically indicating atmospheric drawdown and nitrogen sequestration into the mantle and continental crust. Critical controls on nitrogen distribution include mantle cooling history, weathering, and the total Bulk Silicate Earth+atmosphere nitrogen budget. Linking the nitrogen cycle to phosphorous and oxygen levels, instead of carbon as has been previously done, provides new and more dynamic insight into the history of nitrogen on the planet.
DS201812-2824
2018
Johnson, K.Brauna: South America's first kimberlite diamond producer. Symposio Brasileiro de geologie do diamante , 23 ppts. Available pdfSouth America, Brazil, Bahiadeposit - Brauna
DS201812-2825
2018
Johnson, K.Brauna diamond mine - South America's first kimberlite diamond producer. Lipari7th Symposio Brasileiro de Geologia do Diamante , Presentation listed South America, Brazil, Bahiadeposit - Brauna
DS201811-2582
2018
Johnson, T.E., Gardiner, N.J., Miljkovic, K., Spencer, C.J., Kirkland, C.L., Bland, P.A., Smithies, H.An impact melt origin for Earth's oldest known evolved rocks. Acasta GneissNature Geoscience, Vol. 11, pp. 795-799.Canada, Northwest Territoriesmelting

Abstract: Earth’s oldest evolved (felsic) rocks, the 4.02-billion-year-old Idiwhaa gneisses of the Acasta Gneiss Complex, northwest Canada, have compositions that are distinct from the felsic rocks that typify Earth’s ancient continental nuclei, implying that they formed through a different process. Using phase equilibria and trace element modelling, we show that the Idiwhaa gneisses were produced by partial melting of iron-rich hydrated basaltic rocks (amphibolites) at very low pressures, equating to the uppermost ~3?km of a Hadean crust that was dominantly mafic in composition. The heat required for partial melting at such shallow levels is most easily explained through meteorite impacts. Hydrodynamic impact modelling shows not only that this scenario is physically plausible, but also that the region of shallow partial melting appropriate to formation of the Idiwhaa gneisses would have been widespread. Given the predicted high flux of meteorites in the late Hadean, impact melting may have been the predominant mechanism that generated Hadean felsic rocks.
DS201809-2046
2018
Johnson, T.E., Gardiner, N.J., Miljkovic, K., Spencer, C.J., Kirkland, C.L., Bland, P.A., Smithies, R.H.Are Earth's oldest felsic rocks impact melts? Acasta Gneiss ComplexGoldschmidt Conference, 1p. AbstractCanada, Northwest Territoriesmeteorite

Abstract: Earth’s oldest felsic rocks, the 4.02 billion-year-old Idiwhaa gneisses of the Acasta Gneiss Complex, northwest Canada, have compositions that are distinct from the felsic rocks that typify Earth’s ancient continental nuclei, implying they formed through a different process. Using phase equilibria and trace element modelling, we show that the Idiwhaa gneisses were produced by partial melting of ironrich amphibolite host rocks at very low pressures, equating to the uppermost ~3 km of mafic crust. The heat required for such shallow melting is most easily explained through meteorite impacts. Hydrodynamic impact modelling shows that, not only is this scenario physically plausible, but the region of shallow melting appropriate to formation of the Idiwhaa gneisses would have been widespread. Given the predicted high flux of meteorites during the late Hadean, impact melting may have been the predominant mechanism that generated Hadean felsic rocks.
DS201808-1755
2018
Jollands, M.C., Hanger, B.J., Yaxley, G.M., Hermann, J., Kilburn, M.R.Timescales between mantle metasomatism and kimberlite ascent indicated by diffusion profiles in garnet crystals from peridotite xenoliths.Earth and Planetary Science Letters, Vol. 481, 1, pp. 143-153.Mantlekimberlite

Abstract: Rare garnet crystals from a peridotite xenolith from the Wesselton kimberlite, South Africa, have distinct zones related to two separate episodes of mantle metasomatism. The garnet cores were firstly depleted through melt extraction, then equilibrated during metasomatism by a potentially diamond-forming carbonate-bearing or proto-kimberlitic fluid at 1100-1300?°C and 4.5-5.5 GPa. The garnet rim chemistry, in contrast, is consistent with later overgrowth in equilibrium with a kimberlite at around and . This suggests that the rock was physically moved upwards by up to tens of kilometres between the two metasomatic episodes. Preserved high Ca, Al and Cr contents in orthopyroxenes suggest this uplift was tectonic, rather than magmatic. Diffusion profiles were measured over the transitions between garnet cores and rims using electron microprobe (Mg, Ca, Fe for modelling, plus Cr, Mn, Ti, Na, Al) and nano Secondary Ion Mass Spectrometry (NanoSIMS; 89Y, along with 23Na, Ca, Cr, Fe, Mn and Ti) analyses. The short profile lengths (generally <10 ?m) and low Y concentrations (0.2-60 ppm) make the NanoSIMS approach preferable. Diffusion profiles at the interface between the zones yield constraints on the timescale between the second metasomatic event and eruption of the kimberlite magma that brought the xenolith to the surface. The time taken to form the diffusion profiles is on the order of 25 days to 400 yr, primarily based on modelling of Y diffusion along with Ca, Fe and Mg (multicomponent diffusion) profiles. These timescales are too long to be produced by the interaction of the mantle xenolith with the host kimberlite magma during a single-stage ascent to the crust (hours to days). The samples offer a rare opportunity to study metasomatic processes associated with failed eruption attempts in the cratonic lithosphere.
DS201806-1230
2018
Jones, T.J., Russell, J.K.Attrition in the kimberlite system. Olivine Mineralogy and Petrology, in press available, 11p.Mantlekimberlite ascent

Abstract: The sustained transportation of particles in a suspension commonly results in particle attrition leading to grain size reduction and shape modification. Particle attrition is a well-studied phenomenon that has mainly focussed on sediments produced in aeolian or fluvial environments. Here, we present analogue experiments designed to explore processes of attrition in the kimberlite system; we focus on olivine as it is the most abundant constituent of kimberlite. The attrition experiments on olivine use separate experimental set-ups to approximate two natural environments relevant to kimberlites. Tumbling mill experiments feature a low energy system supporting near continual particle-particle contact and are relevant to re-sedimentation and dispersal processes. Experiments performed in a fluidized particle bed constitute a substantially higher energy environment pertinent to kimberlite ascent and eruption. The run-products of each experiment are analysed for grain size reduction and shape modification and these data are used to elucidate the rates and extents of olivine attrition as a function of time and energy. Lastly, we model the two experimental datasets with an empirical rate equation that describes the production of daughter products (fines) with time. Both datasets approach a fines production limit, or plateau, at long particle residence times; the fluidized system is much more efficient producing a substantially higher fines content and reaches the plateau faster. Our experimental results and models provide a way to forensically examine a wide range of processes relevant to kimberlite on the basis of olivine size and shape properties.
DS201809-2047
2018
Joy, S., Van der Linde, G., Choudbury, A.K., Deb, G.K., Tappe, S.Reassembly of the Dharwar and Bastar cratons at ca. 1 Ga: evidence from multiple tectonothermal events along the Karimnagar granulite belt and Khammam schist belt, southern India.Journal of Earth System Science, Vol. 127, 6, pp. 76- doi:10.1007/s12040-018-0988-2Indiacratons

Abstract: The northern part of the Nellore-Khammam schist belt and the Karimnagar granulite belt, which are juxtaposed at high angle to each other have unique U-Pb zircon age records suggesting distinctive tectonothermal histories. Plate accretion and rifting in the eastern part of the Dharwar craton and between the Dharwar and Bastar craton indicate multiple and complex events from 2600 to 500 Ma. The Khammam schist belt, the Dharwar and the Bastar craton were joined together by the end of the Archaean. The Khammam schist belt had experienced additional tectonic events at ?1900 and ?1600 Ma. The Dharwar and Bastar cratons separated during development of the Pranhita-Godavari (P-G) valley basin at ?1600 Ma, potentially linked to the breakup of the Columbia supercontinent and were reassembled during the Mesoproterozoic at about 1000 Ma. This amalgamation process in southern India could be associated with the formation of the Rodinia supercontinent. The Khammam schist belt and the Eastern Ghats mobile belt also show evidence for accretionary processes at around 500 Ma, which is interpreted as a record of Pan-African collisions during the Gondwana assembly. From then on, southern India, as is known today, formed an integral part of the Indian continent.
DS201810-2334
2018
Juncker, C., Herreweghe, A., DeLaunay, A.Les diamants de Golconde.Revue de Gemmologie A.F.G. IN: French, No. 202, pp. 22-26Indiahistory
DS201808-1756
2018
Kaboli, S., Burnley, P.C.Direct observations of crystal defects in polycrystalline diamond. CVDMaterials Characterization, Vol. 142, pp. 154-161.Globalsynthetics

Abstract: Crystal defects are abundant in synthetic diamond produced by chemical vapor deposition (CVD). We present the first images of crystal defects in a bulk polycrystalline CVD diamond sample using general electron channeling contrast imaging (ECCI) in a field emission scanning electron microscope (FE-SEM). For enhancement of channeling contrast of this material, we introduce a novel protocol for diamond surface preparation that involves acid etching. Using this protocol, we imaged three types of crystal defects including twins, stacking faults and dislocations. Each defect was identified based on its appearance in electron channeling contrast (ECC) micrographs. We analyzed grains containing twins and dislocations using electron backscatter diffraction (EBSD) crystal orientation mapping. We found a large population of grains that contained ?3 type twins on {111} planes with a 60°?111? angle-axis pair of misorientation for twin boundaries. In addition, we identified {111} stacking faults and {111} helical dislocations. These observations are in agreement with reports of crystal defects in CVD diamond thin foils studied by a transmission electron microscope (TEM).
DS201812-2826
2018
Kalikowski Weska, R.Indicator mineral chemistry and geothermobarometry of Sante Fe kimberlitic intrusion.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Mato Grossodeposit - Sante Fe
DS201810-2335
2018
Kaminsky, F., Wirth, R., Schrieber, A.Unusual phosphide, carbide and carbonate from the Morasko 1AB-MG iron meteorite.81st Annual Meeting of the Meteoritical Society 2018 LPI Contribution no. 2067, 2p. Abstract pdfRussiameteorite
DS201802-0243
2017
Kaminsky, F.V.Pecularities of lower-mantle diamonds. ***IN RUSStarosin, V.I. (ed) Problems of the mineralogy, economic geology and mineral resources. MAKS Press, Moscow *** IN RUS, pp. 166-176.Mantlediamond morphology
DS201812-2827
2018
Kaminsky, F.V.Water in the Earth's lower mantle.Geochemistry International, Vol. 56, 12, pp. 1117-1134.Mantlebridgmanite, perovskite
DS201807-1501
2018
Kaminsky, F.V., Wirth, R., Anikin, L.P., Morales, L., Schreiber, A.Carbonado like diamond from the Avacha active volcano in Kamchatka, Russia.Lithos, in press available, 57p.Russiacarbonado

Abstract: In addition to a series of finds of diamond in mafic volcanic and ultramafic massive rocks in Kamchatka, Russia, a carbonado-like diamond aggregate was identified in recent lavas of the active Avacha volcano. This aggregate differs from 'classic carbonado' by its location within an active volcanic arc, well-formed diamond crystallites, and cementing by Si-containing aggregates rather than sintering. The carbonado-like aggregate contains inclusions of Mn-Ni-Si-Fe alloys, native ?-Mn, tungsten and boron carbides, which are uncommon for both carbonado and monocrystalline diamonds. Mn-Ni-Si-Fe alloys, trigonal W2C and trigonal B4C are new mineral species that were not previously found in the natural environment. The formation of the carbonado-like diamond aggregate started with formation at 850-1000 °C of tungsten and boron carbides, Mn-Ni-Si-Fe alloys and native ?-Mn, which were used as seeds for the subsequent crystallization of micro-sized diamond aggregate. In the final stage, the diamond aggregate was cemented by amorphous silica, tridymite, ?-SiC, and native silicon. The carbonado-like aggregate was most likely formed at near-atmospheric pressure conditions via the CVD mechanism during the course or shortly after one of the volcanic eruption pulses of the Avacha volcano. Volcanic gases played a great role in the formation of the carbonado-like aggregate.
DS201804-0705
2017
Kang, S., Fournier, D., Oldenburg, D.W.Inversion of airborne geophysics over D0-27/D0-18 kimberlites. Part 3: Induced polarization.Society of Exploration Geophysicists, Interpretation, August T 327, 14p.Canada, Northwest Territoriesdeposit -Tli Kwi Cho

Abstract: The geologically distinct DO-27 and DO-18 kimberlites, often called the Tli Kwi Cho (TKC) kimberlites, have been used as a testbed for airborne geophysical methods applied to kimberlite exploration. This paper, which is the last of a three-part series, focuses on extracting chargeability information from time-domain electromagnetic (TEM) data. Three different TEM surveys, having similar coincident-loop geometry, have been carried out over TKC. Each records negative transients over the main kimberlite units and this is a signature of induced polarization (IP) effects. By applying a TEM-IP inversion workflow to a VTEM data set we decouple the EM and IP responses in the observations and then recover 3D pseudo-chargeability models at multiple times. A subsequent analysis is used to recover Cole-Cole parameters. Our models demonstrate that both DO-18 and DO-27 pipes are chargeable, but they have different Cole-Cole time constants: 110 and 1160 ?s, respectively. At DO-27, we also distinguish between two adjacent kimberlite units based on their respective Cole-Cole time constants. Our chargeability models are combined with the den-sity, magnetic susceptibility and conductivity models from Papers I and II and allow us to build a 3D petrophysical model of TKC using only information obtained from airborne geophysics. Comparison of this final petrophysical model to a 3D geological model derived from the extensive drilling program demonstrates that we can characterize the three main kimberlite units at TKC: HK, VK, and PK in 3D by using airborne geophysics.
DS201810-2336
2018
Kankeu, B., Greiling, R.O., Nzenti, J.P., Ganno, S., Danguene, P.Y.E., Basshahak, J., Hell, J.V.Contrasting Pan-African structural styles at the NW margin of the Congo shield in Cameroon.Journal of African Earth Sciences, Vol. 146, pp. 28-47.Africa, Camerooncraton

Abstract: Field, microstructural, and anisotropy of magnetic susceptibility (AMS, magnetic fabrics) studies assessed the Pan-African deformational history and strain geometry at the southern margin of the Central African Fold Belt (CAFB) against the older, cratonic basement of the Congo Shield (CS). Reflected light microscopy and thermomagnetic studies supported the identification of magnetic minerals. Data cover a low angle thrust margin (Mbengis-Sangmelima area) in the east and high angle shear zones cutting the margin (Kribi area) in the west, at the Atlantic coast. In the CS basement units, magnetic anisotropy is generally higher than in the low grade Pan-African units. In the latter, early D1/D2 shortening produced a flat-lying magnetic foliation parallel with the regional trend of the belt, a shallow magnetic lineation, and mostly oblate fabrics. Subsequent D3 deformation is only of local importance in the Mbengis-Sangmelima area. The magnetic lineation shows distinct maxima in NNE-SSW direction, parallel with the low angle tectonic transport direction. In the Kribi area, the NNE-SSW trending Kribi-Campo shear zone (KCSZ) affected both older rocks and Pan-African high grade metapelites of the Yaoundé unit together with their basal thrust. The early planar fabric (S1) was overprinted during D2 folding under relatively high T conditions, and subsequent D3 wrenching. Magnetic fabrics document a progressive change from oblate towards prolate ellipsoids towards the KCSZ. Magnetic foliations with medium to steep dips curve into the N-S to NE-SW orientation of the KCSZ, lineations follow the same trend with shallow to medium plunges. This fabric implies that the KCSZ is a Pan-African strike-slip shear zone with a subordinate component of compression. Strike-slip tectonics in the west (KCSZ) and thrusting in the east imply N-S to NE-SW convergence during Pan-African terrane assembly against the present northern margin of the CS. In addition, the KCSZ may separate the CS from the São Francisco Craton in Brazil and thus be the northern part of a link connecting the CAFB to the West Congo Belt in the south. This putative Pan-African link separated the São Francisco Craton from the Congo Shield prior to Mesozoic Gondwana break-up.
DS201801-0027
2017
Kargin, A.V., Golubeva, Yu.Yu.Geochemical typification of kimberlite and related rocks of the North Anabar region, Yakutia.Doklady Earth Sciences, Vol. 477, 1, pp. 1291-1294.Russiakimberlite, alnoite, carbonatite

Abstract: The results of geochemical typification of kimberlites and related rocks (alneites and carbonatites) of the North Anabar region are presented with consideration of the geochemical specification of their source and estimation of their potential for diamonds. The content of representative trace elements indicates the predominant contribution of an asthenospheric component (kimberlites and carbonatites) in their source, with a subordinate contribution of vein metasomatic formations containing Cr-diopside and ilmenite. A significant contribution of water-bearing potassium metasomatic parageneses is not recognized. According to the complex of geochemical data, the studied rocks are not industrially diamondiferous.
DS201802-0244
2017
Kargin, A.V., Golubeva, Yu.Yu., Demonterova, E.I., Kovalchuk, E.V.Petrographical geochemical types of Triassic alkaline ultramafic rocks in the Northern Anabar Province, Yakutia, Russia.Petrology, Vol. 25, 6, pp. 535-565.Russia, Yakutiaorangeite

Abstract: A classification suggested for alkaline ultramafic rocks of the Ary-Mastakh and Staraya Rechka fields, Northern Anabar Shield, is based on the modal mineralogical composition of the rocks and the chemical compositions of their rock-forming and accessory minerals. Within the framework of this classification, the rocks are indentified as orangeite and alkaline ultramafic lamprophyres: aillikite and damtjernite. To estimate how much contamination with the host rocks has modified their composition when the diatremes were formed, the pyroclastic rocks were studied that abound in xenogenic material (which is rich in SiO2, Al2O3, K2O, Rb, Pb, and occasionally also Ba) at relatively low (La/Yb)PM, (La/Sm)PM, and not as much also (Sm/Zr)PM and (La/Nb)PM ratios. The isotopic composition of the rocks suggests that the very first melt portions were of asthenospheric nature. The distribution of trace elements and REE indicates that one of the leading factors that controlled the diversity of the mineralogical composition of the rocks and the broad variations in their isotopic-geochemical and geochemical characteristics was asthenosphere-lithosphere interaction when the melts of the alkaline ultramafic rocks were derived. The melting processes involved metasomatic vein-hosted assemblages of carbonate and potassic hydrous composition (of the MARID type). The alkaline ultramafic rocks whose geochemistry reflects the contributions of enriched vein assemblages to the lithospheric source material, occur in the northern Anabar Shield closer to the boundary between the Khapchan and Daldyn terranes. The evolution of the aillikite melts during their ascent through the lithospheric mantle could give rise to damtjernite generation and was associated with the separation of a C-H-O fluid phase. Our data allowed us to distinguish the evolutionary episodes of the magma-generating zone during the origin of the Triassic alkaline ultramafic rocks in the northern Anabar Shield.
DS201812-2828
2018
Kastek, N., Ernst, R.E., Cousens, B.L., Kamo, S.L., Bleeker, W., Soderlund, U., Baragar, W.R.A., Sylvester, P.U-Pb geochronology and geochemistry of the Povungnituk Group of the Cape Smith Belt: part of a craton scale circa 2.0 Ga Minto-Povungnituk Large Igneous Province, northern Superior craton. Lithos, Vol. 320-321, pp. 315-331.Canada, Quebeccarbonatite

Abstract: Magmatism of the Povungnituk Group of the Cape Smith Belt, northern Superior craton, was formed in three stages: (i)early alkaline magmatism and associated carbonatites (undated), (ii) a main flood basalt sequence (Beauparlant Formation) (constrained between 2040 and 1991?Ma), and (iii) a late stage alkaline pulse (Cecilia Formation) (ca. 1959?Ma). We suggest that the main stage of magmatic activity (middle pulse) was of short duration. A new UPb baddeleyite age of 1998?±?6?Ma is obtained from a dolerite sill intruding the uppermost section of the Beauparlant Formation. This age has regional significance because it matches the previously obtained 1998?±?2?Ma age for the Watts Group (Purtuniq) ophiolite of the northern Cape Smith Belt and the 1998?±?2?Ma?U-Pb age of the Minto dykes intruding the craton to the south. These coeval units, along with additional units correlated on paleomagnetic grounds (Eskimo Formation), are interpreted to define a large igneous province (LIP), extending over an area of >400,000?km2, which we herein define as the Minto-Povungnituk LIP. Geochemical comparison between the Watts Group ophiolite, Minto dykes and the mafic Povungnituk Group shows significant differences allowing these data to be divided into two groups and domains within the LIP. A northern domain, comprising the Povungnituk and Watts groups, shows mixing between a depleted mantle source and a more enriched mantle plume-sourced melt. A southern domain comprising the Minto dykes and the paleomagnetically linked Eskimo Formation shows signs of an even more enriched source, while these magmas also show the effect of crustal contamination. Two distinct source mechanisms can be responsible for the observed geochemical differences between the two domains. First, a difference in lithospheric sources, where melting of different portions of Superior craton lithosphere caused the different melt signatures in the interior of the craton. In this case magmatism in the two domains is only related by having the same heat source (e.g.,a mantle plume) interpreted to be located on the northwestern side of the northern Superior craton. Second, two distinct deep mantle sources that remained separated within the ascending plume. This is analogous to some current hotspots interpreted to sample both large low shear velocity provinces (LLSVP) and adjacent ambient deep mantle. This latter interpretation would allow for the use of bilateral chemistry in LIPs as a potential tool for the recognition and mapping of the LLSVP boundaries throughout Earth's history.
DS201805-0954
2018
Kaur, G., Mitchell, R.H., Ahmed, S.Mineralogy of the Vattikod lamproite dykes, Ramadugu lamproite field, Nalgonda District, Telangama: a possible expression of ancient subduction related alkaline magmatism along eastern Ghats mobile belt, India.Mineralogical Magazine, Vol. 82, 1, pp. 35-58.Indialamproite

Abstract: The mineralogy of nine recently discovered dykes (VL1:VL8 and VL10) in the vicinity of Vattikod village, Nalgonda district in Telangana State is described. The mineral assemblage present and their compositions are comparable to those of bona fide lamproites in terms of the presence of phlogopite (Ti-rich, Al-poor phlogopite and tetraferriphlogopite); amphiboles (potassic-arfvedsonite, potassic-richterite, potassic-ferro-richterite, potassic-katophorite, Ti-rich potassic-katophorite, Ti-rich potassic-magnesio-katophorite); Al-poor clinopyroxenes; feldspars (K-feldspar, Ba-K-feldspar and Na-feldspar) and spinels (chromite-magnetite and qandilite-ulvöspinel-franklinite). These dykes have undergone diverse and significant degrees of deuteric alteration as shown by the formation of secondary phases such as: titanite, allanite, hydro-zircon, calcite, chlorite, quartz and cryptocrystalline SiO2. On the basis of their respective mineralogy: the VL4 and VL5 dykes are classified as pseudoleucite-phlogopite lamproite; VL2 and VL3 dykes as pseudoleucite-amphibole-lamproite; and VL6, VL7 and VL8 as pseudoleucite-phlogopite-amphibole-lamproite. VL10 is extensively altered but contains fresh euhedral apatite microphenocrysts together with pseudomorphs after leucite and is classified as a pseudoleucite-apatite-(phlogopite?) lamproite. The mineralogy of the Vattikod lamproite dykes is compared with that of the Ramadugu, Somavarigudem and Yacharam lamproite dykes which also occur in the Ramadugu lamproite field. The lamproites from the Eastern Dharwar Craton are considered as being possible expressions of ancient subduction-related alkaline magmatism along the Eastern Ghats mobile belt.
DS201812-2829
2018
Kazuchits, N.M., Rusetsky, M.S., Kazuchits, V.N., Korolovic, O.V., Kumar, V., Moe, K.S., Wang, W., Zaitsev, A.M. Comparison of HPHT and LPHT annealing of Ib synthetic diamond.Diamond & Related Materials, doi.1016/j.diamond.2018.11.018 30p. Russiasynthetics

Abstract: Defect transformations in type Ib synthetic diamond annealed at a temperature of 1870?°C under stabilizing pressure (HPHT annealing) and in hydrogen atmosphere at normal pressure (LPHT annealing) are compared. Spectroscopic data obtained on the samples before and after annealing prove that the processes of nitrogen aggregation and formation of nitrogen?nickel complexes are similar in both cases. Essential differences between HPHT and LPHT annealing are stronger graphitization at macroscopic imperfections and enhanced lattice distortions around point defects in the latter case. The lattice distortion around point defects is revealed as a considerable broadening of zero-phonon lines of “soft” (vacancy-related) optical centers. It was found that LPHT annealing may enhance overall intensity of luminescence of HPHT-grown synthetic diamonds.
DS201804-0706
2018
Kehew, A., Curry, B.B.Quaternary glaciation of the Great Lakes region: process, landforms, sediments and chronology.Geological Society of America, SPE 530, 244p. $ 60.00United Statesgeomorphology
DS201809-2048
2018
Kempf, E.D., Hermann, J.Hydrogen in corporation and retention in metamorphic olivine during subduction: implications for the deep water cycle.Geology, Vol. 46, 6, pp. 571-574.Mantlewater

Abstract: Incorporation of hydrogen into metamorphic olivine during dehydration reactions in the subducting oceanic lithosphere provides a mechanism to replenish the deep mantle with water. Fourier transform infrared spectroscopy of metamorphic olivines formed at 2.5 GPa and 550 °C through the reaction antigorite + brucite = olivine + chlorite + water shows water contents between 100 and 140 ppm H2O associated exclusively with silicon vacancies, similar to the highest values found in peridotite xenoliths. Brucite involvement in the olivine-forming reaction ensures H2O saturation and a low Si activity, favoring hydrogen incorporation into Si vacancies. The mapped water distribution in olivine is consistent with growth zoning and there is no evidence of water gain or loss. Thus, even for metamorphic timescales of several million years at 550 °C, no ionic diffusion modification is observed, in agreement with recent experimental findings. Metamorphic olivines formed by this dehydration reaction may contribute considerable amounts of water to the deep water cycle. Additionally, olivine with abundant H in Si vacancies are expected to be rheologically weaker than anyhdrous mantle olivine, and might provide a weak interface between slabs and mantle wedges in subduction zones at conditions beyond the stability of hydrous phases.
DS201807-1502
2018
Kendall, J-M., Lithgow-Bertelloni, C.Why is Africa rifting?Geological Society, London Magmatic Rifting and Active Volcanism, Eds. Wright, T.J., Ayele, A., Ferguson, D.J., Kidane, T., Vye-Brown, X. publ. 2016, SP 420, pp. 11-30. from http://sp.lyell collection.orgAfricatectonics, geodynamics

Abstract: Continental rifting has a fundamental role in the tectonic behaviour of the Earth, shaping the surface we live on. Although there is not yet a consensus about the dominant mechanism for rifting, there is a general agreement that the stresses required to rift the continental lithosphere are not readily available. Here we use a global finite element model of the lithosphere to calculate the stresses acting on Africa. We consider the stresses induced by mantle flow, crustal structure and topography in two types of models: one in which flow is exclusively driven by the subducting slabs and one in which it is derived from a shear wave tomographic model. The latter predicts much larger stresses and a more realistic dynamic topography. It is therefore clear that the mantle structure beneath Africa plays a key part in providing the radial and horizontal tractions, dynamic topography and gravitational potential energy necessary for rifting. Nevertheless, the total available stress (c. 100 MPa) is much less than that needed to break thick, cold continental lithosphere. Instead, we appeal to a model of magma-assisted rifting along pre-existing weaknesses, where the strain is localized in a narrow axial region and the strength of the plate is reduced significantly. Mounting geological and geophysical observations support such a model.
DS201810-2337
2018
Keppler, R.Crystallographic preferred orientations in eclogites - a review.Journal of Structual Geology, Vol. 115, pp. 284-296.Mantlesubduction

Abstract: During the last decades, processes taking place in subduction zones have been a topic of extensive debate. There are many models on a tectonic scale, but knowledge of deformation at microscopic levels is essential for an understanding of the processes involved. Crystallographic preferred orientation (CPO) investigations of minerals in eclogites yield the possibility to study deformation in the crustal part of subducted oceanic lithosphere, as well as subducted continental units containing basic intrusions, which are frequently exhumed during continental collision. From CPO data of omphacite and garnet, as well as other constituent minerals in eclogites, conclusions on stress and strain at depth in currently active subduction zones can be drawn, as the pressure-temperature and strain path of the now exhumed rocks can be unraveled. This contribution provides an overview of CPO studies of eclogites concerning slip systems, deformation, strain and other possible CPO forming mechanisms in all major constituent mineral phases in eclogites and the implications of these microstructural data on subduction zone processes are discussed. Nevertheless, there are still many open questions and future research is essential.
DS201808-1757
2018
Kertsman, V., Moilanen, J., Podmogov, Y.Special place of airborne electromagnetic survey in detailed exploration of kimberlites in the conditions of the Angolan shield. CatocaAEM2018/7th International Workshop on Airborne electromagnetics, Held June 17-20, 3p.Africa, Angolageophysics - EM
DS201801-0028
2017
Khachatryan, G.K.Organic matter in diamonds from kimberlite sources: genetic information content.Rudi I Metalli IN RUSSIAN, No. 4, pp. 77-84.Russiadiamond inclusions
DS201801-0029
2017
Khachatryan, G.K.Significance of geological models of Diamondiferous system development for evaluation of diamond absolute age.Rudi I Metalli IN: RUSSIAN, no. 4, pp. 111-117.Russia, Yakutiageochronology
DS201810-2338
2018
Khanna, T.C., Sesha Sai, V.V., Jaffri, S.H., Keshav Krishna, A., Korakoppa, M.M.Boninites in the ~3.3 Ga Holenarsipur greenstone belt, western Dharwar Craton, India.MDPI Geosciences, Researchgate 17p.Indiaboninites

Abstract: In this contribution, we present detailed field, petrography, mineral chemistry, and geochemistry of newly identified high-Si high-Mg metavolcanic rocks from the southern part of the ~3.3 Ga Holenarsipur greenstone belt in the western Dharwar craton, India. The rocks occur as conformable bands that were interleaved with the mafic-ultramafic units. The entire volcanic package exhibits uniform foliation pattern, and metamorphosed under greenschist to low grade amphibolite facies conditions. The rocks are extremely fine grained and exhibit relict primary igneous textures. They are composed of orthopyroxene and clinopyroxene phenocrysts with serpentine, talc, and amphibole (altered clinopyroxene). Cr-spinel, rutile, ilmenite, and apatite occur as disseminated minute grains in the groundmass. The mineralogical composition and the geochemical signatures comprising of high SiO2 (~53 wt. %), Mg# (~83), low TiO2 (~0.18 wt. %), and higher than chondritic Al2O3/TiO2 ratio (~26), reversely fractionated heavy rare earth elements (REE) (GdN/YbN ~ 0.8), resulting in concave-up patterns, and positive Zr anomaly, typically resembled with the Phanerozoic boninites. Depletion in the high field strength elements Nb, and Ti relative to Th and the REE in a primitive mantle normalized trace element variation diagram, cannot account for contamination by pre-existing Mesoarchean continental crust present in the study area. The trace element attributes instead suggest an intraoceanic subduction-related tectonic setting for the genesis of these rocks. Accordingly, the Holenarsipur high-Si high-Mg metavolcanic rocks have been identified as boninites. It importantly indicates that the geodynamic process involved in the generation of Archean boninites, was perhaps not significantly different from the widely recognized two-stage melt generation process that produced the Phanerozoic boninites, and hence provides compelling evidence for the onset of Phanerozoic type plate tectonic processes by at least ~3.3 Ga, in the Earth’s evolutionary history.
DS201807-1503
2018
Khati, T., Matabane, M.Kimberlite country rock contact delineation at Finsch diamond mine. Mining applications and developmentSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 9-22.Africa, South Africadeposit - Finsch
DS201803-0457
2017
Khedr, M.Z., Arai, S.Peridotite chromitite complexes in the eastern Desert of Egypt: insight into Neoproterozoic sub arc mantle processes.Gondwana Research, Vol. 52, pp. 59-70.Africa, Egyptchromitites

Abstract: The Neoproterozoic peridotite-chromitite complexes in the Central Eastern Desert of Egypt, being a part of the Arabian-Nubian Shield, are outcropped along the E-W trend from Wadi Sayfayn, Wadi Bardah, and Jabal Al-Faliq to Wadi Al-Barramiyah, from east to west. Their peridotites are completely serpentinized, and the abundance of bastite after orthopyroxene suggests harzburgite protoliths with subordinate dunites, confirmed by low contents of Al2O3, CaO and clinopyroxene (< 3 vol%) in bulk peridotites. The primary olivine is Fo89.3-Fo92.6, and the residual clinopyroxene (Cpx) in serpentinites contains, on average, 1.1 wt% Al2O3, 0.7 wt% Cr2O3, and 0.2 wt% Na2O, similar in chemistry to that in Izu-Bonin-Marian forearc peridotites. The wide range of spinel Cr-number [Cr/(Cr + Al)], 0.41-0.80, with low TiO2 (0.03 wt%), MnO (0. 3 wt%) and YFe [(Fe3 +/(Cr + Al + Fe3 +) = 0.03 on average)] for the investigated harzburgites-dunites is similar to spinel compositions for arc-related peridotites. The partial melting degrees of Bardah and Sayfayn harzburgites range mainly from 20 to 25% and 25 to 30% melting, respectively; this is confirmed by whole-rock chemistry and Cpx HREE modelling (~ 20% melting). The Barramiyah peridotite protoliths are refractory residues after a wide range of partial melting, 25-40%, where more hydrous fluids are available from the subducting slab. The Neoproterozoic mantle heterogeneity is possibly ascribed mainly to the wide variations of partial melting degrees in small-scale areas, slab-derived inputs and primordial mantle compositions. The Sayfayn chromitites were possibly crystallized from island-arc basaltic melts, followed by crystallization of Barramiyah chromitites from boninitic melt in the late stage of subduction. The residual Cpx with a spoon-shape REE pattern is rich in both LREE and fluid-mobile elements (e.g., Pb, B, Li, Ba, Sr), but poor in HFSE (e.g., Ta, Nb, Zr, Th), similar to Cpx in supra-subduction zone (SSZ) settings, where slab-fluid metasomatism is a prevalent agent. The studied chromitites and their host peridotites represent a fragment of sub-arc mantle, and originated in an arc-related setting. The systematic increase in the volume of chromitite pods with the increasing of their host-peridotite thickness from Northern to Southern Eastern Desert suggests that the thickness of wall rocks is one factor controlling the chromitite size. The factors controlling the size of Neoproterozoic chromitite pods are the thickness, beside the composition, of the host refractory peridotites, compositions and volumes of the supplied magmas, the amount of slab-derived fluids, and possibly the partial melting degree of the host peridotites.
DS201804-0707
2017
Kidane, A.T., Koch-Muller, M., Wiedenbeck, M., de Wit, M.J.Tracking sources of selected diamonds from southern Africa based on carbon isotopic and chemical impurities. River Ranch, Swartruggens, Klipspringer, PremierSouth African Journal of Geology, Vol. 120, 3, pp. 371-384.Africa, Zimbabwe, South Africadiamond morphology

Abstract: The morphological, chemical impurities and carbon isotope properties of diamonds may reveal subtle details of their mantle source and growth characteristics, supporting efforts towards identifying their original place of harvesting. Here we investigate the mantle carbon and nitrogen sources and growth patterns from selected diamonds mined from four kimberlites: macro-sized diamonds from River Ranch kimberlite in Zimbabwe and the Swartruggens and Klipspringer kimberlitic deposits from South Africa, and micro-sized diamonds from the Klipspringer and Premier kimberlite intrusions in South Africa. Type IaAB diamonds are found in all the samples; Type IaB diamonds only occur in samples from the Swartruggens, River Ranch and Premier kimberlites. A single Type II diamond (nitrogen below the detection limit) was also observed in the River Ranch and Premier kimberlites. Both the micro- and macro-sized diamonds from Klipspringer have similar nitrogen contents. Based on the % B-defect, the diamonds from Klipspringer are grouped into low- and high-nitrogen aggregates (i.e. % of B-defect <40% and >56%, respectively) that likely represent two different diamond forming episodes. Time averaged mantle storage temperatures for Type IaAB diamonds are calculated to have been: 1060°C for Swartruggens; 1190°C for River Ranch; 1100°C (low aggregated); and 1170°C (highly aggregated) for Klipspringer, and 1210°C for Premier diamonds. The CL-images of the River Ranch, Klipspringer and Premier diamonds reveal multi-oscillatory growth zones. The carbon isotopic analyses on the diamonds reveal an average ?13CVPDB value of: -4.5‰ for Swartruggens; -4.7‰ for River Ranch; -4.5‰ for Klipspringer; and -3‰ for Premier. With the exception of the diamond from Premier, the average ?13C value of the diamonds are similar to the average ?13C value of the mantle (-5‰), which is similar to the occurrence of diamonds in the other kimberlites. The internal carbon isotopic variation of individual diamonds from Swartruggens, Klipspringer and Premier are less than 4‰, which is similar to the variability of most other diamond occurrences reported from elsewhere in the world. Up to 6.7‰ internal carbon isotopic variation was observed in a single diamond from River Ranch. The internal carbon isotopic studies of the diamonds reveal that the primary carbon in the Swartruggens and Klipspringer was derived from an oxidation of CH4-bearing fluid, whereas in the River Ranch the primary carbon was derived from the reduction of carbonate-or CO2-bearing fluids. The Swartruggens diamonds also reveal a secondary carbon sourced from a reduction of CO2- or carbonate-rich fluid or melt. Diamonds from Klipspringer exhibit a cyclic change in ?13C values that reflects fluctuation in a complex mantle perturbation system or periodic change in fugacity of the mantle. Based on this study, we conclude that, in principle, a selected range of diamond signatures might be used to fingerprint their origins; especially when linked to their other physical properties such as a low temperature magnetic signature.
DS201808-1758
2018
Kimberley ProcessAnnual global summary: 2017 production, imports, exports and KPC counts. All countries listedKimberley process.com, 1p. Globaldiamond production
DS201804-0708
2018
Kiraly, A., Holt, A.F., Funiciello, F., Faccenna, C., Capitanio, F.A.Modeling slab-slab interactions: dynamics of outward dipping double sided subduction systems.Geochemistry, Geophysics, Geosystems, 22p. PdfMantleplate tectonics

Abstract: Slab?slab interaction is a characteristic feature of tectonically complex areas. Outward dipping double?sided subduction is one of these complex cases, which has several examples on Earth, most notably the Molucca Sea and Adriatic Sea. This study focuses on developing a framework for linking plate kinematics and slab interactions in an outward dipping subduction geometry. We used analog and numerical models to better understand the underlying subduction dynamics. Compared to a single subduction model, double?sided subduction exhibits more time?dependent and vigorous toroidal flow cells that are elongated (i.e., not circular). Because both the Molucca and Adriatic Sea exhibit an asymmetric subduction configuration, we also examine the role that asymmetry plays in the dynamics of outward dipping double?sided subduction. We introduce asymmetry in two ways; with variable initial depths for the two slabs (geometric asymmetry), and with variable buoyancy within the subducting plate (mechanical asymmetry). Relative to the symmetric case, we probe how asymmetry affects the overall slab kinematics, whether asymmetric behavior intensifies or equilibrates as subduction proceeds. While initial geometric asymmetry disappears once the slabs are anchored to the 660 km discontinuity, the mechanical asymmetry can cause more permanent differences between the two subduction zones. In the most extreme case, the partly continental slab stops subducting due to the unequal slab pull force. The results show that the slab?slab interaction is most effective when the two trenches are closer than 10-8 cm in the laboratory, which is 600-480 km when scaled to the Earth.
DS201807-1504
2018
Kirkpatrick, S., Mukendwa, J.Operational changes enable Namdeb's southern coastal mining team to reduce risk and increase productivity as we advance deeper into the Atlantic Ocean. SCMSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 203-218.Africa, Namibiadeposit -Namdeb
DS201808-1759
2018
Kirkpatrick, S., Mukendwa, J.Operational changes enable Namdeb's southern coastal mining team to reduce risk and increase productivity as we advance deeper into the Atlantic Ocean. PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 25 ppts.Africa, Namibiadeposit - Namdeb
DS201809-2049
2018
Kiseeva, E., Wood, B.J.Oxidation state of the mantle through inclusions in diamonds.Goldschmidt Conference, 1p. AbstractMantlediamond inclusions

Abstract: The oxidation state and oxygen fugacity (fO2) of Earth’s mantle exert important influences on the compositions of primary melts the speciation and mobility of carbon and sulphur, diamond formation, and the modification of subducted lithosphere [1, 2] It is generally observed that the oxygen fugacity of both cratonic and asthenospheric mantle is close to FMQ in the spinel field and that fO2 in the cratons generally decreases with depth. According to experimental studies combined with thermodynamic modelling, at depths below 180-200 km the decreasing oxygen fugacity should destabilise carbonate with all carbon at greater depths being stored as diamond [1, 3]. These pressure effects also tend to stabilise metal in the transition zone following the disproportionation of divalent iron (FeO) into Fe (metal) and Fe3+ (accommodated in garnet) [4]. To date, inclusions in diamond are the only available samples from the mantle transition zone and the lower mantle and these provide the opportunity for study of redox relationships in the deep mantle. In this study we used synchrotron Mössbauer Spectroscopy to measure Fe3+/(Fe2++ Fe3+) ratios of majoritic inclusions in diamonds from the lowermost upper mantle and the mantle transition zone for comparison with garnets from the shallow mantle. We find that there is a systematic increase with depth of the oxidation state of iron in garnets included in diamonds, with the deepest samples (~550 km depth) having Fe3+/(Fe2++ Fe3+) of up to 0.30, which is more than twice as great as in non-majoritic upper mantle garnets (< 200 km depth) [5]. When converted to oxygen fugacity these measurements imply conditions just above the stability field of metallic iron (above IW).
DS201802-0245
2017
Kiselev, G.P., Yakovlev, E.Yu., Druzhinin, S.V., Galkin, A.S.Distribution of radioactive isotopes in rock and ore of Arkhanelskava pipe from the Arkhanelsk diamond province.Geology of Ore Deposits, Vol. 59, pp. 391-406.Russia, Archangeldeposit - Arkhangelskaya

Abstract: The contents of radioactive elements and the uranium isotopic composition of kimberlite in the Arkhangelskaya pipe at the M.V. Lomonosov deposit and of nearby country rocks have been studied. A surplus of 234U isotope has been established in rocks from the near-pipe space. The high ? = 234U/238U ratio is controlled by the geological structure of the near-pipe space. A nonequilibrium uranium halo reaches two pipe diameters in size and can be regarded as a local ore guide for kimberlite discovery. The rocks in the nearpipe space are also characterized by elevated or anomalous U, Th, and K contents with respect to the background.
DS201804-0709
2018
Kjarsgaard, B.A.Experimental constraints on kimberlite origin, ascent, and eruption.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 28-29. abstractTechnologykimberlite magma
DS201811-2583
2018
Klumb, A.Shifting shades - project on garnets, tourmalines & sapphires - UsambaraGems & Jewellery, Autumn p. 32-35.Africa, Tanzaniatechnology
DS201812-2830
2018
Kobussen, A.F., Howell, D., Shu, Q., Smith, C.B.Bunder deposit: A study of garnet and chromian spinel xenocrysts from the Atri South ultramafic intrusion, Bundelkhand craton, India.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 223-236.Indiadeposit - Bunder
DS201806-1231
2018
Koelemeijer, P., Schuberth, B.S.A., Davies, D.R., Deuss, A., Ritsema, J.Constraints on the presence of post-perovskite in Earth's lowermost mantle from tomographic geodynamic model comparisons.Earth and Planetary Science Letters, Vol. 494, pp. 226-238.Mantleperovskite

Abstract: Lower mantle tomography models consistently feature an increase in the ratio of shear-wave velocity () to compressional-wave velocity () variations and a negative correlation between shear-wave and bulk-sound velocity () variations. These seismic characteristics, also observed in the recent SP12RTS model, have been interpreted to be indicative of large-scale chemical variations. Other explanations, such as the lower mantle post-perovskite (pPv) phase, which would not require chemical heterogeneity, have been explored less. Constraining the origin of these seismic features is important, as geodynamic simulations predict a fundamentally different style of mantle convection under both scenarios. Here, we investigate to what extent the presence of pPv explains the observed high ratios and negative - correlation globally. We compare the statistical properties of SP12RTS with the statistics of synthetic tomography models, derived from both thermal and thermochemical models of 3-D global mantle convection. We convert the temperature fields of these models into seismic velocity structures using mineral physics lookup tables with and without pPv. We account for the limited tomographic resolution of SP12RTS using its resolution operator for both and structures. This allows for direct comparisons of the resulting velocity ratios and correlations. Although the tomographic filtering significantly affects the synthetic tomography images, we demonstrate that the effect of pPv remains evident in the ratios and correlations of seismic velocities. We find that lateral variations in the presence of pPv have a dominant influence on the / ratio and - correlation, which are thus unsuitable measures to constrain the presence of large-scale chemical variations in the lowermost mantle. To explain the decrease in the / ratio of SP12RTS close to the CMB, our results favour a pPv-bearing CMB region, which has implications for the stability field of pPv in the Earth's mantle.
DS201809-2050
2018
Kohn, S.C., Speich, L., Bulanova, G.P., Smith, C.B., Gress, M.U., Davies, G.R.Modelling the temperature history of mantle lithosphere using FTIR maps of diamonds.Goldschmidt Conference, 1p. AbstractAfrica, Zimbabwe. Australia, Canada, Northwest Territories, South Africa, Botswanadeposit - Murowa, Argyle, Diavik, Venetia, Orapa

Abstract: FTIR maps of diamond plates, cut through the centre of growth, contain abundant information about changing defect concentrations from core to rim. These data can, in principle, be interpreted in terms of the variation in conditions of diamond growth and the temperatures experienced by the diamond during the period of mantle residence between growth and exhumation. Many diamonds show multiple growth zones that can be observed by cathodoluminescence. Importantly, the combination of nitrogen concentration and nitrogen aggregation measured by FTIR can be used to determine whether the growth zones are of similar or very different ages (Kohn et al., 2016). In this study, we use automated fitting of several thousand individual spectra within each FTIR map to define a model temperature for each pixel using the Python program, QUIDDIT. We then use a two-stage aggregation model to constrain potential temperature-time histories for each diamond. To take full advantage of the temperature history recorded by zoned diamonds, radiometric ages of inclusions are required. If the growth ages of each zone and the date of exhumation are well-known, then a model temperature can be calculated for each zone. The combination of zone-specific ages and improved quality and processing of FTIR spectra is able to provide unique new insights into the thermal history of diamondbearing lithospheric mantle. For the first time we will be able to use the N defects in diamonds to work out whether a particular location in the lithosphere has heated or cooled over long periods of geological time. The implications for the mechanism of formation of lithosphere will be discussed. We will illustrate the approach using examples of zoned diamonds from Murowa (Zimbabwe), Argyle (Australia), Diavik (Canada), Venetia (South Africa) and Orapa (Botswana).
DS201806-1232
2018
Koivula, J.I.Cr-diopside in diamond. ( from Kimberley)Gems & Gemology, Vol. 54, 1, p. 73.Technologydiamond inclusions
DS201805-0955
2018
Kokandakar, G.J., Ghodke, S.S., Rathna, K., Laxman, B. M., Nagaraju, B., Bhosle, M.V., Kumar, K.V.Density, viscosity and velocity ( ascent rate) of alkaline magmas.Journal of the Geological Society of India, Vol. 91, pp. 135-146.IndiaAlkaline - Prakasam

Abstract: Three distinct alkaline magmas, represented by shonkinite, lamprophyre and alkali basalt dykes, characterize a significant magmatic expression of rift-related mantle-derived igneous activity in the Mesoproterozoic Prakasam Alkaline Province, SE India. In the present study we have estimated emplacement velocities (ascent rates) for these three varied alkaline magmas and compared with other silicate magmas to explore composition control on the ascent rates. The alkaline dykes have variable widths and lengths with none of the dykes wider than 1 m. The shonkinites are fine- to medium-grained rocks with clinopyroxene, phologopite, amphibole, K-feldspar perthite and nepheline as essential minerals. They exhibit equigranular hypidiomorphic to foliated textures. Lamprophyres and alkali basalts characteristically show porphyritic textures. Olivine, clinopyroxene, amphibole and biotite are distinct phenocrysts in lamprophyres whereas olivine, clinopyroxene and plagioclase form the phenocrystic mineralogy in the alkali basalts. The calculated densities [2.54-2.71 g/cc for shonkinite; 2.61-2.78 g/cc for lamprophyre; 2.66-2.74 g/cc for alkali basalt] and viscosities [3.11-3.39 Pa s for shonkinite; 3.01-3.28 Pa s for lamprophyre; 2.72-3.09 Pa s for alkali basalt] are utilized to compute velocities (ascent rates) of the three alkaline magmas. Since the lamprophyres and alkali basalts are crystal-laden, we have also calculated effective viscosities to infer crystal control on the velocities. Twenty percent of crystals in the magma increase the viscosity by 2.7 times consequently decrease ascent rate by 2.7 times compared to the crystal-free magmas. The computed ascent rates range from 0.11-2.13 m/sec, 0.23-2.77 m/sec and 1.16-2.89 m/sec for shonkinite, lamprophyre and alkali basalt magmas respectively. Ascent rates increase with the width of the dykes and density difference, and decrease with magma viscosity and proportion of crystals. If a constant width of 1 m is assumed in the magma-filled dyke propagation model, then the sequence of emplacement velocities in the decreasing order is alkaline magmas (4.68-15.31 m/sec) > ultramafic-mafic magmas (3.81-4.30 m/sec) > intermediate-felsic magmas (1.76-2.56 m/sec). We propose that SiO2 content in the terrestrial magmas can be modeled as a semi-quantitative "geospeedometer" of the magma ascent rates.
DS201804-0710
2018
Kokandakar, G.K., Ghodke, S.S., Rathna, K., Kumar, K.V.Crustal growth along Proterozoic SE India: parameterization of mantle sources, melting, mechanism, and magma differentiation processes.Journal of the Geological Society of India, Vol. 91, 2, pp. 135-146.Indiamagmatism
DS201804-0711
2018
Kokandakar, G.K., Ghodke, S.S., Rathna, K., Kumar, K.V.Density, viscosity and velocity (ascent rate) of alkaline magmas.Journal of the Geological Society of India, Vol. 91, 2, pp. 135-146.IndiaPrakasam alkaline province

Abstract: Three distinct alkaline magmas, represented by shonkinite, lamprophyre and alkali basalt dykes, characterize a significant magmatic expression of rift-related mantle-derived igneous activity in the Mesoproterozoic Prakasam Alkaline Province, SE India. In the present study we have estimated emplacement velocities (ascent rates) for these three varied alkaline magmas and compared with other silicate magmas to explore composition control on the ascent rates. The alkaline dykes have variable widths and lengths with none of the dykes wider than 1 m. The shonkinites are fine- to medium-grained rocks with clinopyroxene, phologopite, amphibole, K-feldspar perthite and nepheline as essential minerals. They exhibit equigranular hypidiomorphic to foliated textures. Lamprophyres and alkali basalts characteristically show porphyritic textures. Olivine, clinopyroxene, amphibole and biotite are distinct phenocrysts in lamprophyres whereas olivine, clinopyroxene and plagioclase form the phenocrystic mineralogy in the alkali basalts. The calculated densities [2.54-2.71 g/cc for shonkinite; 2.61-2.78 g/cc for lamprophyre; 2.66-2.74 g/cc for alkali basalt] and viscosities [3.11-3.39 Pa s for shonkinite; 3.01-3.28 Pa s for lamprophyre; 2.72-3.09 Pa s for alkali basalt] are utilized to compute velocities (ascent rates) of the three alkaline magmas. Since the lamprophyres and alkali basalts are crystal-laden, we have also calculated effective viscosities to infer crystal control on the velocities. Twenty percent of crystals in the magma increase the viscosity by 2.7 times consequently decrease ascent rate by 2.7 times compared to the crystal-free magmas. The computed ascent rates range from 0.11-2.13 m/sec, 0.23-2.77 m/sec and 1.16-2.89 m/sec for shonkinite, lamprophyre and alkali basalt magmas respectively. Ascent rates increase with the width of the dykes and density difference, and decrease with magma viscosity and proportion of crystals. If a constant width of 1 m is assumed in the magma-filled dyke propagation model, then the sequence of emplacement velocities in the decreasing order is alkaline magmas (4.68-15.31 m/sec) > ultramafic-mafic magmas (3.81-4.30 m/sec) > intermediate-felsic magmas (1.76-2.56 m/sec). We propose that SiO2 content in the terrestrial magmas can be modeled as a semi-quantitative “geospeedometer” of the magma ascent rates.
DS201810-2339
2018
Kolesnichenko, M.V., Zedgenizov, D.A., Ragozin, A.L., Litasov, K.D., Shatsky, V.S.The role of eclogites in the redistribution of water in the subcontinental mantle of the Siberian craton: results of determination of the water content in minerals from the Udachnaya pipe eclogites.Russian Geology and Geophysics, Vol. 59, 7, pp. 763-779.Russia, Siberiadeposit - Udachnaya

Abstract: A comprehensive study of 26 mafic mantle xenoliths from the Udachnaya kimberlite pipe was carried out. The contents of major and trace elements, equilibrium temperature parameters, and water content in the rock-forming minerals were determined. The temperatures of formation of the studied rocks are estimated at 800-1300 °C. According to IR spectroscopy data, the water content in clinopyroxenes from the studied eclogites varies from values below the detection limit to 99 ppm. The IR spectra of garnets lack bands of water. The water content in clinopyroxene and orthopyroxene from garnet websterite is 72 and 8 ppm, respectively. The water content in the average rock, calculated from the ratio of the rock-forming minerals, varies from a few to 55 ppm. No relationship among the water content, equilibrium temperatures, and rock composition is established. The low water contents in the eclogites are close to the earlier determined water contents in peridotites from the same pipe and are, most likely, due to the re-equilibration of the eclogites with the rocks of the peridotitic lithospheric mantle. The dehydration of the protolith during its subduction and the partial melting of eclogites before their removal by kimberlitic magma to the surface might be an additional cause of the low water contents in the mantle eclogite xenoliths.
DS201803-0458
2018
Konopasek, J., Janousek, V., Oyhantcabal, P., Slama, J., Ulrich, S.Did the circum Rodinia subduction trigger the Neoproterozoic rifting along the Congo Kalahari craton margin?International Journal of Earth Sciences, Vol. 106, 8, pp. 1-36.Africa, Namibiacraton

Abstract: Early Neoproterozoic metaigneous rocks occur in the central part of the Kaoko-Dom Feliciano-Gariep orogenic system along the coasts of the southern Atlantic Ocean. In the Coastal Terrane (Kaoko Belt, Namibia), the bimodal character of the ca. 820-785 Ma magmatic suite and associated sedimentation sourced in the neighbouring pre-Neoproterozoic crust are taken as evidence that the Coastal Terrane formed as the shallow part of a developing back arc/rift. The arc-like chemistry of the bimodal magmas is interpreted as inherited from crustal and/or lithospheric mantle sources that have retained geochemical signature acquired during an older (Mesoproterozoic) subduction-related episode. In contrast, the mantle contribution was small in ca. 800-770 Ma plutonic suites in the Punta del Este Terrane (Dom Feliciano Belt, Uruguay) and in southern Brazil; still, the arc-like geochemistry of the prevalent felsic rocks seems inherited from their crustal sources. The within-plate geochemistry of a subsequent, ca. 740-710 Ma syn-sedimentary volcanism reflects the ongoing crustal stretching and sedimentation on top of the Congo and Kalahari cratons. The Punta del Este-Coastal Terrane is interpreted as an axial part of a Neoproterozoic “Adamastor Rift”. Its opening started in a back-arc position of a long-lasting subduction system at the edge of a continent that fragmented into the Nico Pérez-Luís Alves Terrane and the Congo and Kalahari cratons. The continent had to be facing an open ocean and consequently could not be located in the interior of the Rodinia. Nevertheless, the early opening of the Adamastor Rift coincided with the lifetime of the circum-Rodinia subduction system.
DS201806-1233
2018
Koornneef, J.M., Berndsen, M., Hageman, L., Gress, M.U., Timmerman, S., Nikogosian, I., van Bergen, M.J., Chinn, I.L., Harris, J.W., Davies, G.R.Melt and mineral inclusions as messengers of volatile recycling in space and time. ( olivine hosted inclusions)Geophysical Research Abstracts www.researchgate.net, Vol. 20, EGU2018-128291p. AbstractAfrica, South Africadiamond inclusions

Abstract: Changing recycling budgets of surface materials and volatiles by subduction of tectonic plates influence the compositions of Earth’s major reservoirs and affect climate throughout geological time. Fluids play a key role in processes governing subduction recycling, but quantifying the exact fate of volatiles introduced into the mantle at ancient and recent destructive plate boundaries remains difficult. Here, we report on the role of fluids and the fate of volatiles and other elements at two very different tectonic settings: 1) at subduction settings, and 2) within the subcontinental lithospheric mantle (SCLM). We will show how olivine-hosted melt inclusions from subduction zones and mineral inclusions in diamond from the SCLM are used to reveal how changing tectonic settings influence volatile cycles with time. Melt inclusions from the complex Italian post-collisional tectonic setting are used to identify changing subduction recycling through time. The use of CO2 in deeply trapped melt inclusions instead of in lavas or volcanic gases provides a direct estimate of deep recycling, minimizing possible effects of contamination during transfer through the crust. The aim is to distinguish if increased recycling of sediments from the down-going plate at continental subduction settings results in increased deep CO2 recycling or if the increased CO2 flux results from crustal degassing of the overriding plate. Both processes likely affected climate through Earth history but could thus far not be discriminated. The study of mineral inclusions and their host diamonds from the SCLM can link changes in the cycling of carbon-rich fluids and the time and process through which the carbon redistribution took place. We use Sm-Nd isotope techniques to date the mineral inclusions and use the carbon isotope data of the host diamonds to investigate the growth conditions. I will present case-studies of peridotitic and eclogitic diamonds from three mines in Southern Africa.
DS201804-0713
2017
Koptev, A., Cloetingh, S., Gerya, T., Calais, E., Leroy, S.Non-uniform splitting of a single mantle plume by double cratonic roots: insights into the origin of the central and southern East African Rift System.Terra Nova, pp. 125-134.Africa, Tanzaniacraton

Abstract: Using numerical thermo?mechanical experiments we analyse the role of an active mantle plume and pre?existing lithospheric thickness differences in the structural development of the central and southern East African Rift system. The plume?lithosphere interaction model setup captures the essential features of the studied area: two cratonic bodies embedded into surrounding lithosphere of normal thickness. The results of the numerical experiments suggest that localization of rift branches in the crust is mainly defined by the initial position of the mantle plume relative to the cratons. We demonstrate that development of the Eastern branch, the Western branch and the Malawi rift can be the result of non?uniform splitting of the Kenyan plume, which has been rising underneath the southern part of the Tanzanian craton. Major features associated with Cenozoic rifting can thus be reproduced in a relatively simple model of the interaction between a single mantle plume and pre?stressed continental lithosphere with double cratonic roots.
DS201802-0246
2018
Kopylova, M.G.Inclusions in Culli nan diamonds: insights on an ancient hot spot and the origin of Type II diamonds.Vancouver Kimberlite Cluster, Feb. 7, 1p. abstractAfrica, South Africadiamond inclusions
DS201802-0247
2017
Koreshkova, M., Downes, H., Millar, I., Levsky, L., Larianov, A.Geochronology of metamorphic events in the lower crust of NW Russia: a xenolith Hf isotope study.Journal of Petrology, Vol. 58, 8, pp. 1567-1589.Russia, Kola Peninsulageochronology

Abstract: Hf isotope data for zircons and whole-rocks from lower crustal mafic granulite and pyroxenite xenoliths from NW Russia are presented together with the results of U-Pb zircon dating, Sm-Nd and Rb-Sr isotopic compositions of bulk-rocks and minerals, and trace element compositions of minerals. Most zircons preserve a record of only the youngest metamorphic events, but a few Grt-granulite xenoliths retain Archean magmatic zircons from their protolith. Metamorphic zircons have highly variable ?Hf(t) values from -25 to -4. The least radiogenic zircons were formed by recrystallization of primary magmatic Archean zircons. Zircons with the most radiogenic ?Hf grew before garnet or were contemporaneous with its formation. Zircons with ?Hf(t) from -15 to -9 formed by various mechanisms, including recrystallization of pre-existing metamorphic zircons, subsolidus growth in the presence of garnet and exsolution from rutile. They inherited their Hf isotopic composition from clinopyroxene, pargasite, rutile and earlier-formed zircon that had equilibrated with garnet. Subsolidus zircons were formed in response to a major change in mineral association (i.e. garnet- and zircon-producing reactions including partial melting). Recrystallized zircons date the onset of high-temperature conditions without a major change in mineral association. Age data for metamorphic zircons fall into five groups: >1•91 Ga, 1•81-1•86 Ga, 1•74-1•77 Ga, 1•64-1•67 Ga and <1•6 Ga. Most ages correlate with metamorphic events in the regional upper crust superimposed onto rocks of the Belomorian belt during formation of the Lapland Granulite Belt. Zircon formation and resetting at 1•64-1•67 Ga significantly postdates Lapland-Kola orogenic events and may relate to the onset of Mesoproterozoic rifting. The youngest ages (1•6-1•3 Ga) correspond to an event that affected only a few grains in some samples and can be explained by interaction with a localized fluid. The observed garnet-granulite associations were formed at 1•83 Ga in Arkhangelsk xenoliths and 1•74-1•76 Ga in most Kola xenoliths. By the end of the Lapland-Kola orogeny, the rocks were already assembled in the lower crust. However, no addition of juvenile material has been detected and preservation of pre-Lapland-Kola metamorphic zircon indicates that some xenoliths represent an older lower crust. Granulites, pyroxenites and Phl-rich rocks have a common metamorphic history since at least c. 1•75 Ga. At about 1•64 Ga metasomatic introduction of phlogopite took place; however, this was only one of several phlogopite-forming events in the lower crust.
DS201801-0030
2017
Koreshkova, M., Downes, H., Millar, I., Levsky, L., Larionov, A., Sergeev, S.Geochronology of metamorphic events in the lower crust beneath NW Russia: a xenolith Hf isotope study.Journal of Petrology, Vol. 58, 8, pp. 1567-1589.Russia, Kola Peninsulageochronology

Abstract: Hf isotope data for zircons and whole-rocks from lower crustal mafic granulite and pyroxenite xenoliths from NW Russia are presented together with the results of U-Pb zircon dating, Sm-Nd and Rb-Sr isotopic compositions of bulk-rocks and minerals, and trace element compositions of minerals. Most zircons preserve a record of only the youngest metamorphic events, but a few Grt-granulite xenoliths retain Archean magmatic zircons from their protolith. Metamorphic zircons have highly variable ?Hf(t) values from -25 to -4. The least radiogenic zircons were formed by recrystallization of primary magmatic Archean zircons. Zircons with the most radiogenic ?Hf grew before garnet or were contemporaneous with its formation. Zircons with ?Hf(t) from -15 to -9 formed by various mechanisms, including recrystallization of pre-existing metamorphic zircons, subsolidus growth in the presence of garnet and exsolution from rutile. They inherited their Hf isotopic composition from clinopyroxene, pargasite, rutile and earlier-formed zircon that had equilibrated with garnet. Subsolidus zircons were formed in response to a major change in mineral association (i.e. garnet- and zircon-producing reactions including partial melting). Recrystallized zircons date the onset of high-temperature conditions without a major change in mineral association. Age data for metamorphic zircons fall into five groups: >1•91 Ga, 1•81-1•86 Ga, 1•74-1•77 Ga, 1•64-1•67 Ga and <1•6 Ga. Most ages correlate with metamorphic events in the regional upper crust superimposed onto rocks of the Belomorian belt during formation of the Lapland Granulite Belt. Zircon formation and resetting at 1•64-1•67 Ga significantly postdates Lapland-Kola orogenic events and may relate to the onset of Mesoproterozoic rifting. The youngest ages (1•6-1•3 Ga) correspond to an event that affected only a few grains in some samples and can be explained by interaction with a localized fluid. The observed garnet-granulite associations were formed at 1•83 Ga in Arkhangelsk xenoliths and 1•74-1•76 Ga in most Kola xenoliths. By the end of the Lapland-Kola orogeny, the rocks were already assembled in the lower crust. However, no addition of juvenile material has been detected and preservation of pre-Lapland-Kola metamorphic zircon indicates that some xenoliths represent an older lower crust. Granulites, pyroxenites and Phl-rich rocks have a common metamorphic history since at least c. 1•75 Ga. At about 1•64 Ga metasomatic introduction of phlogopite took place; however, this was only one of several phlogopite-forming events in the lower crust.
DS201808-1760
2018
Korolev, N., Kopylova, M., Gurney, J.J., Moore, A.E., Davidson, J.The origin of Type II diamonds as inferred from Culli nan mineral inclusions.Mineralogy and Petrology, doi.org/10.1007/s710-018-0601-z 15p. Africa, South Africadeposit - Cullinan

Abstract: We studied a suite of Cullinan diamonds (<0.3 ct) with mineral inclusions, which comprised 266 Type I and 75 blank Type II (<20 ppm N) diamonds, as classified by infrared spectroscopy. More than 90% (n?=?68) of Type II diamonds do not luminesce. In contrast, 51.9% (n?=?177) of Type I diamonds luminesce, with blue colors of different intensity. Carbon isotopic compositions of Type I and II diamonds are similar, with ?13CVPDB ranging from ?2.1 to ?7.7‰for Type I diamonds (n?=?25), and from ?1.3 to ?7.8- for Type II diamonds (n?=?20). The Type II diamonds are sourced from three parageneses, lithospheric lherzolitic (45%), lithospheric eclogitic (33%), and sublithospheric mafic (22%). The lherzolitic suite contains Cr-pyrope, forsterite, enstatite, clinopyroxene and Cr-spinel formed at 1090-1530 °C and P?=?4.6-7.0 GPa. Lithospheric eclogitic diamonds containing garnet, omphacite, kyanite and coesite comprise 33% of Type II diamonds. The sublithospheric mafic paragenesis is mainly represented by Cr-free majorite, various CaSiO3 phases and omphacite equilibrated at 11.6-26 GPa, in the transition zone and the lower mantle. The lherzolitic paragenesis predominates in Type II diamonds, whereas 79% Type I diamonds are sourced from eclogites. The higher incidence of sublithospheric inclusions was found in Type II diamonds, 22% against 6% in Type I diamonds. The similarity of the mineral parageneses and C isotopic compositions in the small Cullinan Type II and Type I diamonds indicate the absence of distinct mantle processes and carbon sources for formation of studied Type II diamonds. The parent rocks and the carbon sources generally vary for Type II diamonds within a kimberlite and between kimberlites.
DS201804-0714
2018
Korolev, N.M., Kopylova, M., Bussweiller, Y., Pearson, D.G., Gurney, J., Davidson, J.The uniquely high temperature character of Culli nan diamonds: a signature of the Bushveld mantle plume?Lithos, Vol. 304, pp. 362-373.Africa, South Africadeposit - Cullinan

Abstract: The mantle beneath the Cullinan kimberlite (formerly known as "Premier") is a unique occurrence of diamondiferous cratonic mantle where diamonds were generated contemporaneously and shortly following a mantle upwelling that led to the formation of a Large Igneous Province that produced the world's largest igneous intrusion - the 2056?Ma Bushveld Igneous Complex (BIC). We studied 332 diamond inclusions from 202 Cullinan diamonds to investigate mantle thermal effects imposed by the formation of the BIC. The overwhelming majority of diamonds come from three parageneses: (1) lithospheric eclogitic (69%), (2) lithospheric peridotitic (21%), and (3) sublithospheric mafic (9%). The lithospheric eclogitic paragenesis is represented by clinopyroxene, garnet, coesite and kyanite. Main minerals of the lithospheric peridotitic paragenesis are forsterite, enstatite, Cr-pyrope, Cr-augite and spinel; the sublithospheric mafic association includes majorite, CaSiO3 phases and omphacite. Diamond formation conditions were calculated using an Al-in-olivine thermometer, a garnet-clinopyroxene thermometer, as well as majorite and Raman barometers. The Cullinan diamonds may be unique on the global stage in recording a cold geotherm of 40?mW/m2 in cratonic lithosphere that was in contact with underlying convecting mantle at temperatures of 1450-1550?°C. The studied Cullinan diamonds contain a high proportion of inclusions equilibrated at temperatures exceeding the ambient 1327?°C adiabat, i.e. 54% of eclogitic diamonds and 41% of peridotitic diamonds. By contrast, ? 1% of peridotitic diamond inclusions globally yield equally high temperatures. We propose that the Cullinan diamond inclusions recorded transient, slow-dissipating thermal perturbations associated with the plume-related formation of the ~2?Ga Bushveld igneous province. The presence of inclusions in diamond from the mantle transition zone at 300-650?km supports this view. Cullinan xenoliths indicative of the thermal state of the cratonic lithosphere at ~1.2?Ga are equilibrated at the relatively low temperatures, not exceeding adiabatic. The ability of diamonds to record super-adiabatic temperatures may relate to their entrainment from the deeper, hotter parts of the upper mantle un-sampled by the kimberlite in the form of xenoliths or their equilibration in a younger lithosphere after a decay of the thermal disturbance.
DS201811-2584
2018
Kosarev, G., Oreshin, S., Vinnik, L., Makeyeva, L.Mantle transition zone beneath the central Tien Shan: lithospheric delamination and mantle plumes.Tectonophysics, Vol. 723, 1, pp. 172-177.Chinaplumes

Abstract: We investigate structure of the mantle transition zone (MTZ) under the central Tien Shan in central Asia by using recordings of seismograph stations in Kyrgyzstan, Kazakhstan and adjacent northern China. We apply P-wave receiver functions techniques and evaluate the differential time between the arrivals of seismic phases that are formed by P to SV mode conversion at the 410-km and 660-km seismic boundaries. The differential time is sensitive to the thickness of the MTZ and insensitive to volumetric velocity anomalies above the 410-km boundary. Under part of the southern central Tien Shan with the lowest S wave velocity in the uppermost mantle and the largest thickness of the crust, the thickness of the MTZ increases by 15-20 km relative to the ambient mantle and the reference model IASP91. The increased thickness is a likely effect of low (about ? 150 K) temperature. This anomaly is indicative of delamination and sinking of the mantle lithosphere. The low temperature in the MTZ might also be a relic of subduction of the oceanic lithosphere in the Paleozoic, but this scenario requires strong coupling and coherence between structures in the MTZ and in the lithosphere during plate motions in the last 300 Myr. Our data reveal a reduction of thickness of the MTZ of 10-15 km under the Fergana basin, in the neighborhood of the region of small-scale basaltic volcanism at the time near the Cretaceous-Paleogene boundary. The reduced thickness of the MTZ is the effect of a depressed 410-km discontinuity, similar to that found in many hotspots. This depression suggests a positive temperature anomaly of about 100-150 K, consistent with the presence of a thermal mantle plume. A similar depression on the 410-km discontinuity is found underneath the Tarim basin.
DS201811-2585
2018
Kostrovitsky, S., Yakolev, D.Deciphering kimberlite field structure using ilmenite composition: example of Daldyn field ( Yakutia).European Journal of Mineralogy, doi.org./ 101127/ejm/2018/0030-2783 cost $ 30.00 USRussiadeposit - Daldyn

Abstract: The spatial distribution patterns of Mg-bearing ilmenite (Ilm) composition were studied on 54 kimberlite bodies of the Daldyn field in the Yakutian kimberlite province. The representativity of the ilmenites sampled in this study is ensured by analysing ca. 100 grains from each kimberlite body. The major conclusions are as follows: (1) ilmenites from neighbouring pipes within the same linear cluster have similar average compositions and compositional fields on the MgO-Cr2O3 plots; (2) ilmenites from different clusters of pipes show different average compositions and compositional fields on the MgO-Cr2O3 plots. (3) regardless of belonging to different clusters, low-Mg Ilm across the whole Daldyn field is characterized by a direct correlation between Al2O3 and MgO; (4) significant changes of MgO content are observed in high-Mg Ilm, while Al2O3 content remains at the same level. The similarity of Ilm compositions across the kimberlite field, as shown by the MgO-Al2O3 plots, is due to a common asthenospheric source. The similar Ilm compositions in different bodies within cluster of pipes is accounted for by a single supply of magma via a lithospheric mantle channel for all pipes of the cluster. The composition of the kimberlite melts can be altered owing to the incorporation and assimilation of lithospheric mantle rocks rich in Mg and Cr. These changes of the melt cause corresponding changes in the Ilm macrocryst composition, both during and after crystallization of Ilm. Thus, the Ilm macrocryst composition follows a trend from low-Mg/low-Cr for Ilm crystallizing in the asthenosphere, to high-Mg/high-Cr at higher levels in the lithosphere. The key conclusion of this study is that Ilm can be used to decipher the structure of kimberlite fields. This can provide a reliable geological criterion for grouping an association of pipes together in clusters, which were previously identified only through subjective considerations of the spatial proximity of kimberlite bodies.
DS201809-2051
2018
Kraft, H.A., Vinnik, L., Thybo, H.Mantle transition zone beneath central eastern Greenland: possible evidence for a deep tectonosphere from receiver functions.Tectonophysics, Vol. 728, 1, pp. 34-40.Europe, Greenlandgeophysics - seismic

Abstract: We investigate the mantle of central-eastern Greenland by using recordings with data from 24 local broad-band seismograph stations. We apply P wave receiver function technique and evaluate the difference in the arrival times of seismic phases that are formed by P to SV mode conversion at the 410-km and 660-km seismic discontinuities. These boundaries mark the top and bottom of the mantle transition zone (MTZ). The difference in the arrival time of the phases from the 410-km and 660-km discontinuities is sensitive to the thickness of the MTZ and relatively insensitive to volumetric velocity anomalies above the 410-km discontinuity. Near the east coast of Greenland in the region of the Skaergaard basalt intrusions we find two regions where the differential time is reduced by more than 2 s. The 410-km discontinuity in these regions is depressed by more than 20 km. The depression may be explained by a temperature elevation of 150 °C. We hypothesize that the basaltic intrusions and the temperature anomalies at a depth of 400 km are, at least partly, effects of the passage of Greenland over the Iceland hotspot at about 55 Ma. This explanation is consistent with the concept of tectosphere and implies that the upper mantle to a depth of 400 km translates coherently with the Greenland plate.
DS201803-0459
2018
Kramm, U., Korner, T., Kittel, M., Baier, H., Sindern, S.Triassic emplacement age of Kakfeld complex, NW Namibia: implications for carbonatite magmatism and its relationship to the Tristan plume.International Journal of Earth Sciences, Vol. 106, 8, pp. 2797-2813.Africa, Namibiacarbonatite

Abstract: Rb-Sr whole-rock and mineral isotope data from nepheline syenite, tinguaite, and carbonatite samples of the Kalkfeld Complex within the Damaraland Alkaline Province, NW Namibia, indicate a date of 242 ± 6.5 Ma. This is interpreted as the age of final magmatic crystallization in the complex. The geological position of the complex and the spatially close relationship to the Lower Cretaceous Etaneno Alkaline Complex document a repeated channeling of small-scale alkaline to carbonatite melt fractions along crustal fractures that served as pathways for the mantle-derived melts. This is in line with Triassic extensional tectonic activity described for the nearby Omaruru Lineament-Waterberg Fault system. The emplacement of the Kalkfeld Complex more than 100 Ma prior to the Paraná-Etendeka event and the emplacement of the Early Cretaceous Damaraland intrusive complexes excludes a genetic relationship to the Tristan Plume. The initial ?Sr-?Nd pairs of the Kalkfeld rocks are typical of younger African carbonatites and suggest a melt source, in which EM I and HIMU represent dominant components.
DS201812-2831
2018
Krebs, M.Y., Pearson, D.G., Stachel, T., Laiginhas, F., Woodland, S., Chinn, I., Kong, J.A common parentage - Low abundance trace element data of gem diamonds reveals similar fluids to fibrous diamonds. ( silicate/sulphide)Lithos, doi.org/10.1016/ jlithos.2018.11.025 49p.Canada, Ontario, Attawapiskat, Africa, South Africadeposit - Victor, Finsch, Newlands

Abstract: Quantitative trace element data from high-purity gem diamonds from the Victor Mine, Ontario, Canada as well as near-gem diamonds from peridotite and eclogite xenoliths from the Finsch and Newlands mines, South Africa, acquired using an off-line laser ablation method show that we see the same spectrum of fluids in both high-purity gem and near-gem diamonds that was previously documented in fibrous diamonds. “Planed” and “ribbed” trace element patterns characterize not only the high-density fluid (HDF) inclusions in fibrous diamonds but also in gem diamonds. Two diamonds from two Finsch harzburgite xenoliths show trace element patterns similar to those of saline fluids, documenting the involvement of saline fluids in the precipitation of gem diamonds, further strengthening the link between the parental fluids of both gem and fibrous diamonds. Differences in trace element characteristics are evident between Victor diamonds containing silicate inclusions compared with Victor diamonds containing sulphide inclusions. The sulphide-bearing diamonds show lower levels of inter-element fractionation and more widely varying siderophile element concentrations - indicating that the silicate and sulphide-bearing diamonds likely formed by gradations of the same processes, via melt-rock reaction or from a subtly different fluid source. The shallow negative LREEN-HREEN slopes displayed by the Victor diamonds establish a signature indicative of original derivation of the diamond forming agent during major melting (~10% melt). Consequently, this signature must have been passed on to HDFs separating from such silicate melts.
DS201812-2832
2018
Krishna, C., Pande, L., Norris, R., Howell, D., Burgess, J.Bunder deposit: The Bunder diamond project, India: discovery of the Saptarshi lamproite pipes.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 191-200.Indiadeposit - Bunder
DS201801-0031
2017
Krishnamurthy, P.Carbonatites of India: part 1. Field relations, petrology, mineralogy and economic aspects.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 1-2.Indiacarbonatites

Abstract: Carbonatites of India have been reviewed by Krishnamurthy (1988; 2008) and Viladkar (2001). The present review in two parts incorporates all the developments in the field of carbonatites from India since 1963. Carbonatites of India occur in some well-defined geological environments and structural set-ups, and belong to four age groups namely, Palaeoproterozoic, Neoproterozoic, Cretaceous and Palaeocene. The Proterozoic ones are found in the three shield areas, namely southern (e.g., Hogenakal, Sevathur, Samalpatti, Pakkanadu, Khambammettu and Munnar), eastern (e.g. Beldi-Kutni and others) and north-western (e.g., Newania) India, often associated with deep faults and shear zones that may define terrain boundaries (e.g. carbonatites of Tamil Nadu between the Dharwar granite-greenstone schist belt and the southern Indian granulite zone). The Cretaceous and Palaeocene ones (e.g., Amba Dongar, Sirivasan, Sung Valley, Samchampi, Sarnu-Dandali-Kamthai and others) have been found to be related to the flood basalt provinces of Rajmahal, Sylhet (eastern and north-eastern India) and the Deccan (western India). Based on the field relations and associated rock types, the carbonatite-alkaline rock complexes can be grouped into four major types, namely: (a) syenite-dominated complexes with subordinate pyroxenites ± dunites (e.g. Sevathur, Samalpatti, Pakkanadu, and Samchampi); (b) pyroxenite/gabbro dominated ± dunite, ijolite, melteigite with minor syenite (e.g. Sung Valley, Swangre; Mer-Mundwara); (c) carbonatite dominated ringcomplexes or dykes with minor nephelinite and phonolite (e.g. Amba Dongar, Sarnu- Dandali, Kamthai); (d) Sheet-like, minor dykes and veins of carbonatites either alone or with syenites (e.g., Newania, Kunavaram, Eichuru, Munnar and others). Carbonatitekimberlite- lamproite-lamprophyre association has been clearly seen in the Precambrian Wajrakarur kimberlite field (e.g. Chelima dykes and Khaderpet cluster, Andhra Pradesh) and in the Jungal Valley (Mahakhoshal Group, Uttar Pradesh). Such an association from the Cretaceous Deccan basalt province has been shown to exist from Kutch, Gujarat and the Chhatishgargh-Odhisha areas. A wide variety of fenites, notably the syenitic types comprising sodic, sodic-potassic, and potassic variants have been noticed from several complexes, such as Amba Dongar, Newania, Sevattur, Samchampi, and Sung Valley. Fenitisation is attributed to both carbonatite and alkaline rocks as at Amba Dongar, Sevattur, Sung Valley, and Samchampi or to carbonatite alone (e.g. Newania and others).Among the carbonatite types, sovites (calcitic types) are the most common in most of the localities. Beforsitic (dolomitic) and ankeritic/sideritic types occur in complexes which manifest well developed differentiation trends that range from sovite to beforsite or to ankeritic and sideritic types, as exemplified by complexes such as Amba Dongar, Sevattur, Samalpatti, Newania and Sung Valley. Associated alkaline rocks, as mentioned above, enable the grouping of the complexes into four types. Heterogeneity in terms of structures, mineralogy, and chemistry is characteristic of many carbonatite bodies. Apart from the dominant carbonate-minerals such as calcite, dolomite, ankerite and siderite in the major carbonatite types, a variety of minor minerals have also been found in them. Early phase apatite-magnetite and silicate minerals (olivine, aegirineaugite, ritcherite, riebeckite, phlogopite and others) are well-developed in deep-seated plutonic complexes such as Sevattur, Newania, Sung Valley, Samalpatti, Pakkanadu, and Hogenekal. Some uncommon carbonatite types include those containing Fe-Nb rutile and benstonite from Samalpatti and eschynite, monazite, cerianite, celestite, and allanitebearing types from Pakkanadu, and magnesite from Newania. Minerals of economic importance, often in workable concentrations, occur in several complexes. These include: 1. REE minerals consisting of bastnaesite-(La) and daqingshanite-(Ce), bastnaesite-(Ce), ancylite and synchysite occur at Kamthai; bastnaesite and parasite from ankeritic carbonatites at Amba Dongar; bastnaesite-(Ce), ancylite-(Ce), belovite-(Ce), and britholite-(Ce) at Sung Valley. REE also occur as substituted elements in apatite in many complexes. 2. Pyrochlore - often uraniferous, occur at Sevathur, Sung Valley, Newania and Samchampi; 3. Apatite and/or phosphatic rocks (e.g. Beldih-Kutni, Samchampi, Sung, Sevathur and Newania). 4. Ti-magnetite/ hematite deposit at Samchampi. In addition a large fluorite deposit occurs at Amba Dongar and both vermiculite and apatite are mined from the fenitised-pyroxenite envelope to the north of the Sevathur carbonatite-complex. Evaluation of field association of pyroxenite-fenites in carbonatite-syenite association along with development of carbo-thermal and/or pegmatitic and skarn-rock facies in some complexes such as Samalpatti and Pakkanadu in Tamil Nadu suggests strong possibilities of Sc mineralization in some (e.g. 0.02% Sc from Pakkanadu pyroxenite) or Sc along with possible HREE associations.
DS201801-0032
2017
Krishnamurthy, P., VeenakrishnaCarbonatites of India: part 2. Geochemistry, stable and unstable isotopes and petrogenesis.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 26-28.Indiacarbonatites

Abstract: Geochemically carbonatites and genetically associated alkaline rocks represent an anomalous association of both large-ion lithophile (LIL) elements including the highfield strength (HFS) elements group such as Sr, Ba, Zr, Nb, REE, Y, Sc, Th, and U (excluding Rb) often from trace (< 0.1%) to minor/major components (> 0.1-1%) besides Ca, Mg, Fe, Mn, Si, Ti, Al, P, Na, K and CO2 in major components. Extreme heterogeneity in terms of elemental abundances is in fact a characteristic feature, often at a single outcrop level, in many carbonatite complexes (e.g. Amba Dongar, Sevathur, Sung Valley). Such apparent chemical diversity is related to the mineralogical heterogeneity that is not uncommon in many carbonatite complexes, leading to diverse mineral prefixes in carbonatite types such as apatite-sovite, apatite-magnetite soviet, riebeckite beforsite, silico-carbonatite and numerous other types (e.g. Sevathur, Samalpatti and Pakkanadu). The most diagnostic geochemical character of carbonatites stem from their geochemical features, especially the higher abundances of LIL and HFS elements, often the highest among the diverse igneous rock types as also compared to the primitive mantle or sedimentary or metamorphosed limestone/or marble or calc-silicate rocks. This has been shown from several studies of Indian carbonatites (Krishnamurthy, 1988; Schleicher et. al. 1998 and others). Radiogenic and stable isotopic ratios have been used since the mid 1990’s on Indian carbonatites which range in age from mid Proterozoic to Cretaceous in both rift related settings and associated with large igneous provinces, apparently related to deep mantleplumes, to provide constraints on the evolution of the sub-continental mantle through time. Various mantle reservoirs like HIMU (A mantle source enriched in U and Th believed to be due to recycling of ancient altered oceanic crust into the mantle), DMM (Depleted MORB mantle), EM1 (Enriched Mantle 1, generated either by recycling of lower crustal material or enrichment by mantle metasomatism) and EM2 (Enriched Mantle 2, possibly formed by recycling of continentally derived sediment, or ocean island crust into the mantle by subduction processes) with distinct isotopic signatures in the Sr- Nd-Pb isotopic space have been invoked to explain the observed variations in isotopic ratios in carbonatites worldwide (Zindler and Hart, 1984 and others). Stable isotopes of Indian carbonatites have been comprehensively reviewed by Ray and Ramesh (2009). Based on ?13C and ?18O variations, carbonatites have been grouped by them into: 1. Primary, unaltered ?18O values (5.3-7.5‰) which indicate mantle signatures that ensue from batch crystallization under plutonic conditions, as observed at Hogenakal, Sung Valley and Samchampi. ?13C values, however, appear to be more enriched (-6 to - 3.1‰) than expected for the mantle. Such a feature of enrichment probably happened sometime around ~2.4 Ga, as a sequel to metasomatism by fluids derived from recycled oceanic crust through subduction that carried enriched carbon of lithospheric mantle. 2. Secondary, altered carbonatites’ (e.g. mainly Amba Dongar and others) showing wide variations in ?13C and ?18 O values apparently results from low temperature alteration by either meteoric water or CO2-bearing aqueous fluids. The values of ??Sr (+5.3 to +7.8), ??Nd ( +1.7 to + 2.3) and initial Pb ratios (19.02, 15.67 and 39.0) for the Sung Valley complex and ?Sr (+3.0 to + 9.3) and ?Nd (+0.45 to +2.3) and initial Pb ratios ( 206Pb/204Pb= 19.12, 207Pb/204Pb= 15.66 and 208Pb/204Pb= 39.56) for the Samchampi alkaline complex are well constrained and indicate that they have originated from isotopically similar source regions that are characterised by somewhat higher Rb/Sr ratio relative to bulk earth, minor LREE depletion with respect to CHUR and time integrated enhancement of the U/Pb ratio relative to bulk earth. However, carbonatites from Sirivasan and Amba Dongar (Srivatsava and Taylor, 1996, Simonetti et al., 1995, Ray and Ramesh, 2006) indicate higher values with ?Sr = +14.6 to +21.8, ?Nd = -0.6 to -1.84 and measured 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of 19.0, 15.6 and 39.3 and indicate greater enrichment in terms of higher Rb/Sr ratios and LREE enrichment with respect to CHUR. Differences in the north eastern complexes and western complexes are also seen in the stable isotopic data wherein, data for both Sung Valley and Samchampi are constrained with average values of -3.1 ± 0.1‰ for ?13C and 6.33 ± 0.2‰ and -3.1 ± 0.2‰ for ?13C and 7.34 ± 0.7‰ for ?18O respectively whereas data from Amba Dongar and Sirivasan have ?13C of -2.6 to -8.6 ‰ and ?18O of 7.62 to 26.8 ‰. Heterogeneous mantle source has been proposed for the Hogenakal carbonatites with two groups one having high ??Nd and low ??Sr and the other having low ??Nd and high ??Sr. Carbonatites from Sevattur are more enriched with ??Sr (22 to 23), ??Nd ( -5.1 to -5.7) and ?13C ( -4.8 to -6.2‰) and ?18O (6.7 to 7.6 ‰) (Schleicher et.al., 1996, Pandit., et al. 2016). Petrogenetic models of the different carbonatite complexes are reviewed in the light of geochemical and isotopic characteristics. These include models that invoke mantle plumes of both the Kerguelen (e.g. Sung Valley and Samchampi) and Reunion (e.g. Amba Dongar, Sarnu-Dandali and others related to the Deccan volcanism) and their influence on the subcontinental lithosphere. Enriched mantle sources have been indicated for many of the Proterozoic complexes of Tamil Nadu. Evaluations of the different carbonatite complexes in terms of the three known genetic models, listed as follows, have also been elucidated. These include: (a) Direct partial melts from enriched, carbonatedperidotitic sources; (b. Immiscible carbonate and silicate magma after differentiation of the primary, carbonated peridotitic magma; (c) Extreme stage of differentiation of the ultra-alkaline, nephelinite magma. Such approaches also lead us to understand the temporal evolution of the mantle source regions of carbonatites of India since Palaeoproterozoic times. The petrogenetic link between carbonatite-kimberlite-lamproitelamprophyre in the Indian scenario is also briefly reviewed.
DS201810-2340
2018
krivovichev, Hazen, R.M. Krivovichev, V.G. Structural and chemical complexity of minerals: correlations and time evolution.European Journal of Mineralogy, Vol. 30, 2, pp. 231-236.Mantlegeochemistry

Abstract: Correlations between chemical and structural complexities of minerals were analysed using a total of 4962 datasets on the chemical compositions and 3989 datasets on the crystal structures of minerals. The amounts of structural and chemical Shannon information per atom and per unit cell or formula unit were calculated using the approach proposed by Krivovichev with no Hcorrection for the minerals with unknown H positions. Statistical analysis shows that there are strong and positive correlations (R 2 > 0.95) between the chemical and structural complexities and the number of different chemical elements in a mineral. Analysis of relations between chemical and structural complexities provides strong evidence that there is an overall trend of increasing structural complexity with the increasing chemical complexity. Following Hazen, four groups of minerals were considered that represent four eras of mineral evolution: "ur-minerals", minerals from chondritic meteorites, Hadean minerals, and minerals of the post-Hadean era. The analysis of mean chemical and structural complexities for the four groups demonstrate that both are gradually increasing in the course of mineral evolution. The increasing complexity follows an overall passive trend: more complex minerals form with the passage of geological time, yet the simpler ones are not replaced. The observed correlations between the chemical and structural complexities understood in terms of Shannon information suggest that, at a first approximation, chemical differentiation is a major force driving the increase of complexity of minerals in the course of geological time. New levels of complexity and diversifcation observed in mineral evolution are achieved through the chemical differentiation, which favours local concentrations of particular rare elements and creation of new geochemical environments.
DS201810-2341
2018
Krivovichev, V.G., Charykova, M.V., Krivovichev, S.V.The concept of mineral systems and its application to the study of mineral diversity and evolution.European Journal of Mineralogy, Vol. 30, 2, pp. 219-230.Mantlemineralogy

Abstract: The chemical diversity of minerals can be analysed in terms of the concept of mineral systems, defined by the set of chemical elements essential for the definition of a mineral species. Only species-defining elements are considered as essential. According to this approach, all minerals are classified into ten types of mineral systems with the number of essential components ranging from 1 to 10. For all the minerals known today, only 70 chemical elements act as essential species-defining constituents. The number of minerals of different chemical elements are calculated as follows (number of mineral species is given in parentheses): oxygen (4138), hydrogen (2814), silicon (1479), calcium (1182), sulfur (1064), aluminum (989), sodium (953), iron (953), copper (643), arsenic (601), phosphorus (599), and magnesium (576). The distribution of the majority of the species-defining elements among mineral systems submits to a normal distribution. Using the concept of mineral systems, different geological objects can be compared from the viewpoint of their mineral diversity as exemplified by alkaline massifs (Khibiny, Lovozero, Russia, and Mont Saint-Hilaire, Canada), evaporite deposits (Inder, Kazakhstan, and Searles Lake, USA) and fumaroles at active volcanoes (Tolbachik, Kamchatka, Russia, and Vulcano, Sicily, Italy). The concept of mineral systems can be applied to mineral evolution overall by calculating the mean number of elements for the first three stages in the evolution of minerals as proposed by R.M. Hazen and co-authors in 2008, plus a fourth period corresponding to Hazen's stages 4-10, as follows: 2.08?±?0.45 (I: ur-minerals); 2.68?±?0.13 (II: minerals of chondritic meteorites); 3.86?±?0.07 (III: Hadean minerals); 4.50?±?1.47 (IV: post-Hadean minerals).
DS201811-2586
2018
Kroner, A., Nagel, T.J., Hoffmann, J.E., Liu, X., Wong, J., Hegner, E., Xie, H., Kasper, U., Hofmann, A., Liu, D.High temperature metamorphism and crustal melting at ca. 3.2 Ga in the eastern Kaapvaal craton.Precambrian Research, Vol. 317, pp. 101-116.Africa, South Africacraton

Abstract: The question of whether high-grade metamorphism and crustal melting in the early Archaean were associated with modern-style plate tectonics is a major issue in unravelling early Earth crustal evolution, and the eastern Kaapvaal craton has featured prominently in this debate. We discuss a major ca. 3.2?Ga tectono-magmatic-metamorphic event in the Ancient Gneiss Complex (AGC) of Swaziland, a multiply deformed medium- to high-grade terrane in the eastern Kaapvaal craton consisting of 3.66-3.20?Ga granitoid gneisses and infolded greenstone remnants, metasedimentary assemblages and mafic dykes. We report on a 3.2?Ga granulite-facies assemblage in a metagabbro of the AGC of central Swaziland and relate this to a major thermo-magmatic event that not only affected the AGC but also the neighbouring Barberton granitoid-greenstone terrane. Some previous models have related the 3.2?Ga event in the eastern Kaapvaal craton to subduction processes, but we see no evidence for long, narrow belts and metamorphic facies changes reflecting lithospheric suture zones, and there is no unidirectional asymmetry in the thermal structure across the entire region from Swaziland to the southern Barberton granite-greenstone terrane as is typical of Phanerozoic and Proterozoic belts. Instead, we consider an underplating event at ca. 3.2?Ga, giving rise to melting in the lower crust and mixing with mantle-derived under- and intraplated mafic magma to generate the voluminous granitoid assemblages now observed in the AGC and the southern Barberton terrane. This is compatible with large-scale crustal reworking during a major thermo-magmatic event and the apparent lack of a mafic lower crust in the Kaapvaal craton as shown by seismic data.
DS201812-2833
2016
Kroonenberg, S.B., de Roever, E.W.F., Fraga, L.M., Faraco, T., Lafon, J-M., Cordani, U., Wong, T.E.Paleoproterzoic evolution of the Guiana Shield in Suriname: a revised model.Netherlands Journal of Geolsciences, Vol. 95, 4, pp. 491-522.South America, SurinameGuiana shield

Abstract: The Proterozoic basement of Suriname consists of a greenstone-tonalite-trondhjemite-granodiorite belt in the northeast of the country, two high-grade belts in the northwest and southwest, respectively, and a large granitoid-felsic volcanic terrain in the central part of the country, punctuated by numerous gabbroic intrusions. The basement is overlain by the subhorizontal Proterozoic Roraima sandstone formation and transected by two Proterozoic and one Jurassic dolerite dyke swarms. Late Proterozoic mylonitisation affected large parts of the basement. Almost 50 new U-Pb and Pb-Pb zircon ages and geochemical data have been obtained in Suriname, and much new data are also available from the neighbouring countries. This has led to a considerable revision of the geological evolution of the basement. The main orogenic event is the Trans-Amazonian Orogeny, resulting from southwards subduction and later collision between the Guiana Shield and the West African Craton. The first phase, between 2.18 and 2.09 Ga, shows ocean floor magmatism, volcanic arc development, sedimentation, metamorphism, anatexis and plutonism in the Marowijne Greenstone Belt and the adjacent older granites and gneisses. The second phase encompasses the evolution of the Bakhuis Granulite Belt and Coeroeni Gneiss Belt through rift-type basin formation, volcanism, sedimentation and, between 2.07 and 2.05 Ga, high-grade metamorphism. The third phase, between 1.99 and 1.95 Ga, is characterised by renewed high-grade metamorphism in the Bakhuis and Coeroeni belts along an anticlockwise cooling path, and ignimbritic volcanism and extensive and varied intrusive magmatism in the western half of the country. An alternative scenario is also discussed, implying an origin of the Coeroeni Gneiss Belt as an active continental margin, recording northwards subduction and finally collision between a magmatic arc in the south and an older northern continent. The Grenvillian collision between Laurentia and Amazonia around 1.2-1.0 Ga caused widespread mylonitisation and mica age resetting in the basement.
DS201812-2834
2018
Kruk, A.N., Sokol, A.G., Palyanov, Yu.N.Phase relations in the harzburgite-hydrous carbonate melt at 5.5-7.5 Gpa and 1200-1350 C. ( primary kimberlite)Petrology, Vol. 26, 6, pp. 575-587.Mantlemetasomatism

Abstract: Phase relations are studied experimentally in the harzburgite-hydrous carbonate melt system, the bulk composition of which represents primary kimberlite. Experiments were carried out at 5.5 and 7.5 GPa, 1200-1350°?, and \({{X}_{{{\text{C}}{{{\text{O}}}_{2}}}}}\) = 0.39-0.57, and lasted 60 hours. It is established that olivine-orthopyroxene-garnet-magnesite-melt assemblage is stable within the entire range of the studied parameters. With increase of temperature and \({{X}_{{{\text{C}}{{{\text{O}}}_{2}}}}}\) in the system, Ca# in the melt and the olivine fraction in the peridotite matrix significantly decrease. The composition of silicate phases in run products is close to those of high-temperature mantle peridotite. Analysis of obtained data suggest that magnesite at the base of subcontinental lithosphere could be derived by metasomatic alteration of peridotite by asthenospheric hydrous carbonate melts. The process is possible in the temperature range typical of heat flux of 40-45 mW/m², which corresponds to the conditions of formation of the deepest peridotite xenoliths. Crystallization of magnesite during interaction with peridotite matrix can be considered as experimentally substantiated mechanism of CO2 accumulation in subcratonic lithosphere.
DS201807-1505
2018
Kuit, I.F.Coagulation of kimberlitic ore by gypsum. MillingSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 219-232.Africa, South Africadeposit - Voorspoed

Abstract: Presentation: http://www.saimm.co.za/Conferences/Diamonds2018/P219-Kuit.pdf
DS201808-1761
2018
Kumar, M.R., Singh, A., Bhaskar Rao, Y.J., Srijayanthi, G., Satyanarayana, H.V., Sarkar, D.Vestiges of Precambrian subduction in the south Indian shield? - a seismological perspective.Tectonophysics, Vol. 740-741, pp. 27-41.Indiageophysics - seismic

Abstract: Investigation of large scale suture zones in old continental interiors offers insights into the evolution of continents. The Dharwar Craton (DC) and the Southern Granulite Terrain(SGT) of the Indian shield represent large segments of Precambrian middle to lower crust and preserve a geological record spanning from Mesoarchean to Cambrian. This study illuminates the deep structure of the Palghat-Cauvery Shear Zone System (PCSS) and the Palghat-Cauvery Suture Zone (PCSZ) that comprise crustal-scale structures related to multiple episodes of orogeny, crust formation and reworking. We utilize here 3202 high quality P-receiver functions computed using new data from a 23 station seismic network operated by us. Results show a thick (>38?km) mafic (Poisson's ratio >0.25) crust beneath the SGT. The change in crustal thickness is gradual, with a shallower Moho towards the south of PCSZ. We found little evidence for drastic changes in crustal thickness across prominent shear zones like the PCSZ and Moyar-Bhavani. Few seismic stations located along these boundaries have shown evidence for dipping reflectors around 8-20?km depth, with strikes matching well with the trends of surface geological sutures. We opine that these suture zones do not show indications of a terrane boundary. However, a drastic change in the crustal thickness is observed around the prograde metamorphic transition zone or broadly, the “Fermor line”, which separates rocks of Chanockitic (Orthopyroxene bearing granitoid) and non-Charnockitic (Orthopyroxene-free granitoid) mineral assemblage, further north beneath the DC. We suggest that thicknening of crust north of Moyar-Attur Shear Zone (MASZ) and around Fermor line is related to subduction processes operative during the Precambrian.
DS201801-0033
2018
Kumar, R., Bansal, A.R., Anand, S.P., Rao, V.K., Singh, U.K.Mapping of magnetic basement in central India from aeromagnetic dat a for scaling geology. Bastar Craton including Chhattisgarth basin.Geophysical Prospecting, Vol. 66, 1, pp. 226-239.Indiageophysics - magnetics

Abstract: The Central Indian region has a complex geology covering the Godavari Graben, the Bastar Craton (including the Chhattisgarh Basin), the Eastern Ghat Mobile Belt, the Mahanadi Graben and some part of the Deccan Trap, the northern Singhbhum Orogen and the eastern Dharwar Craton. The region is well covered by reconnaissance-scale aeromagnetic data, analysed for the estimation of basement and shallow anomalous magnetic sources depth using scaling spectral method. The shallow magnetic anomalies are found to vary from 1 to 3 km, whereas magnetic basement depth values are found to vary from 2 to 7 km. The shallowest basement depth of 2 km corresponds to the Kanker granites, a part of the Bastar Craton, whereas the deepest basement depth of 7 km is for the Godavari Basin and the southeastern part of the Eastern Ghat Mobile Belt near the Parvatipuram Bobbili fault. The estimated basement depth values correlate well with the values found from earlier geophysical studies. The earlier geophysical studies are limited to few tectonic units, whereas our estimation provides detailed magnetic basement mapping in the region. The magnetic basement and shallow depth values in the region indicate complex tectonic, heterogeneity, and intrusive bodies at different depths, which can be attributed to different thermo-tectonic processes since Precambrian.
DS201809-2052
2017
Kumar, S.P., Patel, S.C., Ravi, S., Pruseth, K.L.Mineralogy of the Banganapalle lamproite, India, and spinel zonation as a record of chemical evolution during crystallization.Geophysical Research Abstracts EGU , Vol. 19, EGU2017-12945-2 1p. AbstractIndialamproites

Abstract: The Mesoproterozoic Banganapalle Lamproite Field of southern India comprises four lamproite dykes which have intruded the Tadpatri Shale of the Cuddapah platformal sedimentary sequence. Mineralogical study of the dyke no. 551/110/4 shows that the rock has an inequigranular texture with megacrysts and macrocrysts of possibly olivine which are completely pseudomorphed by calcite and quartz due to pervasive hydrothermal and/or duteric alteration. Phenocrysts and microphenocrysts of phlogopite are highly chloritised with occasional preservation of relicts. The groundmass is dominated by calcite with subordinate amounts of phlogopite (completely chloritised), diopside, apatite, rutile and spinel. Other minor phases in the groundmass include titanite, allanite, monazite, zircon, barite, carboceranite, pyrite, pyrrhotite, chalcopyrite, galena, sphalerite, heazlewoodite, and pentlandite. Spinel occurs in three textural types: (i) xenocrysts showing homogeneous composition; (ii) phenocrysts and microphenocrysts with continuous compositional zoning from the core to the rim; and (iii) groundmass crystals with distinct growth zones marked by discontinuous compositional zoning from the core to the rim. Four growth zones (zones I-IV) of spinel are recognized. Phenocrysts and microphenocrysts are designated as zone I spinels which have 55.0-65.7 wt% Cr2O3, 2.7-7.2 wt% Al2O3, <0.4 wt% TiO2, and record a decrease in Al/(Al+Cr) from the core to the rim. Zone II spinels either occur as overgrowth rims on xenocrystal and zone I spinels or form cores to zone III rims in discrete grains, and have higher TiO2 (1.2-3.6 wt%), lower Al2O3 (1.2-2.9 wt%) and similar Cr2O3 (55.0-63.8 wt%) contents compared to zone I spinels. Zone III spinels either occur as overgrowth rims on xenocrystal and zone II spinels or form cores to zone IV rims in discrete grains, and contain higher Al2O3 (5.7-10.2 wt%), lower Cr2O3 (45.9-56.0 wt%) and similar TiO2 (1.6-3.4 wt%) compared to zone II spinels. Overgrowth rims of zone II and zone III spinels locally exhibit oscillatory zoning with characteristics of diffusion controlled magmatic growth. Zone IV spinels are marked by low Cr2O3 (17.4-25.5 wt%) and Al2O3 (1.6-2.0 wt%), and high Fe2O3 (28.8-35.4 wt%) and TiO2 (4.0-7.1 wt%) contents. Xenocrystal spinels are distinguished from magmatic spinels by high Al2O3 content (11.3-22.4 wt%) and uniform composition of individual grains. The wide range of composition and the zonation pattern of magmatic spinels suggest that the mineral was on the liquidus through most part of the lamproite crystallisation. The abrupt changes in composition between the zones indicate hiatus in crystallisation and/or sudden changes in the environmental conditions, resulting from crystallisation of associated minerals and periodic emplacement of certain elements into the magma. Diopside occurs in groundmass segregations and has low contents of Na2O (<0.77 wt%), Al2O3 (<1.2 wt%), Cr2O3 (<0.25 wt%) and TiO2 (<1.7 wt%), although higher values of TiO2 (up to 3.0 wt%) are locally encountered. Phenocrystal phlogopite has Mg/(Mg+Fe2+) ratios in the range of 0.76-0.83, and a Cr-rich composition (3.2-3.6 wt% Cr2O3) that indicates its crystallisation at mantle pressures. Co-precipitation of this phlogopite with phencocrystal spinel can explain the observed Al-Cr zoning in the latter.
DS201808-1762
2018
Kusham, A., Pratap, B., Naick, P., Naganjaneyulu, K.Lithospheric architecture in the Archean Dharwar craton, India: a magnetotelluric model.Journal of Asian Earth Sciences, Vol. 183, pp. 43-53.Indiacraton

Abstract: oriented, 280?km long profile (from Yellapura to Sindhanur) with 22 magnetotelluric stations. Regional strike directions, estimated were ?5° and 13° for the crust and the lithospheric mantle respectively. Our results indicate in western Dharwar craton, presence of low resistivity zones in the crust besides two significant upper mantle conductive features within the highly resistive Archaean lithosphere. We analyze the available geophysical data that include heat flow, seismic tomography and magnetotellurics (MT) from the Dharwar craton. Our inference supports to the existence of a thick lithosphere. A thickness of more than 200?km is estimated for the lithosphere beneath the Dharwar craton by our magnetotelluric model. The study has brought out the presence of lithospheric upper mantle conductive features in the depth range of 100-200?km bounded to the west part of the magnetotelluric profile. Significant variations in conductivity are seen on either side of the Chitradurga shear zone. The conductive feature in the depth range 120-150?km is related with kimberlite melts and the conductive nature in the depth range 160-200?km is explained by refertilization process, as craton passed over the Marion (ca. 90?Ma) hotspot.
DS201812-2835
2018
Kuwahara, H., Nomura, R., Nakada, R., Irifune, T.Simultaneous determination of melting phase relations of mantle peridotite and mid-ocean ridge basalt at the uppermost lower mantle conditions.Physics of the Earth and Planetary Interiors, Vol. 284, pp. 36-50.Mantleperidotite

Abstract: Interpretation of melting phase relationships of mantle peridotite and subducted basaltic crust is important for understanding chemical heterogeneity in the Earth’s interior. Although numerous studies have conducted melting experiments on peridotite and mid-ocean ridge basalt (MORB), and suggested that the solidus temperature of MORB is lower than that of peridotite at whole mantle pressure conditions, both solidus temperatures overlap within their uncertainties. In this study, we conducted simultaneous experiments on KLB-1 peridotite and normal MORB (N-MORB) at pressures from 25?GPa to 27?GPa and temperatures from 2398?K to 2673?K, to compare the solidus temperatures and their melting phase relations. The experimental results show that the solidus temperature of the N-MORB is nearly identical to the KLB-1 peridotite at 25?GPa but lower at 27?GPa. In addition, we found that the crossover of melt fractions between KLB-1 peridotite and N-MORB occurs at 25-27?GPa. These changes are likely to be attributed to the majorite-bridgmanite transition of MORB. This indicates that the dominant melting component may change depending on the location of the uppermost lower mantle. Our calculation result on the density of partial melts along the mantle geotherm suggests that partial melts of KLB-1 peridotite are gravitationally stable around the top of the transition zone, whereas partial melts of N-MORB are gravitationally stable even at the top of lower mantle. These results suggest that the distribution of partial melts may be different between KLB-1 peridotite and N-MORB in the deep Earth. Our results may be useful for understanding the fate of partial melts of peridotitic mantle and recycled basaltic crust.
DS201812-2836
2018
Lafranchi, R.A.A view of the potential of diamondiferous mineralization in Bahia using multi-source data.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Bahiatechnology
DS201812-2837
2018
Lai, M.Y.Spectroscopic analysis of yellow diamonds. ( Chidliak, Ekati, Qilalugaq)Thesis, Msc. University of Alberta, 142p. Pdf availableCanada, Nunavut, Northwest Territoriesdeposit - Chidliak, Ekati, Qilalugaq
DS201811-2587
2018
Lai, X., Zhu, F., Zhang, D., Hu, Y., Finkelstein, G.J., Dera, P., Chen, B.The high pressure anisotropic thermelestic properties of a potential inner core carbon bearing phase, Fe-C3, by single crystal X-ray diffraction.American Mineralogist, Vol. 103, pp. 1568-1574.Mantlecarbon

Abstract: Carbon has been suggested as one of the light elements existing in the Earth's core. Under core conditions, iron carbide Fe7C3 is likely the first phase to solidify from a Fe-C melt and has thus been considered a potential component of the inner core. The crystal structure of Fe7C3, however, is still under debate, and its thermoelastic properties are not well constrained at high pressures. In this study, we performed synchrotron-based single-crystal X-ray diffraction experiment using an externally heated diamond-anvil cell to determine the crystal structure and thermoelastic properties of Fe7C3 up to 80 GPa and 800 K. Our diffraction data indicate that Fe7C3 adopts an orthorhombic structure under experimentally investigated conditions. The pressure-volume-temperature data for Fe7C3 were fitted by the high-temperature Birch-Murnaghan equation of state, yielding ambient-pressure unit-cell volume V0 = 745.2(2) Å3, bulk modulus K0 = 167(4) GPa, its first pressure derivative K0? = 5.0(2), dK/dT = -0.02(1) GPa/K, and thermal expansion relation ?T = 4.7(9) × 10-5 + 3(5) × 10-8 × (T - 300) K-1. We also observed anisotropic elastic responses to changes in pressure and temperature along the different crystallographic directions. Fe7C3 has strong anisotropic compressibilities with the linear moduli Ma > Mc > Mb from zero pressure to core pressures at 300 K, rendering the b axis the most compressible upon compression. The thermal expansion of c3 is approximately four times larger than that of a3 and b3 at 600 and 700 K, implying that the high temperature may significantly influence the elastic anisotropy of Fe7C3. Therefore, the effect of high temperature needs to be considered when using Fe7C3 to explain the anisotropy of the Earth's inner core.
DS201809-2053
2018
Lassiter, J.C.On the equilibration timescales of isolated trace phases in mantle peridotites: implications for the interpretation of grain scale isotope heterogeneity in peridotitic sulfides.Earth and Planetary Science Letters, Vol. 498, pp. 427-435.Mantleperidotites

Abstract: Geochemical studies of mid-ocean-ridge basalts (MORB) and mantle peridotites (e.g., abyssal peridotites) provide independent constraints on the composition and evolution of the convecting mantle. Recent studies have revealed systematic differences in the radiogenic isotope compositions of MORB and abyssal peridotites that call into question the complementary nature of these two windows to the upper mantle. The origin of these differences is fundamental to our understanding of MORB petrogenesis and the composition and depletion history of the upper mantle. The use of isotope variations in basalts to probe the composition and evolution of the mantle is predicated on the assumption of local (i.e., grain-scale) isotopic equilibrium during mantle melting. However, several studies have reported Os- and Pb-isotope disequilibrium in distinct populations of peridotite-derived sulfides, with sulfides included within silicate grains typically possessing more “depleted” isotopic compositions than interstitial sulfides. In principle, grain-scale isotopic heterogeneity could reflect variable radiogenic ingrowth in ancient sulfides with variable parent/daughter ratios, or partial re-equilibration of low-Re/Os and U/Pb sulfides with more radiogenic silicate phases along grain boundaries during mantle melting. This would require that sulfides fail to maintain isotopic equilibrium with neighboring phases over geologically long (? Ga) time scales. The preservation of Os-isotope disequilibrium in peridotites has been ascribed in several studies to the armoring effect of low-[Os] silicates, which limits diffusive exchange between isolated Os-rich sulfides. This raises the prospect that peridotite-derived melts may not inherit the Os- (or Pb-) isotope composition of their source, which could account for the recently documented systematic differences in the Os- and Pb-isotope compositions of MORB and mantle peridotites. Although the preservation of isotopic heterogeneity in mantle sulfides is commonly ascribed to the above “armoring effect”, the diffusive equilibration timescale of spatially separated sulfides in mantle peridotites has not previously been rigorously estimated. This study examines the parameters that control this equilibration timescale (average sulfide size and spacing, Os and Pb diffusivity in armoring silicate minerals, and element partitioning between silicate and sulfide phases). Equilibration timescale estimates using available constraints on these parameters reveal that most mantle sulfides are expected to isotopically re-equilibrate with neighboring sulfides in less than a few 10 s of Myr at convecting mantle temperatures. Maintenance of isotopic disequilibrium over the ? Ga timescales suggested by observed intra-sample Os- and Pb-isotope heterogeneity requires very large sulfides (>100 ?m) separated by several mm or diffusion rates (D <10?18 m2/s), slower than for most elements in olivine. Combined with the observation of intra-sample major element heterogeneity in sulfide Ni and Fe abundances (which should equilibrate quickly in the convecting mantle), these results suggest that the observed isotopic disequilibrium is unlikely to be an ancient feature in mantle peridotites. Instead, recent sulfide metasomatism linked to interaction with melts derived from isotopically enriched eclogite or pyroxenite (or fertile and/or metasomatized peridotite) components is a more likely explanation for observed intra-sample isotopic heterogeneity in peridotites. This interpretation is also consistent with systematic differences between the Nd- and Hf-isotope compositions of MORB and abyssal peridotites. These results further strengthen the proposal that MORB do not accurately reflect the average isotopic composition of the convecting upper mantle, and that upper mantle peridotite is, on average, significantly more depleted and refractory than suggested by MORB-based estimates. The effects of melt generation in a heterogeneous marble-cake mantle need to be explicitly considered when using basalt compositions to constrain mantle composition and evolution.
DS201805-0956
2018
Laurs, B.Diamond mining at Namdeb's southern coastal mines, Namibia. Site visitJournal of Gemmology, Vol. 36, 1, pp. 16-18.Africa, Namibiadeposit - namdeb
DS201810-2342
2018
Lawley, C., Kjarsgaard, B., Jackson, S., Yang, Z., Petts, D., Roots, E.Trace metal and isotopic depth profiles through the Abitibi. Kirkland Lake kimberlite field.Lithos, Vol. 314-315, pp. 520-533.Canada, Ontariodeposit - Kirkland Lake

Abstract: Geophysical imaging of trans-lithospheric structures provide a spatial link between ore deposits in the crust and the underlying cratonic mantle. However, the deep lithosphere's role in ore deposit genesis remains poorly understood because remotely acquired datasets do not provide any direct constraints on the behaviour of ore elements within these mantle-roots. The abundance and behaviour of ore elements governs the metallic endowment of the cratonic mantle and the economic potential of mantle-derived magmas. Herein we present in situ electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) geochemical datasets for clinopyroxene and olivine mantle xenocrysts from the Jurassic Kirkland Lake kimberlite field, Abitibi greenstone belt, Canada. We specifically focus on unconventional trace elements, including ore elements with chalcophile and/or siderophile affinities (Ag-As-Au-Bi-Cu-Mo-Pb-Pt-Pd-Sb-Se-Sn-Te-W-Zn). Robust principal component analysis suggests that low-T, large-ion lithophile element alteration (Ba-Sr), which likely occurred during kimberlite emplacement, represents the largest source of variance for the xenocryst dataset. PT-dependent element partitioning during sub-solidus equilibration represents the second most important control on olivine and clinopyroxene chemistry. We demonstrate that least-altered, high-PT mantle silicates are, in fact, a significant mineral host for a range of ore elements (Cu-Zn ± Ag ± As ± Se ± Sn ± Mo) within equilibrated, garnet peridotite at depth (70-190 km). Statistical analysis of the raw, individual mass sweeps for each LA-ICP-MS signal suggest that the most abundant ore elements (Cu-Zn) occur predominantly as PT-dependent substitution reactions with the dominant mineral-forming elements, rather than as inclusions. A subset of high-PT olivine (160-180 km) yields Fe-Ni-S-poor and Na (Au ± Pt ± Pd)-rich compositions, which may reflect metasomatism, sulphide segregation and trapping of precious metal-bearing fluids at the base of the lithosphere. These anomalous mantle fragments possibly represent the first, direct sampling of precious metal-modified mantle peridotite beneath the Abitibi. Mid-PT olivine xenocrysts (70-120 km), which yield Mg-rich and high field-strength element-poor compositions, document a highly melt-depleted segment of mantle peridotite coincident with and below a shallow-dipping, low-seismic-velocity anomaly and conductive feature of the Kirkland Lake mid-lithosphere at 70-100 km. We speculate that the trace element signature of mid-PT xenocrysts documents the re-distribution of high-charge and incompatible elements from refractory garnet peridotite to phlogopite- and/or amphibole-bearing peridotite with conductive metasomatic up-flow zones. The rapid, sub-solidus diffusion of elements at high-T suggest that these processes likely occurred during, and/or immediately preceding, kimberlite volcanism. New in situ Pb isotope analyses of clinopyroxene xenocrysts sampled from metasomatized, low-Al garnet peridotite, however, also document ancient metasomatic events that likely pre-date Jurassic kimberlitic volcanism by at least one billion years.
DS201809-2054
2018
Lawley, C.J.M., Kjarsgaard, B.A., Jackson, S.E., Yang, Z., Petts, D.C.Olivine and clinopyroxene mantle xenocryst geochemistry from the Kirkland Lake kimberlite field, Ontario.Geological Survey of Canada, Open File 8376, 9p.Canada, Ontariogeochemistry
DS201809-2055
2018
Leal, R.E., Lafon, J.M., da Ros Costa, L.T., Dantas, E.L.Orosirian magmatic episodes in the erepercuru-trombetas domain ( southeastern Guyana shield: implications for the crustal evolution of the Amazonian craton.South American Earth Sciences, Vol. 85, pp. 278-297.South America, Guyanacraton - Amazonian
DS201807-1506
2018
Lebedev, A., Rodel, A.Application of dynamic simulation for the Gahcho Kue project. GPSS, LIMNSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 259-284.Canada, Northwest Territoriesdeposit - Gahcho Kue
DS201812-2838
2018
Lee, C., Worsley-Brown, L.Twenty years at the Ekati diamond mine: corporate social responsibility in action. CSR2018 Yellowknife Geoscience Forum , p. 47-48. abstractCanada, Northwest Territoriesdeposit - Ekati

Abstract: The Ekati Diamond Mine in the Northwest Territories is owned and operated by Dominion Diamond Mines, the largest Canadian independent diamond producer. The Ekati mine was the first diamond mine in Canada, and started production in October 1998. In 2018 the operation is celebrating its twenty year anniversary. In the presentation, we will look back on some of the milestones and achievements of the last two decades. We will also discuss the commitment of the company to make a positive difference in the North through Corporate Social Responsibility initiatives, including support for education, training, community development, business opportunities and respect for the environment. Some examples include: Community: Whether mining in northern Canada or sorting diamonds in India, we firmly believe that we can - and should - contribute to the social and economic well-being of the communities near our operations. Dominion's Indigenous partners and business operations are important stakeholders and we respect and value their rights, Traditional Knowledge (TK), and cultural heritage. Hiring, Training and Development: Dominion Diamond Mines is committed to ensuring that the Ekati mine is a welcoming workplace for all employees and that we remain an employer of choice, particularly among northerners and northern Indigenous communities. The company has a number of initiatives and policies to encourage northerners, representatives from Indigenous groups, and women to enter the mining industry. Environment: Throughout the mining process, Dominion Diamond keeps the land and water of the Ekati mine clean and safe for people, plants, and animals. We understand the importance of the Arctic tundra environment and we are committed to mining in the safest, most environmentally responsible way.
DS201811-2588
2018
Lehtonen, M.Gemstones of Finland. Diamond bearing kimberlites pp. 175-193.Geological Survey of Finland, 344p. Europe, Finlandgemology
DS201804-0715
2018
Lemiere, B.A review of pXRF ( field portable X-ray fluoresence) applications for applied geochemisty.Journal of Geochemical Exploration, Vol. 188, pp. 350-362.Technologyflourescence
DS201810-2343
2018
Lenardic, A.The diversity of tectonic modes and thoughts about transitions between them. Philosphical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences, Vol. 376 doi:10.1098/rsta.2017.0416Mantletectonics

Abstract: Plate tectonics is a particular mode of tectonic activity that characterizes the present-day Earth. It is directly linked to not only tectonic deformation but also magmatic/volcanic activity and all aspects of the rock cycle. Other terrestrial planets in our Solar System do not operate in a plate tectonic mode but do have volcanic constructs and signs of tectonic deformation. This indicates the existence of tectonic modes different from plate tectonics. This article discusses the defining features of plate tectonics and reviews the range of tectonic modes that have been proposed for terrestrial planets to date. A categorization of tectonic modes relates to the issue of when plate tectonics initiated on Earth as it provides insights into possible pre-plate tectonic behaviour. The final focus of this contribution relates to transitions between tectonic modes. Different transition scenarios are discussed. One follows classic ideas of regime transitions in which boundaries between tectonic modes are determined by the physical and chemical properties of a planet. The other considers the potential that variations in temporal evolution can introduce contingencies that have a significant effect on tectonic transitions. The latter scenario allows for the existence of multiple stable tectonic modes under the same physical/chemical conditions. The different transition potentials imply different interpretations regarding the type of variable that the tectonic mode of a planet represents. Under the classic regime transition view, the tectonic mode of a planet is a state variable (akin to temperature). Under the multiple stable modes view, the tectonic mode of a planet is a process variable. That is, something that flows through the system (akin to heat). The different implications that follow are discussed as they relate to the questions of when did plate tectonics initiate on Earth and why does Earth have plate tectonics.
DS201811-2589
2017
Lenardic, A.The diversity of tectonic modes and thoughts about transitions between them.Philosophical Transactions Royal Society A, Vol. A376: doi://dx.doi.org/10.1098/rsta.2017.0416 23p.Mantleplate tectonics

Abstract: Plate tectonics is a particular mode of tectonic activity that characterizes the present-day Earth. It is directly linked to not only tectonic deformation but also magmatic/volcanic activity and all aspects of the rock cycle. Other terrestrial planets in our Solar System do not operate in a plate tectonic mode but do have volcanic constructs and signs of tectonic deformation. This indicates the existence of tectonic modes different from plate tectonics. This article discusses the defining features of plate tectonics and reviews the range of tectonic modes that have been proposed for terrestrial planets to date. A categorization of tectonic modes relates to the issue of when plate tectonics initiated on Earth as it provides insights into possible pre-plate tectonic behaviour. The final focus of this contribution relates to transitions between tectonic modes. Different transition scenarios are discussed. One follows classic ideas of regime transitions in which boundaries between tectonic modes are determined by the physical and chemical properties of a planet. The other considers the potential that variations in temporal evolution can introduce contingencies that have a significant effect on tectonic transitions. The latter scenario allows for the existence of multiple stable tectonic modes under the same physical/chemical conditions. The different transition potentials imply different interpretations regarding the type of variable that the tectonic mode of a planet represents. Under the classic regime transition view, the tectonic mode of a planet is a state variable (akin to temperature). Under the multiple stable modes view, the tectonic mode of a planet is a process variable. That is, something that flows through the system (akin to heat). The different implications that follow are discussed as they relate to the questions of when did plate tectonics initiate on Earth and why does Earth have plate tectonics.This article is part of a discussion meeting issue 'Earth dynamics and the development of plate tectonics'.
DS201812-2839
2018
Lenardic, A.The diversity of tectonic modes and thoughts about transitions between them.Philosphical Transactions of the Royal Society, Aug. 9, http://dx.doi.org/10.1098/rsta.2017.0416 23p.Mantleplate tectonics
DS201805-0957
2018
Lepine, I., Farrow, D.3D geological modelling of the Renard 2 kimberlite pipe, Quebec, Canada: from exploration to extraction.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0567-y 9p.Canada, Quebecdeposit - Renard

Abstract: The Renard 2 kimberlite pipe is one of nine diamondiferous kimberlite pipes that form a cluster in the south-eastern portion of the Superior Province, Québec, Canada and is presently being extracted at the Renard Mine. It is interpreted as a diatreme-zone kimberlite consisting of two Kimberley-type pyroclastic units and related country rock breccias, all cross-cut by coherent kimberlite dykes and irregular intrusives. Renard 2 has been the subject of numerous diamond drilling campaigns since its discovery in 2001. The first two geological models modelled kimberlite and country rock breccia units separately. A change in modelling philosophy in 2009, which incorporated the emplacement envelope and history, modelled the entire intrusive event and projected the pipe shape to depth allowing for more targeted deep drilling where kimberlite had not yet been discovered. This targeted 2009 drilling resulted in a?>?400% increase in the volume of the Indicated Resource. Modelling only the kimberlite units resulted in a significant underestimation of the pipe shape. Current open pit and underground mapping of the pipe shape corresponds well to the final 2015 geological model and contact changes observed are within the expected level of confidence for an Indicated Resource. This study demonstrates that a sound understanding of the geological emplacement is key to developing a reliable 3D geological and resource model that can be used for targeted delineation drilling, feasibility studies and during the initial stages of mining.
DS201802-0248
2017
Letnikov, F.A., Los, V.L., Narseev, V.F.Technical diamond deposit Kumdy-Kul ( northern Kazakhstan). ***IN RUSStarosin, V.I. (ed) Problems of the mineralogy, economic geology and mineral resources. MAKS Press, Moscow *** IN RUS, pp. 197-206.Russia, Kazakhstandeposit - Kumdy-Kul
DS201803-0460
2017
Letsch, D.A pioneer of Precambrian geology: Boris Choubert's fit of the continents across the Atlantic ( 1935) and his insights into the Proterozoic tectonic structure of the west African craton and adjacent areas.Precambrian Research, Vol. 294, pp. 230-243.Gondwanadiamonds

Abstract: Plate tectonics revolutionized the Earth Sciences during the 1960s and led to a fundamentally new view of tectonic processes inside mountain belts. Application of the new theory to pre-Permian and especially Precambrian orogenic belts developed somewhat reluctantly during the 1970s and 1980s. The present article presents and discusses the ideas of Boris Choubert (1906-1983), a French colonial geologist of Russian origin, which he first developed in 1935. He tried to test Wegener’s theory of continental displacement (a forerunner of plate tectonics) by applying it to Paleozoic and Precambrian orogenic belts around the Atlantic (a topic altogether neglected by Wegener). To achieve this, he produced a fit of the continents across the Atlantic which is almost identical to the famous 1965 fit of Bullard et al. Starting from this Paleozoic continental configuration, he presented an inter-continental synthesis of Precambrian geology and discussed problems from a wide array of topics, ranging from regional tectonics of the West African Craton, questionable Precambrian fossils, tillites (and cap carbonates) to the supposed origin of detrital diamonds in Gabon and Brazil. He also provided probably the first Precambrian plate reconstruction avant la lettre. After his 1935 paper, Choubert worked for decades in Africa and South America and had opportunity to test and refine his synthesis. His example is a call, addressed to present-day geologists working on Precambrian geology in Africa and other regions, to consult the old colonial literature which contains a wealth of factual information and theoretical inspiration which is still of interest today.
DS201807-1507
2018
Levandowski, W., Herrmann, R.B., Briggs, R., Boyd, O., Gold, R.An updated stress map of the continental United States reveals heterogeneous intraplate stress. TectonicsNature Geoscience, Vol. 11, 6, pp. 433-437.United Statesgeodynamics

Abstract: Knowledge of the state of stress in Earth’s crust is key to understanding the forces and processes responsible for earthquakes. Historically, low rates of natural seismicity in the central and eastern United States have complicated efforts to understand intraplate stress, but recent improvements in seismic networks and the spread of human-induced seismicity have greatly improved data coverage. Here, we compile a nationwide stress map based on formal inversions of focal mechanisms that challenges the idea that deformation in continental interiors is driven primarily by broad, uniform stress fields derived from distant plate boundaries. Despite plate-boundary compression, extension dominates roughly half of the continent, and second-order forces related to lithospheric structure appear to control extension directions. We also show that the states of stress in several active eastern United States seismic zones differ significantly from those of surrounding areas and that these anomalies cannot be explained by transient processes, suggesting that earthquakes are focused by persistent, locally derived sources of stress. Such spatially variable intraplate stress appears to justify the current, spatially variable estimates of seismic hazard. Future work to quantify sources of stress, stressing-rate magnitudes and their relationship with strain and earthquake rates could allow prospective mapping of intraplate hazard.
DS201802-0249
2018
Li, H-Y., Chen, R-X., Zheng, Y-F., Hu, Z.Water in garnet pyroxenite from the Sulu orogen: implications for crust mantle interaction in continental subduction zones.Chemical Geology, Vol. 478, pp. 18-38.Chinasubduction

Abstract: Mineral water contents, together with the major and trace element compositions of minerals and whole-rock, were determined for garnet pyroxenites enclosed by ultrahigh-pressure (UHP) metamorphic gneiss at Hujialin in the Sulu orogen. The garnet pyroxenites have low SiO2 contents of 40.25 to 46.68 wt% and MgO contents of 10.99 to 14.79 wt%. They are characterized by enrichment in LREE and LILE (Ba, Sr, Pb) but depletion in HFSE (Nb, Zr) and HREE. They were generated in the Triassic by metasomatic reaction of the mantle wedge peridotite with hydrous felsic melts derived from partial melting of the deeply subducted continental crust. Measured water contents vary from 523 to 1213 ppm for clinopyroxene, and 55 to 1476 ppm for garnet. These mineral water contents are not only correlated with mineral major and trace element abundances but also relatively homogenous within single mineral grains. Such features preclude significant disturbance of the mineral water contents during pyroxenite exhumation from the mantle depth to the surface and thus indicate preservation of the primary water contents for the UHP metasomatites. The garnet pyroxenites are estimated to have bulk water contents of 424-660 ppm, which are higher than those for the MORB source, similar to or higher than those for the OIB sources and close to the lower limit for the arc magma source. The relationships between contents of mineral water and some elements suggest that the high water contents of garnet pyroxenites are primarily determined by the abundance of water-rich clinopyroxene. Garnet also has the high water contents, suggesting its importance in hosting water at mantle depths. Calculated whole-rock H2O/Ce ratios are 63-145, higher than those for Hawaiian garnet pyroxenites and SWIR abyssal pyroxenites. These observations suggest that metasomatic pyroxene-rich lithologies have the capacity to contribute high H2O concentrations and variable H2O/Ce ratios to the mantle. This lends support to the interpretation that the source of some intraplate basalts may be a heterogeneous mixture of peridotite and pyroxenite. On the other hand, the high water contents of garnet pyroxenites suggest that the presence of ultramafic metasomatites in the mantle wedge would enhance its water storage and thus reduce the water transport into deeper mantle by subduction.
DS201810-2344
2018
Li, M., McNamara, A.K.The influence of deep mantle compositional heterogeneity on Earth's thermal evolution.Earth and Planetary Science Letters, Vol. 500, pp. 86-96.Mantlegeothermometry

Abstract: The seismically-observed large low shear velocity provinces in the Earth's lowermost mantle have been hypothesized to be caused by thermochemical piles of compositionally distinct, more-primitive material which may be remnants of Earth's early differentiation. However, one critical question is how the Earth's thermal evolution is affected by the long-term presence of the large-scale compositional heterogeneity in the lowermost mantle. Here, we perform geodynamical calculations to investigate the time evolution of the morphology of large-scale compositional heterogeneity and its influence on the Earth's long-term thermal evolution. Our results show that a global layer of intrinsically dense material in the lowermost mantle significantly suppresses the CMB heat flux, which leads to faster cooling of the background mantle relative to an isochemical mantle. As the background mantle cools, the intrinsically dense material is gradually pushed into isolated thermochemical piles by cold downwellings. The size of the piles also decreases with time due to entraining of pile material into the background mantle. The morphologic change of the accumulations of intrinsic dense material eventually causes a gradual increase of CMB heat flux, which significantly reduces the cooling rate of Earth's mantle.
DS201805-0958
2018
Li, M., Zhong, S., Olson, P.Linking lowermost mantle structure, core-mantle boundary heat flux and mantle plume formation.Physics of the Earth and Planetary Interiors, Vol. 277, 1, pp. 10-29.MantleGeothermometry

Abstract: The dynamics of Earth’s lowermost mantle exert significant control on the formation of mantle plumes and the core-mantle boundary (CMB) heat flux. However, it is not clear if and how the variation of CMB heat flux and mantle plume activity are related. Here, we perform geodynamic model experiments that show how temporal variations in CMB heat flux and pulses of mantle plumes are related to morphologic changes of the thermochemical piles of large-scale compositional heterogeneities in Earth’s lowermost mantle, represented by the large low shear velocity provinces (LLSVPs). We find good correlation between the morphologic changes of the thermochemical piles and the time variation of CMB heat flux. The morphology of the thermochemical piles is significantly altered during the initiation and ascent of strong mantle plumes, and the changes in pile morphology cause variations in the local and the total CMB heat flux. Our modeling results indicate that plume-induced episodic variations of CMB heat flux link geomagnetic superchrons to pulses of surface volcanism, although the relative timing of these two phenomena remains problematic. We also find that the density distribution in thermochemical piles is heterogeneous, and that the piles are denser on average than the surrounding mantle when both thermal and chemical effects are included.
DS201803-0461
2017
Li, R., Ding, M., Shi, T.Finite element design for the HPHT synthesis of diamond.Journal of Crystal Growth, 11p. Chinacubic diamonds

Abstract: The finite element method is used to simulate the steady-state temperature field in diamond synthesis cell. The 2D and 3D models of the China-type cubic press with large deformation of the synthesis cell was established successfully, which has been verified by situ measurements of synthesis cell. The assembly design, component design and process design for the HPHT synthesis of diamond based on the finite element simulation were presented one by one. The temperature field in a high-pressure synthetic cavity for diamond production is optimized by adjusting the cavity assembly. A series of analysis about the influence of the pressure media parameters on the temperature field are examined through adjusting the model parameters. Furthermore, the formation mechanism of wasteland was studied in detail. It indicates that the wasteland is inevitably exists in the synthesis sample, the distribution of growth region of the diamond with hex-octahedral is move to the center of the synthesis sample from near the heater as the power increasing, and the growth conditions of high quality diamond is locating at the center of the synthesis sample. These works can offer suggestion and advice to the development and optimization of a diamond production process.
DS201812-2840
2018
Li, Y., Zhang, J., Mustofa, K.M.G., Wang, Y., Yu, S., Cai, Z., Li, P., Zhou, G., Fu, C., Mao, X.Petrogenesis of carbonatites in the Luliangshan region, North Qaidam, northern Tibet, China: evidence for recycling of sedimentary carbonate and mantle metasomatism within a subduction zone.Lithos, Vol. 322, pp. 148-165.China, Tibetcarbonatite

Abstract: Carbonatitic magmatism in subduction zones provides extremely valuable information on the cycling, behavior and storage of deep carbon within the Earth. It may also shed light on insights into crust-mantle interaction and mantle metasomatism within subduction zones. Origin of carbonatite has long been debated: all hypotheses need to reflect the different mineral assemblages and geochemical compositions of carbonatites and their diverse tectonic settings. Here we present a petrological, geochronological, geochemical and isotopic study of carbonatite bodies associated with orogenic peridotites, which occur as stocks or dykes with widths of tens to hundreds of meters in the Luliangshan region, North Qaidam, northern Tibet, China. On the basis of modal olivine (Ol) content, the studied samples were subdivided into two groups: Ol-poor carbonatite and Ol-rich carbonatite. Zircon grains from the Ol-poor carbonatite show detrital features, and yield a wide age spectrum between 400?Ma and 1000?Ma with a pronounced peak at ca. 410-430?Ma. By contrast, oscillatory zoned zircons and inherited cores show two relatively small Neoproterozoic age peaks at ca. 920 and 830?Ma. Zircon grains from the Ol-rich carbonatite sample are also distributed in a wide spectrum between 400 and 1000?Ma, with a pronounced peak at ca. 440?Ma and a slightly inferior peak at ca. 410?Ma. The oscillatory zoned zircons and inherited cores exhibit a smaller Neoproterozoic age peak at ca. 740?Ma. The pronounced peaks ranging from 430 to 410?Ma are consistent with the deep subduction and mantle metasomatic events recorded in associated ultramafic rocks. Both groups of carbonatites are characterized by enrichment of light rare earth elements (LREEs) with high (La/Yb)N values and pronounced negative Eu anomalies. They show high 87Sr/86Sr values (0.708156-0.709004), low 143Nd/144Nd values (0.511932-0.512013) and high ?18OV-SMOW values (+17.9 to +21.3‰). This geochemical and isotopic evidence suggests that these carbonatites were derived from remobilized sedimentary carbonate rocks. We propose that the primary carbonatite magma was formed by partial melting of sedimentary carbonates with mantle contributions. Sedimentary carbonates were subducted into the shallow upper mantle where they melted and formed diapirs that moved upwards through the hot mantle wedge. The case presented provides a rare example of carbonatite originating from sedimentary carbonates with mantle contributions and relevant information on the mantle metasomatism within a subduction zone.
DS201808-1763
2018
Li, Z., Fedortchouk, Y., Fulop, A., Chinn, I.L., Forbes, N.Positively oriented trigons - a unique resorption feature of diamonds from Snap Lake kimberlite dyke, Canada.minsocam.org/ MSA/AMMin/ special-collections, doi.org/10.2138/am-2018-6496. 48p. Canada, Northwest Territoriesdeposit - Snap Lake
DS201811-2590
2018
Li, Z., Fedortchouk, Y., Fulop, A., Chinn, I.L., Forbes, N.Positively oriented trigons on diamonds from the Snap Lake kimberlite dike, Canada: implications for fluids and kimberlite cooling rates.American Mineralogist, Vol. 103, pp. 1634-1648.Canada, Northwest Territoriesdeposit - Snap Lake

Abstract: The role of fluid(s) in the formation of different lithological facies of kimberlites is still poorly understood. The uncertainty in the composition of kimberlite melts hampers understanding the composition of volatiles, the depth of exsolution, and the effect on magma ascent and fragmentation. Recent estimates of H2O and CO2 solubility in kimberlite-like magmas suggest very shallow exsolution of fluid, while many features of kimberlites indicate the presence of significant fluid fraction at depth. Deep magmatic fluid produces negative trigonal etch pits on natural diamonds, the characteristics of which depend on the temperature and composition of the fluid. Positively oriented trigonal etch pits are very rare on natural diamonds and are likely a feature of resorption events unique to only some kimberlite magmas. Here we present the first systematic study of positively oriented trigonal etch pits on natural diamonds from Snap Lake kimberlite dike, Northwest Territories, Canada. The study used 91 micro-diamonds selected from a population of 251 diamonds representative of all six kimberlite litho-facies identified in the Snap Lake dike. We established that unlike the majority of diamonds from kimberlite pipes in the Northwest Territories, every studied Snap Lake diamond shows positively oriented trigons. These trigons cover the whole diamond surface starting from the {111} faces and continuing over the resorbed edges. They overprint negatively oriented trigons and modify them into hexagons. Atomic force microscopy obtained detailed geometry of 154 positive trigons on 14 diamonds. Three distinct trigon morphologies dependent on the type of the crystal lattice defect were recognized. The point-bottomed shape and positive correlation between the depth and diameter of the individual pits suggest a high CO2 content in the fluid. Comparison with the existing experimental data on positive trigons implies resorption at low-pressure conditions in the 800-1000 °C temperature range by trapped magmatic fluid after the dike emplacement. The intensity of this late resorption event (and the size of the positive trigons) increases from the dike contact with the country rock into the interior of the dike. Such a late resorption event is absent in the majority of kimberlites, which form pipes, and might be a specific feature of hypabyssal kimberlite bodies (dikes). The absence of positive trigons on diamonds from the majority of kimberlites suggests very quick magma cooling below ?800 °C after the pipe emplacement, precluding the development of any late resorption features. Our study shows that for kimberlitic magmas, for which mineral chemistry is unable to provide a robust record of magmatic fluid, morphological details of dissolution features on the surface of diamond and other mantle-derived minerals can serve as a fluid proxy. Better constraints of the pressure, temperature, and oxygen fugacity of the reversal in the trigon orientation on diamond may help to reconstruct the emplacement path of geologically diverse kimberlite bodies.
DS201809-2057
2018
Lian, D., Yang, J., Wiedenbeck, M., Dilek, Y., Rocholl, A., Wu, W.Carbon and nitrogen isotope, and mineral inclusion studies on the diamonds from the Pozanti-Karsanti chromitite, Turkey. MicrodiamondsContributions to Mineralogy and Petrology, doi.org:10.1007/ s00410-018-1499-5 19p.Europe, Turkeydiamond inclusions

Abstract: The Pozanti-Karsanti ophiolite (PKO) is one of the largest oceanic remnants in the Tauride belt, Turkey. Micro-diamonds were recovered from the podiform chromitites, and these diamonds were investigated based on morphology, color, cathodoluminescence, nitrogen content, carbon and nitrogen isotopes, internal structure and inclusions. The diamonds recovered from the PKO are mainly mixed-habit diamonds with sectors of different brightness under the cathodoluminescence images. The total ?13C range of the PKO diamonds varies between ? 18.8 and ? 28.4‰, with a principle ?13C mode at ? 25‰. Nitrogen contents of the diamonds range from 7 to 541 ppm with a mean value of 171 ppm, and the ?15N values range from ? 19.1 to 16.6‰, with a ?15N mode of ? 9‰. Stacking faults and partial dislocations are commonly observed in the Transmission Electron Microscopy foils whereas inclusions are rather rare. Combinations of ( Ca0.81Mn0.19)SiO3, NiMnCo-alloy and nanosized, quenched fluid phases were observed as inclusions in the PKO diamonds. We believe that the 13C-depleted carbon signature of the PKO diamonds derived from previously subducted crustal matter. These diamonds may have crystallized from C-saturated fluids in the asthenospheric mantle at depth below 250 km which were subsequently carried rapidly upward by asthenospheric melts.
DS201812-2841
2018
Liang, J., Gong, J., Li, W.Applications and impacts of google Earth: a decadal review ( 2006-2016).ISPRS Journal of Photogrammetry and Remote Sensing, Vol. 146, pp. 91-107.Mantleremote sensing

Abstract: Since Google Earth was first released in 2005, it has attracted hundreds of millions of users worldwide and made a profound impact on both academia and industry. It can be said that Google Earth epitomized the first-generation of Digital Earth prototypes. The functionalities and merits that have sustained Google Earth’s lasting influence are worth a retrospective review. In this paper, we take the liberty to conduct a bibliometric study of the applications of Google Earth during 2006-2016. We aim first to quantify the multifaceted impacts, and then to develop a structured understanding of the influence and contribution associated with Google Earth. To accomplish these objectives, we analyzed a total of 2115 Scopus publication records using scientometric methods and then proceed to discussion with a selected set of applications. The findings and conclusions can be summarized as follows: (1) the impact of Google Earth has been profound and persistent over the past decade. Google Earth was mentioned in an average of 229 publications per year since 2009. (2) Broadly, the impact of Google Earth has touched upon most scientific disciplines. Specifically, during 2006-2016, Google Earth has been mentioned in 2115 publications covering all of Scopus’s 26 subject areas; (3) the influence of Google Earth has largely concentrated in GIScience, remote sensing and geosciences. The extended influence of Google Earth has reached a wider range of audiences with a concentration in fields such as human geography, geoscience education and archaeology.
DS201809-2058
2018
Liddell, M.V., Bastow, I., Rawlinson, N., Darbyshire, F., Gilligan, A., Watson, E.Precambrian plate tectonics in northern Hudson Bay: evidence from P and S Wave Seismic tomography and analysis of source side effects in relative arrival-time dat a sets.Journal of Geophysical Research, Vol. 123, 7, pp. 5690-5709.Canada, NunavutGeophysics - seismic

Abstract: The geology of northern Hudson Bay, Canada, documents more than 2 billion years of history including the assembly of Precambrian and Archean terranes during several Paleoproterozoic orogenies, culminating in the Trans?Hudson Orogen (THO) ?1.8 Ga. The THO has been hypothesized to be similar in scale and nature to the ongoing Himalaya?Karakoram?Tibetan orogen, but the nature of lithospheric terrane boundaries, including potential plate?scale underthrusting, is poorly understood. To address this problem, we present new P and S wave tomographic models of the mantle seismic structure using data from recent seismograph networks stretching from northern Ontario to Nunavut (60-100?W and 50-80?N). The large size of our network requires careful mitigation of the influence of source side structure that contaminates our relative arrival time residuals. Our tomographic models reveal a complicated internal structure in the Archean Churchill plate. However, no seismic wave speed distinction is observed across the Snowbird Tectonic Zone, which bisects the Churchill. The mantle lithosphere in the central region of Hudson Bay is distinct from the THO, indicating potential boundaries of microcontinents and lithospheric blocks between the principal colliders. Slow wave speeds underlie southern Baffin Island, the leading edge of the generally high wave speed Churchill plate. This is interpreted to be Paleoproterozoic material underthrust beneath Baffin Island in a modern?style subduction zone setting.
DS201808-1764
2018
Lim, E., Giuliani, A., Phillips, D., Goemann, K.Origin of complex zoning in olivine from diverse, Diamondiferous kimberlites and tectonic settings: Ekati ( Canada), Alto Paranaiba ( Brazil) and Kaalvallei ( South Africa).Mineralogy and Petrology, doi.org/10.1007/s00710-018-0607-6 16p.Canada, Northwest Territories, South America, Brazildeposit - Ekati, Grizzly, Kaola, Limpeza-18, Tres Ranchos-04, Kaalvallei, Samada, New Robinson

Abstract: Olivine in kimberlites can provide unique insights into magma petrogenesis, because it is the most abundant xenocrystic phase and a stable magmatic product over most of the liquid line of descent. In this study we examined the petrography and chemistry of olivine in kimberlites from different tectonic settings, including the Slave craton, Canada (Ekati: Grizzly, Koala), the Brasilia mobile belt (Limpeza-18, Tres Ranchos-04), and the Kaapvaal craton, South Africa (Kaalvallei: Samada, New Robinson). Olivine cores display a wide range of compositions (e.g., Mg#?=?78-95). The similarity in olivine composition, resorption of core zones and inclusions of mantle-derived phases, indicates that most olivine cores originated from the disaggregation of mantle peridotites, including kimberlite-metasomatised lithologies (i.e. sheared lherzolites and megacrysts). Olivine rims typically show a restricted range of Mg#, with decreasing Ni and increasing Mn and Ca contents, a characteristic of kimberlitic olivine worldwide. The rims host inclusions of groundmass minerals, which implies crystallisation just before and/or during emplacement. There is a direct correlation between olivine rim composition and groundmass mineralogy, whereby high Mg/Fe rims are associated with carbonate-rich kimberlites, and lower Mg/Fe rims are correlated with increased phlogopite and Fe-bearing oxide mineral abundances. There are no differences in olivine composition between explosive (Grizzly) and hypabyssal (Koala) kimberlites. Olivine in kimberlites also displays transitional zones and less common internal zones, between cores and rims. The diffuse transitional zones exhibit intermediate compositions between cores and rims, attributed to partial re-equilibration of xenocrystic cores with the ascending kimberlite melt. In contrast, internal zones form discrete layers with resorbed margins and restricted Mg# values, but variable Ni, Mn and Ca concentrations, which indicates a discrete crystallization event from precursor kimberlite melts at mantle depths. Overall, olivine exhibits broadly analogous zoning in kimberlites worldwide. Variable compositions for individual zones relate to different parental melt compositions rather than variations in tectonic setting or emplacement mechanism.
DS201809-2059
2018
Ling, W-L., Wu, H., Berkana, W.Recognition of Neoproterozoic carbonatite intrusion in NW Yangtze block and its implications for continental evolution of south China.Goldschmidt Conference, 1p. AbstractChinacarbonatite

Abstract: Carbonatites are few but significant to understand carbon recycling of the earth, the crust-mantle interactions, deep mantle magmatism and regional continental evolution. The Lijiahe carbonatite intrusion, located at the Micangshan Mountains along the NW margin of the Yangtze block, South China was emplaced into the Paleoproterozoic strata, but the timing of the igneous event has long been unknown. Dating by U-Pb apatite was carried out by this work, and it gives an age of 766 ± 11 Ma (MSWD=0.15) for the carbonatitic magmatism of the region. The carbonatite comprises mainly of calcite, magnitite and apatite with minor minerals of salite, biotite, tremolite, hornblende and muscovite and accessary minerals of pyrrhotite, silver marcasite, niobite, spinel and zircon. Its spatial distribution was obviously controlled by regional tectonics. Besides, ultra-alkaline silicate intrusive complex in the region has been reported by us and other works, and mostly consists of iolite, urtite and jacupirangite with ages of ~890-875 Ma. Furthermore, a large number of gabbro and diorite plutons are found in the Micangshan Mountains and dated at ~780-760 Ma. NW margin of the Yangtze block is connected with the South Qinling orogenic belt generally thought having an affinity of the Yangtze block during the Neoproterozoic. Our works revealed that the South Qinling is discriminated from the NW Yangtze by intensive ~680 Ma igneous activities which are poorly reported in the interior of South China. Given that a ~815 Ma collision between the South Qinling ribbon and NW Yangtze margin is recognized by our recent work, the regional massive mantle-derived magmatism including the Lijiahe carbonatitic pluton is explained to indicate a drifting of South Qinling terrane from the NW margin of Yangtze block along previous weak-tectonic zones during the Rodinia breakup caused by continental rifting.
DS201810-2346
2018
Litvin, Yu.A., Kuzyura, A.V., Varlamov, D.A., Bovkun, A.V., Spival, A.V., Garanin, V.K.Interaction of kimberlite magma with diamonds upon uplift from the upper mantle to the Earth's crust.Geochemistry International, Vol. 56, 9, pp. 881-900.Russiadeposit - Nyurbinskaya

Abstract: Interaction between a melt of kimberlite from the Nyurbinskaya pipe (Yakutia) and natural monocrystalline diamonds was studied experimentally at 0.15 GPa and 1200-1250°C in high-pressure and high-temperature Ar gas “bombs.” The loss of diamond weight with slight surface dissolution of diamonds in a Ca carbonate-bearing kimberlite melt over the course of 2 h (the period of kimberlite transport from upper-mantle diamond-forming chambers to the crustal cumulative centers) is 3-4.5%. In 4 and 7-8 days (under the conditions of crustal cumulative centers), the weight of diamond decreases with remarkable bulk dissolution by 13.5 and 24.5-27.5%, respectively. In the run at 0.15 GPa and 1200°C kimberlite and ilmenite (added) melts interact to produce perovskite melt. Both of the melts, rich in titanium minerals, are immiscible with kimberlite melt and therefore cannot influence the diamond dissolution kinetics in the kimberlite melt. The experimental results suggest that precisely the dissolution processes for thermodynamically metastable diamonds in silicate-carbonate kimberlitic magmas are responsible for the effective decrease in the diamond potential of kimberlite deposits. The paper discusses the physicochemical reasons for the decrease in the kimberlite diamond potential during the chemically active history of diamond genesis: from upper-mantle chambers to the explosive release of diamonds and kimberlite material from cumulative centers to the Earth’s surface. The data on experimental physicochemical studies of the origin, analytical mineralogy of inclusions, and isotope geochemistry of diamonds are correlated.
DS201807-1508
2018
Liu, H., Wang, W., Jia, X., Leng, W., Wu, Z., Sun, D.The combined effects of post-spinel and post-garnet phase transitions on mantle plume dynamics.Earth and Planetary Science Letters, Vol. 496, pp. 80-88.Mantleperovskite, hotspots

Abstract: Mineralogical studies indicate that two major phase transitions occur near the depth of 660 km in the Earth's pyrolitic mantle: the ringwoodite (Rw) to perovskite (Pv) + magnesiowüstite (Mw) and the majorite (Mj) to perovskite (Pv) phase transitions. Seismological results also show a complicated phase boundary structure at this depth in plume regions. However, previous geodynamical modeling has mainly focused on the effects of the Rw-Pv+Mw phase transition on plume dynamics and has largely neglected the effects of the Mj-Pv phase transition. Here, we develop a 3-D regional spherical geodynamic model to study the combined influence of these two phase transitions on plume dynamics. Our results show the following: (1) A double phase boundary occurs in the high-temperature center of the plume, corresponding to the double reflections in seismic observations. Other plume regions feature a single, flat uplifted phase boundary, causing a gap of high seismic velocity anomalies. (2) Large amounts of relatively low-temperature plume materials can be trapped in the transition zone due to the combined effects of phase transitions, forming a complex truncated cone shape. (3) The Mj-Pv phase transition greatly enhances the plume penetration capability through 660-km phase boundary, which has a significant influence on the plume dynamics. Our results provide new insights which can be used to better constrain the 660-km discontinuity variations, seismic wave velocity structure and plume dynamics in the mantle transition zone. The model can also help to estimate the mantle temperature and Clapeyron slopes at the 660 km phase boundary.
DS201809-2060
2018
Liu, J., Brin, L.E., Pearson, D.G., Bretschneider, L., Luguet, A., van Acken, D., Kjarsgaard, B., Riches, A., Miskovic, A.Diamondiferous Paleoproterozoic mantle roots beneath Arctic Canada: a study of mantle xenoliths from Parry Peninsula and Central Victoria Island.Geochimica et Cosmochimica Acta, doi.org/10.1016/j.gca.2018.08.010 78p.Canada, Nunavut, Parry Peninsula. Central Victoria Islandxenoliths

Abstract: While the mantle roots directly beneath Archean cratons have been relatively well studied because of their economic importance, much less is known about the genesis, age, composition and thickness of the mantle lithosphere beneath the regions that surround the cratons. Despite this knowledge gap, it is fundamentally important to establish the nature of relationships between this circum-cratonic mantle and that beneath the cratons, including the diamond potential of circum-cratonic regions. Here we present mineral and bulk elemental and isotopic compositions for kimberlite-borne mantle xenoliths from the Parry Peninsula and Central Victoria Island, Arctic Canada. These xenoliths provide key windows into the lithospheric mantle underpinning regions to the North and Northwest of the Archean Slave craton, where the presence of cratonic material has been proposed. The mantle xenolith data are supplemented by mineral concentrate data obtained during diamond exploration. The mineral and whole rock chemistry of peridotites from both localities is indistinguishable from that of typical cratonic mantle lithosphere. The cool mantle paleogeotherms defined by mineral thermobarometry reveal that the lithospheric mantle beneath the Parry Peninsula and Central Victoria Island terranes extended well into the diamond stability field at the time of kimberlite eruption, and this is consistent with the recovery of diamonds from both kimberlite fields. Bulk xenolith Se and Te contents, and highly siderophile element (including Os, Ir, Pt, Pd and Re) abundance systematics, plus corresponding depletion ages derived from Re-Os isotope data suggest that the mantle beneath these parts of Arctic Canada formed in the Paleoproterozoic Era, at ?2?Ga, rather than in the Archean. The presence of a diamondiferous Paleoproterozoic mantle root is part of the growing body of global evidence for diamond generation in mantle roots that stabilized well after the Archean. In the context of regional tectonics, we interpret the highly depleted mantle compositions beneath both studied regions as formed by mantle melting associated with hydrous metasomatism in the major Paleoproterozoic Wopmay-Great Bear-Hottah arc systems. These ?2?Ga arc systems were subsequently accreted along the margin of the Slave craton to form a craton-like thick lithosphere with diamond potential thereby demonstrating the importance of subduction accretion in building up Earth’s long-lived continental terranes.
DS201809-2062
2018
Liu, J., Pearson, D.G., Bretschneider, L., Luguet, A., Van Acken, D., Kjarsgaard, B., Riches, A., Miskovic, A.Diamondiferous Proterozoic mantle roots beneath Arctic Canada.Goldschmidt Conference, 1p. AbstractCanada, Parry Peninsula, Victoria Islandxenoliths

Abstract: The mantle roots directly beneath Archean cratons have been relatively well studied because of their economic importance, yet much less is known about the genesis, age, composition and thickness of the mantle lithosphere beneath the regions surrounding these cratons. However, it is critically important to establish the nature of the relationship between this circum-cratonic mantle and that beneath the cratons, including the diamond potential of circum-cratonic regions. Here we present mineral and bulk elemental and isotopic compositions for kimberlite-borne mantle xenoliths from the Parry Peninsula (PP) and Central Victoria Island (CVI), Arctic Canada. These xenoliths provide key windows into the lithospheric mantle underpinning regions to the North and Northwest of the Slave craton, where the presence of cratonic mantle has been proposed. The mineral and whole rock chemistry of peridotites from both localities is indistinguishable from that of typical cratonic mantle lithosphere. The cool mantle geotherms defined by mineral thermobarometry reveal that the lithospheric mantle beneath the PP and CVI terranes extended well into the diamond stability field at the time of kimberlite eruption, consistent with the recovery of diamonds from both kimberlite fields. Bulk Se, Te, and highly siderophile element abundance systematics, plus Re-Os isotope age data suggest that the mantle beneath these parts of Arctic Canada formed at ~2 Ga, rather than in the Archean. The presence of a diamondiferous Paleoproterozoic mantle root is part of the growing body of evidence for peridotitic diamond generation in mantle roots that stabilized well after the Archean. In the context of regional tectonics, the highly depleted mantle compositions beneath both regions developed during mantle melting associated with hydrous metasomatism in the major Paleoproterozoic Wopmay- Great Bear-Hottah arc systems. These terranes were subsequently accreted along the margin of the Slave craton to form a craton-like thick lithosphere with significant diamond potential.
DS201809-2061
2018
Liu, J., Pearson, D.G., Shu, Q., Sigurdsson, H.Hafnium osmium isotope systematics of mantle peridotites from the Cameroon Volcanic Line: implications for dating post-Archean lithospheric mantle.Goldschmidt Conference, 1p. AbstractMantleperidotites

Abstract: The Re-Os isotope system is well suited to constraining the timing of melt depletion of Archean mantle peridotites. In contrast, the variability inherent in post-Archean mantle Os isotope evolution leads to increasing uncertainty in Re-Os model ages. The Lu-Hf isotopic system has shown some potential for dating peridotite formation ages, providing valuable ages that are complementary to the Re-Os system. For post-Archean mantle peridotites, the key target in the Lu-Hf isotopic work is clinopyroxene (Cpx), because of its high Lu and Hf concentrations and the typical absence of garnet in these rocks. However, orthopyroxene (Opx) can contrain 20% or more of the Hf budget of spinel peridotites and somethimes over 40% of the Lu budget, with Lu/Hf ratios 3-4 times those of Cpx. Thus, Opx Lu-Hf isotopic compositions cannot be ignored or simply calculated, as the equilibrium temperatures of mantle peridotites prior to eruption could be lower or higher than the Hf closure temperature (Tc(Hf)~900ºC). Here we explore Lu-Hf partitioning in spinel peridotite xenoliths from the Cameroon Volcanic Line in additin to WR Re-Os analyses. The Hf isotopic composition of Opx in these rocks is equal to or higher than that of Cpx, consistent with some samples having equilibrium temperatures close to Tc(Hf). Combining Cpx and Opx, the constructed WR Lu-Hf isochron yields an age of 2.01±0.36 Ga (2?; MSWD = 11.4; ?Hfi = -0.8±19.2), which is in accordance with the oldest of the variable Re-Os model ages. The continental sector of the Cameroon Line runs close to the edge of the Congo craton. The Hf-Os data indicate that the lithosphere underpinning this region formed in the Paleoproterozoic (~2Ga) most likely during the Paleoproterzoic assembly between the Congo and West African Cratons. We emphasize that Opx and Cpx should be combined together to construct the WR isochron in order to obtain the precise age and initial Hf isotope compositions of post-Archean spinel peridotites.
DS201811-2591
2018
Liu, P., Zhang, J., Massonne, H-J., Jin, Z.Polyphase solid-inclusions formed by interactions between infiltrating fluids and precursor minerals enclosed in garnet of UHP rocks from the Dabie Shan, China.American Mineralogist, Vol. 103, pp. 1663-1673.Chinacoesite

Abstract: Three types of polyphase solid-inclusions (PSIs) with distinct mineral assemblages and micro-structures were found in garnet of an ultrahigh-pressure (UHP) eclogite-vein system from the Dabie Shan, east-central China. Type-1 PSI contains variable volumes of quartz, K-feldspar, plagioclase ± other phases, whereas Type-2 PSI contains variable volumes of quartz, calcite ± other phases. Both types display shapes that are compatible with those of euhedral coesite inclusions. Type-3 PSI always contains a rutile core that is surrounded by plagioclase ± quartz and generally displays the morphology of the rutile core. Variable amounts of K-feldspar are embedded within the plagioclase of Type-3 PSIs. The three PSI types developed fluid-mediated microstructures that include wedge-like offshoot and protrusion textures and inclusion-garnet interfaces controlled by the crystallographic structure of garnet. PSIs in peak minerals of UHP rocks have been previously thought to represent primary supercritical fluid or melt inclusions. Here we propose that the studied PSIs were formed under high-pressure (HP) eclogite-facies conditions during exhumation and represent reaction products between an enclosed mineral, such as coesite and rutile, and external fluids infiltrating the host garnet along fractures that have been healed later on. Two immiscible aqueous fluids (i.e., a siliceous and a carbonaceous) were involved in the formation of these PSIs. The siliceous fluid was rich in various large ion lithophile elements like Cs, Rb, Ba, K, Pb, Li, and Sr, whereas the carbonaceous fluid was rich in Pb and Sr. The new PSI formation mechanism proposed in this study brings significant implications for tracing fluid evolution and post-entrapment modifications of mineral inclusions in HP and UHP metamorphic rocks.
DS201810-2348
2018
Liu, Y., Chakhmouradian, A.R., Hou, Z., Song, W., Kynicky, J.Development of REE mineralization in the giant Maoniuping deposit ( Sichuan, China): insights from mineralogy, fluid inclusions, and trace element geochemistry.Mineralium Deposita, doi.org/10.1007/s00126-018-0836-y 18p.Chinacarbonatite

Abstract: Rare-earth deposits associated with intrusive carbonatite complexes are the world’s most important source of these elements (REE). One of the largest deposits of this type is Maoniuping in the Mianning-Dechang metallogenic belt of eastern Tibet (Sichuan, China). In the currently mined central part of the deposit (Dagudao section), REE mineralization is hosted by a structurally and mineralogically complex Late Oligocene (26.4 ±?1.2 Ma, 40Ar/39Ar age of fluorphlogopite associated with bastnäsite) hydrothermal vein system developed in a coeval syenite intrusion. Low-grade stockworks of multiple veinlets and breccias in the lower part of the orebody grade upwards into progressively thicker veins (up to 12 m in width) that are typically zoned and comprise ferromagnesian micas (biotite to fluorphlogopite), sodium clinopyroxenes (aegirine to aegirine-augite), sodium amphiboles (magnesio-arfvedsonite to fluororichterite), K-feldspar, fluorite, barite, calcite, and bastnäsite. The latter four minerals are most common in the uppermost 80 m of the Dagudao section and represent the climax of hydrothermal activity. Systematic variations in the fluid inclusion data indicate a continuous hydrothermal evolution from about 230-400 °C (fluid inclusions in feldspar, clinopyroxene, and amphibole) to 140-240 °C (fluid inclusions in bastnäsite, fluorite, calcite). Hydrothermal REE transport was probably controlled by F?, (SO4)2?, Cl?, and (CO3)2? as complexing ligands. We propose that at Dagudao, silicate magmas produced orthomagmatic fluids that explored and expanded a fissure system generated by strike-slip faulting. Initially, the fluids had appreciable capacity to transport REE and, consequently, no major mineralization developed. The earliest minerals to precipitate were alkali- and Fe-rich silicates containing low levels of F, which caused progressive enrichment of the fluid in Ca, Mg, F, Cl, REE, (SO4)2?, and (CO3)2?, leading to the crystallization of aegirine-augite, fluororichterite, fluorphlogopite, fluorite, barite, calcite, and bastnäsite gradually. Barite, fluorite, calcite, and bastnäsite are the most common minerals in typical ores, and bastnäsite generally postdates these gangue minerals. Thus, it is very probable that fluid cooling and formation of large amount of fluorite, barite, and calcite triggered bastnäsite precipitation in the waning stage of hydrothermal activity.
DS201802-0250
2018
Liu, Y-L., Ling, M-X., Williams, I.S., Yang, X-Y., Wang, C.Y.The formation of the giant Bayan Obo REE Nb Fe deposit, North China, Mesoproterozoic carbonatite and overprinted Paleozoic dolomitization.Ore Geology Reviews, Vol. 92, pp. 73-83.Chinadeposit - Bayan Obo

Abstract: The Bayan Obo ore deposit in Inner Mongolia, North China, the largest-known rare earth element (REE) deposit in the world, is closely associated with carbonatite dykes. Scarce zircon grains, with a wide range of ages and diverse origins, have been extracted from the Wu dyke, a REE-enriched calcitic carbonatite dyke 2?km from the East Ore Body of the Bayan Obo deposit. Three zircon populations were identified based on ages and trace element compositions: 1) Captured zircons with Paleoproterozoic and Archean ages. These zircons have REE patterns and moderate Th/U ratios similar to zircon with silicate inclusions from basement igneous rocks, which have been recognized as contaminants from wall rocks. 2) Carbonatite magmatic zircons with Mesoproterozoic ages. These zircons have high to extremely high Th/U ratios (13-1600), a characteristic signature of the Bayan Obo deposit. Two zircon grains yielded concordant 206Pb/238U ages (1.27?±?0.11?Ga???1.42?±?0.18?Ga) and 208Pb/232Th age (1.26?±?0.20?Ga) with calcite inclusions, indicating that the Wu dyke was emplaced at ca. 1.34?Ga, which coincides with a worldwide generation of Mesoproterozoic kimberlites, lamprophyres, carbonatites, and anorogenic magmatism. 3) Hydrothermal zircons with Caledonian and Triassic ages. The Caledonian zircon has 206Pb/238U age of 381?±?4?Ma and 208Pb/232Th age of 367?±?14?Ma with dolomite inclusion. These evidences are consistent with multiple stages of mineralization, Mesoproterozoic calcite carbonatite magmatism interacted by protracted fluxing of subduction-released Caledonian fluids during the closure of the Palaeo-Asian Ocean, coupled with interaction with the mantle wedge and metasomatism of overlying sedimentary carbonate.
DS201809-2063
2018
Liu, Y-S., Foley, S.F., Chien, C.F., He, D., Zong, K.Q.Mantle recycling of sedimentary carbonate along the northern margin of the North Chin a craton.Goldschmidt Conference, 1p. AbstractChinacarbonatite

Abstract: Sedimentary carbonate rocks, which exist extensively in the oceanic realm, are subducted to differing degrees during the closure of oceanic basins. However, very few observational data exist to provide details on the mechanisms of transport of carbonate materials from the surface to mantle depths and back to the Earth’s surface. Here we presented a series of diamond-bearing carbonatite xenoliths, carbonatite intrusions and carbonatite veins along the northern margin of the North China Craton (NCC). These carbonatites show geochemical features of recycled limestone (similar trace element patterns and high 87Sr/86Sr ratios of 0.705-0.709), indicating that they had a sedimentary limestone precursor. However, the presence of diamond, reduced minerals (e.g., moissanite), mantle-derived silicate minerals (eg., Cpx and Opx), and high Ni content and 143Nd/144Nd ratio indicate their staying for a time in the mantle. Combining with the zircon age spectrums of the carbonatite xenoliths and intrusions and the extensive high-87Sr/86Sr (up to 0.708) carbonatite metasomatism in the lithospheric mantle along the northern margin of NCC, we suggest that the limestone precursor could have been derived from the Paleo-Asian Ocean, and these carbonatites mark the subduction of a carbonate platform of the Paleo-Asian Oceanic slab to mantle depths beneath the NCC. Extensive mantle recycling of sedimentary carbonate could have contributed to the modification of the lithospheric mantle along the northern margin of the North China Craton.
DS201803-0462
2017
Lobanov, S.S., Holtgrewe, N., Lin, J-F, Goncharov, A.F.Radiative conductivity and abundance of post perovskite in the lower most mantle.Earth and Planetary Science Letters, Vol. 479, pp. 43-49.Mantleperovskite

Abstract: Thermal conductivity of the lowermost mantle governs the heat flow out of the core energizing planetary-scale geological processes. Yet, there are no direct experimental measurements of thermal conductivity at relevant pressure-temperature conditions of Earth's core-mantle boundary. Here we determine the radiative conductivity of post-perovskite at near core-mantle boundary conditions by optical absorption measurements in a laser-heated diamond anvil cell. Our results show that the radiative conductivity of Mg0.9Fe0.1SiO3 post-perovskite (?1.1 W/m/K) is almost two times smaller than that of bridgmanite (?2.0 W/m/K) at the base of the mantle. By combining this result with the present-day core-mantle heat flow and available estimations on the lattice thermal conductivity we conclude that post-perovskite is at least as abundant as bridgmanite in the lowermost mantle which has profound implications for the dynamics of the deep Earth.
DS201807-1509
2018
Lock, N., Vercoe, S.Jwaneng - the untold story of the discovery of the world's richest diamond mine.SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 185-202.Africa, Botswanadeposit - Jwaneng
DS201808-1765
2018
Lock, N., Vercoe, S.Jwaneng - the untold story of the discovery of the world's richest diamond mine.SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 14 ppts.Africa, Botswanadeposit - Jwaneng
DS201804-0716
2018
Locock, A.J., Mitchell, R.H.Perovskite classification: an excel spreadsheet to determine and depict end member proportions for the perovskite and vapnikite subgroups of the perovskite supergroup.Computers and Geosciences, Vol. 113, pp. 106-114.Technologyperovskite

Abstract: Perovskite mineral oxides commonly exhibit extensive solid-solution, and are therefore classified on the basis of the proportions of their ideal end-members. A uniform sequence of calculation of the end-members is required if comparisons are to be made between different sets of analytical data. A Microsoft Excel spreadsheet has been programmed to assist with the classification and depiction of the minerals of the perovskite- and vapnikite-subgroups following the 2017 nomenclature of the perovskite supergroup recommended by the International Mineralogical Association (IMA). Compositional data for up to 36 elements are input into the spreadsheet as oxides in weight percent. For each analysis, the output includes the formula, the normalized proportions of 15 end-members, and the percentage of cations which cannot be assigned to those end-members. The data are automatically plotted onto the ternary and quaternary diagrams recommended by the IMA for depiction of perovskite compositions. Up to 200 analyses can be entered into the spreadsheet, which is accompanied by data calculated for 140 perovskite compositions compiled from the literature.
DS201809-2064
2018
Logvinova, A.M., Babushkina, S.A., Oleynikov, O.B., Sobolev, N.V.Shrilankite inclusions in garnets from kimberlite bodies and Diamondiferous volcanic sedimentary rocks of the Yakutian kimberlite province.Doklady Earth Sciences, Vol. 478, 1, pp. 15-19.Russiadiamond inclusions

Abstract: Pyrope-almandine garnets (Mg# = 28.3-44.9, Ca# = 15.5-21.3) from a heavy mineral concentrate of diamondiferous kimberlites of the largest diamond deposit, the Yubileinaya pipe, along with kimberlite- like rocks and diamondiferous volcano-sediments of the Laptev Sea coast, have been found to contain polymineral, predominantly acicular inclusions, composed of aggregates of shrilankite (Ti2ZrO6), rutile, ilmenite, clinopyroxene, and apatite. The presence of shrilankite as an inclusion in garnets from assumed garnet-pyroxene rocks of the lower crust, lifted up by diamond-bearing kimberlite, allows it to be considered as an indicator mineral of kimberlite, which expands the possibilities when searching for kimberlite in the Arctic.
DS201801-0034
2018
Loose, D., Schenk, V.2.09 Ga old eclogites in the Eburnian - Transamazonian orogen of southern Cameroon: significance for Paleoproterozoic plate tectonics.Precambrian Research, Vol. 304, pp. 1-11.Africa, Camerooneclogites

Abstract: Lenses of retrogressed eclogites occur in a 100 km wide zone of the Nyong Complex, a remnant of the Eburnian-Transamazonian orogen, marking a Palaeoproterozoic suture between the Congo and São Francisco Cratons. The eclogites show trace element pattern (depleted in LREE) similar to those of mid-ocean ridge basalts, indicating that the precursor melts formed in a depleted mantle source and the eclogites formed from oceanic crust. Despite numerous plagioclase ‘exsolutions’ up to 25 mol% jadeite component is preserved in omphacite and points to minimum pressures of 16 kbar at c. 800 °C. Pressures may have been 18-20 kbar as indicated by estimated compositions of peak omphacite. The age of eclogite metamorphism has been constrained by U-Pb SHRIMP dating of zircon at 2093 ± 45 Ma. The eclogites are associated with 2.05 Ga old charnockites and mafic granulites containing textures characteristic for near-isobaric cooling. These rocks may represent the plate above a subduction zone in which the eclogites were tectonically emplaced. With an age of 2.09 Ga the eclogites of the Nyong Complex are older than other subduction related Palaeoproterozoic eclogites of the Ubendian (1.88 Ga) and Usagaran belts (2.0 Ga) at the southern border of the Tanzania Craton. They are also older than eclogites in the Belomorian province (1.9 Ga; Russia) and thus represent the oldest known eclogites outcropping in an orogenic belt. The African eclogites (all with MORB chemistry) indicate that during the formation of the Nuna supercontinent the Palaeoproterozoic oceanic lithosphere around the Congo-Tanzania Craton was thick, cold and rigid enough to become subducted similar to cold oceanic lithosphere in the modern plate tectonic regime. However, apparent geothermal gradients of 12-14 °C/km for the Palaeoproterozoic eclogites are higher than those of Neoproterozoic and Phanerozoic eclogites and are interpreted as the result of warm subduction in a hotter Palaeoproterozoic Earth.
DS201804-0717
2018
Loose, D., Schenk, V.2.09 Ga old eclogites in the Eburnian Transamazonian orogen of southern Cameroon: significance for Paleoproterozoic plate tectonics.Precambrian Research, Vol. 304, pp. 1-11.Africa, Camerooneclogites

Abstract: Lenses of retrogressed eclogites occur in a 100 km wide zone of the Nyong Complex, a remnant of the Eburnian-Transamazonian orogen, marking a Palaeoproterozoic suture between the Congo and São Francisco Cratons. The eclogites show trace element pattern (depleted in LREE) similar to those of mid-ocean ridge basalts, indicating that the precursor melts formed in a depleted mantle source and the eclogites formed from oceanic crust. Despite numerous plagioclase ‘exsolutions’ up to 25 mol% jadeite component is preserved in omphacite and points to minimum pressures of 16 kbar at c. 800 °C. Pressures may have been 18-20 kbar as indicated by estimated compositions of peak omphacite. The age of eclogite metamorphism has been constrained by U-Pb SHRIMP dating of zircon at 2093 ± 45 Ma. The eclogites are associated with 2.05 Ga old charnockites and mafic granulites containing textures characteristic for near-isobaric cooling. These rocks may represent the plate above a subduction zone in which the eclogites were tectonically emplaced. With an age of 2.09 Ga the eclogites of the Nyong Complex are older than other subduction related Palaeoproterozoic eclogites of the Ubendian (1.88 Ga) and Usagaran belts (2.0 Ga) at the southern border of the Tanzania Craton. They are also older than eclogites in the Belomorian province (1.9 Ga; Russia) and thus represent the oldest known eclogites outcropping in an orogenic belt. The African eclogites (all with MORB chemistry) indicate that during the formation of the Nuna supercontinent the Palaeoproterozoic oceanic lithosphere around the Congo-Tanzania Craton was thick, cold and rigid enough to become subducted similar to cold oceanic lithosphere in the modern plate tectonic regime. However, apparent geothermal gradients of 12-14 °C/km for the Palaeoproterozoic eclogites are higher than those of Neoproterozoic and Phanerozoic eclogites and are interpreted as the result of warm subduction in a hotter Palaeoproterozoic Earth.
DS201812-2842
2018
Lorenzi, R., Zullino, A., Prosperi, L., Paleari, A.Visible light excited red-emitting vacancies at carbon interstitials as indicators of irradiated and annealed Type Ia diamonds.Diamond & Related Materials, Vol. 90, pp. 188-193.Europe, Italydiamond radiation

Abstract: During the last decades many studies have been carried out to investigate how point defects and aggregates respond and evolve in natural Type Ia diamonds as a result of treatments, and a number of underlying mechanisms have been identified and interpreted. However, the analysis of radiation-induced creation/ionization of defects, as well as their migration and aggregation in secondary defect structures, often requires experimental approaches which can hardly constitute a simple-to-use diagnostic tool for the identification of artificially treated diamonds. Here we disclose a novel simple indicator of artificial exposure of Type Ia diamonds to ionizing radiations and subsequent annealing. This indicator consists in narrow photoluminescence lines in the red region, between 681 and 725?nm, we recently found to result from vacancies trapped by interstitial carbon aggregates and platelets. Our results demonstrate that interstitial structures become sites of vacancy trapping - by thermal migration of radiation-induced vacancies - only when diamond undergoes treatments. We give the rigorous validation of the new spectroscopic probe of artificial treatments analysing photoluminescence and infrared absorption spectra of well-known H1b and H1c centres in a hundred samples. Importantly, the method is based on emission lines which do not require neither high photon-energy excitation nor cryogenic temperatures.
DS201810-2349
2018
Lu, J., Griffin, W.L., Tilhac, R., Xiong, Q., Zheng, J., O'Reilly, S.Y.Tracking deep lithospheric events with garnet-websterite xenoliths from southeastern Australia.Journal of Petrology, Vol. 59, 5, pp. 901-903.Australiabasanite

Abstract: Pyroxenites provide important information on mantle heterogeneity and can be used to trace mantle evolution. New major and trace element and Sr-, Nd-, and Hf-isotope analyses of minerals and whole-rock samples of garnet websterites entrained in basanite tuffs in Bullenmerri and Gnotuk maars, southeastern Australia, are here combined with detailed petrographic observations to constrain the sources and genesis of the pyroxenites, and to trace the dynamic evolution of the lithospheric mantle. Most garnet websterites have high MgO and Cr2O3 contents, relatively flat light rare earth element (LREE) patterns ([La/Nd]CN?=?0•77-2•22) and ocean island basalt-like Sr-, Nd-, and Hf-isotope compositions [87Sr/86Sr?=?0•70412-0•70657; ?Nd(t)?=?-0•32 to +4•46; ?Hf(t)=+1•69 to +18•6] in clinopyroxenes. Some samples show subduction-related signatures with strong enrichments in large ion lithophile elements and LREE, and negative anomalies in high field strength elements, as well as high 87Sr/86Sr (up to 0•709), and decoupled Hf- and Nd-isotope compositions [?Nd(t)?=?-3•28; ?Hf(t) =?+11•6). These data suggest that the garnet pyroxenites represent early crystallization products of mafic melts derived from a convective mantle wedge. Hf model ages and Sm-Nd mineral isochrons suggest that these pyroxenites record at least two stages of evolution. The initial formation stage corresponds to the Paleozoic subduction of the proto-Pacific plate beneath southeastern Australia, which generated hydrous tholeiitic melts that crystallized clinopyroxene-dominated pyroxenites at ?1420-1450°C and ?75?km depth in the mantle wedge. The second stage corresponds to Eocene (c. 40?Ma) back-arc lithospheric extension, which led to uplift of the former mantle-wedge domain to 40-60?km depths, and subsequent cooling to the ambient geotherm (?950-1100°C). Extensive exsolution and recrystallization of garnet and orthopyroxene (±?ilmenite) from clinopyroxene megacrysts accompanied this stage. The timing of these mantle events coincides with vertical tectonism in the overlying crust.
DS201809-2065
2018
Lu, T., Ke, J., Qiu, Z.Surface dissolution features and contact twinning in natural diamonds. ( macle)Neues Jahrbuch fur Mineralogie, Vol. 195, pp. 145-153.Australiadeposit - Argyle

Abstract: Contact twinning with the so-called "macle" form or other shapes are often found in natural diamond crystals. However, the surface microtopographic features associated with twinning have been less investigated. Here, the surface dissolution and growth features seen on the twin boundaries, including the re-entrant angles revealed by differential interference contrast microscope and SEM techniques in 170 natural diamond crystals mainly from Argle mine, Australia are described and summarized. The hexagonal pits, rhombic pits along with higher symmetry observed at the twin boundaries together with dislocations and their formation processes are discussed.
DS201811-2592
2015
Lucas, a.Education and the mine to market story.InColor, December pp. 44-49.Globalemeralds
DS201812-2843
2018
Lunina, O., Glaskov, A.S., Gladkochub, D.P., Joao, F., Karpenko, M.A., Felix, J.T., Koshkarev, D.A., Sklyarov, E.The evolution of the crustal stress state of the Catoca kimberlite pipe area, northeastern Angola. IN RUSGeodynamics and Tectonphysics in RUS, Vol. 9, 3, pp. 827-854. only 1 p. english abstractAfrica, Angoladeposit - Catoca

Abstract: This paper presents the first results of the geostructural and tectonophysical studies of the crustal stress state in the Catoca kimberlite pipe area at the southwestern flank of the Kasai Shield in the northeasternAngola. In the evolution of the crustal stress state, six main stages are distinguished by analyzing the displacements of markers, fold hinges, long axes of boudins, granite dikes of various intrusion phases and kimberlites, as well as fractures with striations. For each of these stages, a dominating horizontal tectonic stress and its orientation is identified. During stage 1 (NW extension and shearing) and at the beginning of stage 2 (NW compression), structures formed in the host rocks in brittle-plastic conditions. The replacement of plastic deformation by faulting could occur about 530-510 Ma ago, when the continental crust ofAfricahad completely formed. Stage 3 (radial, mainly NW extension) and stage 4 (shearing, NW extension, and NE compression) were the most important for kimberlite occurrence: in the Early Cretaceous, radial extension was replaced by shearing. Both stages are related to opening of the central segment of theSouth Atlantic. The main kimberlite magmas occurred during the break-up of the Angola-Brazilian segment of Gondwana. In the course of all the four stages, stress was mainly released by the NE- and E-NE-striking faults and, to a lesser extent, by the NW-striking and latitudinal faults. The initial stage of kimberlite magmatism is associated with the NE- and E-NE-striking faults due to the presence of the Precambrian zones of flow and schistosity, which facilitated the NW-trending subhorizontal extension. Stage 5 (NE compression) began in the second half of the Cretaceous and possibly lasted until the end of the Paleogene, and compression occurred mainly along the NW-striking faults. Regionally, it corresponds to two stages of inversion movements in the southern regions of Africa, during which theAngoladome-shaped uplift emerged and the shoulders of the East African rifts began to take shape. Stage 6 (horizontal extension, mainly in the N-NE direction) is related to the processes that took place in the southern segment of theTanganyikarift and the eastern coast of theAtlantic. Based on the results of our studies, it became for the first time possible to get an idea of the main stages in the evolution of the studied region. Further geostructural measurements and dating of the host rocks will provide for a more precise definition of the proposed stages.
DS201805-0959
2018
Luttinen, A.V.Bilateral geochemical asymmetry in the Karoo large igneous province. ( also mentions Finland.)University of Helsinki, Scientific Report, Vol. 8, 1, DOI:10.1038/s41598-018-23661-3Africa, Europe, Finlandmagmatism

Abstract: In the Karoo large igneous province, the geochemical assessment of mantle source variability and structure is hampered by probable crustal contamination overprinting of compositionally diverse flood basalts. Mantle source characteristics have been defined only for exceptional, primitive rock types. Here I use a compiled dataset for over 800 samples to demonstrate that the abundance of Nb relative to Zr, Ti, and Y provides a useful geochemical tracer of mantle sources for variably contaminated rock types of the Karoo province. Variations in the relative abundance of Nb reveal emplacement of distinctive, Nb-undepleted and Nb-depleted magmas in the North Karoo and South Karoo sub-provinces, respectively, and clarify correlation between flood basalts and previously proposed mantle source components. Judging from plate tectonic reconstructions and the compositions of plausible mantle source components, the geochemical bilateral asymmetry in Karoo may reflect tapping of contrasting plume and upper mantle reservoirs in the two sub-provinces.
DS201812-2844
2018
Ma, Q., Xu, Y-G., Deng, Y,m Zhengm J-P., Sur, M., Griffin, W.L., Xia, B., Yan Wang, C.Similar crust beneath disrupted and intact cratons: arguments against lower crust delamination as a decratonization trigger. North China cratonTectonophysics, in press available 31p.Chinacraton

Abstract: The continental lithosphere is not forever; some cratons have lost their original roots during the course of their evolution. Yet, it is not clear whether gravitational instability of dense lower crust is the primary driver of decratonization. This is addressed here with emphasis being placed on the North China Craton (NCC), because it represents one of the best examples of craton-root disruption in the world, and a place where models can be tested. If lower-crustal delamination was the trigger for decratonization, we would expect a clear contrast in crustal structure and composition between disturbed (rootless) and intact cratons. However, the eastern (disturbed) and western (intact) parts of the NCC show virtually identical physical structure and composition (a thin mafic lower crust and a predominantly intermediate composition overall) although the crust in the disturbed part is thinner than in the intact craton. This suggests that delamination of the lower crust was not a viable mechanism of craton-root disruption in the NCC case. Indeed, the crust beneath the NCC largely resembles those of stable Archean cratons worldwide. Therefore the delamination, if it occurred, may have taken place much earlier (Archean) than previously thought, rather than in the Mesozoic. Delamination may have been a common phenomenon in the early evolution of cratons, probably due to relatively higher mantle temperatures in the Archean Eon.
DS201808-1766
2018
Machev, P., O'Bannon, E.F., Bozhilov, K.N., Wang, Q., Dobrzhinetskaya, L.Not all moissanites are created equal: new constraints on moissanite from metamorphic rocks of Bulgaria. Earth and Planetary Science Letters, Vol. 498, pp. 387-396.Europe, Bulgariamoissanite

Abstract: Terrestrial moissanite (SiC) is widely reported as an ultra-high pressure mineral occurring in kimberlites, diamonds and ultramafic/mafic rocks of mantle origin. However, the conditions of crystallization remain largely unknown. Moreover, dozens of SiC occurrences have been reported from continental crust sources such as granitoids, andesite-dacite volcanic rocks and their breccia, metasomatic and metamorphic rocks, and even limestones. The validity of many of these reports is still debated primarily due to possible contaminations from the widespread use of synthetic SiC abrasives in samples preparation. Indeed, reports of well-documented in-situ occurrences of moissanite in association with co-existing minerals are still scarce. The only condition of moissanite formation that is agreed upon is that extremely reducing media are required (e.g. 4.5-6 log units below the iron-wustite buffer). Here, we report the new occurrence of moissanite that was found in-situ within the garnet-staurolite-mica schists of Topolovgrad metamorphic group of Triassic age in Southern Bulgaria. The 10-300 ?m moissanite crystals are situated within 0.1-1.2 mm isolated clusters, filled with amorphous carbon and nanocrystalline graphite. Most of moissanite crystals are 15R (rhombohedral) and 6H (hexagonal) polytypes, and one prismatic crystal, found within them, exhibits unusual concentric polytypical zoning with core (15R), intermediate zone (6H) and rim (3C-cubic). Experimental data show that this type of polytypical zonation is likely due to a decrease in temperature (or/and pressure?) and changes in Si/C ratio. Indeed, amphibolite facies metamorphism (500-580?°C - garnet-staurolite zone) followed by a subsequent cooling during the retrograde stage of green schist facies metamorphism (?400-500?°C) could have provided a change in temperature. The SiC containing clusters exhibit evidence that they are pre-metamorphic, and we hypothesize that their protolith was a "lack shale" material likely rich in carbon, hydrocarbon and terrigenous silica. The latter served as a source of isolated chemically-reduced media, which is required for SiC formation. Other concepts to explain moissanite occurrences in metasedimentary rocks are also discussed. Importantly, our findings show that the formation conditions of moissanite are likely more variable than previously recognized.
DS201805-0960
2017
Macmillan, H.Mining in South Africa in the last 30 years - an overview.Reviews of African Political Economy, Vol. 44, 152, pp. 272-291.Africa, South Africahistory

Abstract: This article examines the history of South African mining over the last 30 years. It notes the declining contribution of mining to the economy, and a drop in employment levels and labour migration. It considers political, legislative and macro-economic changes, as well as mine ownership and control. It addresses the question why a democratically elected government, progressive labour legislation, trade-unionisation and Black Economic Empowerment have made remarkably little difference to working conditions. After examining the trajectories of individual commodities, such as gold, platinum, coal and diamonds, it concludes there has been no fundamental change in the relationship between state and capital.
DS201812-2845
2018
Macmorran, M.2018 kimberlite discoveries at the Loki ( Lac de Gras, NT) and Mel ( Melville Peninsula, NU) diamond projects.2018 Yellowknife Geoscience Forum , p. 49. abstractCanada, Northwest Territories, Nunavutdeposit - Loki, Mel

Abstract: Details will be provided on the recent kimberlite discoveries at North Arrow's Loki (NT) and Mel (NU) diamond projects. In April of this year, North Arrow announced the discovery of a new kimberlite at its Loki Diamond Project in the Northwest Territories. The Project is located in the Lac de Gras region, approximately 30 km southwest, and 24 km west of the Ekati and Diavik diamond mines, respectively. The Loki claims are contiguous to the south and east of the diamondiferous Monument kimberlite cluster. The project hosts several prospective exploration targets, as well as five known kimberlites: EG-01, EG-02, EG-05 and EG-130. At the beginning of March 2018, North Arrow commenced drilling to test the EG-05 kimberlite, as well as other priority targets. On April 5th, intersections of the first new kimberlite (465) discovered at Lac de Gras in over five years were announced, along with new drilling of kimberlite EG-05. The Mel Diamond Project is located on the Melville Peninsula (NU), approximately 140 km south of the community of Hall Beach, and 210 km northeast of the community of Naujaat (formerly Repulse Bay). A prospecting program conducted in late 2017 focused on discovery of potential kimberlite bedrock sources to a well-defined kimberlite indicator mineral train in the north part of the project area. Kimberlite float and subcrop was found in two areas, including a surface exposure of the ML8 kimberlite. A 62.1 kg sample of ML8 yielded 23 diamonds larger than the 0.106 mm sieve size, including a single, colourless diamond larger than the 0.85 mm sieve size. The 2018 exploration program included 778 m of exploration drilling leading to the discovery of a new kimberlite (ML345) and defining the ML8 kimberlite over a 170 m strike length. In addition, 447 till samples were collected to better define existing and new targets within the project area, 14 magnetic ground survey grids were completed, and over 200 kg of kimberlite was collected from surface at ML8 for further microdiamond analysis.
DS201810-2350
2018
Maconachie, R., Hilson, G.The war whose bullets you don't see: diamond digging, resilience and ebola in Sierra Leone.Journal of Rural Studies, Vol. 61, 1, pp. 110-122.Africa, Sierra Leonealluvials

Abstract: This paper reflects critically on the transformational impacts the recent Ebola epidemic has had in diamond-rich areas of rural Sierra Leone. It focuses specifically on the country's ‘diggers’, a sizable group of labourers who occupy the bottom of the country's artisanal diamond mine production pyramid. Based upon research conducted in the diamond-producing localities of Kenema and Kono, the paper argues how, in sharp contrast to the gloomy picture painted in the literature about their existences and struggles, diggers exhibited considerable resilience during the Ebola crisis. Their diversified livelihood portfolios proved to be effective survival strategies and buffers against the shocks and stresses brought about by lengthy periods of quarantine, and during times when mobility was restricted by the government in a bid to prevent the spreading of the disease. Drawing inspiration from the resilience literature, the paper captures the essence of these survival strategies, which should be viewed as latest reshuffling and expansion of diggers' rural livelihood portfolios. Policymakers and donors have yet to embrace fully these changes in a country where the Ebola recovery period promises to be lengthy and at a time when fresh, locally-informed rural development solutions are in short supply.
DS201812-2846
2018
Madsen, E., Truter, K.The transformation of De Beers Canada.2018 Yellowknife Geoscience Forum , p. 49-50. abstractCanadadeposit - De Beers

Abstract: Over the past two years, De Beers Canada has undergone a transformation. This has included: opening the world's largest newdiamond mine (Gahcho Kué Mine); relocating its operational supportcentre to Calgary from Toronto, andrefocusing the Calgary organizationto ensure it provides support servicesto our remote operations rather thanacting as a “head office”; improving partnerships with localcommunities; preparing to close the highlysuccessful Victor Mine in NorthernOntario; and, looking for opportunities to grow thecompany in Canada. The De Beers Canada of 2018 is a dramatically different company, one that has become a solid contributor to the De Beers Group, is a national leader in safety and has its focus on developing the first diamond mine on Baffin Island. Our presentation will provide an update on the activities of De Beers Canada since 2016 and a look ahead at where our company is going in the future.
DS201812-2847
2018
Magalhaes Macedo, J.Gar Mineracao - discoveries, geology and development of diamond deposits of Romaria and Monte Carmelo.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazildeposit - Romaria, Monte Carmelo
DS201807-1510
2018
Magee, C., Stevenson, C.T.E., Ebmeier, S.K., Keir, D., Hammond, J.O.S., Gottsmann, J.H., Whaler, K.A., Schofield, N., Jackson, C.A-L., Petronis, M.S., O'Driscoll, B., Morgan, J., Cruden, A., Vollgger, S.A., Dering, G., Micklethwaite, S., Jackson, M.D.Magma plumbing systems: a geophysical perspective. InSAR, GPS, GNSS, FWI, UAVsJournal of Petrology, in press available, 99p.Mantlemagmatism - geophysics

Abstract: Over the last few decades, significant advances in using geophysical techniques to image the structure of magma plumbing systems have enabled the identification of zones of melt accumulation, crystal mush development, and magma migration. Combining advanced geophysical observations with petrological and geochemical data has arguably revolutionised our understanding of, and afforded exciting new insights into, the development of entire magma plumbing systems. However, divisions between the scales and physical settings over which these geophysical, petrological, and geochemical methods are applied still remain. To characterise some of these differences and promote the benefits of further integration between these methodologies, we provide a review of geophysical techniques and discuss how they can be utilised to provide a structural context for and place physical limits on the chemical evolution of magma plumbing systems. For example, we examine how Interferometric Synthetic Aperture Radar (InSAR), coupled with Global Positioning System (GPS) and Global Navigation Satellite System (GNSS) data, and seismicity may be used to track magma migration in near real-time. We also discuss how seismic imaging, gravimetry, and electromagnetic data can identify contemporary melt zones, magma reservoirs, and, or, crystal mushes. These techniques complement seismic reflection data and rock magnetic analyses that delimit the structure and emplacement of ancient magma plumbing systems. For each of these techniques, with the addition of full-waveform inversion (FWI), the use of Unmanned Aerial Vehicles (UAVs), and the integration of geophysics with numerical modelling, we discuss potential future directions. We show that approaching problems concerning magma plumbing systems from an integrated petrological, geochemical, and geophysical perspective will undoubtedly yield important scientific advances, providing exciting future opportunities for the volcanological community.
DS201801-0035
2017
Magna, T., Rapprich, V., Wittke, A., Gussone, N., Upadhyay, D., Mikova, J., Pecskay, Z.Calcium isotope systematics and K-Ar and U-Pb temporal constraints on the genesis of Sevattur Samalpatti carbonatite silicate alkaline complexes.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 34-35.Indiadeposit - Samalpatti, Sevattur

Abstract: We present the first systematic survey of Ca isotope compositions in carbonatites and associated silicate rocks from Samalpatti and Sevattur, two Neoproterozoic complexes in Tamil Nadu, south India. Despite their close geographic proximity, their genesis and post-emplacement histories differ (Ackerman et al. 2017). The Sevattur complex appears to have been derived from an enriched mantle source with a limited post-magmatic disturbance. In contrast, carbonatites from Samalpatti show a record of extensive late-stage post-magmatic overprint, also apparent from unusually heavy C-O isotope compositions in a sub-suite of carbonatites (Ackerman et al. 2017). The mean ?44/40Ca = 0.69 ± 0.10‰ is slightly lighter than the average of fertile, unmetasomatized peridotites at ?44/40Ca = 0.95 ± 0.05‰ (Kang et al. 2017). This difference may attest to the general difference between carbonates and silicates (see Kang et al. 2017). It could also reflect Ca isotope fractionation between isotopically heavy silicate and isotopically light carbonate (e.g., John et al. 2012), though to a somewhat minor extent. This is supported by leaching experiments in this study where the extent of silicate-carbonate fractionation (44/40Casilicate-carbonate) has been investigated. The values at ~0.1-0.2‰ are expectedly lower than those reported earlier (~0.6‰; John et al. 2012) and may reflect high-temperature Ca isotope fractionation. The variability in ?44/40Ca values of carbonatites and silico-carbonatites from the Samalpatti complex is larger (0.70- 1.14‰) and appears to be in accord with extensive post-emplacement disturbance. Significant loss of REE and 13C-18O-enriched signature are combined with high ?44/40Ca values, which could reflect massive exchange with metasomatic aqueous fluids. The 40Kdecay correction was applied to K-rich rocks (syenites, monzonites). Given the antiquity of the complex dated at ca. ~800 Ma (Schleicher et al. 1997) and considering high-K/Ca character of some rocks, the resulting ?44/40Ca800 Myr correction was up to ~+1.2‰. In this regard, it is crucial to constrain the age history of the entire region. The nearby Hogenakal carbonatite body was dated at ~2.4 Ga which is much older than Rb-Sr and Sm-Nd age of Sevattur (Kumar et al. 1998) from the same fault system. We have acquired K-Ar mineral (K-feldspar, biotite, amphibole) and U-Pb zircon data from Sevattur and Samalpatti. The K-Ar ages span a range between ~800 and ~510 Ma (~800 Ma for amphiboles and biotites from silico-carbonatites and mafic silicate rocks and ~570-510 Ma for K-feldspars and biotites from syenites), dating two high-grade regional tectono-thermal overprint events, documented earlier. The complex nature of this process is indicated by concordant U-Pb zircon age at ~2.5 Ga yielded for a melatonalite, for which K-Ar biotite age of ~802 Ma was measured. This fits into the age bracket of basement of the Eastern Dharwar Craton. The age distribution bimodality at ~2.5 Ga and ~800 Ma has been found for several other samples, suggesting a pulsed thermal history of the area, associated with a significant overprint by fluids likely derived from the local crust. Particularly high U concentrations in zircons (thousands ppm), combined with a range of K-Ar ages, attest to such multi-episodic history.
DS201810-2351
2018
Mahan, B., Siebert, J., Blanchard, I., Moynier, F.Investigating Earth's formation history through copper & sulfur metal silicate partitioning during core-mantle differentiation.Journal of Geophysical Research: Solid Earth, doi:10.1029/2018JB015991Mantlecore mantle boundary

Abstract: Experiments wherein molten metal and silicate (rock?building) phases un?mix themselves due to their physical properties, i.e. metal?silicate partitioning, can be conducted at the high temperatures and pressures (HP?HT) that characterized Earth's differentiation into a core and mantle. The redistribution of elements between the metal and silicate phases ? their partitioning ? during this process can be measured and mathematically described, then placed into numerical models to better understand Earth's formation history. Here, we have mathematically characterized the HP?HT partitioning of copper, combined this with results for sulfur from literature, and input these characterizations into numerical models that track their distribution between Earth's core and mantle as it grows to its present mass. Copper and sulfur were chosen because they display different sensitivities to the physical mechanisms that govern planetary formation, and we can leverage this to better understand Earth's formation and differentiation history. Our results indicate that ~75% of Earth's precursor materials grew incrementally from relatively small bits of material ? on average ~0.1% of Earth's mass or less ? that is most compositionally similar to meteorite classes that are made up of iron?rich metal and silicate solids (chondrules) that are depleted in easily vaporized (volatile) elements, especially sulfur.
DS201804-0718
2017
Malecka, A.Naming of the Koh-i-Noor and the origin of Mughal-cut diamonds.Journal of Gemmology, Vol. 35, 8, pp. 738-751.Indiadiamonds notable - Koh-i-Noor

Abstract: For centuries, the Koh-i-Noor, or Mountain of Light, has been a diamond of exceptional renown in the East as well as in the West. Several legends circulate regarding this stone, and among these are tales of its origin and the way it received its name. This article attempts to verify the authenticity of these accounts and shows that the true origin of the diamond's name is connected to its appearance achieved through the faceting style known today as the Mughal cut. Although the provenance of this cut has thus far not been determined, this article proposes that it possibly originated in the 16th century in Goa, India, through the Gujaratis and under the influence of European diamond cutters. Various lines of evidence suggest that the Koh-i-Noor may have been worked in the 16th century by an Indian specialist in the Vijayanagara Empire.
DS201801-0036
2017
Malierova, P., Schulmann, K., Gerya, T.Relamination styles in collisional orogens.Tectonics, in press availableMantlesubduction

Abstract: During continental collision, a part of the lower-plate material can be subducted, emplaced at the base of the upper plate, and eventually incorporated into its crust. This mechanism of continental-crust transformation is called relamination and it has been invoked to explain occurrences of high-pressure felsic rocks in different structural positions of several orogenic systems. In the present study we reproduced relamination during continental collision in a thermo-mechanical numerical model. We performed a parametric study and distinguished three main types of evolution regarding the fate of the subducted continental crust: (i) return along the plate interface in a subduction channel or wedge, (ii) flow at the bottom of the upper-plate lithosphere and subsequent trans-lithospheric exhumation near the arc or in the back-arc region ("sub-lithospheric relamination"), and (iii) nearly horizontal flow directly into the upper-plate crust ("intra-crustal relamination"). Sub-lithospheric relamination is preferred for relatively quick convergence of thin continental plates. An important factor for the development of sub-lithospheric relamination is melting of the subducted material, which weakens the lithosphere and opens a path for the exhumation of the relaminant. In contrast, a thick and strong overriding plate typically leads to exhumation near the plate interface. If the overriding plate is too thin or weak, intra-crustal relamination occurs. We show that each of these evolution types has its counterpart in nature: (i) the Alps and the Caledonides, (ii) the Himalayan-Tibetan system and the European Variscides, and (iii) pre-Cambrian ultra-hot orogens.
DS201802-0251
2017
Malov, A.I., Sidkina, E.S., Ryzhenko, B.N.Model of the Lomonosov diamond deposit as a water rock system: migration species, groundwater saturation with rock forming and ore minerals, and ecological assessment of water quality.Geochemistry International, Vol. 55, 12, pp. 1118-1130.Russiadeposit - Lomonosov

Abstract: Thermodynamic numerical simulations were carried out to determine the principal simple and complex migration species of Ca, Mg, Na, K, Al, B, Mn, Mo, Sr, and U with Cl-, OH-, SO4?2, HCO3?, and CO32? in waters at the Lomonosov diamond deposit and to estimate the saturation indexes with respect to kaolinite, Na- and Mg-montmorillonite, Mg- and Na-saponite, muscovite and paragonite, biotite, phlogopite, chromite, pyrite, plagioclase (anorthite, labradorite, and andesine), olivine (forsterite and fayalite), diopside, pyrope, gypsum, anhydrite, barite, magnesite, calcite, dolomite, talc, chrysotile, chlorite, goethite, quartz, microcline, and albite. The waters are proved not to be saturated with respect to the primary (hydrothermal) minerals. The saturation of certain water samples with uranophane suggests that this mineral is of secondary genesis. The ascent of highly mineralized deep waters shall result in the dissolution of minerals whose concentrations are near the saturation ones. To maintain the ecological standards of the discharged waters, they should be diluted and/or purified by adsorbing dissolved U on a reducing reactive barrier.
DS201807-1511
2018
Manning, C.E.Fluids of the lower crust: deep is different.Annual Review of Earth and Planetary Sciences, Vol. 46, pp. 67-97.Mantlecore, boundary

Abstract: Deep fluids are important for the evolution and properties of the lower continental and arc crust in tectonically active settings. They comprise four components: H2O, nonpolar gases, salts, and rock-derived solutes. Contrasting behavior of H2O-gas and H2O-salt mixtures yields immiscibility and potential separation of phases with different chemical properties. Equilibrium thermodynamic modeling of fluid-rock interaction using simple ionic species known from shallow-crustal systems yields solutions too dilute to be consistent with experiments and resistivity surveys, especially if CO2 is added. Therefore, additional species must be present, and H2O-salt solutions likely explain much of the evidence for fluid action in high-pressure settings. At low salinity, H2O-rich fluids are powerful solvents for aluminosilicate rock components that are dissolved as polymerized clusters. Addition of salts changes solubility patterns, but aluminosilicate contents may remain high. Fluids with Xsalt = 0.05 to 0.4 in equilibrium with model crustal rocks have bulk conductivities of 10?1.5 to 100 S/m at porosity of 0.001. Such fluids are consistent with observed conductivity anomalies and are capable of the mass transfer seen in metamorphic rocks exhumed from the lower crust.
DS201812-2848
2018
Mao, W, Zhong, S.Slab stagnation in the transition zone is explained by a thin, weak layer and is transient on timescales of tens or millions of years, according to a global mantle convection model that includes phase changes and plate motion.Nature Geoscience, doi:10.038/s41561-018-0225-2 (pp. 876-881.)Mantleconvection

Abstract: The linear structures of seismically fast anomalies, often interpreted as subducted slabs, in the southern Asia and circum-Pacific lower mantle provided strong evidence for the whole mantle convection model. However, recent seismic studies have consistently shown that subducted slabs are deflected horizontally for large distances in mantle transition zone in the western Pacific and other subduction zones, suggesting that the slabs meet significant resistance to their descending motion and become stagnant in the transition zone. This poses challenges to the whole mantle convection model and also brings the origin of stagnant slabs into question. Here, using a global mantle convection model with realistic spine-post-spinel phase change (?2 MPa K?¹ Clapeyron slope) and plate motion history, we demonstrate that the observed stagnant slabs in the transition zone and other slab structures in the lower mantle can be explained by the presence of a thin, weak layer at the phase change boundary that was suggested by mineral physics and geoid modelling studies. Our study also shows that the stagnant slabs mostly result from subduction in the past 20-30 million years, confirming the transient nature of slab stagnation and phase change dynamics on timescales of tens of millions of years from previous studies.
DS201809-2067
2018
Mao, W.L., Liu, J., Hu, Q.Hydrogen bearing iron peroxide in Earth's lowermost mantle.Goldschmidt Conference, 1p. AbstractMantleWater

Abstract: How water cycles through the Earth's interior, presumably is of fundamental importance for understanding the evolution of our planet. The presence of even trace amounts of water (or hydrogen) can dramatically affect many physical and chemical properties of Earth materials, such as phase stability conditions, viscosity, thermal conductivity, etc. Here, we report that the reaction between water and iron to form a pyrite-structured hydrogen-bearing iron peroxide, FeO2Hx (with x = 0 to 1), under the pressure-temperature conditions relevant to the Earth’s deep lower mantle. Combined with theoretical calculations and high-pressure experiments using laser-heated diamond anvil cells coupled with a suite of insitu and characterization techniques (e.g. nuclear resonant inelastic X-ray scattering spectroscopy, X-ray absorption spectroscopy, and X-ray diffraction), we find that this extremely oxygen-rich form of iron peroxide has properties consistent with ultralow velocity zones that are seismically observed at the core-mantle boundary. This phase may also have implications for deep volatile cycling and mantle redox.
DS201806-1234
2018
Maquire, R., Ritsema, J., Bonnin, M., van Keken, P.E., Goes, S.Evaluating the resolution of deep mantle plumes in teleseismic traveltime tomography.Journal of Geophysical Research, Vol. 123, 1. pp. 384-400.Mantlegeophysics - seismic

Abstract: The strongest evidence to support the classical plume hypothesis comes from seismic imaging of the mantle beneath hot spots. However, imaging results are often ambiguous and it is questionable whether narrow plume tails can be detected by present?day seismological techniques. Here we carry out synthetic tomography experiments based on spectral element method simulations of seismic waves with period T > 10 s propagating through geodynamically derived plume structures. We vary the source?receiver geometry in order to explore the conditions under which lower mantle plume tails may be detected seismically. We determine that wide?aperture (4,000-6,000 km) networks with dense station coverage (<100-200 km station spacing) are necessary to image narrow (<500 km wide) thermal plume tails. We find that if uncertainties on traveltime measurements exceed delay times imparted by plume tails (typically <1 s), the plume tails are concealed in seismic images. Vertically propagating SKS waves enhance plume tail recovery but lack vertical resolution in regions that are not independently constrained by direct S paths. We demonstrate how vertical smearing of an upper mantle low?velocity anomaly can appear as a plume originating in the deep mantle. Our results are useful for interpreting previous plume imaging experiments and guide the design of future experiments.
DS201802-0252
2017
Marchenko, E.I., Eremin, N.N., Bychkov, A.Y., Grechanovskii, A.E.Ca and Mg perovskite phases in the Earth's mantle as a probable reservoir of Al: computer simulated evidence.Moscow University Geology Bulletin, Vol. 72, 5, pp. 299-304.Mantleperovskite

Abstract: Semi-empirical and quantum chemical studies of Al atom energy in CaSiO3 and MgSiO3 with the perovskite-type structure at pressures and temperatures of the Earth’s mantle are reported. The phase diagram for CaSiO3 is reproduced and refined. Probable mechanisms of Al incorporation in the structures studied are considered. According to the results of the calculations, Al is preferably incorporated into MgSiO3, rather than into CaSiO3. Evaluation of the isomorphic capacity of perovskite phases in relation to Al shows that the Al content in MgSiO3 may reach 2.4 mol % at 120 GPa and 2400 K. CaSiO3 cannot be a source of Al atoms in the Earth’s mantle.
DS201807-1512
2018
Marien, C., Dukstra, A.H., Wilkins, C.The hydrothermal alteration of carbonatite in the Fen complex, Norway: mineralogy, geochemistry and implications for rare earth element resource formation.Mineralogical Magazine Open access special publication Critical metal mineralogy and ore genesis, Vol. 82 (S1) pp. S115-S131.Europe, Norwaycarbonatite

Abstract: The Fen Complex in Norway consists of a ~583 Ma composite carbonatite-ijolite-pyroxenite diatreme intrusion. Locally, high grades (up to 1.6 wt.% total REE) of rare-earth elements (REE) are found in a hydrothermally altered, hematite-rich carbonatite known as rødbergite. The progressive transformation of primary igneous carbonatite to rødbergite was studied here using scanning electron microscopy and inductively coupled plasma-mass spectrometry trace-element analysis of 23 bulk samples taken along a key geological transect. A primary mineral assemblage of calcite, dolomite, apatite, pyrite, magnetite and columbite with accessory quartz, baryte, pyrochlore, fluorite and REE fluorocarbonates was found to have transformed progressively into a secondary assemblage of dolomite, Fe-dolomite, baryte, Ba-bearing phlogopite, hematite with accessory apatite, calcite, monazite-(Ce) and quartz. Textural evidence is presented for REE fluorocarbonates and apatite breaking down in igneous carbonatite, and monazite-(Ce) precipitating in rødbergite. The importance of micro-veins, interpreted as feeder fractures, containing secondary monazite and allanite, is highlighted. Textural evidence for included relics of primary apatite-rich carbonatite are also presented. These acted as a trap for monazite-(Ce) precipitation, a mechanism predicted by physical-chemical experiments. The transformation of carbonatite to rødbergite is accompanied by a 10-fold increase in REE concentrations. The highest light REE (LREE) concentrations are found in transitional vein-rich rødbergite, whereas the highest heavy REE (HREE) and Th concentrations are found within the rødbergites, suggesting partial decoupling of LREE and HREE due to the lower stability of HREE complexes in the aqueous hydrothermal fluid. The hydrothermal fluid involved in the formation of rødbergite was oxidizing and had probably interacted with country-rock gneisses. An ore deposit model for the REE-rich rødbergites is presented here which will better inform exploration strategies in the complex, and has implications for carbonatite-hosted REE resources around the world.
DS201803-0463
2017
Maringira, G., Nyamunda, T.Duty versus agency in the security state of Zimbabwe: soldiers deployment in Chiadzwa diamond mining.The Extractive Industries and Society, Vol. 4, pp. 172-179.Africa, Zimbabweartisanal mining

Abstract: The deployment of soldiers’ in diamond mining areas in Zimbabwe is beginning to receive much scholarly attention, partly because scholars researching on such issues are mainly driven by the meta-narratives of ‘artisanal miners’, popularly known as "magweja" in the Zimbabwean context. In many cases soldiers are presented as perpetrators of violence within deployed areas, with magweja and villagers, as victims of military deployment. While this is not untrue, this article explores the ways in which soldiers developed mutual relationships with magweja, friendships and interactions with villagers, including sexual relationships in the communities surrounding the diamond area. However, we assert that these relationships were always implicitly characterised by unequal power dynamics in which the authority of deployed soldiers was ominously present and fear sometimes informed the actions of villagers. Soldiers’ power was always materially represented by the authority vested in them by a powerful demagogic state. It was visibly represented through their combat uniforms, and the gun as part of their daily standing orders, including other soldiering routines such as patrols, and guard duties. We argue that even beyond these circumscribed conditions of relations building, the people behind the combat uniforms had their own agencies that never always resonated with that of the state. Their actions were informed by the chain of command and the consequences wrought by failing to abide by standing orders. In this article, we illuminate those hidden narratives and expose the manner in which the dictatorial state instrumentalises its armed forces despite the disparate personal agencies of those soldiers which are suppressed by the very nature of military service. The paper is based on interviews with soldiers, "magweja" and villagers.
DS201804-0719
2018
Marquardt, K., Faul, U.H.The structure and composition of olivine grain boundaries: 40 years of studies, status and current developments.Physics and Chemistry of Minerals, Vol. 45, 2, pp. 139-172.Mantleolivines

Abstract: Interfaces in rocks, especially grain boundaries in olivine dominated rocks, have been subject to about 40 years of studies. The grain boundary structure to property relation is fundamental to understand the diverging properties of polycrystalline samples compared to those of single crystals. The number of direct structural observations is small, i.e. in range of 100 micrographs, and the number of measurements of properties directly linked to structural observations is even smaller. Bulk aggregate properties, such as seismic attenuation, rheology and electrical conductivity, are sensitive to grain size, and seem to show influences by grain boundary character distributions. In this context we review previous studies on grain boundary structure and composition and plausible relations to bulk properties. The grain boundary geometry is described using five independent parameters; generally, their structural width ranges between 0.4-1.2 nm and the commonly used 1 nm seems a good approximation. This region of enhanced disorder is often enriched in elements that are incompatible in the perfect crystal lattice. The chemical composition of grain boundaries depends on the bulk rock composition. We determined the 5 parameter grain boundary character distribution (GBCD) for polycrystaline Fo90 and studied structure and chemistry at the nm-scale to extend previous measurements. We find that grain boundary planes close to perpendicular to the crystallographic c-direction dominate the grain boundary network. We conclude that linking grain boundary structure in its full geometric parameter space to variations of bulk rock properties is now possible by GBCD determination using EBSD mapping and statistical analyses.
DS201803-0464
2017
Marshall, E.W., Barnes, J.D., Lassiter, J.C.The role of serpentinite derived fluids in metasomatism of the Colorado Plateau ( USA) lithospheric mantle.Geology, Vol. 45, 12, pp. 1103-1106.United States, Colorado Plateausubduction

Abstract: Subducting serpentinized lithosphere has distinct ?D and ?18O values compared to normal mantle. Slab-derived fluids that infiltrate the mantle wedge can alter its oxygen and hydrogen isotope composition, raising or lowering the ?18O and ?D values depending on the nature of the subducted components. Hydrous minerals in peridotite xenoliths from the Colorado Plateau (southwestern USA) have ?D values (up to ?33‰) much higher than average mantle (?80‰), but similar to ?D values of olivine-hosted melt inclusions within arc basalts, suggesting a slab-derived fluid source. Oxygen isotope ratios of olivine from these xenoliths are similar to average mantle, yet display a strong negative correlation with clinopyroxene Ce/Sm, a proxy of metasomatism. This correlation is most simply explained by metasomatism from fluids derived from the serpentinized portion of the Farallon slab. Although ?18O values of mantle minerals span a narrow range, integration of stable isotope data with other geochemical tracers can provide new constraints on modern and ancient subduction-related processes, potentially providing a method for probing Archean lithospheric mantle for evidence of early subduction.
DS201810-2352
2018
Marshall, E.W., Lasiter, J.C., Barnes, J.D.On the (mis) behavior of water in the mantle: controls on nominally anhydrous mineral water content in mantle peridotites.Earth and Planetary Science Letters, Vol. 499, pp. 219-229.United States, Colorado Plateaumetasomatism

Abstract: In magmatic settings, water behaves as an incompatible species and should be depleted during melting and enriched during metasomatism. Previous studies have identified correlations between nominally anhydrous mineral (NAM) water content ([H2O]) and indices of metasomatism or melt extraction, seemingly confirming this behavior in the mantle. However in detail, these correlations are ambiguous and do not reflect robust controls on NAM [H2O]. We measured orthopyroxene (opx) and clinopyroxene (cpx) [H2O] in variably hydrated and metasomatized peridotite xenoliths from the Navajo volcanic field (NVF) that sample the Colorado Plateau subcontinental lithospheric mantle (SCLM), an endmember of SCLM hydration and metasomatism. These xenoliths span a wide range of pyroxene [H2O] (opx from 50 to 588 ppm wt. H2O; cpx from 38 to 581 ppm wt. H2O), but NAM [H2O] does not correlate with either indices of melt depletion or metasomatism. Growth of hydrous minerals suggests higher water activity than in anhydrous peridotites, and therefore hydrous-mineral-bearing xenoliths and anhydrous xenoliths should have different NAM [H2O] and water activities. However, when the two groups are compared no significant differences can be found in either NAM [H2O] or water activity. We propose that the high diffusivity of hydrogen in the mantle allows for equilibration of water activity in the mantle over sub-kilometer length scales over geologic time. Such diffusive equilibration reduces water activity variability and results in the blurring and destruction of correlations between NAM [H2O] and indices of metasomatism or melt extraction. As a result of diffusive equilibration of water, there is a large difference in the variability of concentration between NAM [H2O] (spanning ?2 orders of magnitude) and similarly incompatible elements such as Ce in the same peridotites (spanning ?4 orders of magnitude). This difference in behavior explains why H2O/Ce ratios in mantle peridotites are highly variable relative to those of basalts.
DS201809-2068
2018
Marshall, E.W., Lassiter, J.C., Banes. J.B.Understanding the (mis) behaviour of water contents in nominally anhydrous mantle minerals.Goldschmidt Conference, 1p. AbstractMantleperidotites

Abstract: The H/C ratio in earth’s exosphere is higher than it is in the source region of primitive basalts, suggesting an enriched carbon reservoir in the mantle[1]. A plausible explanation is that subduction of carbon may have enriched the mantle in recycled carbon over time. Average basaltic crust contains ~ 2 wt.% CO2 [2], and modeling of slab devolatilisation suggests that subducted carbonate may survive to be transported deeper into the mantle [3]. Carbonated oceanic crust should melt in the transition zone along most subduction geotherms due to a deep trough in the carbonated basalt solidus, and mineral inclusions in superdeep diamonds testify to carbonate melt in their formation [4]. Along cool subduction geotherms carbonate may subduct into the lower mantle, potentially enriching the deep mantle in carbon. Here we report on laser-heated diamond anvil cell experiments in the CaO-MgO-SiO2-CO2 and FeO-MgO-SiO2-CO2 systems at lower mantle pressures where we investigate the stability of carbonate in oceanic crust, and test for decarbonation and diamond forming reactions involving carbonate and coexisiting free silica. We find that carbonate reacts with silica to form bridgmanite ± Ca-perovskite + CO2 at pressures in the range of ~50 to 70 GPa. These decarbonation reactions form an impenetrable barrier to subduction of carbonate into the deeper lower mantle, however, slabs may carry solid CO2 (Phase V) into the deeper lower mantle. We also identify reactions where carbonate or CO2 dissociate to form diamond plus oxygen. We suggest that the deep lower mantle may become enriched in carbon in the form of diamond over time due to subduction of carbonate and solid CO2 and its eventual dissociation to form diamond plus oxygen. Release of oxygen during diamond formation may also provide a mechanism for locally oxidizing the deep mantle.
DS201806-1235
2018
Marti, J., Groppelli, G., Brum da Silveira, A.Volcanic stratigraphy: a review.Journal of Volcanology and Geothermal Research, Vol. 357, pp. 68-91.Mantlevolcanism

Abstract: Volcanic stratigraphy is a fundamental component of geological mapping in volcanic areas as it yields the basic criteria and essential data for identifying the spatial and temporal relationships between volcanic products and intra/inter-eruptive processes (earth-surface, tectonic and climatic), which in turn provides greater understanding of the geological evolution of a region. Establishing precise stratigraphic relationships in volcanic successions is not only essential for understanding the past behaviour of volcanoes and for predicting how they might behave in the future, but is also critical for establishing guidelines for exploring economic and energy resources associated with volcanic systems or for reconstructing the evolution of sedimentary basins in which volcanism has played a significant role. Like classical stratigraphy, volcanic stratigraphy should also be defined using a systematic methodology that can provide an organised and comprehensive description of the temporal and spatial evolution of volcanic terrain. This review explores different methods employed in studies of volcanic stratigraphy, examines four case studies that use differing stratigraphic approaches, and recommends methods for using systematic volcanic stratigraphy based on the application of the concepts of traditional stratigraphy but adapted to the needs of volcanological environment.
DS201808-1767
2018
Martineau, P., McGuiness, C.De Beers consumer confidence technical research and diamond verification instruments ( synthetic diamonds and their detection). SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 28 ppts.Globalspectrometry
DS201807-1513
2018
Martineau, P.M., McGuinness, C.D.De Beers consumer confidence technical research and diamond verification instruments. Absorption spectrometry, crystal morphology, melee PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13. Presentation, pp. 35-44.Technologyspectrometry
DS201812-2849
2018
Martins, M.Carolina kimberlite and the exploration and potential of the Pimenta Bueno diamond District, Rondonia, Brazil.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Rondoniadeposit - Carolina
DS201811-2593
2018
Martos, Y.M., Jordan, T.A., Catalan, M., Jordan, T.M., Bamber, J.L., Vaughan, D.G.Geothermal heat flux reveals the Iceland hotspot track underneath Greenland.Geophysical Research Letters, Vol. 45, 16, pp. 8214-8222.Europe, Greenlandplumes

Abstract: Heat escaping from the Earth's interior provides important clues about areas of geology and geodynamics. In addition, where a region is covered by an ice sheet, such as Greenland, variations in the heat supplied from the Earth's interior can potentially influence how the ice flows, and hence its future changes. Unfortunately, in ice covered regions direct measurements of heat flow are limited to sparse boreholes, meaning this important quantity is poorly understood. In this study we used variations in the Earth's magnetic field to map out the variations in the amount of heat being supplied to the base of the Greenland Ice Sheet from the Earth's interior. Ice sheet models incorporating these new and improved results will help better constrain future predictions of ice sheet evolution. Overall, the new map not only shows less extreme variations than previous studies, but also reveals a previously unseen band of warmer than expected rock stretching northwest to southeast across Greenland. This band, together with lithospheric models derived from gravity data, is interpreted to be the scar left as the Greenland tectonic plate moved over a region of hot upwelling mantle (the material beneath the tectonic plates), which now underlies Iceland.
DS201810-2353
2018
Matias, M.M.A., vander Neut, J.Marchenko imaging by unidimensional deconvolution.Geophysical Prospecting, doi.10.111/1365-2478.12686Mantlegeophysics

Abstract: Obtaining an accurate image of the subsurface still remains a great challenge for the seismic method. Migration algorithms aim mainly on positioning seismic events in complex geological contexts. Multiple reflections are typically not accounted for in this process, which can lead to the emergence of artefacts. In Marchenko imaging, we retrieve the complete up? and downgoing wavefields in the subsurface to construct an image without such artefacts. The quality of this image depends on the type of imaging condition that is applied. In this paper, we propose an imaging condition that is based on stabilized unidimensional deconvolution. This condition is computationally much cheaper than multidimensional deconvolution, which has been proposed for Marchenko imaging earlier. Two specific approaches are considered. In the first approach, we use the full up? and downgoing wavefields for deconvolution. Although this leads to balanced and relatively accurate amplitudes, the crosstalk is not completely removed. The second approach is to incorporate the initial focussing function in the deconvolution process, in such a way that the retrieval of crosstalk is avoided. We compare images with the results of the classical cross?correlation imaging condition, which we apply to reverse?time migrated wavefields and to the up? and downgoing wavefields that are retrieved by the Marchenko method.
DS201809-2072
2018
Matthews, S., Shorttle, O., Maclennan, J., Rudge, J.F., Miller, W.G.R.Can we detect carbon rich mantle reservoirs?Goldschmidt Conference, 1p. AbstractMantlecarbon

Abstract: The Earth’s surface inventory of carbon is critical for maintaining the planet’s habitability, yet the majority of Earth’s carbon is likely sequestered in the solid Earth. Understanding how Earth’s shallow carbon cycle evolved requires an assesment of the total carbon accreted, how it was distributed between Earth’s reservoirs, and how these reservoirs continue to exchange carbon. The low carbon content of Earth’s depleted upper mantle has been well constrained by primitive olivine hosted melt inclusions and the CO2/3He ratios of magmatic fluids. Using mass balance constraints we show that either the lower mantle is considerably more carbon rich, or the Earth has lost much of its initial carbon inventory. Distinguising between these scenarios is crucial for understanding the development and maintenance of Earth’s shallow carbon cycle. We assess the carbon content of the lower mantle using new melt inclusion datasets from Iceland, sampling both primordial and recycled mantle material. By comparing carbon concentrations with lithophile element concentrations we find evidence that carbon rich material is transported in the Iceland plume. Furthermore, we demonstrate that such datasets provide only a low bound on the true carbon content of the lower mantle, due to fundamental limits imposed by magma mixing, degassing and inclusion decrepitation. Using a global compilation of melt inclusion analyses we argue these processes occur ubiquitously and are likely to limit our ability to robustly resolve high mantle carbon using melt inclusion datasets. By combining these observations with global mass balance constraints we derive new estimates of the carbon content of primordial and recycled mantle material.
DS201805-0961
2018
Mattsson, H.B., Balashova, A., Almqvist, S.A., Bosshard-Stadlin, S.A., Weidendorfer, D.Magnetic mineralogy and rock properties of silicate and carbonatite rocks from Oldoinyo Lengai volcano (Tanzania).Journal of African Earth Sciences, Vol. 142, pp. 193-206.Africa, Tanzaniadeposit - Oldoinyo Lengai

Abstract: Oldoinyo Lengai, a stratovolcano in northern Tanzania, is most famous for being the only currently active carbonatite volcano on Earth. The bulk of the volcanic edifice is dominated by eruptive products produced by silica-undersaturated, peralkaline, silicate magmas (effusive, explosive and/or as cumulates at depth). The recent (2007-2008) explosive eruption produced the first ever recorded pyroclastic flows at this volcano and the accidental lithics incorporated into the pyroclastic flows represent a broad variety of different rock types, comprising both extrusive and intrusive varieties, in addition to various types of cumulates. This mix of different accidental lithics provides a unique insight into the inner workings of the world's only active carbonatite volcano. Here, we focus on the magnetic mineralogy and the rock magnetic properties of a wide selection of samples spanning the spectrum of Oldoinyo Lengai rock types compositionally, as well from a textural point of view. Here we show that the magnetic properties of most extrusive silicate rocks are dominated by magnetite-ulvöspinel solid solutions, and that pyrrhotite plays a larger role in the magnetic properties of the intrusive silicate rocks. The natrocarbonatitic lavas, for which the volcano is best known for, show distinctly different magnetic properties in comparison with the silicate rocks. This discrepancy may be explained by abundant alabandite crystals/blebs in the groundmass of the natrocarbonatitic lavas. A detailed combination of petrological/mineralogical studies with geophysical investigations is an absolute necessity in order to understand, and to better constrain, the overall architecture and inner workings of the subvolcanic plumbing system. The results presented here may also have implications for the quest in order to explain the genesis of the uniquely natrocarbonatitic magmas characteristic of Oldoinyo Lengai.
DS201809-2070
2018
McCoy-West, A.J., Fitton, J.G., Pons, M-L., Inglis, E.C., Williams, H.M.The Fe and Zn isotope composition of deep mantle source regions: insight from Baffin Island picrites.Geochimica et Cosmochimica Acta, Vol. 238, pp. 542-562.Canada, Nunavut, Baffin Islandpicrites

Abstract: Young (61?Ma) unaltered picrites from Baffin Island, northeast Canada, possess some of the highest 3He/4He (up to 50?Ra) seen on Earth, and provide a unique opportunity to study primordial mantle that has escaped subsequent chemical modification. These high-degree partial melts also record anomalously high 182W/184W ratios, but their Sr-Nd-Hf-Pb isotopic compositions (including 142Nd) are indistinguishable from those of North Atlantic mid-ocean ridge basalts. New high precision Fe and Zn stable isotope analyses of Baffin Island picrites show limited variability with ?56Fe ranging from ?0.03‰ to 0.13‰ and ?66Zn varying from 0.18‰ to 0.28‰. However, a clear inflection is seen in both sets of isotope data around the composition of the parental melt (MgO?=?21?wt%; ?56Fe?=?0.08?±?0.04‰; and ?66Zn?=?0.24?±?0.03‰), with two diverging trends interpreted to reflect the crystallisation of olivine and spinel in low-MgO samples and the accumulation of olivine at higher MgO. Olivine mineral separates are significantly isotopically lighter than their corresponding whole rocks (?56Fe????0.62‰ and ?66Zn????0.22‰), with analyses of individual olivine phenocrysts having extremely variable Fe isotope compositions (?56Fe?=??0.01‰ to ?0.80‰). By carrying out modelling in three-isotope space, we show that the very negative Fe isotope compositions of olivine phenocryst are the result of kinetic isotope fractionation from disequilibrium diffusional processes. An excellent correlation is observed between ?56Fe and ?66Zn, demonstrating that Zn isotopes are fractionated by the same processes as Fe in simple systems dominated by magmatic olivine. The incompatible behaviour of Cu during magmatic evolution is consistent with the sulfide-undersaturated nature of these melts. Consequently Zn behaves as a purely lithophile element, and estimates of the bulk Earth Zn isotope composition based on Baffin Island should therefore be robust. The ancient undegassed lower mantle sampled at Baffin Island possesses a ?56Fe value that is within error of previous estimates of bulk mantle ?56Fe, however, our estimate of the Baffin mantle ?66Zn (0.20?±?0.03‰) is significantly lower than some previous estimates. Comparison of our new data with those for Archean and Proterozoic komatiites is consistent with the Fe and Zn isotope composition of the mantle remaining constant from at least 3?Ga to the present day. By focusing on large-degree partial melts (e.g. komatiites and picrites) we are potenitally biasing our record to samples that will inevitably have interacted with, entrained and melted the ambient shallow mantle during ascent. For a major element such as Fe, that will continuosly participate in melting as it rises through the mantle, the final isotopic compositon of the magama will be a weighted average of the complete melting column. Thus it is unsuprising that minimal Fe isotope variations are seen between localities. In contrast, the unique geochemical signatures (e.g. He and W) displayed by the Baffin Island picrites are inferred to solely originate from the lowermost mantle and will be continuously diluted upon magma ascent.
DS201801-0037
2018
McCubbing, M.Using diamond characterization to refine micro and macro processing and recovery.Vancouver Kimberlite Cluster , 1p. AbstractTechnologydiamond recovery
DS201805-0962
2018
McDannell, K.T., Zeitler, P.K., Schneider, D.A.Instability of the southern Canadian Shield during the late Proterozoic.Earth Planetary Science Letters, Vol. 490, pp. 100-109.Canadacraton

Abstract: Cratons are generally considered to comprise lithosphere that has remained tectonically quiescent for billions of years. Direct evidence for stability is mainly founded in the Phanerozoic sedimentary record and low-temperature thermochronology, but for extensive parts of Canada, earlier stability has been inferred due to the lack of an extensive rock record in both time and space. We used 40Ar/39Ar multi-diffusion domain (MDD) analysis of K-feldspar to constrain cratonic thermal histories across an intermediate (~150-350°C) temperature range in an attempt to link published high-temperature geochronology that resolves the timing of orogenesis and metamorphism with lower-temperature data suited for upper-crustal burial and unroofing histories. This work is focused on understanding the transition from Archean-Paleoproterozoic crustal growth to later intervals of stability, and how uninterrupted that record is throughout Earth’s Proterozoic "Middle Age." Intermediate-temperature thermal histories of cratonic rocks at well-constrained localities within the southern Canadian Shield of North America challenge the stability worldview because our data indicate that these rocks were at elevated temperatures in the Proterozoic. Feldspars from granitic rocks collected at the surface cooled at rates of <0.5°C/Ma subsequent to orogenesis, seemingly characteristic of cratonic lithosphere, but modeled thermal histories suggest that at ca. 1.1-1.0 Ga these rocks were still near ~200°C - signaling either reheating, or prolonged residence at mid-crustal depths assuming a normal cratonic geothermal gradient. After 1.0 Ga, the regions we sampled then underwent further cooling such that they were at or near the surface (<< 60°C) in the early Paleozoic. Explaining mid-crustal residence at 1.0 Ga is challenging. A widespread, prolonged reheating history via burial is not supported by stratigraphic information, however assuming a purely monotonic cooling history requires at the very least 5 km of exhumation beginning at ca. 1.0 Ga. A possible explanation may be found in evidence of magmatic underplating that thickened the crust, driving uplift and erosion. The timing of this underplating coincides with Mid-Continent extension, Grenville orogenesis, and assembly of the supercontinent Rodinia. 40Ar/39Ar MDD data demonstrate that this technique can be successfully applied to older rocks and fill in a large observational gap. These data also raise questions about the evolution of cratons during the Proterozoic and the nature of cratonic stability across deep time.
DS201810-2354
2018
McDannell, K.T., Zeitler, P.K., Schneider, D.A.Instability of the southern Canadian shield during the Late Proterozoic.researchgate.com, 29p. PdfCanadacraton

Abstract: Cratons are generally considered to comprise lithosphere that has remained tectonically quiescent for billions of years. Direct evidence for stability is mainly founded in the Phanerozoic sedimentary record and low-temperature thermochronology, but for extensive parts of Canada, earlier stability has been inferred due to the lack of an extensive rock record in both time and space. We used 40Ar/39Ar multi-diffusion domain (MDD) analysis of K-feldspar to constrain cratonic thermal histories across an intermediate (?150-350?°C) temperature range in an attempt to link published high-temperature geochronology that resolves the timing of orogenesis and metamorphism with lower-temperature data suited for upper-crustal burial and unroofing histories. This work is focused on understanding the transition from Archean-Paleoproterozoic crustal growth to later intervals of stability, and how uninterrupted that record is throughout Earth's Proterozoic “Middle Age.” Intermediate-temperature thermal histories of cratonic rocks at well-constrained localities within the southern Canadian Shield of North America challenge the stability worldview because our data indicate that these rocks were at elevated temperatures in the Proterozoic. Feldspars from granitic rocks collected at the surface cooled at rates of <0.5?°C/Ma subsequent to orogenesis, seemingly characteristic of cratonic lithosphere, but modeled thermal histories suggest that at ca. 1.1-1.0 Ga these rocks were still near ?200?°C - signaling either reheating, or prolonged residence at mid-crustal depths assuming a normal cratonic geothermal gradient. After 1.0 Ga, the regions we sampled then underwent further cooling such that they were at or near the surface (?60?°C) in the early Paleozoic. Explaining mid-crustal residence at 1.0 Ga is challenging. A widespread, prolonged reheating history via burial is not supported by stratigraphic information, however assuming a purely monotonic cooling history requires at the very least 5 km of exhumation beginning at ca. 1.0 Ga. A possible explanation may be found in evidence of magmatic underplating that thickened the crust, driving uplift and erosion. The timing of this underplating coincides with Mid-Continent extension, Grenville orogenesis, and assembly of the supercontinent Rodinia. 40Ar/39Ar MDD data demonstrate that this technique can be successfully applied to older rocks and fill in a large observational gap. These data also raise questions about the evolution of cratons during the Proterozoic and the nature of cratonic stability across deep time.
DS201810-2355
2018
McFarlane, M.J., Long, C.W., Coetzee, S.H.Lightning induced beads, 'fulguroids', associated with kimberlite eruptions in the Kalahari, Botswana.International Journal of Earth Sciences, Vol. 107, 7, pp. 2627-2633.Africa, Botswanakimberlites

Abstract: Glassy beads were found in the sand cover associated with known and suspected kimberlites on the Kalahari plateau, Botswana. Morphology and chemistry were examined by ESEM and EDAX. The polymetallic and quartzose "beads", here described for the first time and termed fulguroids, formed at very high temperatures, well in excess of those reached by the kimberlites. They solidified in free fall. We propose that they were melted in the atmosphere by lightning strikes on Kalahari overburden entrained when the kimberlites erupted.
DS201807-1514
2018
McKecknie, W.F.Diamond exploration and mining in southern Africa: some thoughts on past, current, and possible future trends.SAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 89-102.Africa, South Africahistory, economics

Abstract: Presentation: http://www.saimm.co.za/Conferences/Diamonds2018/P103-Pendock.pdf
DS201807-1515
2018
McKenzie, D.A geologist reflects on a long career. Plate tectonics, geotherms, convectionAnnual Review of Earth and Planetary Sciences, Vol. 46, pp. 1-20.Globalplate tectonics

Abstract: Fifty years ago Jason Morgan and I proposed what is now known as the theory of plate tectonics, which brought together the ideas of continental drift and sea floor spreading into what is probably their final form. I was twenty-five and had just finished my PhD. The success of the theory marked the beginning of a change of emphasis in the Earth sciences, which I have spent the rest of my career exploring. Previously geophysicists had principally been concerned with using ideas and techniques from physics to make measurements. But the success of plate tectonics showed that it could also be used to understand and model geological processes. This essay is concerned with a few such efforts in which I have been involved: determining the temperature structure and rheology of the oceanic and continental lithosphere, and with how mantle convection maintains the plate motions and the long-wavelength part of the Earth's gravity field. It is also concerned with how such research is supported.
DS201801-0038
2017
McKenzie, N.R.Evidence for a spike in mantle carbon outgassing during the Ediacaran period.Nature Geoscience, Vol. 10, 12, pp. 930-934.Mantlecarbonatite

Abstract: Long-term cycles in Earth’s climate are thought to be primarily controlled by changes in atmospheric CO2 concentrations. Changes in carbon emissions from volcanic activity can create an imbalance in the carbon cycle. Large-scale changes in volcanic activity have been inferred from proxies such as the age abundance of detrital zircons, but the magnitude of carbon emissions depends on the style of volcanism as well as the amount. Here we analyse U-Pb age and trace element data of detrital zircons from Antarctica and compare the results with the global rock record. We identify a spike in CO2-rich carbonatite and alkaline magmatism during the Ediacaran period. Before the Ediacaran, secular cooling of the mantle and the advent of cooler subduction regimes promoted the sequestration of carbon derived from decarbonation of subducting oceanic slabs in the mantle. We infer that subsequent magmatism led to the extensive release of carbon that may at least in part be recorded in the Shuram-Wonoka carbon isotope excursion. We therefore suggest that this pulse of alkaline volcanism reflects a profound reorganization of the Neoproterozoic deep and surface carbon cycles and promoted planetary warming before the Cambrian radiation.
DS201805-0963
2018
McKenzie, N.R., Smyre, A.J., Hedge, V.S., Stockli, D.F.Continental growth histories revealed by detrital zircon trace elements: a case study from India. Geology, Vol. 46, 3, pp. 275-278.Indiacraton

Abstract: Simultaneous acquisition of detrital zircon Pb-Pb ages and trace element abundances from grains collected across the Indian craton, spanning ?3 b.y., reveals prominent shifts in Eu/Eu* and light and middle to heavy rare earth element ratios. These shifts correspond to a ca. 3.0-2.2 Ga interval of crustal thickening during Indian craton formation, followed by a period wherein arc magmatism occurred along thinner craton margins from ca. 1.9 to 1.0 Ga, with arc magmatism concentrated along attenuated continental margins after ca. 1.0 Ga. Similar temporal shifts in trace element concentrations are recognized in global whole-rock compilations. We propose that the post-1.0 Ga increase in juvenile magmatism reflects a switch to lateral arc terrane accretion as the primary style of continental growth over the past billion years.
DS201812-2850
2018
McPeak, S., Samson, C., Lamontagne, M., Elliott, B.Application of passive seismic methodologies to the determination of overburden thickness.2018 Yellowknife Geoscience Forum , p. 111-112. abstractCanada, Northwest Territoriesgeophysics - seismics

Abstract: Diamond mining is central to the economic development of the Canadian North. Innovative methods are needed to identify new prospective targets, as many of them are hidden beneath a thick overburden of glacial sediments. Passive seismics is an emerging method used to map the thickness of near-surface geological layers. Vibrations from distant earthquakes are used as a source of signal and data is processed to estimate the depth of the interface between the overburden and the underlying bedrock. In July 2018, four Tromino seismographs were taken to a study site located approximately ten minutes driving north of Yellowknife. A total of 146 Tromino measurements and associated GPS elevation measurements were taken at 6 m intervals along a dirt road. Elevation measurements were averaged over the course of four days and the survey line was approximately 740 m long. Results indicated that depth to bedrock decreases near outcrops and increases in valleys however; another geophysical dataset is needed to validate the passive seismic data.
DS201804-0720
2018
Meinhold, G., Celal Sengor, A.M.A historical account of how continental drift and plate tectonics provided the framework for our current understanding of paleogeography.Geological Magazine, Mar. 19, 26p. PdfMantleplate tectonics

Abstract: Palaeogeography is the cartographic representation of the past distribution of geographic features such as deep oceans, shallow seas, lowlands, rivers, lakes and mountain belts on palinspastically restored plate tectonic base maps. It is closely connected with plate tectonics which grew from an earlier theory of continental drift and is largely responsible for creating and structuring the Earth's lithosphere. Today, palaeogeography is an integral part of the Earth sciences curriculum. Commonly, with some exceptions, only the most recent state of research is presented; the historical aspects of how we actually came to the insights which we take for granted are rarely discussed, if at all. It is remarkable how much was already known about the changing face of the Earth more than three centuries before the theory of plate tectonics, despite the fact that most of our present analytical tools or our models were unavailable then. Here, we aim to present a general conspectus from the dawn of ‘palaeogeography’ in the 16th century onwards. Special emphasis is given to innovative ideas and scientific milestones, supplemented by memorable anecdotes, which helped to advance the theories of continental drift and plate tectonics, and finally led to the establishment of palaeogeography as a recognized discipline of the Earth sciences.
DS201807-1516
2018
Mervine, E.M., Wilson, S.A., Power, I.M., Dipple, G.M., Turvey, C.C., Hamilton, J.L., Vanderzee, S., Raudsepp, M., Southam, C., Matter, J.M., Kelemen, P.B., Stiefenhofer, J., Miya, Z., Southam, G.Potential for offsetting diamond mine carbon emissions through mineral carbonation of processed kimberlite: an assessment of De Beers mine sites in South Africa and Canada.Mineralogy and Petrology, 10.1007/ s00710-018- 0589-4, 14p.Africa, South Africa, Canada, Northwest Territories, Ontariodeposit - Venetia, Voorspoed, Gahcho Kue, Victor, Snap Lake

Abstract: De Beers kimberlite mine operations in South Africa (Venetia and Voorspoed) and Canada (Gahcho Kué, Victor, and Snap Lake) have the potential to sequester carbon dioxide (CO2) through weathering of kimberlite mine tailings, which can store carbon in secondary carbonate minerals (mineral carbonation). Carbonation of ca. 4.7 to 24.0 wt% (average?=?13.8 wt%) of annual processed kimberlite production could offset 100% of each mine site’s carbon dioxide equivalent (CO2e) emissions. Minerals of particular interest for reactivity with atmospheric or waste CO2 from energy production include serpentine minerals, olivine (forsterite), brucite, and smectite. The most abundant minerals, such as serpentine polymorphs, provide the bulk of the carbonation potential. However, the detection of minor amounts of highly reactive brucite in tailings from Victor, as well as the likely presence of brucite at Venetia, Gahcho Kué, and Snap Lake, is also important for the mineral carbonation potential of the mine sites.
DS201810-2356
2018
Mining News DigestSwiss scientists developing method to detect low-temperature heated rubies from Mozambique. Montepurezmining.com, Sept. 13, 2p.Africa, Mozambiqueruby
DS201802-0253
2018
Mitchell, A.Popa Loimye Arc, correlations with Tibet, and alluvial diamonds in Myanmar.Geological Belts, Plate Boundaries, and Mineral Deposits in Myanmar., Chapter 17, pp. 473-483.Asia, Myanmaralluvial diamonds
DS201809-2071
2018
Mitton, S., Iddon, F.History of deep carbon science.Goldschmidt Conference, 1p. AbstractMantlecarbon

Abstract: Deep carbon is terrestrial carbon that is not in the atmosphere or oceans or on the surface. We have a great deal of knowledge about the properties of nearsurface carbon, but relatively little is known about the deep carbon cycle. The Deep Carbon Observatory, was founded in 2009, to address major questions about deep carbon. Where are the reservoirs of carbon? Is there significant carbon flux between the deep interior and the surface? What is deep microbial life? Did deep organic chemistry have a role in the origin of life? This project is directed toward documenting and describing of the history of deep carbon science. The narrative begins in 1601, when William Gilbert suggested that Earth’s interior behaves like a giant bar magnet. We trace across three centuries the slow evolution of thought that led to the establishment of the interdisciplinary field of Earth System Science. The concept and then development of the deep carbon cycle of burial and exhumation dates back at least two hundred years. We identify and document the key discoveries of deep carbon science, and assess the impact of this new knowledge on geochemistry, geodynamics, and geobiology. A History of Deep Carbon Science is in preparation for publication by Cambridge University Press in 2019. Its illuminating narrative highlights the engaging human stories of many remarkable researchers who have discovered the complexity and dynamics of Earth’s interior.
DS201804-0721
2018
Moller, V., Williams-Jones, A.E.A hyper spectral study ( V-NIR-SWIR) of the Nechalacho REE-Nb_Zr deposit Canada. Thor lakeJournal of Geochemical Exploration, Vol. 188, pp. 194-215.Canada, Northwest Territoriesrare earths

Abstract: The Canadian Nechalacho rare metal deposit (Thor Lake, Northwest Territories) contains one of the of the world's largest high-grade resources of rare earth elements (REE) and a large niobium (Nb) resource (Avalon Rare Metals Inc., 2013). The deposit formed mainly by magmatic accumulation of eudialyte (a complex REE-Nb-zirconosilicate) at the top of a > 1.1 km deep and ~2 km diameter layered nepheline-sodalite syenite intrusion, the Nechalacho Layered Suite. The strongest enrichment of REE and Nb is contained in the eudialyte cumulates of the Basal Zone layer. However, a strong hydrothermal overprint modified the eudialyte cumulate layers and their host rocks to produce a variety of hydrothermal silicates and REE-Nb minerals. The primary objective of this study is to evaluate the spatial distribution of the alteration minerals and identify possible mineral zoning.
DS201806-1236
2018
Molnar, N.E., Cruden, a.R., Betts, P.G.Unzipping continents and the birth of microcontinents.Geology, Vol. 46, 5, pp. 451-454.Mantlegeodynamics

Abstract: Microcontinents occur outboard of passive margins and stranded in ocean basins. Three-dimensional analogue laboratory experiments of continental rifting demonstrate that microcontinent formation at passive margins requires a combination of preexisting linear weaknesses in the lithosphere and rotational extension. Our results suggest that separation of microcontinents from passive margins occurs during the latest stages of continental breakup, before the onset of seafloor spreading, and that preexisting lithospheric weaknesses are a first-order control on where they form. These findings suggest that microcontinent formation may be restricted to localized regions along passive margins associated with zones of lithospheric weakness, providing a new structural and tectonic framework for the interpretation of microcontinents in the geological record.
DS201808-1768
2018
Moodley, T.Road mapping the digital transformation. Extracting the full benefit from source to use.SAIMM Diamonds - source to use 2018 Conference 'thriving in changing tmes'. June 11-13., 16 ppts.Globaleconomics
DS201812-2851
2018
Moss, S., Marten, B.E., Felgate, M., Smith, C.B., Chimuka, L., Matchan, E.L., Phillips, D.Murowa deposit: Geology, structure and radiometric age determination of the Murowa kimberlites, Zimbabwe.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 379-402.Africa, Zimbabwedeposit - Murowa
DS201812-2852
2018
Moss, S., Porritt, L., Pollock, K., Fomradas, G., Stubley, M., Eichenberg, D., Cutts, J.Diavik deposit: Geology, mineral chemistry, and structure of the kimberlites at Diavik diamond mine: indicators of cluster-scale cross-fertilization, mantle provenance, and pipe morphology.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 287-318.Canada, Northwest Territoriesdeposit - Diavik
DS201810-2357
2018
Moss, S.W., Kobussen, A., Powell, W., Pollock, K.Kimberlite emplacement and mantle sampling through time at A154N kimberlite volcano, Diavik Diamond mine: lessons from the deep.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0630-7 14p.Canada, Northwest Territoriesdeposit - Diavik

Abstract: The Diavik Diamond Mine in the NWT of Canada has produced in excess of 100 million carats from 3 kimberlite pipes since mining commenced in 2002. Here, we present new findings from deep (>400 m below surface) mining, sampling and drilling work in the A154N kimberlite volcano that require a revision of previous geological and emplacement models and provide a window into how the sub-continental lithospheric mantle (SCLM) below Diavik was sampled by kimberlite magmas through time. Updated internal geological models feature two volcanic packages interpreted to represent two successive cycles of explosive eruption followed by active and passive sedimentation from a presumed crater-rim, both preceded and followed by intrusions of coherent kimberlite. Contact relationships apparent among the geological units allow for a sequential organization of as many as five temporally-discrete emplacement events. Representative populations of mantle minerals extracted from geological units corresponding to four of the emplacement events at A154N are analyzed for major and trace elements, and provide insights into the whether or not kimberlites randomly sample from the mantle. Two independent geothermometers using clinopyroxene and garnet data indicate similar source depths for clinopyroxenes and G9 garnets (130-160 km), and suggest deeper sampling with time for both clinopyroxene and garnets. Harzburgite is limited to 110-160 km, and appears more prevalent in early, low-volume events. Variable ratios of garnet parageneses from the same depth horizons suggest random sampling by passing magmas, but deeper garnet sampling through time suggests early preferential sampling of shallow/depleted SCLM. Evaluations of Ti, Zr, Y and Ga over the range of estimated depths support models of the SCLM underlying the central Slave terrane.
DS201808-1769
2018
Motsamai, T., Harris, J.W., Stachel, T., Pearson, D.G., Armstrong, J.Mineral inclusions in diamonds from Karowe mine, Botswana: super-deep sources for super-sized diamonds?Mineralogy and Petrology, doi.org/10.1007/s00710-018-0604-9 12p.Africa, Botswanadeposit - Karowe

Abstract: Mineral inclusions in diamonds play a critical role in constraining the relationship between diamonds and mantle lithologies. Here we report the first major and trace element study of mineral inclusions in diamonds from the Karowe Mine in north-east Botswana, along the western edge of the Zimbabwe Craton. From a total of 107 diamonds, 134 silicate, 15 oxide, and 22 sulphide inclusions were recovered. The results reveal that 53% of Karowe inclusion-bearing diamonds derived from eclogitic sources, 44% are peridotitic, 2% have a sublithospheric origin, and 1% are websteritic. The dominant eclogitic diamond substrates sampled at Karowe are compositionally heterogeneous, as reflected in wide ranges in the CaO contents (4-16 wt%) of garnets and the Mg# (69-92) and jadeite contents (14-48 mol%) of clinopyroxenes. Calculated bulk rock REEN patterns indicate that both shallow and deep levels of the subducted slab(s) were sampled, including cumulate-like protoliths. Peridotitic garnet compositions largely derive from harzburgite/dunite substrates (~90%), with almost half the garnets having CaO contents <1.8 wt%, consistent with pyroxene-free (dunitic) sources. The highly depleted character of the peridotitic diamond substrates is further documented by the high mean and median Mg# (93.1) of olivine inclusions. One low-Ca garnet records a very high Cr2O3 content (14.7 wt%), implying that highly depleted cratonic lithosphere at the time of diamond formation extended to at least 220 km depth. Inclusion geothermobarometry indicates that the formation of peridotitic diamonds occurred along a 39-40 mW/m2 model geotherm. A sublithospheric inclusion suite is established by three eclogitic garnets containing a majorite component, a feature so far unique within the Orapa cluster. These low- and high-Ca majoritic garnets follow pyroxenitic and eclogitic trends of majoritic substitution, respectively. The origin of the majorite-bearing diamonds is estimated to be between 330 to 420 km depth, straddling the asthenosphere-transition zone boundary. This new observation of superdeep mineral inclusions in Karowe diamonds is consistent with a sublithospheric origin for the exceptionally large diamonds from this mine.
DS201808-1770
2018
Mourot, Y., Roddaz, M., Dera, G., Calves, G., Kim, J-H., Charboureau, A-C., Mounic, S., Raisson, S.Geochemical evidence for large scale drainage reorganization in northwest Africa during the Cretaceous.Geochemistry, Geophysics, Geosystems, Vol. 19, 5, pp. 1690-1712.Africageomorphology

Abstract: West African drainage reorganization during Cretaceous opening of the Atlantic Ocean is deciphered here from geochemical provenance studies of Central Atlantic sediments. Changes in the geochemical signature of marine sediments are reflected in major and trace element concentrations and strontium?neodymium radiogenic isotopic compositions of Cretaceous sedimentary rocks from eight Deep Sea Drilling Project (DSDP) sites and one exploration well. Homogeneous major and trace element compositions over time indicate sources with average upper (continental) crust signatures. However, detailed information on the ages of these sources is revealed by neodymium isotopes (expressed as ?Nd). The ?Nd(0) values from the DSDP sites show a three?step decrease during the Late Cretaceous: (1) the Albian?Middle Cenomanian ?Nd(0) values are heterogeneous (-5.5 to ?14.9) reflecting the existence of at least three subdrainage basins with distinct sedimentary sources (Hercynian/Paleozoic, Precambrian, and mixed Precambrian/Paleozoic); (2) during the Late Cenomanian?Turonian interval, ?Nd(0) values become homogeneous in the deepwater basin (-10.3 to ?12.4), showing a negative shift of 2 epsilon units interpreted as an increasing contribution of Precambrian inputs; (3) this negative shift continues in the Campanian?Maastrichtian (?Nd(0)?=??15), indicating that Precambrian sources became dominant. These provenance changes are hypothesized to be related to the opening of the South and Equatorial Atlantic Ocean, coincident with tectonic uplift of the continental margin triggered by Africa?Europe convergence. Finally, the difference between ?Nd(0)values of Cretaceous sediments from the Senegal continental shelf and from the deepwater basins suggests that ocean currents prevented detrital material from the Mauritanides reaching deepwater areas.
DS201802-0254
2018
Moyen, J-F., Laurent, O.Archean tectonic systems: a view from igneous rocks.Lithos, Vol. 302-303, pp. 99-125.Globalgeochemistry

Abstract: This work examines the global distribution of Archaean and modern igneous rock's compositions, without relying on preconceptions about the link between rock compositions and tectonic sites (in contrast with “geotectonic” diagrams). Rather, Archaean and modern geochemical patterns are interpreted and compared in terms of source and melting conditions. Mafic rocks on the modern Earth show a clear chemical separation between arc and non-arc rocks. This points to the first order difference between wet (arc) and dry (mid-ocean ridges and hotspots) mantle melting. Dry melts are further separated in depleted (MORB) and enriched (OIB) sources. This three-fold pattern is a clear image of the ridge/subduction/plume system that dominates modern tectonics. In contrast, Archaean mafic and ultramafic rocks are clustered in an intermediate position, between the three main modern types. This suggests that the Archaean mantle had lesser amounts of clearly depleted or enriched portions; that true subductions were rare; and that the distinction between oceanic plateaus and ridges may have been less significant. Modern granitic rocks dominantly belong to two groups: arc-related granitoids, petrologically connected to arc basalts; and collision granitoids, related to felsic sources. In contrast, the Archaean record is dominated by the TTG suite that derives from an alkali-rich mafic source (i.e. altered basalt). The geochemical diversity of the TTG suite points to a great range of melting depths, from ca. 5 to > 20 kbar. This reveals the absence of large sedimentary accumulations, again the paucity of modern-like arc situations, and the importance played by reworking of an earlier basaltic shell, in a range of settings (including some proto-subduction mechanisms). Nonetheless, granitoids in each individual region show a progressive transition towards more modern-looking associations of arc-like and peraluminous granites. Collectively, the geochemical evidence suggests an Archaean Earth with somewhat different tectonic systems. In particular, the familiar distinction between collision, arcs, ridges and hotspots seems to blur in the Archaean. Rather, the large-scale geochemical pattern reveals a long-lived, altered and periodically resurfaced basaltic crust. This protocrust is reworked, through a range of processes occurring at various depths that correspond to a progressive stabilization of burial systems and the establishment of true subductions. A punctuated onset of global plate tectonics is unlikely to have occurred, but rather short-term episodes of proto-subduction in the late Archaean evolved over time into longer-term, more stable style of plate tectonics as mantle temperature decayed.
DS201801-0039
2017
Moyen, J-F., Paquette, J.L., Ionov, D.A., Gannoun, A., Korsakov, A.V., Golovin, A.V., Moine, B.N.Paleoproterozoic rejuvenation and replacement of Archean lithosphere: evidence from zircon U-Pb dating and Hf isotopes in crustal xenoliths at Udachnaya, Siberian craton.Earth and Planetary Science Letters, Vol. 458, 1, pp. 149-159.Russiadeposit - Udachnaya

Abstract: Cratons represent the oldest preserved lithospheric domains. Their lithosphere (lithospheric mantle welded to overlying Precambrian crystalline basement) is considered to be particularly robust and long-lived due to the protecting presence of buoyant and rigid “keels” made up of residual harzburgites. Although the cratons are mostly assumed to form in the Archaean, the timing of their formation remains poorly constrained. In particular, there are very few datasets describing concurrently the age of both the crustal and mantle portions of the lithosphere. In this study, we report new U-Pb ages and Hf isotope compositions for zircons in crustal xenoliths from the Udachnaya kimberlite in the central Siberian craton; this dataset includes samples from both the upper and lower portions of the crust. The zircon ages agree well with model melt-extraction Re-Os ages on refractory peridotite xenoliths from the same pipe; taken together they allow an integrated view of lithosphere formation. Our data reveal that the present day upper crust is Archaean, whereas both the lower crust and the lithospheric mantle yield Paleoproterozoic ages. We infer that the deep lithosphere beneath the Siberian craton was not formed in a single Archaean event, but grew in at least two distinct events, one in the late Archaean and the other in the Paleoproterozoic. Importantly, a complete or large-scale delamination and rejuvenation of the Archaean lower lithosphere (lower crust and lithospheric mantle) took place in the Paleoproterozoic. This further demonstrates that craton formation can be a protracted, multi-stage process, and that the present day crust and mantle may not represent complementary reservoirs formed through the same tectono-magmatic event. Further, deep cratonic lithosphere may be less robust and long living than often assumed, with rejuvenation and replacement events throughout its history.
DS201808-1771
2018
Muntener, C., Gaudet, M.Geology of the Renard 2 pipe to 1000 depth, Renard mine, Quebec, Canada: insights into Kimberley type pyroclastic kimberlite emplacement.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0614-7 12p.Canada, Quebecdeposit - Renard

Abstract: The Renard 2 pipe is currently the deepest-drilled and most extensively studied kimberlite body in the Renard cluster, central Québec, Canada, forming the major component of the Mineral Resource of Stornoway Diamond Corporation’s Renard Mine. Renard 2 is infilled with two distinct kimberlite units that exhibit Kimberley-type pyroclastic kimberlite and related textures. Hypabyssal kimberlite also occurs as smaller cross-cutting sheets and irregular intrusions. The units are distinguished by their rock textures, groundmass mineral assemblages, olivine macrocryst size distributions and replacement products, mantle and country rock xenolith contents, whole rock geochemical signatures, bulk densities and diamond grades. These differences are interpreted to reflect different mantle ascent and near-surface emplacement processes and are here demonstrated to be vertically continuous from present surface to over 1000 m depth. The distinctive petrological features together with sharp, steep and cross-cutting internal contact relationships, show that each unit was formed from a separate batch of mantle-derived kimberlite magma, and was completely solidified before subsequent emplacement of the later unit. The mineralogy and textures of the ultra-fine-grained interclast matrix are consistent with those described at numerous Kimberley-type pyroclastic kimberlite localities around the world and are interpreted to reflect rapid primary crystallization during emplacement of separate kimberlite magmatic systems. The units of fractured and brecciated country rock surrounding the main kimberlite pipe contain kimberlite-derived material including carbonate providing evidence of subsurface brecciation. Together these data show that Renard 2 represents the deeper parts of a Kimberley-type pyroclastic kimberlite pipe system and demonstrates that their diagnostic features result from magmatic crystallisation during subsurface volcanic emplacement processes.
DS201812-2853
2018
Murri, M., Mazzucchelli, M.L., Campomenosi, N., Korsakov, A.V., Prencipe, M., Mihailova, B.D., Scambelluri, M., Angel, R.J., Alvaro, M.Raman elastic geobarometry for anisotropic mineral inclusions. MirAmerican Mineralogist, Vol. 103, pp. 1869-1872.Russiamineral inclusions

Abstract: Elastic geobarometry for host-inclusion systems can provide new constraints to assess the pressure and temperature conditions attained during metamorphism. Current experimental approaches and theory are developed only for crystals immersed in a hydrostatic stress field, whereas inclusions experience deviatoric stress. We have developed a method to determine the strains in quartz inclusions from Raman spectroscopy using the concept of the phonon-mode Grüneisen tensor. We used ab initio Hartree-Fock/Density Functional Theory to calculate the wavenumbers of the Raman-active modes as a function of different strain conditions. Least-squares fits of the phonon-wavenumber shifts against strains have been used to obtain the components of the mode Grüneisen tensor of quartz (??m1 and ?m3?) that can be used to calculate the strains in inclusions directly from the measured Raman shifts. The concept is demonstrated with the example of a natural quartz inclusion in eclogitic garnet from Mir kimberlite and has been validated against direct X-ray diffraction measurement of the strains in the same inclusion.
DS201807-1517
2018
Musenwa, L., Khumalo, T., Kgaphola, M., Masemola, S., van Wyk, G.The new Culli nan AG milling circuit - a narrative of progress. MiningSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 45-64.Africa, South Africadeposit - Cullinan
DS201803-0465
2018
Mysen, B.Mass transfer in the Earth's interior: fluid melt interaction in aluminosilicate C-O-H-N systems at high pressure and temperature under oxidizing conditions.Progress in Earth and Planetary Science, Vol. 5.6, 18p. AvailableMantleUHP - spectroscopy

Abstract: Understanding what governs the speciation in the C-O-H-N system aids our knowledge of how volatiles affect mass transfer processes in the Earth’s interior. Experiments with aluminosilicate melt?+?C-O-H-N volatiles were, therefore, carried out with Raman and infrared spectroscopy to 800 °C and near 700 MPa in situ in hydrothermal diamond anvil cells. The measurements were conducted in situ with the samples at the desired temperatures and pressures in order to avoid possible structural and compositional changes resulting from quenching to ambient conditions prior to analysis. Experiments were conducted without any reducing agent and with volatiles added as H2O, CO2, and N2 because both carbon and nitrogen can occur in different oxidation states. Volatiles dissolved in melt comprise H2O, CO32-, HCO3-, and molecular N2, whereas in the coexisting fluid, the species are H2O, CO2, CO32-, and N2. The HCO3-/CO32- equilibrium in melts shift toward CO32- groups with increasing temperature with ?H?=?114?±?22 kJ/mol. In fluids, the CO2 abundance is essentially invariant with temperature and pressure. For fluid/melt partitioning, those of H2O and N2 are greater than 1 with temperature-dependence that yields ?H values of ??6.5?±?1.5 and ??19.6?±?3.7 kJ/mol, respectively. Carbonate groups, CO32- are favored by melt over fluid. Where redox conditions in the Earth’s interior exceed that near the QFM oxygen buffer (between NNO and MW buffers), N2 is the stable nitrogen species and as such acts as a diluent of both fluids and melts. For fluids, this lower silicate solubility, in turn, enhances alkalinity. This means that in such environments, the transport of components such as high field strength cations, will be enhanced. Effects of dissolved N2 on melt structure are considerably less than on fluid structure.
DS201809-2073
2018
Mysen, B.Silicate solution, cation properties, and mass transfer by aqueous fluid in the Earth's interior.Progress in Earth and Planetary Science, doi.org/10.1186/ s40645-018-0198-1 10p.Mantlewater

Abstract: Aqueous fluids in the Earth’s interior are multicomponent systems with silicate solubility and solution mechanisms strongly dependent on other dissolved components. Here, solution mechanisms that describe the interaction between dissolved silicate and other solutes were determined experimentally to 825 °C and above 1 GPa with in situ vibrational spectroscopy of aqueous fluid while these were at high temperature and pressure. The silicate content in Na-bearing, silicate-saturated aqueous fluid exceeds that in pure SiO2 at high temperature and pressure. Silicate species were of Q0 (isolated SiO4 tetrahedra) and Q1 (dimers, Si2O7) type. The temperature dependence of its equilibrium constant, K?=?XQ1/(XQo)2, yields enthalpies of 22?±?12 and 51?±?17 kJ/mol for the SiO2-H2O and Na-bearing fluids. In contrast, in Ca-bearing fluids, the solubility is more than an order of magnitude lower, and only Q0 species are present. The present data together with other published experimental information lead to the conclusion that the silicate solubility in aqueous fluids in equilibrium with mafic rocks such as amphibolite and peridotite is an order of magnitude lower than the solubility in fluids in equilibrium with felsic rocks such as andesite and rhyolite compositions (felsic gneiss) under similar temperature and pressure conditions. The silicate speciation also is more polymerized in the felsic systems. This difference is also why second critical end-points in the Earth are at lower temperature and pressure in felsic compared with mafic systems. Alkali-rich fluids formed by dehydration of felsic rocks also show enhanced high field strength element (HFSE) solubility because alkalis in such solution form oxy complexes with the HFSE cations. Fluids formed by dehydration of felsic rocks in the Earth’s interior are, therefore, more efficient transport agents of silicate materials than fluids formed by dehydration of mafic and ultramafic rocks, whether for major, minor, or trace elements.
DS201810-2358
2018
Mysen, B.Redox controlled mechanisms of C and H isotope fractionation between silicate melt and COH fluid in Earth's interior. ReviewProgress in Earth and Planetary Science, doi.org/10.1186/ s4065-018-0203-8 17p. Open accessMantlespectroscopy, redox

Abstract: The behavior of COH fluids, their isotopes (hydrogen and carbon), and their interaction with magmatic liquids are at the core of understanding formation and evolution of the Earth. Experimental data are needed to aid our understanding of how COH volatiles affect rock-forming processes in the Earth’s interior. Here, I present a review of experimental data on structure of fluids and melts and an assessment of how structural factors govern hydrogen and carbon isotope partitioning within and between melts and fluids as a function of redox conditions, temperature, and pressure. The solubility of individual COH components in silicate melts can differ by several orders of magnitude and ranges from several hundred ppm to several wt%. Silicate solubility in fluid can reach several molecular at mantle temperatures and pressures. Different solubility of oxidized and reduced C-bearing species in melts reflects different solution equilibria. These equilibria are 2CH4?+?Qn?=?2CH3??+?H2O?+?Qn?+?1 and 2CO32??+?H2O?+?2Qn +?1 =?HCO3??+?2Qn, under reducing and oxidizing conditions, respectively. In the Qn-notations, the superscript, n, denotes the number of bridging oxygen in the silicate species (Q-species). The structural changes of carbon and silicate in magmatic systems (melts and fluids) with variable redox conditions result in hydrogen and carbon isotope fractionation factors between melt, fluid, and crystalline materials that depend on redox conditions and can differ significantly from 1 even at magmatic temperatures. The ?H of D/H fractionation between aqueous fluid and magma in silicate-COH systems is between ??5 and 25 kJ/mol depending on redox conditions. The ?H values for 13C/12C fractionation factors are near ??3.2 and 1 kJ/mol under oxidizing and reducing conditions, respectively. These differences are because energetics of O-D, O-H, O-13C, and O-12C bonding environments are governed by different solution mechanisms in melts and fluids. From the above data, it is suggested that (COH)-saturated partial melts in the upper mantle can have ?D values 100%, or more, lighter than coexisting silicate-saturated fluid. This effect is greater under oxidizing than under reducing conditions. Analogous relationships exist for 13C/12C. At magmatic temperatures in the Earth’s upper mantle, 13C/12C of melt in equilibrium with COH-bearing mantle in the ??7 to ??30‰ range increases with temperature from about 40 to >?100‰ and 80-120‰ under oxidizing and reducing conditions, respectively.
DS201812-2854
2018
Mysen, B.Solution mechanisms of COHN fluids in melts to upper mantle temperature, pressure and redox conditions.American Mineralogist, Vol. 103, pp. 1780-1788.Mantleredox

Abstract: We wished to advance the knowledge of speciation among volatiles during melting and crystallization in the Earth's interior; therefore, we explored the nature of carbon-, nitrogen-, and hydrogen-bearing species as determined in COHN fluids and dissolved in coexisting aluminosilicate melts. Micro-Raman characterization of fluids and melts were conducted in situ while samples were at a temperature up to 825 °C and pressure up to ?1400 MPa under redox conditions controlled with the Ti-TiO2-H2O hydrogen fugacity buffer. The fluid species are H2O, H2, NH3, and CH4. In contrast, under oxidizing conditions, the species are H2O, N2, and CO2. The equilibria among silicate structures (Q-species) and reduced carbon and nitrogen species are, 2NH3 + 4Qn ? 2Qn-1(NH2) + 2Qn-1(OH), and 2CH4 + 4Qn ? 2Qn-1(CH3) + 2Qn-1(OH). The Qn and Qn-1 denote silicate species with, respectively, n and n-1 bridging O atoms. The formulation in parentheses, (NH2), (CH3), and (OH), is meant to indicate that those functional groups replace one or more oxygen in the silicate tetrahedra. There is no evidence for O-NH2 or O-CH3 bonding. Therefore, a solution of reduced C- and N-species species in the COHN system results in depolymerization of silicate melts. The ?H values derived from the XNH2/XNH3 and XCH3/XCH4 evolution with temperature, respectively, were 8.1 ± 2.3 kJ/mol and between -4.9 ± 1.0 and -6.2 ± 2.2 kJ/mol. The fluid/melt partition coefficients, Kfluid/melt, of the reduced species, H2O, H2, NH3, and CH4, remain above unity at all temperatures. For example, for carbon it is in the 6-15 range with a ?H = -13.4 ± 2.4 KJ/mol. These values compare with a 0.8-3 range with ?H = -19 ± 2.4 kJ/mol in N-free silicate-COH systems. The Kfluid/melt values for reduced nitrogen and molecular hydrogen are in the 6-10 and 6-12 range with ?H values of -5.9 ± 0.9 and = 8 ± 6 kJ/mol, respectively. A change in redox conditions during melting and crystallization in the Earth sufficient to alter oxidized to reduced carbon- and nitrogen-bearing species will affect all melt properties that depend on melt polymerization. This suggestion implies that changing redox conditions during melting of a COHN-bearing mantle can have a profound effect on physical and chemical properties of melts and on melting and melt aggregation processes.
DS201805-0964
2018
Nabiel, F., Badro, J., Dennenwaldt, T., Oveisi, E., Cantoni, M., Hebert, C., El Goresy, A., Barrat, J-A., Gillet, P.A large planetary body inferred from diamond inclusions in a urelite metorite.Nature Communications, doe:10.1038/ s41467-018- 030808-6 6p. PdfTechnologyureilite

Abstract: Planetary formation models show that terrestrial planets are formed by the accretion of tens of Moon- to Mars-sized planetary embryos through energetic giant impacts. However, relics of these large proto-planets are yet to be found. Ureilites are one of the main families of achondritic meteorites and their parent body is believed to have been catastrophically disrupted by an impact during the first 10 million years of the solar system. Here we studied a section of the Almahata Sitta ureilite using transmission electron microscopy, where large diamonds were formed at high pressure inside the parent body. We discovered chromite, phosphate, and (Fe,Ni)-sulfide inclusions embedded in diamond. The composition and morphology of the inclusions can only be explained if the formation pressure was higher than 20?GPa. Such pressures suggest that the ureilite parent body was a Mercury- to Mars-sized planetary embryo.
DS201801-0040
2018
Nadeau, O., Stevenson, R., Jebrak, M.Interaction of mantle magmas and fluids with crustal fluids at the 1894 Ma Montviel alkaline carbonatite complex, Canada: insights from metasomatic and hydrothermal carbonates.Lithos, Vol. 296-299, pp. 563-579.Canada, Quebeccarbonatite - Montviel

Abstract: Alkaline and carbonatite rocks are relatively rare but offer the opportunity to study the contribution of fluids in the genesis of mantle and crustal rocks because they are commonly affected by metasomatism. Carbonate minerals represent versatile archives of mantle and crustal magmatic-hydrothermal processes because they can have magmatic, metasomatic or hydrothermal origins and because they host the trace elements, stable and radiogenic isotopes required to unravel their petrogenesis. Previous studies have shown that the 1894 Ma Montviel alkaline?carbonatite complex was emplaced through four injections of volatile-saturated, mantle magmas which evolved through fractional crystallization, mixing of mantle and crustal fluids and metasomatism. Trace element analyses and ?18O, ?13C, 87Sr/86Sr and 143Nd/144Nd isotope compositions of metasomatic and hydrothermal carbonates further support that each magma injection was accompanied by a volatile phase. Variations in trace element concentrations suggest that the carbonatite might have exsolved from a metasomatized mantle or hybrid silicate?carbonatite magma, and that the fluid composition evolved towards higher REE and lower HFSE with increasing degree of segregation of the carbonatite magma and the silicate source. A strong correlation between the C-O-Sr isotopic systems show that mantle fluids mixed with crustal fluids, increasing the 87Sr/86Sr from mantle to crustal values, and driving the C and O isotopic ratios towards respectively lighter and heavier values. The Sm/Nd isotopic system was weakly coupled with the other isotopic systems as depleted mantle fluids mixed with crustal fluids and metasomatized the crystallizing magmas, thereby redistributing the REE and affecting their Sm/Nd ratios. The Nd isotopes suggest that the mixed mantle/crustal fluids redistributed the rare earth elements, producing ultra-depleted (?Nd = + 10), normally depleted (?Nd = + 4) and slightly enriched (?Nd = ? 2) isotopic compositions.
DS201805-0965
2018
Nagaraju, B., Ghodke, S.S., Rathna, K., Kokandakar, G.J., Bhosle, M.V., Kumar, K.V.Fractal analysis of in situ host rock nepheline sysenite xenoliths in a micro- shonkinite dyke ( The Elchuru alkaline complex, SE India).Journal of the Geological Society of India, Vol. 91, 3, pp. 263-272.Indiashonkinite

Abstract: Formation of the fragments of the wall-rock during dyking is one of the important manifestations of instantaneous magmatic events. This process is well documented at shallower depths of Earth’s crust but not at deeper levels. In this paper the in situ xenoliths of host rock nepheline syenite within a micro-shonkinite dyke emplaced at mid-crustal depths is described and the fractal theory applied to evaluate origin of the xenoliths. The nepheline syenite xenoliths are angular to oval shaped and sub-millimetre to ~50 cm long. The xenoliths are matrix supported with clasts and matrix being in equal proportions. Partly detached wall-rock fragments indicate incipient xenolith formation, which suggested that the model fragmentation processes is solely due to dyke emplacement. Fractal analytical techniques including clast size distribution, boundary roughness fractal dimension and clast circularity was carried out. The fractal data suggests that hydraulic (tensile) fracturing is the main process of host rock brecciation. However, the clast size and shape are further affected by postfragmentation processes including shear and thermal fracturing, and chemical erosion. The study demonstrates that dyking in an isotropic medium produces fractal size distributions of host rock xenoliths; however, post-fragmentation processes modify original fractal size distributions.
DS201810-2359
2018
Nakagawa, T., Iwamori, H., Yanagi, R., Nako, A.On the evolutiom of the water ocean in the plate mantle system.Progress in Earth and Planetary Science, Vol. 5, pp. 51- 16p.Mantlewater

Abstract: Here, we investigate a possible scenario of surface seawater evolution in the numerical simulations of surface plate motion driven by mantle dynamics, including thermo-chemical convection and water migration, from the early to present-day Earth to constrain the total amount of water in the planetary system. To assess the validity of two hypotheses of the total amount of water inferred from early planetary formation processes and mineral physics, we examine the model sensitivity to the total water in the planetary system (both surface and deep interior) up to 15 ocean masses. To explain the current size of the reservoir of surface seawater, the predictions based on the numerical simulations of hydrous mantle convection suggest that the total amount of water should range from 9 to 12 ocean masses. Incorporating the dense hydrous magnesium silicate (DHMS) with a recently discovered hydrous mineral at lower mantle pressures (phase H) indicates that the physical mechanism of the mantle water cycle would not be significantly influenced, but the water storage region would be expanded in addition to the mantle transition zone. The DHMS solubility field may have a limited impact on the partitioning of water in the Earth’s deep mantle.
DS201808-1773
2018
Nakao, A., Iwamori, H., Nakakakuki, T., Suzuki, Y.J., Nakamura, H.Roles of hydrous lithospheric mantle in deep water transportation and subduction dynamics.Geophysical Research Letters, Vol. 45, 11, pp. 5336-5343.Mantlesubduction

Abstract: Rocks on the Earth's surface are cooled, hardened, eventually forming rigid plates that move around relative to one another. When two plates converge, one plate overrides the other, which sinks into the Earth's deep mantle. The sinking plate carries water, which softens rocks and also affects the behavior of the sinking/overriding plates and surrounding mantle flows (“subduction dynamics”). To investigate the role of water in subduction dynamics, 2?D fluid dynamical simulations were performed. The simulations suggest that subduction dynamics change significantly with the level of hydration of the sinking plate, which is represented by the thickness of a hydrous layer. When the hydrous layer is thin, the plate sinks rapidly with a shifting boundary and stagnates above the lower mantle. In contrast, when the hydrous layer is thick, plate convergence is sluggish, the plate boundary remains stationary, and the sinking plate penetrates into the lower mantle. These results indicate that a small amount of water is expected for the northwest part of the Pacific Plate, characterized by the rapid convergence, plate boundary shifting, and stagnation of the sinking plate.
DS201803-0466
2018
Nakashole, A.N., Hodgson, D.M., Chapman, R.J., Morgan, D.J., Jacob, R.J.Long term controls on continental scale bedrock river terrace deposition from integrated clast and heavy mineral assemblage analysis: an example from the Lower Orange River, Namibia. ( Diamondiferous gravel terraces)Sedimentary Geology, Vol. 364, pp. 103-120.Africa, Namibiadeposit - Orange River

Abstract: Establishing relationships between the long-term landscape evolution of drainage basins and the fill of sedimentary basins benefits from analysis of bedrock river terrace deposits. These fragmented detrital archives help to constrain changes in river system character and provenance during sediment transfer from continents (source) to oceans (sink). Thick diamondiferous gravel terrace deposits along the lower Orange River, southern Namibia, provide a rare opportunity to investigate controls on the incision history of a continental-scale bedrock river. Clast assemblage and heavy mineral data from seven localities permit detailed characterisation of the lower Orange River gravel terrace deposits. Two distinct fining-upward gravel terrace deposits are recognised, primarily based on mapped stratigraphic relationships (cross-cutting relationships) and strath and terrace top elevations, and secondarily on the proportion of exotic clasts, referred to as Proto Orange River deposits and Meso Orange River deposits. The older early to middle Miocene Proto Orange River gravels are thick (up to 50 m) and characterised by a dominance of Karoo Supergroup shale and sandstone clasts, whereas the younger Plio-Pleistocene Meso Orange River gravels (6-23 m thick) are characterised by more banded iron formation clasts. Mapping of the downstepping terraces indicates that the Proto gravels were deposited by a higher sinuosity river, and are strongly discordant to the modern Orange River course, whereas the Meso deposits were deposited by a lower sinuosity river. The heavy minerals present in both units comprise magnetite, garnet, amphibole, epidote and ilmenite, with rare titanite and zircon grains. The concentration of amphibole-epidote in the heavy minerals fraction increases from the Proto to the Meso deposits. The decrease in incision depths, recorded by deposit thicknesses above strath terraces, and the differences in clast character (size and roundness) and type between the two units, are ascribed to a more powerful river system during Proto-Orange River time, rather than reworking of older deposits, changes in provenance or climatic variations. In addition, from Proto- to Meso-Orange River times there was an increase in the proportion of sediments supplied from local bedrock sources, including amphibole-epidote in the heavy mineral assemblages derived from the Namaqua Metamorphic Complex. This integrated study demonstrates that clast assemblages are not a proxy for the character of the matrix, and vice versa, because they are influenced by the interplay of different controls. Therefore, an integrated approach is needed to improve prediction of placer mineral deposits in river gravels, and their distribution in coeval deposits downstream.
DS201801-0041
2017
Nanda. L.K., Verma, M.B., Purohit, R.K., Khandelwal, M.K., Rai, S.D., Mundra, K.L.LREE and Nb multi metal potentiality of the Amba Dongar carbonatite complex, Chhota Udepur district, Gujarat.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 43-44.Indiadeposit - Amba Dongar

Abstract: Rare earth elements (REE) are used in science innovations, due to their unique magnetic, fluorescent and chemical properties. REE are key components in rnany technological devices, like hybrid rechargeable batteries, catalysts, glass polishing, magnets, lasers, TV colour components, superconductors, ceramics etc. They are in great demand for hybrid cars, CD, cameras and high end defence systems. Similarly, niobium (Nb) finds its usage in diverse high tech applications including atomic energy. With increasing technological applications of REE and Nb, their global demand has enhanced over the years. To keep pace with the current demand, many carbonatite complexes in India including the Amba Dongar were revisited to assess their REE and Nb content. Amba Dongar is a classic carbonatite-alkalic rock complex of the Deccan basalt plateau and is emplaced in close proximity to Narmada rift zone. The main rock types of carbonatite affinity include sovite (calcium carbonatite), ankerite (Fe-Mg•Mn carbonatite), siderite (Fe carbonatite), carbonatite breccia (mixed rock. fragments with carbonate cement) etc. Sovite forms a large ring-dyke (nearly 1.5 km dia.) surrounding an incomplete ring of carbonatite breccia. Plugs of ankeritic carbonatite intrude the sovite. To assess rare metal and REE potential of the carbonatite complex geological and radiometric surveys followed by core drilling were carried out in western part of the complex. Rocks of carbonatite affinity have been intercepted in all the boreholes upto a maximum drilled depth of 150 m. It is for the first time that presence of carbonatite and carbonatite breccia has been reported below central basalt in the Amba Dongar complex. Continuity of carbonatites beyond the drilled depth is inferred. Petromineralogical and X-Ray Diffraction studies indicated presence of REE minerals such as monazite, thorite, cerite, synchisite and bastnasite. Besides, rare earth fluorocarbonates, parisite, florencite, barite, strontianite and columbite have also been reported by earlier investigators. Fairly good amount of pyrochlore (Nb mineral) is also present in all the variants of carbonatite. Detailed chemical analysis core at 1 m interval and of composite samples from every borehole was carried out. The results indicate homogeneity of mineralisation in the entire column upto an explored vertical depth of 120 m. Except a few lean zones, the entire column hosts REE mineralisation of the order of >1% ?REE. Some zones have indicated REE mineralisation of the order of >4 % also. Major element analysis of a composite sample representing a small block (400 m x 100 m x 113 m) indicates 14.69% SiO2, 10.57% Fe2O3, 7 21% MgO, 32.23% CaO, 2.77%, Al2O3, 1.48% P2O5, 2.13% MnO, 0.84% FeO, 0.37% TiO2, 0.95% Na2O, 1.35% K2O, and 23.50% LOI. 1.16% LREE (including 161 ppm HREE), 215 ppm Y, 650 ppm Nb, 310 ppm Th and 467 ppm V appear to be of economic significance. Additionally, presence of high content of Ba (2.65%), Sr (0.50%), Pb (530 ppm), F (1.95%) and Zn (1248 ppm) is also important. Taking into consideration these results, resource estimation of a small block of 400 m x 100 m (0.04 sq. km) with an average depth of 113 m was carried out Inferred REE resources ~140000 tonnes contained in 12.00 million tonne ore have been estimated with an average grade of 1.16% REE. Additionally, this block contains 9,600 tonnes Nb2O5 at an average grade of 0 08 % Nb2O5. These values indicate high potential of Amba Dongar carbonatite complex.
DS201810-2360
2018
Nasdala, L., Corfu, F., Schoene, B., Tapster, S.R., Wall, C.J., Schmitz, M.D., Ovtcharova, M., Schaltegger, U., Kennedy, A.K., Kronz, A., Reiners, P.W., Yang, Y-H., Wu, F-Y., Gain, S.E.M., Griffin, W.L., Szymanowski, D., Chanmuang, C., Ende, N.M., ValleyGZ7 and GZ8 - two zircon reference materials for SIMS U-Pb geochronology.Geostandards and Geoanalytical Research, http://orchid.org/0000-0002-2701-4635 80p.Asia, Sri Lankageochronology

Abstract: Here we document a detailed characterization of two zircon gemstones, GZ7 and GZ8. Both stones had the same mass at 19.2 carats (3.84 g) each; both came from placer deposits in the Ratnapura district, Sri Lanka. The U-Pb data are in both cases concordant within the uncertainties of decay constants and yield weighted mean ²??Pb/²³?U ages (95% confidence uncertainty) of 530.26 Ma ± 0.05 Ma (GZ7) and 543.92 Ma ± 0.06 Ma (GZ8). Neither GZ7 nor GZ8 have been subjected to any gem enhancement by heating. Structure?related parameters correspond well with the calculated alpha doses of 1.48 × 10¹? g?¹ (GZ7) and 2.53 × 10¹? g?¹ (GZ8), respectively, and the (U-Th)/He ages of 438 Ma ± 3 Ma (2s) for GZ7 and 426 Ma ± 9 Ma (2s) for GZ8 are typical of unheated zircon from Sri Lanka. The mean U concentrations are 680 ?g g?¹ (GZ7) and 1305 ?g g?¹ (GZ8). The two zircon samples are proposed as reference materials for SIMS (secondary ion mass spectrometry) U-Pb geochronology. In addition, GZ7 (Ti concentration 25.08 ?g g?¹ ± 0.18 ?g g?¹; 95% confidence uncertainty) may prove useful as reference material for Ti?in?zircon temperature estimates.
DS201801-0042
2018
Natali, C., Beccaluva, L., Bianchini, G., Siena, F.Coexistence of alkaline carbonatite complexes and high MgO CFB in the Parana-Etendeka province: insights on plume lithosphere interactions in the Gondwana realm.Lithos, Vol. 296-299, pp. 54-66.South America, Brazilcarbonatites
DS201804-0722
2018
Navon, O.Diamond forming fluids.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 30-32. abstractTechnologydiamond inclusions
DS201809-2074
2018
Navon, O., Elazar, O., Kessel, R.Mantle metasomatism and diamond bearing fluids. BultfonteinGoldschmidt Conference, 1p. AbstractMantlecarbon

Abstract: Diamonds and the fluids that form them are important players in the deep carbon cycle that transforms carbon between mantle and surface reservoirs. However, the role of the high-density fluids (HDFs) that are found in microinclusions in diamonds is not limited to diamond formation. Examination of literature data on metasomatized rocks suggests that some may have formed by interaction of peridotites and eclogites with HDF-like melts. For example, silicic HDFs can explain the evoltion of an orthopyroxenerich vein in a garnet hartzburgite from Bulfontein,SA [1]. The composition that was added to the harzburgite and turned it into an orthopyroxene+olivine+phlogopite+garnet+carbonate +sulfide vein (green ellipse in the figure) lies at the extention of the array of silicic to low-Mg carbonatitic HDFs found in fibrous diamonds (pink diamonds). A silicic HDF (blue diamond) that contributed the added component would evolve into more carbonatitic compositions (arrow). Saline melts found in diamonds carry chloride, carbonate and silicate components, similar to saline hydrous fluids found in harzburgites xenoliths from Pinatubo, Phillipeens [2]. The higher water content in Pinatubo is, most probably, the result of lower temperatures and shallower level, but it attests for the role of saline fluids in metasomatism at the arc environment. In a companion abstract (Elazar et al., this volume) we report the finding of potassium-rich microinclusions in garnets in an eclogite xenolith from Robert Victor, SA. Their composition falls close to that of silicic to low-Mg carbonatitic HDFs in diamonds. Their lower potassium and higher aluminum content suggests derivation by higher degree of partial melting compared with the diamond forming fluids. All of the above observations support the important role of HDF-like melts and fluids in mantle processes.
DS201807-1518
2018
Navon, O., Stachel, T., Stern, R.A., Harris, J.W.Carbon and nitrogen systematics in nitrogen-rich, ultradeep diamonds from Sao Luiz, Brazil.Mineralogy and Petrology, 10.1007/ s710-018-0576 -9, 10p.South America, Brazildeposit - Sao Luiz

Abstract: Three diamonds from Sao Luiz, Brazil carrying nano- and micro-inclusions of molecular ?-N2 that exsolved at the base of the transition zone were studied for their C and N isotopic composition and the concentration of N utilizing SIMS. The diamonds are individually uniform in their C isotopic composition and most spot analyses yield ?13C values of ?3.2?±?0.1‰ (ON-SLZ-390) and???4.7?±?0.1‰ (ON-SLZ-391 and 392). Only a few analyses deviate from these tight ranges and all fall within the main mantle range of ?5?±?3‰. Most of the N isotope analyses also have typical mantle ?15N values (?6.6?±?0.4‰, ?3.6?±?0.5‰ and???4.1?±?0.6‰ for ON-SLZ-390, 391 and 392, respectively) and are associated with high N concentrations of 800-1250 atomic ppm. However, some N isotopic ratios, associated with low N concentrations (<400 ppm) and narrow zones with bright luminescence are distinctly above the average, reaching positive ?15N values. These sharp fluctuations cannot be attributed to fractionation. They may reflect arrival of new small pulses of melt or fluid that evolved under different conditions. Alternatively, they may result from fractionation between different growth directions, so that distinct ?15N values and N concentrations may form during diamond growth from a single melt/fluid. Other more continuous variations, in the core of ON-SLZ-390 or the rim of ON-SLZ-392 may be the result of Rayleigh fractionation or mixing.
DS201812-2855
2018
Nazari-Dehkordi, T., Spandler, C., Oliver, N.H.S., Wilson, R.Unconformity related rare earth element deposits: a regional scale hydrothermal mineralization type of Northern Australia.Economic Geology, Vol. 113, 6, pp. 1297-1305.Australia, Northern AustraliaREE

Abstract: Rare earth element (REE) orebodies are typically associated with alkaline igneous rocks or develop as placer or laterite deposits. Here, we describe an economically important heavy (H)REE mineralization type that is entirely hydrothermal in origin with no demonstrable links to magmatism. The mineralization occurs as numerous xenotime-rich vein and breccia orebodies across a large area of northern Australia but particularly close to a regional unconformity between Archean metasedimentary rocks of the Browns Range Metamorphics and overlying Proterozoic sandstones of the Birrindudu Group. The deposits formed at 1.65 to 1.61 Ga along steeply dipping faults; there is no known local igneous activity at this time. Depletion of HREEs in the Browns Range Metamorphics, together with the similar nonradiogenic Nd isotope composition of the orebodies and the Browns Range Metamorphics, indicates that ore metals were leached directly from the Browns Range metasedimentary rocks. We propose an ore genesis model that involves fluid leaching HREEs from the Browns Range Metamorphics and subsequently mixing with P-bearing acidic fluid from the overlying sandstones in fault zones near the unconformity. The union of P and HREEs via fluid mixing in a low-Ca environment triggered extensive xenotime precipitation. This mineralization is unlike that of any other class of REE ore deposit but has a similar setting to unconformity-related U deposits of Australia and Canada, so we assign it the label “unconformity-related REE.” Further discoveries of this REE mineralization type are expected near regional unconformities within Proterozoic intracontinental sedimentary basins across the globe.
DS201812-2856
2019
Nazzarini, S., Nestola, F., Zanon, V., Bindi, L., Scricciolo, E., Petrelli, M., Zanatta, M., Mariotto, G., Giuli, G.Discovery of moissanite in a peralkaline syenite from the Azores Islands.Lithos, Vol. 324-325, pp. 68-73.Europe, Portugal, Azoresmoissanite

Abstract: Our discovery of moissanite grains in a peralkaline syenite from the Água de Pau Volcano (São Miguel, Azores Islands, Portugal) represents the first report of this mineral in present day oceanic geodynamic settings. Raman spectroscopy and single-crystal X-ray diffraction show the presence of both the 6H and 4H polytypes with the predominance of the first one. The distribution of trace elements is homogeneous, except for Al and V. Azorean moissanite often hosts rounded inclusions of metallic Si and other not yet identified metallic alloys. A process involving a flushing of CH4-H2 ultra-reducing fluids in the alkaline melts might be considered as a possible mechanism leading to the formation of natural SiC, thus calling for strongly reducing conditions that were locally met in the crust-mantle beneath the São Miguel Island.
DS201802-0255
2018
Neave, D.A., Shorttle, O., Oeser, M., Weyer, S., Kobayashi, K.Mantle derived trace element variability in olivines and their melt inclusions.Earth and Planetary Science Letters, Vol. 483, 1, pp. 90-104.Europe, Icelandolivines

Abstract: Trace element variability in oceanic basalts is commonly used to constrain the physics of mantle melting and the chemistry of Earth's deep interior. However, the geochemical properties of mantle melts are often overprinted by mixing and crystallisation processes during ascent and storage. Studying primitive melt inclusions offers one solution to this problem, but the fidelity of the melt-inclusion archive to bulk magma chemistry has been repeatedly questioned. To provide a novel check of the melt inclusion record, we present new major and trace element analyses from olivine macrocrysts in the products of two geographically proximal, yet compositionally distinct, primitive eruptions from the Reykjanes Peninsula of Iceland. By combining these macrocryst analyses with new and published melt inclusion analyses we demonstrate that olivines have similar patterns of incompatible trace element (ITE) variability to the inclusions they host, capturing chemical systematics on intra- and inter-eruption scales. ITE variability (element concentrations, ratios, variances and variance ratios) in olivines from the ITE-enriched Stapafell eruption is best accounted for by olivine-dominated fractional crystallisation. In contrast, ITE variability in olivines and inclusions from the ITE-depleted Háleyjabunga eruption cannot be explained by crystallisation alone, and must have originated in the mantle. Compatible trace element (CTE) variability is best described by crystallisation processes in both eruptions. Modest correlations between host and inclusion ITE contents in samples from Háleyjabunga suggest that melt inclusions can be faithful archives of melting and magmatic processes. It also indicates that degrees of ITE enrichment can be estimated from olivines directly when melt inclusion and matrix glass records of geochemical variability are poor or absent. Inter-eruption differences in olivine ITE systematics between Stapafell and Háleyjabunga mirror differences in melt inclusion suites, and confirm that the Stapafell eruption was fed by lower degree melts from greater depths within the melting region than the Háleyjabunga eruption. Although olivine macrocrysts from Stapafell are slightly richer in Ni than those from Háleyjabunga, their overall CTE systematics (e.g., Ni/(Mg/Fe), Fe/Mn and Zn/Fe) are inconsistent with being derived from olivine-free pyroxenites. However, the major element systematics of Icelandic basalts require lithological heterogeneity in their mantle source in the form of Fe-rich and hence fusible domains. We thus conclude that enriched heterogeneities in the Icelandic mantle are composed of modally enriched, yet nonetheless olivine-bearing, lithologies and that olivine CTE contents provide an incomplete record of lithological heterogeneity in the mantle. Modally enriched peridotites may therefore play a more important role in oceanic magma genesis than previously inferred.
DS201803-0467
2017
Nebel, C.E.General properties of diamond: introduction.Nanodiamonds, Chapter 1, pp. 1-22.Technologynanodiamonds
DS201812-2857
2018
Nebel, O., Capitanio, F.A., Moyen, J-F., Weinberg, R.F., Clos, F., Nebel-Jacobsen, Y.J., Cawood, P.A.When crust comes of age: on the chemical evolution of Archaean, felsic continental crust by crustal drip tectonics.Philosphical Transactions of the Royal Society, doi.org/10.1098 / rsta.2018.0103 21p.Mantleplate tectonics

Abstract: The secular evolution of the Earth's crust is marked by a profound change in average crustal chemistry between 3.2 and 2.5?Ga. A key marker for this change is the transition from Archaean sodic granitoid intrusions of the tonalite-trondhjemite-granodiorite (TTG) series to potassic (K) granitic suites, akin (but not identical) to I-type granites that today are associated with subduction zones. It remains poorly constrained as to how and why this change was initiated and if it holds clues about the geodynamic transition from a pre-plate tectonic mode, often referred to as stagnant lid, to mobile plate tectonics. Here, we combine a series of proposed mechanisms for Archaean crustal geodynamics in a single model to explain the observed change in granitoid chemistry. Numeric modelling indicates that upper mantle convection drives crustal flow and subsidence, leading to profound diversity in lithospheric thickness with thin versus thick proto-plates. When convecting asthenospheric mantle interacts with lower lithosphere, scattered crustal drips are created. Under increasing P-T conditions, partial melting of hydrated meta-basalt within these drips produces felsic melts that intrude the overlying crust to form TTG. Dome structures, in which these melts can be preserved, are a positive diapiric expression of these negative drips. Transitional TTG with elevated K mark a second evolutionary stage, and are blends of subsided and remelted older TTG forming K-rich melts and new TTG melts. Ascending TTG-derived melts from asymmetric drips interact with the asthenospheric mantle to form hot, high-Mg sanukitoid. These melts are small in volume, predominantly underplated, and their heat triggered melting of lower crustal successions to form higher-K granites. Importantly, this evolution operates as a disseminated process in space and time over hundreds of millions of years (greater than 200?Ma) in all cratons. This focused ageing of the crust implies that compiled geochemical data can only broadly reflect geodynamic changes on a global or even craton-wide scale. The observed change in crustal chemistry does mark the lead up to but not the initiation of modern-style subduction.This article is part of a discussion meeting issue 'Earth dynamics and the development of plate tectonics'.
DS201810-2361
2018
Nelson, D.A., Cottle, J.M.The secular development of accretionary orogens: linking the Gondwana magmatic arc record of West Antarctica, Australia and South America.Gondwana Research, Vol. 63, pp. 15-33.Australia, South Americageochronology

Abstract: Combined zircon geochronology and Hf isotopes of plutonic rocks from eastern Marie Byrd Land and Thurston Island, Antarctica, provide a detailed record of Phanerzoic arc magmatism along the paleo-Pacific margin of Gondwana. Magmatism along the Antarctic margin initiated in a dominantly contractional arc setting with an isotopically enriched lithospheric mantle source during the Ross Orogeny (c. 540-485?Ma). After termination of the Ross Orogeny through the Cretaceous, detrital zircon and zircon from igneous rocks record relative increases in zircon ?Hfi inferred to represent episodes of lithospheric-scale extension and relative decreases during inferred contractional episodes along the Antarctic margin. Comparison of this secular isotopic evolutionary trend with similar data from along the paleo-Pacific margin of Gondwana demonstrates a shared history among Marie Byrd Land, Australia, and Zealandia that contrasts with the shared record of Thurston Island, Antarctic Peninsula, and South America. These two contrasting histories highlight an early Permian along arc geochemical and inferred geodynamic switch from an isotopically enriched contractional arc system in South America, Antarctic Peninsula, and Thurston Island to an isotopically depleted extensional arc system in Marie Byrd Land, Zealandia, and Australia. Despite differences in timing, all segments of the paleo-Pacific margin underwent a similar secular isotopic evolution with dramatic shifts from enriched to juvenile isotopic compositions during extensional collapse.
DS201804-0723
2018
Nestola, F., Korolev, N., Kopylova, M., Rotiroti, N., Pearson, D.G., Pamato, M.G., Alvaro, M., Peruzzo, L., Gurney, J.J., Moore, A.E., Davidson, J.CaSiO3 perovskite in diamond indicates the recycling of oceanic crust into the lower mantle.Nature, Vol. 555, March 8, pp. 237-241.Mantledeposit - Cullinan

Abstract: Laboratory experiments and seismology data have created a clear theoretical picture of the most abundant minerals that comprise the deeper parts of the Earth’s mantle. Discoveries of some of these minerals in ‘super-deep’ diamonds—formed between two hundred and about one thousand kilometres into the lower mantle—have confirmed part of this picture1,2,3,4,5. A notable exception is the high-pressure perovskite-structured polymorph of calcium silicate (CaSiO3). This mineral—expected to be the fourth most abundant in the Earth—has not previously been found in nature. Being the dominant host for calcium and, owing to its accommodating crystal structure, the major sink for heat-producing elements (potassium, uranium and thorium) in the transition zone and lower mantle, it is critical to establish its presence. Here we report the discovery of the perovskite-structured polymorph of CaSiO3 in a diamond from South African Cullinan kimberlite. The mineral is intergrown with about six per cent calcium titanate (CaTiO3). The titanium-rich composition of this inclusion indicates a bulk composition consistent with derivation from basaltic oceanic crust subducted to pressures equivalent to those present at the depths of the uppermost lower mantle. The relatively ‘heavy’ carbon isotopic composition of the surrounding diamond, together with the pristine high-pressure CaSiO3 structure, provides evidence for the recycling of oceanic crust and surficial carbon to lower-mantle depths.https://www.nature.com/articles/nature25972
DS201811-2594
2018
Nestola, F., Prencipe, M., Nimis, P., Zaffiro, G.Toward a robust elastic geobarometry of kyanite inclusions in eclogitic diamonds. VoorspoedJournal of Geophysical Research: Solid Earth, doi: 10.1029/2018JB016012Africa, South Africadiamond inclusions

Abstract: Here we report the first results from elastic geobarometry applied to a kyanite inclusion entrapped within an eclogitic diamond (from Voorspoed mine, South Africa) using micro?Raman and Fourier transform infrared spectroscopy, electron microprobe analysis, ab initio calculations, and finite element modeling. Application of elastic geobarometry to very elastically anisotropic kyanite inclusions is challenging, as current models do not allow for elastic anisotropy. In order to minimize the effects of anisotropy, we have explored the effects of deviatoric stress on Raman modes via ab initio density functional theory. The results allowed us to select the Raman mode (at ca. 638 cm?1) that is the least sensitive to deviatoric stress. The shift of this band in the inclusion while still trapped within the diamond relative to the inclusion in air (once liberated) was used under hydrostatic approximation to determine a residual pressure on the inclusion of 0.184 ± 0.045 GPa and an entrapment pressure of 5.2 ± 0.3 GPa (~160 km depth) for an FTIR N?aggregation residence temperature of 1119 ± 50 °C. This is the first geothermobarometric determination for a diamond from the Voorspoed kimberlite. It overlaps with P-T estimates obtained by traditional chemical geobarometry for diamonds from other kimberlites from the Kaapvaal craton, suggesting that the hydrostatic approximation does not introduce significant errors in the geobarometric evaluation. Our protocol of Raman peak selection can be used for geobarometry of further kyanite?bearing diamonds and may provide a guide for more robust geobarometry of other types of mineral inclusions in diamonds, both eclogitic and peridotitic.
DS201803-0468
2018
Newton, D.E., Ryan, A.G., Hilchie, L.J.Competence and lithostratigraphy of host rocks govern kimberlite pipe morphology.Canadian Journal of Earth Science, Vol. 55, pp. 130-137.GlobalKimberlite morphology

Abstract: We use analogue experimentation to test the hypothesis that host rock competence primarily determines the morphology of kimberlite pipes. Natural occurrences of kimberlite pipes are subdivided into three classes: class 1 pipes are steep-sided diatremes emplaced into crystalline rock; class 2 pipes have a wide, shallow crater emplaced into sedimentary rock overlain by unconsolidated sediments; class 3 pipes comprise a steep-sided diatreme with a shallow-angled crater emplaced into competent crystalline rock overlain by unconsolidated sediments. We use different configurations of three analogue materials with varying cohesions to model the contrasting geological settings observed in nature. Pulses of compressed air, representing the energy of the gas-rich head of a kimberlitic magma, are used to disrupt the experimental substrate. In our experiments, the competence and configuration of the analogue materials control the excavation processes as well as the final shape of the analogue pipes: eruption through competent analogue strata results in steep-sided analogue pipes; eruption through weak analogue strata results in wide, shallow analogue pipes; eruption through intermediate strength analogue strata results in analogue pipes with a shallow crater and a steep-sided diatreme. These experimental results correspond with the shapes of natural kimberlite pipes, and demonstrate that variations in the lithology of the host rock are sufficient to generate classic kimberlite pipe shapes. These findings are consistent with models that ascribe the pipe morphologies of natural kimberlites to the competence of the host rocks in which they are emplaced.
DS201811-2595
2018
Ngalamo, J.F.G., Sobh, M., Bisso, D., Abdelsalam, M.G., Atekwana, E., Ekodeck, G.E.Lithospheric structure beneath the Central Africa Orogenic Belt in Cameroon from the analysis of satellite gravity and passive seismic data.Tectonophysics, Vol. 745, pp. 326-337.Africa, Cameroongeophysics - seismic

Abstract: We present original results that contribute to the understanding of lithospheric structures modification of regions that have witnessed superimposition of multiple tectonic events throughout their geological history. We analyze satellite gravity data through two-dimensional radially-averaged power spectral analysis as well as passive seismic data through thermal modeling to image the depth to the Moho and the lithosphere - asthenosphere boundary (LAB beneath the Central Africa Orogenic Belt (CAOB). The CAOB is an ENE-trending deformation belt extending from Cameroon in the west to Sudan in the east. In Cameroon, it is found on the northern edge of the Congo craton represented by the Oubanguides orogenic belt (the Western Cameroon, the Adamawa - Yade, and the Yaoundé domains). It coincides with the Adamawa plateau and the Benue Trough, and it is spotted by the Cenozoic Cameroon Volcanic Line (CVL). The CAOB was formed during the Precambrian Greater Gondwana assembly but was reactivated during the Mesozoic as a result of Gondwana breakup. We find deeper Moho and LAB) beneath Congo craton and the Yaoundé domain reaching ~50?km and ~200?km, respectively. We map shallower Moho and LAB beneath the CAOB (together with the Adamawa plateau and the Benue trough) reaching ~25?km and ~70?km, respectively. We interpret the shallower LAB beneath the CAOB as due to zonal sub-continental lithospheric mantle (SCLM) delamination along the northern edge of the Congo craton that occurred in association with collisional assembly of Greater Gondwana. This allowed for channelization of mantle flow during the Cenozoic resulting in the formation of the CVL and the uplift of the Adamawa plateau. Our approach can be used to understand the modification of lithospheric structures beneath other terrains that have long tectonic history.
DS201801-0043
2018
Nicklas, R.W., Puchtel, I.S., Ash, R.D.Redox state of the Archean mantle: evidence from V partioning in 3.5-2.4 komatitites.Geochimica et Cosmochimica Acta, Vol. 222, Feb. 1, pp. 447-466.MantleThermodynamics

Abstract: Oxygen fugacity of the mantle is a crucial thermodynamic parameter that controls such fundamental processes as planetary differentiation, mantle melting, and possible core-mantle exchange. Constraining the evolution of the redox state of the mantle is of paramount importance for understanding the chemical evolution of major terrestrial reservoirs, including the core, mantle, and atmosphere. In order to evaluate the secular evolution of the redox state of the mantle, oxygen fugacities of six komatiite systems, ranging in age from 3.48 to 2.41?Ga, were determined using high-precision partitioning data of the redox-sensitive element vanadium between liquidus olivine, chromite and komatiitic melt. The calculated oxygen fugacities range from ?0.11?±?0.30 ?FMQ log units in the 3.48?Ga Komati system to +0.43?±?0.26 ?FMQ log units in the 2.41?Ga Vetreny system. Although there is a slight hint in the data for an increase in the oxygen fugacity of the mantle between 3.48 and 2.41?Ga, these values generally overlap within their respective uncertainties; they are also largely within the range of oxygen fugacity estimates for modern MORB lavas of +0.60?±?0.30 ?FMQ log units that we obtained using the same technique. Our results are consistent with the previous findings that argued for little change in the mantle oxygen fugacity since the early Archean and indicate that the mantle had reached its nearly-present day redox state by at least 3.48?Ga.
DS201809-2075
2018
Nicklas, R.W., Puchtel, I.S., Ash, R.D.Redox state of the Archean mantle: evidence from V partioning in 3.5-2.4 Ga komatiites. Kidd-Munro, Pyke Hill, AlexoGeochimica et Cosmochimica Acta, Vol. 222, 1, pp. 447-466.Canada, Ontariokomatiites

Abstract: Oxygen fugacity of the mantle is a crucial thermodynamic parameter that controls such fundamental processes as planetary differentiation, mantle melting, and possible core-mantle exchange. Constraining the evolution of the redox state of the mantle is of paramount importance for understanding the chemical evolution of major terrestrial reservoirs, including the core, mantle, and atmosphere. In order to evaluate the secular evolution of the redox state of the mantle, oxygen fugacities of six komatiite systems, ranging in age from 3.48 to 2.41 Ga, were determined using high-precision partitioning data of the redox-sensitive element vanadium between liquidus olivine, chromite and komatiitic melt. The calculated oxygen fugacities range from -0.11 ± 0.30 ?FMQ log units in the 3.48 Ga Komati system to +0.43 ± 0.26 ?FMQ log units in the 2.41 Ga Vetreny system. Although there is a slight hint in the data for an increase in the oxygen fugacity of the mantle between 3.48 and 2.41 Ga, these values generally overlap within their respective uncertainties; they are also largely within the range of oxygen fugacity estimates for modern MORB lavas of +0.60 ± 0.30 ?FMQ log units that we obtained using the same technique. Our results are consistent with the previous findings that argued for little change in the mantle oxygen fugacity since the early Archean and indicate that the mantle had reached its nearly-present day redox state by at least 3.48 Ga.
DS201802-0256
2017
Nikitina, L.P., Bogomolov, E.S., Kyrmsky, R.Sh., Belyatsky, B.V., Korolev, N.M., Zinchenko, V.N.Nd Sr Os systems of eclogites in the lithospheric mantle of the Kasai Craton ( Angola).Russian Geology and Geophysics, Vol. 58, pp. 1305-1316.Africa, Angolaeclogites

Abstract: We studied the Sm-Nd, Rb-Sr, and Re-Os isotope compositions of mantle xenoliths (eclogites and peridotites) from diamondiferous kimberlites of the Catoca cluster of the Kasai Craton. In the eclogites, the primary strontium isotope composition 87Sr/86Sr varies from 0.7056 to 0.7071, and the neodymium isotope composition eNd, from 1.8 to 2.6. The 187Re/188Os and 187Os/188Os ratios range from 135 to 80 and from 1.3110 to 1.9709, respectively, which indicates a significant portion of radiogenic Os: yOs = 129-147. These isotope values exceed the values assumed for model reservoirs (primitive upper mantle (PUM) and bulk silicate Earth (BSE)) and those of chondrites. The isotope composition of the studied systems indicates the formation of eclogites from a rhenium-enriched source, namely, the subducted oceanic crust transformed as a result of metasomatism and/or melting under upper-mantle conditions.
DS201805-0966
2018
Nimis, P.Trapped minerals under stress. ( diamond)Geology, Vol. 46, 3, pp. 287-288.Technologythermobarometry
DS201807-1519
2018
Nkono, C., Liegeois, J-P., Demaiffe, D.Relationships between structural lineaments and Cenozoic volcanism, Tibesti swell, Saharan metacraton.Journal of African Earth Sciences, Vol. 145, pp. 274-283.Africa, Chadlineaments

Abstract: This work reports an analysis of the relationships existing between the structural lineaments and the Cenozoic volcanism of the Tibesti area (northern Chad). Shield volcanoes, cinder cones, structural lineaments, intersection points of lineaments and faults are mapped using the combination of Shuttle Radar Topography Mission (SRTM), Digital Elevation Models (DEMs) and Landsat satellite images of the Tibesti Volcanic Province. The interpretation of the distribution of these structural and morphological features allows constraining the structural/tectonic setting of the Tibesti. We show that the relationships between the lineaments and the volcanic centres of the Tibesti province can locally be explained as the result of the combination of two Riedel dextral tectonic systems, respectively oriented at N120°E and N30-35°E. Taking into account the geological features of the area, a geodynamical model is proposed: the emplacement of the Tibesti Volcanic Province results from the reactivation of inherited structures of the Saharan metacraton, characterized by relict rigid cratonic nuclei and metacratonic areas reworked during the Pan-African orogeny, among which is located the Tibesti. The contrasted behaviour of these rheologically different zones can explain the location and the evolution of the Tibesti swell and volcanism. The new data presented in this paper and their interpretation in terms of the emplacement of the Tibesti volcanic province in the Saharan metacraton bring a new and major information about the behaviour of the African plate within its collisional context with Europe.
DS201807-1520
2018
Nosova, A.A., Sazonova, L.V., Kargin, A.V., Smirnova, M.D., Lapin, A.V., Shcherbakov, V.D.Olivine in ultramafic lamprophyres: chemistry, crystallisation, and melt sources of Siberian pre and post trap aillikites. IlbokichContributions to Mineralogy and Petrology, 10.1007/ s00410-018- 1480-3, 27p.Russia, Siberiakimberlite

Abstract: We studied olivines from the Devonian pre-trap (the Ilbokich occurrence) and the Triassic post-trap (the Chadobets occurrence) carbonate-rich ultramafic lamprophyres (UMLs) in the southwestern portion of the Siberian craton. On the basis of detailed investigations of major, minor, and trace-element distributions, we have reconstructed the main processes that control the origins of these olivines. These include fractional crystallisation from melt, assimilation, and fractional crystallisation processes with orthopyroxene assimilation, melt-reaction diffusive re-equilibration, alkali enrichment, and CO2 degassing of the melt. Furthermore, we inferred the composition of the sources of the primary UML melt and their possible correlations with proto-kimberlitic melts, as well as the influence of the Triassic Siberian plume on the composition of the lithospheric mantle. The main differences between olivines from the Ilbokich and the Chadobets aillikites were that the olivines from the former had more magnesium-rich cores (Mg# = 89.2 ± 0.2), had Mg- and Cr-rich transition zones (Mg# = 89.7 ± 0.2 and 300-500 ppm Cr), had lower Ni (up to 3100 ppm) and Li (1.4-1.5 ppm), and had higher B (0.8-2.6 ppm) contents, all at higher Fo values (90-86), relative to the olivines from the latter (Mg# = 88-75; 200-300 ppm Cr; up to 3400 ppm Ni; 1.4-2.4 ppm Li; 0.4-2.2 ppm B). The Siberian aillikite sources contained a significant amount of metasomatic material. Phlogopite-rich MARID-type veins provided the likely metasomatic component in the pre-trap Devonian Ilbokich aillikite source, whereas the Triassic Chadobets aillikitic post-trap melts were derived from a source with a significant carbonate component. A comparison of UML olivines with olivines from the pre-trap and post-trap Siberian kimberlites shows a striking similarity. This suggests that the carbonate component in the aillikitic source could have been produced by evolved kimberlite melts. The differences in the lithospheric metasomatic component that contributed to pre-trap and post-trap aillikitic melts can be interpreted as reflections of the thermal impact of the Siberian Traps, which reduced phlogopite-bearing metasomes within the southwestern Siberian sub-continental lithospheric mantle.
DS201808-1774
2018
Nowicki, T., Garlick, G., Webb, K., Van Eeden, M.Estimation of commercial diamond grades based on microdiamonds: a case study of the Koidu diamond mine, Sierra Leone.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0620-9 11p.Africa, Sierra Leonedeposit - Koidu

Abstract: This paper documents the application of a microdiamond-based approach to the estimation of diamond grade in the Pipe 1 kimberlite at the Koidu mine in Sierra Leone. A geological model of Pipe 1 was constructed to represent the distribution and volume of the dominant kimberlite units within the pipe. Bulk samples, along with representative microdiamond samples, were collected from these units at surface and were used to define the ratio between microdiamond stone frequency (+212 ?m stones per kilogram) and recoverable macrodiamond grade (+1.2 mm carats per tonne; 1 carat?=?0.2 g). These ratios were applied to a comprehensive, spatially representative microdiamond sample dataset and were combined with a spatial model of country-rock xenolith dilution within the pipe to estimate +1.2 mm recoverable grades. The resource estimate was reconciled with subsequent production results in the elevation range 160 to 100 m above sea level. Production results for each of the six 10 m benches covering this elevation range were compared to the estimated average grades for these zones in the pipe. For the five cases where most of the kimberlite mass on a given bench is represented in the production data, the results show a maximum discrepancy of 6% between predicted and reported production grade with no indication of any consistent bias. This indicates that, when supported by a sound geological model and suitable microdiamond and macrodiamond data, the microdiamond-based estimation approach can provide reliable constraints on macrodiamond grade, even in the case of geologically complex bodies such as Koidu Pipe 1.
DS201805-0967
2007
O'Brien, H., Philippips, D., Spencer, R.Isotopic ages of Lentiira-Kuhmo-Kostomuksha olivine lamproite - Group II kimberlites NOTE Date of publ. Bulletin of the Geological Survey of Finland, Vol. 79, 2, pp. 203-215.Europe, Finlanddeposit - Lentiira Kuhmo

Abstract: The Lentiira-Kuhmo-Kostomuksha triangle, along the Finland - Russian border and within the central part of the Archean Karelian craton, contains numerous examples of phlogopite-rich, ultramafic, mantle-xenocryst-bearing and, in some cases, diamond-bearing dike rocks. Laser probe Ar-Ar data on phlogopite from 3 dike rocks on the Finnish side (Lentiira, Kuhmo) all gave ages within error of each other, 1202 ± 3 Ma (2?), 1199 ± 3 Ma (2?) and 1204 ± 4 Ma (2?) while a fourth sample produced mixed ages. Published Rb-Sr dates on mineralogically and chemically similar dikes from the Russian side (Kostomuksha) are 1232 ± 5 Ma. The question remains open whether these represent two distinct age populations or whether differences in isotopic system behavior are the reason for the 30 m.y. age difference.
DS201811-2596
2015
Ochoa, C.J.C., Herreno Daza, M.J., Fortaleche, D., Jimenez, J.F.Progress on the study of parameters related to the origin of Colombian diamonds.InColor, December pp. 88-97.South America, Colombiaemeralds
DS201810-2362
2018
Ogden, J.Diamonds - an early history of the King of Gems. Yale University Press, 408p. ISBN 978-0300215663Globalhistory

Abstract: This richly illustrated history of diamonds illuminates myriad facets of the “king of gems,” including a cast of larger-than-life characters such as Alexander the Great, the Mughal emperor Jahangir, and East India Company adventurers. It’s an in-depth study tracing the story of diamonds from their early mining and trade more than two thousand years ago to the 1700s, when Brazil displaced India as the world’s primary diamond supplier. Jack Ogden, a historian and gemologist specializing in ancient gems and jewelry, describes the early history of diamond jewelry, the development of diamond cutting, and how diamonds were assessed and valued. The book includes more than one hundred captivating images, from close-up full-color photographs of historic diamond-set jewelry (some previously unpublished), to photomicrographs of individual gems and illustrations of medieval manuscripts, as well as diagrams depicting historical methods of cutting and polishing diamonds.
DS201811-2597
2018
Ohuchi, T., Lei, X., Higo, Y., Tange, Y., Sakai, T., Fujino, K.Semi-brittle behavior of wet olivine aggregates: the role of aqueous fluid in faulting at upper mantle pressures.Contributions to Mineralogy and Petrology, Vol. 173, 21p. Doi.org/10.1007/s00410-018-1515-9Mantlesubduction

Abstract: The role of aqueous fluid in fracturing in subducting slabs was investigated through a series of deformation experiments on dunite that was undersaturated (i.e., fluid-free) or saturated with water (i.e., aqueous-fluid bearing) at pressures of 1.0-1.8 GPa and temperatures of 670-1250 K, corresponding to the conditions of the shallower regions of the double seismic zone in slabs. In situ X-ray diffraction, radiography, and acoustic emissions (AEs) monitoring demonstrated that semi-brittle flow associated with AEs was dominant and the creep/failure strength of dunite was insensitive to the dissolved water content in olivine. In contrast, aqueous fluid drastically decreased the creep/failure strength of dunite (up to ~ 1 GPa of weakening) over a wide range of temperatures in the semi-brittle regime. Weakening of the dunite by the aqueous fluid resulted in the reduction of the number of AE events (i.e., suppression of microcracking) and shortening of time to failure. The AE hypocenters were located at the margin of the deforming sample while the interior of the faulted sample was aseismic (i.e., aseismic semi-brittle flow) under water-saturated conditions. A faulting (slip rate of ~ 10?³ to 10?? s?¹) associated with a large drop of stress (?? ~ 0.5 to 1 GPa) and/or pressure (?P ~ 0.5 GPa) was dominant in fluid-free dunite, while a slow faulting (slip rate < 8 × 10?? s?¹) without any stress/pressure drop was common in water-saturated dunite. Aseismic semi-brittle flow may mimic silent ductile flow under water-saturated conditions in subducting slabs.
DS201805-0968
2018
Ono, K., Harada, Y., Yoneda, A., Yamamoto, J., Yoshiasa, A., Sugiyama, K., Arima, H., Watanabe, T.Determination of elastic constants of single crystal chromian spinel by resonant ultrasound spectroscopy and implications for fluid inclusion geobarometry.Physics and Chemistry of Minerals, Vol. 45, 3, pp. 237-247.Technologyxenolths

Abstract: We determined elastic constants of a single-crystal chromian spinel at temperatures from ?15 to 45 °C through the Rectangular Parallelepiped Resonance method. The sample is a natural chromian spinel, which was separated from a mantle xenolith. Elastic constants at an ambient temperature (T = 24.0 °C) are C 11 = 264.8(1.7) GPa, C 12 = 154.5(1.8) GPa and C 44 = 142.6(0.3) GPa. All the elastic constants decrease linearly with increasing temperature. The temperature derivatives are dC 11/dT = ?0.049(2) GPa/°K, dC 12/dT = ?0.019(1) GPa/°K and dC 44/dT = ?0.020(1) GPa/°K. As an implication of the elastic constants, we applied them to the correction of a fluid inclusion geobarometry, which utilizes residual pressure of fluid inclusion as a depth scale. Before entrainment by a magma, the fluid inclusions must have the identical fluid density in constituent minerals of a xenolith. It has been, however, pointed out that fluid density of fluid inclusions significantly varies with host mineral species. The present study elucidates that elastic constants and thermal expansion coefficients cannot explain the difference in fluid density among mineral species. The density difference would reflect the difference in the degree of plastic deformation in the minerals.
DS201804-0724
2016
Oriolo, S., Oyhantcabal, P., Basei. M.A.S., Wemmer, K., Siegesmund, S.The Nico Perez terrane ( Uruguay): from Archean crustal growth and connections with the Congo Craton to late Neoproterozoic accretion to the Rio de la Plat a Craton.Precambrian Research, Vol. 280, pp. 147-160.South America, Uruguaycraton - Rio de la Plata

Abstract: New U-Pb and first Hf data were obtained from the Nico Pérez and Piedra Alta Terranes as well as from the Congo Craton. Results indicate that the Nico Pérez Terrane was mostly built during Archean episodic crustal growth and this crust underwent significant Paleo- and Neoproterozoic crustal reworking at ca. 2.2-2.0, 1.7 and 0.6 Ga. The Piedra Alta Terrane of the Río de la Plata Craton, in contrast, records only Paleoproteorozoic crustal growth. These evidences together with available geological, geochronological and isotopic data indicate the allochthony of the Nico Pérez Terrane. Furthermore, data point to an African origin of the Nico Pérez Terrane, particularly related to the southwestern Congo Craton. After Cryogenian rifting from the latter during Rodinia break-up, the Nico Pérez Terrane was accreted to the eastern Río de la Plata Craton along the Sarandí del Yí Shear Zone and underwent further crustal reworking during the evolution of the Dom Feliciano Belt.
DS201803-0469
2017
Oriolo, S., Oyhantcabal, P., Wemmer, K., Siegesmund, S.Contemporaneous assembly of western Gondwana and final Rodinia break up: implications for the supercontinent cycle.Geoscience Frontiers, Vol. 8, pp. 1431-1445.South America, Braziltectonics

Abstract: Geological, geochronological and isotopic data are integrated in order to present a revised model for the Neoproterozoic evolution of Western Gondwana. Although the classical geodynamic scenario assumed for the period 800-700 Ma is related to Rodinia break-up and the consequent opening of major oceanic basins, a significantly different tectonic evolution can be inferred for most Western Gondwana cratons. These cratons occupied a marginal position in the southern hemisphere with respect to Rodinia and recorded subduction with back-arc extension, island arc development and limited formation of oceanic crust in internal oceans. This period was thus characterized by increased crustal growth in Western Gondwana, resulting from addition of juvenile continental crust along convergent margins. In contrast, crustal reworking and metacratonization were dominant during the subsequent assembly of Gondwana. The Río de la Plata, Congo-São Francisco, West African and Amazonian cratons collided at ca. 630-600 Ma along the West Gondwana Orogen. These events overlap in time with the onset of the opening of the Iapetus Ocean at ca. 610-600 Ma, which gave rise to the separation of Baltica, Laurentia and Amazonia and resulted from the final Rodinia break-up. The East African/Antarctic Orogen recorded the subsequent amalgamation of Western and Eastern Gondwana after ca. 580 Ma, contemporaneously with the beginning of subduction in the Terra Australis Orogen along the southern Gondwana margin. However, the Kalahari Craton was lately incorporated during the Late Ediacaran-Early Cambrian. The proposed Gondwana evolution rules out the existence of Pannotia, as the final Gondwana amalgamation postdates latest connections between Laurentia and Amazonia. Additionally, a combination of introversion and extroversion is proposed for the assembly of Gondwana. The contemporaneous record of final Rodinia break-up and Gondwana assembly has major implications for the supercontinent cycle, as supercontinent amalgamation and break-up do not necessarily represent alternating episodic processes but overlap in time.
DS201806-1237
2018
Osei Tutu, A., Sobolev, S.V., Steinberger, B., Popov, A.A., Rogozhina, I.Evaluating the influence of plate boundary friction and mantle viscosity on plate velocities.Geochemistry, Geophysics, Geosystems, Vol. 19, 3, pp. 642-666.Mantlegeophysics - seismic
DS201812-2858
2018
Ovsyuk, N.N., Goryainov, S.V., Likhacheva, A.Y.Raman scattering of impact diamonds. PopagaiDiamond & Related Materials, doi.1016/j.diamond .2018.11.017 24p. Russialonsdaleite
DS201811-2598
2018
Page, L., Hattori, K., Guillot, S.Mantle wedge serpentinites: a transient reservoir of halogens, boron and nitrogen for the deeper mantle.Geology, Vol. 46, 9, pp. 883-886.Mantlenitrogen

Abstract: Fluorine (50-650 ppm), bromine (0.03-0.3 ppm), iodine (0.03-0.4 ppm), boron (20-100 ppm) and nitrogen (5-45 ppm) concentrations are elevated in antigorite-serpentinites associated with the Tso Morari ultrahigh-pressure unit (Himalayas) exhumed from >100 km depth in the mantle wedge. These fluid-mobile elements are likely released with fluids from subducted marine sediments on the Indian continental margin to hydrate overlying forearc serpentinites at shallow depths. Of these, F and B appear to remain in serpentinites during the lizardite-antigorite transition. Our results demonstrate serpentinites as transient reservoirs of halogens, B, and N to at least 100 km depth in the mantle wedge, and likely deeper in colder slabs, providing a mechanism for their transport to the deeper mantle.
DS201804-0725
2018
Palke, A.C., Wong, J., Verdel, C., Avila, J.N.A common origin for Thai/Cambodian rubies and blue and violet sapphires from Yogo Gulch, Montana, U.S.A?American Mineralogist, Vol. 103, pp. 469-479.United States, Montanadeposit - Yogo Gulch

Abstract: A wide number of genetic models have been proposed for volcanically transported ruby and sapphire deposits around the world. In this contribution we compare the trace element chemistry, mineral and melt inclusions, and oxygen isotope ratios in blue to reddish-violet sapphires from Yogo Gulch, Montana, U.S.A., with rubies from the Chantaburi-Trat region of Thailand and the Pailin region of Cambodia. The similarities between Thai/Cambodian rubies and Yogo sapphires suggest a common origin for gem corundum from both deposits. Specifically, we advance a model whereby sapphires and rubies formed through a peritectic melting reaction when the lamprophyre or basalts that transported the gem corundum to the surface partially melted Al-rich lower crustal rocks. Furthermore, we suggest the protolith of the rubies and sapphires was an anorthosite or, in the case of Thai/Cambodian rubies, an anorthosite subjected to higher pressures and converted into a garnet-clinopyroxenite. In this model the rubies and sapphires are rightfully considered to be xenocrysts in their host basalts or lamprophyre; however, in this scenario they are not "accidental" xenocrysts but their formation is intimately and directly linked to the magmas that transported them to the surface. The similarities in these gem corundum deposits suggests that the partial melting, non-accidental xenocryst model may be more wide-reaching and globally important than previously realized. Importantly, in both cases the gem corundum has an ostensibly "metamorphic" trace element signature, whereas the presence of silicate melt (or magma) inclusions shows they ought to be considered to be "magmatic" rubies and sapphires. This discrepancy suggests that existing trace element discriminant diagrams intended to separate "metamorphic" from "magmatic" gem corundum ought to be used with caution.
DS201810-2363
2018
Pandey, A., Chalapthi Rao, N.V., Chrabarti, R., Sahoo, S.Post collisional calc-alkaline lamprophyres from the Kadiri greenstone belt: evidence for the Neoarchean convergence related evolution of the eastern Dharwar craton and its schist belts.Lithos, doi.10.1016/j.lithos .2018.09.005Indialamprophyres

Abstract: Lamprophyres from the greenstone belts play a crucial role in deciphering tectonic and geodynamic processes operating during the Archean. This study presents a comprehensive mineralogical and geochemical study of three lamprophyre dykes with calc-alkaline to shoshonitic affinities from the Neoarchean Kadiri schist belt, eastern Dharwar craton, southern India. These rocks display porphyritic-panidiomorphic texture, typical of the lamprophyres with amphibole (magnesio-hornblende) as phenocrysts, biotite as microphenocrysts and feldspar, epidote, titanite and apatite confined to the groundmass. Alteration of biotite to chlorite is observed along with mild deformation in the amphibole phenocrysts. Based on mineralogy and major oxide geochemistry, these rocks are classified as the calc-alkaline lamprophyres. Higher Ba/Nb and low Nb/La points to their derivation from an enriched lithospheric mantle source and higher Th/Yb ratio along with negative TNT (Ti-Nb-Ta) and Zr-Hf anomalies on the primitive mantle (PM) normalized multi-element diagram indicates dehydrated fluids from the foundering slab could be the possible metasomatic agent. Fractionated HREE ratios (GdN/YbN >1.9) and higher SmN/YbN suggests that the source region lies in the garnet stability field. Higher than PM Rb/Sr along with positive correlation between K/La and Rb/La reveals presence of metasomatic phlogopite in the source region. Strong negative initial ?Nd along with radiogenic 87Sr/86Sr ratios further support an enriched mantle reservoir involved in their genesis. Non-modal batch melting (1-5%) of a mixed source (phlogopite-garnet peridotite) assuming 5% mixing of subducted sediment with ambient mantle wedge (depleted mantle) satisfies the multi-element concentration pattern shown by the Kadiri lamprophyres. The source enrichment can be linked to the accretion-related growth of Dharwar craton and its schist belts during Neoarchean. Our study shows that a majority of lamprophyres associated with the Archean greenstone belts display a shoshonitic character; this highlights the role of subduction-related processes in the growth and evolution of the greenstone belts .
DS201801-0044
2017
Pandey, O.P., Chandrakala, K., Vasanthi, A., Satish Kumar, K.Seismically imaged shallow and deep crustal structure and potential field anomalies across the Eastern Dharwar Craton, south Indian shield: possible geodynamical implications.Journal of Asian Earth Sciences, in press available, 11p.Indiageophysics - seismics

Abstract: The time-bound crustal evolution and subsequent deformation of the Cuddapah basin, Nellore Schist Belt and Eastern Ghats terrain of Eastern Dharwar Craton, which have undergone sustained geodynamic upheavals since almost 2.0 billion years, remain enigmatic. An attempt is made here to integrate newly available potential field data and other geophysical anomalies with deep seismic structure, to examine the generative mechanism of major crustal features, associated with this sector. Our study indicates that the initial extent of the Cuddapah basin sedimentation may have been much larger, extending by almost 50-60?km west of Tadipatri during Paleoproterozoic period, which subsequently shrank due to massive erosion following thermal uplift, caused by SW Cuddapah mantle plume. Below this region, crust is still quite warm with Moho temperatures exceeding 500?°C. Similarly, Nallamalai Fold Belt rocks, bounded by two major faults and extremely low gravity, may have occupied a large terrain in western Cuddapah basin also, before their abrasion. No geophysical signatures of thrusting are presently seen below this region, and thus it could not be an alien terrain either. In contrast, Nellore Schist Belt is associated with strikingly high positive gravity, possibly caused by a conspicuous horst structure and up dipping mafic crustal layers underneath, that resulted due to India-east Antarctica collision after the cessation of prolonged subduction (1.6-0.95?Ga). Further, the crustal seismic and gravity signatures would confirm presence of a totally distinct geological terrain east of the Cuddapah basin, but the trace of Eastern Ghats Belt is all together missing. Instead, all the geophysical signatures, point out to presence of a Proterozoic sedimentary terrain, east of Nellore Schist Belt. It is likely that the extent of Prorerozoic sedimentation was much larger than thought today. In addition, presence of a seismically detected Gondwana basin over Nellore Schist Belt, apart from some recently discovered similar subsurface Gondwana occurrences in intracratonic parts, would indicate that Dharwar Craton was rifting even during Gondwana period, thereby challenging the long held view of cratonic stability.
DS201805-0969
2018
Pandey, O.P., Chandrakala, K., Vasanti, A., Kumar, K.S.Seismically imaged shallow and deep crustal structure and potential field anomalies across the Eastern Dharwar Craton, South Indian shield: possible geodynamical implications.Journal of Asian Earth Sciences, Vol. 157, pp. 302-316.Indiageophysics - seismics

Abstract: The time-bound crustal evolution and subsequent deformation of the Cuddapah basin, Nellore Schist Belt and Eastern Ghats terrain of Eastern Dharwar Craton, which have undergone sustained geodynamic upheavals since almost 2.0 billion years, remain enigmatic. An attempt is made here to integrate newly available potential field data and other geophysical anomalies with deep seismic structure, to examine the generative mechanism of major crustal features, associated with this sector. Our study indicates that the initial extent of the Cuddapah basin sedimentation may have been much larger, extending by almost 50-60?km west of Tadipatri during Paleoproterozoic period, which subsequently shrank due to massive erosion following thermal uplift, caused by SW Cuddapah mantle plume. Below this region, crust is still quite warm with Moho temperatures exceeding 500?°C. Similarly, Nallamalai Fold Belt rocks, bounded by two major faults and extremely low gravity, may have occupied a large terrain in western Cuddapah basin also, before their abrasion. No geophysical signatures of thrusting are presently seen below this region, and thus it could not be an alien terrain either. In contrast, Nellore Schist Belt is associated with strikingly high positive gravity, possibly caused by a conspicuous horst structure and up dipping mafic crustal layers underneath, that resulted due to India-east Antarctica collision after the cessation of prolonged subduction (1.6-0.95?Ga). Further, the crustal seismic and gravity signatures would confirm presence of a totally distinct geological terrain east of the Cuddapah basin, but the trace of Eastern Ghats Belt is all together missing. Instead, all the geophysical signatures, point out to presence of a Proterozoic sedimentary terrain, east of Nellore Schist Belt. It is likely that the extent of Prorerozoic sedimentation was much larger than thought today. In addition, presence of a seismically detected Gondwana basin over Nellore Schist Belt, apart from some recently discovered similar subsurface Gondwana occurrences in intracratonic parts, would indicate that Dharwar Craton was rifting even during Gondwana period, thereby challenging the long held view of cratonic stability.
DS201806-1238
2018
Pandey, R., Sahoo, S., Pandit, D., Chalapathi Rao, N.V.Recurrent lamprophyre magmatism in the Narmada rift zone: petrographic and mineral chemistry evidence from xenoliths in the Eocene Dongargaon lamprophyre, NW Deccan Large Igneous Province India.Journal of the Indian Institute of Science, 15p. available in pressIndiamagmatism

Abstract: We report rare occurrence of lamprophyre xenoliths within a host lamprophyre from the Dongargaon area, Deccan Large Igneous Province, NW India. The lamprophyre xenoliths are distinct in texture (grain size) as well in mineralogy from those of their host rock. The clinopyroxene (diopside) in the xenoliths is depleted in Ca and Mg but substantially enriched in Fe compared to those in the host lamprophyre. Mica in the xenoliths is a phlogopite whereas that present in the host rock is compositionally a biotite; spinels in the host lamprophyre are relatively enriched in TiO2. As the host lamprophyre dyke has been dated to be of Eocene (ca. 55 Ma) age, the entrained lamprophyre xenoliths are inferred to represent an earlier pulse of lamprophyre emplacement. The recurrent lamprophyre emplacement in this domain is consistent with the recently brought out polychronous nature of Late Cretaceous alkaline magmatism at the Mundwara and Sarnu Dandali complexes in the NW India and is related to the extensional events linked with the reactivation of the Narmada rift zone.
DS201801-0045
2017
Pandit, M.K.Paleoproterozoic carbonatites Newania and Hogenkkal: geochemical and isotoopic characteristics.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 24.Indiadeposit - Newania. Hogenkkal

Abstract: Several carbonatite occurrences ranging in age from Proterozoic to Phanerozoic are known and reported from India. Only two amongst them, the Hogenakkal and Newania carbonatites are Paleoproterozoic in age. The Newania carbonatite body, emplaced within Mesoarchean Untala Granite, comprises predominantly dolomiticcarbonatite and minor ankeritic and sövitic phases, in the chronological order. Only the dolomitic-carbonatites have mantle like C- and O-isotopic characteristics and some authors argue that the ankeritic phase is its alteration product while sövite represents late stage calcite veins. The Pb - Pb geochronology yields high ratios and 2.23 Ga age for the dolomitic carbonatite and extremely high Pb/Pb ratios resulting in an unrealistic 1550 Ma age for the ankeritic phase. Melt residence in an intermediate upper mantle/lower crust reservoir, prior to emplacement, has been postulated for the high Pb/Pb ratios observed in dolomitic carbonatites. The 2.4 Ga Hogenakkal carbonatites occur in the northern part of the Southern Granulite Terrane as small isolated bodies hosted within two sub-parallel pyroxenite dykes within a milieu of Archean charnockites. These are fine to mediumgrained and named as sövite, silicate sövite and melanocratic silicate sövite, based upon calcite or calcite + pyroxene as dominant mineralogy. The C- and O-isotopic ratios for all the varieties are remarkably consistent and represent unmodified mantle values (-5.8 to - 6.7‰ V-PDB and 7.2 to 8.7‰ V-SMOW, respectively). However, diversity in Sr- and Nd-isotopic characteristics suggest both enriched and depleted source characteristics and call for a heterogeneous mantle beneath the SGT. Both the groups do indicate presence of an enriched mantle component during late Archean
DS201808-1775
2017
Paquette, J.L., Ionov, D.A., Agashev, A.M., Gannoun, A., Nikolenko, E.I.Age, provenance and Precambrian evolution of the Anabar shield from U Pb and Lu Hf isotope dat a on detrital zircons, and the history of the northern and central Siberian craton.Precambrian Research, Vol. 301, pp. 134-144.Russiacraton

Abstract: The Anabar shield in northern Siberia is one of the world’s least studied Precambrian areas, and provides a ‘window’ into the crustal basement of the central and northern Siberian craton. We report U-Pb and Hf isotope data for detrital zircons sampled in a profile across its major structural units. They define a U-Pb age range from 1.8 to 3.4 Ga with three main periods: 1.8-2.0 Ga, 2.4-2.8 Ga and 3.0-3.4 Ga. The oldest zircons yield super-chondritic ?Hf(t) implying that the parental magmas of their source rocks were juvenile, i.e. formed from depleted mantle (DM). Thus, the crustal basement of the Anabar shield, and probably the whole central and northern Siberian craton, started to form in the mid-Paleoarchean, and included no recycled crust. Zircons with 2.5-2.7 Ga ages define two ?Hf(t) intervals. One is super-chondritic (+2 to +7) implying juvenile sources, the other is sub-chondritic (?3 to ?12) indicative of recycled crust, probably formed at 3.2-3.4 Ga, in magma sources. Nearly all 1.8-2.0 Ga zircons have sub-chondritic ?Hf(t) (?2 to ?29) implying derivation from sources dominated by recycled crust formed at ?2.6 Ga and ?3.4 Ga and little or no juvenile addition. These events accompanied amalgamation of the entire craton by welding of Archean domains. The Bekelekh unit of the Daldyn series has the highest proportion of ?2.6 Ga zircons and may be the oldest ‘nucleus’ of the Anabar shield, whereas the Kilegur unit of the same series is essentially Proterozoic (1.95 Ga). The largest amount of 3.1-3.4 Ga zircons, as well as common 2.6-2.7 Ga zircons, occur in the Ambardakh unit of the Upper Anabar series. Our data suggest alternation of areas with dominant ages of 1.95 Ga and ?2.6 Ga, with the younger zircons coming from granites and granulites, and the older ones from gneisses. They show no evidence for significant ages differences for the Anabar and Olenek provinces. The final amalgamation of the entire Siberian craton by welding of Archean blocks, may have taken place at around 1954 ± 6 Ma.
DS201812-2859
2018
Passos, G.Diamond Province of Juina - MT: history of production, types of deposits and exploration frontiers.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Mato Grossodeposit - Juina
DS201806-1239
2018
Patwardhan, B., Nagarkar, S., Gadre, S.R., Lakhotia, S.C., Katoch, V.M., Moher, D.A critical analysis of the 'UGC' approved list of journals.Current Science, Vol. 114, 6, Mar. 25, pp. 1299-1303.Indialegal

Abstract: Scholarly journals play an important role in maintaining the quality and integrity of research by what they publish. Unethical practices in publishing are leading to an increased number of predatory, dubious and low-quality journals worldwide. It has been reported that the percentage of research articles published in predatory journals is high in India. The University Grants Commission (UGC), New Delhi has published an 'approved list of journals', which has been criticized due to inclusion of many substandard journals. We have developed a protocol with objective criteria for identifying journals that do not follow good publication practices. We studied 1336 journals randomly selected from 5699 in the university source component of the 'UGC-approved list'. We analysed 1009 journals after excluding 327 indexed in Scopus/Web of Science. About 34.5% of the 1009 journals were disqualified under the basic criteria because of incorrect or non-availability of essential information such as address, website details and names of editors; another 52.3% of them provided false information such as incorrect ISSN, false claims about impact factor, claimed indexing in dubious indexing databases or had poor credentials of editors. Our results suggest that over 88% of the non-indexed journals in the university source component of the UGC-approved list, included on the basis of suggestions from different universities, could be of low quality. In view of these results, the current UGC-approved list of journals needs serious reconsideration. New regulations to curtail unethical practices in scientific publishing along with organization of awareness programmes about publication ethics at Indian universities and research institutes are urgently needed.
DS201802-0257
2017
Pavlushin, A.D., Zedgenizov, D.A., Pirogovskaya, K.L.Crystal morphological evolution of growth and dissolution of curve faced cubic diamonds from placers of the Anabar Diamondiferous region.Geochemistry International, Vol. 55, 12, pp. 1193-1203.Russiadiamond - crystallography

Abstract: In this paper, we consider an ontogenic model for the formation of morphological types of growth and dissolution of cubic diamonds of variety II by Yu.L. Orlov from placers of the Anabar diamondiferous region. The following ontogenic domains of crystals and corresponding evolutionary stages of growth accompanying a general decrease in supersaturation in the crystallization medium were distinguished: microblock mosaic cuboids with defects produced by the mechanism of rotational plastic deformation-cuboids with linear translation deformations-cuboids and antiskeletal growth forms of cuboids composed of octahedral growth layers-pseudocubic growth forms of a flat-faced octahedron. The crystal morphological evolution of cuboids during the bulk dissolution of individuals in fluid-bearing melt transporting them to the surface was traced. The investigation of transitional forms of cuboid diamond dissolution showed that the final form of diamond dissolution is a rounded tetrahexahedroid independent of the combination of cuboid faces with subordinate faces of octahedron, rhombododecahedron, and tetrahexahedron observed on resorbed crystals of cubic habit. It was found that the final stages of cuboid dissolution produced disk-shaped microrelief features on the diamond surface in the form of randomly distributed ideal rounded etch pits resulting from interaction with microscopic cavitation gas bubbles released during the decompression of ascending kimberlite melt.
DS201804-0726
2018
Pearson, D.G.Making and stabilising the deep diamond bearing roots of continents.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 33-35. abstractMantlecraton - peridotites
DS201812-2860
2018
Pearson, D.G., Liu, J., Smith, C.B., Mather, K.A., Krebs, M.Y., Bulanova, G.P., Kobussen, A.F.Murowa deposit: Characteristics and origin of the mantle root beneath the Murowa diamond mine: implications for craton and diamond formation.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 403-424.Africa, Zimbabwedeposit - Murowa
DS201804-0727
2018
Pell, J., Russell, J.K., Zhang, S.Z.Conodont geothermometry in pyroclastic kimberlite: constraints on emplacement temperatures and cooling histories.Mineralogy and Petrology, in press available 14p.Canada, Nunavut, Baffin Islanddeposit - Chidliak

Abstract: Kimberlite pipes from Chidliak, Baffin Island, Nunavut, Canada host surface-derived Paleozoic carbonate xenoliths containing conodonts. Conodonts are phosphatic marine microfossils that experience progressive, cumulative and irreversible colour changes upon heating that are experimentally calibrated as a conodont colour alteration index (CAI). CAI values permit us to estimate the temperatures to which conodont-bearing rocks have been heated. Conodonts have been recovered from 118 samples from 89 carbonate xenoliths collected from 12 of the pipes and CAI values within individual carbonate xenoliths show four types of CAI distributions: (1) CAI values that are uniform throughout the xenolith; (2) lower CAIs in core of a xenolith than the rim; (3) CAIs that increase from one side of the xenolith to the other; and, (4) in one xenolith, higher CAIs in the xenolith core than at the rim. We have used thermal models for post-emplacement conductive cooling of kimberlite pipes and synchronous heating of conodont-bearing xenoliths to establish the temperature-time history of individual xenoliths within the kimberlite bodies. Model results suggest that the time-spans for xenoliths to reach the peak temperatures recorded by CAIs varies from hours for the smallest xenoliths to 2 or 3 years for the largest xenoliths. The thermal modelling shows the first three CAI patterns to be consistent with in situ conductive heating of the xenoliths coupled to the cooling host kimberlite. The fourth pattern remains an anomaly.
DS201805-0970
2001
Peltonen, P., Manttari, I.An ion microprobe U Th Pb study of zircon xenocrysts from the Lahtojoki kimberlite pipe, eastern Finland. NOTE Date of publ.Bulletin of the Geological Survey of Finland, Vol. 73, 1-2, pp. 47-58.Europe, Finlanddeposit - Lahtojoki

Abstract: Eleven relatively large (diameter 1-2 mm) zircon grains extracted from the Lahtojoki kimberlite pipe (Eastern Finland Kimberlite Province) have been analysed by the ion microprobe NORDSIM for their U- and Pb- isotopic composition. The 207Pb/206Pb ages fall into two concordant age groups: 2.7 Ga and 1.8 Ga. Discordant ages between these two groups are believed to result from partial resetting of Archaean grains in the 1.8 Ga thermal event. Since other datingmethods imply that kimberlites emplaced c. 0.6 Ga ago it is clear that the analysed zircons are xenocrysts inherited from older sources and do not provide the age of the kimberlite magmatism. Their unusual size and morphology, together with very low U- and Pb-concentrations, suggest, however, that these zircon grains are not derived from typical Archaean gneisses. More likely, they originate from lower crustal mafic pegmatites and from hydrous coarse-grained veins within the uppermost lithospheric mantle. The predominance of 1.8 Ga old xenocrystic grains, together with the recovery of mafic granulite xenoliths of similar age in the kimberlites (Hölttä et al. 2000), emphasises the importance of post-collisional lower crustal growth and reworking in central Fennoscandia.
DS201807-1521
2018
Pendock, N.Regional diamond exploration under cover. ASTER bands, LWIR indicator mineralsSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 103-112.Africa, Botswanadeposit - Orapa, Damtshaa, BK09, BK12,AK01
DS201807-1522
2016
Pendock, N.Hot stones: mapping igneous kimberlites under Kalahari cover using LWIR imagery.www.grsg.org.uk/wp-content/uploads/2017/01/Day2/Neil%20Pendock%20RSA.pdf, 29 ppts. AvailableAfrica, Botswanageospectral
DS201808-1776
2018
Pendock, N.Regional diamond exploration under cover. PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 26 ppts.Africa, Botswanageophysics
DS201812-2861
2018
Perchuk, A.L., Yapaskurt, V.O., Zinovieva, N.G., Shur, M. Yu.Experimental evidence for opposite fluxes of sodium, potassium, and CO2 during glaucophane schist interaction with harzburgite and websterite in subduction zones.Petrology, Vol. 26, 6, pp. 599-616.Mantlemetasomatism

Abstract: This paper reports the results of high-pressure experimental modeling of interaction between glaucophane schist and harzburgite or websterite for the evaluation of the influence of mantle material on the input-output of components and character of metasomatic transformations at the crust-mantle boundary in the subduction zone. In all experiments, glaucophane schist (proxy for oceanic crust) containing volatile components (H2O and CO2) incorporated in hydrous minerals (amphiboles, phengite, and epidote) and calcite was loaded into the bottom of each capsule and overlain by mantle material. During the experiments at a temperature of 800°C and a pressure of 2.9 GPa, which correspond to the conditions of a hot subduction zone, the schist underwent partial (up to 10%) eclogitization with the formation of the anhydrous assemblage omphacite + garnet + quartz ± magnesite ± potassic phase. Carbonate and a potassic phase were formed only in the experiments with websterite in the upper layer. A reaction zone was formed at the base of the websterite layer, where newly formed omphacite, quartz, and orthopyroxene replaced in part initial pyroxenes. Orthopyroxene and phlogopite (or an unidentified potassic phase) were formed in the reaction zone at the base of the harzburgite layer; among the initial minerals, only orthopyroxene relicts were preserved. Above the reaction zones produced by diffusion metasomatism, new phases developed locally, mainly at grain boundaries: newly formed orthopyroxene and magnesite were observed in harzburgite, and omphacite and quartz, in websterite. Alterations along grain boundaries extended much further than the reaction zones, which indicates that fluid infiltration dominated over diffusion in the experiments. The experiments demonstrated that the H2O-CO2 fluid with dissolved major components released from the glaucophane schist can produce mineral assemblages of different chemical compositions in mantle materials: Na-bearing in websterite and K-bearing in harzburgite. The complementary components, K2O and CO2 for the websterite layer and Na2O for the harzburgite layer, are fixed in the initial glaucophane schist layer. The distinguished separation of alkalis and CO2 at the crust-mantle boundary can affect the character of metasomatism in the mantle wedge, primary magma compositions, and the chemical evolution of the rocks of the subducting slab.
DS201804-0728
2018
Perkins, S.Pockets of water may lie deep below Earth's surface.sciencemag.org, 10.1126/science.aat5630Mantlegeophysics

Abstract: Small pockets of water exist deep beneath Earth’s surface, according to an analysis of diamonds belched from hundreds of kilometers within our planet. The work, which also identifies a weird form of crystallized water known as ice VII, suggests that material may circulate more freely at some depths within Earth than previously thought. Geophysical models of that flow, which ultimately influences the frequency of earthquakes driven by the scraping of tectonic plates at Earth’s surface, may need to be substantially tweaked, scientists say. Such models also help scientists estimate the long-term rates of heat flow through Earth’s surface and into space.
DS201811-2599
2015
Perretti, A., Bieri, W.Flying into the heart of the Colombian emerald mining region.InColor, December pp. 32-43South America, Colombiaemeralds
DS201810-2364
2018
Perrin, A., Goes, S., Prytulak, J., Rondenay, S., Davies, D.R.Mantle wedge temperatures and their potential relation to volcanic arc location.Earth and Planetary Science Letters, Vol. 501, pp. 67-77.Mantlesubduction

Abstract: The mechanisms underpinning the formation of a focused volcanic arc above subduction zones are debated. Suggestions include controls by: (i) where the subducting plate releases water, lowering the solidus in the overlying mantle wedge; (ii) the location where the mantle wedge melts to the highest degree; and (iii) a limit on melt formation and migration imposed by the cool shallow corner of the wedge. Here, we evaluate these three proposed mechanisms using a set of kinematically-driven 2D thermo-mechanical mantle-wedge models in which subduction velocity, slab dip and age, overriding-plate thickness and the depth of decoupling between the two plates are systematically varied. All mechanisms predict, on the basis of model geometry, that the arc-trench distance, D, decreases strongly with increasing dip, consistent with the negative D-dip correlations found in global subduction data. Model trends of sub-arc slab depth, H, with dip are positive if H is wedge-temperature controlled and overriding-plate thickness does not exceed the decoupling depth by more than 50 km, and negative if H is slab-temperature controlled. Observed global H-dip trends are overall positive. With increasing overriding plate thickness, the position of maximum melting shifts to smaller H and D, while the position of the trenchward limit of the melt zone, controlled by the wedge's cold corner, shifts to larger H and D, similar to the trend in the data for oceanic subduction zones. Thus, the limit imposed by the wedge corner on melting and melt migration seems to exert the first-order control on arc position.
DS201810-2365
2018
Persikov, E.S., Bukhityarov, P.G., Sokol, A.G.Viscosity of haplokimberlitic and basaltic melts at high pressures: experimental and theoretical studies.Chemical Geology, Vol. 497, pp. 54-63.MantleUHP

Abstract: Only limited data are available at present on the viscosity of kimberlite magmas. We investigate viscosity of synthetic carbonate-bearing (silicate82?+?carbonate18, wt%, 100NBO/T?=?313) anhydrous haplokimberlite melts theoretically and in experiments. We use new experimental data on viscosity of anhydrous haplokimberlite melts and a physical-chemical model (Persikov and Bukhtiyarov 2009; Persikov et al. 2015) to compare basic viscosity features in kimberlitic and basaltic melts (100NBO/T?=?56). Viscosity of melts is determined by the falling sphere quenching method in a large range of temperatures from 1300 to 1950?°C and pressures up to 7.5?GPa. We use two types of high-pressure apparatuses: a high gas pressure apparatus and a high pressure split-sphere multi-anvil apparatus to study the viscosity of melts at moderate (100?MPa CO2 pressure) and high (5.5?GPa and 7.5?GPa) pressures, respectively. The measured viscosity ranges for anhydrous haplokimberlite melts are from 1.5 (±0.45) to 0.11(±0.03) Pa s. The temperature dependence of the viscosity of haplokimberlite and basaltic melts is consistent with the theoretical Arrhenian equation. At a constant temperature, viscosity of anhydrous haplokimberlite melts increases exponentially about ten-fold as pressure increases from 100?MPa to 7.5?GPa. The activation energy of viscous flow increases linearly with pressure increase from 100?MPa to 7.5?GPa for anhydrous haplokimberlite melts but decreases in the case of basaltic melts, with the minimum at ~5.5?GPa. At a moderate pressure (100?MPa), haplokimberlite melts are about twenty times less viscous than basaltic melts, but are about four times more viscous at a high pressure (7.5?GPa), the temperature being 1800?°C in both cases. The experimentally observed behavior of the viscosity of anhydrous haplokimberlite melts is consistent with predictions of the physical-chemical model within the range of uncertainties in both experimental and calculated data (±30% rel.). Thus, the physical-chemical model is used to discuss possible effects of volume percentages of crystals and bubbles on viscosity of kimberlitic and basaltic magmas at different pressures and temperatures during their origin, evolution, and ascent.
DS201803-0470
2017
Persikov, E.S., Bukhtiyarov, P.G., Sokol, A.G.Viscosity of hydrous kimberlite and basaltic melts at high pressures.Russian Geology and Geophysics, Vol. 58, pp. 1093-1100.Mantlemelting

Abstract: New experimental data on the temperature and pressure dependences of the viscosity of synthetic hydrous kimberlite melts (82 wt.% silicate + 18 wt.% carbonate; degree of depolymerization: 100NBO/T = 313 for anhydrous melts and 100NBO/T = 247 for melts with 3 wt.% H2O) were obtained at a water pressure of 100 MPa and at lithostatic pressures of 5.5 and 7.5 GPa in the temperature range 1300-1950 °C. The temperature dependence of the viscosity of these melts follows the exponential Arrhenius-Frenkel-Eyring equation in the investigated range of temperatures and pressures. The activation energies of viscous flow for hydrous kimberlite melts were first shown to increase linearly with increasing pressure. Under isothermal conditions (T = 1800 °C), the viscosity of hydrous kimberlite melts increases exponentially by about an order of magnitude as the pressure increases from 100 MPa to 7.5 GPa. The new experimental data on the viscosity of hydrous kimberlite melts (error ± 30 rel.%) are compared with forecast viscosity data for anhydrous kimberlite and basaltic melts (100NBO/T = 51.5) and for hydrous basaltic melts (100NBO/T = 80). It is shown that at comparable temperatures, the viscosity of hydrous kimberlite melts at a moderate pressure (100 MPa) is about an order of magnitude lower than the viscosity of hydrous basaltic melts, whereas at a high pressure (7.5 GPa) it is more than twice higher. It is first established that water dissolution in kimberlite melts does not affect seriously their viscosity (within the measurement error) at both moderate (100 MPa) and high (7.5 GPa) pressures, whereas the viscosity of basaltic melts considerably decreases with water dissolution at moderate pressures (100 MPa) and remains unchanged at high pressures (P > 3.5 GPa).
DS201812-2862
2018
Peters, M.H., Henderson, J.Bridging the gap through care and collaboration: before closure and after production. Snap Lake2018 Yellowknife Geoscience Forum , pp. 60-61. abstractCanada, Northwest territoriesdeposit - Snap Lake

Abstract: Wikipedia defines “Care and Maintenance” as a term used in the mining industry to describe processes and conditions on a closed mine site where there is potential to recommence operations at a later date. During a care and maintenance phase, production is stopped but the site is managed to ensure it remains in a safe and stable condition. De Beers Canada Inc. - Snap Lake Mine entered the Care and Maintenance phase after production ceased in December 2015. The partnership with Det'on Cho Corporation provides for a sustainable execution of care and maintenance activities, taking into consideration approved work plans, mine health and safety considerations and emergency response plans. The mine is currently in its third year of care and maintenance. After exploring the potential sale of the asset and assessing the possibility of reopening the mine, the decision to proceed toward closure was taken in December 2017, ushering Snap Lake into a period of extended care and maintenance (ECM) while a closure plan is developed and finalized. Activities during ECM include monitoring of water quality and other environmental parameters, collecting/treating effluent and making sure that water leaving the site meets water license compliance. Physical infrastructure such as the airstrip, roads, buildings, processed kimberlite containment facilities and associated surface water infrastructure such as sumps, pumps and channels need to be kept in a safe and operable condition. Camp infrastructure such as generators and machinery and equipment are also part of the Care and Maintenance program. Collaboration between the De Beers Canada owner's team and Det'on Cho Corporation resulted in the safe execution of the 2018 work plan which included freshet operations, continued progressive reclamation work, monitoring and maintenance activities. After a trial-run of reduced camp occupancy in the winter of 2017, the site was fully winterized and demobilized in September 2018 to allow for monthly site visits for the duration of the winter and planning for a spring 2019 start-up.
DS201811-2600
2018
Petit, T., Puskar, L.FTIR spectroscopy of nanodiamonds: methods and interpretation.Diamond & Related Materials, Vol. 89, pp. 52-66.Mantlenanodiamonds

Abstract: Fourier transform infrared spectroscopy (FTIR) is highly sensitive to the surface chemistry of nanodiamonds. In this review, we discuss the different FTIR methods available to characterize nanodiamonds and highlight their advantages and limitations. We also summarize the possible assignments of FTIR spectra of nanodiamonds reported in the literature and discuss FTIR spectra of nanodiamonds modified by different surface treatments. Current work of FTIR applied to in situ and operando characterization of nanodiamonds, in particular nanodiamonds exposed to water or characterized during electrochemical and photocatalytic processes, are also discussed. Finally, perspectives regarding possible future FTIR development for nanodiamonds characterization are proposed.
DS201812-2863
2018
Petit, T., Puskar, L.FTIR spectroscopy of nanodiamonds: methods and interpretation.Diamond & Related Materials, Vol. 89, pp. 52-66.Europe, Germanynanodiamonds
DS201808-1777
2018
Pflander, J.A., Jung, S., Klugel, A., Munker, C., Romer, R.L., Sperner, B., Rohrmuller, J.Recurrent local melting of metasomatised lithospheric mantle in response to continental rifting: constraints from basanites and nephelinites/melilitites from SE Germany.Journal of Petrology, Vol. 59, 4, pp. 667-694.Europe, Germanymelilitites

Abstract: Cenozoic primitive basanites, nephelinites and melilitites from the Heldburg region, SE Germany, are high-MgO magmas (8•5-14•1?wt % MgO), with low SiO2 (34•2-47•1?wt %) and low to moderately high Al2O3 (9•0-15•5?wt %) and CaO (8•7-12•7?wt %). The Ni and Cr contents of most samples are up to 470?ppm and 640?ppm, respectively, and match those inferred for primary melts. In multi-element diagrams, all samples are highly enriched in incompatible trace elements with chondrite-normalised La/Yb?=?19-45, strongly depleted in Rb and K, with primitive mantle normalised K/La?=?0•15-0•72, and moderately depleted in Pb. The initial Sr-Nd-Hf isotope compositions (87Sr/86Sr?=?0•7033-0•7051, 143Nd/144Nd?=?0•51279-0•51288 and 176Hf/177Hf?=?0•28284-0•28294) fall within the range observed for other Tertiary volcanic rocks of the Central European Volcanic Province, whereas 208Pb/204Pb and 206Pb/204Pb (38•42-38•88 and 18•49-18•98) are distinctly lower at comparable 207Pb/204Pb (15•60-15•65). Trace element modelling and pressure-temperature estimates based on major element compositions and experimental data suggest that the nephelinites/melilitites formed within the lowermost lithospheric mantle, close to the lithosphere-asthenosphere boundary, by ?3-5% partial melting of a highly enriched, metasomatised, carbonated phlogopite-bearing garnet-lherzolite at temperatures?<1250?°C and pressures of ?2•8?GPa. This corresponds to a melting depth of less than ?85?km. Formation and eruption of these magmas, based on 40Ar/39Ar dating, started in the late Eocene (38•0 Ma) and lasted until the late Oligocene (25•4 Ma). Basanite eruptions occurred in the same area in the middle Miocene, about 7•7 Myr after nephelinite/melilitite generation has ceased, and lasted from 17•7 to 13•1 Ma. The basanites were generated at lower pressures (2•2-1•7?GPa) at similar temperatures (?1220-1250?°C) within the spinel stability field in the lithospheric mantle by 2-6% partial melting. Isotope and trace element systematics indicate that the lithospheric mantle source of the Heldburg magmas was affected by metasomatism associated with long-lasting subduction of oceanic and continental crust during the Variscan orogeny. Aqueous or supercritical fluids that formed at temperatures?<1000?°C and pressures of likely?>4?GPa infiltrated the thermal boundary layer at the base of the lithospheric mantle and imprinted a crustal lead isotope, and to a minor extent crustal Sr, Nd and Hf isotope signatures. They also reduced Nb/U, Ce/Pb, Lu/Hf, Sm/Nd, U/Pb and Th/Pb, but increased Rb/Sr and Nb/Ta and amplified the enrichment of LILE and LREE relative to HREE. This lead to the highly-enriched trace element patterns observed in both sample suites, and to overall less radiogenic 206Pb/204Pb and 208Pb/204Pb compared to other continental basalts in Central Europe, and to less radiogenic 176Hf/177Hf and 143Nd/144Nd that plot distinctly below the terrestrial mantle array. Temporal evolution of magmatism in the Heldburg region coincides with the changing Tertiary intraplate stress field in Central Europe, which developed in response to the Alpine orogeny. Magmatism was most probably caused in response to lithosphere deformation and perturbation of the thermal boundary layer, and not by actively upwelling asthenosphere.
DS201809-2076
2018
Phani, P.R., Srinivas, M.Petrogenesis and diamond prospectivity of kimberlites of Anumpalli cluster, Wajrakarur field, southern India.Goldschmidt Conference, 1p. AbstractIndiadeposit - Anumpalli

Abstract: The Wajrakarur kimberlite field (WKF) records >45 pipes so far, majority being diamodiferous. In addition to pipe-10 (Anumpalli) and 11 (Dibbasanipalli) discovered by the Geological Survey of India, of late, Rio Tinto Group has discovered three more outcropping pipes in this area (east of Dibbasanipalli, west of Anumpalli and Khaderpet) and termed all these five pipes as Anumpalli kimberltie cluster (AKC). The AKC pipes contain crustal granitoid xenoliths. The Khaderpet and Dibbasanipalli east pipes show effects of fenitisation in the country rock granitoids and are intensely chloritised kimberlite granite breccias; however, the former is unique in having its association with carbonatite (sovite) intrusion. Petrographically, the AKC kimberlites exhibit inequigranular texture resulted by anhedral to subhedral olivine macrocrysts and pseudomorphs, phenocrysts of Crdiopside, ilmenite, perovskite and minor or no amounts of phologopite with two generations of olivine within a finegrained matrix of same mineral phases. Based on the major element geochemistry the AKC pipes are classified as Group- I archetypal. Based on trace element modeling, the AKC pipes appear to be originated form garnet lherzolite source with residual garnet of 0.5 to 5%, associated with stable continental and/or orogenic area and remarkably belong to non-subduction environment. The observed LREE enrichment and low HREE cencentrations in the AKC, is consistent with inferior degrees of partial melting (0.1 to 2%). The AKC pipes appear to have originated from a hydrous magma enriched in volatiles. Exploration evidences support that kimberlites of the AKC are diamodiferous. The calculated diamond grade (DG) values of the AKC pipes are high (3.43 to 8.48) which are inversely proportional to the TiO2 content. In the binary diagram of Ta and Sc (ppm), the AKC pipes plot in the field of ‘Fe-Ti diamondiferous kimberlites’. In the Fe2O3 (wt %) vs. Y (ppm) diagram, the AKC pipes plot in the ‘prospective’ field. The diamondiferous nature of the AKC pipes indicates the conditions of diamond preservation at metastable phases in crustal environment during rapid ascent of kimberlite melt to the surface from the deep mantle, which is supported by low density and ultralow viscosity of these intrusions.
DS201801-0046
2017
Phani, P.R.C.A new kimberlite pipe in Balkamthota Vanka, Pennahobilam, Anantapur district, Andhra Pradesh, India - field aspects and preliminary investigations.periodicomineralogia.it, Vol. 86, 3, 7p.India, Andhra Pradeshdeposit - Balkamthota Vanka

Abstract: Systematic closely spaced geological traverses conducted in the year 2010, in Lattavaram Kimberlite Cluster (LKC) of Anantapur district, Andhra Pradesh, India, have led to the discovery of a new kimberlite pipe outcrop in the river bed of Balkamthota Vanka (name of the stream used by local farmers) at its confluence with Penna River, close to Pennahobilam. This new pipe occurs at a distance of 1.5 km in NE direction to hitherto reported pipes-5 and 13 occurring at Muligiripalli and Tummatapalli respectively in the LKC of the Wajrakarur Kimberlite Field (WKF). With this pipe, the total number of kimberlite pipes in the WKF raises to 48, considering all the kimberlites discovered by various public and private organizations so far. Preliminary petrography, geochemistry, petrogenetic aspects and diamond prospectivity of the new occurrence have been presented here. Mineralogically, the kimberlite constitutes olivine macrocrysts, serpentinsed olivine psuedomorphs with xenocrystic ilmenite, phlogopite, perovskite, magnetite, Cr-diopside, garnet along with calcite veins. The kimberlite is classified as hypabyssal macrocrystic calcite- phlogopite kimberlite. Mineralogically, the new kimberlite pipe appears as archetypal Group- I kimberlite however, geochemically; the kimberlite shows character of both Group- I and II varieties, more close to lamproitic character. Although it is too early to comment, based on limited analyses carried out in this study, the diamond potentiality of this pipe is not encouraging; it is noteworthy that it highly warrants detailed investigations involving bulk rock geochemistry and drilling to assess its definite geochemical status, petrogenesis and diamond potentiality.
DS201808-1778
2018
Phani, P.R.C.Role of trace element pedogeochemistry in diamond exploration - a first report from Lattavaram kimberlite cluster, Wajrakarur field, eastern Dharwar craton, southern India.Geochimica Brasiliensis, Vol. 32, 1, pp. 95-114.Indiadeposit - Lattavaram

Abstract: Trends in concentration of selected trace elements in residual soils on four known diamondiferous kimberlite pipes (3, 4, 8 and 9) occurring at Lattavaram within the Wajrakarur Kimberlite Field (WKF) is attempted for the first time. The pipes 3 and 4 are exposed whereas the 8 and 9 are concealed under calcrete and colluvium. For this purpose, elements like Nb, Cr, Ni, Co, Zr, Mg, Sr and La are used to understand their concentrations in the kimberlitic soils in comparison with background granitic soils. It is observed that the soils on kimberlite pipes show conspicuous enrichment of elements such as Cr, Co, Nb, Ni, Mg and Sr when compared to soils in the country rock granitoid. However, no much variation in the elements La and Zr patterns between the kimberlitic and background soils is noticed. The high pulse in trace elements in kimberlitic soils is attributed to the presence of primary kimberlitic minerals and their weathered products in the soil. This particular aspect of pedogeochemistry is envisaged to be useful as an exploration tool in search of kimberlites in cratonic parts of southern India. An enrichment of Nb content upto 45 ppm in residual soils may be considered as anamolous in the craonic parts of Indian subcontinent, which needs to be confirmed and taken forward in conjunction with high resolution geological mapping, geophysics followed up by drilling for confirmation of kimberlite/lamproite occurrence.
DS201805-0971
2018
Phani, R., Raju, V.V., Srinivas, M.Petrological and geochemical characteristics of a shoshonitic lamprophyre, Sivarampet, Wajrakarur, kimberlite field, southern India.Journal of Applied Geology and Geophysics (IOSR), Vol. 6, 2, pp. 55-69. pdfIndiashoshonite

Abstract: Field geological, petrographic and geochemical characteristics of a lamprophyre intrusion, presumably of plug-type, at Sivarampet (SPL), occurring within the Wajrakarur kimberlite field (WKF) to the west of Cuddapah basin, are presented and discussed. The lamprophyre intrusion occurs as brecciated outcrop with angular country rock granitoid clasts and also it forms stringers/veinlets within the granitic country rock. The melanocratic rock displays panidiomorphic/porphyritic texture, typical of lamprophyres, comprising clinopyroxene, biotite, phlogopite set in a groundmass of feldspar, magnetite and spinel. Plagioclase is dominant feldspar. The K2O/Na2O ratio ranges from 1.55 to 1.89 wt %, making it distinctly potassic and brings out its shoshonitic behaviour. The fractionated chondrite normalised patterns of REE (with average (La/Yb)N= 21.01 ppm) implies involvement of an enriched mantle source while depleted values of Nb, Hf, Th and U concentrations indicate prevalence of subducted component in the mantle source. The concentrations of Rb, Sr and Ba indicate presence of phlogopite in the source. Based on the mineral assemblages, the SPL can be classified as calc-alkaline variety; however, its geochemistry shows characteristics of both alkaline and calc-alkaline varieties. The moderate Mg# (52 to 55.6) and low concentration of Ni (95.61 to 112.4 ppm) in the bulk rock indicate a low degree of partial melting of magmatic fluid from enriched asthenospheric mantle which underwent fractionation of olivine and pyroxene, subsequently producing lamprophyre magma. Recent discovery of diamonds in shoshonitic lamprophyres of Canada, appeals further investigations on diamondiferous nature of similar rock types of the WKF.
DS201805-0972
2017
Phani, R., Raju, V.V.N.A new kimberlite pipe in Balkamthota Vanka, Pennahobilam, Anantapur district, Andhra Pradesh, India. Field aspects and preliminary investigations.Periodico di Mineralogia, Vol. 86, pp. 213-228. pdfIndiadeposit - Balkamthota Vanka

Abstract: Systematic closely spaced geological traverses conducted in the year 2010, in Lattavaram Kimberlite Cluster (LKC) of Anantapur district, Andhra Pradesh, India, have led to the discovery of a new kimberlite pipe outcrop in the river bed of Balkamthota Vanka (name of the stream used by local farmers) at its confluence with Penna River, close to Pennahobilam. This new pipe occurs at a distance of 1.5 km in NE direction to hitherto reported pipes-5 and 13 occurring at Muligiripalli and Tummatapalli respectively in the LKC of the Wajrakarur Kimberlite Field (WKF). With this pipe, the total number of kimberlite pipes in the WKF raises to 48, considering all the kimberlites discovered by various public and private organizations so far. Preliminary petrography, geochemistry, petrogenetic aspects and diamond prospectivity of the new occurrence have been presented here. Mineralogically, the kimberlite constitutes olivine macrocrysts, serpentinsed olivine psuedomorphs with xenocrystic ilmenite, phlogopite, perovskite, magnetite, Cr-diopside, garnet along with calcite veins. The kimberlite is classified as hypabyssal macrocrystic calcite- phlogopite kimberlite. Mineralogically, the new kimberlite pipe appears as archetypal Group- I kimberlite however, geochemically; the kimberlite shows character of both Group- I and II varieties, more close to lamproitic character. Although it is too early to comment, based on limited analyses carried out in this study, the diamond potentiality of this pipe is not encouraging; it is noteworthy that it highly warrants detailed investigations involving bulk rock geochemistry and drilling to assess its definite geochemical status, petrogenesis and diamond potentiality.
DS201810-2366
2018
Phillips, D., Harris, J.W., de Wit, M.C.J., Matchan, E.Provenance history of detrital diamond deposits, West Coast of Namaqualand, South Africa.Mineralogy and Petrology, doi:10.1007/ s00710-018-0568-9 15p.Africa, South Africadeposit - Group I, orangeites Group II

Abstract: The West Coast of Namaqualand in South Africa hosts extensive detrital diamond deposits, but considerable debate exists as to the provenance of these diamonds. Some researchers have suggested derivation of the diamonds from Cretaceous-Jurassic kimberlites (also termed Group I kimberlites) and orangeites (also termed Group II kimberlites) located on the Kaapvaal Craton. However, others favour erosion of diamonds from the ca.300 Ma Dwyka Group sediments, with older, pre-Karoo kimberlites being the original source(s). Previous work has demonstrated that 40Ar/39Ar analyses of clinopyroxene inclusions, extracted from diamonds, yield ages approaching the time(s) of source kimberlite emplacement, which can be used to constrain the provenance of placer diamond deposits. In the current study, 40Ar/39Ar analyses were conducted on clinopyroxene inclusions from two similar batches of Namaqualand detrital diamonds, yielding (maximum) ages ranging from 117.5?±?43.6 Ma to 3684?±?191 Ma (2s) and 120.6?±?15.4 Ma to 688.8?±?4.9 Ma (2s), respectively. The vast majority of inclusions (88%) produced ages younger than 500 Ma, indicating that most Namaqualand diamonds originated from Cretaceous-Jurassic kimberlites/orangeites, with few, if any, derived from the Dwyka tillites. The provenance of the Namaqualand diamonds from ca.115-200 Ma orangeites is consistent with Late Cretaceous paleo-drainage reconstructions, as these localities could have been sampled by the ‘paleo-Karoo’ River and transported to the West Coast via an outlet close to the current Olifants River mouth. At ca.90 Ma, this drainage system appears to have been captured by the ‘paleo-Kalahari’ River, a precursor to the modern Orange River system. This latter drainage is considered to have transported diamonds eroded from both ca.80-90 Ma kimberlites and ca.115-200 Ma orangeites to the West Coast, which were subsequently reworked along the Namibian coast, forming additional placer deposits.
DS201807-1523
2018
Phillips, D., Harris, J.W., de Wit, M.C.J., Matchan, E.L.Provenance history of detrital diamond deposits, West Coast of Namaqualand, South Africa.Mineralogy and Petrology, 10.1007/ s00710-018- 0568-9, 15p.Africa, South Africageochronology

Abstract: The West Coast of Namaqualand in South Africa hosts extensive detrital diamond deposits, but considerable debate exists as to the provenance of these diamonds. Some researchers have suggested derivation of the diamonds from Cretaceous-Jurassic kimberlites (also termed Group I kimberlites) and orangeites (also termed Group II kimberlites) located on the Kaapvaal Craton. However, others favour erosion of diamonds from the ca.300 Ma Dwyka Group sediments, with older, pre-Karoo kimberlites being the original source(s). Previous work has demonstrated that 40Ar/39Ar analyses of clinopyroxene inclusions, extracted from diamonds, yield ages approaching the time(s) of source kimberlite emplacement, which can be used to constrain the provenance of placer diamond deposits. In the current study, 40Ar/39Ar analyses were conducted on clinopyroxene inclusions from two similar batches of Namaqualand detrital diamonds, yielding (maximum) ages ranging from 117.5?±?43.6 Ma to 3684?±?191 Ma (2?) and 120.6?±?15.4 Ma to 688.8?±?4.9 Ma (2?), respectively. The vast majority of inclusions (88%) produced ages younger than 500 Ma, indicating that most Namaqualand diamonds originated from Cretaceous-Jurassic kimberlites/orangeites, with few, if any, derived from the Dwyka tillites. The provenance of the Namaqualand diamonds from ca.115-200 Ma orangeites is consistent with Late Cretaceous paleo-drainage reconstructions, as these localities could have been sampled by the ‘paleo-Karoo’ River and transported to the West Coast via an outlet close to the current Olifants River mouth. At ca.90 Ma, this drainage system appears to have been captured by the ‘paleo-Kalahari’ River, a precursor to the modern Orange River system. This latter drainage is considered to have transported diamonds eroded from both ca.80-90 Ma kimberlites and ca.115-200 Ma orangeites to the West Coast, which were subsequently reworked along the Namibian coast, forming additional placer deposits.
DS201811-2601
2018
Piispa, E.J., Smirnov, A.V., Pesonen, L.J., Mitchell, R.H.Paleomagnetism and geochemistry of ~1144.-Ma lamprophyre dikes, northwestern Ontario: implcations for the North American polar wander and plate velocities.Journal of Geophysical Research: Solid Earth, Vol. 123, 8, pp. 6195-6214.Canada, Ontariogeochronology

Abstract: Similar to a magnetic tape, rocks can retain the direction of ancient Earth's magnetic field. Scientists use this record (known as paleomagnetism) to reconstruct past positions of continents and to decipher the geological history of our planet. We investigated paleomagnetism and chemical composition of the ~1.14 Ga?old intrusive rocks called lamprophyres exposed in Northwestern Ontario (Canada). We found that the paleomagnetic field directions recorded in lamprophyres are indistinguishable from those recorded by another similar age suite of basaltic intrusions called the Abitibi dikes, from the same area. The combined data from these rocks allowed us to constrain the position of an ancient supercontinent called Laurentia at ~1.14 billions of years ago more accurately than it was possible before. Our results convincingly show that, during that time, Laurentia moved with a velocity comparable to present?day plate velocities, before switching to an extremely rapid motion approximately 35 millions of years later. The lamprophyre and Abitibi rocks also share similar chemical signatures, close to those observed for ocean island basalts (e.g., Hawaii). These observations support the hypothesis that a failed ocean opening attempt called the North American Midcontinent Rift was instigated by the arrival of a hot mantle material upwelling to the Earth surface.
DS201802-0258
2018
Piper, J.D.A.Dominant Lid Tectonics behaviour of continental lithosphere in Precambrian times: paleomagnetism confirms prolonged quasi-integrity and absence of supercontinent cycles.Geoscience Frontiers, Vol. 9, 1, pp. 61-89.Mantleplate tectonics

Abstract: Although Plate Tectonics cannot be effectively tested by palaeomagnetism in the Precambrian aeon due to the paucity of high precision poles spanning such a long time period, the possibility of Lid Tectonics is eminently testable because it seeks accordance of the wider dataset over prolonged intervals of time; deficiencies and complexities in the data merely contribute to dispersion. Accordance of palaeomagnetic poles across a quasi-integral continental crust for time periods of up to thousands of millions of years, together with recognition of very long intervals characterised by minimal polar motions (?2.6-2.0, ?1.5-1.25 and ?0.75-0.6 Ga) has been used to demonstrate that Lid Tectonics dominated this aeon. The new PALEOMAGIA database is used to refine a model for the Precambrian lid incorporating a large quasi-integral crescentric core running from South-Central Africa through Laurentia to Siberia with peripheral cratons subject to reorganisation at ?2.1, ?1.6 and ?1.1 Ga. The model explains low levels of tidal friction, reduced heat balance, unique petrologic and isotopic signatures, and the prolonged crustal stability of Earth's “Middle Age”, whilst density concentrations of the palaeomagnetic poles show that the centre of the continental lid was persistently focussed near Earth's rotation axis from ?2.8 to 0.6 Ga. The exception was the ?2.7-2.2 Ga interval defined by ?90° polar movements which translated the periphery of the lid to the rotation pole for this quasi-static period, a time characterised by glaciation and low levels of magmatic activity; the ?2.7 Ga shift correlates with key interval of mid-Archaean crustal growth to some 60-70% of the present volume and REE signatures whilst the ?2.2 Ga shift correlates with the Lomagundi ?13 C and Great Oxygenation events. The palaeomagnetic signature of breakup of the lid at ?0.6 Ga is recorded by the world-wide Ediacaran development of passive margins and associated environmental signatures of new ocean basins. This event defined the end of a dominant Lid Tectonic phase in the history of Earth's continental lithosphere recorded by the quasi-integral Precambrian supercontinent Palaeopangaea and the beginning of the comprehensive Plate Tectonics which has characterised the Phanerozoic aeon. Peripheral modifications to the lid achieved a symmetrical and hemispheric shape in Neoproterozoic times comparable to the familiar short-lived supercontinent (Neo)Pangaea (?350-150 Ma) and this appears to be the sole supercontinent cycle recorded by the palaeomagnetic record. Prolonged integrity of a large continental nucleus accompanied by periodic readjustments of peripheral shields can reconcile divergent tectonic analyses of Precambrian times which on the one hand propose multiple Wilson Cycles to explain some signatures of Plate Tectonics, and alternative interpretations which consider that Plate Tectonics did not commence until the end of the Neoproterozoic.
DS201812-2864
2018
Pisani, J.R.Prime diamonds Mineracao, strategy and targets in Brazil,7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazildeposit -
DS201812-2865
2018
Pisani, J.R.Diamonds in Brazil, a window of opportunity still to be explored.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazildiamond occurrence
DS201810-2367
2018
Pitard, P., Replumaz, A., Funiciello, F., Husson, L., Faccenna, C.Mantle kinematics driving collisional subduction: insights from analogue modeling.Earth and Planetary Science Letters, Vol. 502, pp. 96-103.Mantlesubduction

Abstract: Since several decades, the processes allowing for the subduction of the continental lithosphere less dense than the mantle in a collision context have been widely explored, but models that are based upon the premise that slab pull is the prominent driver of plate tectonics fail. The India-Asia collision, where several episodes of continental subduction have been documented, constitute a case study for alternative views. One of these episodes occurred in the early collision time within the Asian plate where continental lithosphere not attached to any oceanic lithosphere subducted southward in front of the Indian lithosphere during its northward subduction that followed the oceanic subduction of the Tethys ocean. This process, known as collisional subduction, has a counter-intuitive behavior since the subduction is not driven by slab pull. It has been speculated that the mantle circulation can play an important role in triggering collisional subduction but a detailed, qualitative analysis of it is not available, yet. In this work we explore the southward subduction dynamics of the Asian lithosphere below Tibet by means of analogue experiments with the aim to highlight how the mantle circulation induces or responds to collisional subduction. We found that during the northward oceanic subduction (analogue of Tethys subduction) attached to the indenter (Indian analogue), the main component of slab motion is driven vertically by its negative buoyancy, while the trench rolls back. In the mantle the convective pattern consists in a pair of wide convective cells on both sides of the slab. But when the indenter starts to bend and plunge in the mantle, trench motion reverses. Its advance transmits the far field forces to two upper plates (Asian analogues). The more viscous frontal plate thickens, and the less viscous hinterland plate, which is attached to the back wall of the box, subducts. During this transition, a pair of sub-lithospheric convective cells is observed on both sides of the Asian analogue slab, driven by the shortening of the frontal plate. It favors the initiation of the backwall plate subduction. Such subduction is maintained during the entire collision by a wide cell with a mostly horizontal mantle flow below Tibet, passively advecting the Asian analogue slab. Experimental results suggest that once the tectonic far-field force related to the forward horizontal motion becomes dominant upon the buoyancy forces, trench advancing and the transmission of the tectonic force to the upper and backwall plates are promoted. This peculiar condition triggers the subduction of the backwall plate, despite it is light and buoyant.
DS201801-0047
2017
Pitawala, H.M.T.G.A.Apatites from Sri Lankan carbonatites: petrogenetic implications.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 19.Asia, Sri Lankacarbonatites

Abstract: Carbonatite exposures are found near the boundary of Highland and Wanni Complexes that are major lithotectonic units of Precambrian basement of Sri Lanka. Larger bodies of carbonatite are found at Eppawala, in northcentral part of the island and smaller intrusions with associated apatite rich silicate dykes are present at Kawisigamuwa, in the Northwestern part. Both carbonatite complexes appear mostly as dykes and have calcite-dolomite-magnetite-apatite assemblages. The aim of present study is to decipher the petrogenetic history of carbonatite via the compositional and petrographical investigations of apatite. The size of apatite varies from fine grained to mega size (up to 1m). Cathodoluminescence and compositional data of apatite from two carbonatite occurrences and associated dykes are variable. Apatite grains of Eppawala are rich in F and Fe with relatively persistent chemical composition of all sizes. However, over growth zones of crystals show highly variable chemical compositions. Kawisigamuwa apatite is characterized by higher concentrations of Cl, Sr and light rare earth elements (LREE). Higher concentrations of Fe and F with lower Sr levels are measured from apatite crystals in silicate dykes. Results of present study are indicative of composition of parent magma and post magmatic fluid activities on the generation of apatite.
DS201804-0729
2018
Plakhotnik, T., Aman, H.NV centers in nanodiamonds: how good they are.Diamond & Related Materials, Vol. 82, pp. 87-95.Technologynanodiamonds

Abstract: This paper presents a method for determination of the size distribution for diamond nanocrystals containing luminescent nitrogen-vacancy (NV) centers using the luminescence intensity only. We also revise the basic photo physical properties of NV centers and conclude that the luminescence quantum yield of such centers is significantly smaller than the frequently stated 100\%. The yield can be as low as 5\% for centers embedded in nanocrystals and depends on their shape and the refractive index of the surrounding medium. The paper also addresses the value of the absorption cross-section of NV centers.
DS201812-2866
2018
Podvysotski, V.Primary diamond placers of Cretaceous age in the Juina area. Mato Grosso State, Brazil7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazil, Mato Grossodeposit - Juina
DS201808-1779
2018
Pointon, M.De Beers's diamond mine in 1880's: Robert Harris and the Kimberley Searching System.History of Photography, Vol. 42, 1, pp. 4-24.Africa, South Africahistory

Abstract: In the mid 1880s a little-known photographer named Robert Harris produced a series of albumen prints showing the stages of body searching that black labourers in De Beers diamond mines were obliged to undergo by state ordinance enacted in 1883. The original photographs surfaced briefly in the sale-room in 2007 but have since disappeared. Two sets of copies survive. Bearing in mind the history of documentary photography in South Africa, this essay examines the historical and textual significance of this series of photographs in the context of the history of mining and discusses the imperatives and ethics of locating, researching and publishing controversial imagery in the internet age.
DS201810-2368
2018
Pointon, M.De Beer's diamond mine in the 1880's: Robert Harris and the Kimberley searching system.History of Photography, Vol. 42, 1, pp. 4-24. doi.org/10.1080/ 03087298.2018. 1429095Africa, South Africadeposit - Kimberley

Abstract: In the mid 1880s a little-known photographer named Robert Harris produced a series of albumen prints showing the stages of body searching that black labourers in De Beers diamond mines were obliged to undergo by state ordinance enacted in 1883. The original photographs surfaced briefly in the saleroom in 2007 but have since disappeared. Two sets of copies survive. Bearing in mind the history of documentary photography in South Africa, this article examines the historical and textual significance of this series of photographs in the context of the history of mining and discusses the imperatives and ethics of locating, researching, and publishing controversial imagery in the Internet age.
DS201812-2867
2018
Poitras, S.P., Pearson, D.G., Hardman, M.F., Stachel, T., Nowell, G.M.Evidence for a 200 km thick diamond bearing root beneath the Central Mackenzie Valley, Northwest Territories, Canada? Diamond indicator mineral geochemistry from the Horn Plateau and Trout Lake regions.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0641-4 18p.Canada, Northwest Territoriesindicator minerals, geocthermobarometry

Abstract: The Central Mackenzie Valley (CMV) area of Northwest Territories is underlain by Precambrian basement belonging to the North American Craton. The potential of this area to host kimberlitic diamond deposits is relatively high judging from the seismologically-defined lithospheric thickness, age of basement rocks (2.2-1.7 Ga) and presence of kimberlite indicator minerals (KIMs) in Quaternary sediments. This study presents data for a large collection of KIMs recovered from stream sediments and till samples from two study areas in the CMV, the Horn Plateau and Trout Lake. In the processed samples, peridotitic garnets dominate the KIM grain count for both regions (> 25% each) while eclogitic garnet is almost absent in both regions (< 1% each). KIM chemistry for the Horn Plateau indicates significant diamond potential, with a strong similarity to KIM systematics from the Central and Western Slave Craton. The most significant issue to resolve in assessing the local diamond potential is the degree to which KIM chemistry reflects local and/or distal kimberlite bodies. Radiogenic isotope analysis of detrital kimberlite-related CMV ilmenite and rutile grains requires at least two broad age groups for eroded source kimberlites. Statistical analysis of the data suggests that it is probable that some of these KIMs were derived from primary and/or secondary sources within the CMV area, while others may have been transported to the area from the east-northeast by Pleistocene glacial and/or glaciofluvial systems. At this stage, KIM chemistry does not allow the exact location of the kimberlitic source(s) to be constrained.
DS201810-2369
2018
Pokhilenko, L.N.Exotic olivine mica rocks from the Udachnaya -East pipe ( Yakutia): features of the chemical composition and origin.Doklady Earth Sciences, Vol. 481, 2, pp. 1050-1055.Russia, Yakutiadeposit - Udachnaya -East
DS201801-0048
2017
Polak, L., Ackerman, L., Rapprich, V., Magna, T.Platinum group element and rhenium osmium geochemistry of selected carbonatites from India, USA and East africa.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 22-23.India, United States, Africa, East Africacarbonatites

Abstract: Carbonatites and associated alkaline silicate rocks might have potential economic impact for a large variety of metals such as Cu, Ni, Fe and platinum-group elements (PGE - Os, Ir, Ru, Pd, Pt) as it is demonstrated in South Africa (Phalaborwa; Taylor et al. 2009) or Brazil (Ipanema; Fontana 2006). In addition, determined PGE contents along with Re-Os isotopic compositions may also provide important information about PGE fractionation during the genesis of upper mantle-derived carbonatitic melts and nature of their sources. Nevertheless, the existing PGE data for carbonatites are extremely rare, limited mostly to Chinese localities and they are not paralleled by Re-Os isotopic data (Xu et al. 2008). Therefore, in this study, we present the first complete PGE datasets together with Re-Os determinations for a suite of selected carbonatite bodies worldwide. We have chosen eight carbonatite sites with different alkaline rock association, age and geotectonic position. Among these, the youngest samples are from East African rift system and include Oldoinyo Dili, Tanzania with an age spanning from ~0 to 45 Ma; same as Tororo and Sukulu in Uganda (Woolley and Kjarsgaard 2008). These carbonatites are in association with pyroxenites and nepheline syenites. Another young carbonatitic complex is Amba Dongar in west India with Cretaceous age of ~65 Ma associated with alkaline volcanic rocks such as trachybasalts within Deccan Traps (Sukheswala and Udas 1963). Proterozoic bodies are represented by Iron Hill, USA carbonatites associated with pyroxenite, melitolite and ijolite with age ranging from ~520 to 580 Ma (Nash 1972). These carbonatites are famous for their intensive and varied fenitization. Last and the oldest carbonatites in this study comes from Samalpatti and Sevattur, South India having the age of ~800 Ma (Schleicher et al. 1997) and outcropping as small bodies within alkaline rocks such as pyroxenite, syenite and gabbro. The PGE concentrations and Re-Os isotopic ratios were determined by standard methods consisting of decarbonatization using HCl, decomposition of samples in Carius Tubes in the presence of reverse aqua regia and spikes (isotopic dilution), separation of Os by CHCl3 followed by N-TIMS measurements and Ir, Ru, Pd, Pt, Re isolation by anion exchange chromatography followed by ICP-MS measurements. All analysed carbonatites exhibit extremely low PGE contents (? PGE up to 1 ppb), even in the samples with high S contents (up to 1.5 wt. %). Such values are much lower than other determined so far for upper mantle-derived melts such as basalts, komatiites, etc. (Day et al. 2016). Such signatures indicate very low partitioning of PGE into carbonatitic melts and/or early separation of PGE-bearing fraction. Elements from iridium-group I-PGE; Os, Ir and Ru; mostly < 0.1 ppb) are distinctly lower compared to palladiumgroup elements and Re (PPGE; Pt, Pd, Re; mostly > 0.1 ppb) with some rocks being largely enriched in Re (up to ~6 ppb). Most of the analysed carbonatites exhibit progressive enrichment from Os to Re and consequently, PdN/ReN < 0.1 except south India carbonatites and associated alkaline rocks (> 0.30). Rocks analysed so far for Os have OsN/IrN up to 6.2 that might suggest that the carbonatites might concentrate Os over Ir. The highest HSEtot contents have been found in Mg-Cr-rich silicocarbonatites from South India (up to 40 ppb) and taking into account their only slightly radiogenic 187Os/188Os ratios (0.14-0.57), these rocks represents mixture of CO2-rich alkaline mantle melts and country rocks. Very high concentrations of HSE have been also found in magnetite separated from Fe-carbonatite from Amba Dongar, India (0.2-0.5 ppb of I-PGE and 0.9-9 ppb of P-PGE). The 187Os/188Os ratios determined so far for carbonatites from South India vary from 0.24 to 6.5 and calculated ?Os values range from +100 up to +5000. Such wide range of values suggest extremely heterogenous source of the melts and/or possible contamination by 187Os-rich crustal materials.
DS201812-2868
2018
Pollock, K., Davy, A.T., Moss, S.Diavik deposit: Evaluation of the Diavik diamond deposit.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 267-286.Canada, Northwest Territoriesdeposit - Diavik
DS201801-0049
2017
Popova, E.A., Lushnikov, S.G., Yakovenchuk, V.N., Krivovichev, S.V.The crystal structure of loparite: a new acentric variety.Mineralogy and Petrology, Vol. 111, pp. 827-832.Russia, Kola Peninsuladeposit - Khibiny

Abstract: The crystal structure of a new structural variety of loparite (Na0.56Ce0.21La0.14Ca0.06Sr0.03Nd0.02Pr0.01)?=1.03(Ti0.83Nb0.15)?=0.98O3 from the Khibiny alkaline massif, Kola peninsula, Russia, was solved by direct methods and refined to R1 = 0.029 for 492 unique observed reflections with I > 2?(I). The mineral is orthorhombic, Ima2, a = 5.5129(2), b = 5.5129(2) and c = 7.7874(5) Å. Similarly to other perovskite-group minerals with the general formula ABO3, the crystal structure of loparite is based upon a three-dimensional framework of distorted corner-sharing BO6. The A cations are coordinated by 12 oxygen atoms and are situated in distorted cuboctahedral cavities. In contrast to the ideal perovskite-type structure (Pm3?m), the unit cell is doubled along the c axis and the a and b axes are rotated in the ab plane at 45o. The BO6 octahedron displays distortion characteristic for the d0 transition metal cations with the out-of-center shift of the B site. The symmetry reduction is also attributable to the distortion of the BO6 octahedra which are tilted and rotated with respect to the c axis. The occurrence of a new acentric variety of loparite can be explained by the pecularities of its chemical composition characterized by the increased content of Ti compared to the previously studied samples.
DS201801-0050
2017
Pratt, M.J., Wysession, M.E., Aleqabi, G., Wiens, D.A., Nyblade, A., Shore, P., Rambolamanana, G., Andriampenomanana, F., Rakotondraibe, T., Tucker, R.D., Barruol, G., Rindraharisaona, E.Shear velocity structure of the crust and upper mantle of Madagascar derived from surface wave tomography.Earth and Planetary Science Letters, Vol. 458, 1, pp.405-417.Africa, Madagascargeophysics - seismics

Abstract: The crust and upper mantle of the Madagascar continental fragment remained largely unexplored until a series of recent broadband seismic experiments. An island-wide deployment of broadband seismic instruments has allowed the first study of phase velocity variations, derived from surface waves, across the entire island. Late Cenozoic alkaline intraplate volcanism has occurred in three separate regions of Madagascar (north, central and southwest), with the north and central volcanism active until <1 Ma, but the sources of which remains uncertain. Combined analysis of three complementary surface wave methods (ambient noise, Rayleigh wave cross-correlations, and two-plane-wave) illuminate the upper mantle down to depths of 150 km. The phase-velocity measurements from the three methods for periods of 8-182 s are combined at each node and interpolated to generate the first 3-D shear-velocity model for sub-Madagascar velocity structure. Shallow (upper 10 km) low-shear-velocity regions correlate well with sedimentary basins along the west coast. Upper mantle low-shear-velocity zones that extend to at least 150 km deep underlie the north and central regions of recent alkali magmatism. These anomalies appear distinct at depths <100 km, suggesting that any connection between the zones lies at depths greater than the resolution of surface-wave tomography. An additional low-shear velocity anomaly is also identified at depths 50-150 km beneath the southwest region of intraplate volcanism. We interpret these three low-velocity regions as upwelling asthenosphere beneath the island, producing high-elevation topography and relatively low-volume magmatism.
DS201803-0471
2018
Presser, J.L.B.An approach to geoethics in Paraguay. Diamonds mentionedAcededo, R.G., Frias, J.M. eds Geoethics in Latin America, Springer Publisher, Chapter 12, 11p. PdfSouth America, Paraguaydiamond mining
DS201802-0259
2017
Presser, J.L.B., Alonso, R.N., Farina Dolsa, S., Larroza, F.A., Rocca, M.C.L., Hornes, K., Baller, L.Impact metamorphism evidence of Negla and Yasuka Renda large impact crater. ***PORT only abstract in eng Boletin Museum History Natural Paraguay ***IN PORT, Vol. 21, no. 2, pp. 69-82. pdfSouth America, Paraguayimpact craters
DS201802-0260
2018
Prokopyev, I.R., Doroshkevich, A.G., Redina, A.A., Obukhov, A.V.Magnetite apatite dolomitic rocks of Ust Chulman ( Aldan Shield, Russia): Seligdar type carbonatites?Mineralogy and Petrology, in press available, 10p.Russia, Aldan shieldcarbonatites

Abstract: The Ust-Chulman apatite ore body is situated within the Nimnyrskaya apatite zone at the Aldan shield in Russia. The latest data confirm the carbonatitic origin of the Seligdar apatite deposit (Prokopyev et al. in Ore Geol Rev 81:296-308, 2017). The results of our investigations demonstrate that the magnetite-apatite-dolomitic rocks of the Ust-Chulman are highly similar to Seligdar-type dolomitic carbonatites in terms of the mineralogy and the fluid regime of formation. The ilmenite and spinel mineral phases occur as solid solutions with magnetite, and support the magmatic origin of the Ust-Chulman ores. The chemical composition of REE- and SO3-bearing apatite crystals and, specifically, monazite-(Ce) mineralisation and the formation of Nb-rutile, late hydrothermal sulphate minerals (barite, anhydrite) and haematite are typical for carbonatite complexes. The fluid inclusions study revealed similarities to the evolutionary trend of the Seligdar carbonatites that included changes of the hydrothermal solutions from highly concentrated chloride to medium-low concentrated chloride-sulphate and oxidized carbonate-ferrous.
DS201809-2077
2018
Pu, Y., Derek, A., Huawei, X.A principal component analysis/fuzzy comprehensive evaluation for rockburst potential in kimberlite.Pure and Applied Physics, Vol. 175, 6, pp. 2141-2151.Canada, Northwest Territoriesmining

Abstract: Kimberlite is an igneous rock which sometimes bears diamonds. Most of the diamonds mined in the world today are found in kimberlite ores. Burst potential in kimberlite has not been investigated, because kimberlite is mostly mined using open-pit mining, which poses very little threat of rock bursting. However, as the mining depth keeps increasing, the mines convert to underground mining methods, which can pose a threat of rock bursting in kimberlite. This paper focuses on the burst potential of kimberlite at a diamond mine in northern Canada. A combined model with the methods of principal component analysis (PCA) and fuzzy comprehensive evaluation (FCE) is developed to process data from 12 different locations in kimberlite pipes. Based on calculated 12 fuzzy evaluation vectors, 8 locations show a moderate burst potential, 2 locations show no burst potential, and 2 locations show strong and violent burst potential, respectively. Using statistical principles, a Mahalanobis distance is adopted to build a comprehensive fuzzy evaluation vector for the whole mine and the final evaluation for burst potential is moderate, which is verified by a practical rockbursting situation at mine site.
DS201808-1780
2018
Putirka, K., Tao, Y., Hari, K.R., Perfit, M., Jackson, M.G., Arevalo, Jr. R.The mantle source of thermal plumes: trace and minor element & major oxides of primitive liquids ( and why olivine compositions don't matter).minoscam.org, doi.org/10.2138/am-2018-6192 59p.Mantleforsterite

Abstract: We estimate the mantle source compositions for mantle plumes, and by implication Earth’s lower mantle, by: (a) measuring trace (e.g, Sc, V, Cu) and minor (e.g., Ca, Mn, Ni) element concentrations of high forsterite olivine grains from several plume localities, (b) estimating the parent liquid compositions from which they crystallized, (c) calculating mantle potential temperatures and degrees of partial melting and (d) estimating trace element compositions of depleted and enriched mantle sources. Our sample set includes two continental flood basalt provinces (Emeishan and Deccan), a flood basalt that erupted in a continental rift setting (Baffin Island), our type example of a thermal mantle plume (Hawaii) and lavas from the Siqueiros Transform at the East Pacific Rise, which represent the mid-ocean ridge system. We also present olivine compositions for the peridotite xenoliths from Kilbourne Hole, New Mexico, USA, which are commonly used as primary and secondary analytical standards. We find that trace elements in lava-hosted olivine grains are too far removed from their mantle source to provided anything but greatly hindered views of such. Olivine compositions reflect not only evolving liquid compositions (including partial melting conditions and later fractionation), but also evolving Ol+liq partition coefficients, which mostly increase with decreasing T during crystallization. Mantle compositions, delimited by maximum forsterite contents and estimates of parental magmas (and experimentally determined partition coefficients) indicate that our selected plumes reflect some combination of (1) a depleted mantle source that is quite similar to that obtained by other methods, and (2) a variably enriched plume source that is more enriched than current estimates of pyrolite. The enriched plume mantle sources can be explained remarkably well as a mixture of subducted mid-ocean ridge basalt (MORB; Gale et al. 2013) and depleted MORB mantle (DM; Salters and Stracke 2004), with MORB:DM ratios of 1:5 to 1:4. These ratios are most sensitive to estimates of melt fraction where plume parental magmas are last equilibrated with their mantle source, but are nonetheless consistent across a wide range of chemically very different elements, and estimates of MORB and DM obtained by very different means. Baffin Island is of particular interest. Like prior studies, we verify a high mantle potential temperature (Tp) of 1630oC (compared to Tp = 1320-1420oC for MORB from Cottrell and Kelley 2011 for Ol of Fo89.3-91.4). The Baffin source is also within error the same as DM with respect to trace elements, although still isotopically distinct; Baffin appears to be sourced in something that is akin to DM that lies at the base of the mantle, where plumes acquire their excess heat. Thus while part of our analysis supports the concept of a "slab graveyard" at the bottom of the lower mantle (e.g., Wyession 1996), that cemetery is by no means ubiquitous at the CMB: subducted slabs are either unevenly interred, or efficiently excavated by later upwellings.
DS201808-1781
2017
Ragozin, A., Zedgenizov, D., Kuper, K., Palyanov, Y.Specific internal structure of diamonds from Zarnitsa kimberlite pipe.Crystals, Vol. 7, 5, pp. 133-Russiadeposit - Zarnitsa

Abstract: The Zarnitsa kimberlite pipe is one of the largest pipes of the Yakutian diamondiferous province. Currently, some limited published data exists on the diamonds from this deposit. Among the diamond population of this pipe there is a specific series of dark gray to black diamonds with transition morphologies between octahedron and rounded rhombic dodecahedron. These diamonds have specific zonal and sectorial mosaic-block internal structures. The inner parts of these crystals have polycrystalline structure with significant misorientations between sub-individuals. The high consistency of the mechanical admixtures (inclusions) in the diamonds cores can cause a high grid stress of the crystal structure and promote the block (polycrystalline) structure of the core components. These diamond crystals have subsequently been formed due to crystallization of bigger sub-individuals on the polycrystalline cores according to the geometric selection law.
DS201806-1241
2018
Ragozin, A.L., Zedgenizov, D.A., Shatsky, V.S., Kuper, K.E.Formation of mosaic diamonds from the Zarnitsa kimberlite.Russian Geology and Geophysics, Vol. 59, pp. 486-498.Russiadeposit - Zarnitsa

Abstract: Mosaic diamonds from the Zarnitsa kimberlite (Daldyn field, Yakutian diamondiferous province) are morphologicaly and structurally similar to dark gray mosaic diamonds of varieties V and VII found frequently in placers of the northeastern Siberian craton. However, although being similar in microstructure, the two groups of diamonds differ in formation mechanism: splitting of crystals in the case of placer diamonds (V and VII) and growth by geometric selection in the Zarnitsa kimberlite diamonds. Selective growth on originally polycrystalline substrates in the latter has produced radial micro structures with grains coarsening rimward from distinctly polycrystalline cores. Besides the formation mechanisms, diamonds of the two groups differ in origin of mineral inclusions, distribution of defects and nitrogen impurity, and carbon isotope composition. Unlike the placer diamonds of varieties V and VII, the analyzed crystals from the Zarnitsa kimberlite enclose peridotitic minerals (olivines and subcalcic Cr-bearing pyropes) and have total nitrogen contents common to natural kimberlitic diamonds (0 to 1761 ppm) and typical mantle carbon isotope compositions (-1.9 to -6.2%c 513C; -4.2%c on average). The distribution of defect centers in the Zarnitsa diamond samples fits the annealing model implying that nitrogen aggregation decreases from core to rim.
DS201801-0051
2017
Rajesh, S., Pradeepkumar, A.P.Carbonatite occurrences in Munnar area, Kerala, southern India.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 36-37.Indiacarbonatites

Abstract: Carbonatites, usually associated with alkaline complexes and emplaced within continental rifting environment, are the rarest of all the igneous rocks. Carbonatite and alkaline intrusive complexes, as well as their weathering products, are the primary sources of REEs (Long et.al. 2010). Carbonatites are defined by the International Union of Geological Sciences (IUGS) system of igneous rock classification as having more than 50 modal percent primary carbonate minerals, such as calcite, dolomite, and ankerite, and less than 20 percent SiO2 (Le Maitre, 2002). Southern India has several carbonatite occurrences and the alkaline complex of Munnar in southern India comprises of an alkali granite plutons with minor patches of charnockite, syenite and carbonatite emplaced within Precambrian gneisses (Nair et.al., 1983, 1984; Santosh et.al., 1987, Nair et.al., 1984). Gneissic layering and foliation are apparent in all but the least deformed granitic rocks in the study area. The Munnar granite body is situated in the western part of the Madurai block in Southern Granulite Terrane (SGT) of Peninsular India, within the newly defined Western Madurai Domain. The complex is spatially related to the intersection zone of Karur-Kambam-Painavu-Trissur lineament. The alkali granite of the complex has been dated at 740±30 my (Odom, 1982) and 804±6 Ma (Brandt et. al., 2014). Present study deals with examining the nature of the carbonatites and takes a relook at its major and REE contents, and for the first time, looks at the stable isotope signatures of these rocks, in an attempt to check whether these rocks are indeed carbonatites. The geology and geochemistry of the rock types in and around Munnar area have been mapped with special focus on carbonatites. Extensive field mapping was carried out and a base map was prepared and all the geological and structural features were recorded in the base map. Intra- and inter-relationships of various rock units were examined. Field photographs of interesting geological features have been recorded. Carbonatites in Munnar area are exposed as two minor patches. The one which occurs towards north of the Munnar town and is seen as patches, lens and veins of 30 cm to 1 m thickness, cutting coarse grained syenite which occurs as a NW- SE along a body. Exposures are found about 15 km from Munnar on the Udumalpet road. The second exposure occurs towards the east of the Munnar town, near at the Ellapatty estate 24 km from Munnar on the road to top station where coarse grained cabonatites occurs as lenticular bodies up to 1.5 m thick within granite. In both the localities, the carbonatite bodies show sharp and discordant margins with absence of any pseudomorphs within them. Fenitisation is characterised by the development of pink K-feldspar megacrystals in the country rock at the contact. The carbonatites are fresh and homogenous and represent two varieties. A coarse grained holocrystalline type and yellowish calcite crystals constituting 90% of the rock, with pyroxene apatite and magnetite correspond to sovite (Streckeisen, 1979). The second variety which contains highly coarse calcite crystals (up to 1 cm) and associated dolomite with mafic minerals constituting 30% of the rock corresponds to alvikite. The sovite exhibits an interlocking crystals mosaic of calcite in thin section. The calcite crystals of alvikite show exsolution blebs of dolomite. The major mafic component in both varieties is aegirine-augite which forms euhedral- subhedral laths (Santosh et al., 1984). The opaque phase is dominantly magnetite. Rarely phlogopite, biotite and minor laths of albite are also noted, small crystals of euhedral apatite are found occluded in calcite grain although alkaline complexes with carbonatite of Munnar devoid of related mafic differentiates like gabbros or lamprophyres may be considered unique. The immiscibility of carbonatitic and alkalic silicate liquids can be physically explained as the separation of a less viscous carbonate liquid from a more viscous polymerized silicate phase. The carbonate liquid would be lower in density because of higher content of H2O and this contrast in density could cause phase separation due to earth’s gravitational field alone (Moller et al., 1980). The pre-requisite to establish separation of immiscible silicate-saturated carbonatite liquid and the associated carbonate-saturated silicate melt is achieved as follows; Large-scale volatile outgassing occurs during crustal wrapping and distention prior to rifting which trigger mantle degassing (Bailey, 1974). An imprint of such large-scale volatile influx is recognised in the Kerala region (Nair et al., 1984). Rapid ascent volatiles enriched in CO2 liberated from the mantle cause partial melting at shallower levels of the mantle.
DS201801-0052
2017
Randive, K.R.Primary carbonate-silicate association in the pelletal lapilli: first direct evidence of carbonated peridotitic mantle source for Amba Dongar carbonatites, Deccan igneous province, India.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 30.Indiadeposit - Amba Dongar

Abstract: Pelletal lapilli are discrete sub-spherical clasts with a central fragment mantled by a rim of probable juvenile origin. They typically range in size from <1 mm – 60 mm, and occur as accessory components of pipe-filling volcaniclastic rocks such as kimberlites, carbonatites, kamafugites, melilitites and orangeites. They have been variously referred to as ‘tuffacitic lapilli’, ‘spherical or elliptical lapilli’, ‘Pele’s tears’, ‘spinning droplets’, ‘cored lapilli’, or ‘concentric shelled lapilli. Their presence has been increasing reported from extrusive carbonatite complexes world over; for e.g. Umbria and Latium, Central Italy, Abruzzo and Lucaniae, Southern Italy; Fort Portal and Katwe Kikorongo, Uganda; West Qinling, China; Campo de Calatrava, Spain, along with others. I am reporting here occurrence of pelletal and cored lapilli in the proximity of Amba Dongar carbonatite complex. The lapillus comprises of abundant phenocrysts of olivine, which are typically rimmed by dark brown thick coating. Such phenocrysts (oikocrysts) acquire remarkable roundedness, many of these show central circular fracture. Some of the phenocrysts are broken yet preserving their thick-brown rim. This feature is accentuated where such olivine oikocrysts are welded over groundmass mafics (typically clinorpyroxenes). However, most conspicuous thing is the presence of chrome spinel, which is dispersed as minor octahedra within the olivine, but not found in association with other minerals implying that olivine and chrome spinels are primary phases within the lapilli. There are other smaller droplets forming cored lapilli, which are dominantly composed of carbonates. Mineral chemistry of different phases indicate presence of forsteric (Fo89.20-67.34: Fa32.10-10.71: Tp0.46-0.04); chromium-rich spinel (Chromite55.34-24.86, Spinel31.88-10.16, Magnetite34.13-8.68, Mag. Chromite24.45-0.00, Ulvospinel23.21-0.00, Mag. Ulvospinel7.00-0.00, diopsidic clinopyroxene (Wo45.36-41.41: En40.92-50.60: Fs7.98-15.46), ilmenite (Il76.79-75.10:Ge13.08-14.60:Py1.72-1.08:He9.22-7.26), calcic-plagioclase (An69.36-47.90:Ab48.32- 29.27:Or3.78-1.37), and chlorite (ripidolite/brunsvigite). Discovery of pelletal and cored lapilli in the proximity of Amba Dongar carbonatite complex thus provide first direct evidence of the carbonated peridotitic mantle source for Amba Dongar carbonatites.
DS201810-2370
2018
Ranger, I.M., Heaman, L.M., Pearson, D.G., Muntener, C., Zhuk, V.Punctuated, long lived emplacement history of the Renard 2 kimberlite, Canada, revealed by new high precision U-Pb groundmass perovskite dating. IF-TIMSMineralogy and Petrology, doi.org/101007/ s00710-018-0629-0 13p.Canada, Quebecdeposit - Renard

Abstract: Kimberlites are rare volatile-rich ultramafic magmas thought to erupt in short periods of time (<1 Myr) but there is a growing body of evidence that the emplacement history of a kimberlite can be significantly more protracted. In this study we report a detailed geochronology investigation of a single kimberlite pipe from the Renard cluster in north-central Québec. Ten new high precision ID-TIMS (isotope dilution - thermal ionization mass spectrometry) U-Pb groundmass perovskite dates from the main pipe-infilling kimberlites and several small hypabyssal kimberlites from the Renard 2 pipe indicate kimberlite magmatism lasted at least ~20 Myr. Two samples of the main pipe-infilling kimberlites yield identical weighted mean 206Pb/238U perovskite dates with a composite date of 643.8?±?1.0 Myr, interpreted to be the best estimate for main pipe emplacement. In contrast, six hypabyssal kimberlite samples yielded a range of weighted mean 206Pb/238U perovskite dates between ~652-632 Myr. Multiple dates determined from these early-, syn- and late-stage small hypabyssal kimberlites in the Renard 2 pipe demonstrate this rock type (commonly used to date kimberlites) help to constrain the duration of kimberlite intrusion history within a pipe but do not necessarily reliably record the emplacement age of the main diatreme in the Renard cluster. Our results provide the first robust geochronological data on a single kimberlite that confirms the field relationships initially observed by Wagner (1914) and Clement (1982); the presence of antecedent (diatreme precursor) intrusions, contemporaneous (syn-diatreme) intrusions, and consequent (post-diatreme) cross-cutting intrusions. The results of this detailed U-Pb geochronology study indicate a single kimberlite pipe can record millions of years of magmatism, much longer than previously thought from the classical viewpoint of a rapid and short-duration emplacement history.
DS201811-2602
2018
Ranta, E., Stockmann, G., Wagner, T., Fusswinkel, T., Sturkell, E., Tollefsen, E., Skelton, A.Fluid-rock reactions in the 1.3 Ga siderite carbonatite of the Gronnedal-Ika alkaline complex, southwest Greenland.Contributions to Mineralogy and Petrology, Vol. 173, 26p. Doi.org/10.1007/s00410-018-1505-yEurope, Greenlandcarbonatite

Abstract: Petrogenetic studies of carbonatites are challenging, because carbonatite mineral assemblages and mineral chemistry typically reflect both variable pressure-temperature conditions during crystallization and fluid-rock interaction caused by magmatic-hydrothermal fluids. However, this complexity results in recognizable alteration textures and trace-element signatures in the mineral archive that can be used to reconstruct the magmatic evolution and fluid-rock interaction history of carbonatites. We present new LA-ICP-MS trace-element data for magnetite, calcite, siderite, and ankerite-dolomite-kutnohorite from the iron-rich carbonatites of the 1.3 Ga Grønnedal-Íka alkaline complex, Southwest Greenland. We use these data, in combination with detailed cathodoluminescence imaging, to identify magmatic and secondary geochemical fingerprints preserved in these minerals. The chemical and textural gradients show that a 55 m-thick basaltic dike that crosscuts the carbonatite intrusion has acted as the pathway for hydrothermal fluids enriched in F and CO2, which have caused mobilization of the LREEs, Nb, Ta, Ba, Sr, Mn, and P. These fluids reacted with and altered the composition of the surrounding carbonatites up to a distance of 40 m from the dike contact and caused formation of magnetite through oxidation of siderite. Our results can be used for discrimination between primary magmatic minerals and later alteration-related assemblages in carbonatites in general, which can lead to a better understanding of how these rare rocks are formed. Our data provide evidence that siderite-bearing ferrocarbonatites can form during late stages of calciocarbonatitic magma evolution.
DS201808-1782
2018
Rapopo, M., Sobie, P.The Liqhobong kimberlite cluster: an update on the geology.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0624-5 12p.Africa, Lesothodeposit - Liqhobong

Abstract: The Cretaceous Liqhobong kimberlite cluster comprises at least six known diamondiferous Group 1 kimberlite bodies; namely the circular Main Pipe (8.5 ha), ovoid Satellite Pipe (1.6 ha), Discovery Blow (0.15 ha), Blow (0.1 ha), the Main Dike adjoining the blows and pipes, and one other recently exposed dike. The kimberlites intrude Jurassic Drakensberg lavas and outcrop at ~2650 masl in rugged Maluti Mountain terrain, and are emplaced along a strike of about 2.5km. The cluster represents at least three episodes of structurally controlled kimberlite intrusion; the first which comprised the dike(s?) and the two blows (the blows being dike enlargements emplaced 1km apart) and later the two separate emplacements of the Main and Satellite Pipes.
DS201808-1783
2018
Ravenna, M., Lebedev, S., Fullea, J., Adam, J.Shear wave velocity structure of Southern Africa's lithosphere: variations in the thickness and composition of cratons and their effect on topography.Geochemistry, Geophysics, Geosystems, Vol. 19, 5, pp. 1499-1518.Africa, South Africacraton

Abstract: Cratons, the ancient cores of continents, have an unusually thick lithosphere (the tectonic plate beneath them). At least ?200 km thick, it has a highly anomalous composition, making it less dense than the surrounding mantle. Cratonic lithosphere can thus be cooled to much lower temperatures than elsewhere. Variations in this delicate buoyancy balance probably give rise to variations in the surface elevation across the Earth's stable continents. Lithospheric thickness and composition are key parameters, but both are notoriously difficult to determine. Here we use very accurate measurements of seismic surface?wave velocities and determine deep structure beneath cratons in southern Africa. We discover an unexpectedly strong, gradual thickening of the lithosphere from the central Kaapvaal Craton to the neighboring Limpopo Belt (from 200 to 300 km thick). Curiously, surface elevation decreases monotonically with increasing lithospheric thickness. This demonstrates the effect of the deep lithosphere on topography and gives us new information on the composition of the deepest parts of lithosphere.
DS201806-1242
2018
Ravi Kumar, M., Singh, A., Bhaskar Rao, Y.J., Srijayanthi, G., Satyanarayana, H.V., Sarkar, D.Vestiges of Precambrian subduction in the south Indian shield? - A seismological perspective.Tectonophysics, Vol. 740-741, pp. 27-41.Indiageophysics - seismic

Abstract: Investigation of large scale suture zones in old continental interiors offers insights into the evolution of continents. The Dharwar Craton (DC) and the Southern Granulite Terrain(SGT) of the Indian shield represent large segments of Precambrian middle to lower crust and preserve a geological record spanning from Mesoarchean to Cambrian. This study illuminates the deep structure of the Palghat-Cauvery Shear Zone System (PCSS) and the Palghat-Cauvery Suture Zone (PCSZ) that comprise crustal-scale structures related to multiple episodes of orogeny, crust formation and reworking. We utilize here 3202 high quality P-receiver functions computed using new data from a 23 station seismic network operated by us. Results show a thick (>38?km) mafic (Poisson's ratio >0.25) crust beneath the SGT. The change in crustal thickness is gradual, with a shallower Moho towards the south of PCSZ. We found little evidence for drastic changes in crustal thickness across prominent shear zones like the PCSZ and Moyar-Bhavani. Few seismic stations located along these boundaries have shown evidence for dipping reflectors around 8-20?km depth, with strikes matching well with the trends of surface geological sutures. We opine that these suture zones do not show indications of a terrane boundary. However, a drastic change in the crustal thickness is observed around the prograde metamorphic transition zone or broadly, the "Fermor line", which separates rocks of Chanockitic (Orthopyroxene bearing granitoid) and non-Charnockitic (Orthopyroxene-free granitoid) mineral assemblage, further north beneath the DC. We suggest that thicknening of crust north of Moyar-Attur Shear Zone (MASZ) and around Fermor line is related to subduction processes operative during the Precambrian.
DS201811-2603
2018
Ravi, S., Bhaskara Rao, K.S., Ready, R.A.Diamond Fields of southern India. Review in researchgateGeological Survey of India Bulletin Series A, No. 68, 996p. Indiahistory, diamond occurrence
DS201805-0973
2017
Ravna, E.K., Zozulya, D., Kullerud, K., Corfu, F., Nabelek, P.I., Janak, M., Slagstad, T., Davidsen, B., Selbekk, R.S., Schertl, H-P.Deep seated carbonatite intrusion and metasomatism in the UHP Tromso Nappe, northern Scandinavian Caledonides - a natural example of generation of carbonatite from carbonated eclogite.Journal of Petrology, Vol. 58, 12, pp. 2403-2428.Europe, Sweden, Norwaycarbonatite

Abstract: Carbonatites (sensu stricto) are igneous rocks typically associated with continental rifts, being emplaced at relatively shallow crustal levels or as extrusive rocks. Some carbonatites are, however, related to subduction and lithospheric collision zones, but so far no carbonatite has been reported from ultrahigh-pressure (UHP) metamorphic terranes. In this study, we present detailed petrological and geochemical data on carbonatites from the Tromsø Nappe—a UHP metamorphic terrane in the Scandinavian Caledonides. Massive to weakly foliated silicate-rich carbonate rocks, comprising the high-P mineral assemblage of Mg-Fe-calcite?±?Fe-dolomite?+?garnet?+?omphacitic clinopyroxene?+?phlogopite?+?apatite?+?rutile?+?ilmenite, are inferred to be carbonatites. They show apparent intrusive relationships to eclogite, garnet pyroxenite, garnet-mica gneiss, foliated calc-silicate marble and massive marble. Large grains of omphacitic pyroxene and megacrysts (up to 5?cm across) of Cr-diopside in the carbonatite contain rods of phlogopite oriented parallel to the c-axis, the density of rods being highest in the central part of the megacrysts. Garnet contains numerous inclusions of all the other phases of the carbonatite, and, in places, composite polyphase inclusions. Zircon, monazite and allanite are common accessory phases. Locally, veins of silicate-poor carbonatite (up to 10?cm across) occur. Extensive fenitization by K-rich fluids, with enrichment in phlogopite along contacts between carbonatite and silicate country rocks, is common. Primitive mantle-normalized incompatible element patterns for the carbonatite document a strong enrichment of light rare earth elements, Ba and Rb, and negative anomalies in Th, Nb, Ta, Zr and Hf. The carbon and oxygen isotope compositions of the carbonatite are distinctly different from those of the spatially associated calc-silicate marble, but also from mantle-derived carbonatites elsewhere. Neodymium and Sr isotope data coupled with the trace element distribution indicate a similarity of the Tromsø carbonatite to orogenic (off-craton) carbonatites rather than to anorogenic (on-craton) ones. U-Pb dating of relatively U-rich prismatic, oscillatory-zoned zircon gives an age of 454•5?±?1•1?Ma. We suggest that the primary carbonatite magma resulted from partial melting of a carbonated eclogite at UHP, in a deeply subducted continental slab.
DS201812-2869
2018
Rayner, M.J., Jaques, A.L., Boxer, G.L., Smith, C.B., Lorenz, V., Moss, S.W., Webb, K., Ford, D.Argyle deposit: The geology of the Argyle ( AK1) diamond deposit, western Australia.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 89-118.Australia, western Australiadeposit - Argyle
DS201809-2078
2018
Rayner, M.J., Moss, S.W., Lorenz, V., Jaques, L., Boxer, G.L., Smith, C.B., Webb, K.New insights into volcanic processes from deep mining of the southern diatreme within the Argyle lamproite pipe, Western Australia.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0625-4 13p.Australia, Western Australiadeposit - Argyle

Abstract: Underground mining and deep drilling of the richly diamondiferous ~1.2 Ga Argyle lamproite in Western Australia has prompted a re-evaluation of the geology of the pipe. Argyle is considered to be a composite pipe that formed by the coalescence of several diatremes and has been offset and elongated by post-emplacement faulting. Recent geological studies have recognised at least five distinct volcaniclastic lamproite lithofacies with differing diamond grades. The new data suggest that the centre of the southern (main) diatreme is occupied by well-bedded, olivine lamproite lapilli tuff with very high diamond grades (>10 ct/t). Characteristic features include a clast-supported fabric and high modal abundance of densely packed lamproite lapilli and coarse-grained, likely mantle-derived olivine now replaced by serpentine and/or talc. The persistence of small-scale graded and cross-bedding in this lithofacies to depths of ~1.5 km below the original surface prior to erosion suggests phreatomagmatic volcanism forming the diatreme was syn-eruptively accompanied by subsidence of the tephra, maintaining a steep-walled diatreme in the water-saturated country rock sediments.
DS201804-0730
2017
Reddicliffe, T.H., Kammermann, M.S.Merlin diamond deposit.Australian Ore Deposits, AusIMM Monograph 32, ed. Phillips, N., pp. 533-534.Australiadeposit - Merlin
DS201804-0731
2018
Reddy, S., Saxey, D., Rickard, W., Fougerouse, D.Atom probe microscopy and potential applications to diamond research.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 36-37. abstractTechnologydiamond inclusions
DS201812-2870
2018
Regier, M.E., Pearson, D.G., Stachel, T., Stern, R.A., Harris, J.Tracing the formation and abundance of superdeep diamonds.2018 Yellowknife Geoscience Forum , p. 63. abstractAfrica, Guineadeposit - Kankan

Abstract: Super-deep diamonds from the transition zone and lower mantle are valuable targets for mining, as they are often large, gem-quality1 or ultra-valuable type IIb stones2. Hence, in mine prospects, it may become important to determine the various populations of sub-lithospheric diamonds. Unambiguously identifying a diamond’s depth of formation is difficult as some minerals can be indicative of various depth regimes (e.g., ferropericlase, Ca-walstromite, enstatite, clinopyroxene, coesite). Here, we use the oxygen isotope compositions of inclusions in Kankan diamonds from Guinea to distinguish between the various diamond-forming processes that happen at lithospheric, asthenospheric to transition zone, and lower mantle depths. In this way, we hope to establish a process by which isotope geochemistry can better constrain the populations of superdeep diamonds in kimberlites, and can assist in estimating a pipe’s propensity for large, valuable stones. Oxygen isotopic analysis by secondary ion mass spectrometry (SIMS) is a high-precision technique that can track hydrothermal alteration that occurred at or close below the ocean floor. Our analyses of inclusions from Kankan diamonds demonstrate that garnets with 3-3.03 Si cations (pfu) have ?18O that are well-constrained within the normal values expected for peridotitic and eclogitic inclusions, but that garnets with ?3.04 Si cations (pfu) have consistently high ?18O (median: 10‰) that slightly decreases with increasing Cr2O3. We interpret this signal as the reaction between a melted carbonate-rich oceanic slab and normal convecting asthenosphere3. In contrast, retrogressed, or former, bridgmanite has ?18O values similar to primitive mantle, suggesting little involvement of slab melts. In contrast to the worldwide suite of lithospheric inclusions of eclogitic paragenesis (median ?18O of 7.03‰)4,5, diamonds derived from ~250 to 500 km have inclusions with consistent, extremely high oxygen isotopes (median: 9.32‰)6,7, due to the melting of extremely enriched carbonated oceanic crust. Diamonds from the lower mantle, however, have inclusions with primitive mantle oxygen isotopes, suggesting a different formation process. The clear distinction in inclusion ?18O between lithospheric, asthenospheric to transition zone, and lower mantle diamond populations is useful in informing the depth regime of a suite of stones, especially those with inclusions of ambiguous depths (e.g., clinopyroxene, coesite, Ca-walstromite, enstatite, ferropericlase, etc.). For instance, we are currently searching for exotic oxygen isotopes in ferropericlase that indicate asthenospheric diamond growth, rather than the primitive mantle values expected for lower mantle ferropericlase. In conclusion, oxygen isotopic analyses of diamond inclusions can identify various sublithsopheric diamond populations, and may benefit the assessment of a mine’s potential for large gem-quality, or type IIb diamonds.
DS201809-2079
2018
Regier, M.E., Pearson, D.G., Stachel, T., Stern, R.A., Harris, J.W.Oxygen isotopes in Kankan super deep diamond inclusions reveal variable slab mantle interaction.Goldschmidt Conference, 1p. AbstractAfrica, South Africa, Guinea, South America, Brazildeposit - Kankan, Jagersfontein, Juina

Abstract: Inclusions in super-deep diamonds provide a unique window to the sublithospheric mantle (e.g. [1-4]). Here we present oxygen isotopes for Kankan majoritic garnet and former bridgmanite inclusions. The clustering of Kankan majorites around a ?18O of +9‰ is nearly identical to those reported from Jagersfontein [1]. This elevated and nearly constant ?18O signal indicates homogenization of partial melts from the uppermost part of altered basaltic slabs. Conversely, ?18O values in Juina majorites are highly variable [2] due to crystallization from small, discrete melt pockets in a heterogeneous eclogitic source. While all these majorites have eclogitic/pyroxenitic Cr2O3 and CaO contents, charge-balance for Si[VI] is achieved very differently, with Jagersfontein [3], Kankan [4], and Juina [2] majorites transitioning from eclogitic Na[VIII]Si[VI] to peridotitic-pyroxenitic [5] Mg[VI]Si[VI] substitutions. We interpret this shift as the result of homogenized eclogitic partial melts infiltrating and reacting with adjacent pyrolitic mantle at Kankan and Jagersfontein. Increases in Mg# and Cr2O3 with reductions in ?18O support this reaction. This model is in agreement with recent experiments in which majorites and diamonds form from a reaction of slab-derived carbonatite with reduced pyrolite at 300-700 km depth [6]. The Kankan diamonds also provide an opportunity to establish the chemical environment of the lower mantle. Four inclusions of MgSiO3, inferred to be former bridgmanite [4], provide the first-measured ?18O values for lower mantle samples. These values suggest derivation from primitive mantle, or unaltered subducted oceanic lithospheric mantle. The Kankan super-deep inclusions thus provide a cross-section of deep mantle that highlights slab-pyrolite reactions in the asthenosphere and primitive compositions in the lower mantle.
DS201801-0053
2017
Reguir, E.P., Chakhmouradian, A.R., Zaitsev, A.N., Yang, P.Trace element variations and zoning in phlogopite from carbonatites and phoscorites.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 8-9.carbonatites

Abstract: Phlogopite from carbonatites and phoscorites worldwide shows three major types of core-to-rim trends of compositional variation: Ba+Al-, Fe and Fe+Al enrichment. These major-element trends are accompanied by largely consistent changes in traceelement abundances. Uptake of Rb, Sr, Ba, Sc, V, Mn and HFSE by phlogopite is susceptible to changes in the availability of these elements due to precipitation of other early silicate and oxide phases (especially, magnetite, apatite and niobates). In rare cases, more complex oscillatory and sector patterns are juxtaposed over the principal evolutionary trend, indicating kinetic and crystal-chemical controls over element uptake. Phlogopite is a common accessory to major constituent of carbonatites and genetically related rocks (including phoscorites). Major-element variations of phlogopite from these rocks have been addressed in much detail in the literature (for references, see Reguir et al. 2009), whereas its trace-element characteristics and zoning patterns have so far received little attention. In this work, we examined the compositional variation of phlogopite from 23 carbonatite and phoscorite localities worldwide. The major-element compositions were determined using wavelength-dispersive X-ray spectrometry (WDS) and trace-element abundances by laser-ablation inductively-coupled-plasma mass-spectrometry (LA-ICPMS). Previously, two major core-to-rim zoning trends have been identified in micas from calcite carbonatites (Reguir et al. 2009, 2010). Phlogopite from Oka (Canada) and Iron Hill (USA), for example, involves an increase in kinoshitalite component rim-ward, accompanied by enrichment in high-field-strength elements (HFSE = Zr, Nb, Ta), Sr and Sc. At most other carbonatite localities (e.g., Kovdor in Russia, or Prairie Lake in Canada), phlogopite crystals exhibit rim-ward enrichment in Fe. In the present work, we confirmed these two common types of zoning, and identified new patterns that have not been reported in the previous literature. In addition to the common Fe-enrichment trend, which occurs in both carbonatites (e.g., Guli in Russia and Sokli in Finland) and phoscorites (e.g., Aley in Canada), we identified a Fe-Al-enrichment subtype of this zoning pattern observed, for example, in samples from the Shiaxiondong calcite carbonatite (China). Overall, the Fe-enrichment pattern is accompanied by rim-ward depletion in Ba, Rb and HFSE, coupled with enrichment in Mn. Other trace elements exhibit no consistent variation among the studied samples. The Shiaxiondong material is characterized by the highest recorded Rb values, ranging from 1120 to 660 ppm. Phlogopite from the Kovdor calcite-forsterite-magnetite phoscorite contains the highest recorded levels of Nb and Ta, ranging from 320 ppm and 40 ppm, respectively, in the core to 85 ppm and 4 ppm in the rim. The maximum levels of Zr (up to 50 ppm) were observed in the core of Prairie Lake phlogopite, whereas its rim contains the highest measured Mn content (up to 4100 ppm). The levels of Sc are typically below 100 ppm in samples from calcite and dolomite carbonatites, but may reach 280 ppm in phoscorites. Interestingly, phlogopite from phoscorites shows rim-ward enrichment in Sc, whereas the opposite trend is observed in carbonatitic micas. Phlogopite from calcite carbonatites at Zibo (China) and Valentine Township (Canada), and from phoscorites at Aley (Canada) shows an unusual zoning pattern involving depletion in Fe, which is accompanied by a decrease in Al, Ba, Sr, Zr, Hf, Y, Sc and V abundances. The concentrations of other trace elements, including Nb and Ta show inconsistent variations. In the Aley phoscorite, phlogopite is enriched in Ba (up to 15000 ppm in the core and < 7500 ppm in the rim), but poor in Sr (80 and 35 ppm in the core and rim, respectively) relative to those from the Zibo and Valentine carbonatites. Zirconium levels reach 200 and 170 ppm in the core, and drop to < 40 and 60 ppm in the rim of the Valentine and Zibo samples, respectively. In the Aley sample, the content of Zr does not exceed 55 ppm. The Zibo sample is also enriched in V (up to 230 and 160 ppm in the core and rim, respectively) relative to the two other samples (< 100 ppm V). The Sc and Hf levels are consistently low (less than 30 and 4 ppm, respectively). In addition to simple core-rim patterns, phlogopite from carbonatites and phoscorites may exhibit oscillatory zoning, which involves periodic variations in Fe/Mg ratio. Iron-rich zones are relatively depleted in Mn, but enriched in Nb. One sample of phoscoritic phlogopite (Aley) exhibits striking sector zoning juxtaposed over the overall Feenrichment trend and Fe-Mg oscillations. In terms of major elements, basal sectors perpendicular to [001] are enriched in Fe and Al, but depleted in Mg and K relative to the flank sectors. This enrichment is accompanied by higher Ba, Sr and HFSE levels in the basal sector. Our data confirm that there is no universal pattern of zoning in carbonatitic or phoscoritic phlogopite, and variations in the content of most trace elements are strongly coupled to major-element patterns. Three major core-to-rim variation trends, as well as juxtaposed oscillatory and sector patterns, can be recognized. The observed compositional variations indicate that, in the majority of cases, the trace-element composition of phlogopite is controlled by partitioning of Rb, Sr, Ba, Sc, V, Mn and HFSE between this mineral, its parental magma, and co-precipitating early phases. Among the latter, magnetite, apatite and niobates appear to exert the greatest influence on element distributions. More complex oscillatory and sector patterns imply the presence of kinetic and crystal-chemical controls over element uptake in certain carbonatitic systems
DS201812-2871
2018
Reimink, J.From Iceland to Indonesia: understanding the Slave Craton from a modern geological context. Keynote address.2018 Yellowknife Geoscience Forum , 1p. AbstractCanada, Northwest Territoriescraton

Abstract: The formation of continental crust makes Earth unique in our solar system. Yet, despite the importance of the continents for the evolution of the atmosphere, hydrosphere, and life, the mechanism and timing of continental growth throughout Earth history is poorly known. The presently exposed continental crust has an age distribution that would suggest most of the mass grew relatively recently. However, the planet is constantly reworking itself, so age distributions are biased towards young ages. Therefore, geochemists must turn to isotopic tracers to infer the amount of crustal reworking that has occurred to form the presently exposed, or previously eroded, continental crust. The Slave craton, in the NWT, Canada, is in many ways a classic Archean craton. One reason for this is that the Slave craton preserves an extensive history of crust formation, spanning from 4.02 Ga to 2.58 Ga. This talk will focus on the petrology and isotope geochemistry of the oldest preserved rocks in the craton, rocks which form the deformed basement gneiss complex. These rocks preserve the oldest history of the craton and form the substrate upon which later geologic events occurred. Our record of crust formation indicates that the Slave craton basement gneisses record a major change in the mechanism of crust formation, a transition that represents a change from internal reprocessing in a setting analogous to modern Iceland, to crust formation in a setting more similar to modern continental-margin settings. This data is discussed in the context of global paradigms for crust formation throughout Earth history.
DS201810-2371
2018
Reis, N.J., Nadeau, S., Fraga, L.M., Betiollo, L.M., Faraco, M.T.L., Reece, J., Lachhman, D., Ault, R.Stratigraphy of the Roraima Supergroup along the Brazil-Guyana border in the Guiana shield, northern Amazonian craton- results of the Brazil-Guyana geology and geodiversity mapping project.Brazilian Journal of Geology, Vol. 47, 1, pp. 43-57.South America, Brazil, Guyanacraton

Abstract: The Geological and Geodiversity Mapping binational program along the Brazil?Guyana border zone allowed reviewing and in? tegrating the stratigraphy and nomenclature of the Roraima Supergroup along the Pakaraima Sedimentary Block present in northeastern Brazil and western Guyana. The area mapped corresponds to a buffer zone of approximately 25 km in width on both sides of the border, of a region extending along the Maú?Ireng River between Mount Roraima (the tri? ple?border region) and Mutum Village in Brazil and Monkey Mountain in Guyana. The south border of the Roraima basin is overlain exclusively by effusive and volcaniclastic rocks of the Surumu Group of Brazil and its correlated equivalent the Burro?Burro Group of Guyana.
DS201809-2080
2018
Renfro, N.D., Palke, A.C., Berg, R.B.Gemological characterization of sapphires from Yogo Gulch, Montana.Gems & Gemology, Vol. 54, 2, pp. 184-201.United States, Montanadeposit - Yogo Gulch

Abstract: Yogo Gulch in central Montana is one of the most important gem deposits in the United States. Although very little material has been recovered there in recent years, it has produced several million carats of rough sapphire over the course of its history (Voynick, 2001). These stones, known for their vibrant untreated blue color and high clarity, have always commanded a price premium, especially in sizes larger than 0.75 ct. This paper offers a thorough gemological characterization of Yogo sapphire, which may be unfamiliar to many gemologists. Fortunately, Yogo sapphires are unique and experienced gemologists can easily separate them from gem corundum of different geographic origins throughout the world, making it possible to determine the provenance of important stones from this deposit.
DS201801-0054
2017
Reutsky, V.N., Shiryaev, A.A., Titkov, S.V., Wiedenbeck, M., Zudina, N.N.Evidence for large scale fractionation of carbon isotopes and of nitrogen impurity during crystallization of gem quality cubic diamonds from placers of North Yakutia.Geochemistry International, Vol. 55, 11, pp. 988-999.Russia, Yakutiaalluvials

Abstract: The spatial distribution of carbon and nitrogen isotopes and of nitrogen concentrations is studied in detail in three gem quality cubic diamonds of variety II according to Orlov’s classification. Combined with the data on composition of fluid inclusions our results point to the crystallization of the diamonds from a presumably oxidized carbonate fluid. It is shown that in the growth direction ?13C of the diamond becomes systematically lighter by 2-3‰ (from -13.7 to -15.6‰ for one profile and from -11.7 to -14.1‰ for a second profile). Simultaneously, we observe substantial decrease in the nitrogen concentration (from 400-1000 to 10-30 at ppm) and a previously unrecognized enrichment of nitrogen in light isotope, exceeding 30‰. The systematic and substantial changes of the chemical and isotopic composition can be explained using the Burton-Prim-Slichter model, which relates partition coefficients of an impurity with the crystal growth rate. It is shown that changes in effective partition coefficients due to a gradual decrease in crystal growth rate describes fairly well the observed scale of the chemical and isotopic variations if the diamond-fluid partition coefficient for nitrogen is significantly smaller than unity. This model shows that nitrogen isotopic composition in diamond may result from isotopic fractionation during growth and not reflect isotopic composition of the mantle fluid. Furthermore, it is shown that the infra-red absorption at 1332 ?m-1 is an integral part of the Y-defect spectrum. In the studied natural diamonds the 1290 ?m-1 IR absorption band does not correlate with boron concentration.
DS201806-1243
2018
Rezvukhin, D.I., Malkovets, V.G., Sharygin, I.S., Tretiakova, I.G., Griffin, W.L., O'Reilly, S.Y.Inclusions of crichtonite group minerals in Cr-pyropes from the Internationalnaya kimberlite pipe, Siberian craton: crystal chemistry, parageneses and relationships to mantle metasomatism.Lithos, Vol. 308, 1, pp. 181-195.Russiadeposit - International

Abstract: Cr-pyrope xenocrysts and associated inclusions of crichtonite-group minerals from the Internatsionalnaya kimberlite pipe were studied to provide new insights into processes in the lithospheric mantle beneath the Mirny kimberlite field, Siberian craton. Pyropes are predominantly of lherzolitic paragenesis (Cr2O3 2-6?wt%) and have trace-element spectra typical for garnets from fertile mantle (gradual increase in chondrite-normalized values from LREE to MREE-HREE). Crichtonite-group minerals commonly occur as monomineralic elongated inclusions, mostly in association with rutile, Mg-ilmenite and Cr-spinel within individual grains of pyrope. Sample INT-266 hosts intergrowth of crichtonite-group mineral and Cl-apatite, while sample INT-324 contains polymineralic apatite- and dolomite-bearing assemblages. Crichtonite-group minerals are Al-rich (1.1-4.5?wt% Al2O3), moderately Zr-enriched (1.3-4.3?wt% ZrO2), and are Ca-, Sr-, and occasionally Ba-dominant in terms of A-site occupancy; they also contain significant amounts of Na and LREE. T-estimates and chemical composition of Cr-pyropes imply that samples represent relatively low-T peridotite assemblages with ambient T ranging from 720 to 820°?. Projected onto the 35?mW/m2 cratonic paleogeotherm for the Mirny kimberlite field (Griffin et al., 1999b. Tectonophysics 310, 1-35), temperature estimates yield a P range of ~34-42?kbar (~110-130?km), which corresponds to a mantle domain in the uppermost part of the diamond stability field. The presence of crichtonite-group minerals in Cr-pyropes has petrological and geochemical implications as evidence for metasomatic enrichment of some incompatible elements in the lithospheric mantle beneath the Mirny kimberlite field. The genesis of Cr-pyropes with inclusions of crichtonite-group minerals is attributed to the percolation of Ca-Sr-Na-LREE-Zr-bearing carbonate-silicate metasomatic agents through Mg- and Cr-rich depleted peridotite protoliths. The findings of several potentially new members of the crichtonite group as inclusions in garnet extend existing knowledge on the compositions and occurrences of exotic titanates stable in the lithospheric mantle.
DS201809-2081
2018
Richards, M.A., Lenardic, A.The Cathles parameter (Ct): a geodynamic definition of the asthenosphere and implications for the nature of plate tectonics.Researchgate, researchgate.net/ publication/ 326722590 46p.Mantlegeophysics

Abstract: A weak asthenosphere, or low viscosity zone (LVZ) underlying Earth’s lithosphere has historically played an important role in interpreting isostasy, post-glacial rebound (PGR), and the seismic low velocity zone, as well as proposed mechanisms for continental drift, plate tectonics, and post-seismic relaxation (PSR). Careful consideration of the resolving power of PGR, PSR, and geoid modeling studies suggests a sublithospheric LVZ perhaps ~100-200 km thick with a viscosity contrast of ~100-1000. Ab initio numerical models of plate-like boundary layer motions in mantle convection also suggest a key role for the LVZ. Paradoxically, a thinner LVZ with a strong viscosity contrast is most effective in promoting plate-like surface motions. These numerical results are explained in terms of the reduction in horizontal shear dissipation due to an LVZ, and a simple scaling theory leads to somewhat non-intuitive model predictions. For example, an LVZ causes stress magnification at the base of the lithosphere, enhancing plate boundary formation. Also, flow within the LVZ may be driven by the plates (Couette flow), or pressure-driven from within the mantle (Poiseuille flow), depending upon the degree to which plates locally inhibit or drive underlying mantle convection. For studies of the long-wavelength geoid, PGR, and mantle convection, a simple dimensionless parameter controls the effect of the LVZ. This “Cathles parameter” is given by the expression Ct=v*(D/L)3, where v* is the viscosity contrast and D is the thickness of the LVZ, and L is the flow wavelength, emphasizing the tightly-coupled, largely un-resolvable tradeoff between LVZ thickness and viscosity contrast.
DS201812-2872
2018
Richards, M.A., Lenardic, A.The Cathles parameter ( Ct): a geodynamic definition of the asthenosphere and implications for the nature of plate tectonics.researchgate.com, doi:10.1029/2018 /GC007664 46p.Mantlegeodynamics

Abstract: The Earth's global system of tectonic plates move over a thin, weak channel ("low viscosity zone") in the mantle immediately underlying the plates. This weak channel is commonly referred to as the asthenosphere, and its presence accounts for a number of important Earth observations, including isostasy (e.g., support for the uplift of large mountain ranges), the shape of the Earth's gravity field, the response of the Earth's surface to the removal of large ice sheets ("postglacial rebound"), and the relationship between plate motions and underlying thermal convection in the mantle. In this paper, we show that these phenomena can be understood in terms of a single unifying parameter consisting of the viscosity contrast between the asthenosphere and the underlying mantle, and the cube of the thickness of the asthenosphere. We propose to call this the "Cathles parameter" in recognition of the author who first recognized its importance in postglacial rebound studies.
DS201811-2604
2018
Richetti, P.C., Schmitt, R.S., Reeves, C.Dividing the South American continent to fit a Gondwana reconstruction: A model based on continental geology.Tectonophysics, Vol. 747-748, pp. 79-98.South Americaplate tectonics

Abstract: The South American continental plate has been affected by intraplate deformation since the start of West Gondwana disruption in the Lower Cretaceous (about 140?Ma). That the present shape of South America is not precisely the same as its shape in reassembled Gondwana partly explains the imperfect fits of the conjugate margins of the South Atlantic proposed since the first reconstruction models of the early 20th century. Several attempts at defining subplates within South America have been published but not all take account of existing knowledge of its continental geology. Here a subdivision into eight rigid subplates is proposed, based primarily on geological and tectonic evidence. Our model is tested against three published models of a multi-subplate Africa, as re-shaped to the pre-breakup outline of that continent, by visual fitting and the use of piercing points. The South America blocks were rotated and the Euler poles calculated interactively in reconstruction software. All three proposed fits had overlapping block margins within South America, indicating post-breakup rifting, except for the Transbrasiliano lineament. This NNE-SSW crustal-scale shear zone was used as a boundary for seven of the eight blocks. It is clearly the main intraplate accommodation zone in South America and an important piercing point in relation to the Kandi lineament in West Africa. The other block boundaries correspond to narrow zones with sedimentary basins and/or dyke swarms that have developed since South Atlantic opening. Each fit required a different configuration of the South America subplates since the pre-rift disposition of the African subplates also differ from each other, contributing to the uncertainty in any detailed reassembly.
DS201812-2873
2018
Richetti, P.C., Schmitt, R.S., Reeves, C.Dividing the South American continent to fit a Gondwana reconstruction: a model based on continental geology.Tectonophysics, Vol. 747-748, pp. 79-98.South Americatectonics

Abstract: The South American continental plate has been affected by intraplate deformation since the start of West Gondwana disruption in the Lower Cretaceous (about 140?Ma). That the present shape of South America is not precisely the same as its shape in reassembled Gondwana partly explains the imperfect fits of the conjugate margins of the South Atlantic proposed since the first reconstruction models of the early 20th century. Several attempts at defining subplates within South America have been published but not all take account of existing knowledge of its continental geology. Here a subdivision into eight rigid subplates is proposed, based primarily on geological and tectonic evidence. Our model is tested against three published models of a multi-subplate Africa, as re-shaped to the pre-breakup outline of that continent, by visual fitting and the use of piercing points. The South America blocks were rotated and the Euler poles calculated interactively in reconstruction software. All three proposed fits had overlapping block margins within South America, indicating post-breakup rifting, except for the Transbrasiliano lineament. This NNE-SSW crustal-scale shear zone was used as a boundary for seven of the eight blocks. It is clearly the main intraplate accommodation zone in South America and an important piercing point in relation to the Kandi lineament in West Africa. The other block boundaries correspond to narrow zones with sedimentary basins and/or dyke swarms that have developed since South Atlantic opening. Each fit required a different configuration of the South America subplates since the pre-rift disposition of the African subplates also differ from each other, contributing to the uncertainty in any detailed reassembly.
DS201810-2372
2018
Rielli A., Tomkins, A.G., Nebel, O., Raveggi, M., Jeon, H., Martin, L., Laure, A., Janaina, N.Sulfur isotope and PGE systematics of metasomatised mantle wedge.Earth and Planetary Science Letters, Vol. 497, 1, pp. 181-192.Mantlemetasomatism

Abstract: At convergent margins fluids liberated from subducting slabs metasomatise the overlying mantle wedge, enriching it in volatiles, incompatible elements and possibly ore-forming metals. Despite the genetic link between this process, the genesis of arc magmas, and formation of porphyry Cu-Au deposits, there is currently little understanding of the behaviour of chalcophile and siderophile elements during subduction-related mantle metasomatism. In this study, we report sulfur isotopic compositions and PGE concentrations of sulfides in a suite of garnet peridotites from the Western Gneiss Region of Norway, sampling mantle wedge from ?100 to ?250 km depth. Sulfides hosted in metasomatised samples have deviated from typical mantle values, ranging between ?10.0 and +5.4‰, indicating derivation of sulfur from subducted crust. Sulfides in pervasively metasomatised samples have atypical PGE signatures, with strong enrichment in Os and Ru relative to Ir, whereas channelised fluid flow produced sulfides extremely enriched in Pd, up to 700 times the concentration found in non-metasomatised samples. These signatures are reconcilable with a high oxidation state of the metasomatising agents and demonstrate that subduction can recycle chalcophile and siderophile elements into and within the mantle, along with sulfur. We further show that because the solubility of Os and Ru in fluids is redox sensitive, and Pd is more soluble than the I-PGE, ratios such as Os/Ir, Ru/Ir plotted against Pd/Ir can be used to trace the metasomatic oxidation of mantle samples, mantle-derived magmas and porphyry Cu±Au deposits. This geochemical insight is used to show that Au-rich porphyry Cu deposits are derived from more oxidised mantle wedge than Au-poor porphyry deposits.
DS201810-2373
2018
Roberts, G.G., White, N., Hoggard, M.J., Ball, P.W., Meenan, C.A Neogene history of mantle convective support beneath Borneo.Earth and Planetary Science Letters, Vol. 496, 1, pp. 142-158.Asia, Borneoconvection

Abstract: Most, but not all, geodynamic models predict 1-2 km of mantle convective draw-down of the Earth's surface in a region centered on Borneo within southeast Asia. Nevertheless, there is geomorphic, geologic and geophysical evidence which suggests that convective uplift might have played some role in sculpting Bornean physiography. For example, a long wavelength free-air gravity anomaly of +60 mGal centered on Borneo coincides with the distribution of Neogene basaltic magmatism and with the locus of sub-plate slow shear wave velocity anomalies. Global positioning system measurements, an estimate of elastic thickness, and crustal isostatic considerations suggest that regional shortening does not entirely account for kilometer-scale regional elevation. Here, we explore the possible evolution of the Bornean landscape by extracting and modeling an inventory of 90 longitudinal river profiles. Misfit between observed and calculated river profiles is minimized by smoothly varying uplift rate as a function of space and time. Erosional parameters are chosen by assuming that regional uplift post-dates Eocene deposition of marine carbonate rocks. The robustness of this calibration is tested against independent geologic observations such as thermochronometric measurements, offshore sedimentary flux calculations, and the history of volcanism. A calculated cumulative uplift history suggests that kilometer-scale Bornean topography grew rapidly during Neogene times. This suggestion is corroborated by an offshore Miocene transition from carbonate to clastic deposition. Co-location of regional uplift and slow shear wave velocity anomalies immediately beneath the lithospheric plate implies that regional uplift could have been at least partly generated and maintained by temperature anomalies within an asthenospheric channel.
DS201802-0261
2017
Robinson, P.T., Yang, J., Tian, Y., Zhu, H.Diamonds, super reduced and crustal minerals in chromitites of the Hegenshan and Sartohay ophiolites, central Asian orogenic belt, China.Acta Geologica Sinica, Vol. 91, 1, p. 32.Asia, Chinamineralogy

Abstract: The Central Asian Orogenic Belt (CAOB) is a huge tectonic mélange that lies between the North China Craton and the Siberian Block. It is composed of multiple orogenic belts, continental fragments, magmatic and metamorphic rocks, suture zones and discontinuous ophiolite belts. Although the Hegenshan and Sartohay ophiolites are separated by nearly 3000 km and lie in completely different parts of the CAOB, they are remarkably similar in many respects. Both are composed mainly of serpentinized peridotite and dunite, with minor gabbro and sparse basalt. They both host significant podiform chromitites that consist of high-Al, refractory magnesiochromite with Cr#s [100Cr/(Cr+Al)] averaging >60. The Sartohay ophiolite has a zircon U-Pb age of ca. 300 Ma and has been intruded by granitic plutons of similar age, resulting in intense hydrothermal activity and the formation of gold-bearing listwanites. The age of the Hegenshan is not firmly established but is thought to have formed in the Carboniferous.Like many other ophiolites that we have investigated in other orogenic belts, the chromitites in these two bodies have abundant diamonds, as well as numerous super-reduced and crustal minerals. The diamonds are mostly, colorless to pale yellow, 200-300 ?m across and have euhedral to anhedral shapes. They all have low carbon isotopes (?14C = ?18 to ?29) and some have visible inclusions. These are accompanied by numerous super-reduced minerals such as moissanite, native elements (Fe, Cr, Si, Al, Mn), and alloys (e.g., Ni-Mn-Fe, Ni-Fe-Al, Ni-Mn-Co, Cr-Ni-Fe, Cr-Fe, Cr-Fe-Mn), as well as a wide range of oxides, sulfides and silicates. Grains of zircon are abundant in the chromitites of both ophiolites and range in age from Precambrian to Cretaceous, reflecting both incorporation of old zircons and modification of grains by hydrothermal alteration. Our investigation confirms that high-Al, refractory chromitites in these two ophiolites have the same range of exotic minerals as high-Cr metallurgical chromitites such as those in the Luobusa ophiolite of Tibet. These collections of exotic minerals in ophiolitic chromitites indicate complex, multi-stage recycling of oceanic and continental crustal material at least to the mantle transition zone, followed by uprise and emplacement of the peridotites into relatively shallow ophiolites.
DS201808-1784
2012
Robles-Cruz, S., Melgarejo, J.C., Escayola, M.Major and trace element compositions of indicator minerals that occur as macro and megacrysts, and xenoliths from kimberlites in northeastern Angola.Minerals, Vol. 2, 4, ppp. 318-337.Africa, Angolageochemistry

Abstract: In this study, we compare the major- and trace-element compositions of olivine, garnet, and clinopyroxene that occur as single crystals (142 grains), with those derived from xenoliths (51 samples) from six kimberlites in the Lucapa area, northeastern Angola: Tchiuzo, Anomaly 116, Catoca, Alto Cuilo-4, Alto Cuilo-63 and Cucumbi-79. The samples were analyzed using electron probe microanalysis (EPMA) and laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS). The results suggest different paragenetic associations for these kimberlites in the Lucapa area. Compositional overlap in some of the macrocryst and mantle xenolith samples indicates a xenocrystic origin for some of those macrocrysts. The presence of mantle xenocrysts suggests the possibility of finding diamond. Geothermobarometric calculations were carried out using EPMA data from xenoliths by applying the program PTEXL.XLT. Additional well calibrated single-clinopyroxene thermobarometric calculations were also applied. Results indicate the underlying mantle experienced different equilibration conditions. Subsequent metasomatic enrichment events also support a hypothesis of different sources for the kimberlites. These findings contribute to a better understanding of the petrogenetic evolution of the kimberlites in northeastern Angola and have important implications for diamond exploration.
DS201812-2874
2018
Rodel, A.Ramping up from construction to operations: lessons learned at Gahcho Kue diamond mine.2018 Yellowknife Geoscience Forum , p. 65. abstractCanada, Northwest Territoriesdeposit - Gahcho Kue

Abstract: Numerous glacial dispersal trains, spatially and compositionally associated to kimberlites, have been characterized and mapped in the Lac de Gras region, Northwest Territories (NT). However, a small number of these trains have yet to be associated with a source. Additionally, a number of known sub-cropping kimberlites do not have well-defined, spatially associated, trains of indicator minerals. These issues suggest that local factors may be important in controlling the occurrence, shape, and strength of a dispersal pattern and its spatial association with a kimberlite. Identifying these factors and understanding their effect on the dispersion of indicator minerals could provide a road map for finding additional diamondiferous kimberlites in the NT and elsewhere. Here we examine contrasting dispersal trains from south and southwest of Lac de Gras, as well as situations where the source of known dispersal trains (e.g., Coppermine Train) continue to elude exploration geologists. Using both surface and subsurface datasets, we find that the bedrock geology and topography of the source area, as well as those of the dispersal area, are potential key controls on the type and shape of dispersal patterns. Even across discontinuous drift and subdued shield relief we find that bedrock topography and lithology modulated the effect of glacial dynamics on till production and provenance. These 'bedrock factors' have interacted in various ways during Quaternary glaciations, in combinations unique to each case, to generate complex dispersal patterns in three dimensions. Accounting for these factors, using both surface and subsurface data, could enhance the success of drift exploration programs and improve their outcome in the glaciated shield terrains of northern Canada.
DS201812-2875
2018
Roffey, S., Rayner, M.J., Davy, A.T., Platell, R.W.Argyle deposit: Evaluation of the AK1 deposit at Argyle diamond mine.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 65-88.Australia, western Australiadeposit - Argyle
DS201806-1244
2018
Rosas, J.C., Korenaga, J.Rapid crustal growth and efficient crustal recycling in the Earth: implications for Hadean and Archean geodynamics.Earth and Planetary Science Letters, Vol. 494, pp. 42-49.Mantlegeodynamics

Abstract: The geodynamic regime of the early Earth remains elusive, with so far proposed hypotheses ranging from stagnant lid convection to rapid plate tectonics. Available geological data are severely limited for the first two billion years of the Earth's history, and this scarcity of relevant data is often compounded by the nonuniqueness of interpretation. Here we propose that the samarium-neodymium isotope evolution, which has been suggested to be consistent with stagnant lid convection in the early Earth, may be better understood as the result of rapid crustal growth and extensive crustal recycling. We delineate the permissible scenario of crustal evolution through geochemical box modeling with a Monte Carlo sampling of the model parameter space, and our results suggest that the net growth of continental crust was complete by the end of the Hadean and that the rate of crustal recycling could have been as high as kg Gyr?1 at that time and has gradually decreased since then. Such crustal evolution yields a specific prediction for the present-day distribution of crustal formation ages, which is shown to be in remarkable agreement with a recent estimate based on the global compilation of zircon age data. The mode of subsolidus mantle convection after the putative magma ocean is probably plate tectonics, but its style could have been very different from that of contemporary plate tectonics, characterized by more voluminous magmatism and more destructive subduction.
DS201808-1785
2018
Rose, B.C. ,Huang, D., Zhang, Z-H., Stevenson, P., Tyryshkin, A.M., Sangtawesin, S., Srinivasan, S., Loudin, L., Markham, M.L., Edmonds, A.M., Twitchen, D.J., Lyon, S.A., de Leon, N.P.Observation of an environmentally insensitive solid-state spin defect in diamond.Science , Vol. 361, July 6, p. 60-63.Technologysynthetic

Abstract: Engineering coherent systems is a central goal of quantum science. Color centers in diamond are a promising approach, with the potential to combine the coherence of atoms with the scalability of a solid-state platform. We report a color center that shows insensitivity to environmental decoherence caused by phonons and electric field noise: the neutral charge state of silicon vacancy (SiV0). Through careful materials engineering, we achieved >80% conversion of implanted silicon to SiV0. SiV0 exhibits spin-lattice relaxation times approaching 1 minute and coherence times approaching 1 second. Its optical properties are very favorable, with ~90% of its emission into the zero-phonon line and near -transform-limited optical linewidths. These combined properties make SiV0 a promising defect for quantum network applications.
DS201810-2374
2018
Rosenthal, A., Yaxley, G.M., Crichton, W.A., Kovacs, I.J., Spandler, C., Hermann, J., Sandorne, J.K., Rose-Koga, E., Pelleter, A-A.Phase relations and melting of nominally 'dry' residual eclogites with variable CaO/Na2O from 3 to 5 Gpa and 1250 to 1500C; implications for refertilisation of upwelling heterogeneous mantle. Lithos, Vol. 314-315, pp. 506-519.Mantlemelting
DS201812-2876
2018
Ross, M., Kelley, S.E., Janzen, R., Stirling, R.A., Normandeau, P.X., Elliott, B.Orphan and elusive glacial dispersal trains from kimberlites in the Lac de Gras area.2018 Yellowknife Geoscience Forum , p. 65-66. abstractCanada, Northwest Territoriesgeochemistry

Abstract: Numerous glacial dispersal trains, spatially and compositionally associated to kimberlites, have been characterized and mapped in the Lac de Gras region, Northwest Territories (NT). However, a small number of these trains have yet to be associated with a source. Additionally, a number of known sub-cropping kimberlites do not have well-defined, spatially associated, trains of indicator minerals. These issues suggest that local factors may be important in controlling the occurrence, shape, and strength of a dispersal pattern and its spatial association with a kimberlite. Identifying these factors and understanding their effect on the dispersion of indicator minerals could provide a road map for finding additional diamondiferous kimberlites in the NT and elsewhere. Here we examine contrasting dispersal trains from south and southwest of Lac de Gras, as well as situations where the source of known dispersal trains (e.g., Coppermine Train) continue to elude exploration geologists. Using both surface and subsurface datasets, we find that the bedrock geology and topography of the source area, as well as those of the dispersal area, are potential key controls on the type and shape of dispersal patterns. Even across discontinuous drift and subdued shield relief we find that bedrock topography and lithology modulated the effect of glacial dynamics on till production and provenance. These 'bedrock factors' have interacted in various ways during Quaternary glaciations, in combinations unique to each case, to generate complex dispersal patterns in three dimensions. Accounting for these factors, using both surface and subsurface data, could enhance the success of drift exploration programs and improve their outcome in the glaciated shield terrains of northern Canada.
DS201803-0472
2017
Rubin, A.E., Ma, C.Meteoritic minerals and their origins. Review Chemie der Erde, Vol. 77, pp. 325-385.Globalmeteorites

Abstract: About 435 mineral species have been identified in meteorites including native elements, metals and metallic alloys, carbides, nitrides and oxynitrides, phosphides, silicides, sulfides and hydroxysulfides, tellurides, arsenides and sulfarsenides, halides, oxides, hydroxides, carbonates, sulfates, molybdates, tungstates, phosphates and silico phosphates, oxalates, and silicates from all six structural groups. The minerals in meteorites can be categorized as having formed by a myriad of processes that are not all mutually distinct: (1) condensation in gaseous envelopes around evolved stars (presolar grains), (2) condensation in the solar nebula, (3) crystallization in CAI and AOI melts, (4) crystallization in chondrule melts, (5) exsolution during the cooling of CAIs, (6) exsolution during the cooling of chondrules and opaque assemblages, (7) annealing of amorphous material, (8) thermal metamorphism and exsolution, (9) aqueous alteration, hydrothermal alteration and metasomatism, (10) shock metamorphism, (11) condensation within impact plumes, (12) crystallization from melts in differentiated or partially differentiated bodies, (13) condensation from late-stage vapors in differentiated bodies, (14) exsolution, inversion and subsolidus redox effects within cooling igneous materials, (15) solar heating near perihelion, (16) atmospheric passage, and (17) terrestrial weathering.
DS201810-2375
2018
Ryan, A.G., Russell, J.K., Heap, M.J.Rapid solid state sintering in volcanic systems.American Mineralogist, MS #6714, 19p.Mantlevolcanism
DS201804-0732
2018
S&P Global Market IntelligenceWorld Exploration trends.PDAC , 12p. PdfGlobaleconomics
DS201812-2877
2018
Sacco, D.A., White, D., McKillop, R.Re-thinking diamond exploration tactics in the Slave Province: a surficial geology perspective. Lac de Gras area2018 Yellowknife Geoscience Forum , p. 66-67. abstractCanada, Northwest Territoriesgeochemistry

Abstract: It took several decades to develop the necessary understanding of glaciation, geochemistry and mineralogy to refine exploration strategies and find the first kimberlite in the Northwest Territories, Canada. These fundamental drift prospecting strategies followed by geophysics and drilling have been used to locate many kimberlite occurrences over the years. Indicator minerals in surface sediments are still the primary datasets used to identify kimberlite exploration targets; however, many of the kimberlite sources for the well-defined indicator mineral dispersals have been identified. Exploration must now focus on regions with more complex surficial geology where primary dispersal patterns in till are obscured by post-depositional modification. These patterns are largely defined using data from historical “˜till' surveys that often failed to properly scrutinize the sample media; reworked tills and other surficial materials were commonly collected. The regional surficial geology maps (e.g., 1:50,000 to 1:250,000) typically published by geological surveys to stimulate reconnaissance exploration in new areas are generally incapable of providing sufficient resolution to determine the genesis and post-glacial alteration of sample media or reconcile complex dispersal patterns. Furthermore, advances in analytical methods have yielded compiled datasets with results from multiple methods that are not always comparable. Without a new, more detailed and systematic approach to evaluating surface sediment data, exploration in areas with complex glacial, deglacial and post-glacial histories will be challenged to discover kimberlite. The accessibility, quality and variety of high-resolution aerial or satellite imagery and topographic data has improved significantly over the years, affording a more detailed interpretation of the surficial environment. These detailed interpretations have allowed us to evaluate historical data with a new perspective and target the collection of new, high-quality data. Throughout the Slave Province, we have tailored surficial interpretations to distinguish in-situ till from reworked till and other materials, which have altered dispersion and indicator mineral concentrations. Using examples from the Lac de Gras area, this presentation demonstrates how a detailed surficial framework, combined with an understanding of the varied analytical methods, is applied to historical datasets to refine indicator dispersal patterns and identify new exploration targets. By standardizing the data based on sediment genesis and transport mechanisms, the dataset becomes more suitable for statistical evaluation and anomaly threshold determinations that are unique to specific data subpopulations. As a result, anomaly contrasts are improved, and complex dispersals can be unravelled. In addition, areas with insufficient data coverage are identified and the necessary framework to complete informed, efficient infill or new sampling is provided. The examples we share highlight that there is no replacement for project-scale understanding of surficial geology and its varied effects on mineral dispersals in the development and interpretation of a surface sediment dataset used to identify kimberlite exploration targets.
DS201806-1245
2018
Saga, S., Dasguota, R., Tsuno, K.High pressure phase relations of a depleted peridotite fluxed by CO2, H2O bearing siliceous melts and the origin of mid lithospheric discontinuity.Geochemistry, Geophysics, Geosystems, Vol. 19, 3, pp. 595-620.Mantleperidotites

Abstract: We present phase equilibria experiments on a depleted peridotite (Mg# 92) fluxed with variable proportions of a slab?derived rhyolitic melt (with 9.4 wt.% H2O, 5 wt.% CO2), envisaging an interaction that could occur during formation of continents by imbrication of slabs/accretion of subarc mantles. Experiments were performed with 5 wt.% (Bulk 2) and 10 wt.% (Bulk 1) melt at 950-1175°C and 2-4 GPa using a piston?cylinder and a multi?anvil apparatus, to test the hypothesis that volatile?bearing mineral?phases produced during craton formation can cause reduction in aggregate shear?wave velocities (VS) at mid?lithospheric depths beneath continents. In addition to the presence of olivine, orthopyroxene, clinopyroxene, and garnet/spinel, phlogopite (Bulk 1: 3-7.6 wt.%; Bulk 2: 2.6-5 wt.%) at 2-4 GPa, and amphibole (Bulk 1: 3-9 wt.%; Bulk 2: 2-6 wt.%) at 2-3 GPa (?1050°C) are also present. Magnesite (Bulk 1: ?1 wt.% and Bulk 2: ?0.6 wt.%) is present at 2-4 GPa (<1000°C at 3 and?100 km depth.
DS201810-2376
2018
Salazar-Mora, C.A., Huismans, R.S., Fossen, H., Egydio-Silva, M.The Wilson cycle and effects of tectonic structural inheritance on rifted passive margin formations.Tectonics, doi.org/10.1029/ 2018TC004962Oceanstectonics

Abstract: The parallelism between older collisional belts and younger rift systems is widely known and particularly well portrayed along the Atlantic Ocean. How tectonic inherited and new?formed shear zones control rift nucleation and the final architecture of rifted conjugate passive margins is still poorly understood. Here we present lithospheric?scale thermo?mechanical numerical models that self?consistently create extensional and contractional tectonic inheritance, where prior extension and contraction are systematically varied. Our results show that (1) initial reactivation occurs along the former lithospheric suture zones; (2) upper crustal thick?skinned basement thrusts are partially or fully reactivated depending on the amount of prior contraction and size of the orogen; (3) with a small amount of contraction, thick?skinned thrusts are efficiently reactivated in extension and provide the template for rifted margin formation; (4) with larger amounts of contraction, thick?skinned thrusts distal to the lithospheric suture zone do not reactivate in extension; and (5) reactivation of prior contractional shear zones dominates during the early stages of rifting, while during the final stage of margin formation new?formed extensional shear zones dominate. Force balance analysis predicts an inverse relation between midcrustal viscosity and the maximum offset for reactivation of weak upper crustal structures. Force balance also predicts that the degree of weakening or healing of the weak suture and the thermal thinning of the necking area control at which stage suture reactivation is deactivated and extension proceeds by mantle lithosphere thermal necking. Two rifted conjugate margins with orogenic inheritance in the North and South Atlantic are used for comparison.
DS201811-2605
2018
Salminen, J., Hanson, R., Evans, D.A.D., Gong, Z., Larson, T., Walker, O., Gumsley, A., Soderlund, U., Ernst, T.Direct Mesoproterozoic connection of the Congo and Kalahari cratons in proto-Africa: strange attractors across supercontinental cycles.Geology, doi.org/10.1130/G45294.1 4p.Africacraton

Abstract: Mobilistic plate-tectonic interpretation of Precambrian orogens requires that two conjoined crustal blocks may derive from distant portions of the globe. Nonetheless, many proposed Precambrian cratonic juxtapositions are broadly similar to those of younger times (so-called “strange attractors”), raising the specter of bias in their construction. We evaluated the possibility that the Congo and Kalahari cratons (Africa) were joined together prior to their amalgamation along the Damara-Lufilian-Zambezi orogen in Cambrian time by studying diabase dikes of the Huila-Epembe swarm and sills in the southern part of the Congo craton in Angola and in Namibia. We present geologic, U-Pb geochronologic, and paleomagnetic evidence showing that these two cratons were directly juxtaposed at ca. 1.1 Ga, but in a slightly modified relative orientation compared to today. Recurring persistence in cratonic connections, with slight variations from one supercontinent to the next, may signify a style of supercontinental transition similar to the northward motion of Gondwana fragments across the Tethys-Indian oceanic tract, reuniting in Eurasia.
DS201804-0733
2017
Sanislav, I.V., Blenkinsop, T.G., Dirks, P.H.G.M.Archean crustal growth through successive partial melting events in an oceanic plateau like setting in the Tanzanian craton.Terra Nova, pp. 1-10.Africa, Tanzaniacraton - geochronology

Abstract: The detrital zircon population in quartzitic conglomerates from the northern Tanzania Craton yield ages between 2640 Ma and 2790 Ma which includes most of the igneous history from this part of the craton. The igneous evolution is characterised by mafic volcanism with an oceanic plateau?like geochemical signature at ~2800 Ma followed by diorite and tonalite-trondhjemite-granodiorite dominated magmatism between 2790 and 2700 Ma, which transitioned into more evolved high?K magmatism between 2700 and 2620 Ma. The ?Hf values of the detrital zircons range from +2.4 to ?1.4 and change with time from radiogenic Hf pre?2700 Ma (98% positive ?Hf) to unradiogenic Hf post?2700 Ma (41% positive ?Hf). The petrological progression from mafic to felsic crust is reflected in the detrital age distribution and Hf isotopes and is consistent with juvenile mafic crust slowly maturing into more evolved felsic crust through a series of successive partial melting events in an oceanic?plateau?like environment.
DS201802-0262
2018
Santosh, M., Hari, K.R., He, X-F., Han, Y-S., Manu Prasanth, M.P.Oldest lamproites from Peninsular India track the onset of Paleoproterozoic plume induced rifting and the birth of Large Igneous Province.Gondwana Research, Vol. 55, pp. 1-20.Indialamproites

Abstract: Potassic and ultrapotassic magmatism from deep lithospheric sources in intra-cratonic settings can be the signal of subsequent voluminous mafic magmatism and the formation of Large Igneous Provinces (LIPs) triggered by mantle plumes. Here we report for the first time, precise zircon U-Pb age data from a suite of lamproites in the Bastar Craton of central India that mark the onset of Paleoproterozoic rifting and culminating in the formation of extensive mafic dyke swarms as the bar codes of one of the major LIP events during the Precambrian evolution of the Indian shield. The lamproites from the Nuapada field occur as dismembered dykes and are composed of phenocrysts and microphenocrysts of altered olivine together with microphenocrysts of phlogopite and magnetite within a groundmass of chlorite and calcite with accessory rutile, apatite and zircon. The rocks compositionally correspond to olivine phlogopite lamproite and phlogopite lamproite. Geochemical features of the lamproites correlate with their counterparts in Peninsular India and other similar suites elsewhere in the world related to rift settings, and also indicate OIB-like magma source. The associated syenite shows subduction-related features, possibly generated in a post-collisional setting. Magmatic zircon grains with high Th/U ratios in the syenite from the Nuapada lamproite form a coherent group with an upper intercept age of 2473 ± 8 Ma representing the timing of emplacement of the magma. Zircon grains in three lamproite samples yield four distinct age groups at ca. 2.4 Ga, 2.2 Ga, 2.0 Ga and 0.8 Ga. The 2.4 Ga group corresponds to xenocrysts entrained from the syenite whereas the 2.2 Ga group is considered to represent the timing of emplacement of the lamproites. The ca. 2.0 Ga zircon grains correlate with the major thermal imprint associated with mafic magmatism and dyke emplacement in southern Bastar and the adjacent Dharwar Cratons. A few young zircon grains in the syenite and lamproites show a range of early to middle Neoproterozoic ages from 879 to 651 Ma corresponding to younger thermal event(s) as also represented by granitic veins cutting across these rocks and extensive silicification. Zircon Lu-Hf isotope data suggest magma derivation from a refertilized Paleo-Mesoarchean sub-continental lithospheric mantle, or OIB-type sources. The differences in Hf-isotope composition among the zircon grains from different age groups indicate that the mantle sources of the lamproite are heterogeneous at the regional scale. A combination of the features from geochemical and zircon Hf isotope data is consistent with asthenosphere-lithosphere interaction during the lamproite magma evolution. The timing of lamproite emplacement in central India correlates with the global 2.2 Ga record of LIPs. We link the origin of the related mantle plume to the recycling of subducted slabs associated with the prolonged subduction-accretion history prior to the Neoarchean cratonization, as well as the thermal blanket effect of the Earth's oldest supercontinent. Pulsating plumes and continued rifting generated voluminous dyke swarms across the Bastar and Dharwar Cratons, forming part of a major global rifting and LIP event.
DS201802-0263
2018
Sarafian, E., Evans, R.L., Abdelsalam, M.G., Atekwana, E., Elsenbeck, J., Jones, A.G., Chikambwe, E.Imaging Precambrian lithospheric structure in Zambia using electromagnetic methods.Gondwana Research, Vol. 54, pp. 38-49.Africa, Zambiageophysics

Abstract: The Precambrian geology of eastern Zambia and Malawi is highly complex due to multiple episodes of rifting and collision, particularly during the formation of Greater Gondwana as a product of the Neoproterozoic Pan-African Orogeny. The lithospheric structure and extent of known Precambrian tectonic entities of the region are poorly known as there have been to date few detailed geophysical studies to probe them. Herein, we present results from electromagnetic lithospheric imaging across Zambia into southern Malawi using the magnetotelluric method complemented by high-resolution aeromagnetic data of the upper crust in order to explore the extent and geometry of Precambrian structures in the region. We focus particularly on determining the extent of subcontinental lithospheric mantle (SCLM) beneath the Archean-Paleoproterozoic cratonic Bangweulu Block and the Mesoproterozoic-Neoproterozoic Irumide and Southern Irumide Orogenic Belts. We also focus on imaging the boundaries between these tectonic entities, particularly the boundary between the Irumide and Southern Irumide Belts. The thickest and most resistive lithosphere is found beneath the Bangweulu Block, as anticipated for stable cratonic lithosphere. Whereas the lithospheric thickness estimates beneath the Irumide Belt match those determined for other orogenic belts, the Southern Irumide Belt lithosphere is substantially thicker similar to that of the Bangweulu Block to the north. We interpret the thicker lithosphere beneath the Southern Irumide Belt as due to preservation of a cratonic nucleus (the pre-Mesoproterozoic Niassa Craton). A conductive mantle discontinuity is observed between the Irumide and Southern Irumide Belts directly beneath the Mwembeshi Shear Zone. We interpret this discontinuity as modified SCLM relating to a major suture zone. The lithospheric geometries determined from our study reveal tectonic features inferred from surficial studies and provide important details for the tectonothermal history of the region.
DS201801-0055
2018
Sarfian, E., Evans, R.L, Abdelsalam, M.G., Atekwana, E., Elsenbeck, J., Jones, A.G., Chikambwe, E..Imaging Precambrian lithospheric structure in Zambia using electromagnetic methods.Gondwana Research, Vol. 54, pp. 38-49.Africa, Zambiageophysics -em
DS201809-2082
2018
Sarkar, C., Kjarsgaard, B.A., Pearson, D.G., Heaman, L.M., Locock, A.J., Armstrong, J.P.Geochronology, classification and mantle source characteristics of kimberlites and related rocks from the Rae craton, Melville Peninsula, Nunavut, Canada.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0632-5 20p.Canada, Nunavut, Melville Peninsuladeposit - Pelly Bay, Darby, Aviat, Qilalugaq

Abstract: Detailed geochronology along with petrographic, mineralogical and geochemical studies have been conducted on recently found diamond-bearing kimberlitic and related rocks in the Rae Craton at Aviat and Qilalugaq, Melville Peninsula, north-east Canada. Magmatic rocks from the Aviat pipes have geochemical (both bulk rock and isotopic) and mineralogical signatures (e.g., core to rim Al and Ba enrichment in phlogopite) similar to Group I kimberlite. In contrast, Aviat intrusive sheets are similar to ‘micaceous’ Group II kimberlite (orangeite) in their geochemical and mineralogical characteristics (e.g., phlogopite and spinel compositions, highly enriched Sr isotopic signature). Qilalugaq rocks with the least crustal contamination have geochemical and mineralogical signatures [e.g., high SiO2, Al2O3 and H2O; low TiO2 and CO2; less fractionated REE (rare earth elements), presence of primary clinopyroxene, phlogopite and spinel compositions] that are similar to features displayed by olivine lamproites from Argyle, Ellendale and West Greenland. The Naujaat dykes, in the vicinity of Qilalugaq, are highly altered due to extensive silicification and carbonation. However, their bulk rock geochemical signature and phlogopite chemistry are similar to Group I kimberlite. U-Pb perovskite geochronology reveals that Aviat pipes and all rocks from Qilalugaq have an early Cambrian emplacement age (540-530 Ma), with the Aviat sheets being ~30 Ma younger. This volatile-rich potassic ultramafic magmatism probably formed by varying degrees of involvement of asthenospheric and lithospherically derived melts. The spectrum of ages and compositions are similar to equivalent magmatic rocks observed from the nearby north-eastern North America and Western Greenland. The ultimate trigger for this magmatism could be linked to Neoproterozoic continental rifting during the opening of the Iapetus Ocean and breakup of the Rodinia supercontinent.
DS201805-0974
2018
Sasman, F., Deetlefs, B., van der Westhuyzen, P.Application of diamond size frequency distribution and XRT technology at a large diamond producer. The Journal of the Southern African Institute of Mining and Metallurgy, Vol. 118, Jan. pp. 1-6.Africa, South Africadiamond size frequency

Abstract: Diamond size frequency distribution (SFD) curves, combined with the associated dollar per carat per size class, play an important role in the diamond industry. Value per size class is unique for each deposit and typically varies from less than a dollar per carat to several thousands of dollars per carat for special stones. Recovery of large stone therefore contributes significantly to the bottom line of a large diamond producer. While the design of the process plant should prevent damage and possible breakage of large stones, it should also ensure adequate liberation of the finer diamonds. Innovative solutions are required to protect and recover type I and II diamonds if prominent within the resource. X-ray transmission (XRT) sorting presents the opportunity to develop flow sheet designs that incorporate a balance between exploitation of the resource and process efficiency, as well as practical capital and operating costs. This paper serves to illustrate the role and application of SFD curves in determining optimum cut-off and re-crush sizes within the flow sheet of a large diamond producer. A thorough understanding of the unique technical and economic aspects of a deposit provides the basis from where new and innovative technologies can be proposed, allowing mining companies to maintain and improve profit margins. It highlights the results of various plant trials and newly commissioned XRT sorters for larger size fractions. It also provides recommendations for future applications of XRT machines in the diamond process flow sheet.
DS201808-1786
2018
Satyanarayanan, M., Subba Rao, D.V., Renjith, M.L., Singh, S.P., Babu, E.V.S.S.K., Korakoppa, M.M.Petrogenesis of carbonatitic lamproitic dykes from Sidhi gneissic complex, central India.Geoscience Frontiers, Vol. 9, 2, pp. 531-547.Indialamproite

Abstract: Petrographic, mineral chemical and whole-rock geochemical characteristics of two newly discovered lamproitic dykes (Dyke 1 and Dyke 2) from the Sidhi Gneissic Complex (SGC), Central India are presented here. Both these dykes have almost similar sequence of mineral-textural patterns indicative of: (1) an early cumulate forming event in a deeper magma chamber where megacrystic/large size phenocrysts of phlogopites have crystallized along with subordinate amount of olivine and clinopyroxene; (2) crystallization at shallow crustal levels promoted fine-grained phlogopite, K-feldspar, calcite and Fe-Ti oxides in the groundmass; (3) dyke emplacement related quench texture (plumose K-feldspar, acicular phlogopites) and finally (4) post emplacement autometasomatism by hydrothermal fluids which percolated as micro-veins and altered the mafic phases. Phlogopite phenocrysts often display resorption textures together with growth zoning indicating that during their crystallization equilibrium at the crystal-melt interface fluctuated multiple times probably due to incremental addition or chaotic dynamic self mixing of the lamproitic magma. Carbonate aggregates as late stage melt segregation are common in both these dykes, however their micro-xenolithic forms suggest that assimilation with a plutonic carbonatite body also played a key role in enhancing the carbonatitic nature of these dykes. Geochemically both dykes are ultrapotassic (K2O/Na2O: 3.0 -9.4) with low CaO, Al2O3 and Na2O content and high SiO2 (53.3 -55.6 wt.%) and K2O/Al2O3 ratio (0.51 -0.89) characterizing them as high-silica lamproites. Inspite of these similarities, many other features indicate that both these dykes have evolved independently from two distinct magmas. In dyke 1, phlogopite composition has evolved towards the minette trend (Al-enrichment) from a differentiated parental magma having low MgO, Ni and Cr content; whereas in dyke 2, phlogopite composition shows an evolutionary affinity towards the lamproite trend (Al-depletion) and crystallized from a more primitive magma having high MgO, Ni and Cr content. Whole-rock trace-elements signatures like enriched LREE, LILE, negative Nb-Ta and positive Pb anomalies; high Rb/Sr, Th/La, Ba/Nb, and low Ba/Rb, Sm/La, Nb/U ratios in both dykes indicate that their parental magmas were sourced from a subduction modified garnet facies mantle containing phlogopite. From various evidences it is proposed that the petrogenesis of studied lamproitic dykes stand out to be an example for the lamproite magma which attained a carbonatitic character and undergone diverse chemical evolution in response to parental melt composition, storage at deep crustal level and autometasomatism.
DS201811-2606
2015
Scarratt, K.Beautifying emeralds…. The perennial debate.InColor, December pp. 50-55.Globalemeralds
DS201806-1247
2018
Schmidt, M.W., Weidendorfer, D.Carbonatites in oceanic hotspots.Geology, Vol. 46, 5, pp. 435-438.Mantlecarbonatite

Abstract: An analysis of the global array of ocean island volcanics shows that carbonatites only form in those hotspots that have the lowest Si- and highest alkali-contents among their primitive melts, such as the Cape Verde and Canary (Islands) hotspots. Fractionated melts from these two hotspots reach, at any given SiO2, several wt% higher total alkali contents than for ocean islands without carbonatites. This is because their strongly silica-undersaturated primitive melts fractionate at low SiO2 to high alkali contents, driving the evolving melt into the silicate-carbonatite miscibility gap. Instead, moderately alkaline magmas fractionate toward the alkali-feldspar thermal divide and do not reach liquid immiscibility. Low SiO2 and high alkalis are the combined result of comparatively deep and low-degree mantle melting, the latter is corroborated by the highest high-field-strength and rare earth element concentrations in the Cape Verde and Canary primitive melts. CO2 in the source facilitates low melt SiO2, but enrichment in CO2 relative to other hotspots is not required. The oceanic hotspots with carbonatites are among those with the thickest thermal lithosphere supporting a deep origin of their asthenospheric parent melts, an argument that could be expanded to continental hotspot settings.
DS201803-0473
2002
Schnitz, M., Chalbaud, D., Castillo, J., Izarra, C.The crystal structure of the Guyana shield, Venezuela, from seismic reflection and gravity data.Tectonophysics, Vol. 345, pp. 103-118.South America, VenezuelaGuyana shield

Abstract: We present results from a seismic refraction experiment on the northern margin of the Guayana Shield performed during June 1998, along nine profiles of up to 320 km length, using the daily blasts of the Cerro Bol?´var mines as energy source, as well as from gravimetric measurements. Clear Moho arrivals can be observed on the main E-W profile on the shield, whereas the profiles entering the Oriental Basin to the north are more noisy. The crustal thickness of the shield is unusually high with up to 46 km on the Archean segment in the west and 43 km on the Proterozoic segment in the east. A 20 km thick upper crust with P-wave velocities between 6.0 and 6.3 km/s can be separated from a lower crust with velocities ranging from 6.5 to 7.2 km/s. A lower crustal low velocity zone with a velocity reduction to 6.3 km/s is observed between 25 and 25 km depth. The average crustal velocity is 6.5 km/s. The changes in the Bouguer Anomaly, positive (30 mGal) in the west and negative ( 20 mGal) in the east, cannot be explained by the observed seismic crustal features alone. Lateral variations in the crust or in the upper mantle must be responsible for these observations.
DS201809-2083
2018
Schulze, K., Marquardt, H., Kawazoe, T., Boallaran, T.B., McCammon, C., Koch-Muller, M., Kurnosov, A., Marquardt, K.Seismically invisable water in Earth's transition zone?Earth and Planetary Science Letters, Vol. 498, pp. 9-16.Mantlewater

Abstract: Ringwoodite, the dominant mineral at depths between 520 km and 660 km, can store up to 2-3 wt.% of water in its crystal structure, making the Earth's transition zone a plausible water reservoir that plays a central role in Earth's deep water cycle. Experiments show that hydration of ringwoodite significantly reduces elastic wave velocities at room pressure, but the effect of pressure remains poorly constrained. Here, a novel experimental setup enables a direct quantification of the effect of hydration on ringwoodite single-crystal elasticity and density at pressures of the Earth's transition zone and high temperatures. Our data show that the hydration-induced reduction of seismic velocities almost vanishes at conditions of the transition zone. Seismic data thus agree with a wide range of water contents in the transition zone.
DS201801-0056
2017
Schulzki, J., Viladkar, S.G., Schleicher, H.Carbonatite breccia: a neglected unit in Amba Dongar distreme, Gujarat, India.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 38.Indiadeposit - Amba Dongar

Abstract: Carbonatite breccia forms a major unit in the carbonatite-alkalic diatreme of Amba Dongar. In addition to the innermost part of the ring structure, it also forms small and large plugs outside ring structure in form of discontinuous ring around sövite. It is mainly composed of rounded to sub-angular fragments of basement metamorphics, Bagh sandstones, pre-carbonatite basalt, nephelinite and sövite set in the carbonatitic matrix. Besides rock fragments it also shows presence xenocrystal minerals. Carbonatite breccia is later invaded by sövite, alvikite and ankeritic carbonatite. Thorite, pyrochlore, barite, apatite, fluorite and small amount of REE-minerals were introduced in carbonatite breccia by these later intrusives. Zircon, however seems have been caught up from metamorphic gneisses. Microprobe analyses of all these minerals are given here. In places, carbonatite breccia has been silicified by invading hydrothermal solutions rich in fluorite and silica.
DS201811-2607
2015
Schwarz, D.The geographic origin. Determination of emeralds.InColor, December pp. 98-103.Globalemeralds
DS201801-0057
2017
Scotese, C.Plate tectonics during last 1.5 billion years: an atlas of ancient oceans and continents.academia.edu blog, #35369866 101p. PdfGlobalplate tectonics - map
DS201808-1787
2018
SEG NewsletterSonic drilling ( brief mention of useage in Siberia on alluvial diamonds.SEG Newsletter, No. 114, July, p. 10-11.Russia, Siberiaalluvials
DS201806-1248
2018
Seitz, H-M., Brey, G.P., Harris, J.W., Durali-Muller, S., Ludwig, T., Hofer, H.E.Ferropericlase inclusions in ultradeep diamonds from Sao Luiz ( Brazil): high Li abundances and diverse Li-isotope and trace element compositions suggest an origin from a subduction melange.Mineralogy and Petrology, in press available, 10p.South America, Brazil, Juinadeposit - Sao Luiz

Abstract: The most remarkable feature of the inclusion suite in ultradeep alluvial and kimberlitic diamonds from Sao Luiz (Juina area in Brazil) is the enormous range in Mg# [100xMg/(Mg?+?Fe)] of the ferropericlases (fper). The Mg-richer ferropericlases are from the boundary to the lower mantle or from the lower mantle itself when they coexist with ringwoodite or Mg- perovskite (bridgmanite). This, however, is not an explanation for the more Fe-rich members and a lowermost mantle or a “D” layer origin has been proposed for them. Such a suggested ultra-deep origin separates the Fe-rich fper-bearing diamonds from the rest of the Sao Luiz ultradeep diamond inclusion suite, which also contains Ca-rich phases. These are now thought to have an origin in the uppermost lower mantle and in the transition zone and to belong either to a peridotitic or mafic (subducted oceanic crust) protolith lithology. We analysed a new set of more Fe-rich ferropericlase inclusions from 10 Sao Luiz ultradeep alluvial diamonds for their Li isotope composition by solution MC-ICP-MS (multi collector inductively coupled plasma mass spectrometry), their major and minor elements by EPMA (electron probe micro-analyser) and their Li-contents by SIMS (secondary ion mass spectrometry), with the aim to understand the origin of the ferropericlase protoliths. Our new data confirm the wide range of ferropericlase Mg# that were reported before and augment the known lack of correlation between major and minor elements. Four pooled ferropericlase inclusions from four diamonds provided sufficient material to determine for the first time their Li isotope composition, which ranges from ?7Li?+?9.6 ‰ to ?3.9 ‰. This wide Li isotopic range encompasses that of serpentinized ocean floor peridotites including rodingites and ophicarbonates, fresh and altered MORB (mid ocean ridge basalt), seafloor sediments and of eclogites. This large range in Li isotopic composition, up to 5 times higher than ‘primitive upper mantle’ Li-abundances, and an extremely large and incoherent range in Mg# and Cr, Ni, Mn, Na contents in the ferropericlase inclusions suggests that their protoliths were members of the above lithologies. This mélange of altered rocks originally contained a variety of carbonates (calcite, magnesite, dolomite, siderite) and brucite as the secondary products in veins and as patches and Ca-rich members like rodingites and ophicarbonates. Dehydration and redox reactions during or after deep subduction into the transition zone and the upper parts of the lower mantle led to the formation of diamond and ferropericlase inclusions with variable compositions and a predominance of the Ca-rich, high-pressure silicate inclusions. We suggest that the latter originated from peridotites, mafic rocks and sedimentary rocks as redox products between calcite and SiO2.
DS201809-2084
2017
Seller, M.H.Lithosphere thickness determinations and kimberlite diamond potential.Geological Survey of Canada, Open File 8345 pp. 35-40.Canada, Northwest Territoriesgeophysics - seismic
DS201807-1524
2018
Semple, A.G., Lenardic, A.Plug flow in the Earth's asthenosphere.Earth and Planetary Science Letters, Vol. 496, pp. 29-36.Mantlerheology, tectonics

Abstract: Recent seismic observations, focused on mantle flow below the Pacific plate, indicate the presence of two shear layers in the Earth's asthenosphere. This is difficult to explain under the classic assumption of asthenosphere flow driven by plate shear from above. We present numerical mantle convection experiments that show how a power law rheology, together with dynamic pressure gradients, can generate an asthenosphere flow profile with a near constant velocity central region bounded above and below by concentrated shear layers (a configuration referred to as plug flow). The experiments show that as the power law dependence of asthenosphere viscosity is increased from 1 to 3, maximum asthenosphere velocities can surpass lithosphere velocity. The wavelength of mantle convection increases and asthenosphere flow transitions from a linear profile (Couette flow) to a plug flow configuration. Experiments in a 3D spherical domain also show a rotation of velocity vectors from the lithosphere to the asthenosphere, consistent with seismic observations. Global mantle flow remains of whole mantle convection type with plate and asthenosphere flow away from a mid-ocean ridge balanced by broader return flow in the lower mantle. Our results are in line with theoretical scalings that mapped the conditions under which asthenosphere flow can provide an added plate driving force as opposed to the more classic assumption that asthenosphere flow is associated with a plate resisting force.
DS201803-0474
2017
Sepehri, M., Apel, D.B., Hall, R.A.Prediction of mining induced surface subsidence and ground movements at a Canadian diamond mine using electroplastic finite element model. International Journal of Rock Mechanics and Mining Sciences, Vol. 100, pp. 73-82.Canada, Northwest Territoriesdeposit - Diavik
DS201801-0058
2017
Sesha Sai, V.V.Petrographic studies in understanding carbonatites.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 48-49.Indiacarbonatites

Abstract: Carbonatites are mantle derived carbonate rich rocks of igneous origin. Carbonatites are often spatially associated with alkaline rocks and typically confined to continental rift related tectonic setting. Mineralogically, carbonatites are predominantly composed of primary carbonate minerals (calcite, dolomite), while, oxides, hydroxides, silicates, phosphate and sulphide minerals are also found as associated minerals in variable amounts. Although geochemical and isotope geology studies significantly contribute to understand the genetic aspects of these rare REE rich rocks of economic significance; petrographic studies with the aid of polarizing microscope play a critical role in (i) identification of the constituent minerals (ii) ascertain the relative abundance of various minerals and (iii) to recognise the textures. All these three aspects along with geochemical, isotope and mineral inclusion studies are extremely important to understand carbonatite petrogenesis. As per the IUGS classification scheme, the primary carbonate minerals [calcite CaCO3, dolomite (Ca, Mg) CO3, ankerite Ca (Fe, Mg, Mn) (CO3)2] constitute > 50 % by mode in carbonatites, while the SiO2 is < 20 % (Le Maitre, 2002). Though the primary mineralogy in carbonatite is variable, petrographic studies do help in establishing the presence of REE rich phases like apatite and pyrochlore; presence of mineral phases like phlogopite, perovskite, olivine, fluorite (transmitted light) and opaque oxides; eg. magnetite (reflected light) in carbonate rich rock with crystalline texture; as an initial stage for identification of a carbonatite. Based on the chemical composition, the carbonatites are classified as calciocarbonatites, magnesiocarbonatites and ferrocarbonatites (Woolley, 1982); the calciocarbonatites are further classified as sovite and alvikite (Le Bas, 1999). Based on the mineralogical-genetic criteria, carbonatites are divided into primary carbonatites and carbothermal residua (Mitchell, 2007). Petrographic studies help to initially identify the chemically distinct calciocarbonatites; sovite or alvikite. Sovite is texturally coarse grained, while alvikite is relatively fine grained. The coarse grained nature of the calciocarbonatites (average grain size of the carbonate minerals ranging from 1 to 5 mm) coupled with their equigranular nature makes them texturally distinct. Calcite and dolomite can be distinguished with the aid of staining techniques (Dickson, 1965). Staining technique will be useful for rapid estimation of the modal contents of the carbonate phases (calcite, ferroan calcite, dolomite,) in carbonatites. Though less abundant, the ferrocarbonatites are charecterised by the presence of clearly relatively large magnetite grains. Often the porphyritic appearance in the ferrocarbonatites is due to the presence of aggregates of celadonite and phlogopite leaving olivine and pyroxene as relict phases. Late stage magmatic-hydrothermal fluids can play a role in alteration of the textural and mineralogy in carbonatites (Duraiswami and Shaikh, 2014). Study the primary magmatic inclusions in silicates phases in carbonatites with the aid of optical and scanning electron microscopy provide critical information to understand the petrogenetic aspects of carbonatites (e.g. Nisbett and Kelly, 1977). Petrographic studies also contribute in identification of textures indicating crystal-melt interaction in carbonatites (Sesha Sai and Sengupta, 2017). Field and laboratory studies leading to chronological understanding of the geotectonic events in a given area, along with petrographic analyses with detailed mineralogical and textural descriptions, not only contribute to understand the fundamental aspects of carbonatites, but also form a solid substratum to build an acceptable petrogenetic model, by synthesising the information obtained by the geochemical, isotope geology and mineral inclusion studies.
DS201805-0975
2018
Shaikh, A.M., Kumar, S.P., Patel, S.C.,Thakur, S.S., Ravi, S., Behera, D.The P3 kimberlite and P4 lamproite, Wajrakur kimberlite field, India: mineralogy, and major and minor element compositions of olivines as records of their phenocrystic vs xenocrystic origin.Mineralogy and Petrology, 16p pdfIndiadeposit - Wajrakarur
DS201812-2878
2018
Shaikh, A.M., Patel, S.C., Bussweiler, Y., Kumar, S.P.K., Tappe, S., Mainkar, D. Ravi, S.Olivine trace element compositions in diamondiferous lamproites from India: proxies for magma origins and the nature of the lithosphere mantle beneath the Bastar and Dharwar cratons. CC2 and P13 Wajrakarur, Kodomali, Behradih Mainpur Lithos, doi:10.1016/j. lithos.2018.11.026 35p.Indiadeposit - Wajrakarur, Mainpur

Abstract: The ~1100 Ma CC2 and P13 lamproite dykes in the Wajrakarur Kimberlite Field (WKF), Eastern Dharwar Craton, and ~65 Ma Kodomali and Behradih lamproite diatremes in the Mainpur Kimberlite Field (MKF), Bastar Craton share a similar mineralogy, although the proportions of individual mineral phases vary significantly. The lamproites contain phenocrysts, macrocrysts and microcrysts of olivine set in a groundmass dominated by diopside and phlogopite with a subordinate amount of spinel, perovskite, apatite and serpentine along with rare barite. K-richterite occurs as inclusion in olivine phenocrysts in Kodomali, while it is a late groundmass phase in Behradih and CC2. Mineralogically, the studied intrusions are classified as olivine lamproites. Based on microtextures and compositions, three distinct populations of olivine are recognised. The first population comprises Mg-rich olivine macrocrysts (Fo89-93), which are interpreted to be xenocrysts derived from disaggregated mantle peridotites. The second population includes Fe-rich olivine macrocrysts (Fo82-89), which are suggested to be the product of metasomatism of mantle wall-rock by precursor lamproite melts. The third population comprises phenocrysts and overgrowth rims (Fo83-92), which are clearly of magmatic origin. The Mn and Al systematics of Mg-rich olivine xenocrysts indicate an origin from diverse mantle lithologies including garnet peridotite, garnet-spinel peridotite and spinel peridotite beneath the WKF, and mostly from garnet peridotite beneath the MKF. Modelling of temperatures calculated using the Al-in-olivine thermometer for olivine xenocrysts indicates a hotter palaeogeotherm of the SCLM beneath the WKF (between 41 and 43 mW/m2) at ~1100 Ma than beneath the MKF (between 38 and 41 mW/m2) at ~65 Ma. Further, a higher degree of metasomatism of the SCLM by precursor lamproite melts has occurred beneath the WKF compared to the MKF based on the extent of CaTi enrichment in Fe-rich olivine macrocrysts. For different lamproite intrusions within a given volcanic field, lower Fo olivine overgrowth rims are correlated with higher phlogopite plus oxide mineral abundances. A comparison of olivine overgrowth rims from the two fields shows that WKF olivines with lower Fo content than MKF olivines are associated with increased XMg in spinel and phlogopite and vice versa. Melt modelling indicates relatively Fe-rich parental melt for WKF intrusions compared to MKF intrusions. The Ni/Mg and Mn/Fe systematics of magmatic olivines indicate derivation of the lamproite melts from mantle source rocks with a higher proportion of phlogopite and/or lower proportion of orthopyroxene for the WKF on the Eastern Dharwar Craton compared to those for the MKF on the Bastar Craton. This study highlights how olivine cores provide important insights into the composition and thermal state of cratonic mantle lithosphere as sampled by lamproites, including clues to elusive precursor metasomatic events. Variable compositions of olivine rims testify to the complex interplay of parental magma composition and localised crystallisation conditions including oxygen fugacity variations, co-crystallisation of groundmass minerals, and assimilation of entrained material.
DS201805-0976
2018
Sharma, A., Kunar, D., Sahoo, S., Pandit, D., Chalapathi Rao, N.V.Chrome diopside megacryst bearing lamprophyre from the Late Cretaceous Mundwara alkaline complex, NW India: petrological and geodynamic implications.Journal of the Geological Society of India, Vol. 91, pp. 395-399.IndiaAlkaline - Mundwara

Abstract: The occurrence of a rare mantle-derived chrome-diopside megacryst (~8 mm), containing inclusions of olivine, in a lamprophyre dyke from the late Cretaceous polychronous (~100 - 68 Ma) Mundwara alkaline complex of NW India is reported. The olivine inclusions are forsteritic (Fo: 85.23) in composition, and their NiO (0.09 wt%) and CaO (0.13 wt%) contents imply derivation from a peridotitic mantle source. The composition of the chrome diopside (Cr2O3: 0.93 wt ) (Wo45.27 En48.47 Fs5.07 and Ac1.18) megacryst is comparable to that occurring in the garnet peridotite xenoliths found in diamondiferous kimberlites from Archaean cratons. Single pyroxene thermobarometry revealed that this chrome diopside megacryst was derived from a depth range of ~100 km, which is relatively much deeper than that of the chrome-diopside megacrysts (~40-50 km) reported in spinellherzolite xenoliths from the alkali basalts of Deccan age (ca. 66- 67 Ma) from the Kutch, NW India. This study highlights that pre- Deccan lithosphere, below the Mundwara alkaline complex, was at least ~100 km thick and, likely, similar in composition to that of the cratonic lithosphere.
DS201809-2085
2018
Sharma, S.K., Chen, B., Gao, J., Lai, X.Micro-Raman investigations of diamond genesis during slab-mantle interaction.Goldschmidt Conference, 1p. AbstractMantlediamond genesis

Abstract: Magnesite is proposed to be a major oxidized carbon storage phase in the mantle due to its wide P-T range of stability [1-2]. The presence of magnesite in the Earth's interior will depend on the redox state of the Earth's interior. Large part of the deep mantel is considered to be significantly reduced with considerable amount of FeO dispersed in rocks [3]. During slab-mantle interaction, subducted carbonates in the slab will undergo redox reactions with metallic Fe. However, the mechanism of this interaction is not well understood. In order to understand diamond genesis during the slabmantle interactions, we have conducted high-pressure and high-temperature experiments in a 2000-ton multi-anvil highpressure press on samples containing MgCO3 and iron foils (50 ?m thick) in BN capsules. The samples under pressures from 10 to 16 GPa were heated to 1200-1700 K. The samples were quenched under pressure and the quenched samples were polished and then analyzed with multi-wavelength micro-Raman spectrometers using 785, 514.5 and 532 nm laser excitations. Micro-Raman investigations show that the iron foils reduce MgCO3 to various sp2 carbon phases, mainly graphite, followed by the transformation to diamond upon long-duration heating. The transformation to diamond is driven by the temperature. For example, in the Run number PL066 with staring material containing magnesite and two Fe foils heated to 1400 K at 10 GPa for 24 hrs, and quenched, the run products were [Mg,Fe]O, and diamond and graphite. The sample PL044 with staring material containing magnesite and three Fe foils heated to 1600 K at 14 GPa for 12 hrs, the run products were larger size (~10 ?m) diamonds, iron carbide and small amount of graphite. Our results indicate that in slow subduction (T~1500 K) all carbonates will be converted in diamond and iron carbide. Under rapid subduction of the slab, the carbonate will survive and be carried to greater depth. The inclusions of [Mg,Fe]O in diamonds, however, do not necessarily indicate that this phase is of lower mantle origin.
DS201804-0734
2018
Sharygin, I.S., Shatskiy, A., Litasov, K.D., Golovin, A.V., Ohtani, E., Pokhilenko, N.P.Interaction of peridotite with Ca-rich carbonatite melt at 3.1 and 6.5 Gpa: implications for merwinite formation in upper mantle, and for metasomatic origin of sublithospheric diamonds with Ca rich suite of inclusions.Contribution to Mineralogy and Petrology, Vol. 173, 22p.Mantlecarbonatite

Abstract: We performed an experimental study, designed to reproduce the formation of an unusual merwinite?+?olivine-bearing mantle assemblage recently described as a part of a Ca-rich suite of inclusions in sublithospheric diamonds, through the interaction of peridotite with an alkali-rich Ca-carbonatite melt, derived from deeply subducted oceanic crust. In the first set of experiments, we studied the reaction between powdered Mg-silicates, olivine and orthopyroxene, and a model Ca-carbonate melt (molar Na:K:Ca?=?1:1:2), in a homogeneous mixture, at 3.1 and 6.5 GPa. In these equilibration experiments, we observed the formation of a merwinite?+?olivine-bearing assemblage at 3.1 GPa and 1200 °C and at 6.5 GPa and 1300-1400 °C. The melts coexisting with this assemblage have a low Si and high Ca content (Ca#?=?molar 100?×?Ca/(Ca?+?Mg)?>?0.57). In the second set of experiments, we investigated reaction rims produced by interaction of the same Ca-carbonate melt (molar Na:K:Ca?=?1:1:2) with Mg-silicate, olivine and orthopyroxene, single crystals at 3.1 GPa and 1300 °C and at 6.5 GPa and 1400 °C. The interaction of the Ca-carbonate melt with olivine leads to merwinite formation through the expected reaction: 2Mg2SiO4 (olivine)?+?6CaCO3 (liquid)?=?Ca3MgSi2O8 (merwinite)?+?3CaMg(CO3)2 (liquid). Thus, our experiments confirm the idea that merwinite in the upper mantle may originate via interaction of peridotite with Ca-rich carbonatite melt, and that diamonds hosting merwinite may have a metasomatic origin. It is remarkable that the interaction of the Ca-carbonate melt with orthopyroxene crystals does not produce merwinite both at 3.1 and 6.5 GPa. This indicates that olivine grain boundaries are preferable for merwinite formation in the upper mantle.
DS201801-0059
2017
Sharygin, V.V., Doroshkevich, A.G.Mineralogy of secondary olivine hosted inclusions in calcite carbonatiites of the Belaya Zima alkaline complex, eastern Sayan Russia: evidence for late magmatic Na-Ca-rich carbonate composition.Journal of the Geological Society of India, Vol. 90, 5, pp. 524-530.Russiacarbonatite

Abstract: Secondary multiphase inclusions were studied in olivine from olivine-pyrochlore varieties of calcite carbonatites of the Belaya Zima alkaline complex, Eastern Sayan, Siberia, Russia. The inclusions form trails cross-cutting the host olivine. Their composition varies from carbonate to silicate-carbonate species. Multiphase silicate-carbonate inclusions contain Na-Ca-carbonates (shortite, nyerereite), Na-Mg-carbonates (northupite, eitelite, bradleyite), common carbonates (calcite, dolomite), Ba-Sr-rich carbonates (olekminskite, burbankite, strontianite), tetraferriphlogopite, magnetite, humite-clinohumite and other mineral phases. Na-Ca-carbonates, tetraferriphlogopite, humiteclinohumite and magnetite are omnipresent and dominant phases within the inclusions. The phase composition of secondary olivinehosted inclusions seems to reflect evolutionary features for the Belaya Zima carbonatites at their late stages of formation. During crystallization calciocarbonatite melt gradually evolved toward enrichment in alkalis (mainly, in sodium) and volatile components (Cl, F and H2O).
DS201801-0060
2018
Shatsky, V.S., Malkovets, V.G., Belousova, E.A., Tretiakova, I.G., Griffin, W.L., Ragozin, A.L., Wang, Q., Gibsher, A.A., O'Reilly, S.Y.Multi-stage modification of Paleoarchean crust beneath the Anabar tectonic province ( Siberian craton).Precambrian Research, Vol. 305, pp. 125-144.Russiacraton - Siberian

Abstract: According to present views, the crustal terranes of the Anabar province of the Siberian craton were initially independent blocks, separated from the convecting mantle at 3.1 (Daldyn terrane), 2.9 (Magan terrane) and 2.5?Ga (Markha terrane) (Rosen, 2003, 2004; Rosen et al., 1994, 2005, 2009). Previous studies of zircons in a suite of crustal xenoliths from kimberlite pipes of the Markha terrane concluded that the evolution of the crust of the Markha terrane is very similar to that of the Daldyn terrane. To test this conclusion we present results of U-Pb and Hf-isotope studies on zircons in crustal xenoliths from the Zapolyarnaya kimberlite pipe (Upper Muna kimberlite field), located within the Daldyn terrane, and the Botuobinskaya pipe (Nakyn kimberlite field) in the center of the Markha terrane. The data on xenoliths from the Botuobinskaya kimberlite pipe record tectonothermal events at 2.94, 2.8, 2.7 and 2?Ga. The event at 2?Ga caused Pb loss in zircons from a mafic granulite. U-Pb dating of zircons from the Zapolyarnaya pipe gives an age of 2.7?Ga. All zircons from the studied crustal xenoliths have Archean Hf model ages ranging from 3.65 to 3.11?Ga. This relatively narrow range suggests that reworking of the ancient crust beneath the Nakyn and Upper Muna kimberlite fields was minor, compared with the Daldyn and Alakit-Markha fields (Shatsky et al., 2016). This study, when combined with dating of detrital zircons, implies that tectonic-thermal events at 2.9-2.85, 2.75-2.7 and 2.0-1.95?Ga occurred everywhere on the Anabar tectonic province, and could reflect the upwelling of superplumes at 2.9, 2.7 and 2?Ga. The presence of the same tectonic-thermal events in the Daldyn and Markha terranes (Rosen et al., 2006a,b) supports the conclusion that the identification of the Markha terrane as a separate unit is not valid.
DS201808-1788
2018
Shatsky, V.S., Malkovets, V.G., Belousova, E.A., Tretiakova, I.G., Griffin, W.L., Ragozin, A.L., Wang, Q., Gibsher, A.A., O'Reilly, S.Y.Multi stage modification of Paleoarchean crust beneath the Anabar tectonic provnce ( Siberian craton).Precambrian Research, Vol. 305, pp. 125-144.Russiatectonics

Abstract: According to present views, the crustal terranes of the Anabar province of the Siberian craton were initially independent blocks, separated from the convecting mantle at 3.1 (Daldyn terrane), 2.9 (Magan terrane) and 2.5?Ga (Markha terrane) (Rosen, 2003, 2004; Rosen et al., 1994, 2005, 2009). Previous studies of zircons in a suite of crustal xenoliths from kimberlite pipes of the Markha terrane concluded that the evolution of the crust of the Markha terrane is very similar to that of the Daldyn terrane. To test this conclusion we present results of U-Pb and Hf-isotope studies on zircons in crustal xenoliths from the Zapolyarnaya kimberlite pipe (Upper Muna kimberlite field), located within the Daldyn terrane, and the Botuobinskaya pipe (Nakyn kimberlite field) in the center of the Markha terrane. The data on xenoliths from the Botuobinskaya kimberlite pipe record tectonothermal events at 2.94, 2.8, 2.7 and 2?Ga. The event at 2?Ga caused Pb loss in zircons from a mafic granulite. U-Pb dating of zircons from the Zapolyarnaya pipe gives an age of 2.7?Ga. All zircons from the studied crustal xenoliths have Archean Hf model ages ranging from 3.65 to 3.11?Ga. This relatively narrow range suggests that reworking of the ancient crust beneath the Nakyn and Upper Muna kimberlite fields was minor, compared with the Daldyn and Alakit-Markha fields (Shatsky et al., 2016). This study, when combined with dating of detrital zircons, implies that tectonic-thermal events at 2.9 -2.85, 2.75 -2.7 and 2.0 -1.95?Ga occurred everywhere on the Anabar tectonic province, and could reflect the upwelling of superplumes at 2.9, 2.7 and 2?Ga. The presence of the same tectonic-thermal events in the Daldyn and Markha terranes (Rosen et al., 2006a,b) supports the conclusion that the identification of the Markha terrane as a separate unit is not valid.
DS201802-0264
2018
Shavers, E.J., Ghulam, A., Encaracion, J.Surface alteration of a melilitite clan carbonatite and the potential for remote carbonatite detection.Ore Geology Reviews, Vol. 92, pp. 19-28.United States, Missourideposit - Avon

Abstract: The varied lithologic facies and mineralogy resulting from emplacement of syngenetic alkaline, ultramafic and carbonatite (AUC) intrusions are made more diverse by variable weathering and alteration. Ultramafic-carbonatite intrusive complexes are a source for many valuable minerals including diamonds and rare earth element minerals. The intrusive bodies are often difficult to detect in the field due to their paucity, weathering, vegetation, and, in some instances, similarity to country rock, especially in the case of carbonatites among sedimentary carbonates. Remote spectroscopic detection is used extensively for geologic mapping yet has not been applied to differentiating sedimentary and igneous carbonate weathering profiles. Here we document the alteration mineralogy of a newly authenticated melilitite-clan carbonatite occurrence in the Avon Volcanic District in southeast Missouri, USA. The presence of lizardite, vermiculite, phlogopite, and andradite in the weathered crust of calcic and dolomitic carbonatites differentiate them from sedimentary dolomites. We apply field and laboratory spectral measurements to determine the feasibility of humid region AUC remote sensing and classification. Automated humid region detection and classification of carbonatites among sedimentary carbonates is shown to be possible using ratios of absorption features in the 2000-2400?nm range as well as features centered near 680, 900, and 1100?nm due transition metal charge transfer and crystal field splitting in garnet, sheet-silicates, and spinel.
DS201801-0061
2018
Shavers, E.J., Ghulam, A., Encarnacion, J.Surface alteration of a melilitite clan carbonatite and the potential for remote carbonatite detection.Ore Geology Reviews, Vol. 92, pp. 19-28.United States, Missourideposit - Avon

Abstract: The varied lithologic facies and mineralogy resulting from emplacement of syngenetic alkaline, ultramafic and carbonatite (AUC) intrusions are made more diverse by variable weathering and alteration. Ultramafic-carbonatite intrusive complexes are a source for many valuable minerals including diamonds and rare earth element minerals. The intrusive bodies are often difficult to detect in the field due to their paucity, weathering, vegetation, and, in some instances, similarity to country rock, especially in the case of carbonatites among sedimentary carbonates. Remote spectroscopic detection is used extensively for geologic mapping yet has not been applied to differentiating sedimentary and igneous carbonate weathering profiles. Here we document the alteration mineralogy of a newly authenticated melilitite-clan carbonatite occurrence in the Avon Volcanic District in southeast Missouri, USA. The presence of lizardite, vermiculite, phlogopite, and andradite in the weathered crust of calcic and dolomitic carbonatites differentiate them from sedimentary dolomites. We apply field and laboratory spectral measurements to determine the feasibility of humid region AUC remote sensing and classification. Automated humid region detection and classification of carbonatites among sedimentary carbonates is shown to be possible using ratios of absorption features in the 2000-2400?nm range as well as features centered near 680, 900, and 1100?nm due transition metal charge transfer and crystal field splitting in garnet, sheet-silicates, and spinel.
DS201806-1249
2018
Shchukina, E.V., Shchukin, V.S.Diamond potential of the northern East European platform. KIMSMinerals *** in ENG, Vol. 8, 17p. Pdf ***ENGRussia, Arkangelskgeochemistry, exploration

Abstract: In this study, we assess the diamond exploration potential of the northern East European Platform based on aeromagnetic survey results and the morphologic and geochemical analysis of 1513 grains of kimberlite indicator minerals (KIMs), such as purple pyrope garnet, olivine, and Cr-diopside. These minerals were recovered from samples collected from modern river and stream sediments in four areas located in the north-eastern (within the Arkhangelsk Diamondiferous Province) and south-western (hundreds of kilometers outside of the Arkhangelsk Diamondiferous Province) parts of the Arkhangelsk region in the European part of Russia. All the studied areas are located within ancient cratons, including the Kola, Karelian, and Shenkursk cratons. Based on the major element compositions of the KIMs and thermobarometric calculations, this study confirms that the lithospheric mantle beneath the studied areas is suitable for the formation and preservation of diamonds. The high percentage of KIMs with primary magmatic grain surface morphologies is evidence of the presence of local kimberlite sources within all of the studied areas. The significant amount of diamond-associated KIMs indicates that the potential sources are diamondiferous. Hence, the results suggest that the studied areas can be recommended for further diamond prospecting activity with a high probability of discovering new diamondiferous kimberlites.
DS201809-2086
2018
Shim, S-H., Nisr, C., Chen, H., Leinenweber. K., Chizmeshya, A., Prakapenka, V., Kunz, M., Bechtel, H., Liu, Z.Hydrous silica in the lower mantle. BridgemaniteGoldschmidt Conference, 1p. AbstractMantlewater

Abstract: While mineral phases stable in the mantle transition zone (such as wadsleyite and ringwoodite) can store up to 3 wt% H2O, those in the lower mantle such as bridgmanite and ferropericlase can contain a very small amount (<50 ppm). While such dramatic differences can lead to dehydration/hydration and hydrous melting at 660-km depth in the mantle [1,2] it is uncertain how much water can be transported and stored at these depths. In order to answer this question, we have conducted a series of high pressure experiments in laser-heated diamondanvil cell and multi-anvil press combined with X-ray diffraction, infrared spectroscopy, laser Raman spectroscopy, and secondary ion mass spectrometry. Initially we examined the water storage capacity of dense (Al free) silica polymorphs at high pressure and temperature. We found that water can dramatically reduce the rutile-type to CaCl2-type phase transition from 55 GPa to 25 GPa and stabilize a new "disordered inverse" inverse NiAs-type phase at pressures above 50 GPa, which is not stable in dry SiO2 system. The CaCl2-type and NiAs-type silica polymorphs contain up to 8 wt% of H2O at 1400-2100 K up to at least 110 GPa. We next explored the effects of water on the mineralogy of the lower mantle and found that hydrous Mg2SiO4 ringwoodite (1 wt% H2O) breaks down to silica + bridgmanite + ferropericlase at pressures up to 60 GPa and 2100 K. The recovered silica samples contain 0.3-1.1 wt% H2O, suggesting that water stabilizes silica even under Si-undersaturated systems because of their large water storage capacity. Therefore, our observations support the stability of silica in hydrous regions in the pyrolitic lower mantle. In the subducting oceanic crust (basalt and sediment), silica represents 20-80% of the mineralogy. Because its stability range spans the mantle transition zone to the deep mantle, hydrous silica is expected to play a major role in the transport and storage of water in the deep mantle.
DS201804-0735
2018
Shirey, S.B., Pearson, D.G.How to obtain and interpret diamond ages.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 38-40. abstractTechnologydiamond ages
DS201801-0062
2017
Shitole, A., Sant, D.A., Parvez, I.A., Rangarajan, G., Patel, S., Viladkar, S.G., Murty, A.S.N., Kumari, G.Shallow seismic studies along Amba Dongar to Sinhada ( longitude 74 3 50E) transect, western India.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 16.Indiadeposit - Amba Dongar

Abstract: The microtremor method is applied to map subsurface rheological boundaries (stratigraphic, faults and plutons) is based on strong acoustic impedance across contrasting density of rock/ sediment/ weathered interfaces up to shallow depths along longitude 74° 3'50" E from village Amba Dongar (latitude: 21° 59'N) up to Sinhada village (latitude: 22° 14' N). The 30 km long transect exposes variety of rocks viz., unclassified granite gneisses and metasediments (Precambrian age); sediments belonging to Bagh Group (Late Cretaceous); alkaline - carbonatite plutons and lava flows belonging to Deccan Traps (Late Cretaceous). In all, sixty stations were surveyed along the longitude 74° 3'50" E with spacing of 500 m. H/V spectral ratio technique reveals four rheological interfaces identified by resonant frequencies (fr) ranges 0.2213 to 0.7456 Hz (L1), 1.0102 to 3.076 Hz (L2), 4.8508 to 21.0502 Hz (L3), and 24.5018 to 27.1119 Hz (L4). L1 represents interface between plutons, Precambrian basement rocks; L2 represents interface between Bagh sediments, Deccan Traps and intrusives whereas L3 and L4 captures depth of top most weathered profile. We estimate the depth range for L1 L2 L3 and L4 using equation (h = 110.18fr?1.97) derived based on Deep Banni Core (1764 m deep from surface: DGH record). Deep Banni Core has a distinct interface between Mesozoic rocks and Precambrian basement. The depths are further compared with terrain-based equation. Further, the overall results from the present study are compared with seismic refraction studies along Phangia-Kadipani (NGRI Technical Report, 2003). The subsurface profile across longitude 74° 3'50" E educe faults that bound Bagh Group of rocks with Deccan Trap and Precambrian. We identify two plutons underneath three zones of intrusive viz., Amba Dongar Carbonatite Complex (Station 1 to 8), Tiloda Alkaline (station 33 to 44) and Rumadia Alkaline (station 46 to 51). The present study demarcates the presence of depression over Amba Dongar hill (station 1 to 3), filled by post carbonatite basalt earlier reported by Viladkar et al., (1996 and 2005) suggesting caldera morphology. Similarly, studies identify intrusive-pluton interfaces one, below the Amba Dongar hill, and second between village Tiloda and Rumadia at depth of ~500 m from the surface. Microtremor survey further depicts both basement morphology and thickness of Bagh Group and Deccan Traps.
DS201807-1525
2018
Shu, Q., Brey, G.P., Pearson, D.G.Eclogites and garnet pyroxenites from Kimberley, Kaapvaal craton, South Africa: their diverse origins and complex metasomatic signatures.Mineralogy and Petrology, June 14, DOI:10.1007/ s00710-018 -0595-6, 16p.Africa, South Africadeposit - Boshof

Abstract: We describe the petrography and mineral chemistry of sixteen eclogite and garnet pyroxenite xenoliths from the reworked Boshof road dump (Kimberley) and define three groups that stem from different depths. Group A, the shallowest derived, has low HREE (heavy rare earth element) abundances, flat middle to heavy REE patterns and high Mg# [= 100•Mg/(Mg?+?Fe)]. Their protoliths probably were higher pressure cumulates (~ 0.7 GPa) of mainly clinopyroxene (cpx) and subordinate orthopyroxene (opx) and olivine (ol). Group B1 xenoliths, derived from the graphite/diamond boundary and below show similarities to present-day N-MORB that were modified by partial melting (higher Mg# and positively inclined MREE (middle REE) and HREE (heavy REE) patterns of calculated bulk rocks). Group B2 samples from greatest depth are unique amongst eclogites reported so far worldwide. The calculated bulk rocks have humped REE patterns with very low La and Lu and prominent maxima at Sm or Eu and anomalously high Na2O (up to 5 wt%) which makes protolith identification difficult. The complex trace element signatures of the full spectrum of Kimberley eclogites belie a multi-stage history of melt depletion and metasomatism with the introduction of new phases especially of phlogopite (phlog). Phlogopite appears to be characteristic for Kimberley eclogites and garnet peridotites. Modelling the metasomatic overprint indicates that groups A and B1 were overprinted by volatile- and potassium-rich melts probably by a process of chromatographic fractionation. Using constraints from other metasomatized Kimberley mantle rocks suggest that much of the metasomatic phlogopite in the eclogites formed during an intense episode of metasomatism that affected the mantle beneath this region 1.1 Gyr ago.
DS201806-1250
2018
Shule, Yu, Garnero, E.J.Ultralow velocity zone locations: a global assessment.Geochemistry, Geophysics, Geosystems, Vol. 19, 2, pp. 396-414.Mantlecore, boundary

Abstract: We have compiled all previous ultralow velocity zone (ULVZ) studies, and digitized their core?mantle boundary (CMB) sampling locations. For studies that presented sampling locations based on infinite frequency ray theory, we approximated Fresnel zones onto a 0.5° × 0.5° grid. Results for these studies were separated according to wave type: (1) core?reflected phases, which have a single location of ULVZ sampling (ScS, ScP, PcP), (2) core waves that can sample ULVZs at the core entrance and exit locations of the wave (e.g., SPdKS, PKKP, and PKP), and (3) waves which have uncertainties of ULVZ location due to long CMB sampling paths, e.g., diffracted energy sampling over a broad region (Pdiff, Sdiff). For studies that presented specific modeled ULVZ geographical shapes or PKP scatter probability maps, we digitized the regions. We present summary maps of the ULVZ coverage, as well as published locations arguing against ULVZ presence. A key finding is that there is not a simple mapping between lowermost mantle reduced tomographic velocities and observed ULVZ locations, especially given the presence of ULVZs outside of lowermost mantle large low velocity provinces (LLVPs). Significant location uncertainty exists for some of the ULVZ imaging wave types. Nonetheless, this compilation supports a compositionally distinct origin for at least some ULVZs. ULVZs are more likely to be found near LLVP boundaries, however, their relationship to overlying surface locations of hot spots are less obvious. The new digital ULVZ database is freely available for download.
DS201809-2087
2018
Shumilova, T.G., Ulyashev, V.V., Isaenko, S.I.A new type of impact diamonds: diamond paramorphs after wood relics. Kara astrobleme ( Pay-Khoy)81st Annual Meeting of the Meteoritical Society 2018, LPI contribution No. 2067, 1p. AbstractRussiadiamond - impact

Abstract: Impact diamonds are known as high quality technical material [1]. Usually they are formed by graphite-to-diamond solid-phase diffuse-less transition at shock pressures > 30 GPa. The diffuse-less mechanism had been proven by numerous experimental studies [2]. But impact diamond formation is possible from non-graphitic precur-sor too, from amorphous carbons and bitumenes, while the process is rare known and slightly studied. In the nature not only graphite of metamorphic rocks but sedimentary organic matter containing rocks can be treated by impact processes resulting by high pressure phases up to after-coal diamond formation [3]. The only two astroblemes with after-coal diamonds have been found by present - the giant Kara and Ust`-Kara astroblemes with 65 and 25 km in diameters correspondently [1, 3]. The novel data on impact diamonds and impact objects are very actual since the practical interest to impact diamonds last time is rising [4, 5]. Here we present the after-coal diamonds features including a new impact diamond variety (Fig. 1) presented by after-organics diamond paramorphs first time found at the Kara astrobleme (Pay-Khoy, Russia) [6]. The paramorphs are characterized with perfectly preserved micromorphology of the wood relics being composed of pure carbon content with polynanocrystalline structure has been proven with Raman spectroscopy, transmission electron microscopy, atomic force microscopy and other modern methods. The received data on after-coal diamonds point to their formation by low-distance diffuse mechanism described for low ordered carbons by Borimchuk et al. [7]. The received data allow to present a new impact diamond variety widely spread through the Kara astrobleme counting huge concentrations - up to several thousand carat per ton [6]. The proposed novel mechanism of impact diamonds formation is characterized with several stages including high pressure high temperature fast pyrolysis with the precursor carbonization co-followed with diamond crystallization through low-distance diffuse mechanism [6]. The provided study allow suppose possibility of wide distribution of impact diamonds formed after noncrystalline carbons and organics of sedimentary objects at large impact craters around the world.
DS201806-1251
2018
Shunilova, T.G., Isaenko, S.I., Ulyashev, V.V., Kazakov, V.A., Makeev, B.A.After coal diamonds: an enigmatic type of impact diamonds. Kara astrobleme ( Pay-Khoy)European Journal of Mineralogy, Vol. 30, 1, pp. 61-76.Russiameteorites

Abstract: Impact diamonds were discovered in the 70s and are usually accepted as being paramorphs after graphite, resulting in grains of extremely high mechanical quality. A diffusion-less mechanism for the graphite-to-diamond transition under huge pressure has been experimentally realized and theoretically explained. Besides, another type of impact product has received much less attention, namely diamonds formed after coal as a result of the impact. Here we describe after-coal impact diamonds from the giant Kara astrobleme (Pay-Khoy, Russia), which resulted from a large asteroid impact about 70?Ma ago. The impact created a large number of unusual impact diamonds, which are described here for the first time using high-resolution techniques including visible and UV Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM) and transmission electron microscopy (TEM). Two main varieties of after-coal diamonds occur: micrograined (sugar-like, subdivided into coherent and friable) and, as a new type, paramorphs after organic relics. After-coal diamonds differ from after-graphite impact diamonds by the texture, the absence of lonsdaleite, a micro- and nanoporous structure. The sugar-like variety consists of tightly aggregated, well-shaped single nanocrystals. The after-organic diamond paramorphs are characterized by a well-preserved relict organic morphology, sub-nanocrystalline-amorphous sp3-carbon (ta-C) nanocomposites and other specific properties (optical transparence, brown color, very high luminescence, spectral features). Based on the description of after-coal diamonds, we propose a new, polystage formation mechanism: high-velocity coal pyrolysis with hetero-elements removal followed by diffusion-limited crystallization of pure carbon. The similarity of the after-coal diamonds features with carbonado is a strong piece of evidence in support of the impact hypothesis for the origin of carbonado.
DS201806-1252
2018
Sicola, S., Vona, A., Romano, C., Ryan, A.G., Russell, J.K.In-situ high-temperature rheology of pore-bearing magmas. ( obsidian )Geophysical Research , Vol. 20, EGU2018-13349 1p. AbstractIcelandmagmatism

Abstract: Porous rocks represent the products of all explosive volcanic eruptions. As magma ascends to the Earth’s surface, bubbles form as a consequence of the evolving saturation state of volatiles dissolved in the melt. The presence of pores (either filled with pressurized volatiles or not) strongly controls the rheological behaviour of magma and thus influences all volcanic processes (pre- syn- and post-eruptive). Nevertheless, the effects of porosity on the rheology of magma are not well characterised, and a general parameterization is not available yet. Here we present a new set of experiments designed to investigate the rheology of porous melts at high temperature (750-800 C), low strain rates (10^6-10^7 s^-1) and variable porosity. Experiments were performed at 1 atm using a Setaram Setsys vertical dilatometer. The starting materials are 5 x 5 mm cores of natural rhyolitic obsidian from Hrafntinnuhryggur, Krafla, Iceland (vesicle and crystal-free) initially containing 0.11(4) wt% dissolved H2O. The experimental procedure is composed by two steps: 1) synthesis of bubble-bearing materials by heating and expansion due to foaming; 2) deformation of the foamed samples. During the first step, the obsidian cores are heated above the glass transition temperature to 900- 1050 C and held for set amounts of time (2-24 h); the volume of the foamed samples increases because H2O vapour-filled bubbles nucleate and expand. The change in volume (measured by He-pycnometry) is linked to the change in porosity (10-50 vol%). For the second step, two different experimental strategies are employed, hereafter “single-stage” and “doublestage” measurements. Single-stage measurements involve deformation of the samples directly after foaming (without quenching). The sample is cooled down from the foaming T to different target T (750-800 C), a constant load (150 g) is applied by silica or alumina probes to the core, and the cores deform isothermally for 5-20 hours. Conversely, double-stage measurements involve deformation of previously synthesised and quenched pore-bearing cores. In this case the sample is heated up to the target T and deformed under an applied load for similar amount of time (5-20 hours). In both cases, the variation in length (displacement) and volume (porosity) is continuously recorded and used to calculate the viscosity of the foamed cores using Gent’s equations. Preliminary results suggest for single-stage measurements a lower effect of bubbles on the bulk viscosity, compared to double-stage measurements. We suggest that the different behaviour may be related to the different microstructure of the experimental materials. For single-stage measurements, closed and H2O vapour-filled bubbles contribute to the observed higher viscosity, whereas in double-stage measurements, possible gas leaking and melt micro-cracking during quenching are able to weaken the porous material and markedly lower suspension viscosity.
DS201812-2879
2018
Sidder, A.How nitrogen contributes to permafrost carbon dynamics.EOS, doi.org/10.1029/2018EO107611 Nov. 2 United States, Alaskacarbon

Abstract: The Arctic is warming 2-3 times faster than the global average. The rapid increase of near-surface air temperatures at high latitudes is driving a loss of ice in oceans, rivers, mountain glaciers, and soil. Permafrost, the perennially frozen ground found in frigid climates, is estimated to store approximately 1,500 gigatons of carbon, or about half of the world’s underground stores. This carbon is slowly escaping from the soil as permafrost thaws; this thawing could release as much carbon into the atmosphere as current emissions from global land use change over the next 80 years. Like many other models of future conditions, uncertainty plagues the estimates of permafrost carbon release. Salmon et al. explored how nitrogen, an important contributor to this uncertainty, interacts with carbon in thawing soils. Nitrogen is an essential nutrient for plants and soil microbes but occurs in limited supply in tundra soils. This limitation restricts plant growth and microbial decomposition, which are critical pieces of the carbon cycle. The researchers drilled soil cores at the Eight Mile Lake site in interior Alaska to depths of 85 centimeters to evaluate the annually thawed active layer (0-55 centimeters) as well as the upper permafrost (below 55 centimeters). They then incubated the soil cores at 15°C for about 8 months and measured the subsequent nitrogen levels and microbial biomass. The data collected in the incubation informed statistical models that were used to analyze the effects of depth, time, and growing season conditions on nitrogen and carbon dynamics. The findings revealed that both carbon loss and microbial biomass decreased significantly with soil depth. Models predicted that soil decomposition would release the largest amount of mineral nitrogen from soils located in the middle of the active layer. Permafrost soils at the bottom of the soil profile, however, released a large flush of mineral nitrogen during the initial thaw but a small flux of mineral nitrogen during subsequent decomposition. These patterns indicate that microbes near the soil surface are nitrogen limited, whereas deep microbial communities are more limited by carbon. The team’s calculations estimate that mineral nitrogen released from the soil profile would increase tenfold during the first 5 years of permafrost thaw. Should permafrost continue to thaw in the Arctic, these results suggest that tundra ecosystems may experience an increase in nitrogen availability that exceeds plant and microbial demands. Excess nitrogen, in turn, could precipitate increased decomposition of soil carbon and increased levels of nitrogen in streams draining from thawing permafrost landscapes. The study offers critical insights into how warming temperatures in the Arctic could dramatically increase permafrost thaw and initiate profound changes in carbon and nitrogen cycling in tundra ecosystems.
DS201803-0475
2017
Simakov, S.K.Nano and micron sized diamond genesis in nature: an overview.Geoscience Frontiers, Vol. Pp. 1-10.Technologynanodiamonds

Abstract: There are four main types of natural diamonds and related formation processes. The first type comprises the interstellar nanodiamond particles. The second group includes crustal nano- and micron-scale diamonds associated with coals, sediments and metamorphic rocks. The third one includes nanodiamonds and microndiamonds associated with secondary alteration and replacing of mafic and ultramafic rocks. The fourth one includes macro-, micron- and nano-sized mantle diamonds which are associated with kimberlites, mantle peridotites and eclogites. Each diamond type has its specific characteristics. Nano-sized diamond particles of lowest nanometers in size crystallize from abiotic organic matter at lower pressures and temperatures in space during the stages of protoplanetary disk formation. Nano-sized diamonds are formed from organic matter at P-T exceeding conditions of catagenesis stage of lithogenesis. Micron-sized diamonds are formed from fluids at P-T exceeding supercritical water stability. Macrosized diamonds are formed from metal-carbon and silicate-carbonate melts and fluids at P-T exceeding 1150 °C and 4.5 GPa. Nitrogen and hydrocarbons play an important role in diamond formation. Their role in the formation processes increases from macro-sized to nano-sized diamond particles. Introduction of nitrogen atoms into the diamond structure leads to the stabilization of micron- and nano-sized diamonds in the field of graphite stability.
DS201810-2377
2018
Simakov, S.K.On the origin of large type IIa gem diamonds.Ore Geology Reviews, Vol. 102, pp. 195-203.Globaldiamond morphology

Abstract: The processes of formation of some diamond types still raise contentious issues, mainly on the origin of the largest diamond crystals recovered from kimberlites. These diamonds constitute less than 2% of worldwide resources and correspond to rare type IIa. They possess some peculiar features: (i) silicate and oxide inclusions are extremely rare, (ii) their ?13C ranges from ?17 to ?21‰. The detailed estimation of the Premier pressure-temperature-oxygen fugacity parameters and the physic-chemical modeling of diamond growth-dissolution processes suggest that extra-large diamonds have multiple origins. Their formation may occur from lower mantle to crustal depths. Their main building-up takes place from fluids in the pegmatitic veins solidified along the contacts of kimberlite magma at a crustal depth. The model explains the main features of the largest kimberlitic diamonds, i.e. their great sizes, light ?13C signatures, low nitrogen contents, high degree of resorption, absence of mantle-derived mineral inclusions and their occurrence in the form of rare isolated crystals in the host kimberlite.
DS201812-2880
2018
Simakov, S.K.The nature of the diamond potential of "cold" paleogeotherms.Doklady Earth Sciences, Vol. 482, 2, pp. 1317-1319.Mantlegeothermometry

Abstract: It is known that the ?-? parameters of diamond-bearing kimberlite xenoliths correspond to subductive paleogeotherms lying between the 36 and 41 mW/m2 conductive models. There are some studies showing the correlation of diamond ability with oxygen fugacity and the fluid composition of mantle xenoliths.The most diamondiferous samples correspond to the water compositions of the calculated O-H-C fluid with a minimum atomic carbon content in it. From the calculations it follows that the fluid carbon atomic content increases with a temperature increase and with the pressure decreasing. The most minor C contents have the 35 mW/m2 conductive model in comparison with the 40 and 45 mW/m2 models. As a result, it is possible to conclude that the low temperature fields (less than 1100°C) of the “cold” geotherms have the highest diamondiferous ability.
DS201812-2881
2018
Simakov, S.K.Type IIa diamond formation.Doklady Earth Sciences, Vol. 482, 2, pp. 1336-1338.Mantlediamond genesis
DS201804-0736
2018
Simakov, S.K., Melnik, N.N., Vyalov, V.I.Nanodiamond formation at the lithogenesis and low-stages of regional metamorphism. DonbassDoklady Earth Sciences, Vol. 478, 2, pp. 214-218.Russiaspectroscopy

Abstract: Samples of gilsonite from Adzharia, anthraxolite and graphite of coal from Taimyr, shungite from Karelia, and anthracite from Donbass are studied using Raman spectroscopy. Peaks at 1600 cm?1, indicating the presence of nanographite, are recorded in all samples. The anthracite sample from Donbass, 1330 cm?1, corresponds to the sp3-line of carbon hybridization conforming to a nanodiamond. It is concluded that in nature diamonds can be formed at late stages of lithogenesis (catagensis, metagenesis), and for coals, it can occur at the zeolite stage of regional metamorphism of rocks, before the green schist stage.
DS201801-0063
2017
Simandl, G.J., Mackay, D.A.R., Ma, X., Luck, P., Gravel, J., Akam, C.The direct indicator mineral concept and QEMSCAN applied to exploration for carbonatite and carbonatite related ore deposits.in: Ferbey, T. Plouffe, A., Hickein, A.S. eds. Indicator minerals in tills and stream sediments of the Canadian Cordillera. Geological Association of Canada Special Paper,, Vol. 50, pp. 175-190.Canada, British Columbiacarbonatite - Aley, Lonnie, Wicheeda

Abstract: This volume consists of a series of papers of importance to indicator minerals in the Canadian Cordillera. Topics include the glacial history of the Cordilleran Ice Sheet, drift prospecting methods, the evolution of survey sampling strategies, new analytical methods, and recent advances in applying indicators minerals to mineral exploration. This volume fills a notable knowledge gap on the use of indicator minerals in the Canadian Cordillera. We hope that the volume serves as a user guide, encouraging the wider application of indicator minerals by the exploration community.
DS201811-2608
2018
Simandl, G.J., Paradis, S.Carbonatites: related ore deposits, resources, footprint, and exploration methods.Applied Earth Science ( Trans. Inst. Min. Metall B), 31p. Doi.org/10.1080/25726388.2018.1516935 31p. Open accessGlobalcarbonatite - review

Abstract: Most carbonatites were emplaced in continental extensional settings and range in age from Archean to recent. They commonly coexist with alkaline silicate igneous rocks, forming alkaline-carbonatite complexes, but some occur as isolated pipes, sills, dikes, plugs, lava flows, and pyroclastic blankets. Incorporating cone sheets, ring dikes, radial dikes, and fenitisation-type halos into an exploration model and recognising associated alkaline silicate igneous rocks increases the footprint of the target. Undeformed complexes have circular, ring, or crescent-shaped aeromagnetic and radiometric signatures. Carbonatites can be effectively detected by soil, till, and stream-sediment geochemical surveys, as well as biogeochemical and indicator mineral surveys Carbonatites and alkaline-carbonatite complexes are the main sources of rare earth elements (REE) and Nb, and host significant deposits of apatite, vermiculite, Cu, Ti, fluorite, Th, U, natural zirconia, and Fe. Nine per cent of carbonatites and alkaline-carbonatite complexes contain active or historic mines, making them outstanding multi-commodity exploration targets.
DS201808-1789
2018
Simon, M., Bongiolo, E.M., Avila, C.A., Oliveira, E.P., Texeira, W., Stohler, R.C., Soares de Oliveira, F.V.Neoarchean reworking of TTG like crust in the southern most portion of the Sao Francisco craton: U-Pb zircon dating and geochemical evidence from the Sao Tiago batholith.Precambrian Research, Vol. 314, pp. 353-376.South America, Brazilcraton

Abstract: Field, petrographic and geochemical data combined with in situ zircon U-Pb LA-ICP-MS ages are documented for the São Tiago Batholith (southernmost portion of the São Francisco Craton) to understand its origin and magmatic evolution. The geologic relations indicate that the batholith is composed of granitic to granodioritic orthogneisses (L2) with tonalitic xenoliths (L1) intruded by pegmatite (L3) and metagranite (L4). L1 consists of two facies of tonalitic orthogneiss, one biotite-rich, and the other biotite-poor. The geochemical evidence, including high K2O with mantle-like chemical signature, suggests that the Bt-rich tonalitic gneiss (2816?±?30?Ma) was derived from contamination of mafic magmas by crustal-derived components. The Bt-poor tonalitic gneiss, of TTG affinity, was generated by partial melting of LILE-enriched mafic rocks, possibly from oceanic plateus in a subduction environment. L2 includes two distinct types of rocks: (i) granodioritic orthogneiss, chemically ranging from medium-pressure TTGs to potassic granitoids originated via partial melting of previous TTG crust, including L1 Bt-poor; and (ii) granitic gneiss (2664?±?4?Ma), geochemically similar to crustal-derived granites, produced by melting of the L1 Bt-rich tonalitic gneiss or mixed TTG/metasedimentary sources. L3 pegmatite (2657?±?23?Ma) results from melting of L2, whereas L4 metagranite (dikes and stocks) shows petrogenesis similar to that of the L2 granitic gneiss. Related orthogneisses occur near the São Tiago Batholith: (i) a hornblende-bearing tonalitic gneiss, and (ii) a hybrid hornblende-bearing granitic gneiss (2614?±?13?Ma), whose genesis is linked with interaction of sanukitoid and felsic potassic melts, representing the last Archean magmatic pulse of the region. The Minas strata along the Jeceaba-Bom Sucesso lineament near our study region encircle the São Tiago Archean crust, representing an irregular paleo-coastline or a micro-terrane amalgamation with the São Francisco Proto-craton, with possible subsequent dome-and-keel deformational processes. Our petrological and geochronological data reevaluate nebulous concepts in the literature about the SFC, revealing (i) a chemically and compositionally diverse crustal segment generated at the Late Archean in diverse geodynamic scenarios, and (ii) a more complex lineament than previously thought in terms of the paleogeography of the southern São Francisco Craton.
DS201801-0064
2017
Simon, S.J., Wei, C.T., Viladkar, S.G., Ellmies, R., Soh, Tamech, L.S., Yang, H., Vatuva, A.Metamitic U rich pyrochlore from Epembe sovitic carbonatite dyke, NW Namibia.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 12.Africa, Namibiadeposit - Epembe

Abstract: The Epembe carbonatite dyke is located about 80 km north of Opuwo, NW Namibia. The 10 km long dyke is dominated by massive and banded sövitic carbonatite intrusions. Two distinct type of sövite have been recognized: (1) coarse-grained light grey Sövite I which is predominant in brecciated areas and (2) medium- to fine-grained Sövite II which hosts notable concentrations of pyrochlore and apatite. The contact between the carbonatite and basement gneisses is marked by K-feldspar fenite. The pyrochlore chemistry at Epembe shows a compositional trend from primary magmatic Ca-rich pyrochlore toward late hydrothermal fluid enriched carbonatite phase, giving rise to a remarkable shift in chemical composition and invasion of elements such as Si, U, Sr, Ba, Th and Fe. Enrichment in elements like U, Sr and Th lead to metamictization, alteration and A-site vacancy. It is therefore suggested that the carbonatite successive intrusive phases assimilated primary pyrochlore leading to extreme compositional variation especially around the rims of the pyrochlore. The genesis of the Epembe niobium deposit is linked to the carbonatite magmatism but the mechanism that manifested such niobium rich rock remains unclear and might be formed as a result of cumulate process and/or liquid immiscibility of a carbonate-silicate pair.
DS201801-0065
2017
Simonetti, A., Kuebler, C.Nd, Sr, Pb and B isotopic investigation of carbonatite/alkaline centers in west central India: insights into plume driven vs lithospheric controlled magmatism.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 17.Indiacarbonatites

Abstract: The exact origin of carbonatite magmas remains debatable as there are two main hypothesis proposed; one relates magmatism to asthenospheric upwellings and/or mantle plumes, whereas the other argues for generation from metasomatized lithosphere. However, proponents of the latter rarely describe in detail the origin of the metasomatic agents required to generate the high concentrations of rare earth and highly incompatible elements present in carbonatite magmas. In a recent study, Boron isotopic signatures of carbonatite complexes worldwide, ranging in age from ~2600 to ~65 million years old, indicate greater input of recycled (subducted), crustal material and plume activity with increasing geologic age of the Earth. More positive Boron isotopic values with increasing geologic time were attributed to the change of Earth’s geodynamics to a modern style of plate tectonics. In this study, the radiogenic (Sr, Nd, Pb) and B isotope systematics of carbonatites and alkaline rocks from west-central India are reported and discussed with reference to the plume-lithosphere interaction model previously proposed for the generation of Deccan-related alkaline centers in this region of the Indian sub-continent
DS201804-0737
2017
Simonov, V.A., Prikhodko, V.S., Vasiliev, Yu.R., Kotlyarov, A.V.Physicochemical conditions of the crystallization of rocks from ultrabasic massifs of the Siberian platform. Konder, Inagli, Chad) Cr-spinelsRussian Journal of Pacific Geology, Vol. 11, 6, pp. 447-468.Russiapicrites

Abstract: A great volume of original information on the formation of the ultrabasic rocks of the Siberian Platform has been accumulated owing to the study of melt inclusions in Cr-spinels. The inclusions show the general tendencies in the behavior of the magmatic systems during the formation of the ultrabasic massifs of the Siberian Platform, tracing the main evolution trend of decreasing Mg number with SiO2 increase in the melts with subsequent transition from picrites through picrobasalts to basalts. The compositions of the melt inclusions indicate that the crystallization conditions of the rocks of the concentrically zoned massifs (Konder, Inagli, Chad) sharply differ from those of the Guli massif. Numerical modeling using the PETROLOG and PLUTON softwares and data on the composition of inclusions in Cr-spinels yielded maximum crystallization temperatures of the olivines from the dunites of the Konder (1545-1430°C), Inagli (1530-1430°C), Chad (1460-1420°C), and Guli (1520-1420°C) massifs, and those of Cr-spinels from the Konder (1420-1380°C), Inagli (up to 1430°C), Chad (1430-1330°C), and Guli (1410-1370°C) massifs. Modeling of the Guli massif with the PLUTON software using the compositions of the melt inclusions revealed the possible formation of the alkaline rocks at the final reverse stage of the evolution of the picritic magmas (with decrease of SiO2 and alkali accumulation) after termination of olivine crystallization with temperature decrease from 1240-1230°C to 1200-1090°C. Modeling with the PLUTON software showed that the dunites of the Guli massif coexisted with Fe-rich (with moderate TiO2 contents) melts, the crystallization of which led (beginning from 1210°C) to the formation of pyroxenes between cumulate olivine. Further temperature decrease (from 1125°C) with decreasing FeO and TiO2 contents provided the formation of clinopyroxenes of pyroxenites. For the Konder massif, modeling with the PLUTON software indicates the possible formation of kosvites from picrobasaltic magmas beginning from 1350°C and the formation of clinopyroxenites and olivine-diopside rocks from olivine basaltic melts from 1250°C.
DS201812-2882
2018
Simpson, L., Sinclair, S., Loescher, B.Short hold time parameters. Diavik mine water treatment plant.2018 Yellowknife Geoscience Forum , p. 74-75. abstractCanada, Northwest Territoriesdeposit - Diavik

Abstract: It is well known that it is very difficult to transport samples from remote locations to the laboratory and allow sufficient time to commence analysis within the prescribed short hold times for certain parameters. Also, the majority of published hold times are based on legacy as opposed to hard science. In an attempt to determine the validity of specific short hold times, a joint study between Diavik and Maxxam was undertaken. The purpose was to determine the stability of short hold time parameters over time using real samples from Diavik sites. Data from two sites will be presented. The first from the Diavik mine water treatment plant influent, which had relatively high levels of the target analytes. The second from a lake water sample with lower native levels of the target analytes. The parameters studied were ammonia (preserved and unpreserved), total nitrogen, nitrite, nitrate, phosphate, total phosphorus and turbidity. All target parameters have a prescribed 3-day hold time.1 pH was also monitored. Samples were collected by Diavik personnel in one-litre containers and extraordinary logistical measures were taken to get them to Maxxam's Burnaby laboratory as soon as possible. On receipt, they were immediately subsampled into appropriate containers. Each parameter (except pH and turbidity) was split into three containers: 1) as received; 2) low level spike added and 3) medium level spike added. All samples were analyzed within 3 at approximately 3-day intervals thereafter for a period of two weeks.
DS201812-2883
2018
Sims, K., Fox, K., Harris, M., Chimuka, L., Reichhardt, F., Muchemwa, E., Gowera, R., Hinks, D., Smith, C.B.Murowa deposit: Discovery of the Murowa kimberlites, Zimbabwe.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 359-378.Africa, Zimbabwedeposit - Murowa
DS201802-0265
2018
Sirotkina, E.A., Bobrov, A.V., Bindi, L., Irifune, T.Chromium bearing phases in the Earth's mantle: experiments in the Mg2SiO4 MgCr2O4 system at 10-24 Gpa and 1600C.American Mineralogist, Vol. 103, pp. 151-160.Mantlechromites

Abstract: Phase relations in the system Mg2SiO4-MgCr2O4 were studied at 10-24 GPa and 1600°C using a high-pressure Kawai-type multi-anvil apparatus. We investigated the full range of starting compositions for the forsterite-magnesiochromite system to derive a P-X phase diagram and synthesize chromium-bearing phases, such as garnet, wadsleyite, ringwoodite, and bridgmanite of a wide compositional range. Samples synthesized at 10 GPa contain olivine with small chromium content and magnesiochromite. Mg2SiO4 wadsleyite is characterized by the pressure-dependent higher chromium solubility (up to 7.4 wt% Cr2O3). The maximal solubility of chromium in ringwoodite in the studied system (~18.5 wt% Cr2O3) was detected at P = 23 GPa, which is close to the upper boundary of the ringwoodite stability. Addition of chromium to the system moves the boundaries of olivine/wadsleyite and wadsleyite/ring-woodite phase transformations to lower pressures. Our experiments simulate Cr-rich phase assemblages found as inclusions in diamonds, mantle xenoliths, and UHP podiform chromitites.
DS201812-2884
2018
Siva-Jothy, W., Chinn, I., Stachel, T., Pearson, D.G.Resorption features of macro and micro diamonds from Gahcho Kue.2018 Yellowknife Geoscience Forum , p. 120. abstractCanada, Northwest Territoriesdeposit - Gahcho Kue

Abstract: Studies into the relationship between oxygen fugacity of mantle fluids/melts and etch features on diamond surfaces have shown specific fluid/melt compositions correspond to associated etch features. A classification scheme has been proposed to determine the fluid composition within a kimberlite by examining etch features associated with diamond surfaces as a proxy for fluid composition in an ascending diamondiferous kimberlite. A suite of 388 microdiamonds (defined as diamonds which pass through a 0.5 mm square mesh screen) and 88 macrodiamonds taken from various drill hole depths in the Hearne kimberlite and 88 inclusion-bearing macrodiamonds from the Gahcho Kué mine (NWT) were viewed under a secondary electron microscope for their surface features in accordance with this scheme. Two hundred and thirty specimens show shallow-depth etch features that can be easily classified: the main features observed were trigons and truncated trigons on the {111} faces and/or tetragons on the {100} faces (indicating etching by fluids of variable CO2:H2O ratios). Thirty-four specimens show deeper etched features that represent either extreme degrees of regular etching (such as deeply-etched tetragons), or corrosion type etching, wherein the diamond lattice is etched in a fluid-free melt. Variability between crystal habits exists between the size fractions studied, with cubic habits only being observed in the microdiamond population. This implies variable formation conditions for the two different diamond size fractions studied from Gahcho Kué. Among microdiamonds, surface textures associated with fluid-related etching are markedly more variable, with truncated trigons, tetragons, and both positive and negative trigons being observed. However, these often occur in combination with features showing a large variability in their depth to size ratio between samples, which is typically caused by mantle-related etching. These observations suggest repeated interaction of fluids/melts with the Gahcho Kué diamond population, with at least some of the fluids affecting the microdiamonds being more CO2-rich than those that etched the macrodiamond fraction.
DS201806-1253
2018
Skalwold, E.A., Bassett, W.A.Omphacite and chromite: a bimineralic inclusion in diamond.Gems & Gemology, Vol. 54, 1, p. 67-68.Technologydiamond inclusions
DS201809-2088
2018
Smart, K.A., Cartigny, P., Tappe, S., O'Brien, H., Klemme, S.Reduced volatile sources for Karelian diamonds linked to punctuated ultramafic magmatism. LahtojokiGoldschmidt Conference, 1p. AbstractEurope, FinlandDeposit - Lahtojoki

Abstract: Diamond xenocrysts and eclogite-hosted diamonds from the Lahtojoki kimberlite (Karelian craton, Finland) indicate metasomatism of the deep lithosphere by N-rich, relatively reduced fluids. P-T-fO2 constraints show that all eclogites were derived from near the base of the lithospheric mantle (>5 GPa), but only the diamond-bearing samples are relatively reduced (?FMQ-3.5 vs. -1.7 for barren eclogites). The Lahtojoki diamonds show evidence of formation from reduced mantle-derived carbon, based on the restricted range of ?13C values (-3 and -7.8 ‰; n = 67) that form a negativelyskewed distribution. This reduced CHO fluid was also anomalously N-rich, based on the diamond N contents that range up to 1830 at. ppm. While N-rich sources for eclogiteassociated diamonds are often linked to recycled crustal materials, in this case we prefer derivation from K-rich cratonic mantle metasomes due to lack of firm crustal geochemical signatures in the eclogites (?18O = 5.7 - 5.9 ‰), in addition to the magmatic history of the Karelian craton. The Karelian craton has been periodically intruded by Krich alkaline lamprophyres, Group-2 kimberlites and olivine lamproites from 1800 to 700 Ma. Such K-rich ultramafic alkaline magmatism is likely linked to phlogopite-rich metasomes, which may represent significant repositories of N (NH4+ substitution for K+). Because the Lahtojoki eclogites resided near the base of the lithospheric mantle, they would have been susceptible to interaction with ascending asthenosphere-derived C-bearing fluids/melts, which were reducing. Following ingress into and interaction with the Krich metasomatised Karelian mantle lithosphere, the increasingly N-enriched, CH4-bearing fluids precipitated diamond during interaction with relatively oxidized eclogite wall rock. In contrast to the prevalent oxidizing effects of mantle metasomatism as identified within cratonic lithosphere-derived samples from worldwide locations, the eclogite-hosted diamonds at Lahtojoki represent a natural example of metasomatic overprinting that was highly reducing.
DS201807-1526
2018
Smit, K.V., D'Haenens-Johannsson, U.F.S., Howell, D., Loudin, L.C., Wang, W.Deformation related spectroscopic features in natural Type 1b-1aA diamonds from Zimmi ( West African Craton).Mineralogy and Petrology, doi.org/10.1007/ s00710-018- 0587-6 16p.Africa, Sierra Leonedeposit - Zimmi

Abstract: Zimmi diamonds (Sierra Leone) have 500 million year mantle residency times whose origin is best explained by rapid tectonic exhumation to shallower depths in the mantle, associated with continental collision but prior to kimberlite eruption. Here we present spectroscopic data for a new suite of Zimmi sulphide-bearing diamonds that allow us to evaluate the link between their spectroscopic features and their unusual geological history. Cathodoluminesence (CL) imaging of these diamonds revealed irregular patterns with abundant deformation lamellae, associated with the diamonds' tectonic exhumation. Vacancies formed during deformation were subsequently naturally annealed to form vacancy clusters, NV0/- centres and H3 (NVN0). The brownish-yellow to greenish-yellow colours observed in Zimmi Ib-IaA diamonds result from visible absorption by a combination of isolated substitutional nitrogen ( {N}S^0 ) and deformation-related vacancy clusters. Colour-forming centres and other spectroscopic features can all be attributed to the unique geological history of Zimmi Ib-IaA diamonds and their rapid exhumation after formation.
DS201809-2089
2018
Smit, K.V., Myagkaya, E., Persaud, S., Wang, W.Black diamonds from Marange ( Zimbabwe): a result of natural irradiation and graphite inclusions.Gems & Gemology, Vol. 54, 2, pp. 132-148.Africa, Zimbabwedeposit - Marange

Abstract: This study investigates the color origin of 40 natural Fancy Dark brown-black round brilliant diamonds from the Marange alluvial deposits in eastern Zimbabwe. Visual observations show that the dark appearance of the Marange diamonds is due to a combination of graphite micro-inclusions (associated with methane), graphite needles, and dark brown radiation stains that occur along internal fractures. The GR1 (V0) defect, typically formed during natural and artificial irradiation, is observed in the optical spectra of 43% of the diamonds, al- though its intensity is too low to significantly impact the bodycolor. Natural irradiation in these diamonds is likely related to their billion-year residence in the Umkondo conglomerate, which is known to contain radioac- tive minerals such as zircon. Aside from radiation staining, irradiation-damaged diamond appears non-lumines- cent in DiamondView images and shows a weaker, broader diamond peak (at 1332 cm?1) in Raman spectroscopy. Brown coloration of the radiation stains is due to heating of the diamonds during later regional metamorphism, which also facilitated the formation of the H3 (NVN0) and NiN complexes.
DS201809-2090
2018
Smit, K.V., Shirey, S.B.Diamonds help solve the enigma of Earth's deep water.Gems & Gemology, Vol. 54, 2, pp. 220-223.Mantlesubduction, water, plate tectonics

Abstract: Water is carried down into Earth at subduction zones by the process of plate tectonics. Much of the water escapes close behind the subduction zone, promoting melting of the mantle and giving rise to the volcanic chains in the Pacific Ocean basin known as the Ring of Fire, and many other volcanoes elsewhere. But can water be carried even further into the mantle? How would we even know? Why is it important, and what are the effects of such deep water storage? Diamonds can give us the answers to these questions. Recent discoveries of water-containing mineral inclusions and even free water held at high pressures in diamonds tell us that water is carried into Earth’s deep interior—perhaps as deep as 700 km.
DS201812-2885
2018
Smith, C.B., Atkinson, W.J., Tyler, E.W.J., Hall, A.E., Macdonald, I.Argyle deposit: The discovery of the Argyle pipe, western Australia: the world's first lamproite-hosted diamond mine.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 49-64.Australia, western Australiadeposit - Argyle
DS201812-2886
2018
Smith, C.B., Bulanova, G.P., Kobussen, A.F., Burnham, A., Chapman, J.G., Davy, A.T., Sinha, K.K.Bunder deposit: Diamonds from the Atri South pipe, Bunder lamproite field, India, and implications for the nature of the underlying mantle.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 237-252.Indiadeposit - Bunder
DS201809-2091
2018
Smith, E., Shirey, S.B., Richardson, S.H., Nestola, F., Bullock, E.S., Wang, J., Wang, W.Blue boron-bearing diamonds from Earth's lower mantle.Nature, Vol. 560, Aug. 2, pp. 84-97.Mantlediamond - Type Ilb blue

Abstract: Geological pathways for the recycling of Earth’s surface materials into the mantle are both driven and obscured by plate tectonics1,2,3. Gauging the extent of this recycling is difficult because subducted crustal components are often released at relatively shallow depths, below arc volcanoes4,5,6,7. The conspicuous existence of blue boron-bearing diamonds (type IIb)8,9 reveals that boron, an element abundant in the continental and oceanic crust, is present in certain diamond-forming fluids at mantle depths. However, both the provenance of the boron and the geological setting of diamond crystallization were unknown. Here we show that boron-bearing diamonds carry previously unrecognized mineral assemblages whose high-pressure precursors were stable in metamorphosed oceanic lithospheric slabs at depths reaching the lower mantle. We propose that some of the boron in seawater-serpentinized oceanic lithosphere is subducted into the deep mantle, where it is released with hydrous fluids that enable diamond growth10. Type IIb diamonds are thus among the deepest diamonds ever found and indicate a viable pathway for the deep-mantle recycling of crustal elements.
DS201804-0738
2017
Smith, E.M., Johnson, P.Lizard skin on deformed diamondGems & Gemology Lab Notes, Vol. 53, 4, p. 460.Technologydiamond crystallography

Abstract: Facets that are nearly parallel to a diamond’s octahedral crystal plane often develop a wavy, rippled appearance called "lizard skin" during polishing (e.g., J.I. Koivula, The MicroWorld of Diamonds, Gemworld International, Northbrook, Illinois, 2000, p. 63). The term is also used more broadly to describe any bumpy, uneven surface texture that develops on polished diamond facets. It is often attributed to polishing off-grain. Recently, GIA’s New York lab encountered a 2.67 ct type IIa diamond (figure 1, left) with especially prominent lizard skin texture on multiple facets (figure 1, center and right). In this case, the texture appears to have developed due to a preexisting deformation fabric or structure inherent to the diamond itself, rather than merely as a consequence of poor polishing technique.
DS201809-2092
2018
Smith, E.M., Shirey, S.B., Richardson, S.H., Nestola, F., Bullock, E.S., Wang, J., Wang, W.Boron bearing, type llb diamonds from superdeep subduction.Goldschmidt Conference, 1p. AbstractMantlesubduction

Abstract: Type IIb diamonds, such as the Hope diamond, contain trace amounts of boron and are prized for their blue colors. Since boron is a quintessential crustal element, it is completely unexpected in diamond-forming fluids at mantle depths. Despite the mineralogical/geochemical interest in type IIb diamonds, almost nothing is known about how they form chiefly because of their rarity (?0.02% of all diamonds) and high gem value. To investigate the type of mantle host rock, the depth of origin (lithospheric vs. convecting mantle), and the source of boron, the high-volume diamond grading stream of the Gemological Institute of America was systematically screened to find type IIb diamonds with inclusions. Over a period of about two years, 46 prospective samples were identified and examined optical microscopy, X-ray diffraction, and infrared/Raman spectroscopy; a few diamonds were also analyzed for carbon isotopic composition and polished for electron probe microanalysis of inclusions. The examined inclusions represent retrogressed highpressure minerals, from metabasic to metaperidotitic hosts in the lowermost mantle transition zone (MTZ) to lower mantle (LM). These include former CaSiO3-perovskite, majorite, bridgmanite, stishovite, calcium-ferrite-type phase, and ferropericlase. The variably light carbon isotope compositions and inclusion mineralogy indicate diamond growth in deeply subducted oceanic lithosphere (crust and mantle). Some inclusions are found to have coexisting fluid (CH4 ± H2) that suggests the original high-pressure minerals interacted with hydrous media. We propose that the boron resided in serpentinized oceanic lithosphere. During subduction, the serpentine was metamorphosed to dense hydrous magnesium silicates (DHMS) that retained some boron. Upon breakdown in the MTZ/LM, these DHMS yielded boron-bearing hydrous fluids conducive to diamond growth.
DS201803-0476
2018
Smith, E.M., Shirey, S.B., Wang, W.The very deep origin of the world's biggest diamonds.Gems & Gemology, Vol. 53, 4, pp. 308-403.TechnologyCLIIPIR

Abstract: Large and relatively pure diamonds like the historic 3,106 ct Cullinan, found in South Africa in 1905, have long been regarded as unusual based on their physical characteristics. For example, they often exhibit exceptional color and clarity, while routinely qualifying as type IIa, a rare designation of chemical purity. A new research discovery about these Cullinan-like diamonds is that they contain heretofore unknown, deeply derived inclusions that originate below the continental mantle keel and are thus known as "superdeep" diamonds (Smith et al., 2016). Originating from a depth between 360 and 750 km, they reveal information about the conditions within the convecting mantle, beneath the earth’s rigid tectonic plates. Here we review the previously published findings, compare the Cullinan-like diamonds to the more abundant lithospheric diamond population, and offer evidence from some additional diamond samples that further verifies their superdeep origin. Cullinan-like diamonds contain minute and rare silicate and iron-rich metallic inclusions surrounded by a fluid jacket composed of methane and hydrogen. The inclusion compositions suggest that this deep mantle environment contains small pockets of oxygen-deficient metallic liquid out of which the diamonds crystallized. This new and unexpected observation made on the world’s most expensive diamonds is important for understanding the chemical reactions between mineral assemblages in the deep earth. It shows that deep regions of the mantle contain metallic iron, as opposed to the shallower, more oxidized mantle rocks actively participating in plate tectonics and its associated volcanism.
DS201805-0977
2018
Smith, M., Kynicky, J., Xu, C., Song, W., Spratt, J., Jeffries, T., Brtnicky, M., Kopriva, A., Cangelosi, D.The origin of secondary heavy rare earth element enrichment in carbonatites: constraints from the evolution of the Huanglongpu district, China.Lithos, Vol. 308-309, pp. 65-82.Chinacarbonatite

Abstract: The silico?carbonatite dykes of the Huanglongpu area, Lesser Qinling, China, are unusual in that they are quartz-bearing, Mo-mineralised and enriched in the heavy rare earth elements (HREE) relative to typical carbonatites. The textures of REE minerals indicate crystallisation of monazite-(Ce), bastnäsite-(Ce), parisite-(Ce) and aeschynite-(Ce) as magmatic phases. Burbankite was also potentially an early crystallising phase. Monazite-(Ce) was subsequently altered to produce a second generation of apatite, which was in turn replaced and overgrown by britholite-(Ce), accompanied by the formation of allanite-(Ce). Bastnäsite and parisite where replaced by synchysite-(Ce) and röntgenite-(Ce). Aeschynite-(Ce) was altered to uranopyrochlore and then pyrochlore with uraninite inclusions. The mineralogical evolution reflects the evolution from magmatic carbonatite, to more silica-rich conditions during early hydrothermal processes, to fully hydrothermal conditions accompanied by the formation of sulphate minerals. Each alteration stage resulted in the preferential leaching of the LREE and enrichment in the HREE. Mass balance considerations indicate hydrothermal fluids must have contributed HREE to the mineralisation. The evolution of the fluorcarbonate mineral assemblage requires an increase in aCa2+ and aCO32? in the metasomatic fluid (where a is activity), and breakdown of HREE-enriched calcite may have been the HREE source. Leaching in the presence of strong, LREE-selective ligands (Cl?) may account for the depletion in late stage minerals in the LREE, but cannot account for subsequent preferential HREE addition. Fluid inclusion data indicate the presence of sulphate-rich brines during alteration, and hence sulphate complexation may have been important for preferential HREE transport. Alongside HREE-enriched magmatic sources, and enrichment during magmatic processes, late stage alteration with non-LREE-selective ligands may be critical in forming HREE-enriched carbonatites.
DS201806-1254
2018
Smolkin, V.F., Lokhov, K.I., Skublov, S.G., Sergeeva, L.Yu., Lokhov, D.K., Sergeev, S.A.Paleoproterozoic Keulik Kenirim ore bearing gabbro-peridotite complex, Kola region: a new occurrence of ferropicritic magmatism.Geology of Ore Deposits, Vol. 60, 2, pp. 142-171.Russia, Kola Peninsulazircon - picrite

Abstract: Comprehensive research of ore-bearing differentiated intrusions of the Keulik-Kenirim structural unit, which represents a fragment of the Paleoproterozoic Pechenga-Varzuga Belt, has been carried out for the first time. The intrusions are subvolcanic by type and lenticular in shape, nearly conformable and steeply dipping. They are made up of peridotite, olivine and plagioclase pyroxenites, and gabbro metamorphosed under amphibolite facies conditions along with host basic volcanics. All intrusive rocks are enriched in TiO2 and FeO. Sulfide Cu-Ni mineralization is represented by disseminated, pocket, and stringer-disseminated types, which are clustered in the peridotitic zone as hanging units and bottom lodes. The Ni content in disseminated ore is estimated at 0.45-0.55 wt % and 1.15-3.32 wt % in ore pockets; the Cu grades are 0.17-0.20 and 0.46-5.65 wt %, respectively. To determine the age of intrusions and metamorphism of intrusive and volcanic rocks, various isotopic systems have been used: Sm-Nd (TIMS) in rock and U-Pb (SIMS SHRIMP) and Lu-Hf (LA-ICP-MS) in zircon. Conclusions on the origin of zircons are based on concentrations of trace elements including REE therein and Hf-Nd correlation in zircons and rocks. The U-Pb system of zircons reflects episodes of igneous rock formation (1982 ± 12 Ma) and their postmagmatic transformation (1938 ± 20 Ma). The last disturbance of the U-Pb isotopic system occurred 700 and 425 Ma. Xenogenic zircons dated from 3.17 to 2.65 Ga have been revealed in the studied samples. These zircons were captured by magma from the Archean basement during its ascent. The intrusions were emplaced synchronously with economic ore formation in the Pechenga ore field (1985 ± 10 Ma). The peak metamorphism of intrusive rocks under amphibolite facies conditions is recorded at 40 Ma later. The differentiated intrusions of the Keulik-Kenirim structural unit are close in their internal structure, mineralogy, and geochemistry, as well as in age and features of related Cu-Ni mineralization to ore-bearing intrusions of the Pechenga ore field, which are derivatives of ferropicritic (ferriferous) magmatism.
DS201809-2093
2018
Snyder, D.B., Schetselaar, E., Pilkington, M., Schaeffer, A.J.Resolution and uncertainty in lithospheric 3-D geological models. Canada MohoMineralogy and Petrology, doi.org/10.1007/ s00710-018-0619-2. 15p.MantleGeophysics

Abstract: As three-dimensional (3-D) modelling of the subcontinental mantle lithosphere is increasingly performed with ever more data and better methods, the robustness of such models is increasingly questioned. Resolution thresholds and uncertainty within deep multidisciplinary 3-D models based on geophysical observations exist at a minimum of three levels. Seismic waves and potential field measurements have inherent limitations in resolution related to their dominant wavelengths. Formal uncertainties can be assigned to grid-search type forward or inverse models of observable parameter sets. Both of these uncertainties are typically minor when compared to resolution limitations related to the density and shape of a specific observation array used in seismological or potential field surveys. Seismic wave source distribution additionally applies in seismology. A fourth, more complex level of uncertainty relates to joint inversions of multiple data sets. Using independent seismic wave phases or combining diverse methods provides another measure of uncertainty of particular physical properties. Extremely sparse xenolith suites provide the only direct correlation of rock type with observed or modelled physical properties at depths greater than a few kilometers. Here we present one case study of the Canadian Mohorovi?i? (Moho) discontinuity using only two data sets. Refracted and converted seismic waves form the primary determinations of the Moho depth, gravity field modeling provide a secondary constraint on lateral variations, the slope of the Moho, between the sparse seismic estimates. Although statistically marginal, the resulting co-kriged Moho surface correlates better with surface geology and is thus deemed superior.
DS201804-0739
2018
Sobolev, N.V.Inclusions in Siberian diamonds and their polycrystalline aggregates and specific features of orogenic diamonds from Kazkhstan.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 41-42. abstractRussiadiamond inclusions
DS201805-0978
2016
Sokolova, T.S., Dorogokupets, P.I., Dymshits, A.M., Danilov, B.S., Konstantin, D.Microsoft excel spreadsheet for calculations of P-V-T relations and thermodynamic properties from equations of state of MgO, diamond and nine other metals as pressure markers in high-pressure and high-temperature experiments.Computers & Geosciences, Vol. 94, 1, pp. 162-169.TechnologyUHP

Abstract: We present Microsoft Excel spreadsheets for calculation of thermodynamic functions and P-V-T properties of MgO, diamond and 9 metals, Al, Cu, Ag, Au, Pt, Nb, Ta, Mo, and W, depending on temperature and volume or temperature and pressure. The spreadsheets include the most common pressure markers used in in situ experiments with diamond anvil cell and multianvil techniques. The calculations are based on the equation of state formalism via the Helmholtz free energy. The program was developed using Visual Basic for Applications in Microsoft Excel and is a time-efficient tool to evaluate volume, pressure and other thermodynamic functions using T-P and T-V data only as input parameters. This application is aimed to solve practical issues of high pressure experiments in geosciences and mineral physics.
DS201803-0477
2018
Soltys, A., Giuliani, A., Phillips, D.A new approach to reconstructing the composition and evolution of kimberlite melts: a case study of the archetypal Bultfontein kimberlite ( Kimberley, South Africa).Lithos, in press available Africa, South Africadeposit - Bultfontein

Abstract: The compositions of kimberlite melts at depth and upon emplacement in the upper crust remain elusive. This can be attributed to the unquantified effects of multiple processes, such as alteration, assimilation, xenocryst contamination, and fractional crystallisation. The inability to accurately constrain the composition and physical properties of kimberlite melts prevents a comprehensive understanding of their petrogenesis. To improve constraints on the compositions of kimberlite melts, we have combined modal analysis including the discrimination of xenocrystic from magmatic phases, with mineral chemistry determinations to reconstruct a whole-rock composition. We apply this approach to a sample of “fresh” macrocrystic hypabyssal kimberlite (sample BK-1) from the Bultfontein mine (Kimberley, South Africa). The accuracy of this whole-rock reconstruction method is validated by the similarity between reconstructed and measured whole-rock compositions. A series of corrections are then applied to account for the effects of post-emplacement serpentinisation, pre-emplacement olivine crystallisation, and the inclusion and assimilation of mantle material. This approach permits discernment of melt compositions at different stages of kimberlite evolution. The primitive melt parental to the Bultfontein kimberlite is estimated to contain 17.4-19.0?wt% SiO2, 20.2-22.8?wt% MgO, 20.9-21.9?wt% CaO, 2.1-2.3?wt% P2O5, 1.2-1.4?wt% TiO2, 0.9-1.1?wt% Al2O3, and 0.6-0.7?wt% K2O, and has a Mg# of 83.4-84.4. Primary volatile contents (i.e., after an attempt to account for volatile loss) are tentatively estimated at ~2.1-2.2?wt% H2O and ~22.9-25.4?wt% CO2. This composition is deficient in SiO2, MgO and H2O, but enriched in CaO and CO2 compared with most previous estimates of primitive kimberlite melts. We suggest that the primitive melt parental to the Bultfontein kimberlite was a transitional silicate-carbonate melt, which was progressively enriched in SiO2, MgO, Al2O3, Cr2O3, and Na2O through the assimilation of lithospheric mantle material. Comparisons with experimentally produced low-degree melts of carbonated lherzolite indicate that the Bultfontein kimberlite could have formed by ~0.5% melting of asthenospheric mantle at ~6.0-8.6?GPa (i.e., ~190-285?km) and ~1400-1500?°C. The low calculated Na2O contents (<0.2?wt%), which are inconsistent with derivation from low-degree melting of lherzolite, suggest that an alkali-bearing, volatile-rich fluid was exsolved during ascent or released after emplacement, and subsequently removed.
DS201807-1527
2018
Soltys, A., Giuliani, A., Phillips, D.Crystallisation sequence and magma evolution of the De Beers dyke ( Kimberley, South Africa).Mineralogy and Petrology, June 14, DOI:10.1007/ s00710-018 -0588-5, 16p.Africa, South Africadeposit - De Beers dyke

Abstract: We present petrographic and mineral chemical data for a suite of samples derived from the De Beers dyke, a contemporaneous, composite intrusion bordering the De Beers pipe (Kimberley, South Africa). Petrographic features and mineral compositions indicate the following stages in the evolution of this dyke: (1) production of antecrystic material by kimberlite-related metasomatism in the mantle (i.e., high Cr-Ti phlogopite); (2) entrainment of wall-rock material during ascent through the lithospheric mantle, including antecrysts; (3) early magmatic crystallisation of olivine (internal zones and subsequently rims), Cr-rich spinel, rutile, and magnesian ilmenite, probably on ascent to the surface; and (4) crystallisation of groundmass phases (i.e., olivine rinds, Fe-Ti-rich spinels, perovskite, apatite, monticellite, calcite micro-phenocrysts, kinoshitalite-phlogopite, barite, and baddeleyite) and the mesostasis (calcite, dolomite, and serpentine) on emplacement in the upper crust. Groundmass and mesostasis crystallisation likely forms a continuous sequence with deuteric/hydrothermal modification. The petrographic features, mineralogy, and mineral compositions of different units within the De Beers dyke are indistinguishable from one another, indicating a common petrogenesis. The compositions of antecrysts (i.e., high Cr-Ti phlogopite) and magmatic phases (e.g., olivine rims, magnesian ilmenite, and spinel) overlap those from the root zone intrusions of the main Kimberley pipes (i.e., Wesselton, De Beers, Bultfontein). However, the composition of these magmatic phases is distinct from those in ‘evolved’ intrusions of the Kimberley cluster (e.g., Benfontein, Wesselton water tunnel sills). Although the effects of syn-emplacement flow processes are evident (e.g., alignment of phases parallel to contacts), there is no evidence that the De Beers dyke has undergone significant pre-emplacement crystal fractionation (e.g., olivine, spinel, ilmenite). This study demonstrates the requirement for detailed petrographic and mineral chemical studies to assess whether individual intrusions are in fact ‘evolved’; and that dykes are not necessarily produced by differentiated magmas.
DS201801-0066
2017
Somani, O.P.Rare earth element applications, market outlook and Indian perspectives.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p.41-42.Indiarare earths

Abstract: Rare earth elements (REE) are a group of seventeen chemical elements that occur together in the periodic table. The group consists of yttrium and the 15 lanthanide elements (lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). Promethium does not occur in nature because it is highly and the only lanthanide which has no stable (or even long-lived) isotopes. The most stable isotope of the element is Promethium-145, a half-life of 17.7 years. Due to its very less half-life most of the Promethium might have exhausted within first 10,000 years of formation of Earth. Scandium is found in most rare earth element deposits and is sometimes classified as a rare earth element. The rare earth elements are all metals, and the group is often referred to as the "rare earth metals." These metals have many similar properties, and that often causes them to be found together in geologic deposits. They are also referred to as "rare earth oxides" because many of them are typically sold as oxide compounds. The rare earths elements are classified into two groups; Cerium Group and Yttrium group, the former consists of light rare earths ( Sc, La, Ce, Nd, Pr, Pm, Sm and Eu ). The later is composed of (Y, Gd,Tb, Dy, Ho, Er, Tm, Yb and Lu). In nature the minerals of cerium group are different then the Yttrium group. The most common light rare earth minerals are monazite and bastnasite and for the heavy rare earth element the mineral is xenotime. Rare earth elements are not as "rare" as their name implies. Thulium and lutetium are the two least abundant rare earth elements - but they each have an average crustal abundance that is nearly 200 times greater than the crustal abundance of gold. However, these metals are very difficult to mine because it is unusual to find them in concentrations high enough for economical extraction. The most abundant rare earth elements are cerium, yttrium, lanthanum and neodymium. They have average crustal abundances that are similar to commonly used industrial metals such as chromium, nickel, zinc, molybdenum, tin, tungsten, and lead. Again, they are rarely found in extractable levels. Because of their unique magnetic, luminescent, and electrochemical properties, these elements help make many technologies perform with reduced weight, emissions, and energy consumption, and give them greater efficiency, performance, miniaturization, speed, durability, and thermal stability. Rare earth-enabled products and technologies help to fuel global economic growth, maintain high standards of living, and save lives. Rare earth elements are used extensively in aerospace and defense, health care, clean energy, electronics, transportation and vehicles, catalysts, polishing industry etc. Global resources of rare earths are about 120 Mt, China tops with 44 Mt, Vietnam and Brazil both 22Mt each, Russia 18 Mt, India 6.9 Mt, Australia 3.4 Mt, USA 1.4 Mt, Greenland 1.5 Mt, Malawi, 0.136 Mt, South Africa 0.86 Mt. The major producers today are China and Australia. China producing about 105,000 tons and Australia, 14000 tons, Russia, 3000 tons, India, 1700 tons, Brazil, 1100 tons, Thailand 800 tons, Malaysia, 300 tons( based on 2016 data). In 2016, excess global supply caused prices for many rare-earth compounds and metals to decline, and China continued to dominate the global supply. In China, the rare-earth mining production quota for 2016 was set at 105,000 tons, unchanged from 2015.The major reason of price decline was the illegal mining of rare earths in China which cause pollution and other financial losses. Now China is clamping down on mining as part of a campaign to tackle pollution and tighten control of its massive industrial complex. Various measures to curb production have already driven up prices of aluminum, steel, and now rare earths. Praseodymium-neodymium oxide, a raw material for the metal, has almost doubled this year, Neodymium surged by nearly a third in August alone and is up 81 percent in 2017. Demand for some rare earths may exceed supply in the second half after the crackdown on illegal mines. The global demand for automobiles, consumer electronics, energy-efficient lighting, permanent magnets and catalysts is expected to rise rapidly over the next decade. Rare earth magnet demand is expected to increase, as is the demand for rechargeable batteries. New developments in medical technology are expected to increase the use of surgical lasers, magnetic resonance imaging, and positron emission tomography scintillation detectors. Rare earth elements are heavily used in all of these industries, so the demand for them should remain high. So far EVs and renewable energy from clean technology point of view are concerned the rare earths join with niche metals including lithium and cobalt as beneficiaries of rapid growth in the electric vehicle industry and in renewable energy in the form of permanent magnets used in gearless turbines. By 2020, the REE demand in EVs will increase from 2000 tons per year to 7000 tons per year in 2020 and 12000 tons by 2024. In India, Indian Rare Earth Ltd is planning to produce 10,000 tons REO per year. The carbonatite hosted REE deposit with non-monazite sources has also been identified in Barmer district of Rajasthan.
DS201805-0979
2018
Song, W., Xi, C., Smith, M.P., Chakhmouradian, A.R., Brenna, M., Kynicky, J., Chen, W., Yang, Y., Tang, H.Genesis of the world's largest rare earth element deposit, Bayan Obo, China: protracted mineralization evolution over ~ 1.b.y.Geology, Vol. 48, 4, pp. 323-326.Chinadeposit - Bayan Obo

Abstract: The unique, giant, rare earth element (REE) deposit at Bayan Obo, northern China, is the world’s largest REE deposit. It is geologically complex, and its genesis is still debated. Here, we report in situ Th-Pb dating and Nd isotope ratios for monazite and Sr isotope ratios for dolomite and apatite from fresh drill cores. The measured monazite ages (361-913 Ma) and previously reported whole-rock Sm-Nd data show a linear relationship with the initial Nd isotope ratio, suggesting a single-stage evolution from a Sm-Nd source that was formed before 913 Ma. All monazites show consistent ?Nd(1.3Ga) values (0.3 ± 0.6) close to those of the adjacent 1.3 Ga carbonatite and mafic dikes. The primary dolomite and apatite show lower 87Sr/86Sr ratios (0.7024-0.7030) than the recrystallized dolomite (0.7038-0.7097). The REE ores at Bayan Obo are interpreted to have originally formed as products of ca. 1.3 Ga carbonatitic magmatism and to have undergone subsequent thermal perturbations induced by Sr-rich, but REE-poor, metamorphic fluids derived from nearby sedimentary rocks.
DS201809-2094
2018
Sonin, V.M., Zhimulev, E.I., Chepurov, A.A., Chepurov, A.I., Pokhilenko, N.P.Influence of the sulfur concentration in the Fe-S melt on diamond preservation under P-T conditions of the Earth's mantle.Doklady Earth Sciences, Vol. 481, 1, pp. 922-924.Mantlegeochemistry

Abstract: The results of experiments on dissolution of diamond in a Fe melt with variable concentrations of S at high P-T parameters are presented. It is established that the maximal degree of diamond dissolution occurs at a sulfur concentration of 15 wt %. With decreasing or increasing S content, dissolution of diamond slows down and almost does not occur during the period of the experiment (60 min), when the "eutectic" composition is gained. In contrast to a pure Fe melt, the presence of S decreases the carbon solubility and, therefore, reduces the aggressiveness of metal melt in relation to diamonds, thus, stimulating their preservation in the Earth’s mantle, especially if the concentration of S exceeds that in the "eutectic" composition.
DS201804-0740
2018
Sonin, V.M., Zhimulev, E.I., Pomazanskiy, B.S., Zemnuhov, A.L., Chepurov, A.A., Afanasiev, V.P., Chepurov, A.I.Morphological features of diamond crystals dissolved in Fe0.7 S0.3 melt at 4GPa and 1400.Geology of Ore Deposits, Vol. 60, pp. 82-92.Technologydiamond morphology

Abstract: An experimental study of the dissolution of natural and synthetic diamonds in a sulfur-bearing iron melt (Fe0.7S0.3) with high P-T parameters (4 GPa, 1400°?) was performed. The results demonstrated that under these conditions, octahedral crystals with flat faces and rounded tetrahexahedral diamond crystals are transformed into rounded octahedroids, which have morphological characteristics similar to those of natural diamonds from kimberlite. It was suggested that, taking into account the complex history of individual natural diamond crystals, including the dissolution stages, sulfur-bearing metal melts up to sulfide melts were not only diamond-forming media during the early evolution of the Earth, but also natural solvents of diamond in the mantle environment before the formation of kimberlitic melts.
DS201801-0067
2017
Sorokhtina, N.V., Belyatsky, B.V., Kononkova, N.N., Rodionov, N.V., Lepkhina, E.N., Antonov, A.V., Sergeev, S.A.Pyrochlore group minerals from Paleozoic carbonatite massifs of the Kola Peninsula: composition and evolution.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 20-21.Russia, Kola Peninsulacarbonatites

Abstract: Chemical composition and evolution of pyrochlore-group minerals (Nb?Ta?Ti) from the early phoscorites and calcite carbonatites, and late rare-earth dolomite carbonatites from Seblyavr and Vuorijarvi Paleozoic massifs have been studied. There are two trends in pyrochlore composition evolution: the change of U, Ti, and Ta enriched varieties by calcium high-Nb, and the change of early calcium varieties by barium-strontium pyrochlores. The substitutions are described by the typical reactions: 2Ti4+ + U4+ ? 2Nb5+ + Ca2+; Ta5+ ? Nb5+; U4+ + v (vacancy) ? 2Ca2+. The Ca ranges in pyrochlores are explained by isomorphic occupation of the cation position A with Ba, Sr, and REE, the total concentration of which increases as the carbonatite melt evolved and reaches a maximum in rare-earth dolomite carbonatites. The formation of barium pyrochlore is mainly due to successive crystallization from the Ba and Sr enriched melt (oscillatory zoning crystals), or with the secondary replacement of grain margins of the calcium pyrochlore, as an additional mechanism of formation. High enrichments in LREE2O3 (up to 6 wt.%) are identified. The fluorine content in pyrochlore group minerals varies widely. A high concentration (up to 8 wt.%) is found in central and marginal zones of crystals from calcite carbonatites, while it decreases in the pyrochlore from dolomite carbonatites. Fluorine in the crystal lattice has sufficient stability during cation-exchange processes and it is not lost in the case of developing of late carbonatites over the earlier ones. In the late mineral populations the relics enriched by this component are observed. There is a positive correlation of fluorine with sodium. The marginal and fractured zones of pyrochlore crystals from all rock types are represented by phases with a cation deficiency in position A and an increased Si. The evolution of mineral composition depends on the alkaline-ultramafic melt crystallization differentiation, enrichment of the late melts by alkalis and alkaline earth metals at the high fluorine activity. It is determined that the fluorine sharply increases from the early pyroxenites to the carbonatite rocks of the massif. The foscorites and carbonatites of the early stages of crystallization are the most enriched in fluorine, while the late dolomite carbonatites are depleted by this component and enriched in chlorine and water. The fluorine saturation of the early stages of carbonatite melting leads to the formation of fluorapatite and pyrochlore minerals which are the main mineralsconcentrators of fluorine. Pyrochlore group minerals from the Paleozoic carbonatite complexes of the Kola Peninsula are characterized by decreasing Pb, Th and U, and Th/U ratios in the transition from the early foscorites to later calcite carbonatites and hydrothermal dolomite carbonatites. The pyrochlore age varies within the 420-320 m.y. interval (U-Pb SHRIMPII data), while the rocks of the earliest magmatic stages has an individual grain age of 423 ± 15 Ma, but pyrochlore ages for calcite and dolomite carbonatites are younger: 351 ± 8.0 Ma and 324 ± 6.1 Ma, respectively. Such a dispersion of the age data is apparently associated with a disturbed Th/U ratio due to high ability for cation-exchange processes of pyrochlore crystalline matrix including secondary transformations. The research was done within the framework of the scientific program of Russian Academy of Sciences and state contract K41.2014.014 with Sevzapnedra.
DS201810-2378
2018
Speelmanns, I.M., Schmidt, M.W., Liebske, C.Nitrogen solubility in core materials.Geophysical Research Letters, Vol. 45, 15, pp. 7434-7443. doi.org/10.1029/ 2018GLO79130Mantlenitrogen

Abstract: On the early Earth nitrogen was redistributed between three prevailing reservoirs: the core forming metal, the silicate magma ocean, and the atmosphere. To shed light on the behavior of N during core segregation, we have experimentally determined N solubilities in Fe?dominated metal melts at high temperatures and pressures (1200-1800 °C, 0.4-9.0 GPa) using high?pressure devices. Based on our experimental results a model has been developed to describe N solubility into metal melts as a function of pressure and temperature. The model suggests that core?forming metal melts can dissolve N quantities that are as high as the Earth's core density deficit. However, the N concentrations in the core?forming metal are dependent on the accretionary scenario and its partitioning with silicate magma ocean; our solubilities provide an upper limit for possible N concentrations within the Earth's core. Nevertheless, this study shows that N in the modern mantle will largely dissolve in its small metal fraction and not in the dominating silicates.
DS201803-0478
2017
Speich, L., Kohn, S.C., Wirth, R., Bulanova, G.P., Smith, C.B.The relationship between platelet size and the B' infrared peak of natural diamonds revisited. Type 1aLithos, Vol. 278-281, pp. 419-426.Technologydiamond morphology

Abstract: Platelets in diamond are extended planar defects that are thought to be generated during the nitrogen aggregation process in type Ia diamonds. They were subjected to intensive research during the 1980s and 1990s but the techniques used for observation of defects in diamond have improved since that time and new insights can be gained by further study. This study combines high resolution Fourier Transform Infrared (FTIR) analysis, with an emphasis on the main platelet peak, and transmission electron microscopic (TEM) imaging. By performing TEM and FTIR analyses on volumes of diamond that were closely spatially related it is shown that the average platelet diameter, D, follows the relationship D=ax?b where x is the position of the platelet peak in the infrared spectrum, a is a constant and b is the minimum position of the platelet peak. The best fit to the data is obtained if a value of b=1360cm?1 is used, giving a fitted value of a=221. The observed variation in infrared (IR) peak width can also be explained in terms of this relationship. Additionally, platelet morphology was found to vary according to diameter with large platelets being more elongated. The tendency to become more elongated can be described by the empirical equation AR=11.9D+19.6+0.4 where AR is the aspect ratio. Using the relationships established here, it will be possible to study platelet abundance and size as a function of parameters such as nitrogen concentration, nitrogen aggregation and diamond residence time in the mantle. This work therefore will open up new methods for constraining the geological history of diamonds of different parageneses and from different localities.
DS201804-0741
2018
Spengler, D., van Roermund, H.L.M., Drury, M.R.Deep komatiite signature in cratonic mantle pyroxenite… websterite/Rae cratonJournal of Metamorphic Geology, in press availableEurope, Greenland, Norwaymineral chemistry

Abstract: We present new and compiled whole rock modal mineral, major and trace element data from extremely melt depleted but pyroxenite and garnet(?ite) bearing Palaeoarchaean East Greenland cratonic mantle, exposed as three isolated, tectonically strained orogenic peridotite bodies (Ugelvik, Raudhaugene, Midsundvatnet) in western Norway. The studied lithologies comprise besides spinel? and/or garnet?bearing peridotite (dunite, harzburgite, lherzolite) garnet?clinopyroxenite and partially olivine?bearing garnet?orthopyroxenite and ?websterite. Chemical and modal data and spatial relationships between different rock types suggest deformation to have triggered mechanical mixing of garnet?free dunite with garnet?bearing enclosures that formed garnet?peridotite. Inclusions of olivine in porphyroclastic minerals of pyroxenite show a primary origin of olivine in olivine?bearing variants. Major element oxide abundances and ratios of websterite differ to those in rocks expected to form by reaction of peridotite with basaltic melts or silica?rich fluids, but resemble those of Archaean Al?enriched komatiite (AEK) flows from Barberton and Commondale greenstone belts, South Africa. Websterite GdN/YbN, 0.49-0.65 (olivine?free) and 0.73-0.85 (olivine?bearing), overlaps that of two subgroups of AEK, GdN/YbN 0.25-0.55 and 0.77-0.90, with each of them being nearly indistinguishable from one another in rare earth element fractionation but also concentration. Websterite MgO content is high, 22.7-29.0 wt.%, and Zr/Y is very low, 0.1-1.0. The other, non?websteritic pyroxenites overlap - when mechanically mixed together with garnetite - in chemistry with that of AEK. It follows an origin of websterite and likely all pyroxenite that involves melting of a garnet?bearing depleted mantle source. Pyroxene exsolution lamellae in the inferred solidus garnet in all lithological varieties require the pyroxenites to have crystallised in the majorite garnet stability field, at 3-4 GPa (90-120 km depth) at minimum 1600 °C. Consequently, we interpret the websterites to represent the first recognised deep plutonic crystallisation products that formed from komatiite melts. The other pyroxenitic rocks are likely fragments of such crystallisation products. An implication is that a mantle plume environment contributed to the formation of (one of) the worldwide oldest lithospheric mantle underneath the eastern Rae craton.
DS201807-1528
2018
Spengler, D., van Roermund, H.L.M., Drury, M.R.Deep komatiite signature in cratonic mantle pryoxenite.Journal of Metamorphic Geology, Vol. 36, 5, pp. 591-602.Mantlecraton

Abstract: We present new and compiled whole?rock modal mineral, major and trace element data from extremely melt depleted but pyroxenite and garnet(?ite)?bearing Palaeoarchean East Greenland cratonic mantle, exposed as three isolated, tectonically strained orogenic peridotite bodies (Ugelvik, Raudhaugene and Midsundvatnet) in western Norway. The studied lithologies comprise besides spinel? and/or garnet?bearing peridotite (dunite, harzburgite, lherzolite) garnet?clinopyroxenite and partially olivine?bearing garnet?orthopyroxenite and ?websterite. Chemical and modal data and spatial relationships between different rock types suggest deformation to have triggered mechanical mixing of garnet?free dunite with garnet?bearing enclosures that formed garnet?peridotite. Inclusions of olivine in porphyroclastic minerals of pyroxenite show a primary origin of olivine in olivine?bearing variants. Major element oxide abundances and ratios of websterite differ to those in rocks expected to form by reaction of peridotite with basaltic melts or silica?rich fluids, but resemble those of Archean Al?enriched komatiite (AEK) flows from Barberton and Commondale greenstone belts, South Africa. Websterite GdN/YbN, 0.49-0.65 (olivine?free) and 0.73-0.85 (olivine?bearing), overlaps that of two subgroups of AEK, GdN/YbN 0.25-0.55 and 0.77-0.90, with each of them being nearly indistinguishable from one another in not only rare earth element fractionation but also concentration. Websterite MgO content is high, 22.7-29.0 wt%, and Zr/Y is very low, 0.1-1.0. The other, non?websteritic pyroxenites overlap—when mechanically mixed together with garnetite—in chemistry with that of AEK. It follows an origin of websterite and likely all pyroxenite that involves melting of a garnet?bearing depleted mantle source. Pyroxene exsolution lamellae in the inferred solidus garnet in all lithological varieties require the pyroxenites to have crystallized in the majorite garnet stability field, at 3-4 GPa (90-120 km depth) at minimum 1,600°C. Consequently, we interpret the websterites to represent the first recognized deep plutonic crystallization products that formed from komatiite melts. The other pyroxenitic rocks are likely fragments of such crystallization products. An implication is that a mantle plume environment contributed to the formation of (one of) the worldwide oldest lithospheric mantle underneath the eastern Rae craton.
DS201809-2095
2018
Spetsius, Z.V., Bogush, I.N.Pecularities of diamonds in eclogitic xenoliths from the Komsomolskaya pipe, Yakutia.Doklady Earth Sciences, Vol. 480, 1, pp. 666-670.Russiadeposit - Komsomolskaya

Abstract: The first studies of diamonds in eclogitic xenoliths from the Komsomolskaya kimberlite pipe are described. Among round and oval-shaped xenoliths with diamond ingrowths, samples with a garnet content of 40-90% of the xenolith volume dominate. Two eclogite samples contain grains of accessory rutile; a kyanite sample is also revealed. Certain samples contain two or more crystals of diamonds. Diamonds with an octahedral habit and crystals with transitional habits, which belong to an octahedral-rhombic dodecahedral row, dominate in eclogites; there are many variety VIII aggregates. A high concentration of structural nitrogen, commonly in the A form, was registered in most of the crystals. Diamonds with a small content of nitrogen impurities, 40-67% in the B1 form, are present in a number of xenoliths. The calculated temperatures of the formation of eclogitic xenoliths is 1100-1300°C. Diversity in the impurity compositions of diamonds in the same xenolith shows that these diamonds were formed at various times and in different settings. The diamond position in xenoliths, the various level of nitrogen aggregation in the diamonds, and a number of other factors point to the later formation of the diamonds, as compared to minerals of eclogites, from fluid or fluid-melts in the process of metasomatosis.
DS201804-0742
2018
Spetsius, Z.V., Bogush, I.N., Ivanov, A.S.Xenolith of eclogites with diamonds from the Yubileinaya kimberlite pipe.Doklady Earth Sciences, Vol. 478, 1, pp. 88-91.Russia, Yakutiadeposit - Yubilienaya

Abstract: The first results of study of minerals and diamonds of diamond-bearing eclogites from kimberlites of the Yubileinaya pipe with a variable percent amount of clinopyroxene and garnet are presented. Samples with a garnet content from 30 to 90% of the xenolith volume are dominant among the round to oval xenoliths with diamonds. Five eclogite samples contain grains of accessory rutile, as well as corundum and kyanite. Some samples host two or more diamond crystals.
DS201810-2379
2018
Spivak, A.V., Litvin, Y.A.Evolution of magmatic and diamond forming systems of the Earth's Lower Mantle.Springer, 108p. ISBN 978-3319785172Mantlemagmatism

Abstract: This book sheds valuable new light on the genetic mineralogy of lower-mantle diamonds and syngenetic minerals. It presents groundbreaking experimental results revealing the melting relations of ultrabasic and basic associations and a physicochemical peritectic mechanism of their evolution. The experimental investigations included here reveal the key multicomponent, multiphase oxide-silicate-carbonate-carbon parental media for lower-mantle diamonds and syngenetic minerals. Consequently, readers will find extensive information on the diamond-parental oxide-silicate-carbonate-carbon melts-solutions that supplement the general features of lower-mantle diamond genesis and the most efficient ultrabasic-basic evolution. The experimental results on physicochemical aspects, combined with analytical mineralogy data, make it possible to create a generalized composition diagram of the diamond-parental melts-solutions, there by completing the mantle-carbonatite concept for the genesis of lower-mantle diamonds and syngenetic minerals. This book addresses the needs of all researchers studying the Earth’s deepest structure, super-deep mineral formation including diamonds, and magmatic evolution.
DS201810-2380
2018
Srinivasan, A.What termites can teach us. Roboticists are fascinated by their 'swarm intelligence', biologists by their ability to turn grass into energy. But can humans replicate their achievements?TheNewYorker.com, Sept. 17, 10p. Globaltermites
DS201804-0743
2018
Stachel, T.Formation of diamond in Earth's mantle.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 43-44. abstractMantlediamond inclusions
DS201806-1255
2018
Stachel, T., Banas, A., Aulbach, S., Smit, K.V., Wescott, P., Chinn, I.L.The Victor mine ( Superior Craton, Canada): Neoproterozoic lherzolitic diamonds from a thermally-modified cratonic root.Mineralogy and Petrology, in press available, 12p.Canada, Ontario, Attawapiskatdeposit - Victor

Abstract: The Jurassic Victor kimberlite (Attawapiskat Field) was emplaced into an area of the central Superior Craton that was affected by a lithosphere-scale thermal event at ~1.1 Ga. Victor diamonds formed ca. 400 million years after this event, in a lithospheric mantle characterized by an unusually cool model geotherm (37-38 mW/m2; Hasterok and Chapman 2011). The bulk of Victor diamonds derives from a thin (<10 km thick) layer that is located at about 180 km depth and represents lherzolitic substrates (for 85% of diamonds). Geothermobarometric calculations (average pressure and temperature at the 1 sigma level are 57?±?2 kbar and 1129?±?16 °C) coupled with typical fluid metasomatism-associated trace element patterns for garnet inclusions indicate diamond precipitation under sub-solidus (lherzolite + H2O) conditions. This conclusion links the presence of a diamond-rich lherzolitic layer in the lithospheric mantle, just above the depth where ascending melts would freeze, to the unusually low paleogeotherm beneath Attawapiskat, because along an average cratonic geotherm (40 mW/m2) lherzolite in the presence of hydrous fluid would melt at depths >140 km.
DS201812-2887
2018
Stachel, T., Harris, J.W., Hunt, L., Muehlenbachs, K., Kobussen, A.F., Edinburgh Ion Micro-Probe facilityArgyle deposit: Argyle diamonds: how subduction along the Kimberley craton edge generated the world's biggest diamond deposit.Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 145-168.Australia, western Australiadeposit - Argyle
DS201812-2888
2018
Stagno, V., Stopponi, V., Kono, Y., Manning, C.E., Irifune, T.Experimenal determination of the viscosity of Na2CO3 melt between 1.7 and 4.6 Gpa at 1200-1700 C: implications for the rheology of carbonatite magmas in the Earth's upper mantle.Chemical Geology, Vol. 501, pp. 19-25.Mantlecarbonatite

Abstract: Knowledge of the rheology of molten materials at high pressure and temperature is required to understand magma mobility and ascent rate at conditions of the Earth's interior. We determined the viscosity of nominally anhydrous sodium carbonate (Na2CO3), an analogue and ubiquitous component of natural carbonatitic magmas, by the in situ “falling sphere” technique at 1.7, 2.4 and 4.6?GPa, at 1200 to 1700?°C, using the Paris-Edinburgh press. We find that the viscosity of liquid Na2CO3 is between 0.0028?±?0.0001?Pa•s and 0.0073?±?0.0001?Pa•s in the investigated pressure-temperature range. Combination of our results with those from recent experimental studies indicate a negligible dependence on pressure from 1?atm to 4.6?GPa, and a small compositional dependence between molten alkali metal-bearing and alkaline earth metal-bearing carbonates. Based on our results, the viscosity of Na2CO3 is consistent with available viscosity data of both molten calcite (determined at high pressure and temperature) and Na2CO3 at ambient pressure. Molten Na2CO3 is a valid experimental analogue for study of the rheology of natural and/or synthetic near-solidus carbonatitic melts. Estimated values of the mobility and ascent velocity of carbonatitic melts at upper conditions are between 70 and 300?g?cm?3•Pa?1•s?1 and 330-1450?m•year?1, respectively, when using recently proposed densities for carbonatitic melts. The relatively slow migration rate allows magma-rock interaction over time causing seismic anomalies and chemical redox exchange.
DS201810-2381
2018
Stamm, N., Schmidt. M.W., Szymanowski, D., von Quadt, A., Mohapi, T., Fourie, A.Primary petrology, mineralogy and age of the Letseng-la-Terae kimberlite ( Lesotho), southern Africa) and parental magmas of Group 1 kimberlites.Contributions to Mineralogy and Petrology, Vol. 173, pp. 76- doi.org/10.1007/ s00410-018-1502-1Africa, Lesothodeposit - Letseng

Abstract: The Letšeng-la-Terae kimberlite (Lesotho), famous for its large high-value diamonds, has five distinct phases that are mined in a Main and a Satellite pipe. These diatreme phases are heavily altered but parts of a directly adjacent kimberlite blow are exceptionally fresh. The blow groundmass consists of preserved primary olivine with Fo86?88, chromite, magnesio-ulvöspinel and magnetite, perovskite, monticellite, occasional Sr-rich carbonate, phlogopite, apatite, calcite and serpentine. The bulk composition of the groundmass, extracted by micro-drilling, yields 24-26 wt% SiO2, 20-21 wt% MgO, 16-19 wt% CaO and 1.9-2.1 wt% K2O, the latter being retained in phlogopite. Without a proper mineral host, groundmass Na2O is only 0.09-0.16 wt%. However, Na-rich K-richterite observed in orthopyroxene coronae allows to reconstruct a parent melt Na2O content of 3.5-5 wt%, an amount similar to that of highly undersaturated primitive ocean island basanites. The groundmass contains 10-12 wt% CO2, H2O is estimated to 4-5 wt%, but volatiles and alkalis were considerably reduced by degassing. Mg# of 77.9 and 530 ppm Ni are in equilibrium with olivine phenocrysts, characterize the parent melt and are not due to olivine fractionation. 87Sr/86Sr(i)?=?0.703602-0.703656, 143Nd/144Nd(i)?=?0.512660 and 176Hf/177Hf(i)?=?0.282677-0.282679 indicate that the Letšeng kimberlite originates from the convective upper mantle. U-Pb dating of groundmass perovskite reveals an emplacement age of 85.5?±?0.3 (2?) Ma, which is significantly younger than previously proposed for the Letšeng kimberlite.
DS201808-1790
2017
Stan, C.V., Obannon, E.F., Dobrzhinetskaya, L.F., Tamura, N.Polytypism in natural SiC using Laue microdiffraction.Acta Crystallographia, A70, 1p. abstractEurope, Israelmoissanite

Abstract: Silicon carbide (SiC, moissanite) is a common industrial material that is rarely found in terrestrial rocks and meteorites. It has been found to adopt over 300 different crystal structures, most of which are polytypic: they consist of alternating layers of Si and C, with only small stacking faults or shears distinguishing them from one another. In nature, only a few polytypes of SiC have been found, primarily a cubic zincblende type (3C-SiC), several hexagonal wurtzite types (4H-SiC and 6H-SiC), and a rhombohedral type (15R-SiC). Our natural silicon carbide sample is from a Miocene tuff (Yizre’el Valley, Israel) related to interplate alkaline basalt volcanism. Three SiC grains with native silicon and metal silicide inclusions were analyzed using Raman spectroscopy and synchrotron Laue X-ray microdiffraction accompanied by mapping at a 5-8 um resolution. SiC is found to crystallize in only the 4H and 6H polytypes. Due to the crystal orientation of the grains, as well as the significant difference in the c-axis length (~10 vs. ~15 um in 4H and 6H respectively), we were able to unambiguously assign polytypes to each diffraction pattern. Each grain contains large areas where one polytype dominates as a single crystal. In some cases, multiple stacking faults and misoriented polycrystalline aggregates of SiC occur at the 4H/6H interface. In other cases we see intercalation of the 4H and 6H crystals throughout the diffracting volume without a significant change in their crystallographic axes orientation, pointing to a possibly incommensurate crystal structure. Stress and strain are also mapped for all three grains, showing a slight (< 2 ppt) compressive strain in the y direction of all three grains, and a tensile strain in the x and z directions. In the SiC-2 grain, a mostly single-crystalline Si inclusion was found, with an exposed surface diameter of ~30 um. We examine residual strain in Si by both Laue X-ray diffraction and Raman spectroscopy, and find results to generally agree between the two measurements.
DS201801-0068
2017
Stark, J.C., Wang, X-C., Denyszyn, S.W., Li, Z-X., Rasmusson, B., Zi, J-W., Sheppard, S., Liu, Y.Newly identified 1.89 Ga mafic dyke swarm in the Archean Yilgarn craton, Western Australia suggests a connection to India.Precambrian Research, in press available 47p.Australia, Indiacraton - Yilgarn

Abstract: The Archean Yilgarn Craton in Western Australia is intruded by numerous mafic dykes of varying orientations, which are poorly exposed but discernible in aeromagnetic maps. Previous studies have identified two craton-wide dyke swarms, the 2408?Ma Widgiemooltha and the 1210?Ma Marnda Moorn Large Igneous Provinces (LIP), as well as limited occurrences of the 1075?Ma Warakurna LIP in the northern part of the craton. We report here a newly identified NW-trending mafic dyke swarm in southwestern Yilgarn Craton dated at 1888?±?9?Ma with ID-TIMS U-Pb method on baddeleyite from a single dyke and at 1858?±?54?Ma, 1881?±?37 and 1911?±?42?Ma with in situ SHRIMP U-Pb on baddeleyite from three dykes. Preliminary interpretation of aeromagnetic data indicates that the dykes form a linear swarm several hundred kilometers long, truncated by the Darling Fault in the west. This newly named Boonadgin dyke swarm is synchronous with post-orogenic extension and deposition of granular iron formations in the Earaheedy basin in the Capricorn Orogen and its emplacement may be associated with far field stresses. Emplacement of the dykes may also be related to initial stages of rifting and formation of the intracratonic Barren Basin in the Albany-Fraser Orogen, where the regional extensional setting prevailed for the following 300?million years. Recent studies and new paleomagnetic evidence raise the possibility that the dykes could be part of the coeval 1890?Ma Bastar-Cuddapah LIP in India. Globally, the Boonadgin dyke swarm is synchronous with a major orogenic episode and records of intracratonic mafic magmatism on many other Precambrian cratons.
DS201811-2609
2018
Stark, J.C., Wilde, S.A., Soderlund, U., Li, Z-X., Rasmussen, B., Zi, J-W.First evidence of Archean mafic dykes at 2.62 Ga in the Yilgarn Craton, Western Australia: links to cratonisation and the Zimbabwe craton.Precambrian Research, Vol. 317, pp. 1-13.Australia, Africa, Zimbabwecraton

Abstract: The Archean Yilgarn Craton in Western Australia hosts at least five generations of Proterozoic mafic dykes, the oldest previously identified dykes belonging to the ca. 2408-2401?Ma Widgiemooltha Supersuite. We report here the first known Archean mafic dyke dated at 2615?±?6?Ma by the ID-TIMS U-Pb method on baddeleyite and at 2610?±?25?Ma using in situ SHRIMP U-Pb dating of baddeleyite. Aeromagnetic data suggest that the dyke is part of a series of NE-trending intrusions that potentially extend hundreds of kilometres in the southwestern part of the craton, here named the Yandinilling dyke swarm. Mafic magmatism at 2615?Ma was possibly related to delamination of the lower crust during the final stages of assembly and cratonisation, and was coeval with the formation of late-stage gold deposit at Boddington. Paleogeographic reconstructions suggest that the Yilgarn and Zimbabwe cratons may have been neighbours from ca. 2690?Ma to 2401?Ma and if the Zimbabwe and Kaapvaal cratons amalgamated at 2660-2610?Ma, the 2615?Ma mafic magmatism in the southwestern Yilgarn Craton may be associated with the same tectonic event that produced the ca. 2607-2604?Ma Stockford dykes in the Central Zone of the Limpopo Belt. Paleomagnetic evidence and a similar tectonothermal evolution, including coeval low-pressure high-temperature metamorphism, voluminous magmatism, and emplacement of mafic dykes, support a configuration where the northern part of the Zimbabwe Craton was adjacent to the western margin of the Yilgarn Craton during the Neoarchean. Worldwide, reliably dated mafic dykes of this age have so far been reported from the Yilgarn Craton, the Limpopo Belt and the São Francisco Craton.
DS201811-2610
2018
Stein, S., Stein, C.A., Elling, R., Kley, J., Keller, G.R., Wysession, M., Rooney, T., Frederiksen, A., Moucha, R.Insights from North America's failed Midcontinent Rift into the evolution of continental rifts and passive continental margins.Tectonophysics, Vol. 744, pp. 403-421.United Statestectonics

Abstract: Continental rifts evolve along two possible paths. In one, a rift successfully evolves into seafloor spreading, leaving the rift structures buried beneath thick sedimentary and volcanic rocks at a passive continental margin. Alternatively, the rift fails and remains as a fossil feature within a continent. We consider insights into these processes from studies of North America's Midcontinent Rift (MCR). The MCR combines the linear geometry of a rift formed at a plate boundary and the huge igneous rock volume of a Large Igneous Province. The rift is a fault bounded basin filled with volcanics and sediments, which record a history of extension, volcanism, sedimentation, subsidence, and inversion. The MCR came close to evolving into an oceanic spreading center, but it instead failed and thus records a late stage of rifting. It thus preserves a snapshot of a stage of the process by which actively extending rifts, characterized by upwelling mantle and negative gravity anomalies, evolve either into failed and often inverted rifts without upwelling mantle and positive gravity anomalies or into passive continental margins. Many rifts can be viewed as following a generally similar evolutionary sequence, within which a complex combination of factors control the variability of structures within and among rifts. Study of the MCR also gives insight into passive continental margins. The MCR gives a snapshot of deposition of a thick, dense, and highly magnetized volcanic section during rifting. Surface exposures, seismic, and gravity data delineate a rift basin filled by inward dipping flood basalt layers, underlain by thinned and underplated crust. The fact that the MCR shows many features of a rifted volcanic margin suggests that it came close to continental breakup before it failed, and illustrates how many passive margin features form prior to breakup.
DS201801-0069
2017
Stern, R.J., Gerya, T.Subduction initiation in nature and models: a review.Tectonophysics, in press available, 26p.Mantlesubduction

Abstract: How new subduction zones form is an emerging field of scientific research with important implications for our understanding of lithospheric strength, the driving force of plate tectonics, and Earth's tectonic history. We are making good progress towards understanding how new subduction zones form by combining field studies to identify candidates and reconstruct their timing and magmatic evolution and undertaking numerical modeling (informed by rheological constraints) to test hypotheses. Here, we review the state of the art by combining and comparing results coming from natural observations and numerical models of SI. Two modes of subduction initiation (SI) can be identified in both nature and models, spontaneous and induced. Induced SI occurs when pre-existing plate convergence causes a new subduction zone to form whereas spontaneous SI occurs without pre-existing plate motion when large lateral density contrasts occur across profound lithospheric weaknesses of various origin. We have good natural examples of 3 modes of subduction initiation, one type by induced nucleation of a subduction zone (polarity reversal) and two types of spontaneous nucleation of a subduction zone (transform collapse and plumehead margin collapse). In contrast, two proposed types of subduction initiation are not well supported by natural observations: (induced) transference and (spontaneous) passive margin collapse. Further work is therefore needed to expand on and understand the implications of these observations. Our future advancing understanding of SI will come from better geologic insights, laboratory experiments, and numerical modeling, and with improving communications between these communities.
DS201804-0744
2018
Stern, R.J., Li, S-M., Keller, G.R.Continental crust of China: a brief guide for the perplexed.Earth Science Reviews, Vol. 179, pp. 72-94.Chinacraton

Abstract: China covers approximately 10?million?km2 and its crust has a complicated evolution of amalgamation, igneous activity, and sedimentation. Many studies address various aspects of China's crust, but few provide a simple geological and geophysical overview that is accessible to students and non-specialists; Filling this void is the objective of this review. China is characterized by thick (40-75?km) crust in the west due to Cenozoic collision with India and thin (30-40?km thick) crust in the east due to E-W Mesozoic-Cenozoic backarc extension. In contrast, overall crustal fabric trends E-W, defined by ophiolite belts and ultra-high pressure metamorphic rocks. This crustal fabric indicates that China has grown like a sandwich, with crust progressively added through Phanerozoic time by closing various E-W oriented Tethys oceans and seaways. In map view, China consists of five E-W trending tiers. Tier 1 is defined by the Central Asian Orogenic Belt (CAOB) along the northern margin of China, which consists of the Xing'an-Mongolia orogenic belt in the NE and the Tianshan Orogen in the NW. The CAOB formed during ~1000?Ma to ~250?Ma and is an accretionary orogen of mostly Paleozoic age that formed through closure of the Paleo-Asian Ocean and collision between the Siberian Craton and Archean-Paleoproterozoic crust to the south, which constitutes Tier 2. The CAOB has a strong aeromagnetic signature. Sediments from the Amur River show detrital U-Pb zircon age peaks at 2.8-2.3?Ga, 1.8?Ga, 450-250?Ma, and 200-100?Ma, which is expected for erosion of the Xing'an-Mongolia belt. Tier 1 igneous rocks are mainly Paleozoic except in the NE (Xing'an-Mongolia orogenic belt) and reflect subduction of the Paleo-Asian Ocean and associated accretion events, whereas Paleozoic CAOB crust in the east is overprinted by Jurassic and Cretaceous igneous rocks related to subduction of ancient Pacific basin oceanic lithosphere. Tier 2 includes the North China Craton (NCC) to the east and Tarim Craton to the west. The NCC contains the oldest rocks in China and is dominated by Archean and Paleoproterozoic ages. The extent of Archean rocks in the NCC may have been overestimated, as suggested by detrital zircons from the Yellow River, which flows across the craton, showing age peaks at 2.5-2.2?Ga, ~1.9?Ga, 500-400?Ma, and 300-200?Ma. The Tarim Craton is dominated by Palaeoproterozoic- Mesoproterozoic metamorphic strata along with a significant proportion of Neoproterozoic (~0.8?Ga) rocks. U-Pb ages for detrital zircons from Tarim River sediments reflect this basement geology, with strong peaks of Early and Late Paleozoic age, less abundant Neoproterozoic ages, and scattered ages back to the Archean. The NCC also was affected by abundant Mesozoic igneous activity with voluminous Early Cretaceous rocks that are associated with lithospheric thinning and decratonization. Tier 3 - also known as the Central China Orogen - is composed of the Sulu-Dabie-Qinling-Kunlun Orogen and records closing of an arm of Prototethys during the Ordovician to Silurian and Paleotethys during the Triassic. Tier 3 contains one of Earth's three giant ultra-high pressure (UHP) terranes with well-documented peak metamorphism of 650-850?°C and 4?GPa, indicating that some of these rocks were deeply subducted and then exhumed from depths of over 120?km in Triassic time. Tier 3 magmatism occurred in two episodes, early-middle Paleozoic and Triassic. Tier 4 contains blocks rifted from Gondwana, which include the Songpan-Ganzi, Qiangtang, and Lhasa terranes of Tibet in the west and the South China Block in the east. These terranes are marked by broad magnetic anomalies with a NE-SW trend along the Pacific margin, and a broad N-S trending anomaly between Tibet and South China. The South China Block is made up of Proterozoic and minor Archean crust of the Yangtze and Cathaysia blocks, which collided at 1.0-0.8?Ga to form the Jiangnan Orogen and the South China Block. Age spectra for detrital zircons from the Yangtze and Pearl Rivers shows major peaks at ~1.8?Ga, 900-800?Ma, ~400?Ma, and 300-150?Ma, which is consistent with the age of South China Block crust. Early-Middle Paleozoic igneous rocks are also found in South China. Mesozoic igneous rocks are widespread in both South China and Tibet and are related to subduction of the Paleo-Pacific and Tethyan oceanic plates, respectively. The accretion of Tibetan terranes to southern Eurasia occurred in the Mesozoic before collision with India at ~55?Ma. Tier 5 is represented by the island of Taiwan on the SE margin of China and marks where China crust continues to grow. Taiwan lies on a complex convergent boundary between the South China Block to the NW, the Philippine Sea Plate to the SE, and the Sunda Plate to the SW.
DS201804-0745
2017
Stern, R.J., Miller, N.R.Did the transition to plate tectonics cause Neoproterozoic Snowball Earth?Terra Nova, pp. 87-94.Mantletectonics

Abstract: When Earth's tectonic style transitioned from stagnant lid (single plate) to the modern episode of plate tectonics is important but unresolved, and all lines of evidence should be considered, including the climate record. The transition should have disturbed the oceans and atmosphere by redistributing continents, increasing explosive arc volcanism, stimulating mantle plumes and disrupting climate equilibrium established by the previous balance of silicate?weathering greenhouse gas feedbacks. Formation of subduction zones would redistribute mass sufficiently to cause true polar wander if the subducted slabs were added in the upper mantle at intermediate to high latitudes. The Neoproterozoic Snowball Earth climate crisis may reflect this transition. The transition to plate tectonics is compatible with nearly all proposed geodynamic and oceanographic triggers for Neoproterozoic Snowball Earth events, and could also have contributed to biological triggers. Only extraterrestrial triggers cannot be reconciled with the hypothesis that the Neoproterozoic climate crisis was caused by a prolonged (200-250 m.y.) transition to plate tectonics.
DS201806-1256
2018
Stern, R.J., Miller, N.R.Did the transition to plate tectonics cause Neoproterozoic Snowball Earth?Terra Nova, Vol. 30, 2, pp. 87-94.Mantletectonics

Abstract: When Earth's tectonic style transitioned from stagnant lid (single plate) to the modern episode of plate tectonics is important but unresolved, and all lines of evidence should be considered, including the climate record. The transition should have disturbed the oceans and atmosphere by redistributing continents, increasing explosive arc volcanism, stimulating mantle plumes and disrupting climate equilibrium established by the previous balance of silicate?weathering greenhouse gas feedbacks. Formation of subduction zones would redistribute mass sufficiently to cause true polar wander if the subducted slabs were added in the upper mantle at intermediate to high latitudes. The Neoproterozoic Snowball Earth climate crisis may reflect this transition. The transition to plate tectonics is compatible with nearly all proposed geodynamic and oceanographic triggers for Neoproterozoic Snowball Earth events, and could also have contributed to biological triggers. Only extraterrestrial triggers cannot be reconciled with the hypothesis that the Neoproterozoic climate crisis was caused by a prolonged (200-250 m.y.) transition to plate tectonics.
DS201810-2382
2013
Stiefenhofer, J.The use of chemical and metallurgical parameters to enhance the economic value of kimberlite resource models. The Southern African Institute of Mining and Metallurgy Diamonds - from source to use 2013, 9p. Pdf researchgateAfrica, Angola, South Africadeposit - Mulepe, Voorspoed

Abstract: Construction of geological models for kimberlites has historically largely been based on visual volcanic textures and features, with chemical data only produced on an ad-hoc basis depending on the level of perceived complexity observed in the geological data. The focus of this manuscript is a high-level mineral resource management view of the impact which the initial absence of proper chemical data had on two kimberlite resource models as well as the increasing magnitude of the problem caused by the lack of chemical data once the resource estimation process commenced. The impact of the absence of chemical data on projects where micro-diamond estimation techniques are employed is also discussed. Metallurgical parameters have historically not been incorporated into kimberlite resource models, but recent work at De Beers Group Services has shown that geostatistical quantification of the DMS (Dense Media Separator) yield is useful for mine planning purposes, and will add value in the understanding of the kimberlite emplacement process. A case study is presented where a geostatistical analysis and conditional simulation was performed on the DMS yield in a kimberlite at a local block scale. These data were used to identify mining blocks where the DMS yield would exceed the capability of the treatment plant.
DS201808-1791
2018
Stiefenhofer, J., Thurston, M., Bush, D.Microdiamond grade as a regionalized variable - some basic requirements for successful local microdiamond resource estimation of kimberlite. ( eg Snap Lake) PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 16 ppts.Globalmicrodiamond
DS201805-0980
2018
Stiefenhofer, J., Thurston, M.L., Bush, D.E.Microdiamond grade as a regionalised variable - some basic requirements for successful local microdiamond resource estimation of kimberlites.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0566-y 12p.Globalmicrodiamonds

Abstract: Microdiamonds offer several advantages as a resource estimation tool, such as access to deeper parts of a deposit which may be beyond the reach of large diameter drilling (LDD) techniques, the recovery of the total diamond content in the kimberlite, and a cost benefit due to the cheaper treatment cost compared to large diameter samples. In this paper we take the first step towards local estimation by showing that micro-diamond samples can be treated as a regionalised variable suitable for use in geostatistical applications and we show examples of such output. Examples of microdiamond variograms are presented, the variance-support relationship for microdiamonds is demonstrated and consistency of the diamond size frequency distribution (SFD) is shown with the aid of real datasets. The focus therefore is on why local microdiamond estimation should be possible, not how to generate such estimates. Data from our case studies and examples demonstrate a positive correlation between micro- and macrodiamond sample grades as well as block estimates. This relationship can be demonstrated repeatedly across multiple mining operations. The smaller sample support size for microdiamond samples is a key difference between micro- and macrodiamond estimates and this aspect must be taken into account during the estimation process. We discuss three methods which can be used to validate or reconcile the estimates against macrodiamond data, either as estimates or in the form of production grades: (i) reconcilliation using production data, (ii) by comparing LDD-based grade estimates against microdiamond-based estimates and (iii) using simulation techniques.
DS201812-2889
2018
Stirling, R.A., Kelley, S.E., Ross, M., Elliott, B., Normandeau, P.X.Surface and subsurface till characteristics in a drumlin field south of Lac de Gras, NT; implications for drift prospecting. ( Dominion's Ekati and North Arrow)2018 Yellowknife Geoscience Forum , p. 80. abstractCanada, Northwest Territoriesdeposit - Ekati

Abstract: Successful diamond exploration is becoming increasingly challenging as the best expressed targets have been found. Areas of variable drift thickness and heterogeneous surficial deposits present several challenges to exploration. One particular aspect that is poorly understood is the effect of well-developed drumlin fields on the surface expression of dispersal trains. Our study focuses on drumlin fields and their potential effects in the expression of a dispersal pattern. Because drumlins are often stratified we hypothesize that multiple till layers of contrasting provenance, representing multiple ice-flow directions, can occur at the surface across drumlin fields due to erosional processes. This has the potential to affect analysis and interpretation of surficial till dispersion data. To test this hypothesis, we examined data from a large RC drilling dataset donated by Dominion Diamond Ekati Corp. and North Arrow Minerals Inc. and complemented it with field-based surficial geology observations and analysis of additional surficial till samples across targeted drumlins. The surficial samples were collected at the top and on the sides of drumlins to test whether any glacial stratigraphy is expressed, especially in areas where post-glacial erosion may have exposed internal drumlin stratigraphy. Based on the RC data and available maps drift thickness within the drumlin field ranges from 1 meter in the swales between drumlins to about 20 meters on the top of the highest amplitude drumlins. Locally measured ice-flow indicators (n=11) show three distinct ice-flow directions from older to youngest: 260, 290, 305 degrees. Preliminary analysis of textural and compositional data shows variations within the till at depth as well as across the drumlin field. Ongoing work focuses on determining the relationship (or lack thereof) between till characteristics, drumlins, and ice flow history (till provenance), as well as on three-dimensional dispersal patterns of kimberlite indicator minerals and related geochemical pathfinders. This work will highlight landform feature considerations by using multiple parameters to analyze sample data in areas with complex glacial geology and high diamond potential.
DS201810-2383
2018
Stocklmayer, S.Hexagonal etch pits on a diamond crystal from western Australia. ArgyleThe Australian Gemmologist, Vol. 26, 9-10. p. 249.Australiadeposit - Argyle

Abstract: Many kimberlite ore bodies are relatively small, and the presence of overburden along with the complexities of interpreting geophysical data can make it challenging to intersect a kimberlite target during exploration drilling. However, the analysis of country rock drill core from the perimeter of several known kimberlites provides evidence that subtle alteration (hydration) halos around kimberlites exist, which can be detected using rapid and cost-effective spectroscopic techniques. Identification of these hydration halos, which are independent of country rock composition, may provide crucial information about the presence of undiscovered kimberlite in an exploration area, especially if kimberlite was not intersected during initial drilling. Preliminary estimates suggest that these hydration halos, which are most likely caused by kimberlite-derived hydrous fluids, can extend more than 65 meters into the country rocks, but their size strongly depends on the size of the kimberlite body. Narrow kimberlite dikes produce much smaller halos compared to large kimberlite pipes. In addition, hydration halos in carbonate rocks appear to be smaller compared to silicate rocks .
DS201807-1529
2015
Stocklmayer, V.and S.A review of diamonds in Zimbabwe - a century on. Part 1.Geological Society of Zimbabwe Newsletter, Oct. pp. 4-11.Africa, Zimbabwedeposit - overview
DS201807-1530
2016
Stocklmayer, V.and S.A review of diamonds in Zimbabwe - a century on. Part 2.Geological Society of Zimbabwe Newsletter, Feb. pp. 6-15.Africa, Zimbabwedeposit - Marange
DS201803-0479
2017
Strati, V., Wipperfurth, S.A., Baldoncini, M., McDonough, W.F., Mantovani, F.Perceiving the crust in 3-D: a model integrating geological, geochemical and geophysical data.Geochemistry, Geophysics, Geosystems G3, pp. 4326-Mantlegeophysics

Abstract: Regional characterization of the continental crust has classically been performed through either geologic mapping, geochemical sampling, or geophysical surveys. Rarely are these techniques fully integrated, due to limits of data coverage, quality, and/or incompatible data sets. We combine geologic observations, geochemical sampling, and geophysical surveys to create a coherent 3-D geologic model of a 50 × 50 km upper crustal region surrounding the SNOLAB underground physics laboratory in Canada, which includes the Southern Province, the Superior Province, the Sudbury Structure, and the Grenville Front Tectonic Zone. Nine representative aggregate units of exposed lithologies are geologically characterized, geophysically constrained, and probed with 109 rock samples supported by compiled geochemical databases. A detailed study of the lognormal distributions of U and Th abundances and of their correlation permits a bivariate analysis for a robust treatment of the uncertainties. A downloadable 3-D numerical model of U and Th distribution defines an average heat production of math formula µW/m3, and predicts a contribution of math formula TNU (a Terrestrial Neutrino Unit is one geoneutrino event per 1032 target protons per year) out of a crustal geoneutrino signal of math formula TNU. The relatively high local crust geoneutrino signal together with its large variability strongly restrict the SNO+ capability of experimentally discriminating among BSE compositional models of the mantle. Future work to constrain the crustal heat production and the geoneutrino signal at SNO+ will be inefficient without more detailed geophysical characterization of the 3-D structure of the heterogeneous Huronian Supergroup, which contributes the largest uncertainty to the calculation.
DS201804-0746
2018
Su, S-H., Uang, Y., Qu, S., Liu, R., Li, L.Microdiamond/PLA ( Polylactic acid) composites with enhanced thermal conductivity through improving filler/matrix interface compatibility.Diamond & Related Materials, Vol. 81, pp. 161-167.Technologymicrodiamonds

Abstract: Polylactic acid (PLA)-based composites filled with 20 or 50 ?m-diameter microdiamond are synthesized by hot pressing. Through improving the interface compatibility between the filler and the matrix enabled by octadecylamine (ODA) coating on the microdiamond particles, the maximum thermal conductivity of the composites is 2.22 Wm? 1 K? 1, which is a ~ 10-fold increase in comparison with that of pure PLA. According to the analysis on the glass transmission of the composites and the surface chemistry of the fillers using DSC, FI-IR, and Raman microscopy, it is found out that ODA is connected with the -OH group on the microdiamond surface through hydrogen bonding and an interfacial structure of PLA/ODA/microdiamond is formed. Thus, the interfacial thermal transport between PLA and microdiamond is significantly improved, leading to the enhancement of the thermal conductivity of the composites. Our work presents a simple method to modify the surface chemistry of microdiamond and to improve the interface compatibility between microdiamond and PLA. The microdiamond/PLA composites with large thermal conductivity are promising thermal management materials used for modern electronic products.
DS201812-2890
2019
Sun, C., Dasgupta, R.Slab mantle interaction, carbon transport, and kimberlite generation in the deep upper mantle.Earth and Planetary Science Letters, Vol. 506, pp. 38-52.Mantlekimberlite genesis

Abstract: Low-degree partial melts from deeply subducted, carbonated ocean crust are carbonatite liquids with ?35-47 wt% CO2. Their reactions with the overlying mantle regulate the slab-mantle interaction and carbon transport in the deep upper mantle but have not been investigated systematically. Here we present new multi-anvil experiments and parameterized phase relation models to constrain the fate of slab-derived carbonatite melts in the upper mantle. The experiments were conducted at 7 GPa/1400 °C and 10 GPa/1450 °C, and used starting compositions mimicking the ambient mantle infiltrated by variable carbonatite fluxes (0-45 wt%) from the slab surface. Kimberlitic melts (CO2 = 14-32 wt%, SiO2 = 15-33 wt%, and MgO = 20-29 wt%) were produced from experiments with 5.8-25.6 wt% carbonatite influxes. Experimental phase relations demonstrate a reactive melting process in which the carbonatite influx increases in proportion by dissolution of olivine, orthopyroxene, garnet and precipitation of clinopyroxene. This manifests a feasible mechanism for slab-derived carbonatite melts to efficiently transport in the ambient mantle through high-porosity channels. The melt and mineral fractions from this study and previous phase equilibria experiments in peridotite + O systems were empirically parameterized as functions of temperature (900-2000 °C), pressure (3-20 GPa), and bulk compositions (e.g., CO2 = 0.9-17.1 wt% and Na2O + K2O = 0.27-2.51 wt%). Applications of the phase relation models to prescribed melting processes indicate that reactive melting of a carbonatite-fluxed mantle source could produce kimberlitic melts with diverse residual lithologies under various melting conditions. However, reactive melting at the slab-mantle interface can only commence when the slab-released carbonatite melt conquers the carbonation freezing front, i.e., the peridotite solidi suppressed by infiltration of CO2-rich melts in an open system. Depending on temperatures and local influxes, reactive melting and carbonation/redox freezing can occur simultaneously above the slab-mantle interface, yielding heterogeneous lithologies and redox conditions as well as various time-scales of carbon transport in Earth's mantle.
DS201802-0267
2018
Sun, J., Tappe, S., Kostrovitsky, S.I., Liu, C-Z., Shuzovatv, S.Yu., Wu, F-Y.Mantle sources of kimberlites through time: a U Pb and Lu Hf isotope study of zircon megacrysts from the Siberian diamond fields.Chemical Geology, in press available, 39p. PdfRussia, Siberiadeposit - Mir, Udachnaya, Anabar alluvials, Ebelyakh placers

Abstract: A comprehensive, internally consistent U-Pb and Lu-Hf isotope data set for 93 mantle-derived zircons from the Yakutian kimberlite province confirms and further refines the four major episodes of kimberlite magmatism on the Siberian craton: 421-409?Ma (Late Silurian-Early Devonian), 358-353?Ma (Late Devonian-Early Carboniferous), 226-218?Ma (Late Triassic), and 161-144?Ma (Middle-Late Jurassic). The relatively narrow, constant range of ?Hf values between +2 and +10 for both the Paleozoic and Mesozoic mantle-derived zircons (and by inference kimberlites) suggests that the volatile-rich magmas were repeatedly sourced from the convecting upper mantle beneath the Siberian craton. This finding is in keeping with the narrow and constant range of ?Nd values for groundmass perovskites from the Yakutian kimberlite province between +1.8 and +5.5 between 420 and 150?Ma. Our preferred model implies that the convecting upper mantle beneath the Yakutian kimberlite province ‘recovered’ rapidly back to ambient conditions shortly after the giant plume-related flood volcanic event that produced the Siberian Traps at 250?Ma. Although close spatial relationships exist between kimberlites and flood basalts on the Siberian craton during both the Paleozoic and Mesozoic, exact timing of the igneous events and the isotopic compositions of the diverse deep-sourced melting products rule out any direct genetic links.Besides the highly economic kimberlite-hosted diamond deposits of Late Devonian age (e.g., Mir and Udachnaya), the Siberian craton also contains significant Mesozoic placer diamond deposits (e.g., along the Anabar river), for which lamproite sources have been suggested recently. Our study shows that mantle-derived zircon megacryst fragments from the Ebelyakh placer deposit have Late Triassic ages of ca. 224?Ma. Their long-term depleted Hf isotopic compositions (+8.5 ?Hf) suggest that the alluvial diamonds were sourced from asthenosphere-derived Triassic kimberlites rather than from lithospheric mantle derived isotopically enriched lamproites.
DS201803-0480
2018
Sun, J., Tappe, S., Kostrovitsky, S.I., liu, C-Z., Skuzovatov, S.Y., Wu, F-Y.Mantle sources of kimberlites through time: A U-Pb and Lu-HF isotope study of zircon megacrysts from the Siberian diamond Fields.Chemical Geology, Vol. 479, pp. 228-240.Russia, Siberiageochronology

Abstract: A comprehensive, internally consistent U-Pb and Lu-Hf isotope data set for 93 mantle-derived zircons from the Yakutian kimberlite province confirms and further refines the four major episodes of kimberlite magmatism on the Siberian craton: 421-409?Ma (Late Silurian-Early Devonian), 358-353?Ma (Late Devonian-Early Carboniferous), 226-218?Ma (Late Triassic), and 161-144?Ma (Middle-Late Jurassic). The relatively narrow, constant range of ?Hf values between +2 and +10 for both the Paleozoic and Mesozoic mantle-derived zircons (and by inference kimberlites) suggests that the volatile-rich magmas were repeatedly sourced from the convecting upper mantle beneath the Siberian craton. This finding is in keeping with the narrow and constant range of ?Nd values for groundmass perovskites from the Yakutian kimberlite province between +1.8 and +5.5 between 420 and 150?Ma. Our preferred model implies that the convecting upper mantle beneath the Yakutian kimberlite province ‘recovered’ rapidly back to ambient conditions shortly after the giant plume-related flood volcanic event that produced the Siberian Traps at 250?Ma. Although close spatial relationships exist between kimberlites and flood basalts on the Siberian craton during both the Paleozoic and Mesozoic, exact timing of the igneous events and the isotopic compositions of the diverse deep-sourced melting products rule out any direct genetic links. Besides the highly economic kimberlite-hosted diamond deposits of Late Devonian age (e.g., Mir and Udachnaya), the Siberian craton also contains significant Mesozoic placer diamond deposits (e.g., along the Anabar river), for which lamproite sources have been suggested recently. Our study shows that mantle-derived zircon megacryst fragments from the Ebelyakh placer deposit have Late Triassic ages of ca. 224?Ma. Their long-term depleted Hf isotopic compositions (+8.5 ?Hf) suggest that the alluvial diamonds were sourced from asthenosphere-derived Triassic kimberlites rather than from lithospheric mantle derived isotopically enriched lamproites.
DS201811-2611
2018
Sun, J., Tappe, S., Kostrovitsky, S.I., Liu, C-Z., Skuzovatov, S.Y., Wu, F-Y.Mantle sources of kimberlites through time: A U-Pb and Lu-Hf isotope study of zircon megacrysts from the Siberian diamond fields.Chemical Geology, Vol. 479, 1, pp. 228-240.Russia, Siberiageochronology

Abstract: A comprehensive, internally consistent U-Pb and Lu-Hf isotope data set for 93 mantle-derived zircons from the Yakutian kimberlite province confirms and further refines the four major episodes of kimberlite magmatism on the Siberian craton: 421-409?Ma (Late Silurian-Early Devonian), 358-353?Ma (Late Devonian-Early Carboniferous), 226-218?Ma (Late Triassic), and 161-144?Ma (Middle-Late Jurassic). The relatively narrow, constant range of ?Hf values between +2 and +10 for both the Paleozoic and Mesozoic mantle-derived zircons (and by inference kimberlites) suggests that the volatile-rich magmas were repeatedly sourced from the convecting upper mantle beneath the Siberian craton. This finding is in keeping with the narrow and constant range of ?Nd values for groundmass perovskites from the Yakutian kimberlite province between +1.8 and +5.5 between 420 and 150?Ma. Our preferred model implies that the convecting upper mantle beneath the Yakutian kimberlite province ‘recovered’ rapidly back to ambient conditions shortly after the giant plume-related flood volcanic event that produced the Siberian Traps at 250?Ma. Although close spatial relationships exist between kimberlites and flood basalts on the Siberian craton during both the Paleozoic and Mesozoic, exact timing of the igneous events and the isotopic compositions of the diverse deep-sourced melting products rule out any direct genetic links. Besides the highly economic kimberlite-hosted diamond deposits of Late Devonian age (e.g., Mir and Udachnaya), the Siberian craton also contains significant Mesozoic placer diamond deposits (e.g., along the Anabar river), for which lamproite sources have been suggested recently. Our study shows that mantle-derived zircon megacryst fragments from the Ebelyakh placer deposit have Late Triassic ages of ca. 224?Ma. Their long-term depleted Hf isotopic compositions (+8.5 ?Hf) suggest that the alluvial diamonds were sourced from asthenosphere-derived Triassic kimberlites rather than from lithospheric mantle derived isotopically enriched lamproites.
DS201811-2612
2018
Sun, M., Fu, X., Liu, K.H., Gai, S.S.Absence of thermal influence from the African Superswell and cratonic keels on the mantle transition zone beneath southern Africa: evidence from receiver function imaging.Earth and Planetary Science Letters, Vol. 503, pp. 108-117.Africa, South Africa, Zimbabwegeophysics - seismic

Abstract: The depths of the 410 km (d410) and 660 km (d660) discontinuities beneath southern Africa, which is presumably underlain by the lower-mantle African Superswell, are imaged in 1? radius consecutive circular bins using over 6400 P-to-S receiver functions (RFs) recorded by 130 seismic stations over a 27 yr period. When the IASP91 standard Earth model is utilized for moveout correction and time-depth conversion, a normal mantle transition zone (MTZ) thickness of 246 ± 7 km is observed, suggesting that the Superswell has no discernible effect on mantle transition zone temperature. Based on the negligible disparity of the mean MTZ thicknesses between on (246 ± 6 km) and off (246 ± 8 km) cratonic regions, we conclude that the deep Archean cratonic keels possess limited influence on MTZ thermal structure. The apparently shallower-than-normal MTZ discontinuities and the parallelism between the d410 and d660 are mostly the results of upper mantle high wave speed anomalies probably corresponding to a thick lithosphere with a mean thickness of about 245 km beneath the Kaapvaal and 215 km beneath the Zimbabwe cratons. In contradiction to conclusions from some of the previous studies, the resulting spatial distribution of the stacking amplitudes of the P-to-S converted phases at the discontinuities is inconsistent with the presence of an excessive amount of water in the MTZ and atop the d410.
DS201805-0981
2018
Sun, N., Wei, W., Han, S., Song, J., Li, X., Duan, Y., Prakapenka, V.B., Mao, Z.Phase transition and thermal equations of state of (Fe, Al) -bridgmanite and post perovskite: implication for the chemical heterogeneity at the lowermost mantle.Earth Planetary Science Letters, Vol. 490, pp. 161-169.Mantleperovskite
DS201802-0268
2018
Sun, W-d., Hawkesworth, C.J., Yao, C., Zhang, C-C., Huang, R.f., Liu, X., Sun, X-L, Ireland, T., Song, M-s., Ling, M-x., Ding, X., Zhang, Z-f., Fan, W-m., Wu, Z-q.Carbonated mantle domains at the base of the Earth's transition zone.Chemical Geology, Vol. 478, pp. 69-75.Mantlecarbonatite

Abstract: The oxygen fugacity of the upper mantle is 3-4 orders of magnitude higher than that of the lower mantle and this has been attributed to Fe2 + disproportionating into Fe3 + plus Fe0 at pressures > 24 GPa. The upper mantle might therefore have been expected to have evolved to more oxidizing compositions through geological time, but it appears that the oxygen fugacity of the upper mantle has remained constant for the last 3.5 billion years. Thus, it indicates that the mantle has been actively buffered from the accumulation of Fe3 +, and that this is linked to oxidation of diamond to carbonate coupled with reduction of Fe3 + to Fe2 +. When subducted plates penetrate into the lower mantle, compensational upwelling transports bridgmanite into the transition zone, where it breaks down to ringwoodite and majorite, releasing the ferric iron. The system returns to equilibrium through oxidation of diamond. Early in Earth history, diamond may have been enriched at the base of the transition zone in the Magma Ocean, because it is denser than peridotite melts at depths shallower than 660 km, and it is more buoyant below. Ongoing oxidation of diamond forms carbonate, leading to relatively high carbonate concentrations in the source of ocean island basalts.
DS201809-2096
2018
Sun, Y., Teng, F.Z., Kuehner, S., Pang, K.N.Origins of Leucite Hills lamproites constrained by magnesium isotopes.Goldschmidt Conference, 1p. AbstractUnited States, Wyominglamproites

Abstract: Lamproites are commonly found in post-collisional or intracontinental environments and characterized by unique elemental and radiogenic isotopic signatures that signify derivation from the subcontinental lithospheric mantle. An improved understanding on their genesis is important regarding the dynamics of the Earth’s mantle lithosphere, and requires knowledge in identifying source components and magmatic processes. In order to better constrain the mechanism producing the geochemical diversity of lamproites, we measure the elemental and Mg isotopic compositions of a suite of lamproites from the well-known locality Leucite Hills, Wyoming, U.S.A. The two types of lamproites therein, madupitic and phlogopite lamproites, display distinct characteristics in many element and Mg isotope diagrams. These variations cannot be ascribed to crustal contamination, fractional crystallization or source heterogeneity. Instead, the strong correlations between melting-sensitive elemental ratios (e.g., Sm/Yb and La/Yb) and indices of carbonatitic metasomatism (e.g., CaO/Al2O3, Hf/Hf*, and Ti/Ti*) with ?26Mg indicate that variable degrees of partial melting of a common carbonated mantle source have generated the observed geochemical distinctions of the Leucite Hills lamproites. Our study reveals that geochemical variations in a given lamproite suite might have been controlled mainly by the degree of mantle melting.
DS201809-2097
2018
Sverjensky, D.A., Huang, F.Mixing of saline and carbonatitic fluids to form peridotitic PAnd a diamonds.Goldschmidt Conference, 1p. AbstractCanada, Northwest Territoriesdeposit - Panda

Abstract: Diamonds containing fluid inclusions provide the most direct samples of upper mantle fluids. In eclogites, diamond can form by pH drop during fluid-rock interaction. However, in peridotites, the cause of the chemical evolution of the fluids and minerals, including the wide range of observed salinities involved, are still unclear. Here we used new experimental calibrations of the Deep Earth Water model involving organic and inorganic complexes of the major rockforming elements to show that fluid mixing can cause diamond formation in the peridotitic environment. Models of the saline and carbonatitic fluid inclusion compositions consistent with the chemistry of measured solid inclusions in Panda diamonds were used to simulate the irreversible, chemical mass transfer when a carbonatitic fluid infiltrates harzburgite containing a saline fluid at 950°C and 4.5 GPa. Simultaneous oxidation of aqueous hydrocarbons in the peridotitic fluid and reduction of the organic acid anion formate as well as bicarbonate in the carbonatitic fluid during mixing and reaction with harzburgite resulted in the formation of diamond, olivine, and garnet, and increases in the logfo2 and pH. Olivine was predicted to become more Ferich and garnet more Ca and Fe-rich with reaction progress, in agreement with reported temporal trends in the composition of mineral inclusions from octahedral cores to coated rims on Panda diamonds. Aqueous phase concentrations of all elements changed consistent with measured trends in fluid inclusion compositions from saline to less saline. For comparison, we also simulated a saline fluid infiltrating a harzburgite containing a carbonatitic fluid. Diamond again formed, but the compositional trends of the silicate minerals and the trend of salinity with reaction progress were all in the opposite direction to data from the Panda diamonds. Overall, our study strongly suggests that mixing of fluids containing carbon from both reduced and oxidized sources, and simultaneous reaction with harzburgite can cause precipitation of diamond, without the need for triggering by temperature or pressure changes, while adding Ca and Fe to the sub-lithospheric mantle.
DS201809-2098
2018
Talukdar, D., Pandey, A., Chalapathi Rao, N.V., Kumar, A., Pandit, D., Belyatsky, B.Petrology and geochemistry of the Mesoproterozoic Vattikod lamproites, eastern Dharwar craton, southern India: evidence for multiple enrichment of sub-continental lithospheric mantle and links with amalgamation and break up of the Columbia supercontinent.Contributions to Mineralogy and Petrology, Vol. 173, doi.org/10.1007/ s00410-018-1493-y 27p.Indialamproites

Abstract: Numerous lamproite dykes are hosted by the Eastern Dharwar Craton, southern India, particularly towards the northwestern margin of the Cuddapah Basin. We present here a comprehensive mineralogical and geochemical (including Sr and Nd isotopic) study on the lamproites from the Vattikod Field, exposed in the vicinity of the well-studied Ramadugu lamproite field. The Vattikod lamproites trend WNW-ESE to NW-SE and reveal effects of low-temperature post-magmatic alteration. The studied lamproites show porphyritic texture with carbonated and serpentinized olivine, diopside, fluorine-rich phlogopite, amphibole, apatite, chromite, allanite, and calcite. The trace-element geochemistry (elevated Sr and HFSE) reveals their mixed affinity to orogenic as well as anorogenic lamproites. Higher fluorine content of the hydrous phases coupled with higher whole-rock K2O highlights the role of metasomatic phlogopite and apatite in the mantle source regions. Trace-element ratios such as Zr/Hf and Ti/Eu reveal carbonate metasomatism of mantle previously enriched by ancient subduction processes. The initial 87Sr/86Sr-isotopic ratios (calculated for an assumed emplacement age of 1350 Ma) vary from 0.7037 to 0.7087 and ?Nd range from ??10.6 to ??9.3, consistent with data on global lamproites and ultrapotassic rocks. We attribute the mixed orogenic-anorogenic character for the lamproites under study to multi-stage metasomatism. We relate the (1) earlier subduction-related enrichment to the Paleoproterozoic amalgamation of the Columbia supercontinent and the (2) second episode of carbonate metasomatism to the Mesoproterozoic rift-related asthenospheric upwelling associated with the Columbia breakup. This study highlights the association of lamproites with supercontinent amalgamation and fragmentation in the Earth history.
DS201806-1257
2018
Tang, M., Erdman, M., Eldridge, G., Lee, C-T.A.The redox filter beneath magmatic orogens and the formation of the continental crust.Science Advances, Vol. 4, 5, 10.1126/ sciadv.eaar 4444Mantlemagmatism

Abstract: The two most important magmatic differentiation series on Earth are the Fe-enriching tholeiitic series, which dominates the oceanic crust and island arcs, and the Fe-depleting calc-alkaline series, which dominates the continental crust and continental arcs. It is well known that calc-alkaline magmas are more oxidized when they erupt and are preferentially found in regions of thick crust, but why these quantities should be related remains unexplained. We use the redox-sensitive behavior of europium (Eu) in deep-seated, plagioclase-free arc cumulates to directly constrain the redox evolution of arc magmas at depth. Primitive arc cumulates have negative Eu anomalies, which, in the absence of plagioclase, can only be explained by Eu being partly reduced. We show that primitive arc magmas begin with low oxygen fugacities, similar to that of mid-ocean ridge basalts, but increase in oxygen fugacity by over two orders of magnitude during magmatic differentiation. This intracrustal oxidation is attended by Fe depletion coupled with fractionation of Fe-rich garnet. We conclude that garnet fractionation, owing to its preference for ferrous over ferric iron, results in simultaneous oxidation and Fe depletion of the magma. Favored at high pressure and water content, garnet fractionation explains the correlation between crustal thickness, oxygen fugacity, and the calc-alkaline character of arc magmas.
DS201804-0747
2017
Tang, S., Song, Z., Lu, T., Su, J., Ma, Y.Two natural type IIa diamonds with strong phosphorescence and Ni related defects.Gems & Gemology Lab Notes, Vol. 53, 4, pp. 476-478.Technologyfluoresecence

Abstract: Strong phosphorescence under UV excitation is rarely seen in natural diamond and normally limited to hydrogen-rich type Ia or type IaA/Ib chameleons and type IIb diamonds (T. Hainschwang et al., "A gemological study of a collection of chameleon diamonds," Spring 2005 G&G, pp. 20-35; S. Eaton-Magaña and R. Lu, "Phosphorescence in type IIb diamonds," Diamond and Related Materials, Vol. 20, No. 7, 2011, pp. 983-989). When seen in other diamond types, an even rarer occurrence, it is shorter and less intense. Recently, the National Gemstone Testing Center (NGTC) in Beijing encountered two natural diamonds that showed extraordinarily strong blue phosphorescence and uncommon fluorescence colors under the DiamondView.
DS201808-1792
2018
Tang, S., Su, J., Lu, T., Ma, Y., Ke, J., Song, Z., Zhang, S., Liu, H.A thick overgrowth of CVD synthetic diamond on a natural diamond.Journal of Gemmology, Vol. 36, 2, pp. 134-141.Technologysynthetics

Abstract: In October 2017, a natural diamond overgrown by a thick layer of CVD synthetic diamond was identified at the Beijing laboratory of the National Gemstone Testing Center (NGTC). The round-brilliant-cut sample was near-colourless and weighed 0.11 ct. No sign of the overgrowth was observed with magnification. However, DiamondView images showed a distinct boundary in the pavilion separating layers of different luminescence: The upper layer displayed red fluorescence with greenish blue phosphorescence, while the lower portion showed deep blue fluorescence and no phosphorescence. Infrared spectroscopy revealed that the upper layer was type IIa and the lower portion was type Ia. Ultraviolet-visible-near infrared (UV-Vis-NIR) spectroscopy recorded an unusual co-existence of the N3 centre at 415 nm together with absorption due to [Si-V]-defects at 737 nm. The photoluminescence (PL) spectrum confirmed a high level of [Si-V]-defects. The approximate thickness of the CVD synthetic layer was ~740 µm, which is much thicker than previously reported for such overgrowths. The presence of the N3 centre in the natural diamond layer caused this sample to be passed as natural by various screening instruments. Luminescence imaging is key to identifying such overgrowths, and should be relied upon more heavily in the screening procedures used by gemmological laboratories in the future.
DS201803-0481
2018
Tao, R., Fei, Y., Bullock, E.S., Xu, C., Zhang, L.Experimental investigation of Fe3+ rich majoritic garnet and its effect on majorite geobarometer.Geochimica et Cosmochimica Acta, Vol. 225, pp. 1-16.Technologygeobarometry

Abstract: Majoritic garnet [(Ca, Mg, Fe2+)3(Fe3+, Al, Si)2(SiO4)3] is one of the predominant and important constituents of upper mantle peridotite and ultra-deep subducted slabs. Majoritic substitution in garnet depends on pressure, and it has been used to estimate the formation pressure of natural majoritic garnet. Ferric iron (Fe3+) substitution occurs in natural majoritic garnets from mantle diamonds and shocked meteorites. However, available majorite geobarometers were developed without considering the effect of Fe3+ substitution in the structure. In this study, we systematically synthesized Fe3+- bearing majoritic garnets from 6.5?GPa to 15?GPa to evaluate the effect of Fe3+ on the majorite geobarometer. The Fe3+ contents of synthetic majoritic garnets were analyzed using the "Flank method" with the electron probe microanalyzer (EPMA). The results were compared with those based on the charge balance calculations. From the known synthesis pressures and measured Fe3+ contents, we developed a new majorite geobarometer for Fe3+-bearing majoritic garnets. Our results show that the existing majorite geobarometer, which does not take into account the Fe3+ substitution, could underestimate the formation pressure of majoritic garnets, especially for samples with a high majoritic component.
DS201809-2099
2018
Tappe, S., Dongre, A., Liu, C-Z., Wu, F-Y.Premier evidence for prolonged kimberlite pipe formation and its influence on diamond transport from deep Earth. Dikes sampled, geochronologyGeology, Vol. 46, pp. 843-846.Africa, South Africadeposit - Cullinan

Abstract: Volcanic pipes, or maar-diatreme volcanoes, form during explosive eruptions of mantle-derived magmas near Earth's surface. Impressive examples are the carrot-shaped, downward tapering structures formed by kimberlite magmas. Kimberlites originate from >150 km depth within Earth's mantle beneath thick continental roots, away from tectonic plate margins. Kimberlite pipes can be significant diamond deposits, and the complex architecture revealed during exploration and mining is ascribed to repeated magma injections leading to multiple eruptions. Repeated magmatic pulses cause diatremes to widen and grow downward, forming kilometer-sized subterranean structures. However, the time-resolved evolution of kimberlite pipe systems is largely unknown. We present the first U/Pb perovskite ages for newly discovered kimberlite dikes (1139.8 ± 4.8 Ma) that cut through the volcaniclastic infill of the Premier kimberlite pipe (1153.3 ± 5.3 Ma) at Cullinan Diamond Mine, South Africa. The ages reveal that renewed kimberlite volcanic activity occurred, at a minimum, 3 m.y. after the main pipe formation. This finding suggests that the largest kimberlite pipes, and maar-diatreme volcanoes in general, may be magmatically active for several millions of years, which conflicts with this volcanism being described as 'monogenetic' at millennia time scales. Exemplified by Tier-1 diamond deposits on the Kaapvaal craton, long-lasting kimberlite volcanic activity may be an important factor in growing large diatremes, plus enabling effective transport of mantle cargo from the diamond stability field to Earth's surface.
DS201801-0070
2018
Tappe, S., Smart, K., Torsvik, T., Massuyeau, M., de Wit, M.Geodynamics of kimberlites on a cooling Earth: clues to plate tectonic evolution and deep volatile cycles.Earth and Planetary Science Letters, Vol. 484, pp. 1-14.Mantlekimberlite, origin, magmatism

Abstract: Kimberlite magmatism has occurred in cratonic regions on every continent. The global age distribution suggests that this form of mantle melting has been more prominent after 1.2 Ga, and notably between 250-50 Ma, than during early Earth history before 2 Ga (i.e., the Paleoproterozoic and Archean). Although preservation bias has been discussed as a possible reason for the skewed kimberlite age distribution, new treatment of an updated global database suggests that the apparent secular evolution of kimberlite and related CO2-rich ultramafic magmatism is genuine and probably coupled to lowering temperatures of Earth's upper mantle through time. Incipient melting near the CO2- and H2O-bearing peridotite solidus at >200 km depth (1100-1400?°C) is the petrologically most feasible process that can produce high-MgO carbonated silicate melts with enriched trace element concentrations akin to kimberlites. These conditions occur within the convecting asthenospheric mantle directly beneath thick continental lithosphere. In this transient upper mantle source region, variable CHO volatile mixtures control melting of peridotite in the absence of heat anomalies so that low-degree carbonated silicate melts may be permanently present at ambient mantle temperatures below 1400?°C. However, extraction of low-volume melts to Earth's surface requires tectonic triggers. Abrupt changes in the speed and direction of plate motions, such as typified by the dynamics of supercontinent cycles, can be effective in the creation of lithospheric pathways aiding kimberlite magma ascent. Provided that CO2- and H2O-fluxed deep cratonic keels, which formed parts of larger drifting tectonic plates, existed by 3 Ga or even before, kimberlite volcanism could have been frequent during the Archean. However, we argue that frequent kimberlite magmatism had to await establishment of an incipient melting regime beneath the maturing continents, which only became significant after secular mantle cooling to below 1400?°C during post-Archean times, probably sometime shortly after 2 Ga. At around this time kimberlites replace komatiites as the hallmark mantle-derived magmatic feature of continental shields worldwide. The remarkable Mesozoic-Cenozoic ‘kimberlite bloom’ between 250-50 Ma may represent the ideal circumstance under which the relatively cool and volatile-fluxed cratonic roots of the Pangea supercontinent underwent significant tectonic disturbance. This created more than 60% of world's known kimberlites in a combination of redox- and decompression-related low-degree partial melting. Less than 2% of world's known kimberlites formed after 50 Ma, and the tectonic settings of rare ‘young’ kimberlites from eastern Africa and western North America demonstrate that far-field stresses on cratonic lithosphere enforced by either continental rifting or cold subduction play a crucial role in enabling kimberlite magma transfer to Earth's surface.
DS201810-2384
2018
Tappert, M.Novel exploration tools: using reflectance spectroscopy to detect hydration halos around kimberlites. Vancouver Kimberlite Cluster , Oct. 3, 1p. AbstractMantlespectroscopy

Abstract: Many kimberlite ore bodies are relatively small and the presence of overburden along with the complexities of interpreting geophysical data can make it challenging to intersect a kimberlite target during exploration drilling. However, the analysis of country rock drill core from the perimeter of several known kimberlites provides evidence that subtle alteration (hydration) halos around kimberlites exist, which can be detected using rapid and cost-effective spectroscopic techniques. Identification of these hydration halos, which are independent of country rock composition, may provide crucial information about the presence of undiscovered kimberlite in an exploration area, especially if kimberlite was not intersected during initial drilling. Preliminary estimates suggest that these hydration halos, which are most likely caused by kimberlite-derived hydrous fluids, can extend more than 65 meters into the country rocks, but their size strongly depends on the size of the kimberlite body. Narrow kimberlite dikes produce much smaller halos compared to large kimberlite pipes. In addition, hydration halos in carbonate rocks also appear to be smaller compared to silicate rocks.
DS201803-0482
2018
Tatsumi, N., Harano, K., Ito, T., Sumiya, H.The luminescence emitted from the type Ib and IIa diamonds under SiO2 polishing process.Diamond & Related Materials, Vol. 83, pp. 104-108.Technologyluminescence

Abstract: The luminescence of triboplasma during diamond polishing was investigated. The main luminescence in the ultraviolet range came from N2 molecules in the air. The colors of the visible range of triboplasma were the same as those observed in the photoluminescence images, excited by the ultraviolet light. The color of the triboplasma luminescence was green for type Ib diamond, which was mainly from the H3 center. The blue luminescence for type IIa diamond was mainly from Band A. The correlation between the diamond temperature and periphery speed indicate that that the mechanical abrasion component also increased linearly. However the polishing rate showed a threshold at the periphery speed of 26?km/h which corresponds well with the threshold of the triboplasma generation. These results imply that the electrical and optical energy of the triboplasma excited the defect level at the diamond surface and enhanced the chemical polishing rate of the diamond.
DS201804-0748
2018
Teixeira, W., Hamilton, M.A., Girardi, A.V., Faleiros, F.M.U Pb baddeleyite ages of key dyke swarms in the Amazonian craton ( Carajas/Rio Maria and Rio Apa areas): tectonic implications for events at 1880, 1110 Ma, 535 Ma and 200 Ma.Precambrian Research, in press available 19p.South Americacraton - Amazonian

Abstract: U-Pb baddeleyite ages for key mafic dykes of the Amazonian Craton reveal four significant intraplate episodes that allow connections with global igneous activity through time and supercontinent cycles. The oldest dykes (Carajás-Rio Maria region) are diabases with ages of 1880.2 ± 1.5 Ma and 1884.6 ± 1.6 Ma, respectively, corresponding with the Tucumã swarm which crops out to the west and is age-equivalent. The magmatic activity has a genetic link with the ca. 1.88 Ga Uatumã Silicic Large Igneous Province (SLIP), characterized by felsic plutonic-volcanic rocks. There is an age correlation with LIP events (ca. 1880 Ma) in the Superior, Slave, Indian and other cratons. This magmatism could be derived from significant perturbations of the upper mantle during the partial assembly of Columbia. Gabbronorite of the Rio Perdido Suite (Rio Apa Terrane) crystallized at 1110.7 ± 1.4 Ma, and is identical to that of the Rincón del Tigre-Huanchaca LIP event of the Amazonian Craton. This event was synchronous with the initiation of Keweenawan magmatism of central Laurentia (Midcontinent Rift) and also with coeval units in the Kalahari, Congo and India cratons. The two youngest U-Pb dates (535 and 200 Ma) occur in the Carajás region. Diabase of the Paraupebas swarm yields an age of 535.1 ± 1.1 Ma, which may be correlative with the giant Piranhas swarm located ca. 900 km apart to the west. The Paraupebas swarm is correlative with post-collisional plutonism within the Araguaia marginal belt. Therefore, the Cambrian dykes may reflect reactivation of cooled lithosphere, due to crustal extension/transtension active along the craton’s margin during assembly of West Gondwana. This magmatism is also contemporaneous with the 539-530 Ma Wichita LIP of southern Laurentia. The youngest studied Carajás region dyke was emplaced at ca. 200 Ma, corresponding with 40Ar/39Ar ages for the Periquito dykes west of Carajás and with most K-Ar ages of the giant Cassiporé swarm, located north of the study area. The newly dated ca. 200 Ma dyke fits well into the known, brief span of ages for the CAMP Large Igneous Province event, around the present central and northern Atlantic Ocean.
DS201801-0071
2017
Teixeira, W., Oliveira, E.P., Marques, L.S.Nature and evolution of the Archean crust of the Sao Francisco Craton.Heibron, H. et al. eds. Sao Francisco Craton, eastern Brazil, Regional geology reviews., Chapter 3, pdfSouth America, BrazilGeology

Abstract: We overview the Archean tectonic framework the São Francisco craton based on geologic constraints, integrated geochronologic interpretation and isotopic-geochemical evidence of basement rocks. U-Pb provenance studies of Archean and Paleoproterozoic supracrustal sequences are also used to provide additional inferences about the geodynamic scenario. The Archean rocks crop out mainly in two large areas in the southern and northern portions of the craton, surrounded and/or in tectonic contact with Paleoproterozoic orogenic belts. The ancient substratum is essentially composed of medium- to high-grade gneissic-migmatitic rocks including TTG suites and coeval granite-greenstone associations that collectively provide an isotopic record as old as 4.1 Ga. The combined U-Pb and Sm-Nd TDM age peaks coupled with U-Pb inherited ages in detrital zircons from the supracrustal sequences indicate that very ancient continental crust (?3.5 Ga) exist, particularly in the northern portion of the craton. Mesoarchean events are episodic between 3.6-3.3 and 3.2-2.9 Ga, as for the Neoarchean (2.8-2.6 Ga) in both cratonic portions. This isotopic record indicates a protracted Archean history for the São Francisco craton, highlighted by peculiar tectonic-metamorphic histories of the basement rocks. From a tectonic point of view the compiled data concur with a diachronic evolution from Paleo- to Neoarchean times by means of juvenile accretion/differentiation events characterized by multiple TTG plutonism in genetic association with greenstone belts, coupled with partial melting events of earlier-formed material. All ancient basement complexes and/or continental blocks assembled diachronically during the Late Neoarchean by convergence-related processes akin to plate dynamics. Late-tectonic K-rich granitoids, mafic-ultramafic complexes and mafic dikes collectively mark the Neoarchean thickening and final cratonization of the continental crust.
DS201808-1793
2018
Temming, M.Designer diamonds could one day help build a quantum internet. Overview (see Rose reference)Science News, July 6, 1p.Globalsynthetic

Abstract: A new kind of artificial diamond is a cut above the rest for quantum memory. Unlike other synthetic diamonds, which could either store quantum information for a long time or transmit it clearly, the new diamond can do both. This designer crystal, described in the July 6 Science, could be a key building block in a quantum internet. Such a futuristic communications network would allow people to send supersecure messages and connect quantum computers around the world (SN: 10/15/16, p. 13). Synthetic diamond can serve as quantum storage thanks to a type of flaw in its carbon lattice, where two neighboring carbon atoms are replaced with one noncarbon atom and an empty space (SN: 4/5/08, p. 216). This pairing exhibits a quantum property known as spin, which can be in an "up" state, a "down" state or both at once. Each of those states reflects a bit of quantum data, or qubit, that may be 1, 0 or both at once. A diamond transmits qubits by encoding them in light particles, or photons, that travel through fiber-optic cables. Qubit-storing diamond defects are typically made with nitrogen atoms, which can store quantum data for milliseconds - a relatively long time in the quantum realm (SN: 4/23/11, p. 14). But nitrogen defects can’t communicate that data clearly. They emit light particles at a broad range of frequencies, which muddles the quantum information written into the photons. Defects made with silicon atoms emit light more precisely, but until now haven’t been able to store qubits for longer than several nanoseconds due to their electrical interactions with nearby particles, explains Nathalie de Leon, an electrical engineer at Princeton University. De Leon and colleagues got around this problem by forging silicon defects in a diamond infused with boron. This extra chemical ingredient shielded the delicate silicon defects from electrical interactions with nearby particles, extending the defects’ quantum memory. The boron-infused crystal nearly rivaled the long-term quantum memory of nitrogen defects, storing qubits for about a millisecond. And it gave a clean photon readout, emitting about 90 percent of its photons at the exact same frequency-compared to just 3 percent of photons spat out by nitrogen defects. Tweaking the environment of the silicon defects was "an extremely creative way" to help keep a better grip on qubits, says Evelyn Hu, an applied physicist and electrical engineer at Harvard University not involved in the work. This new artificial diamond could be used to construct devices called quantum repeaters for long-distance quantum communications, says David Awschalom, a physicist and quantum engineer at the University of Chicago who wasn’t involved in the work. Qubit-carrying photons can travel only up to about 100 kilometers through optical fiber before their signal gets scrambled (SN: 9/30/17, p. 8). Quantum repeaters that catch, store and re-emit photons could serve as stepping stones between fiber-optic cables to extend the reach of future networks.
DS201809-2100
2018
Tepp, G., Ebinger, C.J., Zal, H., Gallacher, R., Accardo, N., Shillington, D.J., Gaherty, J., Keir, D., Nyblade, A.A., Mbogoni, G.J., Chindandali, P.R.N., Ferdinand-Wambura, R., Mulibo, G.D., Kamihanda, G.Seismic anistrotropy of the Upper mantle below the western rfit, East Africa.Journal of Geophysical Research, Vol. 123, 7, pp. 5644-5660.Africa, east Africageophysics - seismic

Abstract: Although the East African rift system formed in cratonic lithosphere above a large?scale mantle upwelling, some sectors have voluminous magmatism, while others have isolated, small?volume eruptive centers. We conduct teleseismic shear wave splitting analyses on data from 5 lake?bottom seismometers and 67 land stations in the Tanganyika?Rukwa?Malawi rift zone, including the Rungwe Volcanic Province (RVP), and from 5 seismometers in the Kivu rift and Virunga Volcanic Province, to evaluate rift?perpendicular strain, rift?parallel melt intrusion, and regional flow models for seismic anisotropy patterns beneath the largely amagmatic Western rift. Observations from 684 SKS and 305 SKKS phases reveal consistent patterns. Within the Malawi rift south of the RVP, fast splitting directions are oriented northeast with average delays of ~1 s. Directions rotate to N?S and NNW north of the volcanic province within the reactivated Mesozoic Rukwa and southern Tanganyika rifts. Delay times are largest (~1.25 s) within the Virunga Volcanic Province. Our work combined with earlier studies shows that SKS?splitting is rift parallel within Western rift magmatic provinces, with a larger percentage of null measurements than in amagmatic areas. The spatial variations in direction and amount of splitting from our results and those of earlier Western rift studies suggest that mantle flow is deflected by the deeply rooted cratons. The resulting flow complexity, and likely stagnation beneath the Rungwe province, may explain the ca. 17 Myr of localized magmatism in the weakly stretched RVP, and it argues against interpretations of a uniform anisotropic layer caused by large?scale asthenospheric flow or passive rifting.
DS201801-0072
2017
Thakor, L., Vyas, D.U., Vora, S.B.Carbonatites-alkaline rocks, and associated economic mineral deposits: a view from beneficiation.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 3.Indiacarbonatites

Abstract: Among the known 20 carbonatite-alkaline rock associations in India, eight contain potentially economic deposits, major among them are: fluorite at Amba Dongar, Gujaratand hematite, Nb, apatite etc. at Samchampi Complex, Assam, Amba Dongar complex is estimated to host 11.6 million tonnes of fluorite ore. In the broad region of the entire Amba Dongar-Mogra-Sedivasan Carbonatite complex, fluorite mineralization has been reported, particularly on the northern and southern flanks as isolated pockets. Starting from 1964, numerous agencies like Geological Survey of India, Directorate of Geology & Mining and, finally GMDC have carried out exploration activities from time to time. The deposit is hydrothermal, mainly in form of vug filling, cavity filling and dissemination and exhibits large variations in grade, in terms of CaF2, CaCO3 and SiO2% as well as in thickness. This being the only commercially viable fluorite deposit in India, GMDC set up a 500 TPD Beneficiation Plant to produce acid/metallurgical grades in 1970. Typical problems of Fine dissemination of major part of fluorite grains, intimate association of fluorite with silica, interstitial presence of apatite in fluorite matrix are some major issues giving rise to difficulties encountered in upgrading the ore. Major setback for the Project has been deteriorating grade of 30% CaF2 at the top to current 20% CaF2 after excavating 90 meters. Having recently found more selective Collector of fluorite from silica and carbonate, an operation of 1000 TPD is now under implementation. Current mine is associated with sovite carbonatite as overburden which are reported to have appreciable amount of RE Elements like Nb, La, Ce etc. simultaneous development of which can provide a strong base for enhancing commercial aspects of the combined Project.
DS201812-2891
2018
The Israeli Diamond IndustryLab-grown diamonds could recharge drones in mid flight. LakeDiamond company.en.israelidiamond.co.il, Nov. 21, 1/2p.Europe, Switzerlandsynthetics

Abstract: LakeDiamond, a Swiss-based company that grows ultra pure diamonds and transforms them for high-tech applications, is currently developing a system that could revolutionize the use of civilian drones. According to a story in phys.org, the Swiss company is testing the use of small lab-grown diamond in recharging drones mid-flight through a laser beam. The laser beam, guided by a tracking system, can recharge photovoltaic cells on the drones’ surface. Recently, LakeDiamond’s project was included among ten projects supported for two years by the Swiss Space Office. Currently, batteries of drones - especially propeller drones - can keep the drones in flight for up to 15 minutes at a time. Using a high-power laser that cannot damage human skin or eyes, LakeDiamond’s technology is built around lab-grown diamonds used as as the optical component on a booster, which is also composed of reflective material and a small metal plate to absorb the heat. According to the pice, “the diamonds are able to transfer heat to a small metal plate that dissipates it, while at the same time reflecting light in such a way as to create a laser beam”. The new diamond-based system could have other potential applications, such as charging and transmitting data to satellites. Although the future for LakeDiamond’s project looks bright, its remote recharging system works in the lab “but will require further development and refinement before it’s ready for field use”. The company also has to work out how to recharge large drones, and how to deal with some expected problems - such as the drone flying behind an obstacle and being cut off from its laser energy source.
DS201804-0749
2018
Thomassot, E.New advances in in-situ stable isotope measurements in diamonds and their inclusions.4th International Diamond School: Diamonds, Geology, Gemology and Exploration Bressanone Italy Jan. 29-Feb. 2nd., pp. 45-47. abstractTechnologydiamond inclusions
DS201809-2101
2018
Thomassot, E.S isotope study of Archean shallow crust recycling in the Earth's mantle.Goldschmidt Conference, 1p. AbstractAfrica, Botswana, Russiadeposit - Jwaneng. Kimberley Pool, Mir, Udachnaya

Abstract: Archean supracrustal rocks (i.e. chemical sediments and metavolcanics) preserve sulfur Mass Independent Fractionations (MIF) that originate from photochemical reactions occurring in atmosphere before the great oxygenation event, 2.45 Ga. Reduced and oxidized aerosols were produced by photochemistry and respectively carry 33S enrichment (?33S > 0‰) and depletion (?33S < 0‰). The relative abundance of the minor isotope of sulfur (36S) was also affected by MIF in such a way that compact negative correlation exists between ?33S and ?36S. For much of Archean sediments, ?36S /?33S? -1, while slight variation of this slope have been attributed to minor change in the chemical composition of the atmosphere affecting global MIF source mechanism. On another hand, 36S abundance is also affected by microbial cycling and in this specific case, ?36S /?33S? -7. Accordingly, ?33S-?36S co-variations can be used to discriminate distinct sedimentary pool. This contribution aims to test the robustness of MIF array of specific exospheric sulfur pools along their journey from the surface to the mantle. We examine the ?36S in addition to ?34S and ?33S signatures measured in-situ with secondary ion mass spectrometer, in sub lithospheric peridotitic and eclogitic sulfides from Kaapvaal (Jwaneng and Kimberley Pool) and Siberian craton (Mir and Udachnaya). Unlike peridotitic sulfides, eclogitic sulfides from both localities display significant MIF attesting from the presence of surficial sulfur in their source. More interestingly, the magnitude of the anomalies as well as ?36S/?33S ratio, differ from one locality to the other. Siberian eclogites match the composition of Eoarchean sulfate (?36S/?33S=-3 and ?33S<0‰). Sample from Jwaneng follow the MIF array previously reported in Archean chemical sediment (?36S/?33S=-1) while sulfide from Kimberley pool match the composition of some meso-Archean sediments in good agreement with isochron age reported in the literature for the sulfide from this locality. This study confirms that surficial sulfur has been efficiently transferred to the lithospheric mantle. More interestingly, it shows that peculiar sedimentary pools are still preserved in the cratonic keels.
DS201809-2102
2018
Thomson, A.R., Dobsdon, D.P., Brodhollt, J., Crichton, W., Cerantola, V., Piltz, R.Crystallographic in corporation of hydrogen in ringwoodite.Goldschmidt Conference, 1p. AbstractMantlewater

Abstract: The transition zone (TZ) is believed to be the primary destination of subducted water [1], with the main TZ minerals (wadsleyite and ringwoodite) capable of holding up to ~ 3 wt.% H2O in their structures’. Observations of high attenuation and elevated conductivity suggest some areas of the transition zone are hydrated [2,3]. Combined with the observation of ~ 1.4 wt% H2O in a diamond-hosted ringwoodite inclusion [4], it is probable that the transition zone is at least regionally, if not globally, “wet”. The presence of water can induce partial melting, alter chemical partitioning and drastically change the strength of rocks. The detailed effect of water’s presence in the TZ will strongly depend on hydrogen’s incorporation mechanism, i.e. exchange with Si4+, Mg2+, Fe2+ cations or coupled substitution with Fe3+ in ringwoodite. Recent developments in neutron single-crystal Laue diffraction now allow measurements on crystals smaller than 0.1 mm3 [5]. Here we quantitatively study the incorporation of hydrogen in a synthetic iron-bearing ringwoodite. A multi-technique approach, with independent determination of chemistry, ferric iron content, water content and structure via x-ray and neutron diffraction allows a detailed study of the hydrous ringwoodite structure and the incorporation mechanism of water throughout Earth’s TZ.
DS201807-1531
2018
Timmerman, S., Chinn, I.L., Fisher, D., Davies, G.R.Formation of unusual Orapa yellow diamonds. Mineralogy and Petrology, 10.1007/ s710-018-0592 -9, 10p.Africa, Botswanadeposit - Orapa, Damtshaa, BK09, BK12,AK01

Abstract: Twenty eclogitic diamonds from Orapa Mine (Botswana) with an unusual yellow colour are characterised for their growth structure, N systematics, and C isotope composition, and the major element composition of their silicate inclusions. The diamonds show complex luminescence with green, blue and non-luminescent zones and occasional sector zonation. All parts of the diamonds have low total N concentrations (<50 at.ppm, with one exception of <125 at.ppm) and a limited range in C isotope composition (?5.7 to ?10.6‰). Fourier Transform Infrared spectra show bands at 1334, 1332, 1282, and 1240 cm?1 typical for Ib-IaA diamonds. Relict unaggregated N defects (Nso and Ns+) are present and the preservation is likely caused by the low N concentrations and possible low mantle residence temperatures rather than young diamond formation (inclusion ages of 140, 1096, 1699 Ma; Timmerman et al. Earth Planet Sc Lett 463:178-188, 2017). Garnet and clinopyroxene inclusions extracted from 14 diamonds have an eclogitic composition with relatively low Ca contents and based on all characteristics, these diamonds form a distinct population from Orapa.
DS201807-1532
2018
Timmerman, S., Honda, M., Phillips, D., Jaques, A.L., Harris, J.W.Noble gas geochemistry of fluid inclusions in South Africa diamonds: implications for the origin of diamond forming fluids. ( fibrous)Mineralogy and Petrology, 10.1007/ s710-018- 0603-x 15p.Africa, South Africadeposit - Finsch, De Beers Pool, Koffiefontein

Abstract: Fibrous diamond growth zones often contain abundant high-density fluid (HDF) inclusions and these provide the most direct information on diamond-forming fluids. Noble gases are incompatible elements and particularly useful in evaluating large-scale mantle processes. This study further constrains the evolution and origin of the HDFs by combining noble gas systematics with ?¹³C, N concentrations, and fluid inclusion compositions for 21 individual growth zones in 13 diamonds from the Finsch (n = 3), DeBeers Pool (n = 7), and Koffiefontein (n = 3) mines on the Kaapvaal Craton. C isotope compositions range from ?2.8 to ?8.6‰ and N contents vary between 268 and 867 at.ppm, except for one diamond with contents of <30 at.ppm N. Nine of the thirteen studied diamonds contained saline HDF inclusions, but the other four diamonds had carbonatitic or silicic HDF inclusions. Carbonatitic and silicic HDFs yielded low He concentrations, R/Ra (³He/?Hesample/³He/?Heair) values of 3.2–6.7, and low ??Ar/³?Ar ratios of 390–1940. Noble gas characteristics of carbonatitic-silicic HDFs appear consistent with a subducted sediment origin and interaction with eclogite. Saline HDFs are characterised by high He concentrations, with R/Ra mostly between 3.9 and 5.7, and a wide range in ??Ar/³?Ar ratios (389–30,200). The saline HDFs likely originated from subducted oceanic crust with low He but moderate Ar contents. Subsequent interaction of these saline HDFs with mantle peridotite could explain the increase in He concentrations and mantle-like He isotope composition, with the range in low to high ??Ar/³?Ar ratios dependent on the initial ³?Ar content and extent of lithosphere interaction. The observed negative correlation between ?He contents and R/Ra values in saline HDFs indicates significant in situ radiogenic ?He production. Noble gas geochemistry of fluid inclusions in South African diamonds: implications for the origin of diamond-forming fluids.
DS201805-0982
2018
Timmerman, S., Jaques, A.L., Weiss, Y., Harris, J.W.N delta 13 inclusion profiles of cloudy diamonds from Koffiefontein: evidence for formation by continuous Rayleigh fractionation and multiple fluids.Chemical Geology, Vol. 483, pp. 31-46.Africa, South Africadeposit - Koffiefontein
DS201812-2892
2018
Tolosana-Delgado, R., von Eynatten, H., Krippner, A., Meinhold, G.A multivariate discrimination scheme of detrital garnet chemistry for use in sedimentary provenance analysis.Sedimentary Geology, Vol. 375, pp. 14-26.Europe, Norway, Austria, Africa, Ugandamineral chemistry

Abstract: Garnet chemistry provides a well-established tool in the discrimination and interpretation of sediment provenance. Current discrimination approaches, however, (i) suffer from using less variables than available, (ii) subjective determination of discrimination fields with strict boundaries suggesting clear separations where in fact probabilities are converging, and (iii) significant overlap of compositional fields of garnet from different host-rock groups. The new multivariate discrimination scheme is based on a large database, a hierarchical discrimination approach involving three steps, linear discriminant analysis at each step, and the five major host-rock groups to be discriminated: eclogite- (A), amphibolite- (B) and granulite- (C) facies metamorphic rocks as well as ultramafic (D) and igneous rocks (E). The successful application of statistical discrimination approaches requires consideration of the a priori knowledge of the respective geologic setting. This is accounted for by the use of prior probabilities. Three sets of prior probabilities (priors) are introduced and their advantages and disadvantages are discussed. The user is free to choose among these priors, which can be further modified according to the specific geologic problem and the level of a priori knowledge. The discrimination results are provided as integrated probabilities of belonging to the five major host-rock groups. For performing calculations and results a supplementary Excel® spreadsheet is provided. The discrimination scheme has been tested for a large variety of examples of crystalline rocks covering all of the five major groups and several subgroups from various geologic settings. In most cases, garnets are assigned correctly to the respective group. Exceptions typically reflect the peculiarities of the regional geologic situation. Evaluation of detrital garnets from modern and ancient sedimentary settings of the Western Gneiss Region (Norway), Eastern Alps (Austria) and Albertine Rift (Uganda) demonstrates the power to reflect the respective geologic situations and corroborates previous results. As most garnet is derived from metamorphic rocks and many provenance studies aim at reconstructing the tectonic and geodynamic evolution in the source area, the approach and the examples emphasize discrimination of metamorphic facies (i.e., temperature-pressure conditions) rather than protolith composition.
DS201811-2613
2018
Tomilenko, A.A., Zhimulev, E.I., Bulbak, T.A., Sonin, V.M., Chepurov, A.I., Pokhilenko, N.P.Peculiarities of the composition of volatiles of diamonds synthesized in the Fe-S-C system: data on gas chromatography - mass spectrometry.Doklady Earth Sciences, Vol. 482, 1, pp. 1207-1211.Russiaspectrometry

Abstract: The first chromatography-mass spectroscopy data on volatiles in diamonds synthesized in the Fe-S-C system with 5 wt % S at 1400-1450°C and 5.0-5.5 GPa indicate the evolution of volatile composition during the diamond growth and, correspondingly, the variation in redox conditions of the reaction cell. A significant role is played by various hydrocarbons (HCs) and their derivatives, the content of which can reach 87%. Our data on possible abiogenic synthesis of HCs (components of natural gas and oil) can result in global recalculations (including climate) related to the global C cycle.
DS201805-0983
2018
Tomlinson, E.L., Kamber, B.S., Hoare, B.C., Stead, C.V., Ildefonse, B.An exsolution origin for Archean mantle garnet. C-SCLM KaapvaalGeology, Vol. 46, 2, pp. 123-126.Africa, South Africacraton

Abstract: It is well established that the cratonic subcontinental lithospheric mantle (C-SCLM) represents a residue of extensively melted peridotite. The widespread occurrence of garnet in C-SCLM remains a paradox because experiments show that it should be exhausted beyond ?20% melting. It has been suggested that garnet may have formed by exsolution from Al-rich orthopyroxene; however, the few documented examples of garnet exsolution in cratonic samples are exotic and do not afford a direct link to garnet in granular harzburgite. We report crystallographic, petrographic, and chemical data for an exceptionally well preserved orthopyroxene megacryst containing garnet lamellae, juxtaposed against granular harzburgite. Garnet lamellae are homogeneously distributed within the host orthopyroxene and occur at an orientation that is unrelated to orthopyroxene cleavage, strongly indicating that they formed by exsolution. Garnet lamellae are subcalcic Cr-pyrope, and the orthopyroxene host is high-Mg enstatite; these phases equilibrated at 4.4 GPa and 975 °C. The reconstructed precursor is a high-Al enstatite that formed at higher pressure and temperature conditions of ?6 GPa and 1750 °C. The megacryst shows evidence for disintegrating into granular peridotite, and garnet and orthopyroxene within the granular peridotite are texturally and chemically identical to equivalent phases in the megacryst. Collectively, this evidence supports a common origin for the granular and exsolved portions of the sample. We hypothesize that high-Al enstatite was a common phase in the C-SCLM and that exsolution during cooling and stabilization of the C-SCLM could be the origin of most subcalcic garnets in depleted peridotites.
DS201802-0269
2017
Tomshin, M.D., Pokhilenko, N.P., Tarskikh, E.V.Morphology of the Nyurba kimberlite pipe and its relationship with the dolerite dike.Doklady Earth Sciences, Vol. 477, 2, pp. 1458-1460.Russiadeposit - Nyturba

Abstract: Study of the magmatics in the Nakyn kimberlite field, with consideration of the isotope dating results, allowed us to establish a sequence of their formation. First, 368.5-374.4 Ma ago intrusions of the Vilyui-Markha dike belt formed. Then (363-364 Ma) intrusion of kimberlites took place. In the Early Carboniferous (338.2-345.6 Ma), alkaline basaltic magma intruded through faults controlling the kimberlites. The magmatic activity finished 331-324.9 Ma ago with the formation of explosive breccias. It has been found that the Nyurba kimberlite pipe consists of two bodies: their kimberlite melts have successively intruded through independent channels.
DS201812-2893
2018
Torsvik, T.H.Earth history: a journey in time and space from base to top.Tectonophysics, in press available 17p.Mantlegeochronology

Abstract: The invention of a robust and accurate sea-going chronometer transformed navigation in the mid-eighteenth century. The calibration of longitude against the prime meridian at Greenwich, in combination with latitude derived from the positions of celestial bodies gave mariners for the first time confidence that they could calculate their position on the Earth's surface. Until recently, Earth scientists have been in a comparable position of having no way of calculating the longitudes of continents before the Cretaceous. Here I discuss Phanerozoic polar wander and paleogeographies and describe ways of quantitatively establishing ancient longitudes which also establish how the Earth's interior can be linked to its surface in geological time. The first method makes use of the fact that longitudinal uncertainty of continents that were assembled in Pangea can, for subsequent times, be eliminated, if longitude motion is known for only one of these continents. The best assumption is zero-longitude motion for Africa and with this assumption we can show that large igneous provinces (LIPs) and kimberlites almost exclusively erupted above the margins of TUZO and JASON in the lower mantle. This remarkable observation, also considering the effect of true polar wander, has led to a second method the plume generation zone reconstruction method unlocking a way forward in modelling absolute plate motions before Pangea and exploring links between plate tectonics, intra-plate volcanism and Deep Earth dynamics. Conceptually, that link can be viewed as a simple mass-balance: subducted lithosphere slabs restore mass to the mantle and trigger the return flow toward the surface including mantle plumes rising from the margins of TUZO and JASON. The surface manifestations of plumes are hotspot lavas, kimberlites and LIPs.
DS201801-0073
2017
Torsvik, T.H., Cocks, R.M.The inegration of paleomagnetism, the geological record and mantle tomography in the location of ancient continents.Geological Magazine, in press availableMantlegeophysics

Abstract: Constructing palaeogeographical maps is best achieved through the integration of data from hotspotting (since the Cretaceous), palaeomagnetism (including ocean-floor magnetic anomalies since the Jurassic), and the analysis of fossils and identification of their faunal and floral provinces; as well as a host of other geological information, not least the characters of the rocks themselves. Recently developed techniques now also allow us to determine more objectively the palaeolongitude of continents from the time of Pangaea onwards, which palaeomagnetism alone does not reveal. This together with new methods to estimate true polar wander have led to hybrid mantle plate motion frames that demonstrate that TUZO and JASON, two antipodal thermochemical piles in the deep mantle, have been stable for at least 300 Ma, and where deep plumes sourcing large igneous provinces and kimberlites are mostly derived from their margins. This remarkable observation has led to the plume generation zone reconstruction method which exploits the fundamental link between surface and deep mantle processes to allow determination of palaeolongitudes, unlocking a way forward in modelling absolute plate motions prior to the assembly of Pangaea. The plume generation zone method is a novel way to derive ‘absolute’ plate motions in a mantle reference frame before Pangaea, but the technique assumes that the margins of TUZO and JASON did not move much and that Earth was a degree-2 planet, as today.
DS201802-0270
2017
Tretiachenko, V.V.General aspects of mineralogical area discrimination within the Archangelsk kimberlite-picrite region. ***IN RUSStarosin, V.I. (ed) Problems of the mineralogy, economic geology and mineral resources. MAKS Press, Moscow *** IN RUS, pp. 288-321.Russia, Archangelkimberlite
DS201805-0984
2018
Tschauner, O., Huang, S., Greenberg, E., Prakapenka, V.B., Ma, C., Rossman, G.R., Shen, A.H., Zhang, D., Newville, M., Lanzirotti, A., Tait, K.Ice-VII inclusions in diamonds: evidence for aqueous fluid in the Earth's deep mantle. Orapa, ShandongScience, Vol. 359, pp. 1136-1139.Africa, South Africa, Botswana, Congo, Sierra Leone, Chinadiamond inclusions
DS201809-2103
2018
Tschauner, O., Huang, S., Wu, Z., Gtreenberg, E., Prakapenka, V.B.Ice-VII inclusions in ultradeep diamonds. Goldschmidt Conference, 1p. AbstractAfrica, South Africa, China, United States, Canada, South Americadiamond inclusions

Abstract: We present the first evidence for inclusions of ice-VII in diamonds from southern Africa, China, North- and South-America [1]. Combining synchrotron X-ray diffraction, - X-ray fluorescence and IR spectroscopy, we show the presence of ice-VII as inclusions in diamonds that have formed at depth > 410 km to about 800 km in the Earth's mantle. What is now crystalline ice-VII, a high pressure polymorph of water-ice, was component of an aqueous fluid entrapped in the diamonds that were growing in the deep mantle. Because of the confinement by the host diamonds, the inclusions retain high pressures. The same holds for inclusions of magnesian calcite, halite, and ilmenite found in the same diamond specimens. These inclusions reflect the presence of aqueous and carbonaceous fluids in the mantle transition zone and the shallow lower mantle. Using their current residual pressures and the equations of state, we can reconstruct their recovery paths [2,3]. Further, we can use the intersection of modelled recovery paths to better constrain the encapsulation pressure and temperature of these inclusions in diamonds.
DS201809-2104
2018
Tsuno, K., Grewal, D.S., Dasgupta, R.Core mantle fractionation of carbon in Earth and Mars: the effects of sulfur.Geochimica et Cosmochimica Acta, Vol. 238, pp. 477-495.Mantlecarbon

Abstract: Constraining carbon (C) fractionation between silicate magma ocean (MO) and core-forming alloy liquid during early differentiation is essential to understand the origin and early distribution of C between reservoirs such as the crust-atmosphere, mantle, and core of Earth and other terrestrial planets. Yet experimental data at high pressure (P)-temperature (T) on the effect of other light elements such as sulfur (S) in alloy liquid on alloy-silicate partitioning of C and C solubility in Fe-alloy compositions relevant for core formation is lacking. Here we have performed multi-anvil experiments at 6-13?GPa and 1800-2000?°C to examine the effects of S and Ni on the solubility limit of C in Fe-rich alloy liquid as well as partitioning behavior of C between alloy liquid and silicate melt (). The results show that C solubility in the alloy liquid as well as decreases with increasing in S content in the alloy liquid. Empirical regression on C solubility in alloy liquid using our new experimental data and previous experiments demonstrates that C solubility significantly increases with increasing temperature, whereas unlike in S-poor or S-free alloy compositions, there is no discernible effect of Ni on C solubility in S-rich alloy liquid. Our modelling results confirm previous findings that in order to satisfy the C budget of BSE, the bulk Earth C undergoing alloy-silicate fractionation needs to be as high as those of CI-type carbonaceous chondrite, i.e., not leaving any room for volatility-induced loss of carbon during accretion. For Mars, on the other hand, an average single-stage core formation at relatively oxidized conditions (1.0 log unit below IW buffer) with 10-16?wt% S in the core could yield a Martian mantle with a C budget similar to that of Earth’s BSE for a bulk C content of ?0.25-0.9?wt%. For the scenario where C was delivered to the proto-Earth by a S-rich differentiated impactor at a later stage, our model calculations predict that bulk C content in the impactor can be as low as ?0.5?wt% for an impactor mass that lies between 9 and 20% of present day Earth’s mass. This value is much higher than 0.05-0.1?wt% bulk C in the impactor predicted by Li et al. (Li Y., Dasgupta R., Tsuno K., Monteleone B., and Shimizu N. (2016) Carbon and sulfur budget of the silicate Earth explained by accretion of differentiated planetary embryos. Nat. Geosci.9, 781-785) because C-solubility limit of 0.3?wt% in a S-rich alloy predicted by their models is significantly lower than the experimentally derived C-solubility of ?1.6?wt% for the relevant S-content in the core of the impactor.
DS201810-2385
2018
Tuck-Martin, A., Adam, J., Eagles, G.New plate kinematic model and tectono-stratigraphic history of the East African and West Madagascar margins.Basin Research, doi:10.1111/bre.12294 23p.Africa, Madagascartectonics

Abstract: The continental margins of East Africa and West Madagascar are a frontier for hydrocarbon exploration. However, the links between the regional tectonic history of sedimentary basins and margin evolution are relatively poorly understood. We use a plate kinematic model built by joint inversion of seafloor spreading data as a starting point to analyse the evolution of conjugate margin segments and corresponding sedimentary basins. By correlating megasequences in the basins to the plate model we produce a margin?scale tectono?stratigraphic framework comprising four phases of tectonic development. During Phase 1 (183-133 Ma) Madagascar/India/Antarctica separated from Africa, first by rifting and later, after breakup (at ca. 170-165 Ma), by seafloor spreading in the West Somali and Mozambique basins and dextral strike?slip movement on the Davie Fracture Zone. Mixed continental/marine syn?rift megasequences were deposited in rift basins followed by shallow?marine early postrift sequences. In Phase 2 (133-89 Ma) spreading ceased in the West Somali basin and Madagascar became fixed to the African plate. However, spreading continued between the African and Antarctic plates and deposition of the early postrift megasequence continued. The onset of spreading on the Mascarene Ridge separated India from Madagascar in Phase 3 (89-60 Ma). Phase 3 was characterized by the onset of deposition of the late postrift megasequence with continued deep marine sedimentation. At the onset of Phase 4 (60 Ma onward) spreading on the Mascarene ridge ceased and the Carlsberg Ridge propagated south to form the Central Indian Ridge, separating India from the Seychelles and the Mascarene Plateau. Late postrift deposition continued until a major unconformity linked to the development of the East African Rift System marked the change to deposition of the modern margin megasequence.
DS201811-2614
2018
Tumiati, S., Malaspina, N.Redox processes and the role of carbon-bearing volatiles from the slab-mantle interface to the mantle wedge. COH system, carbonatiteJournal of the Geological Society, doi.org/10.1144/jgs20`8-046 10p.Mantlemetasomatism

Abstract: The valence of carbon is governed by the oxidation state of the host system. The subducted oceanic lithosphere contains considerable amounts of iron so that Fe3+/Fe2+ equilibria in mineral assemblages are able to buffer the (intensive) fO2 and the valence of carbon. Alternatively, carbon itself can be a carrier of (extensive) ‘excess oxygen’ when transferred from the slab to the mantle, prompting the oxidation of the sub-arc mantle. Therefore, the correct use of intensive and extensive variables to define the slab-to-mantle oxidation by C-bearing fluids is of primary importance when considering different fluid/rock ratios. Fluid-mediated processes at the slab-mantle interface can also be investigated experimentally. The presence of CO2 (or CH4 at highly reduced conditions) in aqueous COH fluids in peridotitic systems affects the positions of carbonation or decarbonation reactions and of the solidus. Some methods to produce and analyse COH fluid-saturated experiments in model systems are introduced, together with the measurement of experimental COH fluids composition in terms of volatiles and dissolved solutes. The role of COH fluids in the stability of hydrous and carbonate minerals is discussed comparing experimental results with thermodynamic models and the message of nature. The investigation of redox processes and the role of volatiles especially at the slab-mantle interface are crucial for depicting the framework of Earth carbon cycling. During the early stages of the Earth's history, the abundances of carbon and other volatiles in the different reservoirs were determined by the coupled evolution of the terrestrial magma ocean and the primitive atmosphere (Hier-Majumder & Hirschmann 2017). Since the Archean, the efficient deep subduction of organic carbon produced by photosynthesis could have promoted carbon burial in the mantle and an increase of atmospheric levels of oxygen through time (Duncan & Dasgupta 2017). In this picture the oxidation state of the mantle, mainly governed by Fe0 and Fe2+/Fe3+ ratios, and its dynamics played a key role in modulating the fO2 of the Earth's surface, leading to the precipitation of minerals in their oxidized forms such as carbonates (Sverjensky & Lee 2010; Andrault et al. 2018). Carbon at the modern terrestrial surface is largely divided between carbonates and organic deposits, with a total budget of 1?×?1023 g C, corresponding to about 100 ppm in the upper mantle (Porcelli & Pepin 2014). Recent estimates from volcanic degassing suggest that the carbon content in the modern deep mantle is even higher (c. 263 ppm; Anderson & Poland 2017; Barry 2017). In fact, the fate of carbonates and organic carbon in modern subduction zones is still largely unconstrained, although recent studies suggest that most of the subducted carbon, in the form of carbonates and organic matter, could be recycled back to the surface (Kelemen & Manning 2015). In this contribution we aim to introduce some basic principles regarding the importance of the use of intensive and extensive variables to define the ‘oxidation transfer’ from the slab to the overlying mantle by C-bearing fluids, and the buffering capacity of the mantle in the carbon speciation at subduction zones, both from the natural and experimental point of view.
DS201802-0271
2017
Turneaure, S.J., Sharma, S.M., Volz, T.J., Winey, J.M., Gupta, Y.M.Transformation of shock compressed graphite to hexagonal diamond in nanoseconds.Science Advances, Vol. 3, 10, 6p.Technologythermodynamics

Abstract: The graphite-to-diamond transformation under shock compression has been of broad scientific interest since 1961. The formation of hexagonal diamond (HD) is of particular interest because it is expected to be harder than cubic diamond and due to its use in terrestrial sciences as a marker at meteorite impact sites. However, the formation of diamond having a fully hexagonal structure continues to be questioned and remains unresolved. Using real-time (nanosecond), in situ x-ray diffraction measurements, we show unequivocally that highly oriented pyrolytic graphite, shock-compressed along the c axis to 50 GPa, transforms to highly oriented elastically strained HD with the (100)HD plane parallel to the graphite basal plane. These findings contradict recent molecular dynamics simulation results for the shock-induced graphite-to-diamond transformation and provide a benchmark for future theoretical simulations. Additionally, our results show that an earlier report of HD forming only above 170 GPa for shocked pyrolytic graphite may lead to incorrect interpretations of meteorite impact events.
DS201812-2894
2018
Ugalde, H., Milkereit, B., Lenauer, I., Morris, W.A., Mirza, A.M., Elliott, B.Airborne Mag/EM data integration of Slave province kimberlites, NWT.2018 Yellowknife Geoscience Forum , p. 84. abstractCanada, Northwest Territoriesgeophysics - Mag, EM

Abstract: As part of the Slave Province Geophysical, Surficial Materials and Permafrost Study, the Northwest Territories Geological Survey (NTGS) commissioned high resolution geophysical surveys in the Slave Geological Province (SGP). This work focuses on the analysis of six horizontal gradient magnetic and frequency domain EM (FDEM) surveys that were flown from February to March 2017 (Munn Lake, Margaret Lake, Zyena Lake, Lac de Gras West, Big Blue and Mackay Lake). All surveys were acquired at 75 m line spacing with nominal terrain clearance of 60 m to maintain bird height of 25 m. They total 4,580 line-km. We use the FDEM data to locate areas of potential remanent magnetization, and thus additional areas that could be related to kimberlite bodies. The area is part of the central Slave Craton, which is dominated by Archean granitoid rocks and Archean metasedimentary rocks. Heaman et al. (2013) identifies several distinct domains based on kimberlite ages in the area. Central Slave is characterized by Tertiary/Cretaceous age kimberlites, whereas the southern part exhibits kimberlites of Cambrian age. This have important implications for the orientation of the remanent magnetization vector. The methodology involves the use of a homogeneous half-space model to invert the data for dielectric permittivity, relative magnetic permeability, apparent resistivity and magnetic susceptibility. Using this model, we calculated Conductivity-Depth-Images (CDIs) for all the EM data. The susceptibility distribution from the EM data (MagEM) is then plotted against an apparent susceptibility derived from the total field data for the main survey via standard FFT calculation (MagTMI). Major differences between both distributions are usually associated to remanence. Once we identify areas of potential remanent magnetization, we use Helbig analysis to estimate the direction of magnetization. The validity of this model is verified by comparison of the computed remanence direction with the appropriate Apparent Polar Wander Path (APWP). We find a good correlation of APWP directions with the estimated remanence, however, a viscous remanence component subparallel to the present's day Earth field is sometimes required. Finally, we show the integration of these results with a structural interpretation of the aeromagnetic data and potential alteration zones derived from Aster imagery for all 6 blocks
DS201807-1533
2018
Underwood, E.Linking mantle plumes to volcanoes and hot spot tracks.Journal of Geophysical Research, DOI.org/ 101029/ 2018EO099733Mantlehotspots
DS201811-2615
2015
Unninayar, C.In search of Colombia's green dreams.InColor, December pp. 21-31.South America, Colombiaemeralds
DS201809-2105
2018
Usenko, O.B.Peridoization and specific features of deep processes in Precambrian by example of the Ukrainian shield.Geophysical Journal, Vol. 39, 6, pp. 41-83.Europe, Ukrainegeophysics - cycles

Abstract: Thorough information on geological structure of the Ukrainian shield (USh) allows to verify opinions existing nowadays that plume and plate tectonic activities are possible only after conclusive formation of sublithospheric mantle 2,8—2,55 Ga and plume episodes of Precambrian occurred 2,75—2,7, 2,45—2,4, 1,9, 1.8—1,75, 1,65 Ga ago. It can be proved nowadays that formation of the crust occurred before 4.0 Ga and plume events result in later transformation of not only crust but also of mantle. Isotope dating of the USh allows allocating of plume episodes in close-range time. Nevertheless these limits for the USh in many cases have connection with geological processes, because not detrite zircons are dated but those ones included in rocks. Individual episodes are united into lasting plume events (activizations) up to 3,2, 3,2—2,8, 2,7—2,3, 2,3—1,65 Ga. Special features of the structure of granite-greenstone area of the Middle Dnieper megablock of the USh support the opinion that before 2,7 Ga thick sub-continental lithosphere consisted of refractory peridotite did not exist. Crystallizable layer consists of relatively low-melt minerals and is enriched by basaltoid component. The thickness of crystallized layer reduces up to 100 and 50 km in case of addition of reheated deep matter and increases during crystallization up to 150—200 km. Asthenosphere compulsory contains the melt diluted by silicate-aqueous-carbonate fluide. After 2,7 Ga subdivision of the area into two big blocks occurred. At the mark of the Archean and Proterozoic (2,5 Ga ago) the territory of Ukraine was subdivided into blocks and territories which spatially were drawn towards suture zones. The composition of the terrains allows supposing that at the mark of the Archean and Proterozoic exarticulation of tectonic units where plume processes went in different ways occurred. The following plume event (2,3—2,65 Ga ago) was manifested as a stage of transformation of mantle and crust on all the cratons. In the structure of the USh obvious features of plate tectonic processes have been found. Movements maximal by amplitude occurred 2,0—1,8 Ga ago. During the process of this plume event abrupt change of composition of fluids and melts removed from the mantle occur. Granitization takes place with participation of aqueous chloride-potassium fluids. After granitization active dry carbonate-fluoride-sodium fluids became active. Removal of melts, fluids occurs by small portions and the regime of pulsating plume considerably specifies the composition of magmatic rocks and hydrothermal solutions.
DS201802-0272
2017
Ustinov, V.N.Conditions of formation of Mesozoic and Cenozoic diamond bearing rocks of north eastern Angola. ***IN RUSOtechestvennaya Geologiya ***IN RUS, No. 6, pp. 40-51. pdfAfrica, Angolakimberlite - pipes, placers, alluvials
DS201802-0273
2017
Ustinov, V.N.Lithological stratigraphic dissection and mineral composition of Mesozoic and Cenozoic diamond bearing rocks of the north eastern Angola. ***IN RUSOres and Metals ***IN RUS, no. 4, pp. 76-84. pdfAfrica, Angolakimberlite - stratigraphy
DS201805-0985
2018
Ustinov, V.N., Antaschuk, M.G., Zagainy, A.K., Kukui, I.M., Lobkova, L.P., Antonov, S.A.Prospects of diamond deposits discovery in the North of the East European platform. Karelian - KolaOres and Metals ***RUS, Vol. 1, pp. 11-26. ***RusRussiakimberlite, lamproite, dispersion haloes
DS201810-2386
2018
Ustinov, V.N., Bartolomeu, A.M.F., Zagainy, A.K., Felix, J.T., Mikoev, I.I., Stegnitskiy, Y.B., Lobkova, L.P., Kukui, I.M., Nikolaeva, E.V., Antonov. S.A.Kimberlites distribution in Angola and prospective areas for new discoveries.Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0628-1 14p.Africa, Angolakimberlites

Abstract: Based on a comprehensive analysis of kimberlite pipes of Angola, including the near surface structural setting, deep lithospheric structure, pipe morphology and emplacement, mineralogical and petrographic features, diamond characteristics and locations of secondary deposits four geographical regions have been outlined within Angola representing four types of diamond bearing potential. These areas include high diamond bearing potential pipes, possible potential, no potential, and unclear potential areas. It was found that the depth of magmatism and diamond potential of kimberlites increases from the Atlantic coast in southwestern Angola into the continent in the north-easterly direction. Areas prospective for the discovery of new primary diamond deposits have been identified.
DS201802-0274
2017
Ustinov, V.N., Golubev, Yu.K., Zagainy, A.K., Kukui, I.M., Mikoev, I.L., Lobkova, L.P., Antonov, S.A., Konkin, V.D.Analysis of the African province diamond prospects in relation to the Russia mineral base development abroad. *** IN RUSOtechestvennaya Geologiya ***IN RUS, No. 6, pp. 52-66. pdfAfricadiamond - arenas
DS201802-0275
2017
Ustinov, V.N., Golubev, Yu.K., Zagainy, A.K., Stegnitsky, Yu.B.The diamond bearing territories of Africa and their importance for expansion of the raw material base of the Russian diamond mining industry. ***IN RUSMineral Resources of Russia: economics and Management *** IN RUS, No. 6, pp. 66-72. pdfAfricadiamond - arenas
DS201802-0276
2017
Ustinov, V.N., Lobkova, L.P., Kukuy, I.M., Antashchuk, G., Nikolaeva, E.V.The Karelian Kola megacraton zoning on types of diamond primary sources. IN RUSGeology and Mineral Resources of Siberia *** IN RUS, No. 7, pp. 51-61.Russia, Kola Peninsulakimberlite - indicator minerals
DS201809-2106
2018
Ustinov, V.N., Mosigi, B., Kukui, I.M., Nikolaeva, E., Campbell, J.A.H., Stegnitskiy, Y.B., Antashchuk, M.G.Eolian indicator mineral dispersion haloes from the Orapa kimberlite cluster, Botswana.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0627-2 9p.Africa, Botswanadeposit - Orapa

Abstract: This paper presents the results of an investigation into the structure of eolian kimberlite indicator minerals (KIMs) haloes present within Quaternary Kalahari Group sediments (up to 20 m thick) overlying the Late Cretaceous kimberlites in the Orapa field in North-East Botswana. A database of more than 8000 samples shows that kimberlites create a general mineralogical blanket of KIMs of various distances of transportation from primary sources in the Orapa area. Models of the reflection and dispersion patterns of KIMs derived from kimberlite pipes including AK10/ AK22/AK23 have been revealed based on 200 selected heavy mineral samples collected during diamond prospecting activities in Botswana from 2014 to 2017. Short distance eolian haloes situated close to kimberlite bodies cover gentle slopes within plains up to 500 × 1000 m in size. They have regularly have oval or conical shapes and are characterized by the presence mainly of unabraded or only slightly abraded KIMs. A sharp reduction of their concentration from hundreds and thousands of grains / 20 l immediately above kimberlites toto 10 grains/20 l at a distance of only 100-200 m from the pipes is a standard feature of these haloes. The variation of concentration, morphology and abrasion of specific KIMs with increasing distance from the primary sources has been investigated and presented herein. Sample volumes recommended for pipes present within a similar setting as those studied, with different depth of sedimentary cover are as follows: up to 10-20 m cover at 20-50 l, 20-30 m cover at 50-100 l and 30-80 m cover at 250 l. It is important to appreciate that the discovery of even single grains of unabraded or slightly abraded KIMs in eolian haloes are of high prospecting significance in this area. The results of the research can be applied to in diamond prospecting programs in various regions with similar environments.
DS201809-2107
2018
Vadlamani, R., Bera, M.K., Samata, A., Mukherjee, S., Adhikari, A., Sarkar, A.Oxygen, Sr and Nd isotopic evidence from kyanite eclogite xenoliths ( KL-2 pipe, Wajrakarur) for pre 1.1 Ga mantle metasomatism in eastern Dharwar SCLM.Goldschmidt Conference, 1p. AbstractIndiadeposit - KL-2

Abstract: Kyanite-eclogite xenoliths from Wajrakarur are considered as remnants of subducted ocean-floor crust. Here trace element concentration and isotopic data are presented in garnet (Grt) and kyanite (Ky) from xenoliths KL-2 E1-E4, characterized by. We use the precise 87Sr/86Sr host kimberlite groundmass perovskite ratio (0.70312-0.70333, as a proxy for the extent of kimberlitic magma infiltration at 1.1 Ga. The xenolithic Grt and Cr-rich (upto 1506 ppm) Ky have more radiogenic 87Sr/86Sr values than kimberlite, at 1.1 Ga, of 0.703829-0.705203 and 0.703811-0.704502, respectively. Furthermore, the Grt and Ky 143Nd/144Nd ratios, at 1.1 Ga, are 0.509321-0.511372 and 0.510951-0.511156, respectively, and are distinctly lower than those of the host kimberlite (0.511870-0.512290). This indicates that the infiltration of kimberlitic fluid has not altered the 87Sr/86Sr and 143Nd/144Nd ratios in the Grt and Ky, and therefore their isotope compositions must be inherited and predate the kimberlite magma generation event at 1.1 Ga. Trace elements in Grt and Ky indicate extreme metasomatism (Sr in Grt 104-296 ppm, in Ky 672-8713 ppm [limit Sr<2ppm] and Nb in Grt 0.64-1.78 ppm, in Ky 1.7-4.54 ppm [limit Nb<0.5ppm]). The xenoliths underwent at least one major melting event inferred from extreme depletions in Re, Os and 177Os/178Os ratios [5]. Their mantle-like ?18O values (Grt 5.3-5.4‰, Ky 5.3-5.9‰), positive Eu anomalies in both Grt and Ky (similar to Group 1 HREE-depleted garnets of) suggests that the protolith likely was a chromite-bearing leucogabbro, emplaced as a high-pressure cumulate at the crust-mantle boundary, which was later eclogitized due to deep-seated subduction and underwent episodes of extreme melting and metasomatism before 1.1 Ga and at least before 1.7 Ga, as inferred from their youngest Re depletion dates.
DS201812-2895
2018
Valdir da Silveira, F.Overview of diamonds in Brazil.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazildiamond occurrence
DS201812-2896
2018
Valdir da Silveira, F.Project diamond Brazil.7th Symposio Brasileiro de Geologia do Diamante , Title only South America, Brazilprospecting
DS201805-0986
2018
van de Locht, J., Hoffmann, J.E., Li, C., Wang, Z., Becker, H., Rosing, M.T., Kleinschrodt, R., Munker, C.Earth's oldest mantle peridotites show entire record of late accretion.Geology, Vol. 46, 3, pp. 199-202.Europe, Greenlandperidotites

Abstract: An important issue in Earth’s earliest history is the timing and mixing history of the late accreted material that supplied highly siderophile elements to Earth’s mantle after core segregation. Previously, constraints on ancient mantle processes could only be obtained indirectly from mantle-derived magmas such as basalts or komatiites. Relics of Eoarchean (older than 3.8 Ga) mantle were proposed to occur within the Eoarchean terrains of western Greenland. Here we provide geochemical evidence, including combined platinum group element (PGE) and Re-Os isotope data, showing that modern mantle-like peridotites occur at two localities in southwest Greenland. Rhenium-depletion model ages of these peridotites are mostly of Eoarchean age, in accord with U-Pb zircon ages of crosscutting granitoid intrusives. PGE abundances and patterns are similar to those of modern depleted mantle peridotites. For the first time, such patterns provide conclusive evidence for preservation of Eoarchean depleted mantle rocks that are clearly distinguishable from magmatic cumulates or komatiites. Abundances of Os, Ir, and Ru combined with Os isotope compositions in the Greenland peridotites reveal that primitive late accreted material appears to have been efficiently mixed into the sampled mantle domains by Eoarchean time.
DS201811-2616
2018
van der Meer, D.G., van Hinsbergen, D.J.J., Spakman, W.Atlas of the underworld: slab remnants in the mantle, their sinking history, and a new outlook on lower mantle viscosity.Tectonophysics, Vol. 773, 1, pp. 309-448.Mantlegeophysics - seismic

Abstract: Across the entire mantle we interpret 94 positive seismic wave-speed anomalies as subducted lithosphere and associate these slabs with their geological record. We document this as the Atlas of the Underworld, also accessible online at www.atlas-of-the-underworld.org, a compilation comprising subduction systems active in the past ~ 300 Myr. Deeper slabs are correlated to older geological records, assuming no relative horizontal motions between adjacent slabs following break-off, using knowledge of global plate circuits, but without assuming a mantle reference frame. The longest actively subducting slabs identified reach the depth of ~ 2500 km and some slabs have impinged on Large Low Shear Velocity Provinces in the deepest mantle. Anomously fast sinking of some slabs occurs in regions affected by long-term plume rising. We conclude that slab remnants eventually sink from the upper mantle to the core-mantle boundary. The range in subduction-age versus - depth in the lower mantle is largely inherited from the upper mantle history of subduction. We find a significant depth variation in average sinking speed of slabs. At the top of the lower mantle average slab sinking speeds are between 10 and 40 mm/yr, followed by a deceleration to 10-15 mm/yr down to depths around 1600-1700 km. In this interval, in situ time-stationary sinking rates suggest deceleration from 20 to 30 mm/yr to 4-8 mm/yr, increasing to 12-15 mm/yr below 2000 km. This corroborates the existence of a slab deceleration zone but we do not observe long-term (> 60 My) slab stagnation, excluding long-term stagnation due to compositional effects. Conversion of slab sinking profiles to viscosity profiles shows the general trend that mantle viscosity increases in the slab deceleration zone below which viscosity slowly decreases in the deep mantle. This is at variance with most published viscosity profiles that are derived from different observations, but agrees qualitatively with recent viscosity profiles suggested from material experiments.
DS201801-0074
2017
van Hinsbergen, D.J., Lippert, P.C., Huang, W.Unfeasible subduction?Nature Geoscience, Vol. 10, 12, pp. 878-9.Mantlesubduction
DS201808-1794
2018
Varas-Reu, M.I., Garrido, C.J., Marchesi, C., Bosch, D., Hidas, K.Genesis of ultra high pressure garnet pyroxenites in orogenic peridotites and its bearing on the compositional heterogeneity of the Earth's mantle.Geochimica et Cosmochimica Acta, Vol. 232, pp. 303-328.Mantledeposit - Ronda, Beni Bousera

Abstract: We present an integrated geochemical study of ultra-high pressure (UHP) garnet pyroxenites from the Ronda and Beni Bousera peridotite massifs (Betic-Rif Belt, westernmost Mediterranean). Based on their Sr-Nd-Pb-Hf isotopic systematics, we classify UHP garnet pyroxenites into three groups: Group A pyroxenites (Al2O3: 15-17.5?wt.%) have low initial 87Sr/86Sr, relatively high ?Nd, ?Hf and 206Pb/204Pb ratios, and variable 207Pb/204Pb and 208Pb/204Pb. Group B pyroxenites (Al2O3?
DS201806-1258
2018
Varas-Reus, M.I., Garrido, C.J., Marchesi, C., Bosch, D., Hidas, K.Genesis of ultra-high pressure garnet pyroxenites in orogenic peridotites and its bearing on the compositional heterogeneity of the Earth's mantle. Ronda, Beni BouseraGeochimica et Cosmochimica Acta, Vol. 232, pp. 303-328.Africa, Morocco, Europe, SpainUHP

Abstract: We present an integrated geochemical study of ultra-high pressure (UHP) garnet pyroxenites from the Ronda and Beni Bousera peridotite massifs (Betic-Rif Belt, westernmost Mediterranean). Based on their Sr-Nd-Pb-Hf isotopic systematics, we classify UHP garnet pyroxenites into three groups: Group A pyroxenites (Al 2 O 3 : 15-17.5 wt. %) have low initial 87 Sr/ 86 Sr, relatively high ? Nd , ? Hf and 206 Pb/ 204 Pb ratios, and variable 207 Pb/ 204 Pb and 208 Pb/ 204 Pb. Group B pyroxenites (Al 2 O 3 < 14 wt. %) are characterized by high initial 87 Sr/ 86 Sr and relatively low ? Nd , ? Hf and 206 Pb/ 204 Pb ratios. Group C pyroxenites (Al 2 O 3 ~ 15 wt. %) have depleted radiogenic signatures with relatively low initial 87 Sr/ 86 Sr and 206 Pb/ 204 Pb, high ? Nd and ? Hf , and their 207 Pb/ 204 Pb and 208 Pb/ 204 Pb ratios are similar to those of Group B pyroxenites. The major and trace element and isotopic compositions of UHP garnet pyroxenites support their derivation from ancient (1.5-3.5 Ga) oceanic crust recycled into the mantle and intimately stirred with peridotites by convection. However, the genesis of these pyroxenites requires also the involvement of recycled continental lower crust with an isotopic composition akin to the lower crustal section of the lithosphere where these UHP garnet pyroxenites now reside in. These oceanic and continental crustal components were stirred in different proportions in the convective mantle, originating pyroxenites with a more marked geochemical imprint of either oceanic (Group A) or continental lower crust (Group B), or hybrid compositions (Group C). The pyroxenite protoliths likely underwent several melting events, one of them related to the formation of the subcontinental lithospheric mantle and continental crust, generating restitic UHP garnet pyroxenites now preserved in the Ronda and Beni Bousera orogenic peridotites. The extent of melting was mostly 3 controlled by the bulk Mg-number (Mg#) of the pyroxenite protoliths, where protoliths with low Mg# experienced higher degrees of partial melting than sources with higher Mg#. Positive Eu and Sr anomalies in bulk rocks, indicative of their origin from cumulitic crustal gabbros, are preserved mostly in high Mg# pyroxenites due to their higher melting temperatures and consequent lower partial melting degrees. The results of this study show that the genesis of UHP garnet pyroxenites in orogenic peridotites requires a new recipe for the marble cake mantle hypothesis, combining significant recycling and stirring of both oceanic and continental lower crust in the Earth's mantle. Furthermore, this study establishes a firm connection between the isotopic signatures of UHP pyroxenite heterogeneities in the mantle and the continental lower crust.
DS201804-0750
2018
Vasilev, Yu.R., Gora, M.P., Kuzmin, D.V.Foidite and meimechite lavas of Polar Siberia ( some questions of petrogenesis.Doklady Earth Sciences, Vol. 478, 1, pp. 103-107.Russia, Siberiapicrites

Abstract: For the Permian-Triassic foidite and meimechite lavas of Polar Siberia, both the whole-rock petrochemistry and geochemistry and that of melt inclusions in olivine phenocrysts from the same rocks have been demonstrated to be similar. In addition, their isotope characteristics imply the possibility of their generation from an abyssal parental melt compositionally resembling a high-Mg alkaline picrite.
DS201805-0987
2017
Vasiliev, E.A., Petrovsky, V.A., Kozlov, A.V., Antonov, A.V.Infrared spectroscope and internal structure of diamonds from the Ichhetju placer ( Middle Timan, Russia).*** IN RUSProceedings of the Russian Mineralogical Society *** IN RUS, Vol. 146, 2, pp. 58-72.Russiadeposit - Ichhetju
DS201805-0988
2018
Vasyukova, O.V., Williams-Jones, A.E.Direct measurement of metal concentrations in fluid inclusions, a tale of hydrothermal alteration and REE ore formation from Strange Lake, Canada.Chemical Geology, Vol. 483, pp. 385-396.Canada, Quebec, LabradorRare earths

Abstract: Granites and pegmatites in the Strange Lake pluton underwent extreme enrichment in high field strength elements (HFSE), including the rare earth elements (REE). Much of this enrichment took place in the most altered rocks, and is expressed as secondary minerals, showing that hydrothermal fluids played an important role in HFSE concentration. Vasyukova et al. (2016) reconstructed a P-T-X path for the evolution of these fluids and provided evidence that hydrothermal activity was initiated by exsolution of fluid during crystallisation of border zone pegmatites (at ~450-500?°C and 1.1?kbar). This early fluid comprised a high salinity (25?wt% NaCl) aqueous phase and a CH4?+?H2 gas. During cooling, the gas was gradually oxidised, first to higher hydrocarbons (e.g., C2H6, C3H8), and then to CO2, and the salinity decreased to 4?wt% (~250-300?°C), before increasing to 19?wt%, due to fluid-rock interaction (~150?°C). Here, we present crush-leach fluid inclusion data on the concentrations of the REE and major ligands at different stages of the evolution of the fluid. The chondrite-normalised REE profile of the fluid evolved from light REE (La-Nd)-enriched at high temperature (~400?°C, Stages 1-2a) to middle REE (Sm-Er)-enriched at 360 to 250?°C (Stages 2b-3) and strongly heavy REE (Tm-Lu)-enriched at low temperature (150?°C, Stage 5). These changes in the REE distribution were accompanied by changes in the concentrations of major ligands, i.e., Cl? was the dominant ligand in Stages 1, 2, 4 and 5, whereas HCO3? was dominant in Stage 3. Alteration of arfvedsonite to aegirine and/or hematite contributed strongly to the mobilisation of the REE. This alteration released middle REE (MREE) and heavy REE (HREE), which either partitioned into the fluid or precipitated directly as bastnäsite-(Ce), ferri-allanite-(Ce) or gadolinite-(Y). Replacement of primary fluorbritholite-(Ce), which crystallised from an immiscible fluoride melt and altered to bastnäsite-(Ce), was also important in mobilising the REE (MREE). This paper presents the first report of the distribution of the REE in an evolving hydrothermal fluid. Using this distribution, in conjunction with information on the changing physicochemical conditions, the study identifies the sources of REE enrichment, reconstructs the path of REE concentration, and evaluates the REE mineralising capacity of the fluid. Finally, this information is integrated into a predictive model for REE mobilisation applicable not only to Strange Lake but any REE ore-forming system, in which hydrothermal processes were important.
DS201803-0483
2018
Verard, C.Plate tectonic modelling: review and perspectives.Geological Magazine, in press available GlobalPlate tectonics

Abstract: Since the 1970s, numerous global plate tectonic models have been proposed to reconstruct the Earth's evolution through deep time. The reconstructions have proven immensely useful for the scientific community. However, we are now at a time when plate tectonic models must take a new step forward. There are two types of reconstructions: those using a ‘single control’ approach and those with a ‘dual control’ approach. Models using the ‘single control’ approach compile quantitative and/or semi-quantitative data from the present-day world and transfer them to the chosen time slices back in time. The reconstructions focus therefore on the position of tectonic elements but may ignore (partially or entirely) tectonic plates and in particular closed tectonic plate boundaries. For the readers, continents seem to float on the Earth's surface. Hence, the resulting maps look closer to what Alfred Wegener did in the early twentieth century and confuse many people, particularly the general public. With the ‘dual control’ approach, not only are data from the present-day world transferred back to the chosen time slices, but closed plate tectonic boundaries are defined iteratively from one reconstruction to the next. Thus, reconstructions benefit from the wealth of the plate tectonic theory. They are physically coherent and are suited to the new frontier of global reconstruction: the coupling of plate tectonic models with other global models. A joint effort of the whole community of geosciences will surely be necessary to develop the next generation of plate tectonic models.
DS201810-2387
2018
Vermeesch, P.Statistical models for point counting data. ( heavy mineral analysis or micropalynology)Earth and Planetary Science Letters, Vol. 501, pp. 112-118.Globalstatistics

Abstract: Point-counting data are a mainstay of petrography, micropalaeontology and palynology. Conventional statistical analysis of such data is fraught with problems. Commonly used statistics such as the arithmetic mean and standard deviation may produce nonsensical results when applied to point-counting data. This paper makes the case that point-counts represent a distinct class of data that requires different treatment. Point-counts are affected by a combination of (1) true compositional variability and (2) multinomial counting uncertainties. The relative magnitude of these two sources of dispersion can be assessed by a chi-square statistic and test. For datasets that pass the chi-square test for homogeneity, the ‘pooled’ composition is shown to represent the optimal estimate for the underlying population. It is obtained by simply adding together the counts of all samples and normalising the resulting values to unity. However, more often than not, point-counting datasets fail the chi-square test. The overdispersion of such datasets can be captured by a random effects model that combines a logistic normal population with the usual multinomial counting uncertainties. This gives rise to the concept of a ‘central’ composition as a more appropriate way to average overdispersed data. Two-or three-component datasets can be displayed on radial plots and ternary diagrams, respectively. Higher dimensional datasets may be visualised and interpreted by Correspondence Analysis (CA). This is a multivariate ordination technique that is similar in purpose to Principal Component Analysis (PCA). CA and PCA are both shown to be special cases of Multidimensional Scaling (MDS). Generalising this insight to multiple datasets allows point-counting data to be combined with other data types such as chemical compositions by means of 3-way MDS. All the techniques introduced in this paper have been implemented in theprovenanceR-package, which is available from http://provenance .london -geochron .com.
DS201801-0075
2018
Vezinet, A., Moyen, J-F., Stevens, G., Nicoli, G., Laurent, O., Couzinie, S., Frei, D.A record of 0.5 Ga of evolution of the continental crust along the northern edge of the Kaapvaal Craton, South Africa: consequences for the understanding of Archean geodynamic processes.Precambrian Research, Vol. 305, pp. 310-326.Africa, South Africacraton - Kaapvaal

Abstract: Geodynamics of crustal growth and evolution consist in one of the thorniest questions of the early Earth. In order to solve it, Archean cratons are intensively studied through geophysical, geochemical and geochronological investigations. However, timing and mechanisms leading to accretion and stabilization of crustal blocks are still under question. In this study, new information on the evolution of Archean cratons is provided through complementary approaches applied to the northern margin of the Archean Kaapvaal craton (KC). The study area comprises the Pietersburg Block (PB) and the terrane immediately adjacent to the North: the Southern Marginal Zone of the Limpopo Complex (SMZ). We present a comprehensive petro-metamorphic study coupled with LA-ICP-MS U-Pb isotope examination of both Na- and K-rich granitoids from the two areas. This dataset points toward a new interpretation of the northern KC (PB?+?SMZ). Two significant magmatic events are newly recognized: (i) a ca. 3.2?Ga event, and (ii) a protracted magmatic event between ca. 2.95–2.75?Ga. These events affected in both investigated areas and are unrelated to the ca. 2.7?Ga-old event usually attributed to the SMZ. More importantly, phase equilibrium modelling of several lithologies from the SMZ basement points to middle-amphibolite facies conditions of equilibration instead of granulite-facies conditions historically assumed. This study has both important regional and global implications. Firstly, the presence of a continuous basement from the Thabazimbi-Murchison Lineament to the Palala Shear Zone, different than Central Zone of the Limpopo Complex basement, implies a complete reviewing of the whole Limpopo Complex concept. Secondly, the geometry observed in the northern Kaapvaal craton is assumed to testify for a complete accretionary orogenic sequence with formation of both mafic and TTG lithologies through arc-back arc geodynamic. This was followed by a long-lived lateral compression triggering partial melting of the lower continental crust and emplacement of Bt-granitoids bodies that stabilizes the continental crust. Lastly, partial melting of the underlying enriched mantle stabilized the entire lithosphere allowing long-term preservation of the crustal block.
DS201807-1534
2018
Vietti, A.J.A strategy for improving water recovery in kimberlitic diamond mines. TSF VlariVie44 dosingSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 247-258.Globalwater - TSF

Abstract: Presentation: http://www.saimm.co.za/Conferences/Diamonds2018/P247-Vietti.pdf
DS201801-0076
2017
Viladakar, S.G.Pyroxene sovite in Amba Dongar carbonatite-alkalic complex, Gujarat.Journal of the Geological Society of India, Vol. 90, 5, pp. 591-594.Indiacarbonatite

Abstract: The present paper for the first times gives details of pyroxenesövites of Amba Dongar and discusses significance of these pyroxenes in evolution of carbonatite magma in Amba Dongar. Calciocarbonatite (sövite) forms the major mass of carbonatite in Amba Dongar complex. It shows large variation in texture and mineral composition and has complex evolutionary history. Three types of compositional variations are observed in sövite samples, (1) monomineralic sövites are coarse grained with 99% calcite, (2) sövites with abundant apatite, barite, pyrochlore, magnetite and zirconolite and (3) silico-sövite with of clinopyroxene and phlogopite. In the crystallization history of various sövite types, silico-sövite seems to have crystallized as an earlier phase and was later caught up in major sövite mass. Both, phlogopite-sövite and pyroxene-sövite are coarse grained and exhibit hypidiomorphic texture. Phlogopite is strongly zoned with Mg-rich core to Fe-rich rims. Pyroxenes also exhibit zoning with decrease in Ca and Mg and increase in Fe and Na from core to rim. In general composition of clinopyroxene varies from diopsidic to aegirine-augite. Pyroxenesövites show good concentration of Ba, Sr, Nb and LREE. Elevated concentrations of LREE are found in two aegirine-sövites.
DS201810-2388
2018
Viladkar, S.G.Ferrocarbonatites in the Amba Dongar diatreme, Gujarat, India.Journal of the Geological Society of India, Vol. 92, 2, pp. 141-144.Indiadeposit - Amba Dongar

Abstract: In the Amba Dongar diatreme, "ferrocarbonatite" is not a single unit of late differentiate of calciocarbonatite magma but it is a family with variation on field occurrence, mineralogy and chemistry of each unit. The family includes dikes of ankeritic carbonatites (phase I and II), plugs of ankeritic carbonatite within sövite ring dike, dikes of sideritic carbonatite in ankeritic carbonatite plug and rödberg veins. Their intrusive relations are very clear in the field and each phase has characteristic mineralogy and trace and REE geochemistry. According to the nomenclature suggested by Harmer and Gittins (1997) majority of "ferrocarbonatites" of Amba Dongar plot in field of "ferruginous calciocarbonatite" and only siderite and rödberg plot in the field of "ferrocarbonatite". Within these family members, their trace and REE show clear increase from early phase to last phase of sideritic carbonatite. The present short communication discusses various aspects of "ferrocarbonatites".
DS201812-2897
2018
Viljoen, K.S., Perritt, S.H., Chinn, I.L.An unusual suite of eclogitic, websteritic and transitional websteritic-lherzolitic diamonds from the Voorspoed kimberlite in South Africa: mineral inclusions and infrared characteristics.Lithos, Vol. 320-321, pp. 416-434.Africa, South Africadeposit - Voorspoed

Abstract: A study of the morphology, mineral inclusions, nitrogen content, and nitrogen aggregation state of diamonds from the Voorspoed kimberlite, was conducted. The diamonds are characterised by a highly unusual inclusion mineral paragenesis dominated by eclogitic and transitional websteritic-lherzolitic inclusions along with related websteritic inclusions, while a comparatively minor harzburgitic diamond inclusion suite account for the remainder. This differs substantially from many of the diamond populations in kimberlites on the Kaapvaal Craton where a harzburgitic inclusion paragenesis predominates. Only in the case of the Orapa kimberlite in Botswana has a similar diamond inclusion suite been encountered before, although in that instance an eclogitic and websteritic inclusion suite predominate. Calculated garnet-clinopyroxene equilibration temperatures, at an assumed pressure of 50?kbar, range from 1040 °C to 1296?°C. Temperatures of 1114?°C to 1348?°C, at 50?kbar, are calculated for lamellar orthopyroxene-clinopyroxene intergrowths. ‘Reconstituted’ pyroxenes mathematically reconstructed from the lamellar orthopyroxene-clinopyroxene intergrowths produce temperatures of 1238?°C to 1416?°C, suggesting that the lithosphere cooled by at least 100?°C after diamond crystallisation. Nitrogen contents and nitrogen aggregation states of whole diamonds range from below the detection limit (~10?ppm) to 1442 atomic ppm (average 167 atomic ppm), and up to 97% of the highly aggregated ‘B' component (average 65%), respectively. The elevated aggregation state of the nitrogen in the diamonds from Voorspoed, coupled with a high level of platelet degradation in many of the diamonds analysed, relative to a world-wide database, is unusual, but broadly comparable to diamonds from kimberlites occurring in craton margin settings, such as Argyle and Venetia. Diamond inclusion thermobarometry, as well as the elevated nitrogen aggregation states of the diamonds (coupled with the evidence for platelet degradation in the diamonds) are indicative of a diamond crystallisation event associated with a transient thermal pulse, as well as associated deformation of the mantle containing the diamonds. The websteritic and the transitional websteritic-lherzolitic mantle source rocks of the Voorspoed diamonds likely formed through melt infiltration into mantle peridotite, possibly in the reaction envelope surrounding an ascending mantle plume. In order to account for the unusually low abundance of harzburgitic diamonds at Voorspoed, it is postulated that a primary, pre-existing suite of harzburgitic diamonds which have crystallised in the Mesoarchaean, was destroyed through heating and oxidation during the passage of magmas associated with the Ventersdorp large igneous province at 2.72?Ga, and which was subsequently followed by the crystallisation of a younger eclogitic and transitional websteritic-lherzolitic suite of diamonds.
DS201802-0277
2017
Villa, I.M., Hanchar, J.M.Age discordance and mineralogy.American Mineralogist, Vol. 102, pp. 2422-2439.Technologygeochronology

Abstract: Observations of discordant ages, meaning that an age given by one mineral geochronometer is different from the age given by another geochronometer from the same rock, began in the early days of geochronology. In the late 1950s and 1960s, discordant U-Pb zircon ages were unquestioningly attributed to Pb diffusion at high temperature. Later, the mineralogical properties and the petrogenesis of the zircon crystals being dated was recognized as a key factor in obtaining concordant U-Pb ages. Advances in analytical methods allowed the analysis of smaller and smaller zircon multigrain fractions, then the analysis of individual grains, and even pieces of grains, with higher degrees of concordancy. Further advances allowed a higher analytical precision, a clearer perception of accuracy, and a better statistical resolution of age discordance. As for understanding the cause(s) of discordance, belief revision followed the coupling of imaging, cathodoluminescence (CL), and backscattered electrons (BSE), to in situ dating by secondary ion mass spectrometry (SIMS) or by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Discordant zircon and other accessory minerals (e.g., monazite, apatite, etc.) often consist of young rims accreted onto/into older cores. Age gradients are sharp, and no Pb diffusion gradients are observed. As U-Pb discordance in crystalline, non-radiation damaged grains is caused by diachronous, heterochemical mineral generations, interpretations of mineral ages, based on the exclusive role of diffusion, are superseded, and closure temperatures of zircon and monazite are irrelevant in geological reality. Other isotopic systems (Rb-Sr, K-Ar) were believed, since the 1960s, to be similarly controlled by the diffusivity of radiogenic daughters. When zircon and monazite discordance were recognized as zone accretion/reaction with sharp boundaries that showed little or no high-temperature diffusive re-equilibration, the other chronometric systems were left behind, and interpretations of mineral ages based on the exclusive role of diffusion survived. The evidence from textural-petrologic imaging (CL, BSE) and element mapping by electron probe microanalyzer (EPMA) or high spatial resolution SIMS or LA-ICP-MS provides the decisive constraints. All microcline and mica geochronometers that have been characterized in detail document patchy textures and evidence for mineral replacement reactions. It is important not to confuse causes and effects; hetero-chemical microstructures are not the cause of Ar and Sr loss; rather, they follow it. Ar and Sr loss by dissolution of the older mineral generation occurs first, heterochemical textures form later, when the replacive assemblage recrystallizes. Heterochemical mineral generations are identified and dated by their Ca/Cl/K systematics in 39Ar-40Ar. Replacive reactions adding or removing Cl, such as, e.g., sericite overgrowths on K-feldspar, retrograde muscovite intergrowths with phengite, etc. are detected by Cl/K vs. Ar/K isotope correlation diagrams. Ca-poor reaction products, such as, e.g., young biotite intergrown with older amphibole, adularia replacing microcline, etc., can be easily identified by Ca/K vs. Ar/K diagrams supported by EPMA analyses. Mixed mineral generations are observed to be the cause of discordant, staircase-shaped age spectra, while step-heating of crystals with age gradients produces concordant plateaus. Age gradients are therefore unrelated to staircase age spectra. There is a profound analogy between the U-Pb, Rb-Sr, and K-Ar systems. Pb and Ar diffusion rates are both much slower than mineral replacement rates for all T < 750 °C. Patchy retrogression textures are always associated with heterochemical signatures (U/Th ratios, REE patterns, Ca/Cl/K ratios). As a rule, single-generation minerals with low amounts of radiation damage give concordant ages, whereas discordance is caused by mixtures of heterochemical, resolvably diachronous, mineral generations in petrologic disequilibrium. This can also include (sub-)grains that have accumulated significant amounts of radiation damage. For accurate geochronology the petrologic characterization with the appropriate technique(s) of the minerals to be dated, and the petrologic context at large, are as essential as the mass spectrometric analyses.
DS201805-0989
2018
Vincente de Gouveia, S., Besse, J., Frizon de Lamotte, D., Greff-Lefftz, M., Lescanne, M., Gueydan, F., Leparmentier, F.Evidence of hot spot paths below Arabia and the Horn of Africa and consequences on the Red Sea opening.Earth Planetary Science Letters, Vol. 487, pp. 210-220.Africatectonics

Abstract: Rifts are often associated with ancient traces of hotspots, which are supposed to participate to the weakening of the lithosphere. We investigated the expected past trajectories followed by three hotspots (Afar, East-Africa and Lake-Victoria) located around the Red Sea. We used a hotspot reference frame to compute their location with respect to time, which is then compared to mantle tomography interpretations and geological features. Their tracks are frequently situated under continental crust, which is known to strongly filter plume activity. We looked for surface markers of their putative ancient existence, such as volcanism typology, doming, and heat-flow data from petroleum wells. Surface activity of the East-Africa hotspot is supported at 110 Ma, 90 Ma and 30 Ma by uplift, volcanic activity and rare gas isotopic signatures, reminiscent of a deep plume origin. The analysis of heat-flow data from petroleum wells under the Arabian plate shows a thermal anomaly that may correspond to the past impact of the Afar hotspot. According to derived hotspot trajectories, the Afar hotspot, situated (at 32 Ma) 1000 km north-east of the Ethiopian-Yemen traps, was probably too far away to be accountable for them. The trigger of the flood basalts would likely be linked to the East-Africa hotspot. The Lake-Victoria hotspot activity appears to have been more recent, attested only by Cenozoic volcanism in an uplifted area. Structural and thermal weakening of the lithosphere may have played a major role in the location of the rift systems. The Gulf of Aden is located on inherited Mesozoic extensional basins between two weak zones, the extremity of the Carlsberg Ridge and the present Afar triangle, previously impacted by the East-Africa hotspot. The Red Sea may have opened in the context of extension linked to Neo-Tethys slab-pull, along the track followed by the East Africa hotspot, suggesting an inherited thermal weakening.
DS201808-1795
2018
Voight, A., Morrison, G., Hill, G., Dellas, G., Mangera, R.The application of XRT in the De Beers Group of Companies. PresentationSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., 25 ppts.GlobalMining - XRT
DS201807-1535
2018
Voigt, A., Morrison, G., Hill, G., Dellas, G., Mangera, R.The application of XRT in the De Beers Group of Companies. Jwaneng, marineSAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 173-184.Africa, Botswana, NamibiaXRT sorters
DS201801-0077
2017
Vrublevskii, V.V., Morova, A.A., Bukharova, O.V., Konovalenko, S.I.Mineralogy and geochemistry of triassic carbonatites in the Matcha alkaline intrusive complex ( Turkestan-Alai Ridge, Kyrhyz southern Tien Shan), SW Central Asian orogenic belt.Journal of Asian Earth Sciences, in press availabe, 30p.Asia, Tien Shancarbonatites

Abstract: Postorogenic intrusions of essexites and alkaline and nepheline syenites in the Turkestan-Alai segment of the Kyrgyz Southern Tien Shan coexist with dikes and veins of carbonatites dated at ?220?Ma by the Ar-Ar and Rb-Sr age methods. They are mainly composed of calcite and dolomite (60-85%), as well as sodic amphibole, phlogopite, clinopyroxene, microcline, albite, apatite, and magnetite, with accessory niobate, ilmenite, Nb-rutile, titanite, zircon, baddeleyite, monazite-(Ce), barite, and sulfides. The rocks share mineralogical and geochemical similarity with carbonatites that originated by liquid immiscibility at high temperatures above 500?°C. Alkaline silicate and salt-carbonate melts are derived from sources with mainly negative bulk ?Nd(t) ? from ?11 to 0 and high initial 87Sr/86Sr ratios (?0.7061-0.7095) which may be due to mixing of PREMA and EM?type mantle material. Pb isotopic ratios in accessory pyrrhotite (206Pb/204Pb?=?18.38; 207Pb/204Pb?=?15.64; 208Pb/204Pb?=?38.41) exhibit an EM2 trend. The intrusions bear signatures of significant crustal contamination as a result of magma genesis by syntexis and hybridism. Concordant isotope composition changes of ?13C (?6.5 to ?1.9‰), ?18O (9.2-23‰), ?D (?58 to ?41‰), and ?34S (12.6-12.8‰) in minerals and rocks indicate inputs of crustal material at the stage of melting and effect of hot fluids released during dehydration of metamorphosed oceanic basalts or sediments. The observed HFSE patterns of the oldest alkaline gabbro may be due to interaction of the primary mafic magma with IAB-type material. The isotope similarity of alkaline rocks with spatially proximal basalts of the Tarim large igneous province does not contradict the evolution of the Turkestan-Alai Triassic magmatism as the “last echo” of the Tarim mantle plume.
DS201802-0278
2018
Vrublevskii, V.V., Morova, A.A., Bukharova, O.V., Konovalenko, S.I.Mineralogy and geochemistry of Triassic carbonatites in the Matcha alkaline intrusive complex ( Turkestan-Alai Ridge, Kyrgyz southern Tien Shan) sw central Asian orogenic belt.)Journal of Asian Earth Sciences, Vol. 153, pp. 252-281.Asiacarbonatite

Abstract: Postorogenic intrusions of essexites and alkaline and nepheline syenites in the Turkestan-Alai segment of the Kyrgyz Southern Tien Shan coexist with dikes and veins of carbonatites dated at ?220?Ma by the Ar-Ar and Rb-Sr age methods. They are mainly composed of calcite and dolomite (60-85%), as well as sodic amphibole, phlogopite, clinopyroxene, microcline, albite, apatite, and magnetite, with accessory niobate, ilmenite, Nb-rutile, titanite, zircon, baddeleyite, monazite-(Ce), barite, and sulfides. The rocks share mineralogical and geochemical similarity with carbonatites that originated by liquid immiscibility at high temperatures above 500?°C. Alkaline silicate and salt-carbonate melts are derived from sources with mainly negative bulk ?Nd(t) ? from ?11 to 0 and high initial 87Sr/86Sr ratios (?0.7061-0.7095) which may be due to mixing of PREMA and EM?type mantle material. Pb isotopic ratios in accessory pyrrhotite (206Pb/204Pb?=?18.38; 207Pb/204Pb?=?15.64; 208Pb/204Pb?=?38.41) exhibit an EM2 trend. The intrusions bear signatures of significant crustal contamination as a result of magma genesis by syntexis and hybridism. Concordant isotope composition changes of ?13C (?6.5 to ?1.9‰), ?18O (9.2-23‰), ?D (?58 to ?41‰), and ?34S (12.6-12.8‰) in minerals and rocks indicate inputs of crustal material at the stage of melting and effect of hot fluids released during dehydration of metamorphosed oceanic basalts or sediments. The observed HFSE patterns of the oldest alkaline gabbro may be due to interaction of the primary mafic magma with IAB-type material. The isotope similarity of alkaline rocks with spatially proximal basalts of the Tarim large igneous province does not contradict the evolution of the Turkestan-Alai Triassic magmatism as the “last echo” of the Tarim mantle plume.
DS201803-0484
2018
Vrubleyskii, V.V., Morova, A.A., Bukharova, O.V., Konovalenko, S.I.Mineralogy and geochemistry of Triassic carbonatites in the Matcha alkaline intrusive complex ( Turkestan Alai Ridge, Kyrgyz southern Tien Shan), SW central Asian orogenic belt.Journal of Asian Earth Sciences, Vol. 153, pp. 252-281.Asiacarbonatite
DS201811-2617
2018
Walter, B.F., Parsapoor, A., Braunger, S., Marks, M.A.W., Wenzel, T., Martin, M., Markl, G.Pyrochlore as a monitor for magmatic and hydrothermal processes in carbonatites from the Kaiserstuhl volcanic complex ( SW Germany).Chemical Geology, Vol. 498, pp. 1-16.Europe, Germanycarbonatite

Abstract: Pyrochlore from the Kaiserstuhl volcanic complex (SW Germany) shows textural and compositional differences between various coarse-grained calcite-carbonatite bodies (Badberg, Degenmatt, Haselschacher Buck, Orberg) and extrusive carbonatites (Henkenberg, Kirchberg). Oscillatory-zoned F-rich pyrochlore with up to 69?wt% Nb2O5 is common in all coarse-grained calcite-carbonatite bodies and probably formed during magmatic conditions. However, only in some of the samples from the Badberg, partly resorbed U- and Ta-enriched pyrochlore cores with up to 22?wt% UO2 and 9?wt% Ta2O5 have been identified, which are interpreted as being inherited from underlying nosean syenites. Pyrochlore data from a drill core penetrating the Badberg indicate increasing contents of REE, U, and Ta with depth, while Nb, F and Na contents decrease. This may reflect the combined effects of fractional crystallization and assimilation (AFC) or indicates a multi-stage emplacement of the carbonatitic magma. Patchy-zoned ceriopyrochlore and REE- and Th-enriched pyrochlore with up to 19?wt% total REE2O3 and 6.5?wt% ThO2 is largely restricted to samples from the Orberg and probably formed during hydrothermal conditions. This can be related to the relatively evolved character of the Orberg carbonatites, based on their relatively high whole-rock Nb/Ta and Zr/Hf mass ratios. This study demonstrates that the textural and compositional variation of pyrochlore in carbonatites is a powerful tool to distinguish magmatic, hydrothermal and weathering processes in carbonatitic systems.
DS201809-2109
2018
Walter, M.J., Drewitt, J.W.E., Thomson, A.R., Zhang, H., Lord, O.T., Heinen, B.The fate of carbonate in oceanic crust subducted into Earth's mantle.Goldschmidt Conference, 1p. AbstractMantlesubduction

Abstract: The H/C ratio in earth’s exosphere is higher than it is in the source region of primitive basalts, suggesting an enriched carbon reservoir in the mantle[1]. A plausible explanation is that subduction of carbon may have enriched the mantle in recycled carbon over time. Average basaltic crust contains ~ 2 wt.% CO2 [2], and modeling of slab devolatilisation suggests that subducted carbonate may survive to be transported deeper into the mantle [3]. Carbonated oceanic crust should melt in the transition zone along most subduction geotherms due to a deep trough in the carbonated basalt solidus, and mineral inclusions in superdeep diamonds testify to carbonate melt in their formation [4]. Along cool subduction geotherms carbonate may subduct into the lower mantle, potentially enriching the deep mantle in carbon. Here we report on laser-heated diamond anvil cell experiments in the CaO-MgO-SiO2-CO2 and FeO-MgO-SiO2-CO2 systems at lower mantle pressures where we investigate the stability of carbonate in oceanic crust, and test for decarbonation and diamond forming reactions involving carbonate and coexisiting free silica. We find that carbonate reacts with silica to form bridgmanite ± Ca-perovskite + CO2 at pressures in the range of ~50 to 70 GPa. These decarbonation reactions form an impenetrable barrier to subduction of carbonate into the deeper lower mantle, however, slabs may carry solid CO2 (Phase V) into the deeper lower mantle. We also identify reactions where carbonate or CO2 dissociate to form diamond plus oxygen. We suggest that the deep lower mantle may become enriched in carbon in the form of diamond over time due to subduction of carbonate and solid CO2 and its eventual dissociation to form diamond plus oxygen. Release of oxygen during diamond formation may also provide a mechanism for locally oxidizing the deep mantle.
DS201804-0751
2018
Wampler, J. , Thiemens, M., Schuller, I.Natural superconductivity observed in meteorites.Bulletin of the American Physical Society, Mar. 7, 2p.Technologymeteorites

Abstract: Previous studies have shown that meteorites can contain unusual natural phases, such as quasicrystals, that have otherwise been found only in synthetic samples [1]. Because of this, meteorites are good candidates to search for natural superconductivity, which has only been found in Covellite [2]. Because natural samples are inhomogeneous and superconducting phases can be very small, we used Magnetic Field Modulated Microwave Spectroscopy (MFMMS), which can detect 10-12 cc of superconducting material, three orders of magnitude better than Vibrating Sample Magnetometry (VSM). We measured a series of meteorites, surveying representative samples from most major categories of meteorites. In two of the meteorites, we discovered superconducting phases above 5 K using MFMMS, and verified this using VSM. We characterized these phases using Energy-dispersive X-ray spectroscopy and Inductively Coupled Plasma Mass Spectroscopy. To our knowledge, these samples are the first identification of extraterrestrial superconducting phases. They are particularly significant because these materials could be superconducting in extraterrestrial environments.
DS201803-0485
2018
Wang, D., Wang, X-L., Cai, Y., Goldstein, S.L., Yang, T.Do Hf isotopes in magmatic zircons represent those of their host rocks?Journal of Asian Earth Sciences, Vol. 154, pp. 202-212.Mantlezircons

Abstract: Lu-Hf isotopic system in zircon is a powerful and widely used geochemical tracer in studying petrogenesis of magmatic rocks and crustal evolution, assuming that zircon Hf isotopes can represent initial Hf isotopes of their parental whole rock. However, this assumption may not always be valid. Disequilibrium partial melting of continental crust would preferentially melt out non-zircon minerals with high time-integrated Lu/Hf ratios and generate partial melts with Hf isotope compositions that are more radiogenic than those of its magma source. Dissolution experiments (with hotplate, bomb and sintering procedures) of zircon-bearing samples demonstrate this disequilibrium effect where partial dissolution yielded variable and more radiogenic Hf isotope compositions than fully dissolved samples. A case study from the Neoproterozoic Jiuling batholith in southern China shows that about half of the investigated samples show decoupled Hf isotopes between zircons and the bulk rocks. This decoupling could reflect complex and prolonged magmatic processes, such as crustal assimilation, magma mixing, and disequilibrium melting, which are consistent with the wide temperature spectrum from ?630?°C to ?900?°C by Ti-in-zircon thermometer. We suggest that magmatic zircons may only record the Hf isotopic composition of their surrounding melt during crystallization and it is uncertain whether their Hf isotopic compositions can represent the primary Hf isotopic compositions of the bulk magmas. In this regard, using zircon Hf isotopic compositions to trace crustal evolution may be biased since most of these could be originally from disequilibrium partial melts.
DS201804-0752
2018
Wang, E., Unsworth, M., Chacko, T.Geoelectric structure of the Great Slave Lake shear zone in northwest Alberta: implications for structure and tectonic history.Canadian Journal of Earth Sciences, Vol. 55, pp. 295-307.Canada, Albertageophysics - electromagnetics, magnetotellurics

Abstract: The study of ancient plate boundaries can provide insights into the past and present-day tectonic processes. Here, we describe a magnetotellurics (MT) study of the Precambrian basement of the Hay River Fault (HRF) in northwest Alberta, which is the southwest segment of the Great Slave Lake shear zone. New broadband MT data were collected to give a clearer image of the crustal structure. The Western Canada Sedimentary Basin was imaged as a low-resistivity layer above the resistive crystalline basement. Four basement conductors were defined, and correlate with the terrane boundaries delineated with aeromagnetic data. These are (1) a major conductor in the Kiskatinaw domain, (2) a conductor on the boundary of the Ksituan and Chinchaga domains, (3) a conductor on the boundary of the Chinchaga and Buffalo Head domains, and (4) a conductor near the HRF. Both (1) and (2) correspond to areas of high seismic reflectivity. The low resistivity can be explained by interconnected grain boundary graphite or sulfide phases deposited by metamorphic fluid migration. The HRF was not definitively located in previous studies. The new data show that the HRF could be thin (1 km) or wide (10 km) and located at the boundary of the contrasting aeromagnetic anomalies or further to the north. Various tectonic processes are proposed to interpret the possible locations of the HRF. No electrical anisotropy structure is required to interpret the MT data in this study.
DS201801-0078
2017
Wang, H., van Hunen, J., Pearson, D.G.Making Archean cratonic roots by lateral compression: a two stage thickening and stabilization model.Tectonophysics, in press available, 10p.Mantlecraton

Abstract: Making Archean cratonic roots by lateral compression: a two stage thickening and stabilization model.
DS201805-0990
2018
Wang, H.A.O., Cartier, L.E., Baumgartner, L.P., Bouvier, A-S., Begue, F., Chalain, J-P., Krzemnicki, M.S.A preliminary SIMS study using carbon isotopes to separate natural from synthetic diamonds.Journal of Gemmology, Vol. 36, 1, pp. 38-43.Technologysynthetics
DS201806-1259
2018
Wang, L., Wang, S., Brown, M., Zhang, J., Feng, P., Jin, Z.M.On the survival of intergranular coesite in UHP eclogite.Journal of Metamorphic Geology, Vol. 36, 2, pp. 173-194.MantleUHP

Abstract: Coesite is typically found as inclusions in rock?forming or accessory minerals in ultrahigh?pressure (UHP) metamorphic rocks. Thus, the survival of intergranular coesite in UHP eclogite at Yangkou Bay (Sulu belt, eastern China) is surprising and implies locally “dry” conditions throughout exhumation. The dominant structures in the eclogites at Yangkou are a strong D2 foliation associated with tight?to?isoclinal F2 folds that are overprinted by close?to?tight F3 folds. The coesite?bearing eclogites occur as rootless intrafolial isoclinal F1 fold noses wrapped by a composite S1-S2 foliation in interlayered phengite?bearing quartz?rich schists. To evaluate controls on the survival of intergranular coesite, we determined the number density of intergranular coesite grains per cm2 in thin section in two samples of coesite eclogite (phengite absent) and three samples of phengite?bearing coesite eclogite (2-3 vol.% phengite), and measured the amount of water in garnet and omphacite in these samples, and also in two samples of phengite?bearing quartz eclogite (6-7 vol.% phengite, coesite absent). As coesite decreases in the mode, the amount of primary structural water stored in the whole rock, based on the nominally anhydrous minerals (NAMs), increases from 107/197 ppm H2O in the coesite eclogite to 157-253 ppm H2O in the phengite?bearing coesite eclogite to 391/444 ppm H2O in the quartz eclogite. In addition, there is molecular water in the NAMs and modal water in phengite. If the primary concentrations reflect differences in water sequestered during the late prograde evolution, the amount of fluid stored in the NAMs at the metamorphic peak was higher outside of the F1 fold noses. During exhumation from UHP conditions, where NAMs became H2O saturated, dehydroxylation would have generated a free fluid phase. Interstitial fluid in a garnet-clinopyroxene matrix at UHP conditions has dihedral angles >60°, so at equilibrium fluid will be trapped in isolated pores. However, outside the F1 fold noses strong D2 deformation likely promoted interconnection of fluid and migration along the developing S2 foliation, enabling conversion of some or all of the intergranular coesite into quartz. By contrast, the eclogite forming the F1 fold noses behaved as independent rigid bodies within the composite S1-S2 foliation of the surrounding phengite?bearing quartz?rich schists. Primary structural water concentrations in the coesite eclogite are so low that H2O saturation of the NAMs is unlikely to have occurred. This inherited drier environment in the F1 fold noses was maintained during exhumation by deformation partitioning and strain localization in the schists, and the fold noses remained immune to grain?scale fluid infiltration from outside allowing coesite to survive. The amount of inherited primary structural water and the effects of strain partitioning are important variables in the survival of coesite during exhumation of deeply subducted continental crust. Evidence of UHP metamorphism may be preserved in similar isolated structural settings in other collisional orogens.
DS201805-0991
2018
Wang, S.Absolute plate motions relative to deep mantle plumes.Earth Planetary Science Letters, Vol. 490, 1, pp. 88-99.Chinaplate tectonics

Abstract: Advances in whole waveform seismic tomography have revealed the presence of broad mantle plumes rooted at the base of the Earth's mantle beneath major hotspots. Hotspot tracks associated with these deep mantle plumes provide ideal constraints for inverting absolute plate motions as well as testing the fixed hotspot hypothesis. In this paper, 27 observed hotspot trends associated with 24 deep mantle plumes are used together with the MORVEL model for relative plate motions to determine an absolute plate motion model, in terms of a maximum likelihood optimization for angular data fitting, combined with an outlier data detection procedure based on statistical tests. The obtained T25M model fits 25 observed trends of globally distributed hotspot tracks to the statistically required level, while the other two hotspot trend data (Comores on Somalia and Iceland on Eurasia) are identified as outliers, which are significantly incompatible with other data. For most hotspots with rate data available, T25M predicts plate velocities significantly lower than the observed rates of hotspot volcanic migration, which cannot be fully explained by biased errors in observed rate data. Instead, the apparent hotspot motions derived by subtracting the observed hotspot migration velocities from the T25M plate velocities exhibit a combined pattern of being opposite to plate velocities and moving towards mid-ocean ridges. The newly estimated net rotation of the lithosphere is statistically compatible with three recent estimates, but differs significantly from 30 of 33 prior estimates.
DS201809-2110
2018
Wang, Y., Liu, X.Mixing behaviour between grossular and andradite: evidences from X-ray diffraction and Raman spectrum. SpectroscopyGoldschmidt Conference, 1p. AbstractMantlediamond inclusions

Abstract: Mineral inclusions in diamonds reflect the compositional features of the diamondiferous sources so that they can provide important information of the upper mantle and even the transition zone. Since Moore and Gurney (1985) [1] found majoritic garnet inclusions in kimberlitic diamonds, the majoritic garnet inclusions have become significant samples to understand deep earth processes. According to Kiseeva et al. (2018) [2], the majoritic garnet inclusions have a ferric iron fraction (Fe3+/?Fe) increasing with depth. Recently, Xu et al. (2017) [3] discovered some majoritic garnets (from a depth of ~ 400 km) with ferric iron proportions as high as 0.81. In order to understand the origin of these Fe3+-rich garnet inclusions, the physical-chemical properties of the Fe3+-bearing garnets should be investigated. So far, no many studies have been carried out though. In this study, we performed experiments to synthesize garnets with their compositions along the grossular-andradite binary at 3 GPa and 1100 - 1200 °C, in order to investigate the effect on the physical-chemical properties of replacing Al3+ with Fe3+ on the octahedral sites of the garnet. The synthetic samples were investigated by BSE, EMPA, powder XRD and unpolarized Raman spectroscopy. The garnets had grain sizes between 20 ~ 100 um as indicated by BSI, and had generally homogenous compositions as suggested by the EMPA data. Charge balance calculations showed that most garnets had ferric iron fractions exceeding ~0.95. With an approximately linear dependence of the lattice parameters on the composition, the volume-mixing behavior should be generally ideal. We collected multiple Raman spectra from each sample, and evaluated the effects of crystal orientation and compositional heterogeneity on the Raman peak positions. Relations between the garnet compositions and Raman peak frequencies were also analyzed. Most Raman modes show linear behavior across the binary, whereas some of them do not. The reasons have been explored. According to the results of this study, we can infer that the elastic properties of the grossular-andradite binary might be linearly dependent to the composition. The Raman spectroscopic data are important for deriving some important thermodynamic data.
DS201802-0279
2018
Wang, Z., Kusky, T.M., Capitanio, F.A.Water transportation ability of flat lying slabs in the mantle transition zone and implications for craton destruction.Tectonophysics, Vol. 723, pp. 95-106.Mantlesubduction

Abstract: Water transported by deep subduction to the mantle transition zone (MTZ) that is eventually released and migrates upwards is invoked as a likely cause for hydroweakening and cratonic lithosphere destruction. The destruction of the North China Craton (NCC) during the Mesozoic has been proposed to be related to hydroweakening. However, the source of water related to large-scale craton destruction in the NCC is poorly constrained. Some suggest that the water was mainly released from a flat-lying (or stagnating) slab in the MTZ, whereas others posit that most water was released from a previously existing strongly hydrous MTZ then perturbed by the stagnating subduction in the MTZ layer. In this study, we use numerical modeling to evaluate the water carrying ability of flat-lying slabs in the MTZ with different slab ages and water contents to simulate its maximum value and discuss its potential role on large-scale hydroweakening and craton destruction. Our results reveal that a single flat-lying slab in the MTZ cannot provide enough water for large-scale cratonic lithosphere hydroweakening and thinning. Water estimates invoked for craton destruction as experienced by the NCC can only be the result of long-term piling of multiple slabs in the MTZ or penetrating deeper into the lower mantle.
DS201810-2389
2018
Wang, Z., Kusky, T.M., Capitanio, F.A.On the role of the lower crust and midlithosphere discontinuity for cratonic lithosphere delamination and recycling.Geophysical Research Letters, Vol. 45, 15, pp. 7425-7433.Chinacraton

Abstract: We use numerical modeling mothed to study the lithosheric delamination in cratonic areas along the intralithosphere weak layers, including the lower crust and the midlithosphere dicontinuity. Our results show that delamination along the midlithosphere discontinuity can take place both near cratonic margins and within cratonic interiors without obvious intraplate deformation. However, delamination along lower crustal depths is mainly initiate at cratonic margins and can lead to intraplate orogeny.
DS201801-0079
2017
Wang, Z., Kusky, T.M., Capitano, F.A.Water transportation ability of flat lying slabs in the mantle transition zone and implications for craton destruction.Tectonophysics, in press available, 53p.Mantlesubduction

Abstract: Water transported by deep subduction to the mantle transition zone (MTZ) that is eventually released and migrates upwards is invoked as a likely cause for hydroweakening and cratonic lithosphere destruction. The destruction of the North China Craton (NCC) during the Mesozoic has been proposed to be related to hydroweakening. However, the source of water related to large-scale craton destruction in the NCC is poorly constrained. Some suggest that the water was mainly released from a flat-lying (or stagnating) slab in the MTZ, whereas others posit that most water was released from a previously existing strongly hydrous MTZ then perturbed by the stagnating subduction in the MTZ layer. In this study, we use numerical modeling to evaluate the water carrying ability of flat-lying slabs in the MTZ with different slab ages and water contents to simulate its maximum value and discuss its potential role on large-scale hydroweakening and craton destruction. Our results reveal that a single flat-lying slab in the MTZ cannot provide enough water for large-scale cratonic lithosphere hydroweakening and thinning. Water estimates invoked for craton destruction as experienced by the NCC can only be the result of long-term piling of multiple slabs in the MTZ or penetrating deeper into the lower mantle.
DS201807-1536
2018
Ware, B., Jourdan, F.40Ar/39/Ar geochronology of terrestrial pyroxene.Geochimica et Cosmochimica Acta, Vol. 230, pp. 112-130.Mantlegeochronology

Abstract: Geochronological techniques such as U/Pb in zircon and baddeleyite and 40Ar/39Ar on a vast range of minerals, including sanidine, plagioclase, and biotite, provide means to date an array of different geologic processes. Many of these minerals, however, are not always present in a given rock, or can be altered by secondary processes (e.g. plagioclase in mafic rocks) limiting our ability to derive an isotopic age. Pyroxene is a primary rock forming mineral for both mafic and ultramafic rocks and is resistant to alteration process but attempts to date this phase with 40Ar/39Ar has been met with little success so far.In this study, we analyzed pyroxene crystals from two different Large Igneous Provinces using a multi-collector noble gas mass spectrometer (ARGUS VI) since those machines have been shown to significantly improve analytical precision compared to the previous single-collector instruments. We obtain geologically meaningful and relatively precise 40Ar/39Ar plateau ages ranging from 184.6?±?3.9 to 182.4?±?0.8?Ma (2? uncertainties of ±1.8-0.4%) and 506.3?±?3.4?Ma for Tasmanian and Kalkarindji dolerites, respectively. Those data are indistinguishable from new and/or published U-Pb and 40Ar/39Ar plagioclase ages showing that 40Ar/39Ar dating of pyroxene is a suitable geochronological tool. Scrutinizing the analytical results of the pyroxene analyses as well as comparing them to the analytical result from plagioclase of the same samples indicate pure pyroxene was dated. Numerical models of argon diffusion in plagioclase and pyroxene support these observations. However, we found that the viability of 40Ar/39Ar dating approach of pyroxene can be affected by irradiation-induced recoil redistribution between thin pyroxene exsolution lamellae and the main pyroxene crystal, hence requiring careful petrographic observations before analysis. Finally, diffusion modeling show that 40Ar/39Ar of pyroxene can be used as a powerful tool to date the formation age of mafic rocks affected by greenschist metamorphism and will likely play an important role in high temperature thermochronology.
DS201809-2111
2018
Wei, S.S., Shearer, P.M.Compositional heterogeneities and flat slabs in the mid to lower mantle revealed by seismic reflected waves.Goldschmidt Conference, 1p. AbstractMantleolivine

Abstract: The mantle transition-zone discontinuities are usually attributed to isochemical phase transformations of olivine and its high-pressure polymorphs. However, recent seismic observations have shown complexities in these discontinuities that cannot be explained by conventional models of thermal variations. Here we analyze SS precursor stacking results to investigate global mantle transition-zone properties. The precursor waveforms provide information on the seismic velocity and density profiles across and near the major mantle discontinuities. A sporadic low-velocity layer immediately above the 410- km discontinuity is observed worldwide, including East Asia, western North America, eastern South America, and 33-50% of the resolved Pacific Ocean [1]. The 520-km discontinuity exhibits significant variations in its sharpness and depth, and occasionally appears to be split. A sub-discontinuity beneath 660 km is detected in some regions, possibly suggesting enrichment of garnet. All of these lateral variations show no geographical correlation with discontinuity topography or tomographic models of seismic velocity, suggesting that they are not caused by regional thermal anomalies. Alternatively, our observations can be explained by compositional heterogeneities in the mid-mantle, including major minerals and volatile content, which may result in additional phase transformations and partial melting. In addition, flat slabs that extend horizontally for at least a few thousand kilometers are imaged beneath several subduction zones at various depths in the lower mantle. This suggests a variety of slab sinking at different stages. A slab morphology in the lower mantle seems to be controlled by its individual evolution rather than specific changes in mantle rheology.
DS201808-1796
2018
Weiss, Y., Goldstein, S.L.The involvement of diamond forming fluids in the metasomatic 'cocktail' of kimberlite sources.Mineralogy and Petrology, doi.org/10.1007/s00710-018-0613-8 19p.Africa, South Africadeposit - Finsch

Abstract: Microinclusion-bearing diamonds offer the opportunity to investigate relationships between mantle metasomatism, diamond formation and kimberlite eruptions in intracratonic provinces. We have analyzed a suite of 7 microinclusion-bearing diamonds from the Finsch Group II kimberlite, South Africa, and identified two diamond populations: ‘Finsch IaA’ diamonds have nitrogen solely in A-centers and contain saline high-density-fluid (HDF) microinclusions, while ‘Finsch IaAB’ diamonds have nitrogen in both A- and B-centers (25-35% B-centers) and are characterized by carbonatite HDF compositions. Based on nitrogen aggregation states and estimates for mantle residence temperatures, we conclude that ‘Finsch IaA’ diamonds formed during a young saline metasomatic event that preceded kimberlite eruption by ~50 kyr to 15 Myr. The possible timing of metasomatism and formation of ‘Finsch IaAB’ diamonds by carbonatite HDFs is less constrained, and could have taken place between ~15 Myr and 2 Gyr before eruption. Two of the diamonds encapsulated omphacite microinclusions in association with saline or low-Mg carbonatitic-like HDF. We observe compositional differences for Al2O3 vs. CaO between these metasomatised omphacites, and also compared to omphacites in mantle eclogites which were identified as metasomatised by kimberlite or high-Mg carbonatite; suggesting a possible relationship between Al2O3 and CaO in metasomatised omphacite and the type of fluid/melt it interacted with. The combined data for microinclusion-bearing diamonds from the Finsch Group II kimberlite and the neighbouring Group I kimberlites at Koffiefontein and De Beers Pool indicate that a substantial volume of the southwest Kaapvaal deep lithosphere was impacted by saline metasomatism during Cretaceous time, and a direct relationship between saline metasomatism, diamond formation and the Kaapvaal late-Mesozoic ‘kimberlite bloom’. We therefore conclude that saline HDFs play a key role in the buildup of metasomatic mantle sources leading to kimberlite eruptions.
DS201805-0992
2018
Weiss, Y., Navon, O., Goldstein, S.L., Harris, J.W.Inclusions in diamonds constrain thermo-chemical conditions during Mesozoic metasomatism of the Kaapvaal cratonic mantle.Earth Planetary Science Letters, Vol. 491, pp. 134-147.Africa, South Africadeposit - De Beers-Pool

Abstract: Fluid/melt inclusions in diamonds, which were encapsulated during a metasomatic event and over a short period of time, are isolated from their surrounding mantle, offering the opportunity to constrain changes in the sub-continental lithospheric mantle (SCLM) that occurred during individual thermo-chemical events, as well as the composition of the fluids involved and their sources. We have analyzed a suite of 8 microinclusion-bearing diamonds from the Group I De Beers Pool kimberlites, South Africa, using FTIR, EPMA and LA-ICP-MS. Seven of the diamonds trapped incompatible-element-enriched saline high density fluids (HDFs), carry peridotitic mineral microinclusions, and substitutional nitrogen almost exclusively in A-centers. This low-aggregation state of nitrogen indicates a short mantle residence times and/or low mantle ambient temperature for these diamonds. A short residence time is favored because, elevated thermal conditions prevailed in the South African lithosphere during and following the Karoo flood basalt volcanism at ?180 Ma, thus the saline metasomatism must have occurred close to the time of kimberlite eruptions at ?85 Ma. Another diamond encapsulated incompatible-element-enriched silicic HDFs and has 25% of its nitrogen content residing in B-centers, implying formation during an earlier and different metasomatic event that likely relates to the Karoo magmatism at ca. 180 Ma. Thermometry of mineral microinclusions in the diamonds carrying saline HDFs, based on Mg-Fe exchange between garnet-orthopyroxene (Opx)/clinopyroxene (Cpx)/olivine and the Opx-Cpx thermometer, yield temperatures between 875-1080?°C at 5 GPa. These temperatures overlap with conditions recorded by touching inclusion pairs in diamonds from the De Beers Pool kimberlites, which represent the mantle ambient conditions just before eruption, and are altogether lower by 150-250?°C compared to P-T gradients recorded by peridotite xenoliths from the same locality. Oxygen fugacity differs as well. The calculated for the saline HDF compositions (to ?1.34) are higher by about a log unit compared with that recorded by xenoliths at 4-7 GPa. We conclude that enriched saline HDFs mediated the metasomatism that preceded Group I kimberlite eruptions in the southwestern Kaapvaal craton, and that their ‘cold and oxidized’ nature reflects their derivation from a deep subducting slab. This event had little impact on the temperature and redox state of the Kaapvaal lithosphere as a reservoir, however, it likely affected its properties along limited metasomatized veins and their wall rock. To reconcile the temperature and oxygen fugacity discrepancy between inclusions in diamonds and xenoliths, we argue that xenoliths did not equilibrate during the last saline metasomatic event or kimberlite eruption. Thus the P-T-gradients they record express pre-existing lithospheric conditions that were likely established during the last major thermal event in the Kaapvaal craton (i.e. the Karoo magmatism at ca. 180 Ma).
DS201809-2112
2018
Weiss,Y., Navon, O.., Goldstein, S.L., Harris, J.W.Inclusions in diamonds constrain thermo-chemical conditions of the Kaapvaal cratonic mantle.Goldschmidt Conference, 1p. AbstractAfrica, South Africadeposit - De Beers Pool

Abstract: Mineral and fluid/melt inclusions in diamonds, which are encapsulated and isolated during a metasomatic event, offer the opportunity to constrain changes in the sub-continental lithospheric mantle that occurred during individual thermochemical events. Fibrous diamonds from the Group I De Beers Pool kimberlites, South Africa (SA), trapped incompatibleelement enriched saline high-density fluids (HDFs) and peridotitic mineral microinclusions. Their substitutional nitrogen resides almost exclusively in A-centers. With regard to the elevated thermal conditions that prevailed in the SA lithosphere during and following Karoo volcanism at ~180 Ma, this low-aggregation state of nitrogen suggests a short mantle residence time, constraining the time of saline metasomatism to be close to the eruption of the kimberlites at ~85 Ma. Thermometry of mineral microinclusions yield temperatures between 875-1080 ºC (at 5 GPa). These temperatures overlap with conditions recorded by touching inclusion pairs, which represent the mantle ambient conditions just before eruption, and are altogether lower by 150-250°C compared to P-T gradients recorded by peridotite xenoliths from the same locality. In addition, the oxygen fugacity calculated for the saline HDF compositions (?log??O2(FMQ) = -2.5 to -1.3) are higher by about a log unit compared with that recorded by xenoliths at 4-7 GPa. We conclude that enriched saline HDFs mediated the metasomatism that preceded Group I kimberlite eruptions in the southwestern Kaapvaal craton, and that their ‘cold and oxidized’ nature reflects their derivation from a deep subducting slab. To reconcile the temperature and oxygen fugacity discrepancy between inclusions in diamonds and xenoliths, we argue that xenoliths did not equilibrate during the last saline metasomatic event or kimberlite eruption. Thus the P-T-??O2 gradients they record express pre-existing lithospheric conditions that were likely established during the last major thermal event in the Kaapvaal craton (i.e. the Karoo magmatism at ca. 180 Ma).
DS201809-2113
2018
Welford, K., Pearce, A., Geng, M., Dehler, S.A., Dickie, K.Crustal structure of Baffin Bay from constrained 3-D gravity inversion and deformable plate tectonic models. Geophysical Journal International, Vol. 214, 2, pp. 1281-1300. doi:1093/gji/ggy193Canada, NunavutGeophysics - gravity

Abstract: Mesozoic to Cenozoic continental rifting, breakup and spreading between North America and Greenland led to the opening, from south to north, of the Labrador Sea and eventually Baffin Bay between Baffin Island, northeast Canada and northwest Greenland. Baffin Bay lies at the northern limit of this extinct rift, transform and spreading system and remains largely underexplored. With the sparsity of existing crustal-scale geophysical investigations of Baffin Bay, regional potential field methods and quantitative deformation assessments based on plate reconstructions provide two means of examining Baffin Bay at the regional scale and drawing conclusions about its crustal structure, its rifting history and the role of pre-existing structures in its evolution. Despite the identification of extinct spreading axes and fracture zones based on gravity data, insights into the nature and structure of the underlying crust have only been gleaned from limited deep seismic experiments, mostly concentrated in the north and east where the continental shelf is shallower and wider. Baffin Bay is partially underlain by oceanic crust with zones of variable width of extended continental crust along its margins. 3-D gravity inversions, constrained by bathymetric and depth to basement constraints, have generated a range of 3-D crustal density models that collectively reveal an asymmetric distribution of extended continental crust, approximately 25-30?km thick, along the margins of Baffin Bay, with a wider zone on the Greenland margin. A zone of 5-13?km thick crust lies at the centre of Baffin Bay, with the thinnest crust (5?km thick) clearly aligning with Eocene spreading centres. The resolved crustal thicknesses are generally in agreement with available seismic constraints, with discrepancies mostly corresponding to zones of higher density lower crust along the Greenland margin and Nares Strait. Deformation modelling from independent plate reconstructions using GPlates of the rifted margins of Baffin Bay was performed to gauge the influence of original crustal thickness and the width of the deformation zone on the crustal thicknesses obtained from the gravity inversions. These results show the best match with the results from the gravity inversions for an original unstretched crustal thickness of 34-36?km, consistent with present-day crustal thicknesses derived from teleseismic studies beyond the likely continentward limits of rifting around the margins of Baffin Bay. The width of the deformation zone has only a minimal influence on the modelled crustal thicknesses if the zone is of sufficient width that edge effects do not interfere with the main modelled domain.
DS201801-0080
2017
Wenker, S., Beaumont, C.Can metasomatic weakening result in the rifting of cratons?Tectonophysics, in press available, 19p.China, Canada, Africa, Tanzaniametasomatism

Abstract: Cratons are strong and their preservation demonstrates that they resist deformation and fragmentation. Yet several cratons are rifting now, or have rifted in the past. We suggest that cratons need to be weakened before they can rift. Specifically, metasomatism of the depleted dehydrated craton mantle lithosphere is a potential weakening mechanism. We use 2D numerical models to test the efficiency of simulated melt metasomatism and coeval rehydration to weaken craton mantle lithosphere roots. These processes effectively increase root density through a parameterized melt-peridotite reaction, and reduce root viscosity by increasing the temperature and rehydrating the cratonic mantle lithosphere. The models are designed to investigate when a craton is sufficiently weakened to undergo rifting and is no longer protected by adjacent standard Phanerozoic lithosphere. We find that cratons only become vulnerable to rifting following large-volume melt metasomatism (~ 30% by volume) and thinning of the gravitationally unstable cratonic lithosphere from > 250 km to ~ 100 km; at which point its residual crustal strength is important. Furthermore, our results indicate that rifting of cratons depends on the timing of extension with respect to metasomatism. An important effect in the large-volume melt models is the melt-induced increase in temperature which must have time to reach peak values in the uppermost mantle lithosphere before rifting. Release of water stored in the transition zone at the base of a big mantle wedge may provide a suitable natural setting for both rehydration and refertilization of an overlying craton and is consistent with evidence from the eastern North China Craton. An additional effect is that cratons subside isostatically to balance the increasing density of craton mantle lithosphere where it is moderately metasomatized. We suggest that this forms intracratonic basins and that their subsidence and subsequent uplift, and cratonic rifting constitute evidence of progressive metasomatism of cratonic mantle lithosphere.
DS201812-2898
2018
Wickham, A.P., Winternurn, P.A., Elliott, B.Till geochemistry and lithogeochemical exploration for a concealed kimberlite.2018 Yellowknife Geoscience Forum , p. 88-89. abstractCanada, Northwest Territoriesdeposit - Kelvin

Abstract: Research at the Kelvin kimberlite, NWT is defining surface exploration practices and developing new exploration tools based on host rock lithogeochemical alteration, that will result in reduced costs and improved discovery success. In regions where recent glaciation has buried kimberlites under glacial sediments, surface geochemical detection methods are best interpreted when coupled with a comprehension of the landscape formation processes. The glacial, post-glacial, and cryoturbation processes that have affected the landscape have, in turn, affected the dispersal of geochemical signatures in the till that can be detected and exploited by detailed surface mapping, sampling, and geochemical analysis. Additionally, the application of geochemical and hyperspectral data to country rock alteration core can aid in the detection of kimberlites during near-miss drilling campaigns. The Kelvin kimberlite is located eight kilometers from the Gahcho Kué diamond mine in the Northwest Territories. The inclined pipe sub-crops beneath a lake and dips into gneiss country rock towards the northwest with a surface projection of more than 600 m long. Relative uniformity of surficial material (<6 m thick till veneer) allows for extensive b-horizon soil sampling above the kimberlite, up-ice, and up to 1 km in the down-ice direction. Samples were sieved to -180 microns and analyzed by four acid digest ICP-MS and aqua-regia digest ICP-MS. Results indicate the soils to be very immature and identify the presence of a subtle Ni-Cr-Mg-Nb train originating from the lake side extending for >1km from source following the most recent ice direction to the west. The material for the train was abraded by the ice from the kimberlite, now sub-cropping beneath a lake, and would have provided additional support to drill what was initially targeted from geophysics. Additional research is being carried out to detect alteration signatures in the country rock induced by the emplacement of the kimberlite. Lithogeochemical data from four drill holes aims to identify and quantify the metasomatic enrichment and depletion of elements sourced from the kimberlite while accounting for country-rock lithology variation. Hyperspectral imaging of the same drill core will aim to detect and quantify secondary mineralogy and subtle changes in mineral composition that otherwise cannot be detected visually. This data will be used to generate mineralogical and chemical vectors beneficial in near-miss situations when drilling kimberlites and defining diatreme geometries.
DS201806-1260
2018
Wiemar, D., Schrank, C.E., Murphy, D.T., Wenham, L., Allen, C.M.Earth's oldest stable crust in the Pilbara craton formed by cyclic gravitational overturns.Nature , Vol. 11, 5, pp. 357-361.Australiageophysics

Abstract: During the early Archaean, the Earth was too hot to sustain rigid lithospheric plates subject to Wilson Cycle-style plate tectonics. Yet by that time, up to 50% of the present-day continental crust was generated. Preserved continental fragments from the early Archaean have distinct granite-dome/greenstone-keel crust that is interpreted to be the result of a gravitationally unstable stratification of felsic proto-crust overlain by denser mafic volcanic rocks, subject to reorganization by Rayleigh-Taylor flow. Here we provide age constraints on the duration of gravitational overturn in the East Pilbara Terrane. Our U-Pb ages indicate the emplacement of ~3,600-3,460-million-year-old granitoid rocks, and their uplift during an overturn event ceasing about 3,413?million years ago. Exhumation and erosion of this felsic proto-crust accompanied crustal reorganization. Petrology and thermodynamic modelling suggest that the early felsic magmas were derived from the base of thick (~43?km) basaltic proto-crust. Combining our data with regional geochronological studies unveils characteristic growth cycles on the order of 100?million years. We propose that maturation of the early crust over three of these cycles was required before a stable, differentiated continent emerged with sufficient rigidity for plate-like behaviour.
DS201807-1537
2018
Williams, Q.The thermal conductivity of Earth's core: a key geophysical parameter's constraints and uncertainties.Annual Review of Earth and Planetary Sciences, Vol. 46, pp. 47-66.Mantlegeothermometry

Abstract: The thermal conductivity of iron alloys at high pressures and temperatures is a critical parameter in governing (a) the present-day heat flow out of Earth's core, (b) the inferred age of Earth's inner core, and (c) the thermal evolution of Earth's core and lowermost mantle. It is, however, one of the least well-constrained important geophysical parameters, with current estimates for end-member iron under core-mantle boundary conditions varying by about a factor of 6. Here, the current state of calculations, measurements, and inferences that constrain thermal conductivity at core conditions are reviewed. The applicability of the Wiedemann-Franz law, commonly used to convert electrical resistivity data to thermal conductivity data, is probed: Here, whether the constant of proportionality, the Lorenz number, is constant at extreme conditions is of vital importance. Electron-electron inelastic scattering and increases in Fermi-liquid-like behavior may cause uncertainties in thermal conductivities derived from both first-principles-associated calculations and electrical conductivity measurements. Additional uncertainties include the role of alloying constituents and local magnetic moments of iron in modulating the thermal conductivity. Thus, uncertainties in thermal conductivity remain pervasive, and hence a broad range of core heat flows and inner core ages appear to remain plausible.
DS201801-0081
2018
Wilson, D., Amos, R.T., Blowes, D.W., Langman, J.B., Ptacek, C.J., Smith, L., Sego, D.C.Diavik waste rock project: a conceptual model for temperature and sulfide content dependent geochemical evolution of waste rock - Laboratory scale.Applied Geochemistry, Vol. 89, pp. 160-172.Canada, Northwest Territoriesdeposit - Diavik

Abstract: The Diavik Waste Rock Project consists of laboratory and field experiments developed for the investigation and scale-up of the geochemical evolution of sulfidic mine wastes. As part of this project, humidity cell experiments were conducted to assess the long-term geochemical evolution of a low-sulfide waste rock. Reactive transport modelling was used to assess the significant geochemical processes controlling oxidation of sulfide minerals and their dependence on temperature and sulfide mineral content. The geochemical evolution of effluent from waste rock with a sulfide content of 0.16 wt.% and 0.02 wt.% in humidity cells was simulated with the reactive transport model MIN3P, based on a conceptual model that included constant water flow, sulfide mineral content, sulfide oxidation controlled by the availability of oxidants, and subsequent neutralization reactions with carbonate and aluminosilicate minerals. Concentrations of Ni, Co, Cu, Zn, and SO4 in the humidity cell effluent were simulated using the shrinking core model, which represented the control of oxidant diffusion to the unreacted particle surface in the sulfide oxidation process. The influence of temperature was accounted for using the Arrhenius relation and appropriate activation energy values. Comparison of the experiment results, consisting of waste rock differentiated by sulfide mineral content and temperature, indicated surface area and temperature play important roles in rates of sulfide oxidation and release of sulfate and metals. After the model was calibrated to fit the effluent data from the higher sulfide content cells, subsequent simulations were conducted by adjusting only measured parameters, including sulfide mineral content and surface area.
DS201809-2115
2018
Wilson, D., Amos, R.T., Blowes, D.W., Langman, J.B., Smith, L., Sego, D.C.Diavik waste rock project: Scale up of a reactive transport model for temperature and sulfide content dependent geochemical evolution of waste rock.Applied Geochemisty, Vol. 96, pp. 177-190.Canada, Northwest Territoriesdeposit - Diavik

Abstract: The Diavik Waste Rock Project, located in a region of continuous permafrost in northern Canada, includes complementary field and laboratory experiments with the purpose of investigating scale-up techniques for the assessment of the geochemical evolution of mine waste rock at a large scale. As part of the Diavik project, medium-scale field experiments (?1.5?m high active zone lysimeters) were conducted to assess the long term geochemical evolution and drainage of a low-sulfide waste rock under a relatively simple (i.e. constrained by the container) flow regime while exposed to atmospheric conditions. A conceptual model, including the most significant processes controlling the sulfide-mineral oxidation and weathering of the associated host minerals as observed in a laboratory humidity cell experiment, was developed as part of a previous modelling study. The current study investigated the efficacy of scaling the calibrated humidity cell model to simulate the geochemical evolution of the active zone lysimeter experiments. The humidity cell model was used to simulate the geochemical evolution of low-sulfide waste rock with S content of 0.053?wt.% and 0.035?wt.% (primarily pyrrhotite) in the active zone lysimeter experiments using the reactive transport code MIN3P. Water flow through the lysimeters was simulated using temporally variable infiltration estimated from precipitation measurements made within 200?m of the lysimeters. Flow parameters and physical properties determined during previous studies at Diavik were incorporated into the simulations to reproduce the flow regime. The geochemical evolution of the waste-rock system was simulated by adjustment of the sulfide-mineral content to reflect the values measured at the lysimeters. The temperature dependence of the geochemical system was considered using temperature measurements taken daily, adjacent to the lysimeters, to correct weathering rates according to the Arrhenius equation. The lysimeter simulations indicated that a model developed from simulations of laboratory humidity cell experiments, incorporating detailed representations of temporally variable temperature and water infiltration, can be scaled to provide a reasonable assessment of geochemical evolution of the medium-scale field experiments.
DS201809-2116
2018
Wilson, D., Sinclair, S.A., Blowes, D.W., Amos,R.T., Smith, L., Sego, D.C.Diavik waste rock project: analysis of measured and simulated acid neutralization processes within a large scale field experiment.Goldschmidt Conference, 1p. AbstractCanada, Northwest Territoriesdeposit - Diavik

Abstract: The geochemical evolution of mine-waste rock often includes concurrent acid generation and neutralization processes. Deposition of mine-waste rock in large, oxygenated, and partially saturated piles can result in release of metals and decreased pH from weathering of sulfide minerals. Acid neutralization processes can often mitigate metals and pH impacts associated with sulfide oxidation. The Diavik Waste Rock Project included large field experiments (test piles built in 2006) conducted to characterize weathering of sulfide waste rock at a scale representative of full size waste-rock piles. Water samples from the unsaturated interior of one of the test piles, constructed of waste rock with ~0.05 wt.% S, were collected using soil water solution samplers and drains at the base of the pile. Field observations indicated pH decreased throughout the depth of the pile during 2008 and 2009 and that carbonate mineral buffering was entirely depleted by 2011 or 2012. Carbonate mineral exhaustion was accompanied by increased concentrations of dissolved Al and Fe in effluent samples collected at the basal drains. These results suggest that dissolution of Al and Fe(oxy)hydroxides occurred after the depletion of carbonate minerals following an acid neutralization sequence that is similar to observations made by previous researchers. A conceptual model of acid neutralization proceses within the pile, developed using physical and geochemical measurements conducted from 2008 to 2012, was used to inform reactive transport simulations conducted in 2017 to quantify the dominant acid neutralization processes within the test pile interior. Reactive transport simulations indicate that the conceptual model developed using the results of field samples provides a reasonable assessment of the evolution of the acid neutralization sequence.
DS201802-0280
2017
Wong, J., Verdel, C., Allen, C.M.Trace element compositions of sapphire and ruby from the eastern Australian gemstone belt.Mineralogical Magazine, Vol. 81, 6, pp. 1551-1576.Australiamineralogy

Abstract: View at publisher (open access) Abstract Significant uncertainty surrounds the processes involved in the formation of basalt-hosted corundum, particularly the role that the mantle plays in corundum generation. Some previous studies have suggested that trace-element ratios (namely, Cr/Ga and Ga/Mg) are useful for distinguishing two types of corundum: “magmatic” and “metamorphic,” designations that include mantle and crustal processes. However, recent studies, including this one, have discovered transitional groups between these end-members that are difficult to classify. We used LA-ICP-MS to measure trace-element concentrations in sapphire and ruby crystals from eight alluvial deposits that span a significant length of the eastern Australian gemstone belt. Additionally, we collected LA-ICP-MS U-Pb and trace-element data from zircon megacrysts at Weldborough, Tasmania, which is also within the gemstone belt. Our sapphire and ruby results reveal a continuum in trace-element compositions, a finding that raises questions about previous classifications that ascribe corundum from basalt-hosted gemfields to either “magmatic” or “metamorphic” sources. The spatial association of basalt-related gemfields in eastern Australia with a long-lived convergent margin suggests a link between corundum formation and Al-enrichment of the mantle wedge during periods of subduction.
DS201804-0753
2018
Wong, J., Verdel, C., Allen, C.M.Trace element compositions of sapphire and ruby from the eastern Australian gemstone belt.Mineralogical Magazine, Vol. 81, 6, pp. 1551-1576.Australia, Tasmaniacorundum classification

Abstract: Significant uncertainty surrounds the processes involved in the formation of basalt-hosted corundum, particularly the role that the mantle plays in corundum generation. Some previous studies have suggested that trace-element ratios (namely, Cr/Ga and Ga/Mg) are useful for distinguishing two types of corundum: ‘magmatic’ and ‘metamorphic’, designations that include mantle and crustal processes. However, recent studies, including this one, have discovered transitional groups between these end-members that are difficult to classify. We used laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to measure trace-element concentrations in sapphire and ruby crystals from eight alluvial deposits that span a significant length of the eastern Australian gemstone belt. Additionally, we collected LA-ICP-MS U-Pb and trace-element data from zircon megacrysts at Weldborough, Tasmania, which is also within the gemstone belt. Our sapphire and ruby results reveal a continuum in trace-element compositions, an observation that raises questions regarding previous classifications that ascribe corundum from basalt-hosted gemfields to either ‘magmatic’ or ‘metamorphic’ sources. The spatial association of basalt-related gemfields in eastern Australia with a long-lived convergent margin suggests a link between corundum formation and Al-enrichment of the mantle wedge during periods of subduction.
DS201802-0281
2018
Wyman, D.Do cratons preserve evidence of stagnant lid tectonics? Superior ProvinceGeoscience Frontiers, Vol. 9, pp. 3-17.Mantleplumes

Abstract: Evidence for episodic crustal growth extending back to the Hadean has recently prompted a number of numerically based geodynamic models that incorporate cyclic changes from stagnant lid to mobile lid tectonics. A large part of the geologic record is missing for the times at which several of these cycles are inferred to have taken place. The cratons, however, are likely to retain important clues relating to similar cycles developed in the Mesoarchean and Neoarchean. Widespread acceptance of a form of plate tectonics by ?3.2 Ga is not at odds with the sporadic occurrence of stagnant lid tectonics after this time. The concept of scale as applied to cratons, mantle plumes and Neoarchean volcanic arcs are likely to provide important constraints on future models of Earth's geodynamic evolution. The Superior Province will provide some of the most concrete evidence in this regard given that its constituent blocks may have been locked into a stagnant lid relatively soon after their formation and then assembled in the next global plate tectonic interval. Perceived complexities associated with inferred mantle plume - volcanic arc associations in the Superior Province and other cratons may be related to an over estimation of plume size. A possible stagnant lid episode between ?2.9 Ga and ?2.8 Ga is identified by previously unexplained lapses in volcanism on cratons, including the Kaapvaal, Yilgarn and Superior Province cratons. If real, then mantle dynamics associated with this episode likely eliminated any contemporaneous mantle plume incubation sites, which has important implications for widespread plumes developed at ?2.7 Ga and favours a shallow mantle source in the transition zone. The Superior Province provides a uniquely preserved local proxy for this global event and could serve as the basis for detailed numerical models in the future.
DS201812-2899
2018
Xia, X.Mineral inclusions in diamonds from Chidliak ( Nunavut, Canada): constraining the diamond substrates.Thesis, Msc. University of Alberta, 112p. Pdf availableCanada, Nunavutdeposit - Chidliak
DS201811-2618
2019
Xie, Y., Qu, Y., Zhong, R., Verplanck, P.L., Meffre, S., Xu, D.The ~1.85 Ga carbonatite in north China and its implications on the evolution of the Columbia supercontinent.Gondwana Research, Vol. 65, pp. 125-141.Chinacarbonatite

Abstract: Mantle-derived carbonatites provide a unique window in the understanding of mantle characteristics and dynamics, as well as insight into the assembly and breakup of supercontinents. As a petrological indicator of extensional tectonic regimes, Archean/Proterozoic carbonatites provide important constraints on the timing of the breakup of ancient supercontinents. The majority of the carbonatites reported worldwide are Phanerozoic, in part because of the difficulty in recognizing Archean/Proterozoic carbonatites, which are characterized by strong foliation and recrystallization, and share broad petrologic similarities with metamorphosed sedimentary lithologies. Here, we report the recognition of a ~1.85?Ga carbonatite in Chaihulanzi area of Chifeng in north China based on systematic geological, petrological, geochemical, and baddeleyite U-Pb geochronological results. The carbonatite occurs as dikes or sills emplaced in Archean metasedimentary rocks and underwent intense deformation. Petrological and SEM/EDS results show that calcite and dolomite are the dominant carbonate minerals along with minor and varied amounts of Mg-rich mafic minerals, including forsterite (with Fo?>?98), phlogopite, diopside, and an accessory amount of apatite, baddeleyite, spinel, monazite, and ilmenite. The relatively high silica content together with the non-arc and OIB-like trace element signatures of the carbonatite indicates a hot mantle plume as the likely magma source. The depleted Nd isotopic signatures suggest that plume upwelling might be triggered by the accumulation of recycled crust in the deep mantle. As a part of the global-scale Columbia supercontinent, the Proterozoic tectonic evolution of the North China Craton (NCC) provides important insights into the geodynamics governing amalgamation and fragmentation of the supercontinent. The Paleo-Mesoproterozoic boundary is the key point of tectonic transition from compressional to extensional settings in the NCC. The newly identified ~1.85?Ga carbonatite provides a direct link between the long-lasting supercontinental breakup and plume activity, which might be sourced from the “slab graveyard,” continental crustal slabs subducted into asthenosphere, beneath the supercontinent. The carbonatite provides a precise constraint of the initiation of the continental breakup at ~1.85?Ga.
DS201812-2900
2019
Xie, Y., Qu, Y., Zhong, R., Verplanck, P.L., Meffre, S., Xu, D.The ~1/85 carbonatite in north China and its implications on the evolution of the Columbia supercontinent.Gondwana Research, Vol. 65, pp. 125-141.Chinacarbonatite

Abstract: Mantle-derived carbonatites provide a unique window in the understanding of mantle characteristics and dynamics, as well as insight into the assembly and breakup of supercontinents. As a petrological indicator of extensional tectonic regimes, Precambrian carbonatites provide important constraints on the timing of the breakup of ancient supercontinents. The majority of the carbonatites reported worldwide are Phanerozoic, in part because of the difficulty in recognizing Precambrian carbonatites, which are characterized by strong foliation and recrystallization, and share broad petrologic similarities with metamorphosed sedimentary lithologies. Here we report the recognition of a ~1.85?Ga carbonatite in Chaihulanzi area of Chifeng in north China based on systematic geological, petrological, geochemical, and baddeleyite U-Pb geochronological results. The carbonatite occurs as dikes or sills emplaced in Archean metasedimentary rocks and underwent intense deformation. Petrological and SEM/EDS results show that calcite and dolomite are the dominant carbonate minerals along with minor and varied amounts of Mg-rich mafic minerals, including forsterite (with Fo?>?98), phlogopite, diopside, and an accessory amount of apatite, baddeleyite, spinel, monazite, and ilmenite. The relatively high silica content together with the non-arc and OIB-like trace element signatures of the carbonatite indicates a hot mantle plume as the likely magma source. The depleted Nd isotopic signatures suggest that plume upwelling might be triggered by the accumulation of recycled crust in the deep mantle. As a part of the global-scale Columbia supercontinent, the Proteozoic tectonic evolution of the North China Craton (NCC) provides important insights into the geodynamics governing amalgamation and fragmentation of the supercontinent. The Paleo-Mesoproterozoic boundary is the key point of tectonic transition from compressional to extensional settings in the NCC. The newly-identified ~1.85?Ga carbonatite provides a direct link between the long-lasting supercontinental breakup and plume activity, which might be sourced from the “slab graveyard”, continental crustal slabs subducted into asthenosphere, beneath the supercontinent. The carbonatite provides a precise constraint of the initiation of the continental breakup at ~1.85?Ga.
DS201805-0993
2018
Xiong, F., Yang, J., Xu, X., Kapsiotis, A., Hao, X., Liu, Z.Compositional and isotopic heterogeneities in the Neo-Tethyan upper mantle recorded by coexisting Al rich and Cr rich chromitites in the Purang massif, SW Tibet (China).Journal of Asian Earth Sciences, Vol. 159, pp. 109-129.China, Tibetchromitites

Abstract: The Purang harzburgite massif in SW Tibet (China) hosts abundant chrome ore deposits. Ores consist of 20 to >95% modal chromian spinel (Cr-spinel) with mylonitic fabric in imbricate shaped pods. The composition of Cr-spinel in these ores ranges from Al-rich [Cr#Sp or Cr/(Cr?+?Al)?×?100?=?47.60-57.56] to Cr-rich (Cr#Sp: 62.55-79.57). Bulk platinum-group element (PGE) contents of chromitites are also highly variable ranging from 17.5?ppb to ?2.5?ppm. Both metallurgical and refractory chromitites show a general enrichment in the IPGE (Os, Ir and Ru) with respect to the PPGE (Rh, Pt and Pd), resulting mostly in right-sloping primitive mantle (PM)-normalized PGE profiles. The platinum-group mineral (PGM) assemblages of both chromitite types are dominated by heterogeneously distributed, euhedral Os-bearing laurite inclusions in Cr-spinel. The Purang chromitites have quite inhomogeneous 187Os/188Os ratios (0.12289-0.13194) that are within the range of those reported for mantle-hosted chromitites from other peridotite massifs. Geochemical calculations demonstrate that the parental melts of high-Cr chromitites were boninitic, whereas those of high-Al chromitites had an arc-type tholeiitic affinity. Chromite crystallization was most likely stimulated by changes in magma compositions due to melt-peridotite interaction, leading to the establishment of a heterogeneous physicochemical environment during the early crystallization of the PGM. The highly variable PGE contents, inhomogeneous Os-isotopic compositions and varying Cr#Sp ratios of these chromitites imply a polygenetic origin for them from spatially distinct melt inputs. The generally low ?Os values (<1) of chromitites indicate that their parental melts originated within different sections of a heterogeneously depleted mantle source region. These melts were most likely produced in the mantle wedge above a downgoing lithospheric slab.
DS201811-2619
2018
Xu, J., Melgarejo, J.C., Castillo, O., Montgarri, A., Laia, S., Santamaria, J.Ilmenite generations in kimberlite from Banankoro, Guinea. ConakryNeues Jahrbuch fur Mineralogie, doi:.org/10.1127/njma/2018/0096Africa, Guineadeposit - Banakoro

Abstract: A complex mineral sequence in a kimberlite from the Banankoro Cluster (Guinea Conakry) has been interpreted as the result of magma mixing processes. The composition of the early generations of phlogopite and spinel suggest direct crystallisation of a kimberlitic magma. However, the compositional trends found in the late generations of phlogopite and spinels could suggest magma mixing. In this context, four ilmenite generations formed. The first generations (types 1 and 2) are geikielitic and are associated with spinel and phlogopite which follow the kimberlitic compositional trends. They are interpreted as produced by crystallization from the kimberlite magma. A third generation of euhedral tabular Mg-rich ilmenite (type 3) formed during the interval between two generations of serpentine. Finally, a late generation of Mn-rich ilmenite (type 4) replaces all the Ti-rich minerals and is contemporaneous with the last generation of serpophitic non-replacing serpentine. Therefore, the formation of type 3 and type 4 ilmenite took place after the crystallization of the groundmass, during late hydrothermal process. Our results suggest a detailed textural study is necessary when use Mg-rich and Mn-rich ilmenites as KIMs.
DS201808-1797
2018
Xu, J., Melgarejo, J.C., Castillo-Oliver, M.Styles of alteration of Ti oxides of the kimberlite groundmass: implications on the petrogenesis and classification of kimberlites and similar rocks.Minerals, Vol. 8, 2, pp. 51-66.Indiaperovskite

Abstract: The sequence of replacement in groundmass perovskite and spinel from SK-1 and SK-2 kimberlites (Eastern Dharwar craton, India) has been established. Two types of perovskite occur in the studied Indian kimberlites. Type 1 perovskite is found in the groundmass, crystallized directly from the kimberlite magma, it is light rare-earth elements (LREE)-rich and Fe-poor and its ?NNO calculated value is from ?3.82 to ?0.73. The second generation of perovskite (type 2 perovskite) is found replacing groundmass atoll spinel, it was formed from hydrothermal fluids, it is LREE-free and Fe-rich and has very high ?NNO value (from 1.03 to 10.52). Type 1 groundmass perovskite may be either replaced by anatase or kassite along with aeschynite-(Ce). These differences in the alteration are related to different f(CO2) and f(H2O) conditions. Furthermore, primary perovskite may be strongly altered to secondary minerals, resulting in redistribution of rare-earth elements (REE) and, potentially, U, Pb and Th. Therefore, accurate petrographic and chemical analyses are necessary in order to demonstrate that perovskite is magmatic before proceeding to sort geochronological data by using perovskite. Ti-rich hydrogarnets (12.9 wt %-26.3 wt % TiO2) were produced during spinel replacement by late hydrothermal processes. Therefore, attention must be paid to the position of Ca-Ti-garnets in the mineral sequence and their water content before using them to classify the rock based on their occurrence.
DS201808-1798
2018
Xu, J., Melgarejo, J.C., Castillo-Oliver, M.Ilmenite as a recorder of kimberlite history from mantle to surface: examples from Indian kimberlites. Bastar, Dharwar cratonsMineralogy and Petrology, 10.1007/s00710-018-0616-5 13p.Indiailmentite

Abstract: Indian kimberlites occur in the Bastar craton (Central India) and in the Eastern Dharwar craton (EDC) Southern India. Nearly 100 kimberlite pipes have been discovered in the Eastern Dharwar craton of southern India, and they are distributed in three distinct fields: 1) the southern Wajrakarur kimberlite field (WKF); 2) the northern Narayanpet kimberlite field (NKF); and 3) the Raichur kimberlite field (RKF) (Chalapathi Rao et al, 2013). Nine kimberlites have been selected for this study: three came from the Siddanpalli cluster of RKF (SK-1, SK-2 and SK-3); other six kimberlites came from WKF, from Chigicherla (CC-4 and CC-5), Kalyandurg (KL-3 and KL-4), Lattavaram (P-3) and Mulligripally (P-5). The kimberlite emplacement took place during the Mesoproterozoic, around 1.1 Ga (Chalapathi Rao et al., 2013). Ilmenite is one of the classic diamond indicator minerals (DIMs) and for long it has been used as a guide for kimberlite exploration. The aim of this study is to evaluate the petrogenetic information that can be provided from the textural and geochemical study of the different ilmenite generations present in the Indian kimberlites studied in this work.
DS201802-0282
2018
Xue, S., Ling, M-X., Liu, Y-L., Su, W.Recycling of subducted carbonates: formation of the Taohuala Mountain carbonatite, North Chin a craton.Chemical Geology, Vol. 478, pp. 89-101.Chinasubduction

Abstract: Carbonatitic magmatism plays a significant role in Earth's carbon cycle, which is also a lithoprobe of crust-mantle interaction, mantle metasomatism and partial melting. Due to different mineral assemblages and geochemical compositions, and diverse tectonic settings, the origin of carbonatite has long been debated. At subduction zones, sediments (including carbonates) are subducted into the mantle with the downgoing oceanic slab. However, the detailed mechanism of how subducted carbonates contribute to carbonatitic magmatism remains unclear. Here we present geochronological, geochemical and isotopic study on the Taohuala Mountain carbonatite at the southern margin of the Alxa Block, North China Craton. The classification of carbonatite from the Taohuala Mountain relies strongly on the observations of obvious intrusion contact relationships and flow structures in field outcrop. The Taohuala Mountain carbonatite has SiO2 ranging from 2.37 wt.% to 11.45 wt%, high CaO (45.93-53.86 wt%) and low MgO (0.51-4.39 wt%), and is characterized by enrichment of LILE (Ba, Sr), depletion of HFSE (Nb, Ta, Zr, Hf), and slightly negative Ce and Eu anomalies. Carbonates in the samples have high 87Sr/86Sr (0.70686-0.70694) and low 143Nd/144Nd (0.511635-0.511924). Remarkably, the highly fractionated ?18OVSMOW (11.83-25.92‰) indicates components of both sedimentary and mantle origin. Detailed zircon in situ U-Pb dating and oxygen isotope analysis exhibit contrast ages and ?18OVSMOW from core to rim, i.e., old ages (mainly > 800 Ma), high Th/U (mainly > 0.5) and low ?18OVSMOW (6.37-11.44‰) in cores (inherited), whereas young ages (~ 400 Ma), low Th/U (mainly < 0.01) and high ?18OVSMOW (20.04-24.54‰) in rims, suggesting that the Taohuala Mountain carbonatite may have been generated from melting of subducted sedimentary carbonates. Considering all these evidences, and that the collision along Qilian Mountains was older than the carbonatite, we propose that a large volume of sedimentary carbonates subducted and remained in the lithospheric mantle under the Alxa block during the closure of the Paleo-Qilian Ocean. Subsequently, the carbonatite was formed by melting of carbonates with minor contributions from the mantle during the breakoff or rollback of the Paleo-Asian oceanic slab.
DS201803-0487
2018
Yakovenchuk, V.N., Yu, G., Pakhomovsky, Y.A., Panikorovskii, T.L., Britvin, S.N., Krivivichev, S.V., Shilovskikh, V.V., Bocharov, V.N.Kampelite, Ba3Mg1.5,Sc4(PO4)6(OH)3.4H2O, a new very complex Ba-Sc phosphate mineral from the Kovdor phoscorite-carbonatite complex ( Kola Peninsula) Russia.Mineralogy and Petrology, Vol. 112, pp. 111-121.Russia, Kola Peninsulacarbonatite - Kovdor
DS201811-2620
2015
Yaluma, C.B.How Zambia transformed its emerald industry.InColor, December pp. 18-19.Africa, Zambiaemeralds
DS201811-2621
2018
Yang, H., Xiao, J., Yao, Z., Zhang, X., Younus, F., Melnik, R., Wen, B.Homogeneous and heterogenous dislocation nucleation in diamond.Diamond & Related Materials, Vol. 88, pp. 110-117.Mantlediamond morphology

Abstract: Dislocation nucleation plays a key role in plastic deformation of diamond crystal. In this paper, homogeneous and heterogeneous nucleation nature for diamond glide set dislocation and shuffle set dislocation is studied by combining molecular dynamics method and continuum mechanics models. Our results show that although heterogeneous dislocation nucleation can decrease its activation energy, the activation energy at 0?GPa for diamond heterogeneous nucleation is still in the range of 100?eV. For glide set and shuffle set homogeneous nucleation, their critical nucleation shear stress approaches to diamond's ideal shear strength which implies that those dislocations do not nucleate before diamond structural instability only by a purely shearing manner. While for glide set and shuffle set heterogeneous nucleation, their critical nucleation shear stresses are 28.9?GPa and 48.2?GPa, these values are less than diamond's ideal shear strength which implies that these dislocations may be nucleated heterogeneously under certain shear stress condition. In addition, our results also indicate there exists a deformation mode transformation for diamond deformation behavior at strain rate of 10?3/s. Our results provide a new insight into diamond dislocation nucleation and deformation.
DS201807-1538
2015
Yang, J., Robinson, P.T., Dilek, Y.Diamond bearing ophiolites and their geological occurrence. ** note dateEpisodes, Vol. 38, 4, pp. 344-364.China, Tibet, Russiaophiolites

Abstract: We document in this study the geological occurrence of diamonds and other ultrahigh-pressure (UHP) minerals in ophiolitic mantle peridotites and podiform chromitites from different orogenic belts. These minerals exist in both high-Cr and high-Al chromitites. Most ophiolite-hosted diamonds are small (? 200-500 ?m across), and some contain distinctive inclusions (i.e., coesite, Ni-Mn-Co alloys, spessartite, tephroite). All of the analyzed diamonds have extremely light carbon isotope compositions (?13C = -28.7 to -18.3‰) and variable trace element contents that distinguish them from most kimberlitic and UHP metamorphic varieties. A wide range of highly reduced minerals, such as native elements, Ni-Mn-Co alloys, Fe-Si and Fe-C phases and moissanite (SiC) also occuras accompanying mineral separates confirming the super-reducing conditions of their environment of formation. The presence of exsolution lamellae of diopside and coesite in some chromite grains suggests chromite crystallization depths around >380 km, near the mantle transition zone. Carbon and other recycled crustal materials at these depths are likely to have been derived from previously subducted material. The peridotites encapsulating the podiform chromitites and diamonds were transported to shallow mantle by convection cells beneath oceanic spreading centers. The chromitites may have formed in the deep mantle or in shallow suprasubduction zone environments. Our observations suggest that diamonds, UHP minerals and recycled crustal material are likely to be ubiquitous in the oceanic mantle.
DS201810-2390
2018
Yang, J.S., Trumball, R.B., Robinson, P.T., Xiong, F.H., Lian, D.Y.Comment: Ultra high pressure and ultra reduced minerals in ophiolites may form by lightning strikes. Super Reduced Minerals SURGeochemical Perspectives Letters, Vol. 8, pp. 6-7.Mantlemoissanite
DS201803-0488
2018
Yang, Y-H., Wu, F-Y., Yang, J-H., Mitchell, R.H., Zhao, Z-F., Xie, L-W., Huang, C., Ma, Q., Yang, M., Zhao, H.U-Pb age determination of schorlomite garnet by laser ablation inductively coupled plasma mass spectrometry. Magnet Cove, Fanshan, Ozernaya, Alno, Prairie LakeJournal of Analytical At. Spectrometry, Vol. 33, pp. 231-239.United States, Arkansas, China, Hebei, Russia, Kola Peninsula, Europe, Sweden, Canada, Ontariogeochronology

Abstract: We report the first U-Pb geochronological investigation of schorlomite garnet from carbonatite and alkaline complexes and demonstrate its applicability for U-Pb age determination using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) due to its relatively high U and Th abundances and negligible common Pb content. The comparative matrix effects of laser ablation of zircon and schorlomite are investigated and demonstrate the necessity of a suitable matrix-matched reference material for schorlomite geochronology. Laser-induced elemental fractional and instrumental mass discrimination were externally-corrected using an in house schorlomite reference material (WS20) for U-Pb geochronology. In order to validate the effectiveness and robustness of our analytical protocol, we demonstrate the veracity of U-Pb age determination for five schorlomite samples from: the Magnet Cove complex, Arkansas (USA); the Fanshan ultrapotassic complex, Hebei (China); the Ozernaya alkaline ultramafic complex, Kola Peninsula (Russia); the Alnö alkaline-rock carbonatite complex (Sweden); and the Prairie Lake carbonatite complex, Ontario (Canada). The schorlomite U-Pb ages range from 96 Ma to 1160 Ma, and are almost identical to ages determined from other accessory minerals in these complexes and support the reliability of our analytical protocol. Schorlomite garnet U-Pb geochronology is considered to be a promising new technique for understanding the genesis of carbonatites, alkaline rocks, and related rare-metal deposits.
DS201812-2901
2018
Yelisseyev, A.P., Afanasyev, V.P., Gromilov, S.A.Yakutites from the Popigai meteorite crater.Diamond & Related Materials, Vol. 89, pp. 10-17.Russiameteorite

Abstract: For the first time, 60 large diamond aggregates were found inside the Popigai meteorite crater during washing of alluvial deposits along the Dogoi river crossing the crater. These aggregates are similar in appearance to yakutites from the placers of Northern Yakutia (YPY), and we regard them as yakutites from the Popigai crater (YPC). The structure and optical properties of Popigai impact diamonds from the impact melt rocks (tagamites) in the crater (PIDT) and yakutites YPC/YPY were compared in detail. In all these cases, a polycrystalline structure consisting of nanoscale grains of cubic and twinned cubic diamond (lonsdaleite) was found. This is the result of a solid-phase graphite-diamond transition due to an impact event 35?million?years ago. The diamond aggregates show the following features: a red shift of the short-wave edge of the transmission, broadening of the diamond Raman peaks, signals from other diamond polytypes and numerous inclusions of other minerals in the Raman spectra, and a dominant broadband photoluminescence (PL). PL in the N3 system associated with N3V centers in PIDT diamonds indicates a high-temperature annealing of these aggregates with resulting aggregation of impurities during the prolonged cooling of large impact melt pockets and pools. It is assumed that some of the impact diamonds were ejected from the crater during the impact event and experienced rapid cooling. Some of these diamonds fell back into the crater (YPC yakutites), others have been deposited outside the crater and displaced during erosion (YPY yakutites). Difference in size and shape between the PIDTs and yakutites YPC/YPY is due to the difference in size of original graphite flakes or aggregates and/or due to the fundamentally different technologies of diamond extraction.
DS201804-0754
2018
Yoshioka, T., Wiedenbeck, M., Shcheka, S., Keppler, H.Nitrogen solubility in the deep mantle and the origin of Earth's primordial nitrogen budget.Earth and Planteray Science Letters, Vol. 488, pp. 134-143.Mantlenitrogen

Abstract: The solubility of nitrogen in the major minerals of the Earth's transition zone and lower mantle (wadsleyite, ringwoodite, bridgmanite, and Ca-silicate perovskite) coexisting with a reduced, nitrogen-rich fluid phase was measured. Experiments were carried out in multi-anvil presses at 14 to 24 GPa and 1100 to 1800?°C close to the Fe-FeO buffer. Starting materials were enriched in 15N and the nitrogen concentrations in run products were measured by secondary ion mass spectrometry. Observed nitrogen (15N) solubilities in wadsleyite and ringwoodite typically range from 10 to 250 ?g/g and strongly increase with temperature. Nitrogen solubility in bridgmanite is about 20 ?g/g, while Ca-silicate perovskite incorporates about 30 ?g/g under comparable conditions. Partition coefficients of nitrogen derived from coexisting phases are DNwadsleyite/olivine = 5.1 ± 2.1, DNringwoodite/wadsleyite = 0.49 ± 0.29, and DNbridgmanite/ringwoodite = 0.24 . Nitrogen solubility in the solid, iron-rich metal phase coexisting with the silicates was also measured and reached a maximum of nearly 1 wt.% 15N at 23 GPa and 1400?°C. These data yield a partition coefficient of nitrogen between iron metal and bridgmanite of DNmetal/bridgmanite???98, implying that in a lower mantle containing about 1% of iron metal, about half of the nitrogen still resides in the silicates. The high nitrogen solubility in wadsleyite and ringwoodite may be responsible for the low nitrogen concentrations often observed in ultradeep diamonds from the transition zone. Overall, the solubility data suggest that the transition zone and the lower mantle have the capacity to store at least 33 times the mass of nitrogen presently residing in the atmosphere. By combining the nitrogen solubility data in minerals with data on nitrogen solubility in silicate melts, mineral/melt partition coefficients of nitrogen can be estimated, from which the behavior of nitrogen during magma ocean crystallization can be modeled. Such models show that if the magma ocean coexisted with a primordial atmosphere having a nitrogen partial pressure of just a few bars, several times the current atmospheric mass of nitrogen must have been trapped in the deep mantle. It is therefore plausible that the apparent depletion of nitrogen relative to other volatiles in the near-surface reservoirs reflects the storage of a larger reservoir of nitrogen in the solid Earth. Dynamic exchange between these reservoirs may have induced major fluctuations of bulk atmospheric pressure over Earth's history.
DS201807-1539
2018
Yuan, H., Bodin, T.A probabilistic shear wave velocity model of the crust in the central west Australian craton constrained by transdimensional inversion of ambient noise dispersion.Tectonics, June 12, DOI: 10.129/ 2017TC004834Australiageophysics - seismic

Abstract: The Capricorn Orogen in central Western Australia played important roles in initializing and finalizing the West Australian craton. Surface geological mapping and isotopic studies show that the crust has recorded over a billion years of tectonic history spanning from its crustal formation in the Archean to episodes of tectono?thermal events during the Proterozoic cratonization processes. The region therefore provides us with an ideal laboratory to characterize the seismic signature associated with tectonic processes. We constructed a crustal shear?wave velocity model of the core region of the orogen, the Glenburgh Terrane and its north boundary, by inverting the array group velocity dispersion data measured from a high density temporary array. A modified Bayesian Transdimensional tomography technique, which incorporates a smooth?varying regional reference velocity model and Moho topography, was used to invert for the crustal velocity variations. The inverted velocity model adds great detail to the intra?crustal structure, and provides complementary seismic velocity information to refine the regional tectonic processes. Distinct patterns in the velocity structure support that the Glenburgh Terrane is a microcontinent originated in the Archean, and favor the operation of Paleoproterozoic subduction/accretion leading to the 2.2 Ga Ophthalmian orogeny that initiated the assembly of the West Australian craton.
DS201802-0283
2017
Zagainy, A.K., Mikoev, I.L., Ustinov, V.N., Feijo, A., Antonov, S.A.Structural tectonic and geophysical premises of kimberlites localization on the territory of Angola. ***IN RUSOres and Metals ***IN RUS, no. 4, pp. 42-49. pdfAfrica, Angolakimberlite - pipes
DS201809-2118
2018
Zaitsev, A.M., Moe, K., Wang, W.Defect transformations in nitrogen doped CVD diamond during irradiation and annealing.Diamond and Related Materials, doi:101016/j.diamond.2018.07.017Russiasynthetics

Abstract: Nitrogen-doped CVD diamond treated with electron irradiation and subsequent annealing at temperatures from 860 to 1900?°C was studied using fluorescence imaging, optical absorption and photoluminescence. It was found that nitrogen impurity produces many optical centers active throughout the infrared and visible spectral ranges. The most prominent of them active in IR spectral range are the centers related to nitrogen-hydrogen complexes. They produce absorption lines at 2827, 2874, 2906, 2949, 2990, 3031, 3107, 3123 and 3310?cm?1. Two characteristic absorptions at wavenumbers 1293?cm?1 and 1341?cm?1 were tentatively ascribed to a modified form of nitrogen A-aggregates. In the visible and near IR spectral ranges, characteristic nitrogen-related centers have zero-phonon lines (ZPLs) at 457, 462, 489, 498, 722.5, 852.5, 865.5, 868.5, 908, 921.5 and 924.5?nm. Some of them, e.g. 457, 462 and 498?nm centers, are unique of CVD diamond. It has been confirmed that the brightest pink color of electron-irradiated nitrogen-doped CVD diamond is produced by annealing at temperatures about 1000?°C. Annealing at temperatures over 1600?°C destroys the irradiation-induced pink color. It was found that the center 489?nm is a major absorption feature in the visible spectral range of electron-irradiated, nitrogen-doped CVD diamond. Green color of electron-irradiated, nitrogen-doped CVD diamond is caused by combined absorption of GR1 center and 489?nm center. It has been confirmed that NV defects produced in CVD diamond during growth are very temperature stable. They survive heating at temperatures at least 2000?°C. In contrast, NV defects produced by irradiation may anneal out at temperatures as low as 1600?°C. This much lower thermal stability of the radiation-induced NV defects is the result of their interaction with other radiation defects produced in their vicinity. A conclusion has been made that in nitrogen-doped CVD diamonds nitrogen atoms may form clusters. These clusters are probably the origin of the broad band luminescence at wavelengths 360, 390, 535 and 720?nm and a strong broadening of ZPLs of many optical centers.
DS201801-0082
2017
Zaitsev, V.A.Preservation model for Kola alkaline province for Paleozoic and Paleoproterozoic alkaline magmatism volume comparing.Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 13.Russia, Kola Peninsulacarbonatites

Abstract: Northern part of the Fennoscandian Shield in Kola Peninsula and Northern Karelia was intruded by alkaline magmatic complexes during the two main episodes. Paleoproterozoic alkaline province consisting from five alkaline massifs and Paleozoic alkaline province, consisting from twenty alkaline-ultramafic rock complexes, together with two giant nepheline syenite complexes are practically overlap. Based on the data about morphology and internal structure of the Paleozoic alkaline and ultramaficcarbonatite intrusions and their average denudation rates, the model of alkaline province destruction was developed. This model allows forecasting, how many intrusions of Kola Paleozoic alkaline province will remain and calculate preservation ratio for any moment of future. The dependence of preservation ratio on the age of province allow to compare the initial numbers of massifs in alkaline provinces and conclude that Paleoproterozoic event of alkaline magmatism in Kola peninsula was even more powerful than Paleozoic one.
DS201810-2391
2018
Zaporozan, T., Fredericksen, A.W., Bryksin, A., Darbyshire, F.Surface wave images of western Canada: lithographic variations across the Cordillera craton boundary.Canadian Journal of Earth Sciences, Vol. 55, pp. 887-896.Canada, Northwest Territories, Alberta, Saskatchewangeophysics - seismic

Abstract: Two-station surface-wave analysis was used to measure Rayleigh-wave phase velocities between 105 station pairs in western Canada, straddling the boundary between the tectonically active Cordillera and the adjacent stable craton. Major variations in phase velocity are seen across the boundary at periods from 15 to 200 s, periods primarily sensitive to upper mantle structure. Tomographic inversion of these phase velocities was used to generate phase velocity maps at these periods, indicating a sharp contrast between low-velocity Cordilleran upper mantle and high-velocity cratonic lithosphere. Depth inversion along selected transects indicates that the Cordillera-craton upper mantle contact varies in dip along the deformation front, with cratonic lithosphere of the Taltson province overthrusting Cordilleran asthenosphere in the northern Cordillera, and Cordilleran asthenosphere overthrusting Wopmay lithosphere further south. Localized high-velocity features at sub-lithospheric depths beneath the Cordillera are interpreted as Farallon slab fragments, with the gap between these features indicating a slab window. A high-velocity feature in the lower lithosphere of the Slave province may be related to Proterozic or Archean subduction.
DS201811-2622
2018
Zedgenizov, D.A., Ragozin, A.L., Shatsky, V.S., Griffin, W.L.Diamond formation during metasomatism of mantle eclogite by chloride-carbonate melt.Contributions to Mineralogy and Petrology, Vol. 173, 16p. Doi.org/10.1007/s00410-018-1513-yRussiadeposit - Udachnaya

Abstract: A xenolith of bimineralic eclogite from the Udachnaya kimberlite pipe provides a snapshot of interaction between mantle rocks and diamond-forming fluids/melts. The major-element composition of the eclogite is similar to that of N-MORB and/or oceanic gabbros, but its trace-element pattern shows the effects of mantle metasomatism, which resulted in diamond formation. The diamonds are clustered in alteration veins that crosscut primary garnet and clinopyroxene. The diamonds contain microinclusions of a fluid/melt dominated by carbonate and KCl. Compared to the worldwide dataset, the microinclusions in these diamonds fall in middle of the range between saline fluids and low-Mg carbonatitic melts. The fluid/melt acted as a metasomatic agent that percolated through ancient eclogitic rocks stored in the mantle. This interaction is consistent with calculated partition coefficients between the rock-forming minerals and diamond-forming fluid/melt, which are similar to experimentally-determined values. Some differences between the calculated and experimental values may be due to the low contents of water and silicates in the chloride-carbonate melt observed in this study, and in particular its high contents of K and LILE. The lack of nitrogen aggregation in the diamonds implies that the diamond-forming metasomatism took place shortly before the eruption of the kimberlite, and that the microinclusions thus represent saline carbonate-rich fluids circulating in the basement of lithospheric mantle (150-170 km depth).
DS201807-1540
2018
Zhang, L., Smyth, J.R., Kawazoe, T., Jacobsen, S.D., Qin, S.Transition metals in the transition zone: partitioning of Ni, Co, and Zn between olivine, wadsleyite, ringwoodite, and clineoenstatite.Contributions to Mineralogy and Petrology, 10.1007/ s00410-018-1478-x 10p.Mantlemelting

Abstract: Ni, Co, and Zn are widely distributed in the Earth’s mantle as significant minor elements that may offer insights into the chemistry of melting in the mantle. To better understand the distribution of Ni2+, Co2+, and Zn2+ in the most abundant silicate phases in the transition zone and the upper mantle, we have analyzed the crystal chemistry of wadsleyite (Mg2SiO4), ringwoodite (Mg2SiO4), forsterite (Mg2SiO4), and clinoenstatite (Mg2Si2O6) synthesized at 12-20 GPa and 1200-1400 °C with 1.5-3 wt% of either NiO, CoO, or ZnO in starting materials. Single-crystal X-ray diffraction analyses demonstrate that significant amounts of Ni, Co, and Zn are incorporated in octahedral sites in wadsleyite (up to 7.1 at%), ringwoodite (up to 11.3 at%), olivine (up to 2.0 at%), and clinoenstatite (up to 3.2 at%). Crystal structure refinements indicate that crystal field stabilization energy (CFSE) controls both cation ordering and transition metal partitioning in coexisting minerals. According to electron microprobe analyses, Ni and Co partition preferentially into forsterite and wadsleyite relative to coexisting clinoenstatite. Ni strongly prefers ringwoodite over coexisting wadsleyite with DRw/WdNi?=?4.13. Due to decreasing metal-oxygen distances with rising pressure, crystal field effect on distribution of divalent metal ions in magnesium silicates is more critical in the transition zone relative to the upper mantle. Analyses of Ni partitioning between the major upper-mantle phases implies that Ni-rich olivine in ultramafic rocks can be indicative of near-primary magmas.
DS201810-2392
2018
Zhang, S.Y., Zhang, H.L., Hou, Z., Ionov, D.A., Huang, F.Rapid determination of trace element compositions in peridotites by LA-ICP-MS using an albite fusion method.Geostandards and Geoanalytical Research, doi:10.111/ggr.12240Globalperidotite

Abstract: A rapid sample preparation procedure is described to determine trace element compositions of peridotites using LA?ICP?MS. Peridotite powders were fused with albite in a molybdenum?graphite assembly to obtain homogeneous glasses. Best conditions for the fusion procedure (heating at 1500 to 1550 °C for 10 to 15 min with a sample?to?flux ratio of 1:2) were constrained with melting experiments on two USGS reference materials, PCC?1 and DTS?2B. Mass fractions of first series transition elements, Ba and Pb in quenched glasses of PCC?1 and DTS?2B are consistent with published data within 10% RSD. Three spinel peridotite xenoliths from eastern China were analysed following both our method and conventional solution ICP?MS. Compared with solution ICP?MS, the relative deviations of our method for most elements were within 10%, while for the REE, Ta, Pb, Th and U, were within 20%. In particular, volatile elements (e.g., Pb and Zn) are retained in the glass. Compared with conventional wet chemistry digestion, our method is faster. Additional advantages are complete sample fusion, especially useful for samples with acid?resistant minerals (spinel, rutile), and long?term conservation of glasses allowing unlimited repeated measurements with micro?beam techniques. The same approach can be used for analyses of other mantle rocks, such as eclogites and pyroxenites.
DS201806-1261
2018
Zhang, W., Zou, G., Qian, Y.Application of rocking-scan method to detect the low- content diamonds in a complex mixture.Diamond and Related Materials, Vol. 85, pp. 1-4.Technologyrocking-scan

Abstract: A method for detecting large-size diamonds with low content in a complex mixture was described. Phase identification via conventional X-ray diffraction method is unsuitable because of the large-size and low-content characteristics of the diamonds. Thus, we proposed a convenient approach (i.e., rocking scan) for assessing the presence of low-content diamonds in a complex mixture. A thorough rocking scan of the (111), (220), and (311) planes revealed the presence of low-content diamonds prepared by reducing dense carbon dioxide with alkali metals. This procedure can be successfully applied to several standard mixture samples prepared by mixing ?-SiO2, ?-Al2O3, graphite, and pure diamond powders, which are commercially available. We estimated that the detection limit was at or below the 0.1?wt% level by using the proposed method under the current condition. This method is straightforward, routinized, and may be specifically developed to satisfy the requirements of public and private institutions for a rapid identification of other mixture phases, of which the large-size and low-content characteristics do not allow an instant phase identification by conventional X-ray diffraction methods.
DS201805-0994
2018
Zhang, Z., Dueker, K.G., Huang, H-H.Ps mantle transition zone imaging beneath the Colorado Rocky Mountains: evidence for an upwelling hydrous mantle.Earth Planetary Science Letters, Vol. 492, pp. 197-205.United States, Coloradomantle - discontinuity

Abstract: We analyze teleseismic P-to-S conversions for high-resolution imaging of the mantle transition zone beneath the Colorado Rocky Mountains using data from a dense PASSCAL seismic broadband deployment. A total of 6,021 P-to-S converted receiver functions are constructed using a multi-channel minimum-phase deconvolution method and migrated using the common converted point technique with the 3-D teleseismic P- and S-wave tomography models of Schmandt and Humphreys (2010). The image finds that the average depths of the 410-km discontinuity (the 410) and 660-km discontinuity (the 660) at and respectively. The peak-to-peak topography of both discontinuities is 33 km and 27 km respectively. Additionally, prominent negative polarity phases are imaged both above and below the 410. To quantify the mean properties of the low-velocity layers about 410 km, we utilize double gradient layer models parameterization to fit the mean receiver function waveform. This waveform fitting is accomplished as a grid-search using anelastic synthetic seismograms. The best-fitting model reveals that the olivine-wadsleyite phase transformation width is 21 km, which is significantly larger than anhydrous mineral physics prediction (4-10 km) (Smyth and Frost, 2002). The findings of a wide olivine-wadsleyite phase transformation and the negative polarity phases above and below the 410, suggest that the mantle, at least in the 350-450 km depth range, is significantly hydrated. Furthermore, a conspicuous negative polarity phase below the 660 is imaged in high velocity region, we speculate the low velocity layer is due to dehydration flux melting in an area of convective downwelling. Our interpretation of these results, in tandem with the tomographic image of a Farallon slab segment at 800 km beneath the region (Schmandt and Humphreys, 2010), is that hydrous and upwelling mantle contributes to the high-standing Colorado Rocky Mountains.
DS201806-1262
2018
Zhang, Z., Dueker, K.G., Huang, H-H.Ps mantle transition zone imaging beneath the Colorado Rocky Mountains: evidence for an upwelling hydrous mantle.Earth and Planetary Science Letters, Vol. 492, pp. 197-205.United States, Coloradogeophysics - seismic

Abstract: We analyze teleseismic P-to-S conversions for high-resolution imaging of the mantle transition zone beneath the Colorado Rocky Mountains using data from a dense PASSCAL seismic broadband deployment. A total of 6,021 P-to-S converted receiver functions are constructed using a multi-channel minimum-phase deconvolution method and migrated using the common converted point technique with the 3-D teleseismic P- and S-wave tomography models of Schmandt and Humphreys (2010). The image finds that the average depths of the 410-km discontinuity (the 410) and 660-km discontinuity (the 660) at and respectively. The peak-to-peak topography of both discontinuities is 33 km and 27 km respectively. Additionally, prominent negative polarity phases are imaged both above and below the 410. To quantify the mean properties of the low-velocity layers about 410 km, we utilize double gradient layer models parameterization to fit the mean receiver function waveform. This waveform fitting is accomplished as a grid-search using anelastic synthetic seismograms. The best-fitting model reveals that the olivine-wadsleyite phase transformation width is 21 km, which is significantly larger than anhydrous mineral physics prediction (4-10 km) (Smyth and Frost, 2002). The findings of a wide olivine-wadsleyite phase transformation and the negative polarity phases above and below the 410, suggest that the mantle, at least in the 350-450 km depth range, is significantly hydrated. Furthermore, a conspicuous negative polarity phase below the 660 is imaged in high velocity region, we speculate the low velocity layer is due to dehydration flux melting in an area of convective downwelling. Our interpretation of these results, in tandem with the tomographic image of a Farallon slab segment at 800 km beneath the region (Schmandt and Humphreys, 2010), is that hydrous and upwelling mantle contributes to the high-standing Colorado Rocky Mountains.
DS201812-2902
2018
Zhao, S., Schettino, E., Merlini, M., Poli, S.The stability and melting of aragonite: an experimental and thermodynamic model for carbonated eclogites in the mantle.Lithos, doi.org/10.1016/ j.lithos.2018.11.005 38p.Mantleeclogite

Abstract: Subduction of calcium carbonate, sequestered in the oceanic crust by hydrothermal metamorphism and biogenic action, accounts for a significant flux of carbon into the mantle, where it contributes to the genesis of carbonatitic and silica-undersaturated melts. However, the reported phase relations in the system CaCO3, notably the transition boundary from disordered calcite (calcite V, here ccv) to aragonite (ara), vary considerably among different studies. Moreover, the thermodynamic properties of ccv and of liquid CaCO3 (CaCO3L) remain to be determined. In order to address the dearth of experimental data on phase relations, and to determine a set of internally consistent thermodynamic properties for ara, ccv and CaCO3L, multi-anvil experiments were performed at 3-6?GPa and 1300-1750?°C. By re-evaluating all experimental data, the transformation of ccv-ara fits the equation Tccv-ara?=?397.6?+?320.17?×?P and the melting curve Tm?=?1578.9?+?139.65?×?P???11.646?×?P2, where pressure is in GPa and temperature in K. Thermodynamic properties retrieved for calcite V and liquid CaCO3 are used to compute phase diagrams of relevance for chemical compositions representative of eclogite heterogeneities of the astenospheric mantle, and compared with experimentally derived phase relationships. Aragonite represents a carbonate of major abundance in carbonated eclogites at high temperature, close to the solidus; its ability to fractionate REE and Ba-Sr contributes to the peculiar geochemical signatures of silica undersaturated magmas. The relatively refractory nature of aragonite impacts on our understanding of the deep carbon cycle.
DS201808-1799
2018
Zhitova, E.S., Krivocichev, S.V., Yakovenchuk, V.N., Ivanyuk, G.Y., Pakhomovsky, Y.A., Mikhailova, J.A.Crystal chemistry of natural layered double hydroxides: 4. Crystal structures and evolution of structural complexity of quintinite polytypes from the Kovdor alkaline ultrabasic massif, Kola Peninsula, Russia.Mineralogical Magazine, Vol. 82, no. 2, pp. 329-346.Russia, Kola Peninsuladeposit - Kovdor

Abstract: Two quintinite polytypes, 3R and 2T, which are new for the Kovdor alkaline-ultrabasic complex, have been structurally characterized. The crystal structure of quintinite-2T was solved by direct methods and refined to R1 = 0.048 on the basis of 330 unique reflections. The structure is trigonal, P c1, a = 5.2720(6), c = 15.113(3) Å and V = 363.76(8) Å3. The crystal structure consists of [Mg2Al(OH)6]+ brucite-type layers with an ordered distribution of Mg2+ and Al3+ cations according to the × superstructure with the layers stacked according to a hexagonal type. The complete layer stacking sequence can be described as …=Ab1C = Cb1A=…. The crystal structure of quintinite-3R was solved by direct methods and refined to R1 = 0.022 on the basis of 140 unique reflections. It is trigonal, R m, a = 3.063(1), c = 22.674(9) Å and V = 184.2(1) Å3. The crystal structure is based upon double hydroxide layers [M2+,3+(OH)2] with disordered distribution of Mg, Al and Fe and with the layers stacked according to a rhombohedral type. The stacking sequence of layers can be expressed as …=?B = BC = CA=… The study of morphologically different quintinite generations grown on one another detected the following natural sequence of polytype formation: 2H ? 2T ? 1M that can be attributed to a decrease of temperature during crystallization. According to the information-based approach to structural complexity, this sequence corresponds to the increasing structural information per atom (IG): 1.522 ? 1.706 ? 2.440 bits, respectively. As the IG value contributes negatively to the configurational entropy of crystalline solids, the evolution of polytypic modifications during crystallization corresponds to the decreasing configurational entropy. This is in agreement with the general principle that decreasing temperature corresponds to the appearance of more complex structures.
DS201810-2393
2018
Zhou, Q., Hu, J., Liu, L., Chaparro, T., Stegman, D.R., Faccenda, M.Western U.S. seismic anisotropy revealing complex mantle dynamics.Earth and Planetary Science Letters, Vol. 500, pp. 156-167.United Statesgeodynamics

Abstract: The origin of the complex pattern of SKS splitting over the western United States (U.S.) remains a long-lasting debate, where a model that simultaneously matches the various SKS features is still lacking. Here we present a series of quantitative geodynamic models with data assimilation that systematically evaluate the influence of different lithospheric and mantle structures on mantle flow and seismic anisotropy. These tests reveal a configuration of mantle deformation more complex than ever envisioned before. In particular, we find that both lithospheric thickness variations and toroidal flows around the Juan de Fuca slab modulate flow locally, but their co-existence enhances large-scale mantle deformation below the western U.S. The ancient Farallon slab below the east coast pulls the western U.S. upper mantle eastward, spanning the regionally extensive circular pattern of SKS splitting. The prominent E-W oriented anisotropy pattern within the Pacific Northwest reflects the existence of sustaining eastward intrusion of the hot Pacific oceanic mantle to beneath the continental interior, from within slab tears below Oregon to under the Snake River Plain and the Yellowstone caldera. This work provides an independent support to the formation of intra-plate volcanism due to intruding shallow hot mantle instead of a rising mantle plume.
DS201803-0619
2018
Zhou, Q., Liu, L.A hybrid approach to dat a assimilation for recsontructing the evolution of mantle dynamics.Geochemistry, Geophysics, Geosystems G3, Vol. 18, pp. 3854-3868.Mantlegeotectonics

Abstract: Quantifying past mantle dynamic processes represents a major challenge in understanding the temporal evolution of the solid earth. Mantle convection modeling with data assimilation is one of the most powerful tools to investigate the dynamics of plate subduction and mantle convection. Although various data assimilation methods, both forward and inverse, have been created, these methods all have limitations in their capabilities to represent the real earth. Pure forward models tend to miss important mantle structures due to the incorrect initial condition and thus may lead to incorrect mantle evolution. In contrast, pure tomography-based models cannot effectively resolve the fine slab structure and would fail to predict important subduction-zone dynamic processes. Here we propose a hybrid data assimilation approach that combines the unique power of the sequential and adjoint algorithms, which can properly capture the detailed evolution of the downgoing slab and the tomographically constrained mantle structures, respectively. We apply this new method to reconstructing mantle dynamics below the western U.S. while considering large lateral viscosity variations. By comparing this result with those from several existing data assimilation methods, we demonstrate that the hybrid modeling approach recovers the realistic 4-D mantle dynamics the best.
DS201811-2623
2018
Zhou, Z.Discovery of Mesoproterozoic kimberlite from Dorbed Banner, Inner Mongolia and its tectonic significance.Geological Journal, Vol. 53, 3, pp. 992-1004.Asia, Mongoliakimberlite

Abstract: Porphyritic olivine kimberlitic breccia, discovered in the Dörbed Banner of Inner Mongolia, Western China, is referred to as Longtou Shan Kimberlite in our study. This kimberlite occurs as a pipe in the Halahuogete Formation of Bayan Obo Group. Zircon U-Pb ages of Longtou Shan Kimberlite reveals a Mesoproterozoic age of ~1,552 Ma, constraining the deposition age of Halahuogete Formation to the Mesoproterozoic. Compared with Mesoproterozoic kimberlite of the ancient landmass, it can be inferred that the North China Craton is a member of the Ur ancient continent of the Columbia supercontinent. Furthermore, according to the tectonic background of the Bayan Obo Group, we raise this possibility that “Bayan Obo Aulacogen” should be renamed the "Bayan Obo Continental Rift."
DS201809-2119
2018
Zhu, Y-S., Yang, J-H., Wang, H., Wu, F-Y.A Paleoproterozoic basement beneath the Rangrim massif revealed by in situ U-Pb ages and Hf isotopes of xenocrystic zircons from Triassic kimberlites of the North Korea.Goldschmidt Conference, 1p. AbstractAsia, North Koreadeposit - Rangrim

Abstract: Zircon xenocrysts from the kimberlites offer a unique opportunity to identify the cryptic basement components hidden in the deep crust and thus to image lithospheric structure and crustal evolution. Zircon xenocrysts from the Triassic kimberlites, exposed in the Rangrim massif of North Korea, were selected for in situ U-Pb and Hf analyses. These zircon xenocrysts are all crust-derived. Their U-Pb age spectrum is characterized by one prominent age population at ca. 1.9-1.8 Ga without any Archean ages, indicating a Paleoproterozoic-dominated basement in the depth of the Rangrim massif. Archean basement should be very limited or absent at depth. This is different with the previous thought of the Rangrim massif being an Archean terrane. However, most of those Paleoproterozoic zircons display negative ?Hf(t) values (-9.7~+0.7) with the average Hf model age of 2.83 ± 0.09 Ga (2?), implying that protoliths of those zircons were not juvenile but derived from reworking of the pre-existed Archean basement. These observations argue for a strong crustal reworking event occurred in the Rangriam massif during Paleoproterozoic, which exhausted most of the preexisted Archean basement rocks and generated a large abundance of Paleoproterozoic rocks. The 1.9~1.8 Ga thermal event has been well documented in the adjacent Jiao- Liao-Ji orogenic belt of the North China Craton. Both of them are characterized by the widely distributed 1.9~1.8 Ga magmatism and share similar igneous rock assemblage. We suggest that the Rangrim massif may be the eastern extension of the Jiao-Liao-Ji belt in North Korea, constituting part of a huge Paleoproterozoic orogen in the eastern margin of the Sino-Korean craton.
DS201807-1541
2018
Zimba, B.Performance of a laminar spiral In let cyclone in a diamond DMS application. Background information CAVEX CVXASAIMM Diamonds - source to use 2018 Conference 'thriving in changing times'. June 11-13., pp. 24-34.Technologymining - DMS
DS201801-0083
2017
Zimnisky, P.Rough diamond prices.Zimnisky.com, Dec. 18, 7p.Globaldiamond production
DS201812-2903
2018
Zimnisky, P.The natural diamond industry in 2018, where do we go from here? Keynote address7th Symposio Brasileiro de Geologia do Diamante , Presentation listed South America, Brazil, Globaleconomics
DS201810-2394
2018
Zolkos, S., Tank, S.E., Kokelj, S.V.Mineral weathering and the permafrost carbon-climate feedback. Peel PlateauGeophysical Research Letters, orchid.org/ 0000-0001-9945-6945Canada, Northwest Territoriespermafrost

Abstract: The origin of the complex pattern of SKS splitting over the western United States (U.S.) remains a long-lasting debate, where a model that simultaneously matches the various SKS features is still lacking. Here we present a series of quantitative geodynamic models with data assimilation that systematically evaluate the influence of different lithospheric and mantle structures on mantle flow and seismic anisotropy. These tests reveal a configuration of mantle deformation more complex than ever envisioned before. In particular, we find that both lithospheric thickness variations and toroidal flows around the Juan de Fuca slab modulate flow locally, but their co-existence enhances large-scale mantle deformation below the western U.S. The ancient Farallon slab below the east coast pulls the western U.S. upper mantle eastward, spanning the regionally extensive circular pattern of SKS splitting. The prominent E-W oriented anisotropy pattern within the Pacific Northwest reflects the existence of sustaining eastward intrusion of the hot Pacific oceanic mantle to beneath the continental interior, from within slab tears below Oregon to under the Snake River Plain and the Yellowstone caldera. This work provides an independent support to the formation of intra-plate volcanism due to intruding shallow hot mantle instead of a rising mantle plume.
 
 

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