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SDLRC - Scientific Articles all years by Author - Si-Sm
The Sheahan Diamond Literature Reference Compilation
The Sheahan Diamond Literature Reference Compilation is compiled by Patricia Sheahan who publishes on a monthly basis a list of new scientific articles related to diamonds as well as media coverage and corporate announcementscalled the Sheahan Diamond Literature Service that is distributed as a free pdf to a list of followers. Pat has kindly agreed to allow her work to be made available as an online digital resource at Kaiser Research Online so that a broader community interested in diamonds and related geology can benefit. The references are for personal use information purposes only; when available a link is provided to an online location where the full article can be accessed or purchased directly. Reproduction of this compilation in part or in whole without permission from the Sheahan Diamond Literature Service is strictly prohibited. Return to Diamond Resource Center
Sheahan Diamond Literature Reference Compilation - Scientific Articles by Author for all years
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International Geology Review, Vol. 58, 12, pp. 1461-1480.
India
Carbonatite
Abstract: The South Indian Granulite Terrane (SGT) is a collage of Archaean to Neoproterozoic age granulite facies blocks that are sutured by an anastomosing network of large-scale shear systems. Besides several Neoproterozoic carbonatite complexes emplaced within the Archaean granulites, there are also smaller Paleoproterozoic (2.4 Ga, Hogenakkal) carbonatite intrusions within two NE-trending pyroxenite dikes. The Hogenakkal carbonatites, further discriminated into sövite and silicate sövite, have high Sr and Ba contents and extreme light rare earth element (LREE) enrichment with steep slopes typical of carbonatites. The C- and O-isotopic ratios [?13CVPDB = ?6.7 to ?5.8‰ and ?18OVSMOW = 7.5-8.7‰ except a single 18O-enriched sample (?18O = 20.0‰)] represent unmodified mantle compositions. The ?Nd values indicate two groupings for the Hogenakkal carbonatites; most samples show positive ?Nd values, close to CHUR (?Nd = ?0.35 to 2.94) and named high-?Nd group while the low-?Nd group samples show negative values (?5.69 to ?8.86), corresponding to depleted and enriched source components, respectively. The 87Sr/86Sri ratios of the two groups also can be distinguished: the high-?Nd ones have low 87Sr/86Sri ratios (0.70161-0.70244) while the low-?Nd group shows higher ratios (0.70247-0.70319). We consider the Nd-Sr ratios as primary and infer derivation from a heterogeneous mantle source. The emplacement of the Hogenakkal carbonatites may be related to Paleoproterozoic plume induced large-scale rifting and fracturing related to initiation of break-up of the Neoarchean supercontinent Kenorland.
International Geology Review, Vol. 58, 12, pp. 1461-1480.
India
carbonatites
Abstract: The South Indian Granulite Terrane (SGT) is a collage of Archaean to Neoproterozoic age granulite facies blocks that are sutured by an anastomosing network of large-scale shear systems. Besides several Neoproterozoic carbonatite complexes emplaced within the Archaean granulites, there are also smaller Paleoproterozoic (2.4 Ga, Hogenakkal) carbonatite intrusions within two NE-trending pyroxenite dikes. The Hogenakkal carbonatites, further discriminated into sövite and silicate sövite, have high Sr and Ba contents and extreme light rare earth element (LREE) enrichment with steep slopes typical of carbonatites. The C- and O-isotopic ratios [?13CVPDB = ?6.7 to ?5.8‰ and ?18OVSMOW = 7.5-8.7‰ except a single 18O-enriched sample (?18O = 20.0‰)] represent unmodified mantle compositions. The ?Nd values indicate two groupings for the Hogenakkal carbonatites; most samples show positive ?Nd values, close to CHUR (?Nd = ?0.35 to 2.94) and named high-?Nd group while the low-?Nd group samples show negative values (?5.69 to ?8.86), corresponding to depleted and enriched source components, respectively. The 87Sr/86Sri ratios of the two groups also can be distinguished: the high-?Nd ones have low 87Sr/86Sri ratios (0.70161-0.70244) while the low-?Nd group shows higher ratios (0.70247-0.70319). We consider the Nd-Sr ratios as primary and infer derivation from a heterogeneous mantle source. The emplacement of the Hogenakkal carbonatites may be related to Paleoproterozoic plume induced large-scale rifting and fracturing related to initiation of break-up of the Neoarchean supercontinent Kenorland.
Maia, M., Sichel, S., Briais, A., Brunelli, D., Ligi, M., Ferreira, N., Campos, T., Mougel, B., Brehme, I., Hemond, C., Motoki, A., Moura, D., Scalabrin, C., Pessanha, I., Alves, E., Ayres, A., Oliveira, P.
Abstract: Mantle exhumation at slow-spreading ridges is favoured by extensional tectonics through low-angle detachment faults1, 2, 3, 4, and, along transforms, by transtension due to changes in ridge/transform geometry5, 6. Less common, exhumation by compressive stresses has been proposed for the large-offset transforms of the equatorial Atlantic7, 8. Here we show, using high-resolution bathymetry, seismic and gravity data, that the northern transform fault of the St Paul system has been controlled by compressive deformation since ~10?million years ago. The long-lived transpression resulted from ridge overlap due to the propagation of the northern Mid-Atlantic Ridge segment into the transform domain, which induced the migration and segmentation of the transform fault creating restraining stepovers. An anticlockwise change in plate motion at ~11?million years ago5 initially favoured extension in the left-stepping transform, triggering the formation of a transverse ridge, later uplifted through transpression, forming the St Peter and St Paul islets. Enhanced melt supply at the ridge axis due to the nearby Sierra Leone thermo chemical anomaly9 is responsible for the robust response of the northern Mid-Atlantic Ridge segment to the kinematic change. The long-lived process at the origin of the compressive stresses is directly linked to the nature of the underlying mantle and not to a change in the far-field stress regime.
Geophysical Research , Vol. 20, EGU2018-13349 1p. Abstract
Iceland
magmatism
Abstract: Porous rocks represent the products of all explosive volcanic eruptions. As magma ascends to the Earth’s surface, bubbles form as a consequence of the evolving saturation state of volatiles dissolved in the melt. The presence of pores (either filled with pressurized volatiles or not) strongly controls the rheological behaviour of magma and thus influences all volcanic processes (pre- syn- and post-eruptive). Nevertheless, the effects of porosity on the rheology of magma are not well characterised, and a general parameterization is not available yet. Here we present a new set of experiments designed to investigate the rheology of porous melts at high temperature (750-800
C), low strain rates (10^6-10^7 s^-1) and variable porosity. Experiments were performed at 1 atm using a Setaram Setsys vertical dilatometer. The starting materials are 5 x 5 mm cores of natural rhyolitic obsidian from Hrafntinnuhryggur, Krafla, Iceland (vesicle and crystal-free) initially containing 0.11(4) wt% dissolved H2O. The experimental procedure is composed by two steps: 1) synthesis of bubble-bearing materials by heating and expansion due to foaming; 2) deformation of the foamed samples. During the first step, the obsidian cores are heated above the glass transition temperature to 900- 1050
C and held for set amounts of time (2-24 h); the volume of the foamed samples increases because H2O vapour-filled bubbles nucleate and expand. The change in volume (measured by He-pycnometry) is linked to the change in porosity (10-50 vol%). For the second step, two different experimental strategies are employed, hereafter “single-stage” and “doublestage” measurements. Single-stage measurements involve deformation of the samples directly after foaming (without quenching). The sample is cooled down from the foaming T to different target T (750-800
C), a constant load (150 g) is applied by silica or alumina probes to the core, and the cores deform isothermally for 5-20 hours. Conversely, double-stage measurements involve deformation of previously synthesised and quenched pore-bearing cores. In this case the sample is heated up to the target T and deformed under an applied load for similar amount of time (5-20 hours). In both cases, the variation in length (displacement) and volume (porosity) is continuously recorded and used to calculate the viscosity of the foamed cores using Gent’s equations. Preliminary results suggest for single-stage measurements a lower effect of bubbles on the bulk viscosity, compared to double-stage measurements. We suggest that the different behaviour may be related to the different microstructure of the experimental materials. For single-stage measurements, closed and H2O vapour-filled bubbles contribute to the observed higher viscosity, whereas in double-stage measurements, possible gas leaking and melt micro-cracking during quenching are able to weaken the porous material and markedly lower suspension viscosity.
Abstract: The Arctic is warming 2-3 times faster than the global average. The rapid increase of near-surface air temperatures at high latitudes is driving a loss of ice in oceans, rivers, mountain glaciers, and soil. Permafrost, the perennially frozen ground found in frigid climates, is estimated to store approximately 1,500 gigatons of carbon, or about half of the world’s underground stores. This carbon is slowly escaping from the soil as permafrost thaws; this thawing could release as much carbon into the atmosphere as current emissions from global land use change over the next 80 years. Like many other models of future conditions, uncertainty plagues the estimates of permafrost carbon release. Salmon et al. explored how nitrogen, an important contributor to this uncertainty, interacts with carbon in thawing soils. Nitrogen is an essential nutrient for plants and soil microbes but occurs in limited supply in tundra soils. This limitation restricts plant growth and microbial decomposition, which are critical pieces of the carbon cycle. The researchers drilled soil cores at the Eight Mile Lake site in interior Alaska to depths of 85 centimeters to evaluate the annually thawed active layer (0-55 centimeters) as well as the upper permafrost (below 55 centimeters). They then incubated the soil cores at 15°C for about 8 months and measured the subsequent nitrogen levels and microbial biomass. The data collected in the incubation informed statistical models that were used to analyze the effects of depth, time, and growing season conditions on nitrogen and carbon dynamics. The findings revealed that both carbon loss and microbial biomass decreased significantly with soil depth. Models predicted that soil decomposition would release the largest amount of mineral nitrogen from soils located in the middle of the active layer. Permafrost soils at the bottom of the soil profile, however, released a large flush of mineral nitrogen during the initial thaw but a small flux of mineral nitrogen during subsequent decomposition. These patterns indicate that microbes near the soil surface are nitrogen limited, whereas deep microbial communities are more limited by carbon. The team’s calculations estimate that mineral nitrogen released from the soil profile would increase tenfold during the first 5 years of permafrost thaw. Should permafrost continue to thaw in the Arctic, these results suggest that tundra ecosystems may experience an increase in nitrogen availability that exceeds plant and microbial demands. Excess nitrogen, in turn, could precipitate increased decomposition of soil carbon and increased levels of nitrogen in streams draining from thawing permafrost landscapes. The study offers critical insights into how warming temperatures in the Arctic could dramatically increase permafrost thaw and initiate profound changes in carbon and nitrogen cycling in tundra ecosystems.
iron-copper-rare earth elements (REE) deposits in Middle Proterozoic rocks of the Midcontinent region of the United States..are they Olympic Dam-type deposits?
The Gangue, Geological Association of Canada (GAC)/Mineral Deposits Newsletter, No. 42, April pp. 1-4
Proceedinds of the National Academy of Sciences, Vol. 117, 19, 9p. Pdf
United States, Colorado
geothermometry
Abstract: The Great Unconformity marks a major gap in the continental geological record, separating Precambrian basement from Phanerozoic sedimentary rocks. However, the timing, magnitude, spatial heterogeneity, and causes of the erosional event(s) and/or depositional hiatus that lead to its development are unknown. We present field relationships from the 1.07-Ga Pikes Peak batholith in Colorado that constrain the position of Cryogenian and Cambrian paleosurfaces below the Great Unconformity. Tavakaiv sandstone injectites with an age of ?676 ± 26 Ma cut Pikes Peak granite. Injection of quartzose sediment in bulbous bodies indicates near-surface conditions during emplacement. Fractured, weathered wall rock around Tavakaiv bodies and intensely altered basement fragments within unweathered injectites imply still earlier regolith development. These observations provide evidence that the granite was exhumed and resided at the surface prior to sand injection, likely before the 717-Ma Sturtian glaciation for the climate appropriate for regolith formation over an extensive region of the paleolandscape. The 510-Ma Sawatch sandstone directly overlies Tavakaiv-injected Pikes granite and drapes over core stones in Pikes regolith, consistent with limited erosion between 717 and 510 Ma. Zircon (U-Th)/He dates for basement below the Great Unconformity are 975 to 46 Ma and are consistent with exhumation by 717 Ma. Our results provide evidence that most erosion below the Great Unconformity in Colorado occurred before the first Neoproterozoic Snowball Earth and therefore cannot be a product of glacial erosion. We propose that multiple Great Unconformities developed diachronously and represent regional tectonic features rather than a synchronous global phenomenon.
Geochemistry International, Vol. 55, 12, pp. 1118-1130.
Russia
deposit - Lomonosov
Abstract: Thermodynamic numerical simulations were carried out to determine the principal simple and complex migration species of Ca, Mg, Na, K, Al, B, Mn, Mo, Sr, and U with Cl-, OH-, SO4?2, HCO3?, and CO32? in waters at the Lomonosov diamond deposit and to estimate the saturation indexes with respect to kaolinite, Na- and Mg-montmorillonite, Mg- and Na-saponite, muscovite and paragonite, biotite, phlogopite, chromite, pyrite, plagioclase (anorthite, labradorite, and andesine), olivine (forsterite and fayalite), diopside, pyrope, gypsum, anhydrite, barite, magnesite, calcite, dolomite, talc, chrysotile, chlorite, goethite, quartz, microcline, and albite. The waters are proved not to be saturated with respect to the primary (hydrothermal) minerals. The saturation of certain water samples with uranophane suggests that this mineral is of secondary genesis. The ascent of highly mineralized deep waters shall result in the dissolution of minerals whose concentrations are near the saturation ones. To maintain the ecological standards of the discharged waters, they should be diluted and/or purified by adsorbing dissolved U on a reducing reactive barrier.
Abstract: This article is devoted to the geology of titanium-rich varieties of the Petyayan-Vara rare-earth dolomitic carbonatites in Vuoriyarvi, Northwest Russia. Analogues of these varieties are present in many carbonatite complexes. The aim of this study was to investigate the behavior of high field strength elements during the late stages of carbonatite formation. We conducted a multilateral study of titanium- and niobium-bearing minerals, including a petrographic study, Raman spectroscopy, microprobe determination of chemical composition, and electron backscatter diffraction. Three TiO2-polymorphs (anatase, brookite and rutile) and three pyrochlore group members (hydroxycalcio-, fluorcalcio-, and kenoplumbopyrochlore) were found to coexist in the studied rocks. The formation of these minerals occurred in several stages. First, Nb-poor Ti-oxides were formed in the fluid-permeable zones. The overprinting of this assemblage by residual fluids led to the generation of Nb-rich brookite (the main niobium concentrator in the Petyayan-Vara) and minerals of the pyrochlore group. This process also caused niobium enrichment with of early generations of Ti oxides. Our results indicate abrupt changes in the physicochemical parameters at the late hydro (carbo) thermal stage of the carbonatite formation and high migration capacity of Ti and Nb under these conditions. The metasomatism was accompanied by the separation of these elements.
Diamond & Related Materials, Vol. 89, pp. 101-107.
Mantle
boron
Abstract: Influence of growth medium composition on the efficiency of boron doping of carbonado-like diamond at 8-9 GPa was studied by diluting the C-B growth system with metallic solvents of carbon, Co and Ni. Addition of these metals to the original system leads to a decrease in the synthesis temperature, degree of doping with boron and suppression of superconductivity in diamond. According to XPS analysis, content of substitutional boron is equal to 0.07, 0.16 and 0.39 at.% in diamonds obtained in Co-C-B, Ni-C-B and C-B growth systems, respectively. Metallic behavior at normal temperatures and superconductivity below 5 K in diamond, synthesized in C-B system, change to semiconducting character of conductivity down to 2 K in diamonds obtained in the diluted systems; a faint hint of superconducting transition at 2 K was detected in the case of diamond grown in Ni-C-B system. By comparing phase composition of the inclusions and the doping efficiency of the diamonds, we are able to suggest that high chemical affinity of boron to boride-forming metals hinders the boron doping of diamond. The heavily boron-doped carbonado-like diamond compacts demonstrate high electrochemical activity in aqueous solutions and can be used as miniature electrodes in electrosynthesis and electroanalysis.
Flourine , yttrium and lanthaide rich cerianite (Ce) from carbonatitic rocks of the Kerimasi volcano and surrounding explosive craters Gregory Rift Tanzania.
Mineralogical Magazine, Vol. 75, 6, pp. 2813-2822.
Shang, C.K., Satir, M., Siebel, W., Nsifa, E.N., Taubald, H., Ligeois, J.P., Tchoua, F.M.
TTG Magmatism in the Congo Craton: a view from major and trace element geochemistry, Rb Sr Sm Nd systematics: case of the Sangmelima region, Ntem Complex
Journal of African Earth Sciences, Vol. 39, 3-5, pp. 61-79.
Hopp, J., Trieloff, M., Brey, G.P., Woodland, A.B., Simon, N.S.C., Wijbrans, J.R., Siebel, W., Reitter, E.
40 Ar 39 Ar ages of phlogopite in mantle xenoliths from South African kimberlites: evidence for metasomatic mantle impregnation during Kilbaran orogenic cycle.
Contributions to Mineralogy and Petrology, Vol. 175, 18p. Pdf
China
lamproites
Abstract: Lamproites and kimberlites are natural probes of the subcontinental lithospheric mantle providing insights into the Earth’s continental lithosphere. Whole-rock major-, trace-element and Sr-Nd-Pb isotopic compositions of the Paleozoic (~?253 Ma) lamproite dikes from the Baifen zone of the Zhenyuan area in southeastern Guizhou Province (in the southern Yangtze Block, South China) are presented. The Baifen lamproites are characterized by high MgO (7.84-14.1 wt%), K2O (3.94-5.07 wt%) and TiO2 (2.69-3.23 wt%) contents, low SiO2 (41.3-45.7 wt%), Na2O (0.21-0.28 wt%) and Al2O3 (6.10-7.20 wt%) contents. All lamproites have elevated Cr (452-599 ppm) and Ni (485-549 ppm) abundances, as well as high Ba (1884-3589 ppm), La (160-186 ppm), Sr (898-1152 ppm) and Zr (532-632 ppm) concentrations. They show uniform REE distribution patterns that are strongly enriched in light REEs relative to heavy REEs [(La/Yb)N?=?71.1-87.6], and exhibit OIB-like geochemical features with obvious enrichment of both LILEs and HFSEs in the primitive mantle-normalized multi-element distribution diagram. Moderately radiogenic Sr (87Sr/86Sri?=?0.706336-0.707439), unradiogenic Nd (143Nd/144Ndi?=?0.511687-0.511704 and ?Nd(t)?=????12.2 to???11.9), and low initial Pb (206Pb/204Pbi?=?16.80-16.90, 207Pb/204Pbi?=?15.34-15.35 and 208Pb/204Pbi?=?37.43-37.70) isotopic compositions are obtained from the rocks. They yield old model ages of TDM(Nd)?=?1.48-1.54 Ga. These signatures suggest that the Baifen lamproite magmas are alkaline, ultrapotassic and ultramafic in character and mainly represent mantle-derived primary melts, which have undergone insignificant crustal contamination and negligible fractional crystallization. The Baifen lamproites originated from a veined metasomatized lithospheric mantle source. We envisage that they were derived by partial melting of old, mineralogically complex metasomatic vein assemblages in the subcontinental lithospheric mantle beneath the southern Yangtze Block. The source region experienced ancient mantle metasomatism with complex modification by enriched fluids and melts. The metasomatic agents are most likely to originate from pre-existing slab subduction beneath the southeastern margin of the Yangtze Block. Tectonically, the Baifen lamproites were emplaced at the southern margin of the Yangtze Block, and they formed in an intraplate extensional setting, showing an anorogenic affinity. In terms of time and space, the genesis of Baifen lamproites is presumably related to the Emeishan large igneous province. The Emeishan mantle plume is suggested as an effective mechanism for rapid extension and thinning of the lithosphere, followed by decompression melting of the subcontinental lithospheric mantle. Combined with the thermal perturbation from asthenospheric upwelling induced by the Emeishan mantle plume, the lamproite magmas, representing small volume and limited partial melts of ancient enriched mantle lithosphere, arose. We propose that the generation of the Baifen lamproite dikes probably was a consequence of the far-field effects of the Emeishan mantle plume.
Journal of Metamorphic Geology, Vol. 33, 5, pp. 463-494.
Africa, Ghana
Geochronology
Abstract: New petrological and geochronological data are presented on high-grade ortho- and paragneisses from northwestern Ghana, forming part of the Paleoproterozoic (2.25-2.00 Ga) West African Craton. The study area is located in the interference zone between N-S and NE--SW-trending craton-scale shear zones, formed during the Eburnean orogeny (2.15-2.00 Ga). High-grade metamorphic domains are separated from low-grade greenstone belts by high-strain zones, including early thrusts, extensional detachments and late-stage strike-slip shear zones. Paragneisses sporadically preserve high-pressure, low-temperature (HP-LT) relicts, formed at the transition between the blueschist facies and the epidote-amphibolite sub-facies (10.0-14.0 kbar, 520-600 °C), and represent a low (~15 °C km?1) apparent geothermal gradient. Migmatites record metamorphic conditions at the amphibolite-granulite facies transition. They reveal a clockwise pressure-temperature-time (P-T-t) path characterized by melting at pressures over 10.0 kbar, followed by decompression and heating to peak temperatures of 750 °C at 5.0-8.0 kbar, which fit a 30 °C km?1 apparent geotherm. A regional amphibolite facies metamorphic overprint is recorded by rocks that followed a clockwise P-T-t path, characterized by peak metamorphic conditions of 7.0-10.0 kbar at 550-680 °C, which match a 20-25 °C km?1 apparent geotherm. These P-T conditions were reached after prograde burial and heating for some rock units, and after decompression and heating for others. The timing of anatexis and of the amphibolite facies metamorphic overprint is constrained by in-situ U-Pb dating of monazite crystallization at 2138 ± 7 and 2130 ± 7 Ma respectively. The new data set challenges the interpretation that metamorphic breaks in the West African Craton are due to diachronous Birimian ‘basins’ overlying a gneissic basement. It suggests that the lower crust was exhumed along reverse, normal and transcurrent shear zones and juxtaposed against shallow crustal slices during the Eburnean orogeny. The craton in NW Ghana is made of distinct fragments with contrasting tectono-metamorphic histories. The range of metamorphic conditions and the sharp lateral metamorphic gradients are inconsistent with ‘hot orogeny’ models proposed for many Precambrian provinces. These findings shed new light on the geodynamic setting of craton assembly and stabilization in the Paleoproterozoic. It is suggested that the metamorphic record of the West African Craton is characteristic of Paleoproterozoic plate tectonics and illustrates a transition between Archean and Phanerozoic orogens.
Abstract: The West-African craton is defined by a combination of Archean and Palaeoproterozoic rocks that stabilised at ~2 Ga towards the end of the Paleoproterozoic Eburnean Orogeny, and therefore may reflect the transition from Archean to modern tectonic processes. Exploring its present lithospheric architecture aids further understanding of not only the craton’s stability through its history but also its formation. We investigate the lithospheric structure of the craton through analysing and modelling magnetotelluric (MT) data from a 500-km-long east-west profile in northern Ghana and southern Burkina Faso crossing part of the Baoulé-Mossi Domain and reaching the Volta Basin in the south-eastern part of the craton. Although the MT stations are along a 2D profile, due to the complexity of the structures characterising the area, 3D resistivity modelling of the data is performed to obtain insights on the thermal signature and composition of the subcontinental lithosphere beneath the area. The thermal structure and water content estimates from different resistivity models highlight a strong dependence on the starting model in the 3D inversions, but still enable us to put constraints on the deep structure of the craton. The present?day thermal lithosphere?asthenosphere boundary (LAB) depth is estimated to be at least 250 km beneath the Baoulé-Mossi domain. The area likely transitions from a cold and thick lithosphere with relatively low water content into thinner, more fertile lithosphere below the Volta Basin. Although the inferred amount of water could be explained by Paleoproterozoic subduction processes involved in the formation of the Baoulé-Mossi domain, later enrichment of the lithosphere cannot be excluded.
Contributions to Mineralogy and Petrology, Vol. 177, 44, 10.1007/s00410-022-01905-w.
Mantle
peridotites
Abstract: Devolatilization of subducting lithologies liberates COH-fluids. These may become partially sequestered in peridotites in the slab and the overlying forearc mantle, affecting the cycling of volatiles and fluid mobile elements in subduction zones. Here we assess the magnitudes, timescales and mechanism of channelized injection of COH-fluids doped with Ca2+aq, Sr2+aq and Ba2+aq into the dry forearc mantle by performing piston cylinder experiments between 1-2.5 GPa and 600-700 °C. Cylindrical cores of natural spinel-bearing harzburgites were used as starting materials. Based on mineral assemblage and composition three reaction zones are distinguishable from the rim towards the core of primary olivine and orthopyroxene grains. Zone 1 contains carbonates?+?quartz?±?kyanite and zone 2 contains carbonates?+?talc?±?chlorite. Olivine is further replaced in zone 3 by either antigorite?+?magnesite or magnesite?+?talc within or above antigorite stability, respectively. Orthopyroxene is replaced in zone 3 by talc?+?chlorite. Mineral assemblages and the compositions of secondary minerals depend on fluid composition and the replaced primary silicate. The extent of alteration depends on fluid CO2 content and fluid/rock-ratio, and is further promoted by fluid permeable reaction zones and reaction driven cracking. Our results show that COH-fluid induced metasomatism of the forearc mantle is self-perpetuating and efficient at sequestering Ca2+aq, Sr2+aq, Ba2+aq and CO2aq into newly formed carbonates. This process is fast with 90% of the available C sequestered and nearly 50% of the initial minerals altered at 650 °C, 2 GPa within 55 h. The dissolution of primary silicates under high COH-fluid/rock-ratios, as in channelized fluid flow, enriches SiO2aq in the fluid, while CO2aq is sequestered into carbonates. In an open system, the remaining CO2-depleted, Si-enriched aqueous fluid may cause Si-metasomatism in the forearc further away from the injection of the COH-fluid into peridotite.
Abstract: Recent palaeomagnetic observations1 report the existence of a magnetic field on Earth that is at least 3.45 billion years old. Compositional buoyancy caused by inner-core growth2 is the primary driver of Earth’s present-day geodynamo3, 4, 5, but the inner core is too young6 to explain the existence of a magnetic field before about one billion years ago. Theoretical models7 propose that the exsolution of magnesium oxide—the major constituent of Earth’s mantle—from the core provided a major source of the energy required to drive an early dynamo, but experimental evidence for the incorporation of mantle components into the core has been lacking. Indeed, terrestrial core formation occurred in the early molten Earth by gravitational segregation of immiscible metal and silicate melts, transporting iron-loving (siderophile) elements from the silicate mantle to the metallic core8, 9, 10 and leaving rock-loving (lithophile) mantle components behind. Here we present experiments showing that magnesium oxide dissolves in core-forming iron melt at very high temperatures. Using core-formation models11, we show that extreme events during Earth’s accretion (such as the Moon-forming giant impact12) could have contributed large amounts of magnesium to the early core. As the core subsequently cooled, exsolution7 of buoyant magnesium oxide would have taken place at the core-mantle boundary, generating a substantial amount of gravitational energy as a result of compositional buoyancy. This amount of energy is comparable to, if not more than, that produced by inner-core growth, resolving the conundrum posed by the existence of an ancient magnetic field prior to the formation of the inner core.
Abstract: Recent palaeomagnetic observations report the existence of a magnetic field on Earth that is at least 3.45 billion years old. Compositional buoyancy caused by inner-core growth is the primary driver of Earth's present-day geodynamo, but the inner core is too young to explain the existence of a magnetic field before about one billion years ago. Theoretical models propose that the exsolution of magnesium oxide--the major constituent of Earth's mantle--from the core provided a major source of the energy required to drive an early dynamo, but experimental evidence for the incorporation of mantle components into the core has been lacking. Indeed, terrestrial core formation occurred in the early molten Earth by gravitational segregation of immiscible metal and silicate melts, transporting iron-loving (siderophile) elements from the silicate mantle to the metallic core and leaving rock-loving (lithophile) mantle components behind. Here we present experiments showing that magnesium oxide dissolves in core-forming iron melt at very high temperatures. Using core-formation models, we show that extreme events during Earth's accretion (such as the Moon-forming giant impact) could have contributed large amounts of magnesium to the early core. As the core subsequently cooled, exsolution of buoyant magnesium oxide would have taken place at the core-mantle boundary, generating a substantial amount of gravitational energy as a result of compositional buoyancy. This amount of energy is comparable to, if not more than, that produced by inner-core growth, resolving the conundrum posed by the existence of an ancient magnetic field prior to the formation of the inner core.
Journal of Geophysical Research: Solid Earth, doi:10.1029/2018JB015991
Mantle
core mantle boundary
Abstract: Experiments wherein molten metal and silicate (rock?building) phases un?mix themselves due to their physical properties, i.e. metal?silicate partitioning, can be conducted at the high temperatures and pressures (HP?HT) that characterized Earth's differentiation into a core and mantle. The redistribution of elements between the metal and silicate phases ? their partitioning ? during this process can be measured and mathematically described, then placed into numerical models to better understand Earth's formation history. Here, we have mathematically characterized the HP?HT partitioning of copper, combined this with results for sulfur from literature, and input these characterizations into numerical models that track their distribution between Earth's core and mantle as it grows to its present mass. Copper and sulfur were chosen because they display different sensitivities to the physical mechanisms that govern planetary formation, and we can leverage this to better understand Earth's formation and differentiation history. Our results indicate that ~75% of Earth's precursor materials grew incrementally from relatively small bits of material ? on average ~0.1% of Earth's mass or less ? that is most compositionally similar to meteorite classes that are made up of iron?rich metal and silicate solids (chondrules) that are depleted in easily vaporized (volatile) elements, especially sulfur.
Geophysical Research Letters, Vol. 45, 24, pp. 13,240-13,248.
Mantle
geodynamics
Abstract: We measure the incorporation of magnesium oxide (one of the main components of Earth's mantle) into iron (the main constituent Earth's core), using extremely high pressure and temperature experiments that mimic the conditions of Earth's mantle and core. We find that magnesium oxide dissolution depends on temperature but not on pressure, and on metal (i.e., core) composition but not silicate (i.e., mantle) composition. Our findings support the idea that magnesium oxide dissolved in the core during its formation will precipitate out during subsequent core cooling. The precipitation should stir the entire core to produce a magnetic field in Earth's distant past, at least as intense as the present?day field.
Abstract: Zircon- and bulk-rock Zr-based thermometric parameters have become fundamental to petrogenetic models of magmatism, from which broader geochronological and tectonic implications are being made. In particular, petrogenetic models have become increasingly reliant on Ti concentration in zircon geothermometry (TZircTi) and zircon saturation temperature (TZircsat). A feature of many of these studies is an implicit assumption that all zircons present in the host igneous rock are autocrystic, that is, crystallised from the surrounding melt. However, it has long been recognised that zircons present in an igneous rock can be inherited either from the surrounding country rock or source region (xenocrysts), or from earlier phases of magmatism or the magmatic plumbing system (antecrysts). Distinguishing these different origins for zircon crystals or domains within crystals is not straightforward. Here, we first review the utility and reliability of zircon-based thermometers for petrogenetic studies and show that TZircsat is a theoretical temperature and cannot be used to constrain magmatic or partial melting temperatures. It is a dynamic variable that changes during magma crystallisation, and essentially increases as fractional crystallisation proceeds, whereas true magmatic temperatures (TMagma) decrease. Generally, in Temperature-SiO2 space, the cross-over point of these two temperatures is magmatic system dependent, and also affected by the type of calibration used for the TZircsat calculations. Consequently, each magmatic system needs to be evaluated independently to assess the validity and usefulness of TZircsat. A fundamental conclusion of TZircsat and TMagma relationships assessed here is that new zircon generally only crystallises in silicic (granitic/rhyolitic) melt compositions, and thus autocrystic zircons should not be assumed to be present in igneous rocks with bulk compositions < 64 wt% SiO2, although inherited and minor zircons crystallising from late-stage differentiated melt pockets can be present. This highlights the importance of discriminating autocrystic from inherited zircons in igneous rocks. We then review techniques available to discriminate autocrystic from inherited zircons, and propose a new methodology to assist in the identification of autocrystic zircons for emplacement age determination and separate evaluation of inherited zircon components. The approach uses two strands of data: 1) zircon data such as zircon morphologies, textures, compositions and U-Pb ages, and 2) whole-rock data, in particular SiO2 and coupled geothermometry (TZircsat and TMagma) to estimate whether the magma was zircon-saturated or undersaturated. To test this new protocol, we use as examples, several Phanerozoic granitic rocks intersected by drilling in Queensland where contextual information is limited, and show how antecrystic and xenocrystic zircons and monazites can be distinguished. In contrast, where zircons are metamict (for example, high U and Th-rich zircons), much of the ability to discriminate is impacted because such zircons have suffered Pb loss and have modified compositions (e.g., higher TZircTi). We recommend an integrated approach incorporating whole-rock chemistry, independent geothermometric constraints, zircon composition, textures and ages obtained by routine cathodoluminescence and LA-ICP-MS or ion microprobe analysis to provide increased confidence for the discrimination of inherited zircons from autocrystic zircons and determination of the emplacement age.
Abstract: Zircon- and bulk-rock Zr-based thermometric parameters have become fundamental to petrogenetic models of magmatism, from which broader geochronological and tectonic implications are being made. In particular, petrogenetic models have become increasingly reliant on Ti concentration in zircon geothermometry (TZircTi) and zircon saturation temperature (TZircsat). A feature of many of these studies is an implicit assumption that all zircons present in the host igneous rock are autocrystic, that is, crystallised from the surrounding melt. However, it has long been recognised that zircons present in an igneous rock can be inherited either from the surrounding country rock or source region (xenocrysts), or from earlier phases of magmatism or the magmatic plumbing system (antecrysts). Distinguishing these different origins for zircon crystals or domains within crystals is not straightforward. Here, we first review the utility and reliability of zircon-based thermometers for petrogenetic studies and show that TZircsat is a theoretical temperature and cannot be used to constrain magmatic or partial melting temperatures. It is a dynamic variable that changes during magma crystallisation, and essentially increases as fractional crystallisation proceeds, whereas true magmatic temperatures (TMagma) decrease. Generally, in Temperature-SiO2 space, the cross-over point of these two temperatures is magmatic system dependent, and also affected by the type of calibration used for the TZircsat calculations. Consequently, each magmatic system needs to be evaluated independently to assess the validity and usefulness of TZircsat. A fundamental conclusion of TZircsat and TMagma relationships assessed here is that new zircon generally only crystallises in silicic (granitic/rhyolitic) melt compositions, and thus autocrystic zircons should not be assumed to be present in igneous rocks with bulk compositions < 64 wt% SiO2, although inherited and minor zircons crystallising from late-stage differentiated melt pockets can be present. This highlights the importance of discriminating autocrystic from inherited zircons in igneous rocks. We then review techniques available to discriminate autocrystic from inherited zircons, and propose a new methodology to assist in the identification of autocrystic zircons for emplacement age determination and separate evaluation of inherited zircon components. The approach uses two strands of data: 1) zircon data such as zircon morphologies, textures, compositions and U-Pb ages, and 2) whole-rock data, in particular SiO2 and coupled geothermometry (TZircsat and TMagma) to estimate whether the magma was zircon-saturated or undersaturated. To test this new protocol, we use as examples, several Phanerozoic granitic rocks intersected by drilling in Queensland where contextual information is limited, and show how antecrystic and xenocrystic zircons and monazites can be distinguished. In contrast, where zircons are metamict (for example, high U and Th-rich zircons), much of the ability to discriminate is impacted because such zircons have suffered Pb loss and have modified compositions (e.g., higher TZircTi). We recommend an integrated approach incorporating whole-rock chemistry, independent geothermometric constraints, zircon composition, textures and ages obtained by routine cathodoluminescence and LA-ICP-MS or ion microprobe analysis to provide increased confidence for the discrimination of inherited zircons from autocrystic zircons and determination of the emplacement age.
Geophysical Research Letters, Vol. 46, 15, pp. 8731-8740.
Mantle
bridgmanite
Abstract: The lower mantle encompasses the largest region of the Earth's interior and is mainly composed of the perovskite?structured mineral (Mg,Fe,Al)(Al,Si)O3 bridgmanite. Its properties, therefore, control both the diffusive transport of elements and solid state flow in the lower mantle, which will be strongly influenced by point defects. We have identified and quantified defects in bridgmanite that arise from the replacement of silicon by aluminum and result in the creation of a vacant oxygen site. These oxygen defects are also found to form clusters in the structure, which in other perovskite structured minerals have been shown to strongly affect physical properties. As defect formation and ordering is dependent on composition and pressure, strong variations in physical properties may be expected within the upper 300 km of the lower mantle.
Abstract: Geological, geochronological and isotopic data are integrated in order to present a revised model for the Neoproterozoic evolution of Western Gondwana. Although the classical geodynamic scenario assumed for the period 800–700 Ma is related to Rodinia break-up and the consequent opening of major oceanic basins, a significantly different tectonic evolution can be inferred for most Western Gondwana cratons. These cratons occupied a marginal position in the southern hemisphere with respect to Rodinia and recorded subduction with back-arc extension, island arc development and limited formation of oceanic crust in internal oceans. This period was thus characterized by increased crustal growth in Western Gondwana, resulting from addition of juvenile continental crust along convergent margins. In contrast, crustal reworking and metacratonization were dominant during the subsequent assembly of Gondwana. The Río de la Plata, Congo-São Francisco, West African and Amazonian cratons collided at ca. 630–600 Ma along the West Gondwana Orogen. These events overlap in time with the onset of the opening of the Iapetus Ocean at ca. 610–600 Ma, which gave rise to the separation of Baltica, Laurentia and Amazonia and resulted from the final Rodinia break-up. The East African/Antarctic Orogen recorded the subsequent amalgamation of Western and Eastern Gondwana after ca. 580 Ma, contemporaneously with the beginning of subduction in the Terra Australis Orogen along the southern Gondwana margin. However, the Kalahari Craton was lately incorporated during the Late Ediacaran–Early Cambrian. The proposed Gondwana evolution rules out the existence of Pannotia, as the final Gondwana amalgamation postdates latest connections between Laurentia and Amazonia. Additionally, a combination of introversion and extroversion is proposed for the assembly of Gondwana. The contemporaneous record of final Rodinia break-up and Gondwana assembly has major implications for the supercontinent cycle, as supercontinent amalgamation and break-up do not necessarily represent alternating episodic processes but overlap in time.
Journal of the Geological Society, Vol. 174, pp. 609-626.
South America, Uruguay
magmatism
Abstract: The crystalline basement of Uruguay was assembled during the Brasiliano Orogeny in the Neoproterozoic Era and was later affected by discrete tectonic activity. A new multi-method low-temperature dataset including (U–Th)/He ages from both zircon and apatite, T–t modelling and K–Ar dating of fine sericite fractions and fault gouge reveal a detailed post-orogenic geological history spanning the Phanerozoic Eon. The juxtaposition of the terranes that compose the area was achieved in the Ediacaran Period, and post-collision was marked by intense exhumation, in which the crystalline basement reached near-surface conditions by the early to mid-Palaeozoic. Regional subsidence promoted sedimentation in the Paraná Basin until the Permian, covering and reheating much of the basement that is at present exposed. Afterwards, deposition and volcanism were mostly confined to its current limits. Regional exhumation of the shield during the Permo-Triassic exposed much of the northern portion of the basement, and the south was further affected by the opening of the South Atlantic Ocean during the Mesozoic. Little exhumation affected the Uruguayan Shield during the Cenozoic, as reflected in its modest topography. The reactivation of inherited Neoproterozoic structures influenced the development of Mesozoic basins and the present-day landscape.
Abstract: Geological, geochronological and isotopic data are integrated in order to present a revised model for the Neoproterozoic evolution of Western Gondwana. Although the classical geodynamic scenario assumed for the period 800-700 Ma is related to Rodinia break-up and the consequent opening of major oceanic basins, a significantly different tectonic evolution can be inferred for most Western Gondwana cratons. These cratons occupied a marginal position in the southern hemisphere with respect to Rodinia and recorded subduction with back-arc extension, island arc development and limited formation of oceanic crust in internal oceans. This period was thus characterized by increased crustal growth in Western Gondwana, resulting from addition of juvenile continental crust along convergent margins. In contrast, crustal reworking and metacratonization were dominant during the subsequent assembly of Gondwana. The Río de la Plata, Congo-São Francisco, West African and Amazonian cratons collided at ca. 630-600 Ma along the West Gondwana Orogen. These events overlap in time with the onset of the opening of the Iapetus Ocean at ca. 610-600 Ma, which gave rise to the separation of Baltica, Laurentia and Amazonia and resulted from the final Rodinia break-up. The East African/Antarctic Orogen recorded the subsequent amalgamation of Western and Eastern Gondwana after ca. 580 Ma, contemporaneously with the beginning of subduction in the Terra Australis Orogen along the southern Gondwana margin. However, the Kalahari Craton was lately incorporated during the Late Ediacaran-Early Cambrian. The proposed Gondwana evolution rules out the existence of Pannotia, as the final Gondwana amalgamation postdates latest connections between Laurentia and Amazonia. Additionally, a combination of introversion and extroversion is proposed for the assembly of Gondwana. The contemporaneous record of final Rodinia break-up and Gondwana assembly has major implications for the supercontinent cycle, as supercontinent amalgamation and break-up do not necessarily represent alternating episodic processes but overlap in time.
Abstract: New U-Pb and first Hf data were obtained from the Nico Pérez and Piedra Alta Terranes as well as from the Congo Craton. Results indicate that the Nico Pérez Terrane was mostly built during Archean episodic crustal growth and this crust underwent significant Paleo- and Neoproterozoic crustal reworking at ca. 2.2-2.0, 1.7 and 0.6 Ga. The Piedra Alta Terrane of the Río de la Plata Craton, in contrast, records only Paleoproteorozoic crustal growth. These evidences together with available geological, geochronological and isotopic data indicate the allochthony of the Nico Pérez Terrane. Furthermore, data point to an African origin of the Nico Pérez Terrane, particularly related to the southwestern Congo Craton. After Cryogenian rifting from the latter during Rodinia break-up, the Nico Pérez Terrane was accreted to the eastern Río de la Plata Craton along the Sarandí del Yí Shear Zone and underwent further crustal reworking during the evolution of the Dom Feliciano Belt.
Abstract: Carbonatites and alkaline-silicate rocks are the most important sources of rare earth elements (REE) and niobium (Nb), both of which are metals imperative to technological advancement and associated with high risks of supply interruption. Cooling and crystallizing carbonatitic and alkaline melts expel multiple pulses of alkali-rich aqueous fluids which metasomatize the surrounding country rocks, forming fenites during a process called fenitization. These alkalis and volatiles are original constituents of the magma that are not recorded in the carbonatite rock, and therefore fenites should not be dismissed during the description of a carbonatite system. This paper reviews the existing literature, focusing on 17 worldwide carbonatite complexes whose attributes are used to discuss the main features and processes of fenitization. Although many attempts have been made in the literature to categorize and name fenites, it is recommended that the IUGS metamorphic nomenclature be used to describe predominant mineralogy and textures. Complexing anions greatly enhance the solubility of REE and Nb in these fenitizing fluids, mobilizing them into the surrounding country rock, and precipitating REE- and Nb-enriched micro-mineral assemblages. As such, fenites have significant potential to be used as an exploration tool to find mineralized intrusions in a similar way alteration patterns are used in other ore systems, such as porphyry copper deposits. Strong trends have been identified between the presence of more complex veining textures, mineralogy and brecciation in fenites with intermediate stage Nb-enriched and later stage REE-enriched magmas. However, compiling this evidence has also highlighted large gaps in the literature relating to fenitization. These need to be addressed before fenite can be used as a comprehensive and effective exploration tool.
Abstract: Security of supply of “hi-tech” raw materials (including the rare earth elements (REE) and some high-field-strength elements (HFSEs)) is a concern for the European Union. Exploration and research projects mostly focus on deposit- to outcrop-scale description of carbonatite- and alkaline igneous-associated REE-HFSE mineralization. The REE-HFSE mineral system concept and approach are at a nascent stage, so developed further here. However, before applying the mineral system approach to a chosen REE-HFSE metallogenic province its mineral system extent first needs defining and mapping. This shifts a mineral system project’s foundation from the mineral system concept to a province’s mineral system extent. The mapped extent is required to investigate systematically the pathways and potential trap locations along which the REE-HFSE mass may be distributed. A workflow is presented to standardize the 4-D definition of a REE-HFSE mineral system at province-scale: (a) Identify and hierarchically organize a mineral system’s genetically related sub-divisions and deposits, (b) map its known and possible maximum extents, (c) name it, (d) discern its size (known mineral endowment), and (e) assess the favorability of the critical components to prioritize further investigations. The workflow is designed to generate process-based perspective and improve predictive targeting effectiveness along under-evaluated plays of any mineral system, for the future risking, comparing and ranking of REE-HFSE provinces and plays.
Abstract: The Southern Irumide Belt (SIB) of Zambia consists of predominantly Mesoproterozoic terranes that record a pervasive tectono-metamorphic overprint from collision between the Congo and Kalahari cratons in the final stages of Gondwana amalgamation. This study applies multi-method thermochronology to samples throughout southern Zambia to constrain the post-collisional, Phanerozoic thermo-tectonic evolution of the region. U-Pb apatite and 40Ar/39Ar muscovite data are used to constrain the cooling history of the region following Congo-Kalahari collision, and reveal ages of c. 550-450?Ma. Variations in the recorded cooling ages are interpreted to relate to localised post-tectonic magmatism and the proximity of analysed samples to the Congo-Kalahari suture. Apatite fission track data are used to constrain the low-temperature thermo-tectonic evolution of the region and identify mean central ages of c. 320-300, 210-200 and 120-110?Ma. Thermal modelling of these samples identifies a number of thermal events occurring in the region throughout the Phanerozoic. Carboniferous to Permian-Triassic heating is suggested to relate to the development of Karoo rift basins found throughout central Africa and constrain the timing of sedimentation in the basin. Permian to Jurassic cooling is identified in a number of samples, reflecting exhumation as a result of the Mauritanian-Variscan and Gondwanide orogenies. Subsequent cooling of the majority of samples occurs from the Cretaceous and persists until present, reflecting exhumation in response to larger scale rifting associated with the break-up of Gondwana. Each model reveals a later phase of enhanced cooling beginning at c. 30?Ma that, if not an artefact of modelling, corresponds to the development of the East African Rift System. The obtained thermochronological data elucidate the previously unconstrained thermal evolution of the SIB, and provides a refined regional framework for constraining the tectonic history of central Africa throughout the Phanerozoic.
Abstract: Carbonate-bearing fluorapatite rocks occur at over 30 globally distributed carbonatite complexes and represent a substantial potential supply of phosphorus for the fertiliser industry. However, the process(es) involved in forming carbonate-bearing fluorapatite at some carbonatites remain equivocal, with both hydrothermal and weathering mechanisms inferred. In this contribution, we compare the paragenesis and trace element contents of carbonate-bearing fluorapatite rocks from the Kovdor, Sokli, Bukusu, Catalão I and Glenover carbonatites in order to further understand their origin, as well as to comment upon the concentration of elements that may be deleterious to fertiliser production. The paragenesis of apatite from each deposit is broadly equivalent, comprising residual magmatic grains overgrown by several different stages of carbonate-bearing fluorapatite. The first forms epitactic overgrowths on residual magmatic grains, followed by the formation of massive apatite which, in turn, is cross-cut by late euhedral and colloform apatite generations. Compositionally, the paragenetic sequence corresponds to a substantial decrease in the concentration of rare earth elements (REE), Sr, Na and Th, with an increase in U and Cd. The carbonate-bearing fluorapatite exhibits a negative Ce anomaly, attributed to oxic conditions in a surficial environment and, in combination with the textural and compositional commonality, supports a weathering origin for these rocks. Carbonate-bearing fluorapatite has Th contents which are several orders of magnitude lower than magmatic apatite grains, potentially making such apatite a more environmentally attractive feedstock for the fertiliser industry. Uranium and cadmium contents are higher in carbonate-bearing fluorapatite than magmatic carbonatite apatite, but are much lower than most marine phosphorites.
Geochemistry, Geophysics, Geosystems, Vol. 20, 9, pp. 4426-4456.
Russia
xenoliths
Abstract: This paper presents the results of a study of rare rock fragments (xenoliths) that were transported from the Earth's deep interior to the surface during an eruption of Kharchinsky volcano, Kamchatka. The chemical compositions, mineralogy, and textures of the samples were studied with the goal of understanding the processes that affected rocks, which may play a role in the formation of magmas in the Kamchatka subduction zone. The key process that affected the xenoliths involved the addition of fluids and dissolved elements to the samples at temperatures of 500-700 °C. These fluids are derived from seawater that was transported to 30? to 50?km depths by subduction of the Pacific Plate beneath Kamchatka. Subsequent to the addition of fluid, there was a shift in the position of the Kamchatka?Pacific Plate boundary that led to an increase in temperature and the formation of small quantities of melt that crystallized to a distinctive group of secondary minerals that are present in the samples and that postdate (overprint) the initial effects of fluid addition. The final step in the evolution of the samples was infiltration by an Fe? and Mg?rich magma that crystallized principally amphibole?group minerals.
Galloway, M., Nowicki, T., Van Coller, B., Mukodzani, B., Siemens, K., Hetman, C., Webb, K., Gurney, J.
Constraining kimberlite geology through integration of geophysical, geological and geochemical methods: a case study of the Mothae kimberlite, northern Lesotho.
Bonadiman, C., Beccaluva, L., Coltort, M., Siena, F.
Kimberlite like metasomatism and garnet signature in spinel peridotite xenoliths from Sal, Cape Verde Archipelago: relics of subcontinental mantle domain.
Abstract: A comprehensive study including new field, petrological and geochemical data is reported on the Jacupiranga alkaline-carbonatite complex (133-131 Ma) which, together with other alkaline complexes, occurs in southern Brazil and is coeval with the Paraná CFB province. It consists of a shallow intrusion (ca. 65 km2) in the Precambrian crystalline basement, and can be subdivided in two main diachronous plutonic bodies: an older dunite-gabbro-syenite in the NW and a younger clinopyroxenite-ijolite (s.l.) in the SE, later injected by a carbonatitic core (ca. 1 km2). An integrated petrogenetic model, based on bulk rock major and trace element analyses, mineral chemistry and Sr-Nd-Pb-C isotopic data, suggests that the two silicate intrusions generated from different mantle-derived magmas that evolved at shallow level (2-3 km depth) in two zoned cup-shaped plutonic bodies growing incrementally from independent feeding systems. The first intrusion was generated by OIB-like alkaline to mildly alkaline parental basalts that initially led to the formation of a dunitic adcumulate core, discontinuously surrounded by gabbroic cumulates, in turn injected by subanular syenite intrusive and phonolite dykes. Nephelinitic (± melilite) melts - likely generated deep in the lithosphere at ? 3 GPa - were the parental magmas of the second intrusion and gave rise to large coarse-grained clinopyroxenite ad- to meso-cumulates, in turn surrounded, and partially cut, by semi-annular fine-layered melteigite-ijolite-urtite ortho-cumulates. The available isotopic data do not evidence genetic links between carbonatites and the associated silicate intrusions, thus favouring an independent source from the mantle. Moreover, it may be suggested that, unlike gabbro-syenites and carbonatites, mostly generated from lithospheric mantle sources, the parental magmas of the ijolite-clinopyroxenite intrusion also record the influence of sublithospheric (plume-related?) geochemical components.
Natali, C., Beccaluva, L., Bianchini, G., Siena, F.
Coexistence of alkaline carbonatite complexes and high MgO CFB in the Parana-Etendeka province: insights on plume lithosphere interactions in the Gondwana realm.
Abstract: The effect of aluminum (Al) on the elasticity of majorite-pyrope garnets was investigated by means of ultrasonic interferometry measurements on well-fabricated polycrystalline specimens. Both velocities and elastic moduli increase almost linearly with increasing Al content within analytical uncertainty. No significant variation of the velocities and elastic moduli is observed across the tetragonal-to-cubic phase transition at majorite with the pyrope content up to 26 mol% along the majorite-pyrope system. The elasticity variation of majorite-pyrope garnets is largely dominated by the Al content, while the phase transition as a result of cation ordering/disordering of Mg and Si via substitution of Al on octahedral sites cannot significantly affect elastic properties. Seismic velocity variations of a garnet-bearing mantle transition zone are therefore dominated by garnet composition (e.g., Al, Fe, Ca, and Na) rather than the tetragonal-to-cubic phase transition because of cation ordering/disordering.
Abstract: Seismology records the presence of various heterogeneities throughout the lower mantle1,2, but the origins of these signals—whether thermal or chemical—remain uncertain, and therefore much of the information that they hold about the nature of the deep Earth is obscured. Accurate interpretation of observed seismic velocities requires knowledge of the seismic properties of all of Earth’s possible mineral components. Calcium silicate (CaSiO3) perovskite is believed to be the third most abundant mineral throughout the lower mantle. Here we simultaneously measure the crystal structure and the shear-wave and compressional-wave velocities of samples of CaSiO3 perovskite, and provide direct constraints on the adiabatic bulk and shear moduli of this material. We observe that incorporation of titanium into CaSiO3 perovskite stabilizes the tetragonal structure at higher temperatures, and that the material’s shear modulus is substantially lower than is predicted by computations3,4,5 or thermodynamic datasets6. When combined with literature data and extrapolated, our results suggest that subducted oceanic crust will be visible as low-seismic-velocity anomalies throughout the lower mantle. In particular, we show that large low-shear-velocity provinces (LLSVPs) are consistent with moderate enrichment of recycled oceanic crust, and mid-mantle discontinuities can be explained by a tetragonal-cubic phase transition in Ti-bearing CaSiO3 perovskite.
Angewandte Chemie International, Vol. 60, 3, pp. 1546-1549. pdf
Global
diamond, graphite
Abstract: Recent density?functional theory (DFT) calculations raised the possibility that diamond could be degenerate with graphite at very low temperatures. Through high?accuracy calorimetric experiments closing gaps in available data, we reinvestigate the relative thermodynamic stability of diamond and graphite. For T<400 K, graphite is always more stable than diamond at ambient pressure. At low temperatures, the stability is enthalpically driven, and entropy terms add to the stability at higher temperatures. We also carried out DFT calculations: B86bPBE?25X?XDM//B86bPBE?XDM and PBE0?XDM//PBE?XDM results overlap with the experimental ?T?S results and bracket the experimental values of ?H and ?G, displaced by only about 2× the experimental uncertainty. Revised values of the standard thermodynamic functions for diamond are ?fHo=?2150±150 J?mol?1, ?fSo=3.44±0.03 J?K?1?mol?1 and ?fGo=?3170±150 J?mol?1.
Physics of the Earth and Planetary Interiors, doi.org/10.1016/ j.pepi.2020.106638 51p. Pdf
Mantle
geophysics - magnetics
Abstract: Decompression melting of the upper mantle produces magmas and volcanism at the Earth's surface. Experimental petrology demonstrates that the presence of CO2 and H2O enhances peridotite melting anywhere within the upper mantle down to approximately 200-300?km depth. The presence of mantle melts with compositions ranging from carbonate-rich to silicate-rich unavoidably affects the geophysical signals retrieved from Earth's mantle. Geochemical investigations of erupted intraplate magmas along with geophysical surveys allow for constraining the nature and volume of primary melts, and a sound formalism is required to integrate these diverse datasets into a realistic model for the upper mantle including melting processes. Here, we introduce MAGLAB, a model developed to calculate the composition and volume fraction of melts in the upper mantle, together with the corresponding electrical conductivity of partially molten mantle peridotites at realistic pressure-temperature conditions and volatile contents. We use MAGLAB to show how the compositions of intraplate magmas relate to variations in lithosphere thickness. Progressive partial melting of a homogeneous peridotitic mantle source can in theory create the diversity of compositions observed among the spectrum of intraplate magma types, with kimberlite melts beneath thick continental shields, alkaline magmas such as melilitite, nephelinite and basanite beneath thinner continents and relatively old plus thick oceanic lithospheres, and ‘regular’ basalts beneath the youngest and thinnest oceanic lithospheres as well as beneath significantly thinned continental lithospheres. MAGLAB calculations support recent experimental findings about the role of H2O in the upper mantle on producing primary kimberlitic melts in addition to CO2. We demonstrate the robustness of MAGLAB calculations by reproducing the compositions of erupted melts as well as associated mantle electrical conductivities beneath the Society hotspot in the Pacific Ocean. A comparison of our simulations with magnetotelluric surveys at various oceanic settings shows that the heterogeneities in electrical conductivity of Earth's upper mantle are related to variations in volatile content via the presence of small (generally <<1?wt%) and heterogeneously distributed fractions of CO2-H2O-bearing melts.
Abstract: Hydrogen (H) and carbon (C) have probably been delivered to the Earth mainly during accretion processes at High Temperature (HT) and High Pressure (HP) and at variable redox conditions. We performed HP (1-15?GPa) and HT (1600-2300°C) experiments, combined with state-of-the-art analytical techniques to better understand the behavior of H and C during planetary differentiation processes. We show that increasing pressure makes H slightly siderophile and slightly decreases the highly siderophile nature of C. This implies that the capacity of a growing core to retain significant amounts of H or C is mainly controlled by the size of the planet: small planetary bodies may retain C in their cores while H may have rather been lost in space; larger bodies may store both H and C in their cores. During the Earth's differentiation, both C and H might be sequestrated in the core. However, the H content of the core would remain one or two orders of magnitude lower than that of C since the (H/C)core ratio might range between 0.04 and 0.27.
Passarelli, C.R., Basei, M.A.S., Wemmer, K., Siga, O., Oyhantcabal, P.
Major shear zones of southern Brazil and Uruguay: escape tectonics in the eastern border of Rio de la Plat a and Parananpanema cratons during West Gondwana
International Journal of Earth Sciences, in press available,
Passarelli, C.R., Basei, M.A.S., Wemmer,K., Siga, O., Oyhantcabal, P.
Major shear zones of southern Brazil and Uruguay: escape tectonics in the eastern border of Rio de la Plat a and Paranapanema cratons during w. Gondwana amal.
International Journal of Earth Sciences, Vol. 100, 2, pp. 391-414.
Abstract: Gravity anomalies across the Indian region depict most of the geological and tectonic domains of the Indian continental lithosphere, which evolved through Archean cratonic nucleation, Proterozoic accretion, Phanerozoic India-Eurasia plate convergence, and modification through many thermal perturbations and rifting. Integrated analysis of gravity and geoid anomalies together with topographic and heat flow data led to deciphering the mechanism of isostatic compensation of topographic and geological loads, lithospheric structure, and composition. This study discusses the nature of gravity (free-air, Bouguer and Isostatic) and geoid anomalies in relation to the topography, geology, and tectonics, and presents a lithospheric density model across the peninsular India and Himalaya. Southern peninsular Indian region shows relatively low Bouguer gravity anomalies compared to the northern region. The mobile belts are generally observed to have relatively higher Bouguer gravity anomalies, e.g., Eastern Ghats Mobile Belt compared to the shield regions. The gravity lows are observed over topographic features like the Western Ghats and Himalaya, while some of the topographic highs like Aravalli show positive gravity anomaly. The Indian Ocean Geoid Low varies from -82 m over Dharwar Craton to -98 m over the Southern Granulite Terrain and finally reaches a significant low of -106 m in the Indian Ocean. Flexural isostatic compensation with variable Effective Elastic Thickness (EET) ~10 km to 50 km prevails over the stable continental region. The lithospheric thickness varies from 80 km along the coastal region to 120-130 km beneath the Saurashtra Plateau, the Southern Granulite Terrain, and the Eastern Indian Shield, and reaches to more than 200 km under the Himalayan orogenic belt in the north. From Dharwar Craton to Bundelkhand Craton in central India, the lithospheric thickness varies between 160 and 180 km.
Geochemistry, Geophysics, Geosystems, Vol. 19, 5, pp. 1464-1483.
Mantle
geophysics - seismic
Abstract: SubMachine is a collection of web-based tools for the interactive visualisation, analysis, and quantitative comparison of global-scale, volumetric (3-D) data sets of the subsurface, with supporting tools for interacting with other, complementary models and data sets as listed below. In short, SubMachine is a computational engine (Machine) to visualize models and datasets of the sub-surface (Sub).
Abstract: The Re-Os isotope system is well suited to constraining the timing of melt depletion of Archean mantle peridotites. In contrast, the variability inherent in post-Archean mantle Os isotope evolution leads to increasing uncertainty in Re-Os model ages. The Lu-Hf isotopic system has shown some potential for dating peridotite formation ages, providing valuable ages that are complementary to the Re-Os system. For post-Archean mantle peridotites, the key target in the Lu-Hf isotopic work is clinopyroxene (Cpx), because of its high Lu and Hf concentrations and the typical absence of garnet in these rocks. However, orthopyroxene (Opx) can contrain 20% or more of the Hf budget of spinel peridotites and somethimes over 40% of the Lu budget, with Lu/Hf ratios 3-4 times those of Cpx. Thus, Opx Lu-Hf isotopic compositions cannot be ignored or simply calculated, as the equilibrium temperatures of mantle peridotites prior to eruption could be lower or higher than the Hf closure temperature (Tc(Hf)~900ºC). Here we explore Lu-Hf partitioning in spinel peridotite xenoliths from the Cameroon Volcanic Line in additin to WR Re-Os analyses. The Hf isotopic composition of Opx in these rocks is equal to or higher than that of Cpx, consistent with some samples having equilibrium temperatures close to Tc(Hf). Combining Cpx and Opx, the constructed WR Lu-Hf isochron yields an age of 2.01±0.36 Ga (2?; MSWD = 11.4; ?Hfi = -0.8±19.2), which is in accordance with the oldest of the variable Re-Os model ages. The continental sector of the Cameroon Line runs close to the edge of the Congo craton. The Hf-Os data indicate that the lithosphere underpinning this region formed in the Paleoproterozoic (~2Ga) most likely during the Paleoproterzoic assembly between the Congo and West African Cratons. We emphasize that Opx and Cpx should be combined together to construct the WR isochron in order to obtain the precise age and initial Hf isotope compositions of post-Archean spinel peridotites.
Geochimica et Cosmochimica Acta, in press available. 13p.
Africa, Cameroon
peridotite
Abstract: Highly depleted Archean peridotites have proven very amenable to Re-Os model age dating. In contrast, due to the increasing heterogeneity of mantle Os isotope compositions with time, the Re-Os system has not been as effective in dating post-Archean peridotites. The timing of depletion and accretion of post-Archean lithospheric mantle around cratons is important to understand within the context of the evolution of the continents. In an attempt to precisely date post-Archean peridotite xenoliths, we present a study of the petrology, mineralogy and geochemistry, including whole-rock Re-Os isotopes, highly siderophile elements and clinopyroxene-orthopyroxene Sr-Nd-Hf isotopes of peridotite xenoliths from Lake Nyos in the Cameroon Volcanic Line (CVL). Eight Nyos peridotite xenoliths, all fresh spinel lherzolites, are characterized by low to moderate olivine Fo contents (88.9-91.2) and low spinel Cr# (8.4-19.3), together with moderate to high whole-rock Al2O3 contents (2.0-3.7%). These chemical characteristics indicate that they are mantle residues of a few percent to <20% partial melting. However, trace element patterns of both clinopyroxene and orthopyroxene are not a pristine reflection of melt depletion but instead show various extents of evidence of metasomatic enrichment. Some of the samples contain orthopyroxene with 143Nd/144Nd lower than its coexisting clinopyroxene, which is best explained by recent short-timescale alteration, most likely by infiltration of the host basalt. Because of these metasomatic effects, the Sr-Nd isotope systematics in pyroxenes cannot sufficiently reflect melt depletion signatures. Unlike Sr-Nd isotopes, the Lu-Hf isotope system is less sensitive to recent metasomatic overprinting. Given that orthopyroxene hosts up to 33% of the Lu and 14% of the Hf in the whole rock budget of these rocks and has 176Hf/177Hf similar to, or higher than, coexisting clinopyroxene, it is necessary to reconstruct a whole-rock Lu-Hf isochron in order to constrain the melt depletion age of peridotites. The reconstructed Nyos Lu-Hf isochron from ortho- and clinopyroxenes gives an age of 2.01?±?0.18?Ga (1?), and when olivine and spinel are considered, is 1.82?±?0.14?Ga (1?). Both ages are identical within error, and they are within error of the alumina-187Os/188Os pseudo-isochron ages (1.2-2.4?Ga) produced on the peridotites from Lake Nyos, consistent with their oldest rhenium depletion Os model ages (2.0?Ga). We conclude that the Nyos peridotites, and the lithospheric mantle that they represent, were formed at ?2.0?Ga, indicating that the reconstructed whole-rock Lu-Hf isotope system can be a powerful radiometric dating tool that is complementary to and in some instances, more precise than the Re-Os isotope system in dating well-preserved post-Archean peridotites. The recognition of ?2.0?Ga subcontinental lithospheric mantle (SCLM) in the Nyos area suggests that the Nyos region was assembled as a Paleoproterozoic block, or that it represents fragments of the SCLM from the nearby Paleoproterozoic domain juxtaposed through collisional emplacement during the Pan African Orogeny. With regards to the origin of the CVL, our data reveal that the Hf isotopic compositions of the Nyos peridotites are too radiogenic to be the main source of the CVL basalts.
Geochimica et Cosmochimica Acta, Vol. 278, pp. 177-198.
Africa, Cameroon
peridotites
Abstract: Highly depleted Archean peridotites have proven very amenable to Re-Os model age dating. In contrast, due to the increasing heterogeneity of mantle Os isotope compositions with time, the Re-Os system has not been as effective in dating post-Archean peridotites. The timing of depletion and accretion of post-Archean lithospheric mantle around cratons is important to understand within the context of the evolution of the continents. In an attempt to precisely date post-Archean peridotite xenoliths, we present a study of the petrology, mineralogy and geochemistry, including whole-rock Re-Os isotopes, highly siderophile elements and clinopyroxene-orthopyroxene Sr-Nd-Hf isotopes of peridotite xenoliths from Lake Nyos in the Cameroon Volcanic Line (CVL). Eight Nyos peridotite xenoliths, all fresh spinel lherzolites, are characterized by low to moderate olivine Fo contents (88.9-91.2) and low spinel Cr# (8.4-19.3), together with moderate to high whole-rock Al2O3 contents (2.0-3.7%). These chemical characteristics indicate that they are mantle residues of a few percent to <20% partial melting. However, trace element patterns of both clinopyroxene and orthopyroxene are not a pristine reflection of melt depletion but instead show various extents of evidence of metasomatic enrichment. Some of the samples contain orthopyroxene with 143Nd/144Nd lower than its coexisting clinopyroxene, which is best explained by recent short-timescale alteration, most likely by infiltration of the host basalt. Because of these metasomatic effects, the Sr-Nd isotope systematics in pyroxenes cannot sufficiently reflect melt depletion signatures. Unlike Sr-Nd isotopes, the Lu-Hf isotope system is less sensitive to recent metasomatic overprinting. Given that orthopyroxene hosts up to 33% of the Lu and 14% of the Hf in the whole rock budget of these rocks and has 176Hf/177Hf similar to, or higher than, coexisting clinopyroxene, it is necessary to reconstruct a whole-rock Lu-Hf isochron in order to constrain the melt depletion age of peridotites. The reconstructed Nyos Lu-Hf isochron from ortho- and clinopyroxenes gives an age of 2.01?±?0.18?Ga (1?), and when olivine and spinel are considered, is 1.82?±?0.14?Ga (1?). Both ages are identical within error, and they are within error of the alumina-187Os/188Os pseudo-isochron ages (1.2-2.4?Ga) produced on the peridotites from Lake Nyos, consistent with their oldest rhenium depletion Os model ages (2.0?Ga). We conclude that the Nyos peridotites, and the lithospheric mantle that they represent, were formed at ?2.0?Ga, indicating that the reconstructed whole-rock Lu-Hf isotope system can be a powerful radiometric dating tool that is complementary to and in some instances, more precise than the Re-Os isotope system in dating well-preserved post-Archean peridotites. The recognition of ?2.0?Ga subcontinental lithospheric mantle (SCLM) in the Nyos area suggests that the Nyos region was assembled as a Paleoproterozoic block, or that it represents fragments of the SCLM from the nearby Paleoproterozoic domain juxtaposed through collisional emplacement during the Pan African Orogeny. With regards to the origin of the CVL, our data reveal that the Hf isotopic compositions of the Nyos peridotites are too radiogenic to be the main source of the CVL basalts.
Earth and Planetary Science Letters, Vol. 494, 1, pp. 92-98.
Mantle
water
Abstract: In this study, we present new experimental constraints on the phase stability and thermal equation of state of an important hydrous phase, ?-AlOOH, using synchrotron X-ray diffraction up to 142 GPa and 2500 K. Our experimental results have shown that ?-AlOOH remains stable at the whole mantle pressure-temperature conditions above the D? layer yet will decompose at the core-mantle boundary because of a dramatic increase in temperature from the silicate mantle to the metallic outer core. At the bottom transition zone and top lower mantle, the formation of ?-AlOOH by the decomposition of phase Egg is associated with a ?2.1-2.5% increase in density (?) and a ?19.7-20.4% increase in bulk sound velocity (V?). The increase in ? across the phase Egg to ?-AlOOH phase transition can facilitate the subduction of ?-AlOOH to the lower mantle. Compared to major lower-mantle phases, ?-AlOOH has the lowest ? but greatest V?, leading to an anomalous low ? /V? ratio which can help to identify the potential presence of ?-AlOOH in the region. More importantly, water released from the breakdown of ?-AlOOH at the core-mantle boundary could lower the solidus of the pyrolitic mantle to cause partial melting and/or react with Fe in the region to form the low-velocity FeO2Hx phase. The presence of partial melting and/or the accumulation of FeO2Hx phase at the CMB could be the cause for the ultra-low velocity zone. ?-AlOOH is thus an important phase to transport water to the lowermost mantle and helps to understand the origin of the ultra-low velocity zone.
South African Institute of Mining and Metallurgy, Vol. 116, 8, pp. 709-714.
Africa, Botswana
deposit - Karowe
Abstract: Historically, the recovery of large diamonds in conventional treatment plant flow sheets has been associated with dense media separation (DMS). This is attributed mainly to DMS's highly efficient and proven track record in the concentration and separation of ores with variable solids densities. In most instances, DMS has been utilized as a pre-concentration step ahead of any recovery plant, due to its ability and versatility in reducing feed within a specific size range to manageable volumes for downstream X-ray processing and subsequent diamond recovery. The benefit of using carbon-signature-based detection equipment for retrieving large stones upfront in the flow sheet not only equates to earlier recovery of diamonds from the system, but also lessens the exposure of diamond-bearing ore to additional materials handling, pumping, and/or crushing, which has been known to damage or even break diamonds and decrease revenue.
Geophysical Research Letters, Vol. 46, 20, pp. 11065-110670.
Mantle
geothermometry
Abstract: Earth's magnetic field is produced by a dynamo in the core that requires motion of the fluid Fe alloy. Both thermal convection, arising from the transport of heat in excess of conducted heat, and compositional convection, arising from light element exsolution at the freezing inner core boundary, are suggested as energy sources. The contribution of thermal convection (possibly ranging from nothing to significant) depends on thermal conductivity of the outer core. Our experimental measurements of electrical resistivity of solid and liquid Fe at high pressures show that resistivity is constant along the pressure?dependent melting boundary of Fe. Using our derived thermal conductivity value at the inner core (freezing) boundary, we calculate the heat conducted in the liquid outer core and find that thermal convection is needed to carry additional heat through the outer core to match the heat extracted through the core?mantle boundary.
Diamonds & Related Materials, Vol. 101, 107640, 13p. Pdf
Russia
Popigai
Abstract: The special features of impact diamonds are the orientation of the nanosized grains relative to each other, the presence of hexagonal diamond (lonsdaleite, L) in a large part of the samples and the increased wear resistance. Using Raman spectroscopy and XRD, two groups of translucent samples of Popigai impact diamonds (PIDs) were selected: with and without lonsdaleite and the effect of lonsdaleite on the optical properties of the samples was studied. In all L-containing PIDs there is a strong absorption band of about 1230 cm-1 in the one-phonon region, in the mid-IR. The absorption edge is blurred and described by the Urbach rule. The estimated value of Eg ~4 eV for L is consistent with the first principles calculations. Impurity nitrogen is found only in L-free PIDs: There are signals from nitrogen-vacancy complexes in the photoluminescence (PL) spectra. Variations in the number of nitrogen atoms (N = 1 to 4) in the structure of these centers indicate significant variations in the parameters of PID annealing. L-containing PIDs are characterized by large strains in the lattice and, as a consequence, there are problems with the defect diffusion. The narrow lines in PL spectra, uncommon for diamond, can be the result of several orders of magnitude higher concentrations of impurities in PIDs formed during the solid-phase transition. The broadened peaks of 180, 278 and 383 K are distinguishable in the curves of thermostimulated luminescence (TSL) for L-free PIDs, but in the presence of L the TSL glow becomes continuous as in natural IaA-type diamonds with platelets. In general, lonsdaleite deteriorates the optical properties of impact diamonds and makes it difficult to create certain types of impurity-vacancy complexes for different applications.
PluS One, Vol. 13, 8, doi:10.1371/journal.pone.0200351
Asia, Thailand
garnets
Abstract: Garnets from disparate geographical environments and origins such as oxidized soils and river sediments in Thailand host intricate systems of microsized tunnels that significantly decrease the quality and value of the garnets as gems. The origin of such tunneling has previously been attributed to abiotic processes. Here we present physical and chemical remains of endolithic microorganisms within the tunnels and discuss a probable biological origin of the tunnels. Extensive investigations with synchrotron-radiation X-ray tomographic microscopy (SRXTM) reveal morphological indications of biogenicity that further support a euendolithic interpretation. We suggest that the production of the tunnels was initiated by a combination of abiotic and biological processes, and that at later stages biological processes came to dominate. In environments such as river sediments and oxidized soils garnets are among the few remaining sources of bio-available Fe2+, thus it is likely that microbially mediated boring of the garnets has trophic reasons. Whatever the reason for garnet boring, the tunnel system represents a new endolithic habitat in a hard silicate mineral otherwise known to be resistant to abrasion and chemical attack.
Abstract: Geometallurgy aims to develop and deploy predictive spatial models based on tangible and quantitative resource characteristics that are used to optimize the efficiency of minerals beneficiation and extractive metallurgy operations. Whilst most current applications of geometallurgy are focused on the major commodity to be recovered from a mineral deposit, this contribution delineates the opportunity to use a geometallurgical approach to provide an early assessment of the economic potential of by-product recovery from an ongoing mining operation. As a case study for this methodology possible REE-recovery as a by-product of Nb-production at the Catalão I carbonatite complex, the Chapadão mine is used. Catalão I is part of the Alto Paranaíba Igneous Province in the Goias Province of Brazil. Nowadays, niobium is produced in the complex as a by-product of the Chapadão phosphates mine. This production is performed on the Tailings plant, the focus of this study. Rare earth elements, albeit present in significant concentrations, are currently not recovered as by-products. Nine samples from different stages of the Nb beneficiation process in the Tailings plant were taken and characterized by Mineral Liberation Analyzer, X-ray powder diffraction, and bulk rock chemistry. The recovery of rare earth elements in each of the tailing streams was quantified by mass balance. The quantitative mineralogical and microstructural data are used to identify the most suitable approach to recover REE as a by-product-without placing limitations on niobium production. Monazite, the most common rare earth mineral identified in the feed, occurs as Ce-rich and La-rich varieties that can be easily distinguished by SEM-based image analysis. Quartz, FeTi-oxides and several phosphate minerals are the main gangue minerals. The highest rare earth oxide content concentrations (1.75 wt.% TREO) and the greatest potential for REE processing are reported for the final flotation tailings stream. To place tentative economic constraints on REE recovery from the tailings material, an analogy to the Browns Range deposit in Australia is drawn. Its technical flow sheet was used to estimate the cost for a hypothetical REE-production at Chapadão. Parameters derived from SEM-based image analysis were used to model possible monazite recovery and concentrate grades. This exercise illustrates that a marketable REE concentrate could be obtained at Chapadão if the process recovers at least 53 % of the particles with no less than 60% of monazite on their surface. Applying CAPEX and OPEX values similar to that of Browns Range suggest that such an operation would be profitable at current REE prices.
Oliveira, E.P., Talavera, C., Windley, B.F., Zhao, L., Semprich, J.J., McNaughton, N.J., Amaral, W.S., Sombini, G., Navarro, M., Silva, D.
Mesoarchean ( 2820 Ma )high pressure mafic granulite at Uaus, Sao Francisco craton, Brazil, and its potential significance for the assembly of Archean supercraton.
Society for Mining, Metallurgy and Exploration (SME) stock exchange - it could happen... comments on letter from previous column on concerns as to status .
Mining Engineering, Vol. 48, No. 7, July p. 10, 17
Riding the Wilson cycle: the theory of plate tectonics continues to evolve. Now new research is answering some of the most exciting lingering questions ....
45th. Annual Yellowknife Geoscience Forum, p. 65 abstract
Canada, Northwest Territories
deposit - Giraffe
Abstract: Several Lac de Gras kimberlite pipes host thick accumulations of stratified post-eruptive lacustrine sediment and peat. Given the range of Lac de Gras kimberlite emplacement ages, these fills - though rare - provide a unique sedimentary archive of paleoenvironments during the sustained Early Cenozoic “greenhouse” interval, in a high-latitude region otherwise devoid of Phanerozoic sediment cover. Extensive exploration drilling has provided a valuable window into this unique sedimentary record, which would have otherwise remained covered by Quaternary glacial deposits. Our focus to date has been multidisciplinary study of the Giraffe pipe sediment fill: an ~80 m-thick sequence of post-eruptive lacustrine silt overlain by peat, which paints a remarkable picture of a humid-temperate Middle Eocene forest ecosystem on the Canadian Shield. Post-eruptive chronology is provided by interbedded distal tephra horizons, likely sourced from Alaska, that have been dated by glass fission-track and zircon U-Pb techniques. Paleoclimate proxies derived from pollen, wood cellulose oxygen isotopes, and biomarkers converge on reconstructed mean annual temperatures >17 °C warmer than present, with mean winter temperatures above freezing, and mean annual precipitation ~4x present. Two independent reconstructions of CO2 from well preserved conifer foliage suggest that this warming occurred under relatively modest atmospheric CO2 concentrations of 430-630 ppm. These findings provide direct field-based evidence for dramatic past arctic warming at CO2 concentrations that were well within the range of projections under “business-as-usual” emissions scenarios, underscoring the capacity for exceptional polar amplification of climate change under modest CO2 concentrations once both fast and slow feedbacks processes become expressed. Our studies at Giraffe pipe also highlight the scientific value of archived exploration drill core in the Lac de Gras kimberlite field, particularly with respect to pipes that are unremarkable for the purpose of diamond exploration.
Silversmit, G., Vekemans, B., Appel, K., Schmitz, S., Schoonjans, T., Brenker, F.E., Kaminsky, F., Vincze, L.
Three dimensional Fe speciation of an inclusion cloud within an ultradeep diamond by confocal u-x-ray absortion near edge structure: evidence for late stage
Abstract: The paper discusses questions related to the generation of increasing crustal horizontal compressive stresses compared to the idea of the standard gravitational state at the elastic stage or even from the prevalence of horizontal compression over vertical stress equal to the lithostatic pressure. We consider a variant of superfluous horizontal compression related to internal lithospheric processes occurrin in the crust of orogens, shields, and plates. The vertical ascending movements caused by these motions at the sole of the crust or the lithosphere pertain to these and the concomitant exogenic processes giving rise to denudation and, in particular, to erosion of the surfaces of forming rises. The residual stresses of the gravitational stressed state at the upper crust of the Kola Peninsula have been estimated for the first time. These calculations are based on the volume of sediments that have been deposited in Arctic seas beginning from the Mesozoic. The data speak to the possible level of residual horizontal compressive stresses up to 90 MPa in near-surface crustal units. This estimate is consistent with the results of in situ measurements that have been carried out at the Mining Institute of the Kola Science Center, Russian Academy of Sciences (RAS), for over 40 years. It is possible to forecast the horizontal stress gradient based on depth using our concept on the genesis of horizontal overpressure, and this forecasting is important for studying the formation of endogenic deposits.
Ore and Energy Resource Geology, Vol. 7, 100013 12p. Pdf
Russia
mantle fluids
Abstract: P-T- Oxygen fugacity (fO2) conditions and fluid compositions were estimated for the formation conditions of pyrope garnet inclusions in diamonds and xenocrysts from diamond-bearing and diamond-free kimberlites using their total chemical analyses and single oxythermobarometry. Our data indicate that optimal conditions for diamond growth and preservation occur in the presumed water-rich mantle fluids containing the lowest abundance of free atomic carbon. The majority of the calculated C-H-O fluid compositions for diamond formation in peridotite xenoliths from high diamond grade kimberlites correspond to a high hydrogen and low carbon and oxygen atomic fluid percents, while those from the majority of peridotite xenoliths in the low grade diamond kimberlites corresponds to the low hydrogen, high carbon and oxygen atomic percent fluids. This new approach defines the conditions of diamond formation for kimberlitic deposits. It better characterizes diamond grades in kimberlites in comparison to the previous empirical mineralogical Ca-Cr methods and can be used as a more precise mineralogical-petrological method for prospecting for kimberlitic diamond deposits.
Evaluation of the Diamond Content of Deep Seated Rocks (kimberlites) Based on the Calculation of Free Energy of the Diamond Dissolution Iron Containing Melt.
Doklady Academy of Sciences AKAD. NAUK SSSR., Vol. 271, No. 2, PP. 443-446.
Abstract: There are four main types of natural diamonds and related formation processes. The first type comprises the interstellar nanodiamond particles. The second group includes crustal nano- and micron-scale diamonds associated with coals, sediments and metamorphic rocks. The third one includes nanodiamonds and microndiamonds associated with secondary alteration and replacing of mafic and ultramafic rocks. The fourth one includes macro-, micron- and nano-sized mantle diamonds which are associated with kimberlites, mantle peridotites and eclogites. Each diamond type has its specific characteristics. Nano-sized diamond particles of lowest nanometers in size crystallize from abiotic organic matter at lower pressures and temperatures in space during the stages of protoplanetary disk formation. Nano-sized diamonds are formed from organic matter at P-T exceeding conditions of catagenesis stage of lithogenesis. Micron-sized diamonds are formed from fluids at P-T exceeding supercritical water stability. Macrosized diamonds are formed from metal-carbon and silicate-carbonate melts and fluids at P-T exceeding 1150 °C and 4.5 GPa. Nitrogen and hydrocarbons play an important role in diamond formation. Their role in the formation processes increases from macro-sized to nano-sized diamond particles. Introduction of nitrogen atoms into the diamond structure leads to the stabilization of micron- and nano-sized diamonds in the field of graphite stability.
Abstract: Samples of gilsonite from Adzharia, anthraxolite and graphite of coal from Taimyr, shungite from Karelia, and anthracite from Donbass are studied using Raman spectroscopy. Peaks at 1600 cm?1, indicating the presence of nanographite, are recorded in all samples. The anthracite sample from Donbass, 1330 cm?1, corresponds to the sp3-line of carbon hybridization conforming to a nanodiamond. It is concluded that in nature diamonds can be formed at late stages of lithogenesis (catagensis, metagenesis), and for coals, it can occur at the zeolite stage of regional metamorphism of rocks, before the green schist stage.
Abstract: The processes of formation of some diamond types still raise contentious issues, mainly on the origin of the largest diamond crystals recovered from kimberlites. These diamonds constitute less than 2% of worldwide resources and correspond to rare type IIa. They possess some peculiar features: (i) silicate and oxide inclusions are extremely rare, (ii) their ?13C ranges from ?17 to ?21‰. The detailed estimation of the Premier pressure-temperature-oxygen fugacity parameters and the physic-chemical modeling of diamond growth-dissolution processes suggest that extra-large diamonds have multiple origins. Their formation may occur from lower mantle to crustal depths. Their main building-up takes place from fluids in the pegmatitic veins solidified along the contacts of kimberlite magma at a crustal depth. The model explains the main features of the largest kimberlitic diamonds, i.e. their great sizes, light ?13C signatures, low nitrogen contents, high degree of resorption, absence of mantle-derived mineral inclusions and their occurrence in the form of rare isolated crystals in the host kimberlite.
Doklady Earth Sciences, Vol. 482, 2, pp. 1317-1319.
Mantle
geothermometry
Abstract: It is known that the ?-? parameters of diamond-bearing kimberlite xenoliths correspond to subductive paleogeotherms lying between the 36 and 41 mW/m2 conductive models. There are some studies showing the correlation of diamond ability with oxygen fugacity and the fluid composition of mantle xenoliths.The most diamondiferous samples correspond to the water compositions of the calculated O-H-C fluid with a minimum atomic carbon content in it. From the calculations it follows that the fluid carbon atomic content increases with a temperature increase and with the pressure decreasing. The most minor C contents have the 35 mW/m2 conductive model in comparison with the 40 and 45 mW/m2 models. As a result, it is possible to conclude that the low temperature fields (less than 1100°C) of the “cold” geotherms have the highest diamondiferous ability.
Simandl, G.J., Paradis, S., Stone, R.S., Fajber, R., Kressall, R.D., Grattan, K., Crozier, J., Simandl, L.J.
Applicablity of handheld X-ray fluroescence spectrometry in the exploration and development of carbonatite related niobium deposits: a case study of the Aley carbonatite, British Columbia, Canada.
Geochemistry: Exploration, Environment, Analysis, Vol. 14, 3, pp. 211-221.
Symposium on critical and strategic materials, British Columbia Geological Survey Paper 2015-3, held Nov. 13-14, pp. 241-244.
Canada, British Columbia
Carbonatite
Abstract: Carbonatites host economic deposits of niobium (Nb), rare earth elements (REE), phosphate, baddeleyite (natural zirconia), vermiculite, and fl uorspar, and historically, supplied copper, uranium, carbonate (for cement industries) and sodalite (Pell, 1994 and Simandl, this volume). The Upper Fir carbonatite is in southeastern British Columbia, approximately 200 km north of Kamloops (Fig. 1). It is one ofmany known carbonatite occurrences in the British Columbia alkaline province, which follows the Rocky Mountain Trench and extends from the southeastern tip of British Columbia to its northern boundaries with the Yukon and Northwest Territories (Pell, 1994). The Upper Fir is a strongly deformed carbonatite with an indicated mineral resource of 48.4 million tonnes at 197 ppm of Ta2O5 and 1,610 ppm of Nb2O5, and an inferred resource of 5.4 million tonnes at 191 ppm of Ta2O5 and 1760 ppm of Nb2O5 (Kulla et al. 2013). The Nb, Ta, and vermiculite mineralization is described by Simandl et al. (2002, 2010), Chong, et al, (2012), and Chudy (2014). In this document we present the results of an orientation survey designed to determine the biogechemical signature of a typical carbonatite in the Canadian Cordillera. This survey suggests that needles and twigs of White Spruce (Picea glauca) and Subalpine Fir (Abies lasio carpa) are suitable sampling media to explore for carbonatites and carbonatite-related rare earth elements (REE), niobium (Nb), and tantalum (Ta) deposits.
Symposium on critical and strategic materials, British Columbia Geological Survey Paper 2015-3, held Nov. 13-14, pp. 13-22.
Global
Niobium, tantalum
Abstract: Until 2014, niobium (Nb) and tantalum (Ta) were on the critical metals list of the European Union (European Commission, 2011; 2014). Both Ta and Nb have high levels of supply chain risk and even temporary disruptions in supply could be difficult to cope with. The Ta market is subject to infl ux of ‘conflict’ columbite-tantalite concentrate, or ’Coltan,’ into the supply chain, displacing production in Australia and Canada. The growing consumer appetite for goods made of ethically sourced or ‘confl ict-free’ minerals and metals has put pressure on manufacturers of components for consumer electronics, such as smart phones, laptop computers, computer hard drives, digital cameras, GPS navigation systems, and airbag triggers to stop using Ta from ‘confl ict’ areas. Other uses of Ta include medical implants, super alloys used in jet turbine and rocket nozzle production, corrosion prevention in chemical and nuclear plants, as a sputtering target, and in optical lenses (Tantalum-Niobium International Study Center, 2015a, b). These applications make Ta economically and strategically important to industrialised countries (European Commission, 2011, 2014; Brown et al., 2012; Papp, 2012). Niobium (Nb) is primarily used in high-strength low-alloy (HSLA) steel used extensively in the oil and gas and automotive industries. Niobium is also a major component in vacuum-grade alloys used in rocket components and other aeronautic applications (Tantalum-Niobium International Study Center, 2015a, c). Demand for Nb is increasing due to greater use of Nb in steel making in China, India, and Russia (Roskill, 2013b; Mackay and Simandl, 2014). Because most primary Nb production is restricted to a single country (Brazil), security of supply is considered at risk (European Commission, 2014). New sources of supply may be developed to diversify geographic location of supply for strategic reasons (Mackay and Simandl, 2014). Herein we summarize the geology, market, and supply chains of Niobium and Tantalum metals.
Symposium on critical and strategic materials, British Columbia Geological Survey Paper 2015-3, held Nov. 13-14, pp. 211-218.
Technology
Rare earths
Abstract: Quantitative Evaluation of Materials by Scanning electron microscopy (QEMSCAN®) was used to assess carbonatite indicator minerals in fl uvial sediments from the drainage area of the Aley carbonatite, in north-central British Columbia. QEMSCAN® is a viable method for rapid detection and characterization of carbonatite indicator minerals with minimal processing other than dry sieving. Stream sediments from directly above, and up to 11 km downstream, of the carbonatite deposit were selected for this indicator mineral study. The geology of the Aley carbonatite is described by Mäder (1986), Kressal et al. (2010), McLeish (2013), Mackay and Simandl (2014), and Chakhmouradian et al. (2015). Traditional indicator mineral exploration methods use the 0.25-2.0 mm size fraction of unconsolidated sediments (Averill, 2001, 2014; McCurdy, 2006, 2009; McClenaghan, 2011, 2014). Indicator minerals are detectable by QEMSCAN® at particle sizes smaller than those used for hand picking (<0.25 mm). Pre-concentration (typically by shaker table) is used before heavy liquid separation, isodynamic magnetic separation, optical identifi cation using a binocular microscope, and hand picking (McClenaghan, 2011). Following additional sieving, the 0.5-1 and 1-2 mm fractions are hand picked for indicator minerals while the 0.25-0.5 mm fraction is subjected to paramagnetic separation before hand picking (Averill, 2001; McClenaghan, 2011). Hand picking indicator minerals focuses on monomineralic grains, and composite grains may be lost during processing. Composite grains are diffi cult and time consuming to hand pick and characterize using optical and Scanning Electron Microscopy (SEM) methods. A single grain mount can take 6-12 hours to chemically analyse (Layton- Matthews et al., 2014). Detailed sample analysis using the QEMSCAN® Particle Mineral Analysis routine allows for 5-6 samples to be analyzed per day. When only mineral identifi cation and mineral concentrations and counts are required, the use of a Bulk Mineral Analysis routine reduces the analysis time from ~4 hours to ~30 minutes per sample.
Symposium on critical and strategic materials, British Columbia Geological Survey Paper 2015-3, held Nov. 13-14, pp. 251-264.
Technology
Rare earths
Abstract: Fluorite (CaF2) belongs to the isometric system, with a cubic, face-centred lattice. Fluorite commonly forms cubes or octahedrons, less commonly dodecahedrons and, rarely, tetrahexahedrons, trapezohedrons, trisoctahedrons, hexoctahedrons, and botyroidal forms. Fluorite is transparent to translucent, and has vitreous luster. It occurs in a variety of colours including purple, green, blue, or yellow, however it can also be colourless, and can exhibit colour zoning, (Staebler et al., 2006). Fluorite from many localities is fl uorescent (Verbeek, 2006). Fluorite density varies from 3.0-3.6 g/cm3, depending to a large extent on inclusions and impurities in the crystal lattice (Staebler et al., 2006), and its hardness is 4 on Mohs scale (Berry et al., 1983). Many single fl uorite crystals display sector zoning, refl ecting preferential substitution and incorporation of trace elements along successive crystal surfaces (Bosce and Rakovan, 2001). The Ca2+ ion in the fl uorite crystal structure can be substituted by Li+, Na+, K+, Mg2+, Mn2+, Fe2+,3+, Zn2+, Sr2+, Y3+, Zr4+, Ba2+, lanthanides ions, Pb2+, Th4+, and U4+ ions (Bailey et al., 1974; Bill and Calas, 1978, Gagnon et al., 2003; Schwinn and Markl, 2005; Xu et al., 2012; Deng et al., 2014). Concentrations of these impurities do not exceed 1% (Deer, 1965) except in yttrofl uorite (Ca,Y)F2-2.33 and cerfl uorite (Ca,Ce)F2-2.33 (Sverdrup, 1968). Fluorite occurs in a variety of rocks, as an accessory and as a gangue mineral in many metalliferous deposits and, in exceptional cases, as the main ore constituent of economic deposits (Simandl, 2009). Good examples of fl uorite mines are Las Cuevas, Encantada-Buenavista (Mexico); St. Lawrence pluton-related veins and the Rock Candy Mine (Canada); El Hamman veins (Morocco) and LeBurc Montroc -Le Moulinal and Trebas deposits (France) as documented by Ruiz et al. (1980), Grogan and Montgomery (1975), González-Partida et al. (2003), Munoz et al. (2005), and Fulton III and Miller (2006). Fluorite also commonly occurs adjacent to or within carbonatites and alkaline complexes (Kogut et al., 1998; Hagni,1999; Alvin et al., 2004; Xu et al., 2004; Salvi and Williams-Jones, 2006); Mississippi Valley-type (MVT) Pb- Zn-F-Ba deposits; F-Ba-(Pb-Zn) veins (Grogan and Bradbury, 1967 and 1968; Baxter et al., 1973; Kesler et al., 1989; Cardellach et al., 2002; Levresse et al., 2006); hydrothermal Fe (±Au, ±Cu) and rare earth element (REE) deposits (Borrok et al., 1998; Andrade et al., 1999; Fourie, 2000); precious metal concentrations (Hill et al., 2000); fl uorite/metal-bearing skarns (Lu et al., 2003); Sn-polymetallic greissen-type deposits (Bettencourt et al., 2005); and zeolitic rocks and uranium deposits (Sheppard and Mumpton, 1984; Cunningham et al., 1998; Min et al., 2005). Ore deposit studies that document the trace element distribution in fl uorite are provided by Möller et al. (1976), Bau et al. (2003), Gagnon et al. (2003), Schwinn and Markl (2005), and Deng et al. (2014). The benchmark paper by Möller et al. (1976) identifi ed variations in the chemical composition of fl uorites according their origin (sedimentary, hydrothermal, or pegmatitic). Recently, Makin et al. (2014) compiled trace-element compositions of fl uorite from MVT, fl uorite-barite veins, peralkaline-related, and carbonatite-related deposits. They showed that fl uorite from MVT and carbonatite deposits can be distinguished through trace element concentrations, and that the REE concentration of fl uorite from veins is largely independent of the composition of the host rock. Based on the physical and chemical properties of fl uorite, its association with a variety of deposit types, and previous studies, it is possible that fl uorite can be used as a proximal indicator mineral to explore for a variety of deposit types. Unfortunately, the compilation by Makin et al. (2014) contained chemical analyses performed at different laboratories using different analytical techniques (including laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS), electron microprobe, neutron activation, and ICP-MS), and precision and accuracy varied accordingly. As an orientation survey, herein we present data from fi ve deposits, with two samples from the Rock Candy deposit (British Columbia), and one sample from each of Kootenay Florence (British Columbia), Eaglet (British Columbia), Eldor (Quebec), and Hastie quarry (Illinois) deposits (Table 1). The main objectives of this study are to: 1) assess variations in chemical composition of fl uorite in the samples and deposit types; 2) evaluate relations between analyses made using laser ablation-inductively coupled plasma mass spectrometry on individual grains [LA-ICP-MS(IG)], and those made using laser ablation-inductively coupled plasma mass spectrometry on fused beads [LA-ICP-MS(FB)] and X-ray fl uorescence (XRF); 3) test the use of stoichiometric Ca content as an internal fl uorite standard, such has been done by Gagnon et al. (2003) and Schwinn and Markl, (2005); 4) select the elements that are commonly present in concentrations above the lower limit of detection of LA-ICP-MS and available for constructing discrimination diagrams; 5) consider if our results agree with the preliminary discrimination diagrams of Makin et al. (2014).
Symposium on critical and strategic materials, British Columbia Geological Survey Paper 2015-3, held Nov. 13-14, pp. 31-38.
Global
Carbonatite
Abstract: Mineralized carbonatite systems are multi-commodity, highly sought after, but poorly understood exploration targets (Mariano, 1989a, b; Pell, 1996; Birkett and Simandl, 1999). They are the main sources of niobium and rare earth elements (REE), which are considered critical metals for some key economic sectors (European Commission, 2014), and have become popular exploration targets for junior mining companies worldwide. Carbonatites also contribute to our understanding of the Earth’s mantle (e.g., Bell and Tilton, 2001, 2002). Herein, we discuss the defi nition and classifi cation of carbonatites; summarize information pertinent for carbonatite exploration such as tectonic setting, shape, geophysical signature, associated rocks, alteration, and temporal distribution; and highlight the multi-commodity aspect of carbonatiterelated exploration targets and mineral prospectivity. 2. Defi nition and classifi cation Carbonatites are defi ned by the International Union of Geological Sciences (IUGS) as igneous rocks containing more than 50% modal primary carbonates (Le Maitre, 2002). Depending on the predominant carbonate mineral, a carbonatite is referred to as a ‘calcite carbonatite’ (sövite), ‘dolomite carbonatite’ (beforsite) or ‘ankerite carbonatite’. If more than one carbonate mineral is present, the carbonates are named in order of increasing modal concentrations, for example a ‘calcite-dolomite carbonatite’ is composed predominately of dolomite. If non-essential minerals (e.g., biotite) are present, this can be refl ected in the name as ‘biotite-calcite carbonatite’. Where the modal classifi cation cannot be applied, the IUGS chemical classifi cation is used (Fig. 1). This classifi cation subdivides carbonatites into calciocarbonatites, magnesiocarbonatites, and ferrocarbonatites. For calciocarbonatites, the ratio of CaO/(CaO+MgO+FeO +Fe2O3+MnO) is greater than 0.8. The remaining carbonatites are subdivided (based on wt.% ratios) into magnesiocarbonatite [MgO > (FeO+Fe2O3+MnO)] and ferrocarbonatite [MgO < (FeO+Fe2O3+MnO)] (Woolley and Kempe, 1989; Le Maitre, 2002). If the SiO2 content of the rock exceeds 20%, the rock is referred to as silicocarbonatite. When the IUGS chemical classifi cation is used, care should be taken to ensure that magnetite and hematite-rich calciocarbonates or magnesiocarbonatites are not erroneously classifi ed as ferrocarbonatites (Gittins and Harmer, 1997). A refi nement to the IUGS chemical classifi cation based on molar proportions (Gittins and Harmer, 1997), introduced ‘ferrugineous’ carbonatites (Fig. 2). The boundary separating calciocarbonatites from magnesiocarbonatites and ‘ferrugineous’ carbonatites is set at 0.75, above which carbonatites contain more than 50% calcite on a molar basis. Although not universally accepted, Gittins and Harmer’s classifi cation is commonly used in studies of carbonatitehosted ore deposits. A mineralogical-genetic classifi cation of carbonatites was proposed by Mitchell (2005). His paper points to pitfalls of the IUGS classifi cation and subdivides carbonatites into ‘primary carbonatites’ and ‘carbothermal residua’. The introduction of the term ‘carbothermal residua’ is signifi cant as it alerts mantle specialists to fundamental processes involved in the formation of many carbonatite-related deposits, and reduces rifts between camps of ore deposit geologists, petrologists, and mantle specialists. From the exploration
Abstract: In response to rising demand of the rare earth elements (REE), recent exploration of the British Columbia alkaline province has identified the Wicheeda Carbonatite, which contains an estimated 11.3 million tons of light REE-enriched ore grading 1.95 wt.% TREO, to be the highest-grade prospect known in British Columbia. However, research of the deposit is restricted to one paper describing mineralization in carbonatite dikes adjacent to the main plug. This study describes the nature and origin of REEmineralization in the Wicheeda plug. The carbonatite was emplaced in metasedimentary limestone and argillaceous limestone belonging to the Kechika Group, which has been altered to potassic fenite immediately adjacent to the carbonatite and to sodic fenite at greater distances from it. The carbonatite comprises a ferroan dolomite core, which passes outwards gradationally into calcite carbonatite. Three texturally distinct varieties of dolomite have been recognized. Dolomite 1 constitutes most of the carbonatite; Dolomite 2 replaced Dolomite 1 near veins and vugs; Dolomite 3 occurs as a fracture and vug-lining phase with the REE mineralization. Stable carbon and oxygen isotopic ratios indicate that the calcite carbonatite is of mantle origin, that Dolomite 1 is of primary igneous origin, that Dolomite 2 is largely primary igneous with minor hydrothermal signature contamination, and that Dolomite 3 is of hydrothermal origin. Rare-metal mineralization in the deposit is, with the exception of pyrochlore, which occurs in the calcite carbonatite, restricted to veins and vugs in the dolomite carbonatite. There it occurs as hydrothermal veins and in vugs infilled by REE-fluorocarbonates, i.e., bastnäsite-(Ce), ancylite-(Ce), and monazite- (Ce) together with accessory pyrite, barite, molybdenite, and thorite. A model is proposed in which calcite carbonatite was the earliest magmatic phase to crystallize. The calcite carbonatite magma saturated with niobium relatively early, precipitating pyrochlore. The magma later evolved to a dolomite carbonatite composition which, upon cooling exsolved an aqueous carbonic fluid, which altered the Kechika metasediments to potassic fenite and mixed with formational waters further from the carbonatite to produce sodic fenite. This fluid mobilized the REE as chloride complexes into vugs and fractures in the dolomite carbonatite. Upon progressive fluid-rock interaction, the REE precipitated largely in response to cooling and pH. Hydrothermal concentration led to remarkable grade consistency, with virtually all of the dolomite carbonatite containing >1 wt.% TREO, making the Wicheeda Carbonatite a very attractive exploration target.
Journal of Geochemical Exploration, Vol. 165, pp. 159-173.
Canada, British Columbia
Geochemistry - carbonatites
Abstract: This orientation survey indicates that Quantitative Evaluation of Materials by Scanning electron microscopy (QEMSCAN®) is a viable alternative to traditional indicator mineral exploration approaches which involve complex processing followed by visual indicator mineral hand-picking with a binocular microscope. Representative polished smear sections of the 125-250 ?m fraction (dry sieved and otherwise unprocessed) and corresponding Mozley C800 table concentrates from the drainages of three carbonatites (Aley, Lonnie, and Wicheeda) in the British Columbia Alkaline Province of the Canadian Cordillera were studied. Polished smear sections (26 × 46 mm slide size) contained an average of 20,000 exposed particles. A single section can be analyzed in detail using the Particle Mineral Analysis routine in approximately 3.5-4.5 h. If only mineral identification and mineral concentrations are required, the Bulk Mineral Analysis routine reduces the analytical time to 30 min. The most useful carbonatite indicator minerals are niobates (pyrochlore and columbite), REE-fluorocarbonates, monazite, and apatite. Niobate minerals were identified in the 125-250 ?m fraction of stream sediment samples more than 11 km downstream from the Aley carbonatite (their source) without the need for pre-concentration. With minimal processing by Mozley C800, carbonatite indicator minerals were detected downstream of the Lonnie and Wicheeda carbonatites. The main advantages of QEMSCAN® over the traditional indicator mineral exploration techniques are its ability to: 1) analyze very small minerals, 2) quickly determine quantitative sediment composition and mineralogy by both weight percent and mineral count, 3) establish mineral size distribution within the analyzed size fraction, and 4) determine the proportions of monomineralic (liberated) grains to compound grains and statistically assess mineral associations in compound grains. One of the key advantages is that this method permits the use of indicator minerals based on their chemical properties. This is impossible to accomplish using visual identification.
in: Ferbey, T. Plouffe, A., Hickein, A.S. eds. Indicator minerals in tills and stream sediments of the Canadian Cordillera. Geological Association of Canada Special Paper,, Vol. 50, pp. 175-190.
Canada, British Columbia
carbonatite - Aley, Lonnie, Wicheeda
Abstract: This volume consists of a series of papers of importance to indicator minerals in the Canadian Cordillera. Topics include the glacial history of the Cordilleran Ice Sheet, drift prospecting methods, the evolution of survey sampling strategies, new analytical methods, and recent advances in applying indicators minerals to mineral exploration. This volume fills a notable knowledge gap on the use of indicator minerals in the Canadian Cordillera. We hope that the volume serves as a user guide, encouraging the wider application of indicator minerals by the exploration community.
Applied Earth Science ( Trans. Inst. Min. Metall B), 31p. Doi.org/10.1080/25726388.2018.1516935 31p. Open access
Global
carbonatite - review
Abstract: Most carbonatites were emplaced in continental extensional settings and range in age from Archean to recent. They commonly coexist with alkaline silicate igneous rocks, forming alkaline-carbonatite complexes, but some occur as isolated pipes, sills, dikes, plugs, lava flows, and pyroclastic blankets. Incorporating cone sheets, ring dikes, radial dikes, and fenitisation-type halos into an exploration model and recognising associated alkaline silicate igneous rocks increases the footprint of the target. Undeformed complexes have circular, ring, or crescent-shaped aeromagnetic and radiometric signatures. Carbonatites can be effectively detected by soil, till, and stream-sediment geochemical surveys, as well as biogeochemical and indicator mineral surveys Carbonatites and alkaline-carbonatite complexes are the main sources of rare earth elements (REE) and Nb, and host significant deposits of apatite, vermiculite, Cu, Ti, fluorite, Th, U, natural zirconia, and Fe. Nine per cent of carbonatites and alkaline-carbonatite complexes contain active or historic mines, making them outstanding multi-commodity exploration targets.
Geochemistry: Exploration, Environment, Analysis, Vol. 19, pp. 414-430.
Canada, British Columbia
geochemistry
Abstract: Using Rock Canyon Creek REE-F-Ba deposit as an example, we demonstrate the need for verifying inherited geochemical data. Inherited La, Ce, Nd, and Sm data obtained by pressed pellet XRF, and La and Y data obtained by aqua regia digestion ICP-AES for 300 drill-core samples analysed in 2009 were compared to sample subsets reanalysed using lithium metaborate-tetraborate (LMB) fusion ICP-MS, Na2O2 fusion ICP-MS, and LMB fusion-XRF. We determine that LMB ICP-MS and Na2O2 ICP-MS accurately determined REE concentrations in SY-2 and SY-4, and provided precision within 10%. Fusion-XRF was precise for La and Nd at concentrations exceeding ten times the lower detection limit; however, accuracy was not established because REE concentrations in SY-4 were below the lower detection limit. Analysis of the sample subset revealed substantial discrepancies for Ce concentrations determined by pressed pellet XRF in comparison to other methods due to Ba interference. Samarium, present in lower concentrations than other REE compared, was underestimated by XRF methods relative to ICP-MS methods. This may be due to Sm concentrations approaching the lower detection limits of XRF methods, elemental interference, or inadequate background corrections. Aqua regia dissolution ICP-AES results, reporting for La and Y, are underestimated relative to other methods.
Applied Earth Science Transactions of the Institute of Mining and Metallurgy, doi.org/10.1080/ 25726838.2018.1516935 32p. Pdf
Global
carbonatite
Abstract: Most carbonatites were emplaced in continental extensional settings and range in age from Archean to recent. They commonly coexist with alkaline silicate igneous rocks, forming alkaline-carbonatite complexes, but some occur as isolated pipes, sills, dikes, plugs, lava flows, and pyroclastic blankets. Incorporating cone sheets, ring dikes, radial dikes, and fenitisation-type halos into an exploration model and recognising associated alkaline silicate igneous rocks increases the footprint of the target. Undeformed complexes have circular, ring, or crescent-shaped aeromagnetic and radiometric signatures. Carbonatites can be effectively detected by soil, till, and stream-sediment geochemical surveys, as well as biogeochemical and indicator mineral surveys Carbonatites and alkaline-carbonatite complexes are the main sources of rare earth elements (REE) and Nb, and host significant deposits of apatite, vermiculite, Cu, Ti, fluorite, Th, U, natural zirconia, and Fe. Nine per cent of carbonatites and alkaline-carbonatite complexes contain active or historic mines, making them outstanding multi-commodity exploration targets.
Simandl, G.J., Paradis, S., Stone, R.S., Fajber, R., Kressall, R.D., Grattan, K., Crozier, J., Simandl, L.J.
Applicablity of handheld X-ray fluroescence spectrometry in the exploration and development of carbonatite related niobium deposits: a case study of the Aley carbonatite, British Columbia, Canada.
Geochemistry: Exploration, Environment, Analysis, Vol. 14, 3, pp. 211-221.
Geochemistry, Geophysics, Geosystems, Vol. 20, pp. 3268-3288.
Mantle
subduction
Abstract: Molnar and England (1990, https://doi.org/10.1029/JB095iB04p04833) introduced equations using a semianalytical approach that approximate the thermal structure of the forearc regions in subduction zones. A detailed new comparison with high?resolution finite element models shows that the original equations provide robust predictions and can be improved by a few modifications that follow from the theoretical derivation. The updated approximate equations are shown to be quite accurate for a straight?dipping slab that is warmed by heat flowing from its base and by shear heating at its top. The approximation of radiogenic heating in the crust of the overriding plate is less accurate but the overall effect of this heating mode is small. It is shown that the previous and updated approximate equations become increasingly inaccurate with decreasing thermal parameter and increasing variability of slab dip. It is also shown that the approximate equations cannot be extrapolated accurately past the brittle?ductile transition. Conclusions in a recent paper (Kohn et al., 2018, https://doi.org/10.1073/pnas.1809962115) that modest amount of shear heating can explain the thermal conditions of past subduction from the exhumed metamorphic rock record are invalid due to a number of compounding errors in the application of the Molnar and England (1990, https://doi.org/10.1029/JB095iB04p04833) equations past the brittle?ductile transition. The use of the improved approximate equations is highly recommended provided their limitations are taken into account. For subduction zones with variable dip and/or low thermal parameter finite element modeling is recommended.
Earth and Planetary Science Letters, Vol. 536, 116161 7p. Pdf
Mantle
geothermometry
Abstract: Knowledge of thermal conductivity of mantle minerals is crucial for understanding heat transport from the Earth's core to mantle. At the pressure-temperature conditions of the Earth's core-mantle boundary, calculations of lattice thermal conductivity based on atomistic models have determined values ranging from 1 to 14 W/m/K for bridgmanite and bridgmanite-rich mineral assemblages. Previous studies have been performed at room temperature up to the pressures of the core-mantle boundary, but correcting these to geotherm temperatures may introduce large errors. Here we present the first measurements of lattice thermal conductivity of mantle minerals up to pressures and temperatures near the base of the mantle, 120 GPa and 2500 K. We use a combination of continuous and pulsed laser heating in a diamond anvil cell to measure the lattice thermal conductivity of pyrolite, the assemblage of minerals expected to make up the lower mantle. We find a value of W/m/K at 80 GPa and 2000 to 2500 K and 5.9 W/m/K at 124 GPa and 2000 to 3000 K. These values rule out the highest calculations of thermal conductivity of the Earth's mid-lower mantle (i.e. W/m/K at 80 GPa), and are consistent with both the high and low calculations of thermal conductivity near the base of the lower mantle.
Earth and Planetary Science Letters, Vol. 536, 116161, 11p. Pdf
Mantle
geothermometry
Abstract: Knowledge of thermal conductivity of mantle minerals is crucial for understanding heat transport from the Earth's core to mantle. At the pressure-temperature conditions of the Earth's core-mantle boundary, calculations of lattice thermal conductivity based on atomistic models have determined values ranging from 1 to 14 W/m/K for bridgmanite and bridgmanite-rich mineral assemblages. Previous studies have been performed at room temperature up to the pressures of the core-mantle boundary, but correcting these to geotherm temperatures may introduce large errors. Here we present the first measurements of lattice thermal conductivity of mantle minerals up to pressures and temperatures near the base of the mantle, 120 GPa and 2500 K. We use a combination of continuous and pulsed laser heating in a diamond anvil cell to measure the lattice thermal conductivity of pyrolite, the assemblage of minerals expected to make up the lower mantle. We find a value of W/m/K at 80 GPa and 2000 to 2500 K and 5.9 W/m/K at 124 GPa and 2000 to 3000 K. These values rule out the highest calculations of thermal conductivity of the Earth's mid-lower mantle (i.e. W/m/K at 80 GPa), and are consistent with both the high and low calculations of thermal conductivity near the base of the lower mantle.
Deijanin, B., Simic, D., Zaitsev, A., Chapman, J., Dobrinets, I., Widemann, A., Del Re, N., Middleton, T., Dijanin, E., Se Stefano, A.
Characterization of pink diamonds of different origin: natural ( Argyle, non-Argyle), irradiated and annealed, treated with multi-process, coated and synthetic.
Diamond and Related Materials, Vol. 17, 7-10, pp. 1169-1178.
Direct discovery of concealed kimberlites with microbial community fingerprinting.
2018 Yellowknife Geoscience Forum , p. 36. abstract
Canada, Northwest Territories
mineral chemistry
Abstract: Mineral exploration in Canada is becoming increasingly complex as the majority of undiscovered commodities are likely deeply buried beneath significant glacial overburden and bedrock, reducing the effectiveness of many existing tools. The development of innovative exploration protocols and techniques is imperative to the continuation of discovery success. Preliminary experimentation has demonstrated the potential viability of microbial fingerprinting through genetic sequencing to directly identify the projected subcrop of mineralization in addition to the more distal entrained geochemical signatures in till. With the advent of inexpensive modern sequencing technology and big-data techniques, microbiological approaches to exploration are becoming more quantitative, cost effective, and efficient. The integration of microbial community information with soil chemistry, mineralogy and landscape development coupled with geology and geophysics propagates the development of an improved decision process in mineral exploration. Soils over porphyry, kimberlite, and VMS deposits have undergone microbial community profiling. These community-genome derived datasets have been integrated with trace metal chemistry, mineralogy, surface geology and other environmental variables including Eh and pH. Analyses of two kimberlites in the Northwest Territories show significant microbial community shifts that are correlated with subsurface mineralization, with distinctive microbial community profiles present directly above the kimberlite. The relationship between microbial profiles and mineralization leads to the use of microbial fingerprinting as a method for more accurately delineating ore deposits in glacially covered terrain. As databases are developed, there is potential for application as a field based technique, as sequencing technology is progressively developed into portable platforms.
Yellowknife Forum NWTgeoscience.ca, abstract volume p. 42-43.
Canada, Northwest Territories
kimberlite
Abstract: Mineral exploration in northern latitudes is challenging in that undiscovered deposits are likely buried beneath significant glacial overburden. The development of innovative exploration strategies and robust techniques to see through cover is imperative to future discovery success. Microbial communities are sensitive to subtle environmental fluctuations, reflecting these changes on very short timescales. Shifts in microbial community profiles, induced by chemical differences related to geology, are detectable in the surficial environment, and can be used to vector toward discrete geological features. The modernization of genetic sequencing and big-data evaluation allows for efficient and cost-effective microbial characterization of soil profiles, with the potential to see through glacial cover. Results to date have demonstrated the viability of microbial fingerprinting to directly identify the surface projection of kimberlites in addition to entrained geochemical signatures in till. Soils above two kimberlites in the Northwest Territories, have undergone microbial community profiling. These community-genome derived datasets have been integrated with chemistry, mineralogy, surface geology, vegetation type and other environmental variables including Eh and pH. Analyses show significant microbial community shifts, correlated with the presence of kimberlites, with a distinct community response at the species level directly over known deposits. Diversity of soil bacteria is also depressed in the same regions of the microbial community response. The relationship between microbial profiles and buried kimberlites has led to the application of microbial fingerprinting as a method to accurately delineate potential ore deposits in covered terrain. The integration of microbial community information with soil chemistry and landscape development coupled with geology and geophysics significantly improves the drill / no-drill decision process and has proven to be far more accurate than traditional surficial exploration methods. There is high potential for application as a field-based technique as microbial databases for kimberlites in northern regions are refined, and as sequencing technology is progressively developed into portable platforms.
Joint seismic geodynamic mineral physical modeling of African geodynamics: a reconciliation of deep mantle convection with surface geophysical constraints.
Earth and Planetary Science Letters, Vol. 295, 3-4, pp. 329-341.
Journal of the Geological Society, Vol. 76, pp. 817-829.
Europe, Scotland
impact crater
Abstract: The Lairg Gravity Low may represent a buried impact crater c. 40 km across that was the source of the 1.2 Ga Stac Fada Member ejecta deposit but the gravity anomaly is too large to represent a simple crater and there is no evidence of a central peak. Reanalysis of the point Bouguer gravity data reveals a ring of positive anomalies around the central low, suggesting that it might represent the eroded central part of a larger complex crater. The inner or peak rings of complex craters show a broadly consistent 2:1 relationship between ring diameter and total crater diameter, implying that the putative Lairg crater may be as much as 100 km across. This would place the crater rim within a few kilometres of the Stac Fada Member outcrop, a location inconsistent with the thickness and clast size of the ejecta deposit. We propose that the putative impact crater originally lay further east, substantially further from the Stac Fada Member than today, and was translocated westwards to its present location beneath Lairg during the Caledonian Orogeny. This model requires that a deep-seated thrust fault, analogous to the Flannan and Outer Isles thrusts, exists beneath the Moine Thrust in north-central Scotland.
Hudgins, T.R., Mukasa, S.B., Simon, A.C., Moore, G., Barifaijo, E.
Melt inclusion evidence for CO2 rich melts beneath the western branch of the East African Rift: implications for long term storage of volatiles in the deep lithospheric mantle.
Contributions to Mineralogy and Petrology, Vol. 169, 5p.
Abstract: There are two types of emerged relief on the Earth: high elevation areas (mountain belts and rift shoulders) in active tectonic settings and low elevation domains (anorogenic plateaus and plains) characteristic of the interior of the continents i.e. 70% of the Earth emerged relief. Both plateaus and plains are characterized by large erosional surfaces, called planation surfaces that display undulations with middle (several tens of kilometres) to very long (several thousands of kilometres) wavelengths, i.e. characteristic of lithospheric and mantle deformations respectively. Our objective is here (1) to present a new method of characterization of the very long and long wavelength deformations using planation surfaces with an application to Central Africa and (2) to reconstruct the growth of the very long wavelength relief since 40 Ma, as a record of past mantle dynamics below Central Africa. (i) The African relief results from two major types of planation surfaces, etchplains (weathering surfaces by laterites) and pediplains/pediments. These planation surfaces are stepped along plateaus with different elevations. This stepping of landforms records a local base level fall due to a local tectonic uplift. (ii) Central Africa is an extensive etchplain-type weathering surface - called the African Surface - from the uppermost Cretaceous (70 Ma) to the Middle Eocene (45 Ma) with a paroxysm around the Early Eocene Climatic Optimum. Restoration of this surface in Central Africa suggests very low-elevation planation surfaces adjusted to the Atlantic Ocean and Indian Ocean with a divide located around the present-day eastern branch of the East African Rift. (iii) The present-day topography of Central Africa is younger than 40 -30 Ma and records very long wavelength deformations (1000 -2000 km) with (1) the growth of the Cameroon Dome and East African Dome since 34 Ma, (2) the Angola Mountains since 15 -12 Ma increasing up to Pleistocene times and (3) the uplift of the low-elevation (300 m) Congo Basin since 10 -3 Ma. Some long wavelength deformations (several 100 km) also occurred with (1) the low-elevation Central African Rise since 34 Ma and (2) the Atlantic Bulge since 20 -16 Ma. These very long wavelength deformations record mantle dynamics, with a sharp increase of mantle upwelling around 34 Ma and an increase of the wavelength of the deformation and then of mantle convection around 10 -3 Ma.
Abstract: Field, petrographic and geochemical data combined with in situ zircon U-Pb LA-ICP-MS ages are documented for the São Tiago Batholith (southernmost portion of the São Francisco Craton) to understand its origin and magmatic evolution. The geologic relations indicate that the batholith is composed of granitic to granodioritic orthogneisses (L2) with tonalitic xenoliths (L1) intruded by pegmatite (L3) and metagranite (L4). L1 consists of two facies of tonalitic orthogneiss, one biotite-rich, and the other biotite-poor. The geochemical evidence, including high K2O with mantle-like chemical signature, suggests that the Bt-rich tonalitic gneiss (2816?±?30?Ma) was derived from contamination of mafic magmas by crustal-derived components. The Bt-poor tonalitic gneiss, of TTG affinity, was generated by partial melting of LILE-enriched mafic rocks, possibly from oceanic plateus in a subduction environment. L2 includes two distinct types of rocks: (i) granodioritic orthogneiss, chemically ranging from medium-pressure TTGs to potassic granitoids originated via partial melting of previous TTG crust, including L1 Bt-poor; and (ii) granitic gneiss (2664?±?4?Ma), geochemically similar to crustal-derived granites, produced by melting of the L1 Bt-rich tonalitic gneiss or mixed TTG/metasedimentary sources. L3 pegmatite (2657?±?23?Ma) results from melting of L2, whereas L4 metagranite (dikes and stocks) shows petrogenesis similar to that of the L2 granitic gneiss. Related orthogneisses occur near the São Tiago Batholith: (i) a hornblende-bearing tonalitic gneiss, and (ii) a hybrid hornblende-bearing granitic gneiss (2614?±?13?Ma), whose genesis is linked with interaction of sanukitoid and felsic potassic melts, representing the last Archean magmatic pulse of the region. The Minas strata along the Jeceaba-Bom Sucesso lineament near our study region encircle the São Tiago Archean crust, representing an irregular paleo-coastline or a micro-terrane amalgamation with the São Francisco Proto-craton, with possible subsequent dome-and-keel deformational processes. Our petrological and geochronological data reevaluate nebulous concepts in the literature about the SFC, revealing (i) a chemically and compositionally diverse crustal segment generated at the Late Archean in diverse geodynamic scenarios, and (ii) a more complex lineament than previously thought in terms of the paleogeography of the southern São Francisco Craton.
Hopp, J., Trieloff, M., Brey, G.P., Woodland, A.B., Simon, N.S.C., Wijbrans, J.R., Siebel, W., Reitter, E.
40 Ar 39 Ar ages of phlogopite in mantle xenoliths from South African kimberlites: evidence for metasomatic mantle impregnation during Kilbaran orogenic cycle.
Simon, S.J., Wei, C.T., Viladkar, S.G., Ellmies, R., Soh, Tamech, L.S., Yang, H., Vatuva, A.
Metamitic U rich pyrochlore from Epembe sovitic carbonatite dyke, NW Namibia.
Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 12.
Africa, Namibia
deposit - Epembe
Abstract: The Epembe carbonatite dyke is located about 80 km north of Opuwo, NW Namibia. The 10 km long dyke is dominated by massive and banded sövitic carbonatite intrusions. Two distinct type of sövite have been recognized: (1) coarse-grained light grey Sövite I which is predominant in brecciated areas and (2) medium- to fine-grained Sövite II which hosts notable concentrations of pyrochlore and apatite. The contact between the carbonatite and basement gneisses is marked by K-feldspar fenite. The pyrochlore chemistry at Epembe shows a compositional trend from primary magmatic Ca-rich pyrochlore toward late hydrothermal fluid enriched carbonatite phase, giving rise to a remarkable shift in chemical composition and invasion of elements such as Si, U, Sr, Ba, Th and Fe. Enrichment in elements like U, Sr and Th lead to metamictization, alteration and A-site vacancy. It is therefore suggested that the carbonatite successive intrusive phases assimilated primary pyrochlore leading to extreme compositional variation especially around the rims of the pyrochlore. The genesis of the Epembe niobium deposit is linked to the carbonatite magmatism but the mechanism that manifested such niobium rich rock remains unclear and might be formed as a result of cumulate process and/or liquid immiscibility of a carbonate-silicate pair.
Abstract: The Miaoya carbonatite complex (MCC) is located within the southern edge of the Qinling orogenic belt in central China, and is associated with significant rare earth element (REE) and Nb mineralization. The MCC consists of syenite and carbonatite that were emplaced within Neo- to Mesoproterozoic-aged supracrustal units. The carbonatite intruded the associated syenite as stocks and dikes, and is mainly composed of medium- to fine-grained calcite and abundant REE-bearing minerals. Carbonatite melt generation and emplacement within the MCC occurred during the Silurian (at ~440?Ma), and was subsequently impacted by a late-stage hydrothermal event (~232?Ma) involving REE-rich fluids/melt. This study reports trace element and stable (B, C, and O) and radiogenic (Nd, Pb, and Sr) isotope data for the MCC carbonatite, and these have been subdivided into three groups that represent different REE contents, interpreted as varying degrees of hydrothermal interaction. Overall, the group of carbonatites with the lowest enrichment in LREEs (i.e., least affected by hydrothermal event) is characterized by ?11B values that vary between ?7 (typical asthenospheric mantle) and?+?4‰; ?11B values and B abundances (~0.2 to ~1?ppm) do not correlate with LREE contents. The Sm-Nd and Pb-Pb isotope systems have both been perturbed by the late-stage, REE-rich hydrothermal activity and corroborate open-system behavior. Contrarily, initial 87Sr/86Sr ratios (vary between ~0.70355 and 0.70385) do not correlate significantly with both LREEs and Sr abundances, nor with initial 143Nd/144Nd ratios. The late-stage hydrothermal event overprinted the Nd and Pb isotope compositions for most of the carbonatite samples examined here, whereas a majority of the samples preserve their variable B and Sr isotope values inherited from their mantle source. The B and Sr isotope data for carbonatites exhibiting the least LREE enrichment correlate positively and suggest carbonatite melt generation from a heterogenous upper mantle source that records the input of recycled crustal material. This finding is consistent with those previously reported for young (<300?Ma old) carbonatites worldwide.
neodymium, lead, and Strontium isotopic dat a Napak carbonatite -nephelinite centre, eastern Uganda: implications for crustal assimilation and fractional crystalization
Eos Transactions, Vol. 73, No. 14, April 7, supplement abstracts p.329
Doornbos, C., Heaman, L.M., Doupe, J.P., England, J., Simonetti, A., Lejeunesse, P.
The first integrated use of in situ U Pb geochronology and geochemical analyses to determine long distance transport of glacial erratics from maIn land Canada into western Arctic Archipelgo.
Canadian Journal of Earth Sciences, Vol. 46, 2, pp. 101-122.
Tappe, S., Heaman, L.M., Smart, K.A., Muehlenbachs, K., Simonetti, A.
First results from Greenland eclogite xenoliths: evidence for an ultra depleted peridotitic component within the North Atlantic craton mantle lithosphere.
GAC/MAC/AGU Meeting held May 23-27 Toronto, Abstract only
Hunt, L., Stachel, T., Grutter, H., Armstrong, J., McCandless, T.E., Simonetti, A., Tappe, S.
Small mantle fragments from the Renard kimberlites, Quebec: powerful recorders of mantle lithosphere formation and modification beneath the eastern Superior Craton.
Combined U-Pb geochronology and Sr-Nd isotope analysis of the Ice River perovskite standard, with implications for kimberlite and alkaline rock petrogenesis.
In situ determination of major and trace elements in calcite and apatite, and U-Pb ages of apatite from the Oka carbonatite complex: insights into a complex crystallization history.
Smart, K.A., Chacko, T., Simonetti, A., Sharp, Z.D., Heaman, L.M.
A record of Paleoproterozoic subduction preserved in the northern Slave cratonic mantle: Sr-Pb-O isotope and trace element investigations of eclogite xenoliths from the Jericho and Muskox kimberlites.
Abstract: Oldoinyo Lengai is situated within the Gregory Rift Valley (northern Tanzania) and is the only active volcano erupting natrocarbonatite lava. This study investigates the texture and mineralogy of the June 1993 lava at Oldoinyo Lengai, and presents petrographic evidence of liquid immiscibility between silicate, carbonate, chloride, and fluoride melt phases. The 1993 lava is a porphyritic natrocarbonatite consisting of abundant phenocrysts of alkali carbonates, nyerereite and gregoryite, set in a quenched groundmass, composed of sodium carbonate, khanneshite, Na-sylvite and K-halite, and a calcium fluoride phase. Dispersed in the lava are silicate spheroids (< 2 mm) with a cryptocrystalline silicate mineral assemblage wrapped around a core mineral. We have identified several textural features preserved in the silicate spheroids, melt inclusions, and carbonatite groundmass that exhibit evidence of silicate-carbonate, carbonate-carbonate and carbonate-halide immiscibility. Rapid quenching of the lava facilitated the preservation of the end products of these liquid immiscibility processes within the groundmass. Textural evidence (at both macro- and micro-scales) indicates that the silicate, carbonate, chloride and fluoride phases of the lava unmixed at different stages of evolution in the magmatic system.
Tectonic significance and redox state of Paleoproterozoic eclogite and pyroxenite components in the Slave cratonic mantle lithosphere, Voyageur kimberlite, Arctic Canada.
Abstract: The global boron geochemical cycle is closely linked to recycling of geologic material via subduction processes that have occurred over billions of years of Earth’s history. The origin of carbonatites, unique melts derived from carbon-rich and carbonate-rich regions of the upper mantle, has been linked to a variety of mantle-related processes, including subduction and plume-lithosphere interaction. Here we present boron isotope (?11B) compositions for carbonatites from locations worldwide that span a wide range of emplacement ages (between ~40 and ~2,600?Ma). Hence, they provide insight into the temporal evolution of their mantle sources for ~2.6 billion years of Earth’s history. Boron isotope values are highly variable and range between ?8.6 and +5.5, with all of the young (<300?Ma) carbonatites characterized by more positive ?11B values (>?4.0‰ whereas most of the older carbonatite samples record lower B isotope values. Given the ?11B value for asthenospheric mantle of ?7 ± 1‰ the B isotope compositions for young carbonatites require the involvement of an enriched (crustal) component. Recycled crustal components may be sampled by carbonatite melts associated with mantle plume activity coincident with major tectonic events, and linked to past episodes of significant subduction associated with supercontinent formation.
Abstract: The global boron geochemical cycle is closely linked to recycling of geologic material via subduction processes that have occurred over billions of years of Earth’s history. The origin of carbonatites, unique melts derived from carbon-rich and carbonate-rich regions of the upper mantle, has been linked to a variety of mantle-related processes, including subduction and plume-lithosphere interaction. Here we present boron isotope (?11B) compositions for carbonatites from locations worldwide that span a wide range of emplacement ages (between ~40 and ~2,600?Ma). Hence, they provide insight into the temporal evolution of their mantle sources for ~2.6 billion years of Earth’s history. Boron isotope values are highly variable and range between ?8.6‰ and +5.5‰, with all of the young (<300?Ma) carbonatites characterized by more positive ?11B values (>?4.0‰), whereas most of the older carbonatite samples record lower B isotope values. Given the ?11B value for asthenospheric mantle of ?7 ± 1‰, the B isotope compositions for young carbonatites require the involvement of an enriched (crustal) component. Recycled crustal components may be sampled by carbonatite melts associated with mantle plume activity coincident with major tectonic events, and linked to past episodes of significant subduction associated with supercontinent formation.
Abstract: Oldoinyo Lengai is situated within the Gregory Rift Valley (northern Tanzania) and is the only active volcano erupting natrocarbonatite lava. This study investigates the texture and mineralogy of the June 1993 lava at Oldoinyo Lengai, and presents petrographic evidence of liquid immiscibility between silicate, carbonate, chloride, and fluoride melt phases. The 1993 lava is a porphyritic natrocarbonatite consisting of abundant phenocrysts of alkali carbonates, nyerereite and gregoryite, set in a quenched groundmass, composed of sodium carbonate, khanneshite, Na-sylvite and K-halite, and a calcium fluoride phase. Dispersed in the lava are silicate spheroids (< 2 mm) with a cryptocrystalline silicate mineral assemblage wrapped around a core mineral. We have identified several textural features preserved in the silicate spheroids, melt inclusions, and carbonatite groundmass that exhibit evidence of silicate-carbonate, carbonate-carbonate and carbonate-halide immiscibility. Rapid quenching of the lava facilitated the preservation of the end products of these liquid immiscibility processes within the groundmass. Textural evidence (at both macro- and micro-scales) indicates that the silicate, carbonate, chloride and fluoride phases of the lava unmixed at different stages of evolution in the magmatic system.
Abstract: Mantle-derived eclogite and pyroxenite xenoliths from the Jurassic Voyageur kimberlite on the northern Slave craton in Arctic Canada were studied for garnet and clinopyroxene major and trace element compositions, clinopyroxene Pb and garnet O isotopic compositions, and garnet Fe3 +/?Fe contents. The Voyageur xenoliths record a wide range of pressures, but are cooler compared to mantle xenoliths derived from the nearby, coeval Jericho kimberlite. The CaO, TiO2 and Zr contents of Voyageur eclogites increase with depth, which is also observed in northern Slave peridotite xenoliths, demonstrating ‘bottom-up’ metasomatic processes within cratonic mantle lithosphere. The Voyageur eclogites have positive Eu anomalies, flat HREEN patterns, and major element compositions that are consistent with ultimate origins from basaltic and gabbroic protoliths within oceanic lithosphere. Clinopyroxene Pb isotope ratios intercept the Stacey-Kramers two-stage terrestrial Pb evolution curve at ca. 2.1 Ga, and form an array towards the host kimberlite, indicating isotopic mixing. The 2.1 Ga eclogite formation age broadly overlaps with known Paleoproterozoic subduction and collision events that occurred along the western margin of the Slave craton. Unlike the eclogites, the Voyageur pyroxenites contain garnet with distinctive fractionated HREEN, sinusoidal REE patterns of calculated bulk rocks, and clinopyroxene with 206Pb/204Pb ratios that intercept the Stacey-Kramers curve at 1.8 Ga. This suggests a distinct origin as Paleoproterozoic high-pressure mantle cumulates. However, the pyroxenite Pb isotope ratios fall within the eclogite array and could also be explained by protoliths formation at ca. 2.1 Ga followed by minor isotopic mixing during mantle metasomatism. Thus, an alternative scenario involves pyroxenite formation within the mantle section of Paleoproterozoic oceanic lithosphere followed by variable metasomatism after incorporation into cratonic mantle lithosphere. This model allows for a linked petrogenesis of the Voyageur eclogites (crust) and pyroxenites (mantle) as part of the same subducting oceanic slab. Oxygen fugacity determinations for one pyroxenite and ten eclogite xenoliths show a range of 3 log units, from ? 4.6 to ? 1.6 ?FMQ, similar to the range observed for nearby Jericho and Muskox eclogites (?FMQ ? 4.2 to ? 1.5). Importantly, the northern Slave eclogite and pyroxenite mantle components are highly heterogeneous in terms of redox state provided that they range from reduced to oxidized relative to Slave peridotite xenoliths. Moreover, the Voyageur eclogites do not exhibit any trend between oxidation state and equilibration depth, which contrasts with the downward decrease in fO2 shown by Slave and worldwide cratonic peridotite xenoliths. Our investigation of mantle eclogite and pyroxenite fO2 reinforces the important influence of recycled mafic components in upper mantle processes, because their high and variable redox buffering capacity strongly controls volatile speciation and melting relations under upper mantle conditions.
Abstract: Mantle-derived eclogite xenoliths are key for studying the evolution of the cratonic lithosphere, because geochemical evidence suggests that they typically represent fragments of Archean and Proterozoic oceanic lithosphere [1]. Recently, it has been suggested that eclogite xenoliths can serve as redox sensors of the Precambrian upper mantle using V/Sc as a redox proxy [2]. However, metasomatism can change the original oxidation state of the cratonic mantle [3], thereby limiting its use for monitoring mantle redox evolution. Circa 1.8–2.2 Ga eclogite xenoliths erupted with Jurassic kimberlites of the northern Slave craton have geochemical features that indicate oceanic crust protoliths [4, 5]. Such Paleoproterozoic ages are common for Slave craton mantle eclogites [6], linking eclogite formation with 1.9 Ga subduction-collision events at the western craton margin. The eclogites studied here have highly variable Fe3+/?Fe (0.019 – 0.076 ±0.01), with logfO2 (?FMQ-4 to +2 ±0.5) that are both relatively oxidized and reduced compared to Slave mantle peridotite xenoliths [3]. Also, eclogite fO2 positively correlates with some indicies of metasomatism, such as elevated TiO2 in garnet. In addition to considering the time gap between eclogite formation and kimberlite eruption, the highly variable fO2–depth systematics of the eclogites studied here illustrate the drawbacks of using averaged eclogite fO2 to define the redox evolution of the upper mantle. Despite this, the ca. 2 Ga northern Slave craton eclogites have an average depth-corrected logfO2 of ?FMQ-0.5±1.3 (1?) that overlaps with modern MORB, and complies with the upper mantle redox evolution trend predicted using V/Sc ratios of mantlederived melts [2]. However, given the debate around the secuarity of mantle redox [7], further research into the suitability of mantle eclogites as redox sensors is warranted.
Nd, Sr, Pb and B isotopic investigation of carbonatite/alkaline centers in west central India: insights into plume driven vs lithospheric controlled magmatism.
Carbonatite-alkaline rocks and associated mineral deposits , Dec. 8-11, abstract p. 17.
India
carbonatites
Abstract: The exact origin of carbonatite magmas remains debatable as there are two main hypothesis proposed; one relates magmatism to asthenospheric upwellings and/or mantle plumes, whereas the other argues for generation from metasomatized lithosphere. However, proponents of the latter rarely describe in detail the origin of the metasomatic agents required to generate the high concentrations of rare earth and highly incompatible elements present in carbonatite magmas. In a recent study, Boron isotopic signatures of carbonatite complexes worldwide, ranging in age from ~2600 to ~65 million years old, indicate greater input of recycled (subducted), crustal material and plume activity with increasing geologic age of the Earth. More positive Boron isotopic values with increasing geologic time were attributed to the change of Earth’s geodynamics to a modern style of plate tectonics. In this study, the radiogenic (Sr, Nd, Pb) and B isotope systematics of carbonatites and alkaline rocks from west-central India are reported and discussed with reference to the plume-lithosphere interaction model previously proposed for the generation of Deccan-related alkaline centers in this region of the Indian sub-continent
Abstract: The genesis of Earth’s largest rare earth element (REE) deposit, Bayan Obo (China), has been intensely debated, in particular whether the host dolomite marble is of sedimentary or igneous origin. The protracted (Mesoproterozoic to Paleozoic) and intricate (magmatic to metasomatic) geological processes complicate geochemical interpretations. In this study, we present a comprehensive petrographic and in situ, high-spatial resolution Sr-Pb isotopic and geochemical investigation of the host dolomite from the Bayan Obo marble. Based on petrographic evidence, the dolomite marble is divided into three facies including coarse-grained (CM), fine-grained (FM), and heterogeneous marble (HM). All carbonates are ferroan dolomite with high SrO and MnO contents (>?0.15 wt.%), consistent with an igneous origin. Trace element compositions of these dolomites are highly variable both among and within individual samples, with CM dolomite displaying the strongest LREE enrichment. In situ 206Pb/204Pb and 207Pb/204Pb ratios of the dolomite are generally consistent with mantle values. However, initial 208Pb/204Pb ratios define a large range from 35.45 to 39.75, which may result from the incorporation of radiogenic Pb released from decomposition of monazite and/or bastnäsite during Early Paleozoic metasomatism. Moreover, in situ Sr isotope compositions of dolomite indicate a large range (87Sr/86Sr?=?0.70292-0.71363). CM dolomite is characterized by a relatively consistent, unradiogenic Sr isotope composition (87Sr/86Sr?=?0.70295-0.70314), which is typical for Mesoproterozoic mantle. The variation of 87Sr/86Sr ratios together with radiogenic 206Pb/204Pb signatures for dolomite within FM and HM possibly represents recrystallization during Early Paleozoic metasomatism with the contribution of radiogenic Sr and Pb from surrounding host rocks. Therefore, our in situ geochemical data support a Mesoproterozoic igneous origin for the ore-bearing dolomite marble in the Bayan Obo deposit, which subsequently underwent intensive metasomatism during the Early Paleozoic.
Abstract: This study reports the combined major, minor and trace element compositions, and stable (C, O), radiogenic (Nd, Pb, and Sr) isotopic compositions, and first ?11B isotopic data for the Fir, Felix, Gum, and Howard Creek carbonatites from the Blue River Region, British Columbia (Canada). These sill-like occurrences were intruded into Late Proterozoic strata during rifting and extensional episodes during the Late Cambrian and Devonian -Mississippian, and subsequently deformed and metamorphosed to amphibolite grade in relation to a collisional-type tectonic environment. The carbonatites at Fir, Gum, and Felix contain both calcite and dolomite, whereas the carbonatite at Howard Creek contains only calcite. The dolomite compositions reported here are consistent with those experimentally determined by direct partial melting of metasomatized peridotitic mantle. The combined major and trace element compositions and ?13CPDB (?5.37 to ?4.85‰) and ?18OSMOW (9.14 to 9.62‰) values for all the samples investigated are consistent with those for primary igneous carbonate and support their mantle origin. However, these signatures cannot be attributed to closed system melt differentiation from a single parental melt. The initial Nd, Pb, and Sr isotopic ratios are highly variable and suggest generation from multiple, small degree parental melts derived from a heterogeneous mantle source. The ?11B values for carbonates from Felix, Gum, and Howard Creek vary between ?8.67 and ?6.36‰, and overlap the range for asthenospheric mantle (?7.1?±?0.9‰), whereas two samples from Fir yield heavier values of ?3.98 and ?2.47‰. The latter indicate the presence of recycled crustal carbon in their mantle source region, which is consistent with those for young (<300?Ma) carbonatites worldwide. The radiogenic and B isotope results for the Blue River carbonatites are compared to those from contrasting, anorogenic tectonic settings at Chipman Lake, Fen, and Jacupiranga, and indicate that similar upper mantle sources are being tapped for carbonatite melt generation. The pristine, mantle-like ?11B values reported here for the Blue River carbonatites clearly demonstrate that this isotope system is robust and was not perturbed by post-solidification tectono-metamorphic events. This observation indicates that B isotope signatures are a valuable tool for deciphering the nature of the upper mantle sources for carbonates of igneous origin.
Chemical Geology, doi.org/10.1016/j.chemgeo.2019.07.015 59p.
Canada, British Columbia
carbonatite - Blue River
Abstract: This study reports the combined major, minor and trace element compositions, and stable (C, O), radiogenic (Nd, Pb, and Sr) isotopic compositions, and first ?11B isotopic data for the Fir, Felix, Gum, and Howard Creek carbonatites from the Blue River Region, British Columbia (Canada). These sill-like occurrences were intruded into Late Proterozoic strata during rifting and extensional episodes during the Late Cambrian and Devonian -Mississippian, and subsequently deformed and metamorphosed to amphibolite grade in relation to a collisional-type tectonic environment. The carbonatites at Fir, Gum, and Felix contain both calcite and dolomite, whereas the carbonatite at Howard Creek contains only calcite. The dolomite compositions reported here are consistent with those experimentally determined by direct partial melting of metasomatized peridotitic mantle. The combined major and trace element compositions and ?13CPDB (?5.37 to ?4.85‰) and ?18OSMOW (9.14 to 9.62‰) values for all the samples investigated are consistent with those for primary igneous carbonate and support their mantle origin. However, these signatures cannot be attributed to closed system melt differentiation from a single parental melt. The initial Nd, Pb, and Sr isotopic ratios are highly variable and suggest generation from multiple, small degree parental melts derived from a heterogeneous mantle source. The ?11B values for carbonates from Felix, Gum, and Howard Creek vary between ?8.67 and ?6.36‰, and overlap the range for asthenospheric mantle (?7.1?±?0.9‰), whereas two samples from Fir yield heavier values of ?3.98 and ?2.47‰. The latter indicate the presence of recycled crustal carbon in their mantle source region, which is consistent with those for young (<300?Ma) carbonatites worldwide. The radiogenic and B isotope results for the Blue River carbonatites are compared to those from contrasting, anorogenic tectonic settings at Chipman Lake, Fen, and Jacupiranga, and indicate that similar upper mantle sources are being tapped for carbonatite melt generation. The pristine, mantle-like ?11B values reported here for the Blue River carbonatites clearly demonstrate that this isotope system is robust and was not perturbed by post-solidification tectono-metamorphic events. This observation indicates that B isotope signatures are a valuable tool for deciphering the nature of the upper mantle sources for carbonates of igneous origin.
Geochimica et Cosmochimica Acta, in press available 45p. Pdf
China
deposit - Miaoya
Abstract: A majority of carbonatite-related rare earth element (REE) deposits are found in cratonic margins and orogenic belts, and metasomatic/hydrothermal reworking is common in these deposits; however, the role of metasomatic processes involved in their formation remains unclear. Here, we present a comprehensive in situ chemical and isotopic (C-Sr) investigation of calcite and fluorapatite within the Miaoya carbonatite complex located in the South Qinling orogenic belt, with the aim to better define the role of late-stage metasomatic processes. Carbonatite at Miaoya commonly occurs as stocks and dykes intruded into associated syenite, and can be subdivided into equigranular (Type I) and inequigranular (Type II) calcite carbonatites. Calcite in Type I carbonatite is characterized by the highest Sr (up to ?22,000?ppm) and REE (195-542?ppm) concentrations with slight LREE-enriched chondrite normalized patterns [(La/Yb)N?=?2.1-5.2]. In situ C and Sr isotopic compositions of calcite in Type I carbonatite define a limited range (87Sr/86Sr?=?0.70344-0.70365; ?13C?=??7.1 to ?4.2 ‰) that are consistent with a mantle origin. Calcite in Type II carbonatite has lower Sr (1708-16322?ppm) and REEs (67-311?ppm) and displays variable LREE-depleted chondrite normalized REE patterns [(La/Yb)N?=?0.2-3.3; (La/Sm)N?=?0.2-2.0]. In situ 87Sr/86Sr and d13C isotopic compositions of Type II calcite are highly variable and range from 0.70350 to 0.70524 and ?7.0 to ?2.2 ‰, respectively. Fluorapatite in Type I and Type II carbonatites is characterized by similar trace-element and isotopic compositions. Both types of fluorapatite display variable trace element concentrations, especially LREE contents, whereas they exhibit relatively consistent near-chondritic Y/Ho ratios. Fluorapatite is characterized by consistent Sr isotopic compositions with a corresponding average 87Sr/86Sr ratio of 0.70359, which suggests that fluorapatite remained relatively closed in relation to contamination. The combined geochemical and isotopic data for calcite and fluorapatite from the Miaoya complex suggest that carbonatite-exsolved fluids together with possible syenite assimilation during the Mesozoic metasomatism overprinted the original trace-element and isotopic signatures acquired in the early Paleozoic magmatism. Hydrothermal reworking resulted in dissolution-reprecipitation of calcite and fluorapatite, which served as the dominant source of REE mineralization during the much younger metasomatic activity. The results from this study also suggest that carbonatites located in orogenic belts and cratonic edges possess a great potential for forming economic REE deposits, especially those that have undergone late-stage metasomatic reworking.
Cimen, O., Corcoran, L., Kuebler, C., Simonetti, S.S., Simonetti, A.
Geochemical, stable ( O, C, and B) and radiogenic ( Sr, Nd, Pb) isotopic data from the Eskisehir-Kizulxaoren ( NW-Anatolia) and the Malatya-Kuluncak ( E- central Anatolia) F-REE-Th deposits, Turkey: implications for nature of carbonate-hosted mineralizati
Turkish Journal of Earth Sciences, Vol. 29, doe:10.3906/yer-2001-7 18p. Pdf
Turkish Journal of Earth Sciences, Vol. 29, pp. 798-814. pdf
Europe, Turkey
REE
Abstract: In Turkey, the largest fluorine (F)-rare earth element (REE)-thorium (Th) deposits are located within the Eski?ehir-K?z?lcaören (north-western Anatolia) and the Malatya-Kuluncak (east-central Anatolia) regions, and these are associated with Oligocene extensional alkaline volcanic and Late Cretecaous-Early Paleocene postcollisional intrusive rocks, respectively. In the K?z?lcaören region, the basement units include the Triassic Karakaya Complex and the Late Cretaceous oceanic units (Neotethyan suture) that are cut and overlain by phonolite and carbonatite intrusions and lava flows. In the Kuluncak region, the plutonic rocks are mainly composed of syenite, quartz syenite, and rare monzonite, and these cut the late-Cretaceous Karap?nar limestone, which hosts the F-REE-Th mineralization in contact zones. A carbonatite sample from the K?z?lcaören region displays both a total rare earth element (TREE) concentration (4795 ppm) and ?11B (-6.83‰) isotope composition consistent with mantle-derived carbonatite; whereas it is characterized by heavier ?13C (+1.43‰) and ?18O (+20.23‰) isotope signatures compared to those for carbonatites worldwide. In contrast, the carbonates which host the F-REE-Th mineralization in the Kuluncak region are characterized by lower TREE concentrations (5.13 to 55.88 ppm), and heavier ?13C (-0.14 to -0.75‰), ?18O (+27.36 to +30.61‰), and ?11B (+5.38 to +6.89‰) isotope ratios compared to mantle-derived carbonatites. Moreover, the combined initial 87Sr/86Sr (0.70584 to 0.70759) and 143Nd/144Nd (0.512238 to 0.512571) isotope ratios for samples investigated here are distinct and much more radiogenic compared to those for carbonatites worldwide, and therefore indicate significant crustal input and/or hydrothermal metasomatic-related alteration. Overall, stable and radiogenic isotope data suggest that the host carbonate rocks for the F-REE-Th mineralization in both the K?z?lcaören and the Kuluncak regions consist of hydrothermally metasomatized carbonatite and limestone, respectively. The mineralization in the K?z?lcaören region may potentially be related to carbonatite magmatism, whereas the mineralization in the Kuluncak region, which most likely formed through interactions between the plutonic rocks and surrounding limestone at contact metamorphism zone, involved hydrothermal/magmatic fluids associated with extensive postcollisional magmatism.
Abstract: The central region of the Kaapvaal craton is relatively understudied in terms of its lithospheric mantle architecture, but is commonly believed to be significantly impacted by post-Archean magmatism such as the ca. 2056 Ma Bushveld large igneous event. We investigate a collection of 17 eclogite xenoliths from the Cretaceous Palmietfontein kimberlite at the Western Limb of the Bushveld Complex for their mineralogical compositions (major and trace elements, plus Fe3+ contents), as well as stable oxygen and radiogenic Pb isotopic compositions to gain further insights into the nature and evolution of the central Kaapvaal cratonic mantle lithosphere. New U/Pb age determinations on mantle-derived zircon yield a magma emplacement age of ca. 75 Ma for the Palmietfontein Group-1 kimberlite, which means that the entrained eclogite xenoliths may record a protracted metasomatic history from the Proterozoic through to most of the Phanerozoic eon. Garnet ?18O values of up to 6.9‰ and positive Eu anomalies for the bulk rocks suggest seawater-altered oceanic crustal protoliths for the Palmietfontein eclogite xenolith suite, which is typical for the eclogitic components of the Kaapvaal root and other cratonic mantle sections worldwide. However, several features of the Palmietfontein eclogites are commonly not observed in other mantle-derived eclogite xenolith suites. Firstly, the samples studied yield relatively low equilibration pressures and temperatures between 2.7 and 4.5 GPa and 740-1064 °C, indicating a relatively shallow residence between 90 and 150 km depths. Secondly, euhedral coarse amphibole is present in several eclogite nodules where it is in equilibrium with ‘touching’ garnet, supporting eclogite residence within the amphibole stability field at uppermost lithospheric mantle conditions. Thirdly, primary omphacitic clinopyroxene is often overgrown by diopside, and is significantly enriched in incompatible trace elements. The clinopyroxene is also characterized by elevated 206Pb/204Pb of 17.28-19.20 and 207Pb/204 Pb of 15.51-16.27, and these Pb isotopic compositions overlap with those of Mesozoic Group-2 kimberlites from the Kaapvaal craton. Our results show that eclogites reside at ~85 km depth beneath the central Kaapvaal craton as part of a layer that corresponds to an approximately 50 km thick seismically-detected mid-lithospheric discontinuity. Mid-lithospheric discontinuities have been interpreted as metasomatic fronts formed by focussed crystallization of hydrous mineral phases from enriched volatile-bearing melts, and as such the strongly overprinted amphibole-bearing eclogite xenoliths from Palmietfontein may represent a physical expression of such seismically anomalous metasomatic layer at mid-lithospheric depth. Our Pb isotope data suggest that the focussed metasomatism can be attributed to volatile-rich melts reminiscent of potassic Group-2 kimberlites, which have been invoked in MARID-style metasomatic overprinting of the lower lithospheric mantle beneath the western Kaapvaal craton. However, the relatively low fO2 recorded by the Palmietfontein eclogites (minimum FMQ-4.5) suggests that the metasomatism at mid-lithospheric depth was less protracted compared to the more intensive and oxidizing metasomatism typically observed near the base of cratonic mantle roots. While it is possible that Proterozoic magmatic events were responsible for the focussed mid-lithospheric metasomatism of the Kaapvaal mantle, on the basis of the Pb isotope constraints the Palmietfontein eclogites were most likely overprinted during ca. 120 Ma Group-2 kimberlite magmatism.
Abstract: Mantle-derived eclogite xenoliths are key for studying the evolution of the cratonic lithosphere, because geochemical evidence suggests that they typically represent fragments of Archean and Proterozoic oceanic lithosphere [1]. Recently, it has been suggested that eclogite xenoliths can serve as redox sensors of the Precambrian upper mantle using V/Sc as a redox proxy [2]. However, metasomatism can change the original oxidation state of the cratonic mantle [3], thereby limiting its use for monitoring mantle redox evolution. Circa 1.8–2.2 Ga eclogite xenoliths erupted with Jurassic kimberlites of the northern Slave craton have geochemical features that indicate oceanic crust protoliths [4, 5]. Such Paleoproterozoic ages are common for Slave craton mantle eclogites [6], linking eclogite formation with 1.9 Ga subduction-collision events at the western craton margin. The eclogites studied here have highly variable Fe3+/?Fe (0.019 – 0.076 ±0.01), with logfO2 (?FMQ-4 to +2 ±0.5) that are both relatively oxidized and reduced compared to Slave mantle peridotite xenoliths [3]. Also, eclogite fO2 positively correlates with some indicies of metasomatism, such as elevated TiO2 in garnet. In addition to considering the time gap between eclogite formation and kimberlite eruption, the highly variable fO2–depth systematics of the eclogites studied here illustrate the drawbacks of using averaged eclogite fO2 to define the redox evolution of the upper mantle. Despite this, the ca. 2 Ga northern Slave craton eclogites have an average depth-corrected logfO2 of ?FMQ-0.5±1.3 (1?) that overlaps with modern MORB, and complies with the upper mantle redox evolution trend predicted using V/Sc ratios of mantlederived melts [2]. However, given the debate around the secuarity of mantle redox [7], further research into the suitability of mantle eclogites as redox sensors is warranted.
Turkish Journal of Earth Sciences, Vol. 29, pp. 798-814. pdf
Europe, Turkey
REE
Abstract: In Turkey, the largest fluorine (F)-rare earth element (REE)-thorium (Th) deposits are located within the Eski?ehir-K?z?lcaören (north-western Anatolia) and the Malatya-Kuluncak (east-central Anatolia) regions, and these are associated with Oligocene extensional alkaline volcanic and Late Cretecaous-Early Paleocene postcollisional intrusive rocks, respectively. In the K?z?lcaören region, the basement units include the Triassic Karakaya Complex and the Late Cretaceous oceanic units (Neotethyan suture) that are cut and overlain by phonolite and carbonatite intrusions and lava flows. In the Kuluncak region, the plutonic rocks are mainly composed of syenite, quartz syenite, and rare monzonite, and these cut the late-Cretaceous Karap?nar limestone, which hosts the F-REE-Th mineralization in contact zones. A carbonatite sample from the K?z?lcaören region displays both a total rare earth element (TREE) concentration (4795 ppm) and ?11B (-6.83‰) isotope composition consistent with mantle-derived carbonatite; whereas it is characterized by heavier ?13C (+1.43‰) and ?18O (+20.23‰) isotope signatures compared to those for carbonatites worldwide. In contrast, the carbonates which host the F-REE-Th mineralization in the Kuluncak region are characterized by lower TREE concentrations (5.13 to 55.88 ppm), and heavier ?13C (-0.14 to -0.75‰), ?18O (+27.36 to +30.61‰), and ?11B (+5.38 to +6.89‰) isotope ratios compared to mantle-derived carbonatites. Moreover, the combined initial 87Sr/86Sr (0.70584 to 0.70759) and 143Nd/144Nd (0.512238 to 0.512571) isotope ratios for samples investigated here are distinct and much more radiogenic compared to those for carbonatites worldwide, and therefore indicate significant crustal input and/or hydrothermal metasomatic-related alteration. Overall, stable and radiogenic isotope data suggest that the host carbonate rocks for the F-REE-Th mineralization in both the K?z?lcaören and the Kuluncak regions consist of hydrothermally metasomatized carbonatite and limestone, respectively. The mineralization in the K?z?lcaören region may potentially be related to carbonatite magmatism, whereas the mineralization in the Kuluncak region, which most likely formed through interactions between the plutonic rocks and surrounding limestone at contact metamorphism zone, involved hydrothermal/magmatic fluids associated with extensive postcollisional magmatism.
Abstract: Mantle-derived eclogite and pyroxenite xenoliths from the Jurassic Voyageur kimberlite on the northern Slave craton in Arctic Canada were studied for garnet and clinopyroxene major and trace element compositions, clinopyroxene Pb and garnet O isotopic compositions, and garnet Fe3 +/?Fe contents. The Voyageur xenoliths record a wide range of pressures, but are cooler compared to mantle xenoliths derived from the nearby, coeval Jericho kimberlite. The CaO, TiO2 and Zr contents of Voyageur eclogites increase with depth, which is also observed in northern Slave peridotite xenoliths, demonstrating ‘bottom-up’ metasomatic processes within cratonic mantle lithosphere. The Voyageur eclogites have positive Eu anomalies, flat HREEN patterns, and major element compositions that are consistent with ultimate origins from basaltic and gabbroic protoliths within oceanic lithosphere. Clinopyroxene Pb isotope ratios intercept the Stacey-Kramers two-stage terrestrial Pb evolution curve at ca. 2.1 Ga, and form an array towards the host kimberlite, indicating isotopic mixing. The 2.1 Ga eclogite formation age broadly overlaps with known Paleoproterozoic subduction and collision events that occurred along the western margin of the Slave craton. Unlike the eclogites, the Voyageur pyroxenites contain garnet with distinctive fractionated HREEN, sinusoidal REE patterns of calculated bulk rocks, and clinopyroxene with 206Pb/204Pb ratios that intercept the Stacey-Kramers curve at 1.8 Ga. This suggests a distinct origin as Paleoproterozoic high-pressure mantle cumulates. However, the pyroxenite Pb isotope ratios fall within the eclogite array and could also be explained by protoliths formation at ca. 2.1 Ga followed by minor isotopic mixing during mantle metasomatism. Thus, an alternative scenario involves pyroxenite formation within the mantle section of Paleoproterozoic oceanic lithosphere followed by variable metasomatism after incorporation into cratonic mantle lithosphere. This model allows for a linked petrogenesis of the Voyageur eclogites (crust) and pyroxenites (mantle) as part of the same subducting oceanic slab. Oxygen fugacity determinations for one pyroxenite and ten eclogite xenoliths show a range of 3 log units, from ? 4.6 to ? 1.6 ?FMQ, similar to the range observed for nearby Jericho and Muskox eclogites (?FMQ ? 4.2 to ? 1.5). Importantly, the northern Slave eclogite and pyroxenite mantle components are highly heterogeneous in terms of redox state provided that they range from reduced to oxidized relative to Slave peridotite xenoliths. Moreover, the Voyageur eclogites do not exhibit any trend between oxidation state and equilibration depth, which contrasts with the downward decrease in fO2 shown by Slave and worldwide cratonic peridotite xenoliths. Our investigation of mantle eclogite and pyroxenite fO2 reinforces the important influence of recycled mafic components in upper mantle processes, because their high and variable redox buffering capacity strongly controls volatile speciation and melting relations under upper mantle conditions.
Geochimica et Cosmochimica Acta, Vol. 213, pp. 574-592.
Africa, Botswana
deposit - Orapa
Abstract: Major- and trace-element compositions of garnet and clinopyroxene, as well as 87Sr/86Sr in clinopyroxene and ?18O in garnet in eclogite and pyroxenite xenoliths from Orapa, at the western margin of the Zimbabwe craton (central Botswana), were investigated in order to trace their origin and evolution in the mantle lithosphere. Two groups of eclogites are distinguished with respect to 87Sr/86Sr: One with moderate ratios (0.7026-0.7046) and another with 87Sr/86Sr >0.7048 to 0.7091. In the former group, heavy ?18O attests to low-temperature alteration on the ocean floor, while 87Sr/86Sr correlates with indices of low-pressure igneous processes (Eu/Eu?, Mg#, Sr/Y). This suggests relatively undisturbed long-term ingrowth of 87Sr at near-igneous Rb/Sr after metamorphism, despite the exposed craton margin setting. The high-87Sr/86Sr group has mainly mantle-like ?18O and is suggested to have interacted with a small-volume melt derived from an aged phlogopite-rich metasome. The overlap of diamondiferous and graphite-bearing eclogites and pyroxenites over a pressure interval of ?3.2 to 4.9 GPa is interpreted as reflecting a mantle parcel beneath Orapa that has moved out of the diamond stability field, due to a change in geotherm and/or decompression. Diamondiferous eclogites record lower median 87Sr/86Sr (0.7039) than graphite-bearing samples (0.7064) and carbon-free samples (0.7051), suggesting that interaction with the - possibly oxidising - metasome-derived melt caused carbon removal in some eclogites, while catalysing the conversion of diamond to graphite in others. This highlights the role of small-volume melts in modulating the lithospheric carbon cycle. Compared to diamondiferous eclogites, eclogitic inclusions in diamonds are restricted to high FeO and low SiO2, CaO and Na2O contents, they record higher equilibrium temperatures and garnets have mostly mantle-like O isotopic composition. We suggest that this signature was imparted by a sublithospheric melt with contributions from a clinopyroxene-rich source, possibly related to the ca. 2.0 Ga Bushveld event.
Geochimica et Cosmochinica Acta, Vol. 213, pp. 574-592.
Africa, Botswana
deposit - Orapa
Abstract: Major- and trace-element compositions of garnet and clinopyroxene, as well as 87Sr/86Sr in clinopyroxene and ?18O in garnet in eclogite and pyroxenite xenoliths from Orapa, at the western margin of the Zimbabwe craton (central Botswana), were investigated in order to trace their origin and evolution in the mantle lithosphere. Two groups of eclogites are distinguished with respect to 87Sr/86Sr: One with moderate ratios (0.7026-0.7046) and another with 87Sr/86Sr >0.7048 to 0.7091. In the former group, heavy ?18O attests to low-temperature alteration on the ocean floor, while 87Sr/86Sr correlates with indices of low-pressure igneous processes (Eu/Eu?, Mg#, Sr/Y). This suggests relatively undisturbed long-term ingrowth of 87Sr at near-igneous Rb/Sr after metamorphism, despite the exposed craton margin setting. The high-87Sr/86Sr group has mainly mantle-like ?18O and is suggested to have interacted with a small-volume melt derived from an aged phlogopite-rich metasome. The overlap of diamondiferous and graphite-bearing eclogites and pyroxenites over a pressure interval of ?3.2 to 4.9 GPa is interpreted as reflecting a mantle parcel beneath Orapa that has moved out of the diamond stability field, due to a change in geotherm and/or decompression. Diamondiferous eclogites record lower median 87Sr/86Sr (0.7039) than graphite-bearing samples (0.7064) and carbon-free samples (0.7051), suggesting that interaction with the - possibly oxidising - metasome-derived melt caused carbon removal in some eclogites, while catalysing the conversion of diamond to graphite in others. This highlights the role of small-volume melts in modulating the lithospheric carbon cycle. Compared to diamondiferous eclogites, eclogitic inclusions in diamonds are restricted to high FeO and low SiO2, CaO and Na2O contents, they record higher equilibrium temperatures and garnets have mostly mantle-like O isotopic composition. We suggest that this signature was imparted by a sublithospheric melt with contributions from a clinopyroxene-rich source, possibly related to the ca. 2.0 Ga Bushveld event.
Geochimica et Cosmochimica Acta, Vol. 213, 1, pp. 574-592.
Africa, Botswana
deposit - Orapa
Abstract: Major- and trace-element compositions of garnet and clinopyroxene, as well as 87Sr/86Sr in clinopyroxene and ?18O in garnet in eclogite and pyroxenite xenoliths from Orapa, at the western margin of the Zimbabwe craton (central Botswana), were investigated in order to trace their origin and evolution in the mantle lithosphere. Two groups of eclogites are distinguished with respect to 87Sr/86Sr: One with moderate ratios (0.7026-0.7046) and another with 87Sr/86Sr >0.7048 to 0.7091. In the former group, heavy ?18O attests to low-temperature alteration on the ocean floor, while 87Sr/86Sr correlates with indices of low-pressure igneous processes (Eu/Eu?, Mg#, Sr/Y). This suggests relatively undisturbed long-term ingrowth of 87Sr at near-igneous Rb/Sr after metamorphism, despite the exposed craton margin setting. The high-87Sr/86Sr group has mainly mantle-like ?18O and is suggested to have interacted with a small-volume melt derived from an aged phlogopite-rich metasome. The overlap of diamondiferous and graphite-bearing eclogites and pyroxenites over a pressure interval of ?3.2 to 4.9 GPa is interpreted as reflecting a mantle parcel beneath Orapa that has moved out of the diamond stability field, due to a change in geotherm and/or decompression. Diamondiferous eclogites record lower median 87Sr/86Sr (0.7039) than graphite-bearing samples (0.7064) and carbon-free samples (0.7051), suggesting that interaction with the - possibly oxidising - metasome-derived melt caused carbon removal in some eclogites, while catalysing the conversion of diamond to graphite in others. This highlights the role of small-volume melts in modulating the lithospheric carbon cycle. Compared to diamondiferous eclogites, eclogitic inclusions in diamonds are restricted to high FeO and low SiO2, CaO and Na2O contents, they record higher equilibrium temperatures and garnets have mostly mantle-like O isotopic composition. We suggest that this signature was imparted by a sublithospheric melt with contributions from a clinopyroxene-rich source, possibly related to the ca. 2.0 Ga Bushveld event.
Abstract: The Miaoya carbonatite complex (MCC) is located within the southern edge of the Qinling orogenic belt in central China, and is associated with significant rare earth element (REE) and Nb mineralization. The MCC consists of syenite and carbonatite that were emplaced within Neo- to Mesoproterozoic-aged supracrustal units. The carbonatite intruded the associated syenite as stocks and dikes, and is mainly composed of medium- to fine-grained calcite and abundant REE-bearing minerals. Carbonatite melt generation and emplacement within the MCC occurred during the Silurian (at ~440?Ma), and was subsequently impacted by a late-stage hydrothermal event (~232?Ma) involving REE-rich fluids/melt. This study reports trace element and stable (B, C, and O) and radiogenic (Nd, Pb, and Sr) isotope data for the MCC carbonatite, and these have been subdivided into three groups that represent different REE contents, interpreted as varying degrees of hydrothermal interaction. Overall, the group of carbonatites with the lowest enrichment in LREEs (i.e., least affected by hydrothermal event) is characterized by ?11B values that vary between ?7 (typical asthenospheric mantle) and?+?4‰; ?11B values and B abundances (~0.2 to ~1?ppm) do not correlate with LREE contents. The Sm-Nd and Pb-Pb isotope systems have both been perturbed by the late-stage, REE-rich hydrothermal activity and corroborate open-system behavior. Contrarily, initial 87Sr/86Sr ratios (vary between ~0.70355 and 0.70385) do not correlate significantly with both LREEs and Sr abundances, nor with initial 143Nd/144Nd ratios. The late-stage hydrothermal event overprinted the Nd and Pb isotope compositions for most of the carbonatite samples examined here, whereas a majority of the samples preserve their variable B and Sr isotope values inherited from their mantle source. The B and Sr isotope data for carbonatites exhibiting the least LREE enrichment correlate positively and suggest carbonatite melt generation from a heterogenous upper mantle source that records the input of recycled crustal material. This finding is consistent with those previously reported for young (<300?Ma old) carbonatites worldwide.
Abstract: This study reports the combined major, minor and trace element compositions, and stable (C, O), radiogenic (Nd, Pb, and Sr) isotopic compositions, and first ?11B isotopic data for the Fir, Felix, Gum, and Howard Creek carbonatites from the Blue River Region, British Columbia (Canada). These sill-like occurrences were intruded into Late Proterozoic strata during rifting and extensional episodes during the Late Cambrian and Devonian -Mississippian, and subsequently deformed and metamorphosed to amphibolite grade in relation to a collisional-type tectonic environment. The carbonatites at Fir, Gum, and Felix contain both calcite and dolomite, whereas the carbonatite at Howard Creek contains only calcite. The dolomite compositions reported here are consistent with those experimentally determined by direct partial melting of metasomatized peridotitic mantle. The combined major and trace element compositions and ?13CPDB (?5.37 to ?4.85‰) and ?18OSMOW (9.14 to 9.62‰) values for all the samples investigated are consistent with those for primary igneous carbonate and support their mantle origin. However, these signatures cannot be attributed to closed system melt differentiation from a single parental melt. The initial Nd, Pb, and Sr isotopic ratios are highly variable and suggest generation from multiple, small degree parental melts derived from a heterogeneous mantle source. The ?11B values for carbonates from Felix, Gum, and Howard Creek vary between ?8.67 and ?6.36‰, and overlap the range for asthenospheric mantle (?7.1?±?0.9‰), whereas two samples from Fir yield heavier values of ?3.98 and ?2.47‰. The latter indicate the presence of recycled crustal carbon in their mantle source region, which is consistent with those for young (<300?Ma) carbonatites worldwide. The radiogenic and B isotope results for the Blue River carbonatites are compared to those from contrasting, anorogenic tectonic settings at Chipman Lake, Fen, and Jacupiranga, and indicate that similar upper mantle sources are being tapped for carbonatite melt generation. The pristine, mantle-like ?11B values reported here for the Blue River carbonatites clearly demonstrate that this isotope system is robust and was not perturbed by post-solidification tectono-metamorphic events. This observation indicates that B isotope signatures are a valuable tool for deciphering the nature of the upper mantle sources for carbonates of igneous origin.
Chemical Geology, doi.org/10.1016/j.chemgeo.2019.07.015 59p.
Canada, British Columbia
carbonatite - Blue River
Abstract: This study reports the combined major, minor and trace element compositions, and stable (C, O), radiogenic (Nd, Pb, and Sr) isotopic compositions, and first ?11B isotopic data for the Fir, Felix, Gum, and Howard Creek carbonatites from the Blue River Region, British Columbia (Canada). These sill-like occurrences were intruded into Late Proterozoic strata during rifting and extensional episodes during the Late Cambrian and Devonian -Mississippian, and subsequently deformed and metamorphosed to amphibolite grade in relation to a collisional-type tectonic environment. The carbonatites at Fir, Gum, and Felix contain both calcite and dolomite, whereas the carbonatite at Howard Creek contains only calcite. The dolomite compositions reported here are consistent with those experimentally determined by direct partial melting of metasomatized peridotitic mantle. The combined major and trace element compositions and ?13CPDB (?5.37 to ?4.85‰) and ?18OSMOW (9.14 to 9.62‰) values for all the samples investigated are consistent with those for primary igneous carbonate and support their mantle origin. However, these signatures cannot be attributed to closed system melt differentiation from a single parental melt. The initial Nd, Pb, and Sr isotopic ratios are highly variable and suggest generation from multiple, small degree parental melts derived from a heterogeneous mantle source. The ?11B values for carbonates from Felix, Gum, and Howard Creek vary between ?8.67 and ?6.36‰, and overlap the range for asthenospheric mantle (?7.1?±?0.9‰), whereas two samples from Fir yield heavier values of ?3.98 and ?2.47‰. The latter indicate the presence of recycled crustal carbon in their mantle source region, which is consistent with those for young (<300?Ma) carbonatites worldwide. The radiogenic and B isotope results for the Blue River carbonatites are compared to those from contrasting, anorogenic tectonic settings at Chipman Lake, Fen, and Jacupiranga, and indicate that similar upper mantle sources are being tapped for carbonatite melt generation. The pristine, mantle-like ?11B values reported here for the Blue River carbonatites clearly demonstrate that this isotope system is robust and was not perturbed by post-solidification tectono-metamorphic events. This observation indicates that B isotope signatures are a valuable tool for deciphering the nature of the upper mantle sources for carbonates of igneous origin.
Cimen, O., Corcoran, L., Kuebler, C., Simonetti, S.S., Simonetti, A.
Geochemical, stable ( O, C, and B) and radiogenic ( Sr, Nd, Pb) isotopic data from the Eskisehir-Kizulxaoren ( NW-Anatolia) and the Malatya-Kuluncak ( E- central Anatolia) F-REE-Th deposits, Turkey: implications for nature of carbonate-hosted mineralizati
Turkish Journal of Earth Sciences, Vol. 29, doe:10.3906/yer-2001-7 18p. Pdf
Abstract: Knowledge of the Guiana Shield evolution during the Gondwana break-up is key to a better understanding of craton dynamics and margin response to transtensional opening. To improve this knowledge, we investigated the dynamics and thermal evolution of French Guiana, using several low-temperature thermochronology methods applied to basement rocks, including apatite and zircon (U-Th)/He and apatite fission tracks. Inverse modelling of results allows us to reconstruct the Phanerozoic thermal history of French Guiana margin and to give a preview of the Guiana Shield evolution. Three main events are inferred: firstly, a long-term period of relative stability since ~1.2 Ga, with no strong evidence for any erosional or burial event (>5-7 km); secondly, a heating phase between ~210 and ~140 Ma consistent with the Central Atlantic Magmatic Province-related event. Finally, an exhumation phase between ~140 and ~90 Ma, triggered by the Equatorial Atlantic opening, brought samples close to the surface (<40°C).
Russian Journal of Pacific Geology, Vol. 11, 6, pp. 447-468.
Russia
picrites
Abstract: A great volume of original information on the formation of the ultrabasic rocks of the Siberian Platform has been accumulated owing to the study of melt inclusions in Cr-spinels. The inclusions show the general tendencies in the behavior of the magmatic systems during the formation of the ultrabasic massifs of the Siberian Platform, tracing the main evolution trend of decreasing Mg number with SiO2 increase in the melts with subsequent transition from picrites through picrobasalts to basalts. The compositions of the melt inclusions indicate that the crystallization conditions of the rocks of the concentrically zoned massifs (Konder, Inagli, Chad) sharply differ from those of the Guli massif. Numerical modeling using the PETROLOG and PLUTON softwares and data on the composition of inclusions in Cr-spinels yielded maximum crystallization temperatures of the olivines from the dunites of the Konder (1545-1430°C), Inagli (1530-1430°C), Chad (1460-1420°C), and Guli (1520-1420°C) massifs, and those of Cr-spinels from the Konder (1420-1380°C), Inagli (up to 1430°C), Chad (1430-1330°C), and Guli (1410-1370°C) massifs. Modeling of the Guli massif with the PLUTON software using the compositions of the melt inclusions revealed the possible formation of the alkaline rocks at the final reverse stage of the evolution of the picritic magmas (with decrease of SiO2 and alkali accumulation) after termination of olivine crystallization with temperature decrease from 1240-1230°C to 1200-1090°C. Modeling with the PLUTON software showed that the dunites of the Guli massif coexisted with Fe-rich (with moderate TiO2 contents) melts, the crystallization of which led (beginning from 1210°C) to the formation of pyroxenes between cumulate olivine. Further temperature decrease (from 1125°C) with decreasing FeO and TiO2 contents provided the formation of clinopyroxenes of pyroxenites. For the Konder massif, modeling with the PLUTON software indicates the possible formation of kosvites from picrobasaltic magmas beginning from 1350°C and the formation of clinopyroxenites and olivine-diopside rocks from olivine basaltic melts from 1250°C.
Abstract: 40Ar/39Ar analysis showed a simultaneous (at about 490 Ma) formation of the Paleozoic picrite and basalt complexes of the West Siberian Plate basement. The petrochemistry, trace and REE geochemistry, and composition of clinopyroxene indicate the formation of the picrite of well no. 11 (Chkalov area) as a result of intraplate magmatism of the OIB type. Calculations based on the compositions of clinopyroxene allowed crystallization of minerals of porphyric picrite at 1215-1275°C and 4.5-8 kbar. In general, it has been found that the picrite basalt complexes considered were formed from enriched igneous plume systems under intraplate conditions near the active margin of the ancient ocean.
Abstract: Experimental studies of phase relations in the oxide-silicate system MgO-FeO-SiO2 at 24 GPa show that the peritectic reaction of bridgmanite controls the formation of stishovite as a primary in situ mineral of the lower mantle and as an effect of the stishovite paradox. The stishovite paradox is registered in the diamond-forming system MgO-FeO-SiO2-(Mg-Fe-Ca-Na carbonate)-carbon in experiments at 26 GPa as well. The physicochemical mechanisms of the ultrabasic-basic evolution of deep magmas and diamondforming media, as well as their role in the origin of the lower mantle minerals and genesis of ultradeep diamonds, are studied.
Geochemistry International, Vol. 57, 9, pp. 1000-1007.
Mantle
diamond genesis
Abstract: The peritectic reaction of ringwoodite (Mg,Fe)2SiO4 and silicate-carbonate melt with formation of magnesiowustite (Fe,Mg)O, stishovite SiO2, and Mg, Na, Ca, K-carbonates is revealed by experimental study at 20 GPa of phase relations in the multicomponent diamond-forming MgO-FeO-SiO2-Na2CO3-CaCO3-K2CO3 system of the Earth mantle transition zone. An interaction of CaCO3 and SiO2 with a formation of Ca-perovskite CaSiO3 is also detected. It is shown that the peritectic reaction of ringwoodite and melt with the formation of stishovite controls physicochemically the fractional ultrabasic-basic evolution of both magmatic and diamond-forming systems of deep horizons of the transition zone up to its boundary with the Earth lower mantle.
GEM: International Journal on Geomathematics, open access 38p. Pdf
Mantle
geophysics - magnetics
Abstract: We discuss the resolving power of three geophysical imaging and inversion techniques, and their combination, for the reconstruction of material parameters in the Earth’s subsurface. The governing equations are those of Newton and Poisson for gravitational problems, the acoustic wave equation under Hookean elasticity for seismology, and the geodynamics equations of Stokes for incompressible steady-state flow in the mantle. The observables are the gravitational potential, the seismic displacement, and the surface velocity, all measured at the surface. The inversion parameters of interest are the mass density, the acoustic wave speed, and the viscosity. These systems of partial differential equations and their adjoints were implemented in a single Python code using the finite-element library FeNICS. To investigate the shape of the cost functions, we present a grid search in the parameter space for three end-member geological settings: a falling block, a subduction zone, and a mantle plume. The performance of a gradient-based inversion for each single observable separately, and in combination, is presented. We furthermore investigate the performance of a shape-optimizing inverse method, when the material is known, and an inversion that inverts for the material parameters of an anomaly with known shape.
Geological Society of America Special Paper, No. 514, pp. SPE514-08.
Mantle
Hotspots
Abstract: Thorne et al. (2004), Torsvik et al. (2010; 2006) and Burke et al. (2008) have suggested that the locations of melting anomalies ("hot spots") and the original locations of large igneous provinces ("LIPs") and kimberlite pipes, lie preferentially above the margins of two "large lower-mantle shear velocity provinces", or LLSVPs, near the bottom of the mantle, and that the geographical correlations have high confidence levels (> 99.9999%) (Burke et al., 2008, Fig. 5). They conclude that the LLSVP margins are "Plume-Generation Zones", and that deep-mantle plumes cause hot spots, LIPs, and kimberlites. This conclusion raises questions about what physical processes could be responsible, because, for example, the LLSVPs are apparently dense and not abnormally hot (Trampert et al., 2004). The supposed LIP-hot spot-LLSVP correlations probably are examples of the "Hindsight Heresy" (Acton, 1959), of performing a statistical test using the same data sample that led to the initial formulation of a hypothesis. In this process, an analyst will consider and reject many competing hypotheses, but will not adjust statistical assessments correspondingly. Furthermore, an analyst will test extreme deviations of the data, , but not take this fact into account. "Hindsight heresy" errors are particularly problematical in Earth science, where it often is impossible to conduct controlled experiments. For random locations on the globe, the number of points within a specified distance of a given curve follows a cumulative binomial distribution. We use this fact to test the statistical significance of the observed hot spot-LLSVP correlation using several hot-spot catalogs and mantle models. The results indicate that the actual confidence levels of the correlations are two or three orders of magnitude smaller than claimed. The tests also show that hot spots correlate well with presumably shallowly rooted features such as spreading plate boundaries. Nevertheless, the correlations are significant at confidence levels in excess of 99%. But this is confidence that the null hypothesis of random coincidence is wrong. It is not confidence about what hypothesis is correct. The correlations probably are symptoms of as-yet-unidentified processes.
Recovery Plant Practice at de Beers Consolidated Mines Limited, Kimberley with Particular Reference to Improvements Made for the Sorting of the Final Concentrates.
South African Institute of Mining and Metallurgy. Journal, Vol. 80, No. 9, PP. 317-328.
Short hold time parameters. Diavik mine water treatment plant.
2018 Yellowknife Geoscience Forum , p. 74-75. abstract
Canada, Northwest Territories
deposit - Diavik
Abstract: It is well known that it is very difficult to transport samples from remote locations to the laboratory and allow sufficient time to commence analysis within the prescribed short hold times for certain parameters. Also, the majority of published hold times are based on legacy as opposed to hard science. In an attempt to determine the validity of specific short hold times, a joint study between Diavik and Maxxam was undertaken. The purpose was to determine the stability of short hold time parameters over time using real samples from Diavik sites. Data from two sites will be presented. The first from the Diavik mine water treatment plant influent, which had relatively high levels of the target analytes. The second from a lake water sample with lower native levels of the target analytes. The parameters studied were ammonia (preserved and unpreserved), total nitrogen, nitrite, nitrate, phosphate, total phosphorus and turbidity. All target parameters have a prescribed 3-day hold time.1 pH was also monitored. Samples were collected by Diavik personnel in one-litre containers and extraordinary logistical measures were taken to get them to Maxxam's Burnaby laboratory as soon as possible. On receipt, they were immediately subsampled into appropriate containers. Each parameter (except pH and turbidity) was split into three containers: 1) as received; 2) low level spike added and 3) medium level spike added. All samples were analyzed within 3 at approximately 3-day intervals thereafter for a period of two weeks.
Kimberlite indicator minerals in southwestern Saskatchewan
Mid-continent diamonds Geological Association of Canada (GAC)-Mineralogical Association of Canada (MAC) Symposium ABSTRACT volume, held Edmonton May, pp. 53-58.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 359-378.
Abstract: The use of drones in mining environments is one way in which data pertaining to the state of a site in various industries can be remotely collected. This paper proposes a combined system that employs a 6-bands multispectral image capturing camera mounted on an Unmanned Aerial Vehicle (UAV) drone, Spectral Angle Mapping (SAM), as well as Artificial Intelligence (AI). Depth possessing multispectral data were captured at different flight elevations. This was in an attempt to find the best elevation where remote identification of magnetite iron sands via the UAV drone specialized in collecting spectral information at a minimum accuracy of +/? 16 nm was possible. Data were analyzed via SAM to deduce the cosine similarity thresholds at each elevation. Using these thresholds, AI algorithms specialized in classifying imagery data were trained and tested to find the best performing model at classifying magnetite iron sand. Considering the post flight logs, the spatial area coverage of 338 m2, a global classification accuracy of 99.7%, as well the per-class precision of 99.4%, the 20 m flight elevation outputs presented the best performance ratios overall. Thus, the positive outputs of this study suggest viability in a variety of mining and mineral engineering practices.
Short hold time parameters. Diavik mine water treatment plant.
2018 Yellowknife Geoscience Forum , p. 74-75. abstract
Canada, Northwest Territories
deposit - Diavik
Abstract: It is well known that it is very difficult to transport samples from remote locations to the laboratory and allow sufficient time to commence analysis within the prescribed short hold times for certain parameters. Also, the majority of published hold times are based on legacy as opposed to hard science. In an attempt to determine the validity of specific short hold times, a joint study between Diavik and Maxxam was undertaken. The purpose was to determine the stability of short hold time parameters over time using real samples from Diavik sites. Data from two sites will be presented. The first from the Diavik mine water treatment plant influent, which had relatively high levels of the target analytes. The second from a lake water sample with lower native levels of the target analytes. The parameters studied were ammonia (preserved and unpreserved), total nitrogen, nitrite, nitrate, phosphate, total phosphorus and turbidity. All target parameters have a prescribed 3-day hold time.1 pH was also monitored. Samples were collected by Diavik personnel in one-litre containers and extraordinary logistical measures were taken to get them to Maxxam's Burnaby laboratory as soon as possible. On receipt, they were immediately subsampled into appropriate containers. Each parameter (except pH and turbidity) was split into three containers: 1) as received; 2) low level spike added and 3) medium level spike added. All samples were analyzed within 3 at approximately 3-day intervals thereafter for a period of two weeks.
Abstract: The geochemical evolution of mine-waste rock often includes concurrent acid generation and neutralization processes. Deposition of mine-waste rock in large, oxygenated, and partially saturated piles can result in release of metals and decreased pH from weathering of sulfide minerals. Acid neutralization processes can often mitigate metals and pH impacts associated with sulfide oxidation. The Diavik Waste Rock Project included large field experiments (test piles built in 2006) conducted to characterize weathering of sulfide waste rock at a scale representative of full size waste-rock piles. Water samples from the unsaturated interior of one of the test piles, constructed of waste rock with ~0.05 wt.% S, were collected using soil water solution samplers and drains at the base of the pile. Field observations indicated pH decreased throughout the depth of the pile during 2008 and 2009 and that carbonate mineral buffering was entirely depleted by 2011 or 2012. Carbonate mineral exhaustion was accompanied by increased concentrations of dissolved Al and Fe in effluent samples collected at the basal drains. These results suggest that dissolution of Al and Fe(oxy)hydroxides occurred after the depletion of carbonate minerals following an acid neutralization sequence that is similar to observations made by previous researchers. A conceptual model of acid neutralization proceses within the pile, developed using physical and geochemical measurements conducted from 2008 to 2012, was used to inform reactive transport simulations conducted in 2017 to quantify the dominant acid neutralization processes within the test pile interior. Reactive transport simulations indicate that the conceptual model developed using the results of field samples provides a reasonable assessment of the evolution of the acid neutralization sequence.
International Journal of Earth Sciences, in press available 17p.
Africa, Namibia
Alkaline rocks
Abstract: Rb-Sr whole-rock and mineral isotope data from nepheline syenite, tinguaite, and carbonatite samples of the Kalkfeld Complex within the Damaraland Alkaline Province, NW Namibia, indicate a date of 242?±?6.5 Ma. This is interpreted as the age of final magmatic crystallization in the complex. The geological position of the complex and the spatially close relationship to the Lower Cretaceous Etaneno Alkaline Complex document a repeated channeling of small-scale alkaline to carbonatite melt fractions along crustal fractures that served as pathways for the mantle-derived melts. This is in line with Triassic extensional tectonic activity described for the nearby Omaruru Lineament-Waterberg Fault system. The emplacement of the Kalkfeld Complex more than 100 Ma prior to the Paraná-Etendeka event and the emplacement of the Early Cretaceous Damaraland intrusive complexes excludes a genetic relationship to the Tristan Plume. The initial ?Sr-?Nd pairs of the Kalkfeld rocks are typical of younger African carbonatites and suggest a melt source, in which EM I and HIMU represent dominant components.
International Journal of Earth Sciences, Vol. 106, pp. 2797-2813.
Africa, Namibia
carbonatites
Abstract: Rb-Sr whole-rock and mineral isotope data from nepheline syenite, tinguaite, and carbonatite samples of the Kalkfeld Complex within the Damaraland Alkaline Province, NW Namibia, indicate a date of 242?±?6.5 Ma. This is interpreted as the age of final magmatic crystallization in the complex. The geological position of the complex and the spatially close relationship to the Lower Cretaceous Etaneno Alkaline Complex document a repeated channeling of small-scale alkaline to carbonatite melt fractions along crustal fractures that served as pathways for the mantle-derived melts. This is in line with Triassic extensional tectonic activity described for the nearby Omaruru Lineament-Waterberg Fault system. The emplacement of the Kalkfeld Complex more than 100 Ma prior to the Paraná-Etendeka event and the emplacement of the Early Cretaceous Damaraland intrusive complexes excludes a genetic relationship to the Tristan Plume. The initial ?Sr-?Nd pairs of the Kalkfeld rocks are typical of younger African carbonatites and suggest a melt source, in which EM I and HIMU represent dominant components.
International Journal of Earth Sciences, Vol. 106, 8, pp. 2797-2813.
Africa, Namibia
carbonatite
Abstract: Rb-Sr whole-rock and mineral isotope data from nepheline syenite, tinguaite, and carbonatite samples of the Kalkfeld Complex within the Damaraland Alkaline Province, NW Namibia, indicate a date of 242 ± 6.5 Ma. This is interpreted as the age of final magmatic crystallization in the complex. The geological position of the complex and the spatially close relationship to the Lower Cretaceous Etaneno Alkaline Complex document a repeated channeling of small-scale alkaline to carbonatite melt fractions along crustal fractures that served as pathways for the mantle-derived melts. This is in line with Triassic extensional tectonic activity described for the nearby Omaruru Lineament-Waterberg Fault system. The emplacement of the Kalkfeld Complex more than 100 Ma prior to the Paraná-Etendeka event and the emplacement of the Early Cretaceous Damaraland intrusive complexes excludes a genetic relationship to the Tristan Plume. The initial ?Sr-?Nd pairs of the Kalkfeld rocks are typical of younger African carbonatites and suggest a melt source, in which EM I and HIMU represent dominant components.
Abstract: Magmatic pulses in intraplate sedimentary Basins are windows to understand the tectonomagmatic evolution and paleaoposition of the Basin. The present study reports the U-Pb zircon ages of mafic flows from the Cuddapah Basin and link these magmatic events with the Pangean evolution during late Carboniferous-Triassic/Phanerozoic timeframe. Zircon U-Pb geochronology for the basaltic lava flows from Vempalle Formation, Cuddapah Basin suggests two distinct Phanerozoic magmatic events coinciding with the amalgamation and dispersal stages of Pangea at 300 Ma (Late Carboniferous) and 227 Ma (Triassic). Further, these flows are characterized by analogous geochemical and geochronological signatures with Phanerozoic counterparts from Siberian, Panjal Traps, Emeishan and Tarim LIPs possibly suggesting their coeval and cogenetic nature. During the Phanerozoic Eon, the Indian subcontinent including the Cuddapah Basin was juxtaposed with the Pangean LIPs which led to the emplacement of these pulses of magmatism in the Basin coinciding with the assemblage of Pangea and its subsequent breakup between 400 Ma and 200 Ma.
Abstract: Investigation of large scale suture zones in old continental interiors offers insights into the evolution of continents. The Dharwar Craton (DC) and the Southern Granulite Terrain(SGT) of the Indian shield represent large segments of Precambrian middle to lower crust and preserve a geological record spanning from Mesoarchean to Cambrian. This study illuminates the deep structure of the Palghat-Cauvery Shear Zone System (PCSS) and the Palghat-Cauvery Suture Zone (PCSZ) that comprise crustal-scale structures related to multiple episodes of orogeny, crust formation and reworking. We utilize here 3202 high quality P-receiver functions computed using new data from a 23 station seismic network operated by us. Results show a thick (>38?km) mafic (Poisson's ratio >0.25) crust beneath the SGT. The change in crustal thickness is gradual, with a shallower Moho towards the south of PCSZ. We found little evidence for drastic changes in crustal thickness across prominent shear zones like the PCSZ and Moyar-Bhavani. Few seismic stations located along these boundaries have shown evidence for dipping reflectors around 8-20?km depth, with strikes matching well with the trends of surface geological sutures. We opine that these suture zones do not show indications of a terrane boundary. However, a drastic change in the crustal thickness is observed around the prograde metamorphic transition zone or broadly, the "Fermor line", which separates rocks of Chanockitic (Orthopyroxene bearing granitoid) and non-Charnockitic (Orthopyroxene-free granitoid) mineral assemblage, further north beneath the DC. We suggest that thicknening of crust north of Moyar-Attur Shear Zone (MASZ) and around Fermor line is related to subduction processes operative during the Precambrian.
Abstract: Investigation of large scale suture zones in old continental interiors offers insights into the evolution of continents. The Dharwar Craton (DC) and the Southern Granulite Terrain(SGT) of the Indian shield represent large segments of Precambrian middle to lower crust and preserve a geological record spanning from Mesoarchean to Cambrian. This study illuminates the deep structure of the Palghat-Cauvery Shear Zone System (PCSS) and the Palghat-Cauvery Suture Zone (PCSZ) that comprise crustal-scale structures related to multiple episodes of orogeny, crust formation and reworking. We utilize here 3202 high quality P-receiver functions computed using new data from a 23 station seismic network operated by us. Results show a thick (>38?km) mafic (Poisson's ratio >0.25) crust beneath the SGT. The change in crustal thickness is gradual, with a shallower Moho towards the south of PCSZ. We found little evidence for drastic changes in crustal thickness across prominent shear zones like the PCSZ and Moyar-Bhavani. Few seismic stations located along these boundaries have shown evidence for dipping reflectors around 8-20?km depth, with strikes matching well with the trends of surface geological sutures. We opine that these suture zones do not show indications of a terrane boundary. However, a drastic change in the crustal thickness is observed around the prograde metamorphic transition zone or broadly, the “Fermor line”, which separates rocks of Chanockitic (Orthopyroxene bearing granitoid) and non-Charnockitic (Orthopyroxene-free granitoid) mineral assemblage, further north beneath the DC. We suggest that thicknening of crust north of Moyar-Attur Shear Zone (MASZ) and around Fermor line is related to subduction processes operative during the Precambrian.
Abstract: We analyzed satellite gravity and geoid anomaly and topography data to determine the 3D lithospheric density structure of the Singhbhum Protocontinent. Our density model shows that distinct vertical density heterogeneities exist throughout the lithosphere beneath the Singhbhum Protocontinent. The crustal structure identified includes a lateral average crustal density variation from 2800 to 2890 kg/m3 as well as a relatively flat Moho at 35-40 km depth in Singhbhum Protocontinent and Bastar Craton. A similar Moho depth range is found for the Mahanadi, Damodar, and Bengal basins. In the northern part of the area, Moho undulates between more than 40 km under the confluence of Mahanadi-Damodar Gondwana basins and the Ganga foreland basin, and 36-32 km under the Eastern Ghats Mobile belt and finally reaches 24 km in the Bay of Bengal. The lithosphere-asthenosphere boundary (LAB) across the Singhbhum Protocontinent is at a depth of about 130-140 km. In the regions of Bastar Craton and Bengal Basin, the LAB dips to about 155 ± 5 km depth. The confluence of Mahanadi and Damodar Gondwana basins toward the north-west and the foreland Ganga Basin toward the north are characterized by a deeper LAB lying at a depth of over 170 and 200 km, respectively. In the Bay of Bengal, the LAB is at a shallower depth of about 100-130 km except over the 85 0E ridge (150 km), and off the Kolkata coast (155 km). Significant density variation as well as an almost flat crust-mantle boundary indicates the effect of significant crustal reworking. The thin (135-140 km) lithosphere provides compelling evidence of lithospheric modification in the Singhbhum Protocontinent. Similarities between the lithospheric structures of the Singhbhum Craton, Chhotanagpur Gneiss Complex, and Northern Singhbhum Mobile Belt confirm that the repeated thermal perturbation controlled continental lithospheric modification in the Singhbhum Protocontinent.
Abstract: The eastern Indian shield consists of Archaean Singhbhum Craton and Proterozoic Chhotanagpur Gneissic Complex sandwiching the Singhbhum Mobile Belt. Since the cratonization of the Singhbhum Craton in Archaean, the growth of the eastern Indian shield took place in time and space through tectono-magmatic processes. The stability of cold and thick lithosphere is fundamental to long-term survival of cratons, whereas the geophysical studies have detected the lithosphere-asthenosphere boundary (LAB) under the eastern Indian shield at depths too shallow to be called stable. We analysed the terrestrial Bouguer gravity anomaly, and satellite-based free-air anomaly, geoid undulation, and elevation data to ascertain the 2D lithospheric density structure across the region. Our density model illustrates that the density inhomogeneity exists in the crust across the three tectonic domains of the eastern Indian shield. The derived crustal model shows an upper and lower crustal density variation from 2740 to 2770 kg/m3, and from 2930 to 2940 kg/m3, respectively, and a reasonably smooth Moho at 37-41 km depth. Towards the north, the Moho undulates from 40 to 43 km under the foreland Ganga basin, whereas in the south, it varies from 38 to 30 km under the Eastern Ghats Mobile Belt and lastly moves to ~20 km in the Bay of Bengal. In the southern part of the Singhbhum Craton, an undissipated lithospheric mantle root is found at a depth of ~150 km. Otherwise, the LAB shallows to ~132 km in the northern Singhbhum Craton and Singhbhum Mobile Belt and then thickens to about 135-140 km depth beneath the Chhotanagpur Gneissic Complex. The foreland Ganga basin toward the extreme north is characterized by a more in-depth LAB lying at a depth of over 200 km. The LAB, in the Bay of Bengal, is at a depth of 112-125 km, except for the Kolkata coast (135 km). Moderate crustal density difference in various crustal domains, as well as an almost smooth crust-mantle boundary at 37-40 km depth, suggests the effect of substantial mafic-ultramafic crustal intrusion and together with the thin (135-140 km) lithosphere reinforces the evidence of thermo-chemical processes that controlled the lithospheric modification in the eastern Indian shield.
Abstract: The Singhbhum craton is among the five Archean cratons of Peninsular India that preserves some of the oldest continental nuclei. In this work, we present a new and complete Bouguer gravity map of this craton with insights into its deep crust-mantle structure, lithospheric thickness and density variations beneath this craton. The conspicuous presence of high-order residual gravity low anomalies, together with low estimated densities, suggests voluminous presence of Singhbhum granitic batholiths that built the dominant crustal architecture. The isolated residual gravity highs correspond to the mafic and ultramafic volcanic suites like, Dhanjori, Simlipal and Dalma, while the relatively low gravity anomalies observed over the western volcanic suites like Malangtoli, Jagannathpur and Ongarbira, indicate their relatively felsic nature. The estimated lithospheric thickness of about ~ 130 km below the granitic batholithic region, and about 112 km beneath the Precambrian volcanic terranes, together with low effective elastic thickness (Te,) of only about 31 km, suggest a thin and weak lithosphere. The craton witnessed extensive lithospheric destruction with the removal of nearly 100-150 km of the cratonic root. The decratonization may be linked to subduction during the Paleo-Mesoproterozoic period, together with mantle plumes at different times, suggesting a combined mechanical, thermal and chemical erosion of the cratonic keel.
Abstract: In ore processing, electric-pulse disaggregation (EPD) is used for the liberation of mineral crystals from host rocks. Since 2019, EPD technology has been used exclusively to recover emeralds produced from the Kagem mine in Zambia. This article compares the differences in the recovery of emeralds from micaceous schist host rock at the Kagem mine by EPD technology versus the conventional hand-cobbing method. The amount of emeralds obtained using both methods was similar, but EPD had numerous advantages in terms of liberation speed, ease of performing the process and the characteristics of the liberated emeralds.
Journal of Geological Society of India, Vol. 96, 3, pp. 239-249. pdf
India
craton
Abstract: Dharwar craton (DC), by far the largest geological domain in South Indian Shield, occupying about 0.5 million sq. km area, is well-studied terrain both for regional geoscientific aspects and as part of mineral exploration over several important blocks such as the greenstone belts, ultramafic complexes, granite-gneissic terrain and the Proterozoic sediments of Cuddapah basin. The re-look into regional gravity data offers several insights into nature of crust, sub-divisions within the craton, bedrock geology in the covered areas and mineral potentiality of this ancient and stable crust. The regional gravity profiles drawn across the south Indian region mainly suggest that the area can be divided into five domains as Western Dharwar craton (WDC), Central Dharwar craton (CDC), Eastern Dharwar craton (EDC 1), transitory zone of EDC (EDC 2) and Eastern Ghats mobile belt (EGMB) areas. The Bouguer gravity anomaly pattern also questions some of the earlier divisions like eastern margin of Chitradurga schist belt between the WDC and EDC and the boundary of DC with southern granulite terrain (SGT) as they do not restrict at these main boundaries. In this study, mainly four issues are addressed by qualitative and quantitative analysis of regional gravity data and those revealed significant inferences. (1) A distinct gravity character in central part of south Indian shield area occupying about 60, 000 sq. km, suggests that the transitory crustal block, faulted on both sides and uplifted. This area designated as central Dharwar craton (CDC) is characterized with schist belts having characters of both parts of western and eastern Dharwar craton. This inference also opens up the debate about the boundary between western and eastern parts of the craton. Another significant inference is the extension of major schist belts beneath both Deccan volcanic province (DVP) in northwestern part and Cuddapah basin (CB) in southeastern part. (2) Eastern Dharwar craton is reflected as two distinct domains of different gravity characters; one populated with number of circular gravity lows and a few linear gravity high closures indicative of plutonic and volcanic activity and another domain devoid of these intrusive younger granites or schist belts. (3) Large wave length gravity highs occupying thousands of sq.km area and those not relatable to surface geology in eastern Dharwar craton that may have significance for mineral exploration. (4) Gravity data was subjected to further processing like two dimensional modeling which have yielded insights into crustal architecture beneath the Dharwar craton, crustal scale lineaments, craton-mobile belt contact zone and younger intrusives.
Sharma, R., Muthry, Ch.V.V.S., Nagaraju, B.V., Gouda, H.C., Singh, R.K.
Interpretation of aeromagnetic dat a of Panna and adjoining areas for evaluating of structural patterns favourable for emplacement of KCRs and depth magnetics
Geological Society of India, Bangalore November Meeting Group Discussion on Kimberlites and Related Rocks India, Abstract p. 121-122.
India, Madhya Pradesh, Aravalli Bundelkhand Craton
International Journal of Earth Sciences, Vol. 105, 4, pp. 1087-1107.
India
Not specific to diamonds
Abstract: We have carried out radioelemental (232Th, 238U, 40K), petrological and geochemical analyses on granitoids and gneisses covering major rock formations of the Bundelkhand craton, central India. Our data reveal that above characteristics are distinct among granitoids (i.e. pink, biotite and grey granitoids) and gneisses (i.e. potassic and sodic types). Pink granitoid is K-feldspar-rich and meta-aluminous to per-aluminous in character. Biotite granitoid is meta-aluminous in character. Grey granitoid is rich in Na-feldspar and mafic minerals, granodiorite to diorite in composition and meta-aluminous in character. Among these granitoids, radioelements (Th, U, K) are highest in pink granitoid (45.0 ± 21.7 ppm, 7.2 ± 3.4 ppm, 4.2 ± 0.4 %), intermediate in biotite granitoid (44.5 ± 28.2 ppm, 5.4 ± 2.8 ppm, 3.4 ± 0.7 %) and lowest in grey granitoid (17.7 ± 4.3 ppm, 4.4 ± 0.6 ppm, 3.0 ± 0.4 %). Among gneisses, potassic-type gneisses have higher radioelements (11.8 ± 5.3 ppm, 3.1 ± 1.2 ppm, 2.0 ± 0.5 %) than the sodic-type gneisses (5.6 ± 2.8 ppm, 1.3 ± 0.5 ppm, 1.4 ± 0.7 %). Moreover, the pink granitoid and the biotite granitoid have higher Th/U (6 and 8, respectively) compared to the grey granitoid (Th/U: 4), implying enrichment of Th in pink and biotite granitoids relative to grey granitoid. K/U among pink, biotite and grey granitoids shows little variation (0.6 × 104, 0.6 × 104, 0.7 × 104, respectively), indicating relatively similar increase in K and U. Therefore, mineralogical and petrological data along with radioelemental ratios suggest that radioelemental variations in these lithounits are mainly related to abundances of the radioactive minerals that have formed by the fractionation of LILE from different magma sources. Based on present data, the craton can be divided into three distinct zones that can be correlated with its evolution in time and space. The central part, where gneisses are associated with metavolcanics of greenstone belt, is characterized by lowest radioelements and is the oldest component. The southern part, dominated by pink granitoid, is characterized by highest radioelements and is the youngest part. The northern part, dominated by grey and biotite granitoid, is characterized by moderate radioelements.
Abstract: Petrographic, mineral chemical and whole-rock geochemical characteristics of two newly discovered lamproitic dykes (Dyke 1 and Dyke 2) from the Sidhi Gneissic Complex (SGC), Central India are presented here. Both these dykes have almost similar sequence of mineral-textural patterns indicative of: (1) an early cumulate forming event in a deeper magma chamber where megacrystic/large size phenocrysts of phlogopites have crystallized along with subordinate amount of olivine and clinopyroxene; (2) crystallization at shallow crustal levels promoted fine-grained phlogopite, K-feldspar, calcite and Fe-Ti oxides in the groundmass; (3) dyke emplacement related quench texture (plumose K-feldspar, acicular phlogopites) and finally (4) post emplacement autometasomatism by hydrothermal fluids which percolated as micro-veins and altered the mafic phases. Phlogopite phenocrysts often display resorption textures together with growth zoning indicating that during their crystallization equilibrium at the crystal-melt interface fluctuated multiple times probably due to incremental addition or chaotic dynamic self mixing of the lamproitic magma. Carbonate aggregates as late stage melt segregation are common in both these dykes, however their micro-xenolithic forms suggest that assimilation with a plutonic carbonatite body also played a key role in enhancing the carbonatitic nature of these dykes. Geochemically both dykes are ultrapotassic (K2O/Na2O: 3.0 -9.4) with low CaO, Al2O3 and Na2O content and high SiO2 (53.3 -55.6 wt.%) and K2O/Al2O3 ratio (0.51 -0.89) characterizing them as high-silica lamproites. Inspite of these similarities, many other features indicate that both these dykes have evolved independently from two distinct magmas. In dyke 1, phlogopite composition has evolved towards the minette trend (Al-enrichment) from a differentiated parental magma having low MgO, Ni and Cr content; whereas in dyke 2, phlogopite composition shows an evolutionary affinity towards the lamproite trend (Al-depletion) and crystallized from a more primitive magma having high MgO, Ni and Cr content. Whole-rock trace-elements signatures like enriched LREE, LILE, negative Nb-Ta and positive Pb anomalies; high Rb/Sr, Th/La, Ba/Nb, and low Ba/Rb, Sm/La, Nb/U ratios in both dykes indicate that their parental magmas were sourced from a subduction modified garnet facies mantle containing phlogopite. From various evidences it is proposed that the petrogenesis of studied lamproitic dykes stand out to be an example for the lamproite magma which attained a carbonatitic character and undergone diverse chemical evolution in response to parental melt composition, storage at deep crustal level and autometasomatism.
Abstract: Madawara ultramafic complex (MUC) in the southern part of Bundelkhand Craton, Central India comprises peridotite, olivine pyroxenite, pyroxenite, gabbro, and diorite. Coarse?grained olivine, clinopyroxene (Cpx), amphibole (Amp), Al?chromite, Fe?chromite, and magnetite with rare orthopyroxene (Opx) are common minerals in peridotite. Chromites are usually coarse?grained euhedral found as disseminated crystals in the olivine matrix showing both homogeneous and zoned texture. Al?chromite, primarily characterizes Cr?spinels and its subsequent fluid activity and alteration can result in the formation of Fe?chromite, chrome magnetite, and magnetite. Mineral chemistry data suggest that Al?chromite is characterized by moderately high Cr2O3 (38.16-51.52 wt.%) and Fe2O3 (3.22-14.51 wt.%) and low Al2O3 (10.63-21.87 wt.%), MgO (1.71-4.92 wt.%), and TiO2 (0.22-0.67 wt.%), whereas the homogeneous Fe?chromite type is characterized by high Fe2O3 (25.54-47.60 wt.%), moderately low Cr2O3 (19.56-37.90 wt.%), and very low Al2O3 (0.06-1.53 wt.%). Subsequent alteration of Al?chromite and Fe?chromite leads to formation of Cr?magnetite and magnetite. The Cr# of Al?chromite varies from 55.12 to 76.48 and ?Fe3+# from 8 to 19, whereas the ferrian chromite has high Cr# varying from 94.27 to 99.53 while its ?Fe3+# varies from 38 to 70. As a whole, the primary Al?chromite shows low Al2O3, TiO2 contents, and high Fe#, Cr# values. Olivines have forsterite ranging from 75.96% to 77.59%. The bulk?rock geochemistry shows continental arc geochemical affinities indicated by the high concentration of large?ion lithophile elements and U, Th relative to the low concentration of high?field strength elements. These petrological and mineralogical as well as primary Al?chromite compositions plotted in different discrimination diagrams suggest an arc environment that is similar to Alaskan?type intrusion.
Abstract: This study reports major, trace, rare earth and platinum group element compositions of lava flows from the Vempalle Formation of Cuddapah Basin through an integrated petrological and geochemical approach to address mantle conditions, magma generation processes and tectonic regimes involved in their formation. Six flows have been identified on the basis of morphological features and systematic three-tier arrangement of vesicular-entablature-colonnade zones. Petrographically, the studied flows are porphyritic basalts with plagioclase and clinopyroxene representing dominant phenocrystal phases. Major and trace element characteristics reflect moderate magmatic differentiation and fractional crystallization of tholeiitic magmas. Chondrite-normalized REE patterns corroborate pronounced LREE/HREE fractionation with LREE enrichment over MREE and HREE. Primitive mantle normalized trace element abundances are marked by LILE-LREE enrichment with relative HFSE depletion collectively conforming to intraplate magmatism with contributions from sub-continental lithospheric mantle (SCLM) and extensive melt-crust interaction. PGE compositions of Vempalle lavas attest to early sulphur-saturated nature of magmas with pronounced sulphide fractionation, while PPGE enrichment over IPGE and higher Pd/Ir ratios accord to the role of a metasomatized lithospheric mantle in the genesis of the lava flows. HFSE-REE-PGE systematics invoke heterogeneous mantle sources comprising depleted asthenospheric MORB type components combined with plume type melts. HFSE-REE variations account for polybaric melting at variable depths ranging from garnet to spinel lherzolite compositional domains of mantle. Intraplate tectonic setting for the Vempalle flows with P-MORB affinity is further substantiated by (i) their origin from a rising mantle plume trapping depleted asthenospheric MORB mantle during ascent, (ii) interaction between plume-derived melts and SCLM, (iii) their rift-controlled intrabasinal emplacement through Archean-Proterozoic cratonic blocks in a subduction-unrelated ocean-continent transition zone (OCTZ). The present study is significant in light of the evolution of Cuddapah basin in the global tectonic framework in terms of its association with Antarctica, plume incubation, lithospheric melting and thinning, asthenospheric infiltration collectively affecting the rifted margin of eastern Dharwar Craton and serving as precursors to supercontinent disintegration.
Abstract: The Central Indian region is having complex geology covering the Godavari Graben, the Bastar Craton (including the Chhattisgarh Basin), the Eastern Ghat Mobile Belt, the Mahanadi Graban and some part of the Deccan Trap, the Northern Singhbhum Orogen and the Eastern Dharwar Craton. The region is well covered by reconnaissance scale aeromagnetic data, analyzed for the estimation of basement and shallow anomalous magnetic sources depth using scaling spectral method. The shallow magnetic anomalies are found to vary from 1 to 3 km whereas magnetic basement depth values are found to vary from 2 to 7 km. The shallowest basement depth of 2 km corresponds to the Kanker granites, a part of the Bastar Craton, whereas deepest basement depth of 7 km is for the Godavari Basin and the southeastern part of the Eastern Ghat Mobile Belts near the Parvatipuram Bobbili fault. The estimated basement depth values correlate well with the values found from earlier geophysical studies. The earlier geophysical studies are limited to few tectonic units whereas our estimation provides detailed magnetic basement mapping in the region. The magnetic basement and shallow depth values in the region indicate complex tectonic, heterogeneity and intrusive bodies at different depth which can be attributed to different thermo-tectonic processes since Precambrian.
Abstract: The Central Indian region has a complex geology covering the Godavari Graben, the Bastar Craton (including the Chhattisgarh Basin), the Eastern Ghat Mobile Belt, the Mahanadi Graben and some part of the Deccan Trap, the northern Singhbhum Orogen and the eastern Dharwar Craton. The region is well covered by reconnaissance-scale aeromagnetic data, analysed for the estimation of basement and shallow anomalous magnetic sources depth using scaling spectral method. The shallow magnetic anomalies are found to vary from 1 to 3 km, whereas magnetic basement depth values are found to vary from 2 to 7 km. The shallowest basement depth of 2 km corresponds to the Kanker granites, a part of the Bastar Craton, whereas the deepest basement depth of 7 km is for the Godavari Basin and the southeastern part of the Eastern Ghat Mobile Belt near the Parvatipuram Bobbili fault. The estimated basement depth values correlate well with the values found from earlier geophysical studies. The earlier geophysical studies are limited to few tectonic units, whereas our estimation provides detailed magnetic basement mapping in the region. The magnetic basement and shallow depth values in the region indicate complex tectonic, heterogeneity, and intrusive bodies at different depths, which can be attributed to different thermo-tectonic processes since Precambrian.
Journal of Geological Society of India, Vol. 88, 5, pp. 539-548.
India
Craton, Bundelkhand
Abstract: Two Archaean supracrustal complexes are documented in the Bundelkhand craton viz. 1) the Central Bundelkhand greenstone complex (formed the Babina and Mauranipur belts), and 2) the Southern Bundelkhand metasedimentary (paragneisses, schists) complex (formed the Girar belt). The Central Bundelkhand greenstone complex consists of (i) an early assemblage composed of basic-ultrabasic, felsic volcanics, banded iron formation (BIF), and (ii) a late assemblage which contains felsic volcanics. The U-Pb zircon ages of felsic volcanics from the early assemblage, formed in an arc-type subduction setting, are 2813 Ma (Mesoarchaean). The U-Pb zircon ages of felsic volcanics from the late assemblage, which also occur in subduction settings as an active continental marginal type, are 2542 Ma (Neoarchaean). The Girar belt, located in the southern part of the craton, consists generally of metasedimentary rocks namely quartzites and BIFs. Quartzites are represented by fuchsite- and hematite- bearing quartz arenite and lesser quartz pebble conglomerates that have been subjected to low-grade metamorphism. BIF is represented by thinly-bedded quartz-hematite (±magnetite) rocks. Some lenses of marble and chlorite schist are present at the contact between the two formations. BIF is fairly rich in Cr and Ni, poor in Zr, Hf, Ba, Th, Sr, Yb and Lu, and displays a distinct positive Euanomaly (Eu/Eu* = 1.14-2.46). Zircons from quartzites give two U-Pb ages: 3432±9.7 Ma and 3252±6.4 Ma. The Sm-Nd isotope study of quartzite from the Girar belt shows that the TDM is 3.29 Ga. This TDM correlates well with the U-Pb ages of zircon and indicates that the continental crust in the Girar area began to form in the Paleoarchaean (3.4-3.2 Ga). The Central Bundelkhand greenstone complex was thus formed in a subduction-accretion setting in Mesoarchaean (ca 2.8 Ga) and Neoarchaean (2.54 Ga) time, and the Southern Bundelkhand metasedimentary complex originated in a sedimentary basin on the old continental crust apparently at ca ~ 2.7 Ga.
Abstract: In 2015, a field team from GIA visited the Indian city of Jaipur to capture the full scope of its gem and jewelry industry: colored stone cutting, wholesale trading, jewelry design, manufacturing, and retail. The authors documented the current state of the industry from a manufacturing as well as a business perspective. The results substantiated many of the team's prior assessments but also brought to light recent developments with far-reaching effects. The impact of vertical integration, consolidation, globalization, and jewelry television retail far exceeded expectations. Once known as a colored stone manufacturing center, Jaipur has rapidly climbed the value chain into jewelry manufacturing and retail by successfully incorporating experience and tradition with technology and innovation.
Late Proterozoic magmatism in the eastern United States: neodymium, lead and Strontium isotope systematics and implications for crust-mantle interactions
Geological Society of America Annual Meeting Abstract Volume, Vol. 23, No. 5, San Diego, p. A 135
Srivastava, R.K., Heaman, L.M., Sinha, A.K., Shihua, S.
Emplacement age and isotope geochemistry of Sung Valley alkaline carbonatite complex, Shillong Plateau, northeastern India: implications for primary carbonate
Srivastava, R.K., Chalapathi Rao, N.V., Sinha, A.K.
Cretaceous potassic intrusives with affinities to aillikites from Jharia area: magmatic expression of metasomatically veined and thinned lithospheric mantle
Srivastava, R.K., Chalapathi Rao, N.V., Sinha, A.K.
Cretaceous potassic intrusives with affinities to aillikites from Jharia area: magmatic expression of metasomatically veined and thinned lithospheric mantle
Geological Society of London Special Publication, Vol. 457, pp. 339-351.
India
Tectonics
Abstract: In this short paper, we outline the potential links between India and the East Antarctica region from Enderby Land to Princess Elizabeth Land using the Mesozoic East Gondwana configuration as a starting point. Palaeomagnetic data indicate that East Gondwana did not exist prior to the Ediacaran-Cambrian. Early Neoproterozoic (1050-950 Ma) deformation in East Antarctica and along the Eastern Ghats Province in India marks the initial contact between the two regions. Volcanism in the Kerguelen hotspot led to final break-up of India and East Antarctica in the Cretaceous. Although connections between the Archaean and Proterozoic provinces of India and East Antarctica have been proposed, the current record of large igneous provinces (or dyke swarms), palaeomagnetic data and geochronology do not show a consistently good match between the two regions.
Abstract: New in-situ U-Pb ages and Sr-Nd-Hf isotopic data on mineral phases of the Sung Valley and Jasra ultramafic-alkaline-(carbonatite) intrusions (Shillong Plateau, India) shed new light on the petrogenetic processes of volcanism in north-eastern India during the Cretaceous. Perovskites of Sung Valley dunite, ijolite and uncompahgrite yielded U-Pb ages of 109.1?±?1.6, 104.0?±?1.3 and 101.7?±?3.6?Ma, respectively. A U-Pb age of 106.8?±?1.5?Ma was obtained on zircons of a Sung Valley nepheline syenite. Perovskite of a Jasra clinopyroxenite yielded an age of 101.6?±?1.2?Ma, different from the U-Pb age of 106.8?±?0.8?Ma on zircon of Jasra syenites. The variation in Sr-Nd-Hf isotopic compositions [initial 87Sr/86Sr?=?0.70472 to 0.71080; ?Nd i?=??10.85 to +0.86; ?Hf i?=??7.43 to +1.52] matches the bulk-rock isotopic composition of the different rock units of Sung Valley and Jasra. Calcite and apatite in the carbonatites, the perovskite in a dunite, and the bulk-rock carbonatites of Sung Valley intrusion have the lowest initial 87Sr/86Sr and ?Nd, taken to be the best proxies of the mantle source composition, which is dominated by components derived from the lithospheric mantle. The alkaline intrusions of north-eastern India are significantly younger than the Sylhet tholeiitic magmatism. The silicate rocks of both intrusions have isotopic composition trending to that of the underlying Shillong crust, indicating the effects of fractional crystallization and low-pressure crustal contamination during the emplacement of the various intrusive magma pulses.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 237-252.
Ratre, K., De Waele, B., Kumar, Biswal, T., Sinha, S.
Shrimp geochronology for the 1450 Ma Lakhna dyke swarm: its implication for the presence of Eoarchean crust in the Bastar Craton and the 1450-517 Ma depositional age
Journal of Asian Earth Sciences, Vol. 39, 6, pp. 565-577.
Abstract: The Tanzania?North Mozambique continental margin is a transform segment associated with Davie Fracture Zone (DFZ). The DFZ is described as an elongated linear oceanic fracture zone, commonly linked with the breakup between Eastern and Western Gondwana. We conducted a synthesized study using gravity, magnetic and seismic data presenting the crustal architecture, geometry and the kinematic nature of continental breakup along a transform margin. The Crustal nature of DFZ, its role in forming kinematic linkage between two extensional margins during continental breakup processes is focus of our study. The two extensional margins, Somalia?Majunga and North Mozambique?Antarctica were linked via a 2600 km long dextral transform segment, partially overlapping with DFZ. Absence of classical rift indicators, weak signs of hyperextension, abrupt ocean?continent boundary (OCB) suggests transform margin architecture. We redefined this feature as the Davie Transform System (DTS). The nature of deformation varies form transtensional pull?apart in Tanzania to almost pure strike?slip in North Mozambique. The southern transform segment exhibits abrupt change in ocean continent transition with a narrow zone of continental extension. This variation is recognized through the newly interpreted OCB along this entire transform segment. Notably, within large pull?apart systems in the north, presence of fossilized incipient spreading center suggest that the extension had reached at quite advanced stages, characterized by significant thermal weakening as a consequence of strong magmatic activity. Through a series of reconstruction snapshots, we show the geodynamic evolution along the Tanzania?North Mozambique margin explaining the role of DTS in the southward movement of Madagascar.
Abstract: The Cana Brava complex is the northernmost of three layered complexes outcropping in the Goiás state (central Brasil). New field and geochemical evidences suggest that Cana Brava underwent hyper- to subsolidus deformation during its growth, acquiring a high-temperature foliation that is generally interpreted as the result of a granulite-facies metamorphic event. The increase along the stratigraphy of the incompatible elements abundances (LREE, Rb, Ba) and of the Sr isotopic composition, coupled with a decrease in ?Nd(790), indicate that the complex was contaminated by the embedded xenoliths from the Palmeirópolis Sequence. The geochemical data suggest that the contamination occurred along the entire magma column during the crystallization of the Upper Mafic Zone, with in situ variations determined by the abundance and composition of the xenoliths. These features of the Cana Brava complex point to an extremely similarity with the Lower Sequence of the most known Niquelândia intrusion (the central of the three complexes). This, together with the evidences that the two complexes have the same age (c.a. 790 Ma) and their thickness and units decrease northwards suggests that Cana Brava and Niquelândia are part of a single giant Brasilia body grown through several melt impulses.
Abstract: The subparallel maflc dykes of the Aorida-Durazno-S.José region (SW Uruguay) trend N60-80W and vary in thickness from 0.6 to 50 m. They are part of the mafic dyke swarms intrudlng granitic-gnelssic basement that were mappecl by BOSSI et ai. (1989), In an ares approximately 200 km In length and 100 km in bresdth. Plagioclass, augite, subcalclc augite (plgeonite) and opaques are the maln components of the dykes. Orthopyroxene and oIlvine are very rare. Blotite and homblende are secondary minerais. Quartz-feldspar Intergrowths occur In the coarser gralnecl dykes. The characterlstlc textures are subophitic and intersertal.
Abstract: A review of the compositional features of Tunisia, Algeria, and Morocco phosphorites is proposed in order to assess and compare the paleoenvironmental conditions that promoted the deposit formation as well as provide information about their economic perspective in light of growing worldwide demand. Since these deposits share a very similar chemical and mineralogical composition, the attention was focused on the geochemistry of rare earth elements (REEs) and mostly on ?REEs, Ce and Eu anomalies, and (La/Yb) and (La/Gd) normalized ratios. The REEs distributions reveal several differences between deposits from different locations, suggesting mostly that the Tunisian and Algerian phosphorites probably were part of the same depositional system. There, sub-reducing to sub-oxic conditions and a major REEs adsorption by early diagenesis were recorded. Conversely, in the Moroccan basins, sub-oxic to oxic environments and a minor diagenetic alteration occurred, which was likely due to a different seawater supply. Moreover, the drastic environmental changes associated to the Paleocene-Eocene Thermal Maximum event probably influenced the composition of Northern African phosphorites that accumulated the highest REEs amounts during that span of time. Based on the REEs concentrations, and considering the outlook coefficient of REE composition (Koutl) and the percentage of critical elements in ?REEs (REEdef), the studied deposits can be considered as promising to highly promising REE ores and could represent a profitable alternative source for critical REEs.
Abstract: Iron- and aluminum-bearing MgSiO3 bridgmanite is the most abundant mineral in the Earth’s interior; hence its crystal chemistry is fundamental to expanding our knowledge of the deep Earth and its evolution. In this study, the valence and spin state of iron in well-characterized Al-free Fe3+-rich bridgmanite were investigated by means of Mössbauer spectroscopy to understand the effect of ferric iron on the spin state. We found that a minor amount of Fe3+ is in the low-spin state above 36 GPa and that its proportion does not increase substantially with pressure up to 83 GPa. This observation is consistent with recent experimental studies that used Mössbauer and X-ray emission spectroscopy. In the Earth’s deep lower mantle, Fe3+ spin crossover may take place at depths below 900 and 1200 km in pyrolite and MORB, respectively. However, the effect of spin crossover on physical properties may be small due to the limited amount of Fe3+ in the low-spin state.
Abstract: As the most abundant material of rocky planets, high-pressure polymorphs of iron- and aluminum-bearing magnesium silicates have long been sought by both observations and experiments. Meanwhile, it was recently revealed that iron oxides form (FeO)m(Fe2O3)n homologous series above ?10 GPa according to laboratory high-pressure experiments. Here, we report a new high-pressure iron-magnesium silicate, recently approved by the International Mineralogical Association as a new mineral (No. 2020-086) and named elgoresyite, in a shock-induced melt vein of the Suizhou L6 chondrite with a chemistry of (Mg,Fe)5Si2O9. The crystal structure of this new silicate is the same as the iron oxide Fe7O9, strongly suggesting that silicates also form ((Mg,Fe)O)m + n(SiO2)n series that are isostructural to iron oxides via (Mg2+,Fe2+) + Si4+ = 2Fe3+ substitution. To test this hypothesis, the phase relationships of the silicates and iron oxides should be further investigated at higher temperature conditions. Newly found iron-magnesium silicate is a potential constituent mineral in rocky planets with relatively high MgO + FeO content.
Soares Rocha Barbosa, E., Brod, J.A., Junqueira-Brod, T.C., Dantas, E.L., De Oliveira Cordeiro, P.F., Siqueira Gomide, C.
Bebdourite from its type area Sailtre 1 complex: a key petrogenetic series in the Late-Cretaceous Alto Paranaiba kamafugite carbonatite phoscorite association, central Brazil.
International Journal of Earth Sciences, Vol. 108, pp. 89-113.
Africa, Angola
thermochronology
Abstract: There are two main points of view regarding how continental margins evolve. The first one argues that the present-day margins have been developed by long-term denudation since a major exhumation episode, probably driven by rifting or another relevant tectonic event. The second one argues that continental margins underwent alternating burial and exhumation episodes related to crustal tectonic and surface uplift and subsidence. To demonstrate that the proximal domain of the southwestern Angolan margin has evolved in a polycyclic pattern, we present a review of geological and thermochronological information and integrate it with new combined apatite fission-track and (U-Th)/He data from Early Cretaceous volcanic and Precambrian basement samples. We also provide hypotheses on the possible mechanisms able to support the vertical crustal movements of this margin segment, which are also discussed based on some modern rifting models proposed for Central South Atlantic. The central apatite fission-track ages range from 120.6?±?8.9 to 272.9?±?21.6 Ma, with the mean track lengths of approximately 12 µm. The single-grain apatite (U-Th)/He ages vary between 52.2?±?1 and 177.2?±?2.6 Ma. The integration of the thermochronological data set with published geological constraints supports the following time-temperature evolution: (1) heating since the Carboniferous-Permian, (2) cooling onset in the Early Jurassic, (3) heating onset in the Early Cretaceous, (4) cooling onset in the Mid- to Late Cretaceous, (5) heating onset in the Late Cretaceous, and (6) cooling onset in the Oligocene-Miocene. The thermochronological data and the geological constraints, support that the proximal domain of the southwestern Angolan margin was covered in the past by pre-, syn-, and post-rift sediments, which were eroded during succeeding exhumation events. For this margin segment, we show that a development based on long-term denudation is less realistic than one based on burial and exhumation episodes during the last 130 Myr.
Veevers, J.J., Belousova, E.A., Saced, A., Sircombe, K., Cooper, A.F., Read, S.E.
Pan-Gondwanaland detrital zircons from Australia analyzed for Hf isotopes and trace elements reflect an ice covered Antartic provenance 700-500 Ma alkalinity
Veevers, J.J., Belousova, E.A., Saeed, A., Sircombe, K., Cooper, A.F., Read, S.E.
Pan Gondwanaland detrital zircons from Australia analysed for Hf isotopes and trace elements reflect an ice covered Antarctic provenance of 700-500 Ma ...
Earth Science Reviews, Vol. 76, 3-4, June pp. 135-174.
Campbell, L.S., Compston, W., Sircombe, K.N., Wilkinson, C.C.
Zircon from the East orebody of the Bayan Obo Fe Nb REE deposit, China, and SHRIMP ages for carbonatite related magmatism and REE mineralization events.
Contributions to Mineralogy and Petrology, Vol. 168, pp. 1041-
Diamond & Related Materials, Vol. 89, pp. 101-107.
Mantle
boron
Abstract: Influence of growth medium composition on the efficiency of boron doping of carbonado-like diamond at 8-9 GPa was studied by diluting the C-B growth system with metallic solvents of carbon, Co and Ni. Addition of these metals to the original system leads to a decrease in the synthesis temperature, degree of doping with boron and suppression of superconductivity in diamond. According to XPS analysis, content of substitutional boron is equal to 0.07, 0.16 and 0.39 at.% in diamonds obtained in Co-C-B, Ni-C-B and C-B growth systems, respectively. Metallic behavior at normal temperatures and superconductivity below 5 K in diamond, synthesized in C-B system, change to semiconducting character of conductivity down to 2 K in diamonds obtained in the diluted systems; a faint hint of superconducting transition at 2 K was detected in the case of diamond grown in Ni-C-B system. By comparing phase composition of the inclusions and the doping efficiency of the diamonds, we are able to suggest that high chemical affinity of boron to boride-forming metals hinders the boron doping of diamond. The heavily boron-doped carbonado-like diamond compacts demonstrate high electrochemical activity in aqueous solutions and can be used as miniature electrodes in electrosynthesis and electroanalysis.
Abstract: Phase relations in the system Mg2SiO4-MgCr2O4 were studied at 10-24 GPa and 1600°C using a high-pressure Kawai-type multi-anvil apparatus. We investigated the full range of starting compositions for the forsterite-magnesiochromite system to derive a P-X phase diagram and synthesize chromium-bearing phases, such as garnet, wadsleyite, ringwoodite, and bridgmanite of a wide compositional range. Samples synthesized at 10 GPa contain olivine with small chromium content and magnesiochromite. Mg2SiO4 wadsleyite is characterized by the pressure-dependent higher chromium solubility (up to 7.4 wt% Cr2O3). The maximal solubility of chromium in ringwoodite in the studied system (~18.5 wt% Cr2O3) was detected at P = 23 GPa, which is close to the upper boundary of the ringwoodite stability. Addition of chromium to the system moves the boundaries of olivine/wadsleyite and wadsleyite/ring-woodite phase transformations to lower pressures. Our experiments simulate Cr-rich phase assemblages found as inclusions in diamonds, mantle xenoliths, and UHP podiform chromitites.
Abstract: Interphase partitioning of minor elements was studied experimentally upon partial melting of model pyrolite [1] with addition of 2 wt % H2O, 10, and 15 wt % of multicomponent carbonate at 22-24 GPa and 1300-2200°C. The concentrations of minor elements were analyzed on an Agilent 7500a mass spectrometer. Phase associations included quenched melt (L), bridgmanite (Brd), CaSiO3- perovskite (CaPrv), ringwoodite (Rwd), ferropericlase (Fp), and majoritic garnet (Maj). The sequence of phase assemblages in our runs is consistent to that reported in [2] for melting of anhydrous pyrolite at 24 GPa: Fp+L, Fp+Maj+Brd(Rwd)+L, Fp+Maj+Brd(Rwd)+CaPrv. Most of minor elements, except for Sc, Cr, and Ni, are incompatible for Brd and show slight increase in partitioning coefficients from LREEs to HREEs in the H2O-bearing system. Pyrolite with carbonate is characterized by slightly higher LREE partitioning coefficients. Monovalent elements (Li, K, Cs, Rb), as well as Sr and Pb, are strongly incompatible for Brd in all systems. The similar features are observed for Fp enriched in HREEs and depleted in LREEs; all minor elements show redistribution into Fp with pressure. CaPrv is enriched in LREEs and depleted in HREEs. We applied the lattice strain model [3] for interpretation of the analytical data, which allowed us to study the behavior of minor elements as a function of P-T parameters. Our data and some previous results [4] were used for estimation of the composition of melts in equilibrium with inclusions in diamonds from the transition zone and lower mantle.
White-Gaynor, A.L., Nyblade, A.A., Durrheim, R., Raveloson, R., van der Meijde, M., Fadel, I., Paulssen, H., Kwadiba, M., Ntibinyane, O., Titus, N., Sitali, M.
Geochemistry, Geophysics, Geosystems, 10.1029/GC008925 20p. Pdf
Africa, South Africa
Geophysics, seismic
Abstract: We report new P and S wave velocity models of the upper mantle beneath southern Africa using data recorded on seismic stations spanning the entire subcontinent. Beneath most of the Damara Belt, including the Okavango Rift, our models show lower than average velocities (?0.8% Vp; ?1.2% Vs) with an abrupt increase in velocities along the terrane's southern margin. We attribute the lower than average velocities to thinner lithosphere (~130 km thick) compared to thicker lithosphere (~200 km thick) immediately to the south under the Kalahari Craton. Beneath the Etendeka Flood Basalt Province, higher than average velocities (0.25% Vp; 0.75% Vs) indicate thicker and/or compositionally distinct lithosphere compared to other parts of the Damara Belt. In the Rehoboth Province, higher than average velocities (0.3% Vp; 0.5% Vs) suggest the presence of a microcraton, as do higher than average velocities (1.0% Vp; 1.5% Vs) under the Southern Irumide Belt. Lower than average velocities (?0.4% Vp; ?0.7% Vs) beneath the Bushveld Complex and parts of the Mgondi and Okwa terranes are consistent with previous studies, which attributed them to compositionally modified lithosphere resulting from Precambrian magmatic events. There is little evidence for thermally modified upper mantle beneath any of these terranes which could provide a source of uplift for the Southern African Plateau. In contrast, beneath parts of the Irumide Belt in southern and central Zambia and the Mozambique Belt in central Mozambique, deep?seated low velocity anomalies (?0.7% Vp; ?0.8% Vs) can be attributed to upper mantle extensions of the African superplume structure.
Critical evaluation of the status of the areas for future research regarding the wide band GAP semi-conductors diamond, gallium nitride and silicon carbide
Material Sci. Eng. B. Solid State Adv. Technol, Vol. B1, No. 1, Aug. pp. 77-104
Abstract: The study of diamond surfaces is traditionally undertaken in geology and materials science. As a sample material, two natural diamond crystals of type Ia were selected, and their luminescence and nitrogen state was characterized. In order to etch the surface catalytic hydrogenation was performed using Fe particles as an etchant. Micromorphology of the surface was investigated by scanning electron and laser confocal microscopy. It was demonstrated that etching occurred perpendicular to the crystal surface, with no signs of tangential etching. The average depth of caverns did not exceed 20-25 ?m with a maximal depth of 40 ?m. It is concluded that catalytic hydrogenation of natural type Ia diamonds is effective to produce a porous surface that can be used in composites or as a substrate material. Additionally, the comparison of results with porous microsculptures observed on natural impact diamond crystals from the Popigai astrobleme revealed a strong resemblance.
Abstract: Significant variations in the composition of garnets, both within individual grains and in the rock, are found in the xenolith of deformed garnet lherzolite from the Udachnaya kimberlite pipe. The central parts of the grains, corresponding in composition to the garnets of the lherzolite paragenesis, demonstrate a sinusoidal distribution of rare earth elements (REEs). At the same time, the edge portions have a distribution characteristic of garnet mega-crystals from kimberlites. Despite being depleted in Y and HREE, the cores are enriched in light rare earth elements, Nb, Ta, Th, and U relative to garnet from primitive garnet peridotite. In terms of the REE distribution, the model melts, which are in equilibrium with the edge parts of garnet, are close to kimberlite but are significantly enriched in comparison with kimberlite in Nb, Ta, and Hf and depleted in Sr. Melts in equilibrium with the central parts of garnet are characterized by a steeper negative slope in the region of heavy and medium REEs and approach kimberlite in the region of light REEs. Based on the data obtained, several stages in the evolution of deformed garnet lherzolite are distinguished. The first stage involves the interaction of depleted peridotite with a melt similar in composition to carbonatite melts. This stage is associated with the formation of garnet with a sinusoidal REE distribution. At the next stage, which was preceded by the dissolution of garnet grains, garnet rims with increased Ti, Zr, and Y contents were formed and clinopyroxene appeared. At the final stage, garnet melted, caused by the inflow of a water-carbon dioxide fluid with a high potassium content, leading to polymineral inclusions and kelyphite rims.
Abstract: Recent exploration work in South Morocco revealed the occurrence of several carbonatite bodies, including the Paleoproterozoic Gleibat Lafhouda magnesiocarbonatite and its associated iron oxide mineralization, recognized here as iron-oxide-apatite (IOA) deposit type. The Gleibat Lafhouda intrusion is hosted by Archean gneiss and schist and not visibly associated with alkaline rocks. Metasomatized micaceous rocks occur locally at the margins of the carbonatite outcrop and were identified as glimmerite fenite type. Rare earth element (REE) and Nb mineralization is mainly linked to the associated IOA mineralization and is represented by monazite-(Ce) and columbite-(Fe) as major ore minerals. The IOA mineralization mainly consists of magnetite and hematite that usually contain large apatite crystals, quartz and some dolomite. Monazite-(Ce) is closely associated with fluorapatite and occurs as inclusions within the altered parts of apatite and along cracks or as separate phases near apatite. Monazite shows no zonation patterns and very low Th contents (<0.4?wt%), which would be beneficial for commercial extraction of the REE and which indicates monazite formation from apatite as a result of hydrothermal volatile-rich fluids. Similar monazite-apatite mineralization and chemistry also occurs at depth within the carbonatite, although the outcropping carbonatite is barren, suggesting an irregular REE ore distribution within the carbonatite body. The barren carbonatite contains some tiny unidentified secondary Nb-Ta-U phases, synchysite and monazite. Niobium mineralization is commonly represented by anhedral minerals of columbite-(Fe) which occur closely associated with magnetite-hematite and host up to 78?wt% Nb2O5, 7?wt% Ta2O5 and 1.6?wt% Sc2O3. This association may suggest that columbite-(Fe) precipitated by an interaction of Nb-rich fluids with pre-existing Fe-rich minerals or as pseudomorphs after pre-existing Nb minerals like pyrochlore. Our results most strongly suggest that the studied mineralization is economically important and warrants both, further research and exploration with the ultimate goal of mineral extraction.
Abstract: Recent exploration work in South Morocco revealed the occurrence of several carbonatite bodies, including the Paleoproterozoic Gleibat Lafhouda magnesiocarbonatite and its associated iron oxide mineralization, recognized here as iron-oxide-apatite (IOA) deposit type. The Gleibat Lafhouda intrusion is hosted by Archean gneiss and schist and not visibly associated with alkaline rocks. Metasomatized micaceous rocks occur locally at the margins of the carbonatite outcrop and were identified as glimmerite fenite type. Rare earth element (REE) and Nb mineralization is mainly linked to the associated IOA mineralization and is represented by monazite-(Ce) and columbite-(Fe) as major ore minerals. The IOA mineralization mainly consists of magnetite and hematite that usually contain large apatite crystals, quartz and some dolomite. Monazite-(Ce) is closely associated with fluorapatite and occurs as inclusions within the altered parts of apatite and along cracks or as separate phases near apatite. Monazite shows no zonation patterns and very low Th contents (<0.4?wt%), which would be beneficial for commercial extraction of the REE and which indicates monazite formation from apatite as a result of hydrothermal volatile-rich fluids. Similar monazite-apatite mineralization and chemistry also occurs at depth within the carbonatite, although the outcropping carbonatite is barren, suggesting an irregular REE ore distribution within the carbonatite body. The barren carbonatite contains some tiny unidentified secondary Nb-Ta-U phases, synchysite and monazite. Niobium mineralization is commonly represented by anhedral minerals of columbite-(Fe) which occur closely associated with magnetite-hematite and host up to 78?wt% Nb2O5, 7?wt% Ta2O5 and 1.6?wt% Sc2O3. This association may suggest that columbite-(Fe) precipitated by an interaction of Nb-rich fluids with pre-existing Fe-rich minerals or as pseudomorphs after pre-existing Nb minerals like pyrochlore. Our results most strongly suggest that the studied mineralization is economically important and warrants both, further research and exploration with the ultimate goal of mineral extraction.
Abstract: The recently discovered REE and Nb mineralization in the Twihinat area in the western part of the Oulad Dlim Massif (Adrar Souttouf) in South Morocco is linked to a Cretaceous calciocarbonatite intrusion which was likely formed in an intracontinental rift setting and crops out locally within a ring structure that mainly consists of massive Fe-oxide mineralization and silica breccia. The carbonatite shows intensively metasomatized zones, which contain bastnaesite and pyrochlore-group minerals as the main REE and Nb ore minerals. They are usually associated with apatite, quartz and Fe-oxides, or trapped in calcite voids, suggesting a secondary ore formation. Within the associated Fe-oxide mineralization, pyrochlore and monazite-(Ce) are the main ore minerals occurring closely associated with quartz and magnetite or hematite. The silica breccia also shows significant subsequent infill of barite, bastnaesite-(Ce) and hydrated ceriopyrochlore, which was identified by EPMA and Raman spectroscopy. Bastnaesite commonly forms prismatic aggregates whereas pyrochlore and ceriopyrochlore usually display subhedral grains along tiny fractures. Structural and textural relationships clearly indicate epigenetic ore formation induced by multiple stages of hydrothermal fluid flow and fracturing. Ore precipitation likely resulted from interaction between low-pH mineralizing hydrothermal fluids and the wall-rock. The latter efficiently buffered the acidity of the fluids and allowed significant amounts of REE and Nb ore minerals to precipitate. Trace element ICP-MS analyses show very high REE and Nb concentrations of up to 0.76 wt% ?REE and 0.21 wt% Nb in carbonatite and up to 3 wt% ?REE and 1.3 wt% Nb in the associated silica and Fe-oxide mineralization. The results clearly demonstrate that the Twihinat REE-Nb deposits are significant and represent a potential new high-grade resource for these critical metals.
Abstract: The Neoproterozoic Lofdal alkaline carbonatite complex consists of a swarm of carbonatite dykes and two plugs of calcite carbonatite known as the ‘Main’ and ‘Emanya’ carbonatite intrusions, with associated dykes and plugs of phonolite, syenite, rare gabbro, anorthosite and quartz-feldspar porphyry. In the unaltered Main Intrusion calcite carbonatite the principal rare-earth host is burbankite. As burbankite typically forms in a magmatic environment, close to the carbohydrothermal transition, this has considerable petrogenetic significance. Compositional and textural features of Lofdal calcite carbonatites indicate that burbankite formed syngenetically with the host calcite at the magmatic stage of carbonatite evolution. The early crystallisation of burbankite provides evidence that the carbonatitic magma was enriched in Na, Sr, Ba and light rare earth elements. In common with other carbonatites, the Lofdal burbankite was variably affected by alteration to produce a complex secondary mineral assemblage. Different stages of burbankite alteration are observed, from completely fresh blebs and hexagonal crystals through to complete pseudomorphs, consisting of carbocernaite, ancylite, cordylite, strontianite, celestine, parisite and baryte. Although most research and exploration at Lofdal has focused on xenotime-bearing carbonatite dykes and wall-rock alteration, this complex also contains a more typical calcite carbonatite enriched in light rare earth elements and their alteration products.
Siva-Jothy, W., Chinn, I., Stachel, T., Pearson, D.G.
Resorption features of macro and micro diamonds from Gahcho Kue.
2018 Yellowknife Geoscience Forum , p. 120. abstract
Canada, Northwest Territories
deposit - Gahcho Kue
Abstract: Studies into the relationship between oxygen fugacity of mantle fluids/melts and etch features on diamond surfaces have shown specific fluid/melt compositions correspond to associated etch features. A classification scheme has been proposed to determine the fluid composition within a kimberlite by examining etch features associated with diamond surfaces as a proxy for fluid composition in an ascending diamondiferous kimberlite. A suite of 388 microdiamonds (defined as diamonds which pass through a 0.5 mm square mesh screen) and 88 macrodiamonds taken from various drill hole depths in the Hearne kimberlite and 88 inclusion-bearing macrodiamonds from the Gahcho Kué mine (NWT) were viewed under a secondary electron microscope for their surface features in accordance with this scheme. Two hundred and thirty specimens show shallow-depth etch features that can be easily classified: the main features observed were trigons and truncated trigons on the {111} faces and/or tetragons on the {100} faces (indicating etching by fluids of variable CO2:H2O ratios). Thirty-four specimens show deeper etched features that represent either extreme degrees of regular etching (such as deeply-etched tetragons), or corrosion type etching, wherein the diamond lattice is etched in a fluid-free melt. Variability between crystal habits exists between the size fractions studied, with cubic habits only being observed in the microdiamond population. This implies variable formation conditions for the two different diamond size fractions studied from Gahcho Kué. Among microdiamonds, surface textures associated with fluid-related etching are markedly more variable, with truncated trigons, tetragons, and both positive and negative trigons being observed. However, these often occur in combination with features showing a large variability in their depth to size ratio between samples, which is typically caused by mantle-related etching. These observations suggest repeated interaction of fluids/melts with the Gahcho Kué diamond population, with at least some of the fluids affecting the microdiamonds being more CO2-rich than those that etched the macrodiamond fraction.
Physics of the Earth and Planetary Interiors, Vol. 306, 106543, 9p. Pdf
India
geophysics -seismic
Abstract: The south Indian shield, primarily consisting of Archean cratons and Cretaceous-Tertiary Deccan Volcanic Province (DVP), has undergone several major tectonic episodes during its evolution. The Deccan volcanism at Cretaceous-Tertiary (~65 Ma) is the last major tectono-thermal event, which influenced a substantial part of the south Indian shield. To understand the influence of the Deccan volcanism on the evolution of the south Indian shield, we study the crustal seismic structure of the ~65 Ma Deccan Volcanic Province and the adjacent ~2.6 Ga Eastern Dharwar Craton (EDC), which forms the basement of the volcanic terrain. We calculate teleseismic receiver functions for 18 broadband seismic stations along a ~1000 km long seismological profile that cut across both the EDC and DVP. The analysis and modelling, using H-Vp/Vs stacking and generalized neighbourhood algorithm inversion of the receiver functions show distinct crustal structure (crustal thickness, average composition, shear wave velocity variation, nature of crust-mantle boundary, etc.) across the EDC and DVP. The results clearly indicate that the crustal structure is heterogeneous beneath the DVP compared to a relatively uniform structure below the EDC. Using results from this study along with earlier results, we infer that the present Eastern Dharwar Craton terrain is not affected by any tectono-thermal event for a long geological time, including the Deccan volcanism. Whereas, the present Deccan Volcanic Province is highly affected by the Reunion mantle plume-crust interaction.
Abstract: Eocene paleoclimate reconstructions are rarely accompanied by parallel estimates of CO2 from the same locality, complicating assessment of the equilibrium climate response to elevated CO2. We reconstruct temperature, precipitation, and CO2 from latest middle Eocene (ca. 38 Ma) terrestrial sediments in the posteruptive sediment fill of the Giraffe kimberlite in subarctic Canada. Mutual climatic range and oxygen isotope analyses of botanical fossils reveal a humid-temperate forest ecosystem with mean annual temperatures (MATs) more than 17 °C warmer than present and mean annual precipitation ?4× present. Metasequoia stomatal indices and gas-exchange modeling produce median CO2 concentrations of ?630 and ?430 ppm, respectively, with a combined median estimate of ?490 ppm. Reconstructed MATs are more than 6 °C warmer than those produced by Eocene climate models forced at 560 ppm CO2. Estimates of regional climate sensitivity, expressed as ?MAT per CO2 doubling above preindustrial levels, converge on a value of ?13 °C, underscoring the capacity for exceptional polar amplification of warming and hydrological intensification under modest CO2 concentrations once both fast and slow feedbacks become expressed.
Bulk organic geochemistry and U-Pb zircon geochronology of the Wombat sedimentary fill.
2018 Yellowknife Geoscience Forum , p. 98-99. abstract
Canada, Northwest Territories
deposit - Wombat
Abstract: The Wombat locality (64.73°N, 110.59°W) is a diamondiferous kimberlite in the Lac de Gras kimberlite field of Northwest Territories. Two drill cores, CH 93-29 and DDH 0-005, intersect the Wombat crater facies and include 195 m of well preserved, undisturbed lake sediment fill. Bulk sediment elemental analysis, C isotope composition, and Rock-Eval pyrolysis, together with inferences from microfossils, are used to characterize conditions of sedimentation and paleoenvironment in the maar lake. Bulk sediment C/N, hydrogen index (HI), and ?13C indicate material derived from C3 land plants dominates the sedimentary organic matter, with a minor algal contribution. The ?13C values range from -25.3 ‰ to -30.2 ‰ (average -26.6 ‰) and are typical for C3 land plants, with fluctuations in ?13C likely related to shifts in the proportions of land-derived material and algal organic matter. An overall trend of higher ?13C towards the top of the core suggests increasing autochthonous organic matter production. 18 samples analyzed by Rock-Eval pyrolysis all plot in the Type III kerogen field for HI vs. Tmax,with average Tmax values ~425 °C indicative of the low thermal maturity of organic matter. Total organic carbon (TOC) averages 3.6 wt.% and average total carbonate content is 14.1 wt.%, indicating bottom water anoxia and substantial carbonate input from weathering of overlying carbonate cover rocks, respectively. Together with well-preserved freshwater microfossils (e.g. diatoms, chrysophytes, synurophytes), the results indicate deposition in a non-marine setting. The age of the Wombat maar lake sediments is determined using MC-LA-ICP-MS U-Pb zircon geochronology from two distal rhyolitic tephra beds found in the core DDH 0-005, yielding a date of 82.97±0.60 Ma (MSWD = 1.7, n=18 of 33 grains analyzed). This minimum age suggests that Wombat kimberlite pipe emplacement occurred during the Late Cretaceous, with sedimentation in the maar beginning shortly thereafter. Though our geochronology is preliminary at this point, our findings from the Wombat pipe post-eruptive lake sediment fill provide direct evidence for a non-marine environment in the Lac De Gras area during the Late Cretaceous. Furthermore, microfossils in the Wombat pipe sediment fill likely include the oldest-known occurrence of freshwater diatoms.
Australian Gemmologist, Vol. 25, 3, July-Sept. pp.
Technology
Diamond features
Abstract: This study describes how visual properties determine the perception of a diamond’s appearance and its performance attributes of brilliance, scintillation and fire, and how these influence beauty. Further articles will describe other parts of our cut study project. This research enables the development of methods and instruments for diamond performance analyses, shifting from current diamond cut rejection based tools, to diamond performance scoring systems, and the introduction of a new consumer language for communication between diamond buyers and sellers. The proposed Performance Scoring System is consumer friendly and can be used to design and manufacture new diamond cuts with improved optical appearance.
Geochemistry, Vol. 80, doi.org/10.1016 /j.chemer.2019 .04.002 5p. Pdf
Russia
deposit - Khibiny
Abstract: This article presents an analysis of the influences of nature and production factors relating to the chemical-mineralogical composition of products that formed at the stages of mining and processing apatite-nepheline ores in the Khibiny Mountain Massif. It is shown that all main production processes are connected to the formation of dump waste products that are subject to further changes under the influence of exogenous factors, which include conditions of outdoor storage in dumps and sludge accumulators. According to the dead tails (stale tails) of apatite production, the characteristic changes in the chemical-mineralogical composition and grain-size distribution are determined and have a significant effect on the indicators of their mineral processing. The experimental study of dead tails includes processing a set of technological operations, and their flowsheets are also determined. These flowsheets provide a nepheline concentrate of the required composition with indicators no worse than when processing the tailings of the current composition. It is shown that the existing flowsheets for apatite or nepheline concentrate processing lead to the accumulation of significant amounts of mulls associated with the separation of less valuable components of raw materials into the dump waste products, including calcium and silica. The experimental work also demonstrates the conversion process of gypsum wastes produced during the production of phosphoric acid and shows the importance of additional hydrochemical treatment of belite mull to achieve an economically justified ratio of the main and by-products in the processing of aluminosilicate raw materials.
Abstract: The Tiksheozero ultramafic-alkaline-carbonatite intrusive complex, like numerous carbonatite-bearing complexes of similar composition, is a part of a large igneous province related to the ascent of a thermochemical mantle plume. The geochemical and isotopic data indicate that the formation of the ultramafic and alkaline rocks was related to crystallization differentiation of a primary alkali picritic melt, whereas carbonatite magmas were derived from an independent mantle source. We suggest that the origin of parental magmas of the Tiksheozero Complex, as well as other ultramafic-alkaline-carbonatite complexes, was provided by two-stage melting of the mantle-plume head: (1) adiabatic melting of its inner part generated moderately alkaline picrites, the subsequent fractional crystallization of which led to the appearance of alkaline magmas, and (2) incongruent melting of the upper cooled margin of the plume head under the influence of CO2-rich fluids, which arrived from underlying adiabatic melting zone, gave rise to carbonatite magmas.
Abstract: Rare-earth elements play a crucial role in modern technologies and are necessary for a transition to a green economy. Potentially economic deposits of these elements are typically hosted in minerals such as monazite, bastnäsite, and eudialyte (a complex Na-Ca-Fe-Zr silicate mineral with Cl), making these prime targets for geological research. Globally, rare-earth mineral deposits commonly show evidence of polyphase development and mineralisation processes, which need to be better understood to improve exploration strategies. The Norra Kärr alkaline complex (Sweden) contains a globally significant deposit of rare-earth elements, hosted in the mineral eudialyte. In this study, we focussed on eudialyte crystals in undeformed, cross-cutting pegmatoid veins from Norra Kärr. In order to determine their age, we refined an established micromilling method to enable sampling of minerals rich in rare-earth elements for precise analysis of major and trace elements, Nd isotope ratios, and Sm-Nd geochronology down to a scale of <200??m. Mineral samples were subjected to detailed textural and chemical characterisation by backscattered electron imaging and laser ablation inductively coupled plasma mass spectrometry, by which precise and accurate Sm/Nd ratios were determined to steer subsequent micromill sampling for small-aliquot Sm-Nd isotope analysis by isotope dilution thermal ionisation mass spectrometry. Given enough internal spread in Sm/Nd ratios, reliable Sm-Nd isochrons can be derived from discrete textural domains within a single crystal. This provided an age of 1.144?±?0.053?Ga (95% confidence); approximately 350?million?years younger than the magmatic intrusion of the alkaline complex (ca. 1.49?Ga). Primary compositional sector and oscillatory zoning in these eudialyte crystals shows core-to-rim enrichment in rare-earth elements and significant fractionation of K/Rb, Y/Ho, Zr/Hf, and Nb/Ta, which we attribute to crystallisation under influence of complexing ligands in a confined volume. We argue that these mineralised pegmatoid veins formed by low-temperature (<550?°C) partial melting of the agpaitic host rock during an early Sveconorwegian (Grenvillian) metamorphic overprinting event. Given the challenge of directly dating rare-earth ore minerals by conventional methods, modification of rare-earth mineral deposits may be more widespread than already assumed, which shows the importance of investigations that date the rare-earth minerals themselves.
Ph.d. thesis University of Gootenberg Sweden, 105p. Pdf
Europe, Sweden
REE
Abstract: The Norra Kärr alkaline complex in southern Sweden (58°06’N, 14°34’E) is a classic occurrence of agpaitic rocks, which contains a large mineral deposit of rare-earth elements (REE), Zr, and Nb. The complex consists of different varieties of agpaitic peralkaline nepheline syenite that are defined by the occurrence of Na-rich Zr-Ti silicate minerals that contain volatiles F and Cl, including members of the rinkite, catapleiite, and eudialyte groups. The eudialyte-group minerals in Norra Kärr contain different ratios of light to heavy REE across the lithological domains. The magmatic age of the alkaline complex, which is poor in common chronometric minerals, was determined at 1.49 ± 0.01 Ga (2?) by U-Pb dating of zircon that formed during alkali metasomatism (fenitisation) of the surrounding 1.8 Ga granite. The 176Hf/177Hf isotopic ratio of this metasomatic zircon is different from Hf isotopes in the granite, but is identical with the Hf isotope composition of Lu-poor eudialyte from the alkaline complex. The relatively highly radiogenic composition of the Hf isotopes is consistent with a mantle source for the agpaitic magma. New radiometric dating methods were developed. These allow precise in situ measurements of isotope ratios of the Rb-Sr and K-Ca as well as Sm-Nd systems in K-rich and Nd-rich minerals, respectively. Three varieties of alkaline rocks in Sweden were dated by the in situ Rb-Sr method. Biotite Rb-Sr cooling ages in the region east of Norra Kärr are approximately coeval with the emplacement of the alkaline rocks. The complex has been affected by metamorphic overprinting. The foliated and folded fine-grained nepheline syenite is frequently cross-cut by coarse-grained eudialyte- rich pegmatoids. One eudialyte crystal with primary zoning from a pegmatoid was pre-characterised by SEM BSE imaging and in situ chemical analysis by LA-ICP-MS, including full REE composition and precise Sm/Nd ratios. Sampling at a resolution of <200 ?m by micromill provided a sufficient Nd aliquot for routine high-precision ID- TIMS Sm-Nd isotope analysis. Eudialyte crystal growth was dated at 1144 ± 53 Ma (2?) in the undeformed pegmatoid vein, about 350 million years after the magmatic event. The pegmatoid is suggested to have formed by low-temperature partial melting of the peralkaline nepheline syenite host at the margin of Sveconorwegian orogeny. The agpaitic rocks were produced from a magma that formed by extensive fractional crystallisation of an alkali basaltic parental magma. The concentrations of highly enriched incompatible elements in the most differentiated nepheline syenite may indicate 98 % crystallisation of the parental magma.
U Pb geochronology and geochemistry of early Proterozoic rocks of the tectonic basement windows in central Nordland, Caledonides of north central Norway.
Mineralogical-geochemical criteria for the exploration and prospecting of rocks of ultrabasic alkaline formations and carbonatites and the relatedapatite
Geol. Zhurn., (Russian), Vol. 47, No. 2, pp. 102-106
Skeleton, A., Whitmarsh, R., Arghe, F., Crill, P., Koyi, H.
Constraining the rate and extent of mantle serpentinization from seismic and petrological data: implications for chemosynthesis and tectonic processes.
Skelton, A., Whitmarsh, R., Arghe, F., Crill, P., Koyi, H.
Constraining the rate and extent of mantle serpentinization from seismic and petrological data: implications for chemosynthesis and tectonic processes.
Contributions to Mineralogy and Petrology, Vol. 173, 26p. Doi.org/10.1007/s00410-018-1505-y
Europe, Greenland
carbonatite
Abstract: Petrogenetic studies of carbonatites are challenging, because carbonatite mineral assemblages and mineral chemistry typically reflect both variable pressure-temperature conditions during crystallization and fluid-rock interaction caused by magmatic-hydrothermal fluids. However, this complexity results in recognizable alteration textures and trace-element signatures in the mineral archive that can be used to reconstruct the magmatic evolution and fluid-rock interaction history of carbonatites. We present new LA-ICP-MS trace-element data for magnetite, calcite, siderite, and ankerite-dolomite-kutnohorite from the iron-rich carbonatites of the 1.3 Ga Grønnedal-Íka alkaline complex, Southwest Greenland. We use these data, in combination with detailed cathodoluminescence imaging, to identify magmatic and secondary geochemical fingerprints preserved in these minerals. The chemical and textural gradients show that a 55 m-thick basaltic dike that crosscuts the carbonatite intrusion has acted as the pathway for hydrothermal fluids enriched in F and CO2, which have caused mobilization of the LREEs, Nb, Ta, Ba, Sr, Mn, and P. These fluids reacted with and altered the composition of the surrounding carbonatites up to a distance of 40 m from the dike contact and caused formation of magnetite through oxidation of siderite. Our results can be used for discrimination between primary magmatic minerals and later alteration-related assemblages in carbonatites in general, which can lead to a better understanding of how these rare rocks are formed. Our data provide evidence that siderite-bearing ferrocarbonatites can form during late stages of calciocarbonatitic magma evolution.
Compositional variations (major and trace elements) of clinopyroxene and Ti and radite from pyroxenite, ijolite and nepheline syenite, Alno Island, Sweden.
The 4th Colloquium on Diamonds - source to use held Gabarone March 1-3, 2010, 14p.
Canada, Quebec
Deposit - Renard
Abstract: The Renard kimberlite cluster is located in the Monts Otish region of Quebec, Canada. A Canadian National Instrument (NI) 43-101 compliant resource statement for the Renard kimberlites 2, 3, 4 and 9 and the Lynx kimberlite dyke was first issued in 2008 followed by a Preliminary Economic Assessment and the development of a conceptual mine plan. Following a successful drill program in 2009 tbat greatly expanded the amount of kimberlite in Renard 2, a revised resource statement was issued in December 2009 comprising 23 mitlion carats of Indicated Mineral Resources and 13 million carats of Inferred Mineral Resources, a threefold increase on the previous estimate. The project is currently the focus of a second Preliminary Economic Assessment and it is expected that a full feasibility and permitting program will commence in 2010 leading to the creation of Quebec's first diamond mine by 2013
Geochemistry, Geophysics, Geosystems: G3, Vol. 16, 10, pp. 3436-3455.
Mantle
Geophysics - seismics
Abstract: Relating seismic anisotropy to mantle flow requires detailed understanding of the development and evolution of olivine crystallographic preferred orientation (CPO). Recent experimental and field studies have shown that olivine CPO evolution depends strongly on the integrated deformation history, which may lead to differences in how the corresponding seismic anisotropy should be interpreted. In this study, two widely used numerical models for CPO evolution—D-Rex and VPSC—are evaluated to further examine the effect of deformation history on olivine texture and seismic anisotropy. Building on previous experimental work, models are initiated with several different CPOs to simulate unique deformation histories. Significantly, models initiated with a preexisting CPO evolve differently than the CPOs generated without preexisting texture. Moreover, the CPO in each model evolves differently as a function of strain. Numerical simulations are compared to laboratory experiments by Boneh and Skemer (2014). In general, the D-Rex and VPSC models are able to reproduce the experimentally observed CPOs, although the models significantly over-estimate the strength of the CPO and in some instances produce different CPO from what is observed experimentally. Based on comparison with experiments, recommended parameters for D-Rex are: M*?=?10, ?*?=?5, and ??=?0.3, and for VPSC: ??=?10-100. Numerical modeling confirms that CPO evolution in olivine is highly sensitive to the details of the initial CPO, even at strains greater than 2. These observations imply that there is a long transient interval of CPO realignment which must be considered carefully in the modeling or interpretation of seismic anisotropy in complex tectonic settings.
Ultramafic xenoliths from the Palo-Aike basalts: Implications for the nature and evolution of the subcontinental lithosphere below southern SouthAmerica
Proceedings of the Fourth International Kimberlite Conference, Held Perth, Australia, No. 16, pp. 343-345
De Wit, M., Bhebhe, Z., Davidson, J., Haggerty, S.E., Hundt, P., Jacob, J., Lynn, M., Marshall, T.R., Skinner, C., Smithson, K., Stiefenhofer, J., Robert, M., Revitt, A., Spaggiari, R., Ward, J.
Abstract: From the discovery of diamonds in South Africa in 1866 until the end of 2013, Africa is estimated to have produced almost 3.2 Bct out of a total global production of 5.03 Bct, or 63.6% of all diamonds that have ever been mined. In 2013 African countries ranked 2nd (Botswana), 3rd (DRC), 6th (Zimbabwe), 7th (Angola), 8th (South Africa), and 9th (Namibia), in terms of carat production and 1st (Botswana), 4th (Namibia), 5th (Angola), 6th (South Africa), 7th (Zimbabwe), and 9th (DRC), in terms of value of the diamonds produced. In 2013 Africa produced 70.6 Mct out of a global total of 130.5 Mct or 54.1%, which was valued at US$ 8.7 billion representing 61.5% of the global value of US$ 14.1 billion.
The geology and emplacement of the Jwaneng DK2 kimberlite, southern Botswana, based on a petrographic study of samples selected from all parts of the kimberlite.
GSSA Kimberley Diamond Symposium and Trade Show provisional programme, Sept. 12, title only
Petrology of the hypapbyssal kimberlite of the Kroonstad group II kimberlite (orangeite) cluster, South Africa: evolution of the magma within the cluster
Mitchell, R.H., Scott Smith, B.H., Skinner, E.M.W.
Mineralogy of magmaclasts and interclast matrices of Kimberley-type pyroclastic kimberlites from the Kao, Letseng-La-Terae, Lethlakane and Premier kimberlite pipes of southern Africa.
10th. International Kimberlite Conference Held Bangalore India Feb. 6-11, Poster abstract
Scott Smith, B.H., Nowicki, T.E., Russell, J.K., Webb, K.J., Mitchell, R.H., Hetman, C.M., Harder, M., Skinner, E.M.W., Robey, Jv.A.
Kimberlite terminology and classification.
Proceedings of the 10th. International Kimberlite Conference, Vol. 2, Special Issue of the Journal of the Geological Society of India,, Vol. 2, pp. 1-17.
The 4th Colloquium on Diamonds - source to use held Gabarone March 1-3, 2010, 14p.
Mantle
Emplacement
Abstract: Various models of near-surface kimberlite pipe emplacement have been proposed over the years. These include a top-down, phreatomagmatic model, a bottom-up, embryonic pipe model and three top-down explosive dyke models. All of these models consider kimberlites as essentially the same rock type. However. different kimberlites have different pipe shapes and contain different rock types with very specific mineral assemblages and textures and therefore are likely to have been emplaced by different processes. Some authors have considered local geological differences as the principal reason for the contrasting geology but others argue that, while geological differences might contribute locally the petrographic peculiarities of particular kimberlites may be due mainly to inherent compositional differences specifically in the ratios of juvenile CO2 and H20.
Precambrian Research, doi.org/10.1016/j.precamres.2020.105703 in press available 80p. Pdf
Canada
geothermometry
Abstract: The northern Canadian Shield is comprised of multiple Archean cratons that were sutured by the late Paleoproterozoic to form the Canadian component of supercontinent Nuna. More than 2000 combined K-Ar and 40Ar/39Ar cooling ages from across the region reveal a stark contrast in upper and lower plate thermal responses to Nuna-forming events, with the Churchill Province in particular revealing near complete thermal reworking during the late Paleoproterozoic. We review the detailed cooling history for five regions that span the Churchill Province and Trans-Hudson orogen (THO): Thelon Tectonic Zone, South Rae, Reindeer Zone, South Hall Peninsula, and the Cape Smith Belt. The cooling patterns across Churchill Province are revealed in two >1500 km transects. At the plate scale, Churchill’s cooling history is dominated by THO accretionary and collisional events, during which it formed the upper plate. Cooling ages generally young from west to east across both southern and central Churchill, and latest cooling in the THO is 50 myr older in southernmost Churchill (Reindeer Zone) compared to eastern Churchill (Hall Peninsula), indicating diachronous thermal equilibration across 2000 km strike length of the THO. Churchill exhibits relatively high post-terminal THO cooling rates of ~4 °C/myr, which support other geological evidence for widespread rapid exhumation of the THO upper plate following terminal collision, potentially in response to lithospheric delamination.
Abstract: The previously unstudied cooling and exhumation history of mid-crustal rocks exposed on southeastern Baffin Island (Canada) provides new insights into the post-orogenic evolution of the Paleoproterozoic Trans-Hudson Orogen (THO). New 40Ar/39Ar step-heat analyses of biotite, muscovite and phlogopite and core-to-rim intra-grain 40Ar/39Ar analyses of muscovite have a range of apparent ages compatible with slow regional cooling following peak metamorphism. Twenty-nine amphibolite- to granulite-facies rocks were dated using the 40Ar/39Ar step-heating laser (CO2) method. 40Ar/39Ar spot analyses were performed across muscovite grains from three samples using an ultraviolet (UV) laser to investigate intra-grain 40Ar/39Ar age variations. Step-heating apparent ages range from ca. 1788–1622 Ma for biotite, 1720–1630 Ma for phlogopite and 1729–1657 Ma for muscovite. UV spot 40Ar/39Ar analyses in the three muscovite grains range from ca. 1661–1640 Ma, 1675–1645 Ma and 1680–1652 Ma, with core-to-rim apparent age gradients of 20–30 Myr. Previous studies resolved peak metamorphism in this region to between ca. 1860 and 1820 Ma and identified late- to post-THO zircon and monazite populations at ca. 1800–1750 Ma. Numerical diffusion models for Ar in muscovite were conducted to test different Proterozoic cooling and exhumation scenarios. Comparisons with our 40Ar/39Ar ages attest to cooling rates of ~ 1–2 °C/Myr following peak metamorphism and ~ 1.5–2.5 °C/Myr after ca. 1740 Ma. Anomalously old apparent 40Ar/39Ar ages, in cases equivalent to U–Pb zircon rim and monazite ages, likely result from incorporation of excess Ar. The results suggest that mid-crustal rocks on southeastern Baffin Island remained hotter than ~ 420–450 °C for ~ 150–200 Myr after peak metamorphism, with subsequent slow cooling and denudation rates that are typical of Proterozoic orogens. The apparent absence of orogenic collapse implies that, despite high temperatures and estimated maximum crustal thicknesses comparable to those of large, hot orogens, the THO remained gravitationally stable during its terminal phase.
Geodynamics and Tectonphysics in RUS, Vol. 9, 3, pp. 827-854. only 1 p. english abstract
Africa, Angola
deposit - Catoca
Abstract: This paper presents the first results of the geostructural and tectonophysical studies of the crustal stress state in the Catoca kimberlite pipe area at the southwestern flank of the Kasai Shield in the northeasternAngola. In the evolution of the crustal stress state, six main stages are distinguished by analyzing the displacements of markers, fold hinges, long axes of boudins, granite dikes of various intrusion phases and kimberlites, as well as fractures with striations. For each of these stages, a dominating horizontal tectonic stress and its orientation is identified. During stage 1 (NW extension and shearing) and at the beginning of stage 2 (NW compression), structures formed in the host rocks in brittle-plastic conditions. The replacement of plastic deformation by faulting could occur about 530-510 Ma ago, when the continental crust ofAfricahad completely formed. Stage 3 (radial, mainly NW extension) and stage 4 (shearing, NW extension, and NE compression) were the most important for kimberlite occurrence: in the Early Cretaceous, radial extension was replaced by shearing. Both stages are related to opening of the central segment of theSouth Atlantic. The main kimberlite magmas occurred during the break-up of the Angola-Brazilian segment of Gondwana. In the course of all the four stages, stress was mainly released by the NE- and E-NE-striking faults and, to a lesser extent, by the NW-striking and latitudinal faults. The initial stage of kimberlite magmatism is associated with the NE- and E-NE-striking faults due to the presence of the Precambrian zones of flow and schistosity, which facilitated the NW-trending subhorizontal extension. Stage 5 (NE compression) began in the second half of the Cretaceous and possibly lasted until the end of the Paleogene, and compression occurred mainly along the NW-striking faults. Regionally, it corresponds to two stages of inversion movements in the southern regions of Africa, during which theAngoladome-shaped uplift emerged and the shoulders of the East African rifts began to take shape. Stage 6 (horizontal extension, mainly in the N-NE direction) is related to the processes that took place in the southern segment of theTanganyikarift and the eastern coast of theAtlantic. Based on the results of our studies, it became for the first time possible to get an idea of the main stages in the evolution of the studied region. Further geostructural measurements and dating of the host rocks will provide for a more precise definition of the proposed stages.
A period of global uncertainty ( Blank spot) in the Precambrian history of the southern Siberian Craton and the problem of the transproterozoic supercontinent.
Abstract: We report new geological, mineralogical, geochemical and geochronological data about the Katugin Ta-Nb-Y-Zr (REE) deposit, which is located in the Kalar Ridge of Eastern Siberia (the southern part of the Siberian Craton). All these data support a magmatic origin of the Katugin rare-metal deposit rather than the previously proposed metasomatic fault-related origin. Our research has proved the genetic relation between ores of the Katugin deposit and granites of the Katugin complex. We have studied granites of the eastern segment of the Eastern Katugin massif, including arfvedsonite, aegirine-arfvedsonite and aegirine granites. These granites belong to the peralkaline type. They are characterized by high alkali content (up to 11.8?wt% Na2O?+?K2O), extremely high iron content (FeO?/(FeO??+?MgO)?=?0.96-1.00), very high content of most incompatible elements - Rb, Y, Zr, Hf, Ta, Nb, Th, U, REEs (except for Eu) and F, and low concentrations of CaO, MgO, P2O5, Ba, and Sr. They demonstrate negative and CHUR-close ?Nd(t) values of 0.0…?1.9. We suggest that basaltic magmas of OIB type (possibly with some the crustal contamination) represent a dominant part of the granitic source. Moreover, the fluorine-enriched fluid phases could provide an additional source of the fluorine. We conclude that most of the mineralization of the Katugin ore deposit occurred during the magmatic stage of the alkaline granitic source melt. The results of detailed mineralogical studies suggest three major types of ores in the Katugin deposit: Zr mineralization, Ta-Nb-REE mineralization and aluminum fluoride mineralization. Most of the ore minerals crystallized from the silicate melt during the magmatic stage. The accessory cryolites in granites crystallized from the magmatic silicate melt enriched in fluorine. However, cryolites in large veins and lens-like bodies crystallized in the latest stage from the fluorine enriched melt. The zircons from the ores in the aegirine-arfvedsonite granite have been dated at 2055?±?7?Ma. This age is close to the previously published 2066?±?6?Ma zircon age of the aegirine-arfvedsonite granites, suggesting that the formation of the Katugin rare-metal deposit is genetically related to the formation of peralkaline granites. We conclude that Katugin rare-metal granites are anorogenic. They can be related to a Paleoproterozoic (?2.05?Ga) mantle plume. As there is no evidence of the 2.05?Ga mantle plume in other areas of southern Siberia, we suggest that the Katugin mineralization occurred on the distant allochtonous terrane, which has been accreted to Siberian Craton later.
Mineralogy and Petrology, Vol. 115, 19p. Doi.org/101007 /s00710-020- 00723-x pdf
South America, Colombia
REE
Abstract: A multi-methodological study was conducted in order to provide further insight into the structural and compositional complexity of rare earth element (REE) fluorcarbonates, with particular attention to their correct assignment to a mineral species. Polycrystals from La Pita Mine, Municipality de Maripí, Boyacá Department, Colombia, show syntaxic intergrowth of parisite-(Ce) with röntgenite-(Ce) and a phase which is assigned to B3S4 (i.e., bastnäsite-3-synchisite-4; still unnamed) fluorcarbonate. Transmission electron microscope (TEM) images reveal well-ordered stacking patterns of two monoclinic polytypes of parisite-(Ce) as well as heavily disordered layer sequences with varying lattice fringe spacings. The crystal structure refinement from single crystal X-ray diffraction data - impeded by twinning, complex stacking patterns, sequential and compositional faults - indicates that the dominant parisite-(Ce) polytype M1 has space group Cc. Parisite-(Ce), the B3S4 phase and röntgenite-(Ce) show different BSE intensities from high to low. Raman spectroscopic analyses of parisite-(Ce), the B3S4 phase and röntgenite-(Ce) reveal different intensity ratios of the three symmetric CO3 stretching bands at around 1100 cm?1. We propose to non-destructively differentiate parisite-(Ce) and röntgenite-(Ce) by their 1092 cm?1 / 1081 cm?1 ?1(CO3) band height ratio.
Abstract: A multi-methodological study was conducted in order to provide further insight into the structural and compositional complexity of rare earth element (REE) fluorcarbonates, with particular attention to their correct assignment to a mineral species. Polycrystals from La Pita Mine, Municipality de Maripí, Boyacá Department, Colombia, show syntaxic intergrowth of parisite-(Ce) with röntgenite-(Ce) and a phase which is assigned to B3S4 (i.e., bastnäsite-3-synchisite-4; still unnamed) fluorcarbonate. Transmission electron microscope (TEM) images reveal well-ordered stacking patterns of two monoclinic polytypes of parisite-(Ce) as well as heavily disordered layer sequences with varying lattice fringe spacings. The crystal structure refinement from single crystal X-ray diffraction data - impeded by twinning, complex stacking patterns, sequential and compositional faults - indicates that the dominant parisite-(Ce) polytype M1 has space group Cc. Parisite-(Ce), the B3S4 phase and röntgenite-(Ce) show different BSE intensities from high to low. Raman spectroscopic analyses of parisite-(Ce), the B3S4 phase and röntgenite-(Ce) reveal different intensity ratios of the three symmetric CO3 stretching bands at around 1100 cm-1. We propose to non-destructively differentiate parisite-(Ce) and röntgenite-(Ce) by their 1092 cm-1 / 1081 cm-1 ?1(CO3) band height ratio.
Mineralogy and Petrology, doi.org/101007/ s00710-018-0623-6 10p.
Europe, Sweden
alkaline
Abstract: Potassic-richterite, ideally AKB(NaCa)CMg5TSi8O22W(OH)2, is recognized as a valid member of the amphibole supergroup (IMA-CNMNC 2017-102). Type material is from the Pajsberg Mn-Fe ore field, Filipstad, Värmland, Sweden, where the mineral occurs in a Mn-rich skarn, closely associated with mainly phlogopite, jacobsite and tephroite. The megascopic colour is straw yellow to grayish brown and the luster vitreous. The nearly anhedral crystals, up to 4 mm in length, are pale yellow (non-pleochroic) in thin section and optically biaxial (?), with ??=?1.615(5), ??=?1.625(5), ??=?1.635(5). The calculated density is 3.07 g•cm?1. VHN100 is in the range 610-946. Cleavage is perfect along {110}. EPMA analysis in combination with Mössbauer and infrared spectroscopy yields the empirical formula (K0.61Na0.30Pb0.02)?0.93(Na1.14Ca0.79Mn0.07)?2(Mg4.31Mn0.47Fe3+0.20)?5(Si7.95Al0.04Fe3+0.01)?8O22(OH1.82F0.18)?2 for a fragment used for collection of single-crystal X-ray diffraction data. The infra-red spectra show absorption bands at 3672 cm?1 and 3736 cm?1 for the ? direction. The crystal structure was refined in space group C2/m to R1?=?3.6% [I >?2?(I)], with resulting cell parameters a?=?9.9977(3) Å, b?=?18.0409(4) Å, c?=?5.2794(2) Å, ??=?104.465(4)°, V?=?922.05(5) Å3 and Z?=?2. The A and M(4) sites split into A(m) (K+), A(2/m) (Na+), A(2) (Pb2+), and M(4?) (Mn2+) subsites, respectively. The remaining Mn2+ is strongly ordered at the octahedrally coordinated M(2) site, possibly together with most of Fe3+. The skarn bearing potassic-richterite formed at peak metamorphism, under conditions of low SiO2 and Al2O3 activities and relatively high oxygen fugacities.
PluS One, Vol. 13, 8, doi:10.1371/journal.pone.0200351
Asia, Thailand
garnets
Abstract: Garnets from disparate geographical environments and origins such as oxidized soils and river sediments in Thailand host intricate systems of microsized tunnels that significantly decrease the quality and value of the garnets as gems. The origin of such tunneling has previously been attributed to abiotic processes. Here we present physical and chemical remains of endolithic microorganisms within the tunnels and discuss a probable biological origin of the tunnels. Extensive investigations with synchrotron-radiation X-ray tomographic microscopy (SRXTM) reveal morphological indications of biogenicity that further support a euendolithic interpretation. We suggest that the production of the tunnels was initiated by a combination of abiotic and biological processes, and that at later stages biological processes came to dominate. In environments such as river sediments and oxidized soils garnets are among the few remaining sources of bio-available Fe2+, thus it is likely that microbially mediated boring of the garnets has trophic reasons. Whatever the reason for garnet boring, the tunnel system represents a new endolithic habitat in a hard silicate mineral otherwise known to be resistant to abrasion and chemical attack.
Persikov, E., Bukhtiyarov, P., Skol, A., Palyanov, Y.
Viscosity of kimberlite and basaltic magmas to 10 Gpa and 2000K.
V.S. Sobolev Institute of Geology and Mineralogy Siberian Branch Russian Academy of Sciences International Symposium Advances in high pressure research: breaking scales and horizons ( Courtesy of N. Poikilenko), Held Sept. 22-26, 2p. Abstract
Camara, F., Skolova, E., Abdu, Y.A., Hawthorne, F.C.
Nafertisite Na3Fe2 10Ti2(Si6017)02(OH)6F(H2))2 from Mt. Kukisvumchorr Khibiny alkaline massif, Kola Peninsula, Russia: refinement of the crystal structure and revision of the chemical formula.
European Journal of Mineralogy, Vol. 26, pp. 689-700.
Galimov, E., Kudin, A., Skorobogatskii, V., Plotnichenko, V., Bondarev, O., Zarubin, B., Strazdovskii, V., Aronin, A., Fisenko, A., Bykov, I., Barinov, A.
Experimental corrobation of the synthesis of diamond in the cavitation process.
Doklady Physical Chemistry, Vol. 49, 3, pp. 150-153.
Pure and Applied Geophysics, Vol. 177, 8, pp. 3775-3795. pdf
Europe, Finland
geophysics - seismics
Abstract: The Kokkola-Kymi Deep Seismic Sounding profile crosses the Fennoscandian Shield in northwest-southeast (NW-SE) direction from Bothnian belt to Wiborg rapakivi batholith through Central Finland granitoid complex (CFGC). The 490-km refraction seismic line is perpendicular to the orogenic strike in Central Finland and entirely based on data from quarry blasts and road construction sites in years 2012 and 2013. The campaign resulted in 63 usable seismic record sections. The average perpendicular distance between these and the profile was 14 km. Tomographic velocity models were computed with JIVE3D program. The velocity fields of the tomographic models were used as starting points in the ray tracing modelling. Based on collected seismic sections a layer-cake model was prepared with the ray tracing package SEIS83. Along the profile, upper crust has an average thickness of 22 km average, and P-wave velocities (Vp) of 5.9-6.2 km/s near the surface, increasing downward to 6.25-6.40 km/s. The thickness of middle crust is 14 km below CFGC, 20 km in SE and 25 km in NW, but Vp ranges from 6.6 to 6.9 km/s in all parts. Lower crust has Vp values of 7.35-7.4 km/s and lithospheric mantle 8.2-8.25 km/s. Moho depth is 54 km in NW part, 63 km in the middle and 43 km in SW, yet a 55-km long section in the middle does not reveal an obvious Moho reflection. S-wave velocities vary from 3.4 km/s near the surface to 4.85 km/s in upper mantle, consistently with P-wave velocity variations. Results confirm the previously assumed high-velocity lower crust and depression of Moho in central Finland.
Abstract: Comprehensive research of ore-bearing differentiated intrusions of the Keulik-Kenirim structural unit, which represents a fragment of the Paleoproterozoic Pechenga-Varzuga Belt, has been carried out for the first time. The intrusions are subvolcanic by type and lenticular in shape, nearly conformable and steeply dipping. They are made up of peridotite, olivine and plagioclase pyroxenites, and gabbro metamorphosed under amphibolite facies conditions along with host basic volcanics. All intrusive rocks are enriched in TiO2 and FeO. Sulfide Cu-Ni mineralization is represented by disseminated, pocket, and stringer-disseminated types, which are clustered in the peridotitic zone as hanging units and bottom lodes. The Ni content in disseminated ore is estimated at 0.45-0.55 wt % and 1.15-3.32 wt % in ore pockets; the Cu grades are 0.17-0.20 and 0.46-5.65 wt %, respectively. To determine the age of intrusions and metamorphism of intrusive and volcanic rocks, various isotopic systems have been used: Sm-Nd (TIMS) in rock and U-Pb (SIMS SHRIMP) and Lu-Hf (LA-ICP-MS) in zircon. Conclusions on the origin of zircons are based on concentrations of trace elements including REE therein and Hf-Nd correlation in zircons and rocks. The U-Pb system of zircons reflects episodes of igneous rock formation (1982 ± 12 Ma) and their postmagmatic transformation (1938 ± 20 Ma). The last disturbance of the U-Pb isotopic system occurred 700 and 425 Ma. Xenogenic zircons dated from 3.17 to 2.65 Ga have been revealed in the studied samples. These zircons were captured by magma from the Archean basement during its ascent. The intrusions were emplaced synchronously with economic ore formation in the Pechenga ore field (1985 ± 10 Ma). The peak metamorphism of intrusive rocks under amphibolite facies conditions is recorded at 40 Ma later. The differentiated intrusions of the Keulik-Kenirim structural unit are close in their internal structure, mineralogy, and geochemistry, as well as in age and features of related Cu-Ni mineralization to ore-bearing intrusions of the Pechenga ore field, which are derivatives of ferropicritic (ferriferous) magmatism.
Abstract: Zircon from Tomtor syenites and kamaphorites was dated following the U-Pb method (SHRIMP-II), and the distribution of trace and rare-earth elements (REE) was studied at the same zircon point using an ion microprobe. The main zircon population from syenites was dated at 402?±?7 Ma, while the age range of single zircon grains was 700-660 M?. Different-aged zircon groups from syenites exhibited the characteristics of magmatic zircon, but their concentrations of REE and other trace elements differed markedly. The REE distribution in 700-660-M? zircon is consistent with that of the typical zircon from syenites (Belousova et al., 2002), while the heavy rare-earth elements (HREE), P, Ti, and Y concentrations of ca. 400-Ma zircon differ from those of older zircon. This is the first isotope-geochemical study of zircon from kamaphorites, and the U-Pb age of ca. 400 M? is within the error limits with of the main zircon population from syenites. The considerable enrichment of REE, C?, Ti, Sr, Y, Nb, and Ba in zircon from kamaphorites may be partly due to the presence of burbankite microinclusions. The trace-element distribution pattern of zircon from kamaphorites is very similar to the geochemical characteristics of zircon from Tiksheozero carbonatites (Tichomirowa et al., 2013). The new age dates for Tomtor syenites and kamaphorites, consistent with 700-660 M? and ca. 400 M? events, support the zircon (Vladykin et al., 2014) and pyrochlore (Antonov et al., 2017) age dates determined following the U-Pb method and those of biotite obtained following the 40Ar-39Ar method (Vladykin et al., 2014).
Abstract: In the northern part of the Anabar Shield, orthopyroxene plagiogneisses of the granulite Daldyn Group host lenses of mafic rocks surrounded by melanocratic rims. According to their chemical composition, the mafic rocks correspond to subalkaline gabbro, the plagiogneisses correspond to granodiorites contaminated with mafic material, and the rims are diorites. The orthopyroxene plagiogneisses of granodiorite composition have 147Sm/144Nd = 0.1097, ?Nd(?) = 1.6, TNd(DM) = 3.47 Ga and are metamorphosed anatectic granitoids with an age of 3.34 Ga. The mafic rocks have high Zr, Th, and Pb contents, are enriched in REE (?REE = 636 ppm), with a high degree of fractionation [(La/Yb)N = 17.73] and a well-defined Eu minimum (Eu/Eu* = 0.51), and have 147Sm/144Nd = 0.099, ?Nd(?) = 1.4 and TNd(DM) = 3.65 Ga. It is assumed that these rocks crystallized from melt derived from an enriched mantle (plume) source. Based on U-Pb (SHRIMP-II) dating of 50 zircon grains from the mafic rocks, a group of grains with concordant ages from 3567 to 1939 Ma was distinguished, along with a large number of discordant values. Multiple measurements in zircon grains with discordant age values make it possible to identify seven grains of Eoarchean age, with upper intercepts of the discordia corresponding to 3987 ± 71 to 3599 ± 33 Ma. The Lu-Hf systematics of 14 zircon grains is characterized by ?Hf(T) = +3.7 and by close values of THf(DM) = 3.95 and TCHf = 3.93 Ga (3.99 Ga for the oldest zircon). The Paleoarchean (3.57 Ga) zircons are characterized by negative values of ?Hf(T) = -5.3 and -6.8, THf(DM) = 3.92-3.98 Ga, and TCHf = 4.14-4.24 Ga, which indicate recycling of the preexisting Eoarchean and Hadean continental crust. The younger zircon (3287-2410 Ma) was also formed when the preexisting crust was recycled.
Abstract: Zircon from Tomtor syenites and kamaphorites was dated following the U-Pb method (SHRIMP-II), and the distribution of trace and rare-earth elements (REE) was studied at the same zircon point using an ion microprobe. The main zircon population from syenites was dated at 402?±?7 Ma, while the age range of single zircon grains was 700-660 M?. Different-aged zircon groups from syenites exhibited the characteristics of magmatic zircon, but their concentrations of REE and other trace elements differed markedly. The REE distribution in 700-660-M? zircon is consistent with that of the typical zircon from syenites (Belousova et al., 2002), while the heavy rare-earth elements (HREE), P, Ti, and Y concentrations of ca. 400-Ma zircon differ from those of older zircon. This is the first isotope-geochemical study of zircon from kamaphorites, and the U-Pb age of ca. 400 M? is within the error limits with of the main zircon population from syenites. The considerable enrichment of REE, C?, Ti, Sr, Y, Nb, and Ba in zircon from kamaphorites may be partly due to the presence of burbankite microinclusions. The trace-element distribution pattern of zircon from kamaphorites is very similar to the geochemical characteristics of zircon from Tiksheozero carbonatites (Tichomirowa et al., 2013). The new age dates for Tomtor syenites and kamaphorites, consistent with 700-660 M? and ca. 400 M? events, support the zircon (Vladykin et al., 2014) and pyrochlore (Antonov et al., 2017) age dates determined following the U-Pb method and those of biotite obtained following the 40Ar-39Ar method (Vladykin et al., 2014).
Abstract: Very few zircon-bearing, kimberlite-hosted mantle eclogite xenoliths have been identified to date; however, the zircon they contain is crucial for our understanding of subcratonic lithospheric mantle evolution and eclogite genesis. In this study, we constrain the characteristics of zircon from mantle eclogite xenoliths based on existing mineralogical and geochemical data from zircons from different geological settings, and on the inferred origin of mantle eclogites. Given the likely origin and subsequent evolution of mantle eclogites, we infer that the xenoliths can contain zircons with magmatic, metamorphic and xenogenic (i.e. kimberlitic zircon) origins. Magmatic zircon can be inherited from low-pressure mafic oceanic crust precursors, or might form during direct crystallization of eclogites from primary mantle-derived melts at mantle pressures. Metamorphic zircon within mantle eclogites has a number of possible origins, ranging from low-pressure hydrothermal alteration of oceanic crustal protoliths to metasomatism related to kimberlite magmatism. This study outlines a possible approach for the identification of inherited magmatic zircon within subduction-related mantle eclogites as well as xenogenic kimberlitic zircon within all types of mantle eclogites. We demonstrate this approach using zircon grains from kimberlite-hosted eclogite xenoliths from the Kasai Craton, which reveals that most, if not all, of these zircons were most likely incorporated as a result of laboratory-based contamination.
Geochemistry, Vol. 80, doi.org/10.1016 /j.chemer. 2019.04.001 11p. Pdf
Russia
deposit - Tomtor
Abstract: Zircon from Tomtor syenites and kamaphorites was dated following the U-Pb method (SHRIMP-II), and the distribution of trace and rare-earth elements (REE) was studied at the same zircon point using an ion microprobe. The main zircon population from syenites was dated at 402?±?7 Ma, while the age range of single zircon grains was 700-660 M?. Different-aged zircon groups from syenites exhibited the characteristics of magmatic zircon, but their concentrations of REE and other trace elements differed markedly. The REE distribution in 700-660-M? zircon is consistent with that of the typical zircon from syenites (Belousova et al., 2002), while the heavy rare-earth elements (HREE), P, Ti, and Y concentrations of ca. 400-Ma zircon differ from those of older zircon. This is the first isotope-geochemical study of zircon from kamaphorites, and the U-Pb age of ca. 400 M? is within the error limits with of the main zircon population from syenites. The considerable enrichment of REE, C?, Ti, Sr, Y, Nb, and Ba in zircon from kamaphorites may be partly due to the presence of burbankite microinclusions. The trace-element distribution pattern of zircon from kamaphorites is very similar to the geochemical characteristics of zircon from Tiksheozero carbonatites (Tichomirowa et al., 2013).The new age dates for Tomtor syenites and kamaphorites, consistent with 700-660 M? and ca. 400 M? events, support the zircon (Vladykin et al., 2014) and pyrochlore (Antonov et al., 2017) age dates determined following the U-Pb method and those of biotite obtained following the 40Ar-39Ar method (Vladykin et al., 2014).
Abstract: This study highlights the usefulness of rutile when applied for reconstruction of the metamorphic evolution of ultrahigh-pressure rocks containing diamond. Within the diamondiferous kyanite gneiss (Kokchetav massif, Northern Kazakhstan), rutile shows three distinct textural positions: (i) rounded/irregular-shaped grains in the rock matrix; (ii) monomineralic inclusions in garnet, kyanite, quartz, and zircon; and (iii) grains in polyphase inclusions within garnet and kyanite porphyroblasts. High Nb (1990-3197 ppm) and relatively low Cr (404-703 ppm) concentrations in rutile indicate its metapelitic derivation. The Zr content in rutile varies from 480 to 798 ppm and the average temperature estimates yielded by the Zr-in-rutile geothermometer for 5 GPa are 880 °C. Rutile-hosted Zn-rich (up to 1.74 wt% ZnO) staurolite is interpreted as a record of the prograde metamorphic stage formed as a result of gahnite+pyrophyllite+diaspore breakdown at 0.3-0.8 GPa, 400-450 °C. Inclusions of diamond±CO2 ± carbonate±garnet in rutile originated near the peak of metamorphism (~5 GPa and ~ 880 °C). U-Pb ID-TIMS dating of a representative rutile separate yielded a concordant age of 519 ± 1.6 Ma that is younger than the previously estimated U-Pb crystallization ages of the peak metamorphic assemblages of the Kokchetav massif (528 ± 3 Ma). The obtained age represents the timing of cooling to the closure temperature for Pb diffusion in rutile (Tc; 420-640 °C). The cooling of the rocks from the peak temperatures to Tc occurred with the rates of 27-51 °C/Ma, whereas the exhumation rates (from 880 °C and 5 GPa to 420-640 °C and 0.5-1 GPa) were 1.3-1.5 cm/year. The peak temperature estimates as well as rapid cooling and exhumation rates reported here are in agreement with published data on zircon from similar diamondiferous Kokchetav gneisses. This work demonstrates that rutile provides a beneficial tool in studies dealing with reconstruction of the metamorphic evolution of diamondiferous rocks.
Abstract: To clarify the tectonic-thermal evolution of the Anabar tectonic province in the central Siberian Craton, we performed an isotope-geochemical study of 20 xenoliths from the Udachnaya, Zarnitsa, and Komsomolskaya kimberlite pipes to represent different crustal levels. Most mafic granulites have Proterozoic Nd model ages and geochemical characteristics close to those of intraplate basalts, whereas some mafic and intermediate granulites with Archean model ages exhibit geochemical features of supra-subduction ophiolitic basalts. Analysis of U-Pb ages and hafnium isotopic composition of zircon indicates that the main tectonic-thermal events modified the crust at 2.7 and 1.9-1.8?Ga, which is consistent with ages of mantle depletion events from previous studies. All zircons have Archean Hf model ages (3.2?Ga). Overall, thermal events with ages of 2.9-2.8, 2.7, 2.4, 1.97 and 1.8?Ga have remarkable influence on the studied zircons. Tectono-thermal events at 2.4 1.97, 1.9 and 1.8?Ga with no addition of juvenile material are recorded by zircons from xenoliths of mafic and intermediate granulites and metadiorites. A compilation of isotope-geochemical data demonstrates that instead of age-stratified, the crust of the Anabar tectonic province consists of variably reworked Paleoarchean rocks and juvenile Proterozoic rocks at all crustal levels. Hence the crust and mantle of the Siberian Craton has been coupled since the Paleoarchean.
Abstract: Microinclusions of high-density fluids (HDF's) occur in cloudy diamonds from the Mir and Internatsionalnaya kimberlite pipes (Malobotuobia kimberlite field, Siberian platform). These HDFs are of typical high-Mg carbonatitic composition; a few diamonds contain microinclusions that define a low-Mg carbonatitic to silicic trend. The observed variations are interpreted as resulted from mixing of two contrasting fluids derived from the partial melting mainly of carbonated peridotite (the high-Mg carbonatitic HDFs) and eclogite (silica-rich HDFs and HDFs with high Ca/(Ca + Mg + Fe)). Immiscibility of carbonatitic and silica-rich fluids provides a possible mechanism for the co-existence of the observed HDFs but needs further proof. The uniform carbon isotope composition of cloudy diamonds with high-Mg carbonatitic microinclusions from both kimberlite pipes implies a single peridotitic source.
Abstract: International Symposium on Deep Earth Exploration and Practices Beijing, China -October24-26, 2018The protolithnatureof diamondiferous metamorphic rocks of the Kokchetav MassifVladislav Shatsky1,2,3, Emil Jagoutz4, Olga Kozmenko1, Alexey Ragozin1,3, Sergei Skuzovatov2and Nikolai Sobolev1,31Sobolev Institute of Geology and Mineralogy SB RAS, Novosibirsk, 630090, Russia, [email protected] Institute of Geochemistry SB RAS, Irkutsk, Russia3Novosibirsk State University, Novosibirsk, Russia4Max Planck Institute for Chemistry, Mainz, GermanyUltra-high-pressure diamondiferous rocks (UHP) of the Kokchetav subduction-collision zone are considered as an idealobject for studying the mobility of elements insubduction zones of the continental type. The compositional diversity of metasedimentary rocks subjected to UHP metamorphism makes it difficult to establish the nature of their protoliths. This, in turn, complicates estimatesof the degree of depletionof the UHP metamorphic rocks relative to the protoliths.To clarify the nature of protholiths of the Kokchetav diamondiferous rocks we studied the geochemical features and Sm-Nd isotopic composition of diamondiferous calc-silicate, garnet-pyroxene rocks, high-alumina metapelitesand barren granite-gneisses.The nine samples of the Kumdy Kol mocrodiamond deposit (one granite-gneiss, 4-calc-silicate rocks, 3-garnet-pyroxenite) yielded aSm-Nd whole-rockisochronageof 1052±44 Ma. This age is close to the age of formation of the granitic gneiss basement of the Kokchetav massif (1.2-1.05 Ga) (Glorie et al., 2015). Therefore, we assume that the protoliths of these rocks were basementrocks. In this interpretation, their geochemical features may not be directly related to the processes of ultrahigh-pressure metamorphism.At the same time, the high-alumina rocks of the Barchinsky area are depleted todifferent degreeswithrespect to LREE and K yieldeda whole-rockisochron with an age of 509 ± 32 Ma, which suggests partial melting of these rocks duringthe exhumation stage.It was previously assumed that metasedimentary rocks of the Kokchetav microcontinent are the protoliths of diamondiferous rocks (Buslov et al., 2015). However, this contradicts with Sm-Nd isotopic data for metasedimentary rocks of quartzite-schist sequences of the Kokchetav microcontinent (Kovach et al., 2017). The metasedimentary rocks of the Sharyk Formation are characterized by variations in the ?Nd(t)from +4.1 to -3.3 and intNd(DM)from 1.9 to 1.25 Ga, whereasin the UHP metamorphic rocks ?Nd(t)varies from -7.6 to -13.2, and the model ages range from 2.7 to 2.3 Ga. These data clearly indicate that the metasedimentary rocks of the Kokchetav massif could not be the protolith of the ultrahigh-pressure rocks.
Abstract: The eclogites of the North Muya complex (Eastern Siberia) are located within the Early Neoproterozoic metasedimentary and felsic rocks of the Baikal-Muya Fold Belt (BMFB). The eclogites show subduction-related affinity, with large-ion lithophile (LILE) and light rare-earth element (LREE) enrichment and high field-strength element (HFSE) depletion signatures, similar to the exposed plutonic and volcanic rocks of the Early Neoproterozoic (Early Baikalian) subduction setting in the BMFB. Coupled Nd (?Nd(T) of +6 to ?1.4) and Sr (87Sr/86Sr ratio of 0.705-0.708), along with key trace-element indicators, imply progressive crustal recycling (up to 5-10%) from the Early Precambrian continental rocks to a depleted mantle source or equivalent crustal contribution via intracrustal contamination. Mineral ?18O data (+3.9???+11.5) indicate that the contaminant or recycled crustal substrate might be represented by rocks altered at both low and high-temperature, or result from variable fluid-rock interaction in the subduction channel. Pseudosection modelling of eclogites, coupled with zircon UPb geochronology (~630?Ma) suggest that the Ediacarian high-pressure metamorphic event for different rocks shared a maximum depth corresponding to 2.5-2.7?GPa with variable temperature range (560-760?°C), reflecting their potential relation to distinct slices of the subducted crust. The estimated metamorphic conditions for both the burial and exhumation of rocks indicate a continental subduction setting, but with a relatively cold geotherm (~20-25?°C/kbar). These conditions resulted from the continental subduction of the Baikal-Muya composite structure beneath the relatively thin and immature overlying arc lithosphere of southern Siberia. Some carbonate-bearing eclogites and garnet-pyroxene rocks, metamorphosed under T below 700?°C and a minimum P up to 1.4?GPa, exhibit LREE-enriched patterns and low ?Nd(T) values of ?7 to ?16. These rocks have Paleoproterozoic to Archean model ages and may support the existence of a Paleoproterozoic or older lithosphere in the Baikal-Muya Fold Belt, but their subduction history and origin remain uncertain due to geochemical and isotopic signatures probably overprinted by carbonate metasomatism.
Russian Geology and Geophysics, Vol. 62, pp. 547-556, pdf
Russia, Kazakhstan
deposit - Kokchetav
Abstract: The isotope-geochemical features of diamondiferous metamorphic rocks of the Kokchetav subduction–collision zone (KSCZ) show that both the basement rocks and the sediments of the Kokchetav massif were their protoliths. A whole-rock Sm–Nd isochron from the diamondiferous calc-silicate, garnet–pyroxene rocks and migmatized granite-gneisses of the western block of the KSCZ yielded an age of 1116 ± 14 Ma, while an age of 1.2–1.1 Ga was obtained by U–Pb dating of zircons from the granite-gneiss basement of the Kokchetav microcontinent. Based on these data, we assume that the protoliths of the calc-silicate, garnet–pyroxene rocks and the granite-gneisses of the KSCZ were the basement rocks sharing an initially single Nd source, which was not influenced by high- to ultrahigh-pressure metamorphism (~530 Ma). Therefore, their geochemical features are probably not directly related to ultrahigh-pressure metamorphism. The corresponding rock associations lack isotope-geochemical evidence of partial melting that would occur during ultrahigh-pressure metamorphism, which suggesting that they were metamorphosed under granulite-facies conditions. At the same time, the high-alumina diamondiferous rocks of the Barchi area (garnet–kyanite–mica schists and granofelses), which were depleted to different degrees in light rare-earth elements (REE) and K, have yielded a Sm–Nd whole-rock isochron age of 507 ± 10 Ma indicating partial melting of these rocks during their exhumation stage. The close ?Nd (1100) values of the basement rocks and garnet–kyanite–mica schist with geochemical characteristics arguing against its depletion during high-pressure metamorphism indicate that the basement rocks were a crustal source for high-alumina sediments.
Abstract: Comprehensive studies of zircon xenocrysts from kimberlites of the Kuoika field (northeastern Siberian craton) and several kimberlite fields of the eastern Anabar shield, along with data compilation on the age of kimberlite-hosting terranes, reveal details of the evolution of the northern Siberian craton. The age distribution and trace element characteristic of zircons from the Kuoika field kimberlites (Birekte terrane) provide evidence of significant basic and alkaline-carbonatite magmatism in northern Siberia in the Paleozoic and Mesozoic periods. The abundance of 1.8-2.1 Ga zircons in both the Birekte and adjacent Hapchan terranes (the latter hosting kimberlites of the eastern Anabar shield) supports the Paleoproterozoic assembly and stabilization of these units in the Siberian craton and the supercontinent Columbia. The abundance of Archean zircons in the Hapchan terrane reflects the input of an ancient source other than the Birekte terrane and addresses the evolution of the terrane to west (Magan and Daldyn terranes of the Anabar shield). The present study has also revealed the oldest known remnant of the Anabar shield crust, whose 3.62 Ga age is similar to that of the other ancient domain of Siberia, the Aldan shield. The first Hf isotope data for the Anabar shield coupled with the U-Pb systematics indicate three stages of crustal growth (Paleoproterozoic, Neoarchean and Paleoarchean) and two stages of the intensive crustal recycling in the Paleoproterozoic and Neoarchean. Intensive reworking of the existing crust at 2.5-2.8 Ga and 1.8-2.1 Ga is interpreted to provide evidence for the assembly of Columbia. The oldest Hf model age estimation provides a link to Early Eoarchean (3.7-3.95 Ga) and possibly to Hadean crust. Hence, some of the Archean cratonic segments of the Siberian craton could be remnants of the Earth's earliest continental crust.
Abstract: A comprehensive, internally consistent U-Pb and Lu-Hf isotope data set for 93 mantle-derived zircons from the Yakutian kimberlite province confirms and further refines the four major episodes of kimberlite magmatism on the Siberian craton: 421-409?Ma (Late Silurian-Early Devonian), 358-353?Ma (Late Devonian-Early Carboniferous), 226-218?Ma (Late Triassic), and 161-144?Ma (Middle-Late Jurassic). The relatively narrow, constant range of ?Hf values between +2 and +10 for both the Paleozoic and Mesozoic mantle-derived zircons (and by inference kimberlites) suggests that the volatile-rich magmas were repeatedly sourced from the convecting upper mantle beneath the Siberian craton. This finding is in keeping with the narrow and constant range of ?Nd values for groundmass perovskites from the Yakutian kimberlite province between +1.8 and +5.5 between 420 and 150?Ma. Our preferred model implies that the convecting upper mantle beneath the Yakutian kimberlite province ‘recovered’ rapidly back to ambient conditions shortly after the giant plume-related flood volcanic event that produced the Siberian Traps at 250?Ma. Although close spatial relationships exist between kimberlites and flood basalts on the Siberian craton during both the Paleozoic and Mesozoic, exact timing of the igneous events and the isotopic compositions of the diverse deep-sourced melting products rule out any direct genetic links. Besides the highly economic kimberlite-hosted diamond deposits of Late Devonian age (e.g., Mir and Udachnaya), the Siberian craton also contains significant Mesozoic placer diamond deposits (e.g., along the Anabar river), for which lamproite sources have been suggested recently. Our study shows that mantle-derived zircon megacryst fragments from the Ebelyakh placer deposit have Late Triassic ages of ca. 224?Ma. Their long-term depleted Hf isotopic compositions (+8.5 ?Hf) suggest that the alluvial diamonds were sourced from asthenosphere-derived Triassic kimberlites rather than from lithospheric mantle derived isotopically enriched lamproites.
Abstract: A comprehensive, internally consistent U-Pb and Lu-Hf isotope data set for 93 mantle-derived zircons from the Yakutian kimberlite province confirms and further refines the four major episodes of kimberlite magmatism on the Siberian craton: 421-409?Ma (Late Silurian-Early Devonian), 358-353?Ma (Late Devonian-Early Carboniferous), 226-218?Ma (Late Triassic), and 161-144?Ma (Middle-Late Jurassic). The relatively narrow, constant range of ?Hf values between +2 and +10 for both the Paleozoic and Mesozoic mantle-derived zircons (and by inference kimberlites) suggests that the volatile-rich magmas were repeatedly sourced from the convecting upper mantle beneath the Siberian craton. This finding is in keeping with the narrow and constant range of ?Nd values for groundmass perovskites from the Yakutian kimberlite province between +1.8 and +5.5 between 420 and 150?Ma. Our preferred model implies that the convecting upper mantle beneath the Yakutian kimberlite province ‘recovered’ rapidly back to ambient conditions shortly after the giant plume-related flood volcanic event that produced the Siberian Traps at 250?Ma. Although close spatial relationships exist between kimberlites and flood basalts on the Siberian craton during both the Paleozoic and Mesozoic, exact timing of the igneous events and the isotopic compositions of the diverse deep-sourced melting products rule out any direct genetic links. Besides the highly economic kimberlite-hosted diamond deposits of Late Devonian age (e.g., Mir and Udachnaya), the Siberian craton also contains significant Mesozoic placer diamond deposits (e.g., along the Anabar river), for which lamproite sources have been suggested recently. Our study shows that mantle-derived zircon megacryst fragments from the Ebelyakh placer deposit have Late Triassic ages of ca. 224?Ma. Their long-term depleted Hf isotopic compositions (+8.5 ?Hf) suggest that the alluvial diamonds were sourced from asthenosphere-derived Triassic kimberlites rather than from lithospheric mantle derived isotopically enriched lamproites.
Abstract: Five typical coated diamonds (from Udachnaya, Yubileynaya, and Aikhal kimberlite pipes) with untypically low microinclusion abundances and four monocrystalline diamonds (Udachnaya, Mir, Nyurbinskaya pipes) that exhibit thin intermediate microinclusion-bearing zones were examined in details for growth structures, characteristic infrared absorption and photoluminescence, and composition of microinclusions. The internal structures of diamonds of both types imply that fluid inclusions entrapment in diamonds does not necessarily relate to the terminal stage of rapid fibrous growth. Instead, nitrogen aggregation state in some diamonds showed that both fibrous coats and inclusion-bearing layers might experience an annealing during mantle residence long enough to pre-date the ultimate kimberlite eruption, whereas the diamonds with internal inclusion-bearing zones also experienced later protracted history of monocrystalline growth. The presence of chloride-carbonate-silicate fluids/melts in monocrystalline diamonds indicate their generation from media generally similar to that observed in some fibrous diamonds. However, the composition of these metasomatizing fluids is different for the mantle beneath Udachnaya (mostly carbonatitic) and other pipes (Aikhal, Yubileynaya, Mir; variable abundance of silicic high-density fluids). The abundance of silica-rich fluids record either a heterogeneous distribution of eclogites in the subcontinental lithospheric mantle, or the operation of silica-rich slab-derived fluids. The inclusion abundance as well as the type of growth (fibrous or monocrystalline) is considered to be controlled by the volume of fluid fluxes; in this case, fluid consumption leads to decreasing growth rates, diminishing inclusion entrainment and stability of layered octahedrons. The detected minor compositional variations of high-density fluids in these diamonds may be due to local scale thermal perturbation in the host source and/or limited chemical heterogeneity of the parental fluid. The high amount of chlorides in high-density fluids from monocrystalline diamonds provide a new evidence for compositions of fluids/melts acting as primary metasomatic agent in the deep mantle of Siberian craton.
Contributions to Mineralogy and Petrology, Vol. 175, 106, 21p. Pdf
Russia
deposit - Nyurbinskaya
Abstract: We present a new dataset on the composition of high-density fluids (HDFs) in cloudy (n?=?25), coated (n?=?10) and cuboid (n?=?10) diamonds from the Nyurbinskaya kimberlite pipe. These diamonds represent different populations each showing distinct growth histories. The cores of coated diamonds display multiple growth stages and contrasting sources of carbon. Fibrous coats and cuboid diamonds have similar carbon isotopes and nitrogen systematics, suggesting their formation in the last metasomatic events related to kimberlite magmatism, as is common for most such diamonds worldwide. The HDFs in most of these diamonds span a wide range from low-Mg carbonatitic to hydrous silicic compositions. The major- and trace-element variations suggest that the sources for such HDFs range in composition between the depleted mantle and more fertile mantle reservoirs. Hydrous-silicic HDFs could originate from a 13C-enriched source, which originates through subduction of crustal metasedimentary material. Percolation of such HDFs through carbonated eclogites and peridotites facilitates the formation of cuboid diamonds and fibrous coats in the mantle section beneath the corresponding area of the Siberian craton. Cloudy diamonds represent an apparently older population, reflecting continuous diamond formation predominantly from high-Mg carbonatitic HDFs that caused discrete episodes of diamond precipitation. Their high Mg# and enrichment in incompatible elements support a metasomatized peridotitic source for these HDFs.
International Geology Review, Vol. 64, 8, pp. 1119-1138.
Russia, Siberia
kimberlite magmatism
Abstract: Zircon xenocrysts from two diamond-barren kimberlite pipes (Leningrad and Ruslovaya) in the West Ukukit kimberlite field opened a ‘window’ to the buried crustal basement in the northern Siberian craton. Zircon U-Pb ages reveal a close affinity of the basement of the Khapchan belt to the Archaean Anabar province and a significant tectonomagmatic reworking in the Paleoproterozoic (~2.1-1.8 Ga) due to collision between the Anabar province and the Olenek province. The West Ukukit kimberlite field experienced multiple tectonomagmatic reactivation from ~670 to 144 Ma, which can be attributed to interaction of the deep crust with mantle-derived melts. Hf isotope composition of zircon xenocrysts reveals significant addition of juvenile material into the crust during the Paleoproterozoic orogeny in diamond-barren kimberlite fields, which is different from the reworking crust in the southern Yakutia diamondiferous kimberlite fields. Eruption of the Leningrad and Ruslovaya pipes were constrained as the Late Jurassic, much later than the well-known Late Silurian-Earth Devonian kimberlites in the West Ukukit kimberlite field. A NE-trending, >2000 km long kimberlite corridor is proposed to account for a prolonged lithospheric channel for episodic eruption of kimberlites in the Siberian craton. The diamond storage in the lithosphere beneath the West Ukukit kimberlite field may have been largely reduced by the Paleoproterozoic orogeny and Phanerozoic reworking.
Multiple growth events in diamonds with cloudy Micro inclusions from the Mir kimberlite pipe: evidence from the systematics of optically active defects.
Russian Geology and Geophysics, Vol. 56, 1, pp. 330-343.
Russian Geology and Geophysics, Vol. 56, pp. 1016-1034.
Russia
Kokchetav massif
Abstract: We studied clastics of high-alumina garnet-kyanite-mica schists and garnet-kyanite-quartz granofelses, including diamond-bearing ones, found in the eluvial sediments near Lake Barchi. In contents of major elements the studied rocks correspond to argillaceous shales. The garnet-kyanite-quartz granofelses are poorer in K (0.49-1.35 wt.% K2O) than the garnet-kyanite-mica schists (4.9-2.2 wt.% K2O) but have the same contents of other major components. The REE patterns of most of the garnet-kyanite-phengite schists are similar to those of the Post-Archean Australian Shale (PAAS) (xLa/Yb = 13). All garnet-kyanite-quartz rocks are much stronger depleted in LREE (xLa/Yb = 1.4) and other incompatible elements. Our studies show that allanite and monazite are the main concentrators of LREE and Th in the garnet-kyanite-phengite rocks of the Barchi site. Monazite, occurring as inclusions in garnet, contains not only LREE but also Th, U, and Pb. Rutile of the nondepleted rocks is enriched in Fe and Nb impurities only. The garnet-kyanite-quartz granofelses bear rutile, apatite, and xenotime as accessory phases. Rutile of the depleted rocks shows wide variations in contents of Nb, Ta, and V impurities. In places, the contents of Nb and Ta reach 10.5 and 2.3 wt.%, respectively. The rutile decomposes into rutile with Nb (1.4 wt.%) and Fe (0.87 wt.%) impurities and titanium oxide rich in Fe (6.61 wt.%), Nb (up to 20.8 wt.%), and Ta (up to 2.81%) impurities. Based on the measured contents of incompatible elements in differently depleted high-alumina rocks, the following series of element mobility during UHP metamorphism has been established: Th > Ce > La > Pr > Nd > K > Ba > Rb > Cs > Sm > Eu. The contents of U, P, and Zr in the depleted rocks are similar to those in the nondepleted rocks. The studies have shown that metapelites subducted to the depths with diamond stability conditions can be depleted to different degrees. This might be either due to their exhumation from different depths of the subduction zone or to the presence of an external source of water controlling the temperature of dissolution of phengite and the formation of supercritical fluid/melt.
Mineralogy and Petrology, 10.1007/s0710-019-00661-3
Russia
diamond morphology
Abstract: Five typical coated diamonds (from Udachnaya, Yubileynaya, and Aikhal kimberlite pipes) with untypically low microinclusion abundances and four monocrystalline diamonds (Udachnaya, Mir, Nyurbinskaya pipes) that exhibit thin intermediate microinclusion-bearing zones were examined in details for growth structures, characteristic infrared absorption and photoluminescence, and composition of microinclusions. The internal structures of diamonds of both types imply that fluid inclusions entrapment in diamonds does not necessarily relate to the terminal stage of rapid fibrous growth. Instead, nitrogen aggregation state in some diamonds showed that both fibrous coats and inclusion-bearing layers might experience an annealing during mantle residence long enough to pre-date the ultimate kimberlite eruption, whereas the diamonds with internal inclusion-bearing zones also experienced later protracted history of monocrystalline growth. The presence of chloride-carbonate-silicate fluids/melts in monocrystalline diamonds indicate their generation from media generally similar to that observed in some fibrous diamonds. However, the composition of these metasomatizing fluids is different for the mantle beneath Udachnaya (mostly carbonatitic) and other pipes (Aikhal, Yubileynaya, Mir; variable abundance of silicic high-density fluids). The abundance of silica-rich fluids record either a heterogeneous distribution of eclogites in the subcontinental lithospheric mantle, or the operation of silica-rich slab-derived fluids. The inclusion abundance as well as the type of growth (fibrous or monocrystalline) is considered to be controlled by the volume of fluid fluxes; in this case, fluid consumption leads to decreasing growth rates, diminishing inclusion entrainment and stability of layered octahedrons. The detected minor compositional variations of high-density fluids in these diamonds may be due to local scale thermal perturbation in the host source and/or limited chemical heterogeneity of the parental fluid. The high amount of chlorides in high-density fluids from monocrystalline diamonds provide a new evidence for compositions of fluids/melts acting as primary metasomatic agent in the deep mantle of Siberian craton.
Abstract: U-Pb geochronological, trace?element and Lu-Hf isotopic studies have been made on zircons from ultrahigh?pressure (UHP) mafic eclogite from the Kumdy?Kol area, one of the diamond?facies domains of the Kokchetav Massif (northern Kazakhstan). The peak eclogitic assemblage equilibrated at >?900?°C, whereas the bulk sample composition displays light rare?earth element (LREE) and Th depletion evident of partial melting. Zircons from the eclogite are represented by exclusively newly formed metamorphic grains and have U-Pb age spread over 533-459?Ma, thus ranging from the time of peak subduction burial to that of the late post?orogenic collapse. The major zircon group with concordant age estimates have a concordia age of 508.1?±4.4?Ma, which corresponds to exhumation of the eclogite?bearing UHP crustal slice to granulite? or amphibolite?facies depths. This may indicate potentially incoherent exhumation of different crustal blocks within a single Kumdy?Kol UHP domain. Model Hf isotopic characteristics of zircons (?Hf(t) +1.5 to +7.8, Neoproterozoic model Hf ages of 1.02-0.79?Ga) closely resemble the whole?rock values of the Kumdy?Kol eclogites and likely reflect in situ derivation of HFSE source for newly formed grains. The ages coupled with geochemical systematics of zircons confirm that predominantly late zircon growth occurred in Th-LREE?depleted eclogitic assemblage, that experienced incipient melting and monazite dissolution in melt at granulite?facies depths, followed by amphibolite?facies rehydration during late?stage exhumation?related retrogression.
Doklady Earth Sciences, Vol. 465, 1, pp. 1187-1190.
Russia
Deposit - Udachnaya
Abstract: The composition, structure, and morphology of iron-containing diamond-kimberlite contact sites were studied by means of scanning electron microscopy and Raman spectroscopy. The data obtained confirm the hypothesis of the similarity of mechanisms of diamond formation in nature and in experiments.
Doklady Earth Sciences, Vol. 476, 2, pp. 1155-1158.
Russia, Yakutia
deposit - Udachnaya
Abstract: The crystallographic orientation of three diamonds and 19 olivine inclusions from Udachnaya kimberlite pipe was studied using monocrystal X-ray diffractometry. No epitaxial olivine inclusions were found.
Abstract: The paper presents a summary of extensive experiments on diamond resorption rates in presence of various ions performed at Prof. Rudenko lab at Moscow State University. For the first time all experimental data are shown together allowing direct comparison. Surface features of the samples etched in different conditions were studied using optical, scanning electron and atomic force microscopy. It is shown that catalytic theory of diamond resorption, a variant of topochemical adsorption theory of crystal etching, explains dramatic differences between activities of ions from different groups of periodic table on diamond resorption rate at least on qualitative level. Strong variations in surface features on diamonds etched in presence of ions with various catalytic activities are observed.
Optics and Spectroscopy, Vol. 127, 3, pp. 564-570. doi.org/10.3390/min100100018
Global
luminescence
Abstract: To identify the signs that distinguish natural diamonds from artificial diamonds, a comparative analysis of the luminescence spectra with regards to the Q factor, center of gravity, bandwidth parameter, and energy losses in the diamond crystal lattice under conditions of ohmic and dielectric relaxation of luminescence is performed. The phenomenon of resonant luminescence in the femtosecond time range is detected in diamond. It is established that natural and artificial diamonds noticeably differ in the relaxation frequency and in the energy of resonant radiation.
Journal of Geological Society of India, Vol. 88, 5, pp. 539-548.
India
Craton, Bundelkhand
Abstract: Two Archaean supracrustal complexes are documented in the Bundelkhand craton viz. 1) the Central Bundelkhand greenstone complex (formed the Babina and Mauranipur belts), and 2) the Southern Bundelkhand metasedimentary (paragneisses, schists) complex (formed the Girar belt). The Central Bundelkhand greenstone complex consists of (i) an early assemblage composed of basic-ultrabasic, felsic volcanics, banded iron formation (BIF), and (ii) a late assemblage which contains felsic volcanics. The U-Pb zircon ages of felsic volcanics from the early assemblage, formed in an arc-type subduction setting, are 2813 Ma (Mesoarchaean). The U-Pb zircon ages of felsic volcanics from the late assemblage, which also occur in subduction settings as an active continental marginal type, are 2542 Ma (Neoarchaean). The Girar belt, located in the southern part of the craton, consists generally of metasedimentary rocks namely quartzites and BIFs. Quartzites are represented by fuchsite- and hematite- bearing quartz arenite and lesser quartz pebble conglomerates that have been subjected to low-grade metamorphism. BIF is represented by thinly-bedded quartz-hematite (±magnetite) rocks. Some lenses of marble and chlorite schist are present at the contact between the two formations. BIF is fairly rich in Cr and Ni, poor in Zr, Hf, Ba, Th, Sr, Yb and Lu, and displays a distinct positive Euanomaly (Eu/Eu* = 1.14-2.46). Zircons from quartzites give two U-Pb ages: 3432±9.7 Ma and 3252±6.4 Ma. The Sm-Nd isotope study of quartzite from the Girar belt shows that the TDM is 3.29 Ga. This TDM correlates well with the U-Pb ages of zircon and indicates that the continental crust in the Girar area began to form in the Paleoarchaean (3.4-3.2 Ga). The Central Bundelkhand greenstone complex was thus formed in a subduction-accretion setting in Mesoarchaean (ca 2.8 Ga) and Neoarchaean (2.54 Ga) time, and the Southern Bundelkhand metasedimentary complex originated in a sedimentary basin on the old continental crust apparently at ca ~ 2.7 Ga.
Russian Geology and Geophysics, Vol. 62, pp. 525-546. pdf
Europe, Finland, Sweden
eclogites
Abstract: The Belomorian Province (BP) of the Fennoscandian Shield is a high-grade belt composed of Meso- to Neoarchean tonalite- trondhjemite-granodiorite (TTG) gneisses with subordinate supracrustal complexes. The Belomorian crust is underlined by a thick mantle keel, a structural element typical of Archean cratons. Belomorian rocks were metamorphosed under conditions of mainly high-pressure amphibolite to granulite facies in both Archean and Paleoproterozoic times. The TTG gneisses contain numerous blocks of almost completely retrogressed eclogite (eclogite-1). This paragenetic association of eclogite-1 and gneisses can be classified as an Archean eclogite-TTG gneiss mélange, a component of the Belomorian continental crust produced by subductional, accretionary, and collisional processes of the Belomorian collisional orogeny 2.9-2.66 Ga. The Paleoproterozoic history of the BP comprises of two prominent tectonic periods: (i) early Paleoproterozoic (~2.5-2.4 Ga), related to a superplume, and (ii) late Paleoproterozoic (2.0-1.85 Ga), resulted from crustal reworking during the Lapland-Kola collisional orogeny that produced strong penetrative metamorphic and local deformational overprint. The Paleoproterozoic highest-grade metamorphic overprint is represented by patches of eclogites (eclogite-2) in Paleoproterozoic mafic dikes and eclogite-1. Field relations between eclogite-1 and eclogite-2 are described in the Gridino area of the western coast of the White Sea. So, the BP is a high-grade polymetamorphic belt formed by a superposition of the Neoarchean Belomorian and Paleoproterozoic Lapland-Kola orogenies, whose characteristic features are eclogites produced by subduction and collision.
Abstract: Carbonatites (sensu stricto) are igneous rocks typically associated with continental rifts, being emplaced at relatively shallow crustal levels or as extrusive rocks. Some carbonatites are, however, related to subduction and lithospheric collision zones, but so far no carbonatite has been reported from ultrahigh-pressure (UHP) metamorphic terranes. In this study, we present detailed petrological and geochemical data on carbonatites from the Tromsø Nappe—a UHP metamorphic terrane in the Scandinavian Caledonides. Massive to weakly foliated silicate-rich carbonate rocks, comprising the high-P mineral assemblage of Mg-Fe-calcite?±?Fe-dolomite?+?garnet?+?omphacitic clinopyroxene?+?phlogopite?+?apatite?+?rutile?+?ilmenite, are inferred to be carbonatites. They show apparent intrusive relationships to eclogite, garnet pyroxenite, garnet-mica gneiss, foliated calc-silicate marble and massive marble. Large grains of omphacitic pyroxene and megacrysts (up to 5?cm across) of Cr-diopside in the carbonatite contain rods of phlogopite oriented parallel to the c-axis, the density of rods being highest in the central part of the megacrysts. Garnet contains numerous inclusions of all the other phases of the carbonatite, and, in places, composite polyphase inclusions. Zircon, monazite and allanite are common accessory phases. Locally, veins of silicate-poor carbonatite (up to 10?cm across) occur. Extensive fenitization by K-rich fluids, with enrichment in phlogopite along contacts between carbonatite and silicate country rocks, is common. Primitive mantle-normalized incompatible element patterns for the carbonatite document a strong enrichment of light rare earth elements, Ba and Rb, and negative anomalies in Th, Nb, Ta, Zr and Hf. The carbon and oxygen isotope compositions of the carbonatite are distinctly different from those of the spatially associated calc-silicate marble, but also from mantle-derived carbonatites elsewhere. Neodymium and Sr isotope data coupled with the trace element distribution indicate a similarity of the Tromsø carbonatite to orogenic (off-craton) carbonatites rather than to anorogenic (on-craton) ones. U-Pb dating of relatively U-rich prismatic, oscillatory-zoned zircon gives an age of 454•5?±?1•1?Ma. We suggest that the primary carbonatite magma resulted from partial melting of a carbonated eclogite at UHP, in a deeply subducted continental slab.
Abstract: We report on the Lu-Hf and Re-Os isotope systematics of a well-characterized suite of spinel and garnet pyroxenites from the Gföhl Unit of the Bohemian Massif (Czech Republic, Austria). Lu-Hf mineral isochrons of three pyroxenites yield undistinguishable values in the range of 336-338 Ma. Similarly, the slope of Re-Os regression for most samples yields an age of 327 ± 31 Ma. These values overlap previously reported Sm-Nd ages on pyroxenites, eclogites and associated peridotites from the Gföhl Unit, suggesting contemporaneous evolution of all these HT-HP rocks. The whole-rock Hf isotopic compositions are highly variable with initial ?Hf values ranging from ? 6.4 to + 66. Most samples show a negative correlation between bulk rock Sm/Hf and ?Hf and, when taking into account other characteristics (e.g., high 87Sr/86Sr), this may be explained by the presence of recycled oceanic sediments in the source of the pyroxenite parental melts. A pyroxenite from Horní Kounice has decoupled Hf-Nd systematics with highly radiogenic initial ?Hf of + 66 for a given ?Nd of + 7.8. This decoupling is consistent with the presence of a melt derived from a depleted mantle component with high Lu/Hf. Finally, one sample from Be?váry plots close to the MORB field in Hf-Nd isotope space consistent with its previously proposed origin as metamorphosed oceanic gabbro. Some of the websterites and thin-layered pyroxenites have variable, but high Os concentrations paralleled by low initial ?Os. This reflects the interaction of the parental pyroxenitic melts with a depleted peridotite wall rock. In turn, the radiogenic Os isotope compositions observed in most pyroxenite samples is best explained by mixing between unradiogenic Os derived from peridotites and a low-Os sedimentary precursor with highly radiogenic 187Os/188Os. Steep increase of 187Os/188Os at nearly uniform 187Re/188Os found in a few pyroxenites may be connected with the absence of primary sulfides, but the presence of minor late stage sulfide-bearing veinlets likely associated with HT-HP metamorphism at crustal conditions.
International Journal of Earth Sciences, Vol. 106, 8, pp. 1-36.
Africa, Namibia
craton
Abstract: Early Neoproterozoic metaigneous rocks occur in the central part of the Kaoko-Dom Feliciano-Gariep orogenic system along the coasts of the southern Atlantic Ocean. In the Coastal Terrane (Kaoko Belt, Namibia), the bimodal character of the ca. 820-785 Ma magmatic suite and associated sedimentation sourced in the neighbouring pre-Neoproterozoic crust are taken as evidence that the Coastal Terrane formed as the shallow part of a developing back arc/rift. The arc-like chemistry of the bimodal magmas is interpreted as inherited from crustal and/or lithospheric mantle sources that have retained geochemical signature acquired during an older (Mesoproterozoic) subduction-related episode. In contrast, the mantle contribution was small in ca. 800-770 Ma plutonic suites in the Punta del Este Terrane (Dom Feliciano Belt, Uruguay) and in southern Brazil; still, the arc-like geochemistry of the prevalent felsic rocks seems inherited from their crustal sources. The within-plate geochemistry of a subsequent, ca. 740-710 Ma syn-sedimentary volcanism reflects the ongoing crustal stretching and sedimentation on top of the Congo and Kalahari cratons. The Punta del Este-Coastal Terrane is interpreted as an axial part of a Neoproterozoic “Adamastor Rift”. Its opening started in a back-arc position of a long-lasting subduction system at the edge of a continent that fragmented into the Nico Pérez-Luís Alves Terrane and the Congo and Kalahari cratons. The continent had to be facing an open ocean and consequently could not be located in the interior of the Rodinia. Nevertheless, the early opening of the Adamastor Rift coincided with the lifetime of the circum-Rodinia subduction system.
Abstract: On the basis of quantum-chemical calculations of the linear to isomeric bent transition of the SiO2 molecule, it is suggested that the bent to linear transition of SiO2 forms can occur in melted mantle minerals of the lower mantle. This may be important for the formation of the peculiarities of mantle convection and origination of plumes.
Nuclear Instruments and Methods in Physics Research Section A., A785, pp. 9-13.
Technology
Methodology
Abstract: A new technology for diamond detection in kimberlite based on the tagged neutron method is proposed. The results of experimental researches on irradiation of kimberlite samples with 14.1-MeV tagged neutrons are discussed. The source of the tagged neutron flux is a portable neutron generator with a built-in 64-pixel silicon alpha-detector with double-sided stripped readout. Characteristic gamma rays resulting from inelastic neutron scattering on nuclei of elements included in the composition of kimberlite are registered by six gamma-detectors based on BGO crystals. The criterion for diamond presence in kimberlite is an increased carbon concentration within a certain volume of the kimberlite sample.
Abstract: Apatite can host significant levels of trace elements, including REE, within its crystal lattice, making it particularly useful for deciphering geological events and processes. This study employs hyperspectral cathodoluminescence (CL) and in situ microchemical techniques to identify and characterize various generations of apatite occurring in the phoscorites, carbonatites, and fenites of the Gifford Creek Carbonatite Complex (GCCC), Western Australia. Hyperspectral CL revealed that apatite crystals in all samples have complex internal zoning, including multiple distinct generations, with zones of relatively bright CL generally having more complex spectra compared to darker CL zones. Most of the CL spectra have prominent sharp peaks at ?1.4 eV and ?2.l eV as well as a broad peak between 2.3 eV and 3.5 eV. We relate these different peaks to individual REE activators and groups of activators, in particular Nd3+, Eu3+, Sm3+, and Ce3+. Trace element analyses of apatite confirm the relative enrichment of REE in the CL brighter zones. Most apatite generations exhibit concave-down to sinusoidal REY patterns lacking Eu anomalies, but often feature distinct negative Y anomalies. The depletion in LREE is interpreted to be due to LREE sequestration into monazite, which is relatively abundant in most of the samples. Most apatite samples contain very low Si contents, but appreciable Na, so REE incorporation into apatite was primarily via a coupled substitution of REE + Na replacing 2Ca, which is consistent with the highly alkaline, low SiO2 environment under which the apatite formed. Based on the combined trace-element signatures and CL textures, we interpret the multiple generations of apatite to reflect magmatic growth from alkaline magmas followed by recrystallization during subsequent metamorphic/hydrothermal events. The notable exception is the apatite core domains from a fenite sample that contain relatively high Si and Mn contents, low Sr, and relatively HREE-enriched REY patterns with distinct negative Eu anomalies. This apatite is interpreted to be relict from the granitic precursor to fenitization. The apatite samples also show systematic compositional variations across the GCCC, with apatite from phoscorite samples from the southeast part of the complex containing higher Sr, lower Gd/Ce, and lower ?3 values (normalized REE pattern inflections) compared to apatite from the northwest part of the complex. Recognition of these spatial variations in apatite compositions from the intra-grain micro-scale through to the district scale demonstrates the utility of combining advanced petrographic methods, such as hyperspectral CL, with micro-chemical analysis to reveal complex geological records preserved in apatite. As apatite is a common accessory mineral, these techniques may be more broadly applicable to igneous source tracing, understanding metamorphic and/or metasomatic processes, provenance studies from detrital mineral records, and studies of the evolution of ore systems.
Abstract: The Gifford Creek Carbonatite Complex (GCCC), Western Australia contains a diverse suite of alkaline igneous rocks, including magnesiocarbonatites, ferrocarbonatites, phoscorites, fenites, magmatic-hydrothermal peralkaline dykes, and ironstones. This study employs U-Pb, Sm-Nd, and Lu-Hf radiogenic isotope techniques on monazite - (Ce), fluorapatite, and zircon to determine the origin, age, and history of the GCCC. Zircon crystals found in glimmerite alteration selvages adjacent to ferrocarbonatites exhibit pyramidal crystal morphologies, ?Hf values of ?1.8 to ?4.3, high Th/U, and variable Zr/Hf, all of which are indicative of carbonatitic zircon sourced from an enriched mantle component. Uranium-Pb dating of these zircons returned a definitive magmatic age of ~1370?Ma for the GCCC. Monazite hosted in the ferrocarbonatites, phoscorites, and fenite alteration assemblages yielded variable U-Pb ages ranging from ca. 1250?Ma to 815?Ma. Neodymium isotope isochrons determined from coexisting monazite and apatite gave ages between ca. 1310?Ma to ca. 1190?Ma, but all with similar initial 143Nd/144Nd values of 0.51078-0.51087. The 1370?Ma age of the GCCC does not correspond to any known mantle plume activity, but does broadly correlate with the separation of the North China Craton from the West Australian Craton as part of the greater breakup of Nuna. The monazite and apatite ?Nd data illustrate that the multiple younger U-Pb monazite and Nd isotope isochron ages are not recording multiple magmatic intrusions into the complex, but rather represent partial recrystallisation/resetting of REE-bearing minerals during the protracted tectonic history of the Western Australia Craton from ~1300?Ma to 815?Ma and its involvement in the breakup of Nuna and assembly and disassembly of Rodinia. The age variability in the U-Pb and the Sm-Nd isotope systems in monazite and apatite reveal that tectonically-induced hydrothermalism can contribute to the isotopic resetting of phosphate minerals. This age resetting, if properly identified, can be used as a thorough geochronological record of tectonism affecting alkaline igneous complexes after initial magmatic emplacement.
Contributions to Mineralogy and Petrology, Vol. 175, 28p. Pdf.
Australia
carbonatite
Abstract: The 1370 Ma Gifford Creek Carbonatite Complex (GCCC) comprises a diverse suite of alkaline dyke and sill complexes that cover an area of?~?250 km2 in the Gascoyne Province, Western Australia. Most carbonatite types are interpreted to be related products of fractional crystallisation, with calcite carbonatites representing cumulate rocks and dolomite carbonatites representing crystallised products of the derivative liquids. Genetic relationships between these carbonatites and other alkaline igneous units are less clear. The ankerite-siderite carbonatites and magnetite-biotite dykes are likely of related magmatic origin as both have distinctly high LREE and low HFSE contents. The ankerite-siderite carbonatites have mantle-like ?13C isotope values of ? 6.1 to ? 7.1‰ and similar geochemistry to other known magmatic ferrocarbonatites. Silica-rich alkaline veins found near the centre of the complex have trace element signatures that are antithetic to the magnetite-biotite dykes, so these veins are interpreted to represent products of alkali- and F-rich magmatic-hydrothermal fluids exsolved from the magnetite-biotite dykes during their emplacement. Carbon, O, Sr, and Nd isotope data are consistent with an enriched mantle source for the origin of the GCCC, with mantle enrichment likely caused by plate convergence processes associated with the c. 2.0 Ga Glenburgh Orogeny. There is no evidence to link mantle plume activity with formation of the GCCC; rather, alkaline magmatism is interpreted to result from low degree melting of the metasomatised mantle during reactivation of the crustal suture zone at 1370 Ma. The carbonatitic magmas utilised the Lyons River Fault to traverse the crust to be emplaced as the GCCC. Post magmatic alteration has variably modified the O and Sr isotope compositions of carbonates from these rocks. We therefore appeal for careful evaluation of isotopic data from ancient carbonatites, as isotopic resetting may be more common than currently recognised.
Abstract: Australia is host to a diverse range of rare earth element (REE) ore deposits, and therefore is well placed to be a major supplier of REE into the future. This paper presents a review of the geology and tectonic setting of Australia's hard-rock REE resources. The deposits can be classified into four groups: 1. Carbonatite associated; 2. Peralkaline/alkaline volcanic associated; 3. Unconformity related, and; 4. Skarns and iron-oxide?copper?gold (IOCG) related. With the exception of the unconformity related deposits, all of these deposit groups are directly or indirectly related to continental alkaline magmatism. Extensive fractional crystallisation and/or igneous accumulation of REE minerals were essential ore-forming processes for carbonatite-associated and peralkaline/alkaline volcanic-associated deposits, while hydrothermal transport and concentration of REE sourced from basement rocks was responsible for producing ore in unconformity-related, skarns and, potentially, IOCG deposits. The economic potential of many deposits has also been enhanced by supergene alteration processes. All of Australia's REE deposits formed in an intracontinental setting in association with crustal-scale fault zones or structures that acted as transport conduits for ore-forming magmas or fluids. Most deposits formed in the Mesoproterozoic under conditions of relative tectonic quiescence. There is little evidence for the involvement of mantle plumes, with the exception of the Cenozoic peralkaline volcanic systems of eastern Australia, and possibly the IOCG deposits. Instead, ore productive magmas were generated by melting of previously-enriched mantle lithosphere in response to disruption of the lithosphere-asthenophere boundary due to fault activation. REE minerals in many deposits also record episodes of recrystallisation/resetting due to far-field effects of orogenic activity that may significantly postdate primary ore formation. Therefore, REE orebodies can be effective recorders of intracontinental deformation events. In general, Australia's inventory of REE deposits is similar to the global record. Globally, the Mesoproterozoic appears to be a particularly productive time period for forming REE orebodies due to favourable conditions for generating ore-fertile magmas and favourable preservation potential due to a general lack of aggressive continental recycling (i.e., active plate tectonics).
Mineralium Deposita, 10.1007/s00126-020-01026-z 20p. Pdf
Australia
REE
Abstract: The Yangibana rare earth element (REE) district consists of multiple mineral deposits/prospects hosted within the Mesoproterozoic Gifford Creek Carbonatite Complex (GCCC), Western Australia, which comprises a range of rock types including calcite carbonatite, dolomite carbonatite, ankerite-siderite carbonatite, magnetite-biotite dykes, silica-rich alkaline veins, fenite, glimmerites and what have historically been called “ironstones”. The dykes/sills were emplaced during a period of extension and/or transtension, likely utilising existing structures. The Yangibana REE deposits/prospects are located along many of these structures, particularly along the prominent Bald Hill Lineament. The primary ore mineral at Yangibana is monazite, which is contained within ankerite-siderite carbonatite, magnetite-biotite dykes and ironstone units. The ironstones comprise boxwork-textured Fe oxides/hydroxides, quartz, chalcedony and minor monazite and subordinate rhabdophane. Carbonate mineral-shaped cavities in ironstone, fenite and glimmerite alteration mantling the ironstone units, and ankerite-siderite carbonatite dykes altering to ironstone-like assemblages in drill core indicate that the ironstones are derived from ankerite-siderite carbonatite. This premise is further supported by similar bulk-rock Nd isotope composition of ironstone and other alkaline igneous rocks of the GCCC. Mass balance evaluation shows that the ironstones can be derived from the ankerite-siderite carbonatites via significant mass removal, which has resulted in passive REE concentration by ~?2 to ~?10 times. This mass removal and ore tenor upgrade is attributed to extensive carbonate breakdown and weathering of ankerite-siderite carbonatite by near-surface meteoric water. Monazite from the ironstones has strong positive and negative correlations between Pr and Nd, and Nd and La, respectively. These relationships are reflected in the bulk-rock drill assays, which display substantial variation in the La/Nd throughout the GCCC. The changes in La/Nd are attributed to variations in primary magmatic composition, shifts in the magmatic-hydrothermal systems related to CO2 versus water-dominated fluid phases, and changes in temperature.
Abstract: Bull Hill is a carbonatite diatreme within the Paleogene Bear Lodge Carbonatite Complex in Wyoming, USA. Rare earth element (REE)-bearing carbonate, fluorocarbonate, phosphate, and oxide minerals occur within near-vertical carbonatite dikes on the western margin of Bull Hill. Changes in mineralogy and REE concentrations with depth are ascribed mainly to late-stage magmatic-hydrothermal and supergene alteration. Approximately 35 m of drill core from Bull Hill was analyzed and encompasses least altered, weakly weathered, and moderately weathered carbonatite. The least altered carbonatite contains magmatic burbankite, typically as inclusions within Mn-rich calcite (stage I). Secondary REE-bearing minerals, which pseudomorphically replaced unidentified hexagonal phenocrysts, include ancylite, bastnäsite with synchysite/parisite, and an unidentified Sr-Ca-REE-phosphate (stage II). These replacive minerals generated small amounts of incipient porosity (~7-8%) and are largely stable in the lower portion of the weathering profile. Progressive weathering (stages III and IV) of the carbonatite involved the oxidation of pyrite to iron oxides and iron hydroxides, dissolution of calcite and strontianite, and the replacement of Mn-rich calcite by manganese oxides. These mineralogical changes resulted in an ~40% porosity gain in the core studied here. The volumetric concentration of weathering resistant REE-bearing minerals resulted in REE enrichment from an average of 5.4 wt % in the least weathered carbonatite to an average of 12.6 wt % in moderately weathered carbonatite, and to an overall increase in REE ore tenor of two to three times compared to the least altered carbonatite. Isocon plots confirm the increased concentration of REEs in the weathered carbonatite and demonstrate that REEs, along with TiO2, Ta, Nb, Zr, and Hf, were conserved in the lower weathered zone.
Kinematics of the North American-African plate boundary between 28 and 29 N (North) during the last 10 Ma: evolution of the axial geometry and spreading rate and direction.
Earth and Planetary Science Letters, Vol. 113, pp. 323-341.
The Effect of Analytical and Experimental Errors on Temperature and Pressure Estimates Based on Analyses of Pyroxenes From Garnet Lherzolite Xenoliths in Kimberlites.
Abstract: Mantle flow can cause the Earth’s surface to uplift and subside, but the rates and durations of these motions are, in general, poorly resolved due to the difficulties in making measurements of relatively small vertical movements (hundreds of metres) over sufficiently large distances (about 1,000?km). Here we examine the effect of mantle upwelling through a study of Quaternary uplift along the coast of Angola. Using both optically stimulated luminescence on sediment grains, and radiocarbon dating of fossil shells, we date a 25?m coastal terrace at about 45 thousand years old, when sea level was about 75?m lower than today, indicating a rapid uplift rate of 1.8-2.6?mm?yr?1 that is an order of magnitude higher than previously obtained rates averaged over longer time periods. Automated extraction and correlation of coastal terrace remnants from digital topography uncovers a symmetrical uplift with diameter of more than 1,000?km. The wavelength and relatively short timescale of the uplift suggest that it is associated with a mantle process, possibly convective upwelling, and that the topography may be modulated by rapid short-lived pulses of mantle-derived uplift. Our study shows that stable continental regions far from the effects of glacial rebound may experience rapid vertical displacements of several millimetres per year.
Geophysical Research Letters, Vol. 46, 22, pp. 12862-12869.
Australia
geophysics - seismic
Abstract: Despite decades of study, the mechanisms that lead to the localization of intracontinental seismicity remain vigorously debated. We find a very strong correlation between the attenuation of teleseismic P waves and the occurrence of intraplate seismicity in Australia. The regions with the highest attenuation host ~2 orders of magnitude more earthquakes per unit of area than the least attenuating regions. We argue that the attenuation we observe is produced by lateral variations in the thickness and/or viscosity of the lithospheric mantle and further suggest that the correlation we document implies that lithospheric mantle structure exerts first?order controls on the localization of intraplate seismicity.
Aravanis, T., Chen, J., Fuechsle, M., Grujic, M., Johnston, P., Kok, Y., Magaraggia, R., Mann, A., Mann, L., McIntoshm S., Rheinberger, G., Saxey, D., Smalley, M., van Kann, F., Walker, G., Winterflood, J.
Abstract: The minerals exploration industry’s demand for a highly precise airborne gravity gradiometer has driven development of the VK1TM Airborne Gravity Gradiometer, a collaborative effort by Rio Tinto and the University of Western Australia. VK1TM aims to provide gravity gradient data with lower uncertainty and higher spatial resolution than current commercial systems. In the recent years of VK1TM development, there have been significant improvements in hardware, signal processing and data processing which have combined to result in a complete AGG system that is approaching competitive survey-ready status. This paper focuses on recent improvements. Milestone-achieving data from recent lab-based and moving-platform trials will be presented and discussed, along with details of some advanced data processing techniques that are required to make the most use of the data.
Journal of Geophysical Research, Vol. 120, 8, pp. 5782-5803.
United States, Arkansas
Geophysics - seismics
Abstract: Global Navigation Satellite System data across the New Madrid seismic zone (NMSZ) in the central United States over the period from 2000 through 2014 are analyzed and modeled with several deformation mechanisms including the following: (1) creep on subsurface dislocations, (2) postseismic frictional afterslip and viscoelastic relaxation from the 1811–1812 and 1450 earthquakes in the NMSZ, and (3) regional strain. In agreement with previous studies, a dislocation creeping at about 4 mm/yr between 12 and 20 km depth along the downdip extension of the Reelfoot fault reproduces the observations well. We find that a dynamic model of postseismic frictional afterslip from the 1450 and February 1812 Reelfoot fault events can explain this creep. Kinematic and dynamic models involving the Cottonwood Grove fault provide minimal predictive power. This is likely due to the smaller size of the December 1811 event on the Cottonwood Grove fault and a distribution of stations better suited to constrain localized strain across the Reelfoot fault. Regional compressive strain across the NMSZ is found to be less than 3?×?10?9/yr. If much of the present-day surface deformation results from afterslip, it is likely that many of the earthquakes we see today in the NMSZ are aftershocks from the 1811–1812 New Madrid earthquakes. Despite this conclusion, our results are consistent with observations and models of intraplate earthquake clustering. Given this and the recent paleoseismic history of the region, we suggest that seismic hazard is likely to remain significant.
Gems & Gemology, Sixth International Gemological Symposium Vol. 54, 3, 1p. Abstract p. 265-6.
Global
Fluoresence
Abstract: The effect of fluorescence on the appearance of diamonds has been a subject of debate for many years (Moses et al., 1997). In the trade, fluorescence is generally perceived as an undesirable characteristic. Nearly 80% of diamonds graded at HRD Antwerp receive a “nil” fluorescence grade, while the remainder are graded as “slight,” “medium,” and “strong,” their value decreasing with level of fluorescence. To understand how fluorescence might change diamond appearance, a selection of 160 round brilliant-cut diamonds were investigated in detail. This study focused on the effect of thetic samples, it is possible that some of the observed phosphorescence does not involve boron impurities. In this paper we report on the results of combined fluorescence, phosphorescence, thermoluminescence, and quantitative charge transfer investigations undertaken on both HPHT and CVD synthetic diamond, with the objective of identifying which defects are involved in the fluorescence and phosphorescence processes.
Canadian Journal of Earth Sciences, Vol. 54, pp. 203-232.
Canada, Northwest Territories
kimberlite
Abstract: The Wopmay orogen is a Paleoproterozoic accretionary belt preserved to the west of the Archean Slave craton, northwest Canada. Reworked Archean crystalline basement occurs in the orogen, and new bedrock mapping, U–Pb geochronology, and Sm–Nd isotopic data further substantiate a Slave craton parentage for this basement. Detrital zircon results from unconformably overlying Paleoproterozoic supracrustal rocks also support a Slave craton provenance. Rifting of the Slave margin began at ca. 2.02 Ga with a second rift phase constrained between ca. 1.92 and 1.89 Ga, resulting in thermal weakening of the Archean basement and allowing subsequent penetrative deformation during the Calderian orogeny (ca. 1.88–1.85 Ga). The boundary between the western Slave craton and the reworked Archean basement in the southern Wopmay orogen is interpreted as the rifted cratonic margin, which later acted as a rigid backstop during compressional deformation. Age-isotopic characteristics of plutonic phases track the extent and evolution of these processes that left penetratively deformed Archean basement, Paleoproterozoic cover, and plutons in the west, and “rigid” Archean Slave craton to the east. Diamond-bearing kimberlite occurs across the central and eastern parts of the Slave craton, but kimberlite (diamond bearing or not) has not been documented west of ?114°W. It is proposed that while the crust of the western Slave craton escaped thermal weakening, the mantle did not and was moved out of the diamond stability field. The Paleoproterozoic extension–convergence cycle preserved in the Wopmay orogen provides a reasonable explanation as to why the western Slave craton appears to be diamond sterile.
Tectonic significance and redox state of Paleoproterozoic eclogite and pyroxenite components in the Slave cratonic mantle lithosphere, Voyageur kimberlite, Arctic Canada.
Abstract: Mantle-derived eclogite xenoliths are key for studying the evolution of the cratonic lithosphere, because geochemical evidence suggests that they typically represent fragments of Archean and Proterozoic oceanic lithosphere [1]. Recently, it has been suggested that eclogite xenoliths can serve as redox sensors of the Precambrian upper mantle using V/Sc as a redox proxy [2]. However, metasomatism can change the original oxidation state of the cratonic mantle [3], thereby limiting its use for monitoring mantle redox evolution. Circa 1.8–2.2 Ga eclogite xenoliths erupted with Jurassic kimberlites of the northern Slave craton have geochemical features that indicate oceanic crust protoliths [4, 5]. Such Paleoproterozoic ages are common for Slave craton mantle eclogites [6], linking eclogite formation with 1.9 Ga subduction-collision events at the western craton margin. The eclogites studied here have highly variable Fe3+/?Fe (0.019 – 0.076 ±0.01), with logfO2 (?FMQ-4 to +2 ±0.5) that are both relatively oxidized and reduced compared to Slave mantle peridotite xenoliths [3]. Also, eclogite fO2 positively correlates with some indicies of metasomatism, such as elevated TiO2 in garnet. In addition to considering the time gap between eclogite formation and kimberlite eruption, the highly variable fO2–depth systematics of the eclogites studied here illustrate the drawbacks of using averaged eclogite fO2 to define the redox evolution of the upper mantle. Despite this, the ca. 2 Ga northern Slave craton eclogites have an average depth-corrected logfO2 of ?FMQ-0.5±1.3 (1?) that overlaps with modern MORB, and complies with the upper mantle redox evolution trend predicted using V/Sc ratios of mantlederived melts [2]. However, given the debate around the secuarity of mantle redox [7], further research into the suitability of mantle eclogites as redox sensors is warranted.
Earth and Planetary Science Letters, Vol. 484, pp. 1-14.
Mantle
kimberlite, origin, magmatism
Abstract: Kimberlite magmatism has occurred in cratonic regions on every continent. The global age distribution suggests that this form of mantle melting has been more prominent after 1.2 Ga, and notably between 250-50 Ma, than during early Earth history before 2 Ga (i.e., the Paleoproterozoic and Archean). Although preservation bias has been discussed as a possible reason for the skewed kimberlite age distribution, new treatment of an updated global database suggests that the apparent secular evolution of kimberlite and related CO2-rich ultramafic magmatism is genuine and probably coupled to lowering temperatures of Earth's upper mantle through time. Incipient melting near the CO2- and H2O-bearing peridotite solidus at >200 km depth (1100-1400?°C) is the petrologically most feasible process that can produce high-MgO carbonated silicate melts with enriched trace element concentrations akin to kimberlites. These conditions occur within the convecting asthenospheric mantle directly beneath thick continental lithosphere. In this transient upper mantle source region, variable CHO volatile mixtures control melting of peridotite in the absence of heat anomalies so that low-degree carbonated silicate melts may be permanently present at ambient mantle temperatures below 1400?°C. However, extraction of low-volume melts to Earth's surface requires tectonic triggers. Abrupt changes in the speed and direction of plate motions, such as typified by the dynamics of supercontinent cycles, can be effective in the creation of lithospheric pathways aiding kimberlite magma ascent. Provided that CO2- and H2O-fluxed deep cratonic keels, which formed parts of larger drifting tectonic plates, existed by 3 Ga or even before, kimberlite volcanism could have been frequent during the Archean. However, we argue that frequent kimberlite magmatism had to await establishment of an incipient melting regime beneath the maturing continents, which only became significant after secular mantle cooling to below 1400?°C during post-Archean times, probably sometime shortly after 2 Ga. At around this time kimberlites replace komatiites as the hallmark mantle-derived magmatic feature of continental shields worldwide. The remarkable Mesozoic-Cenozoic ‘kimberlite bloom’ between 250-50 Ma may represent the ideal circumstance under which the relatively cool and volatile-fluxed cratonic roots of the Pangea supercontinent underwent significant tectonic disturbance. This created more than 60% of world's known kimberlites in a combination of redox- and decompression-related low-degree partial melting. Less than 2% of world's known kimberlites formed after 50 Ma, and the tectonic settings of rare ‘young’ kimberlites from eastern Africa and western North America demonstrate that far-field stresses on cratonic lithosphere enforced by either continental rifting or cold subduction play a crucial role in enabling kimberlite magma transfer to Earth's surface.
Abstract: Low-volume alkaline silicate and carbonate magmas are products of volatile-controlled incipient melting processes in the Earth’s mantle. Although this form of melting is ubiquitous beneath the thick and cold portions of continental lithosphere, such melts rarely reach the Earth’s surface due to a combination of their small volumes, reactive nature, and great depths of origin. In spite of being rare at surface, the impact of alkaline and carbonate magmatism on the dynamic stability of mantle lithosphere and its metal endowment may be disproportionately large, but it is difficult to grasp in the absence of spatial and temporal constraints on melt mobility. We review evidence from major alkaline and carbonatite provinces for metasomatic overprinting of the underlying continental mantle lithosphere, and evaluate how these processes influenced plate tectonic evolution in these regions. Key examples from Greenland and Africa show that metasomatic weakening of mantle lithosphere by pervasive alkaline and carbonate melts is frequently the first step in continent fragmentation ultimately leading to supercontinent dispersal. A major obstacle in identifying carbonate melt metasomatized mantle is the use of differentiated ‘surface’ carbonatite compositions as proxies for geochemical processes operating at great depths. We assess the robustness of some of the classic geochemical proxies, such as Ti/Eu and Zr/Sm, and identify new promising fingerprints of passing carbonate melts in the deep mantle lithosphere. New evidence from the Kaapvaal craton, one of world’s best endowed metallogenic provinces, shows that redox- and volatile-controlled alkaline melting events can effectively mobilize sulphide-hosted PGE and base metal budgets from eclogite components within the thick mantle lithosphere. Such precursor alkaline magmatic events, heralding the formation of major continental rifts and mantle plume impingement, can enhance the metal contents of subsequent asthenosphere-derived mafic magmas, thereby upgrading oreforming potential. However, economic metal deposits only form when geologic conditions during magma emplacement in the crust are favorable, with mantle metal budgets being less critical.
Abstract: The central region of the Kaapvaal craton is relatively understudied in terms of its lithospheric mantle architecture, but is commonly believed to be significantly impacted by post-Archean magmatism such as the ca. 2056 Ma Bushveld large igneous event. We investigate a collection of 17 eclogite xenoliths from the Cretaceous Palmietfontein kimberlite at the Western Limb of the Bushveld Complex for their mineralogical compositions (major and trace elements, plus Fe3+ contents), as well as stable oxygen and radiogenic Pb isotopic compositions to gain further insights into the nature and evolution of the central Kaapvaal cratonic mantle lithosphere. New U/Pb age determinations on mantle-derived zircon yield a magma emplacement age of ca. 75 Ma for the Palmietfontein Group-1 kimberlite, which means that the entrained eclogite xenoliths may record a protracted metasomatic history from the Proterozoic through to most of the Phanerozoic eon. Garnet ?18O values of up to 6.9‰ and positive Eu anomalies for the bulk rocks suggest seawater-altered oceanic crustal protoliths for the Palmietfontein eclogite xenolith suite, which is typical for the eclogitic components of the Kaapvaal root and other cratonic mantle sections worldwide. However, several features of the Palmietfontein eclogites are commonly not observed in other mantle-derived eclogite xenolith suites. Firstly, the samples studied yield relatively low equilibration pressures and temperatures between 2.7 and 4.5 GPa and 740-1064 °C, indicating a relatively shallow residence between 90 and 150 km depths. Secondly, euhedral coarse amphibole is present in several eclogite nodules where it is in equilibrium with ‘touching’ garnet, supporting eclogite residence within the amphibole stability field at uppermost lithospheric mantle conditions. Thirdly, primary omphacitic clinopyroxene is often overgrown by diopside, and is significantly enriched in incompatible trace elements. The clinopyroxene is also characterized by elevated 206Pb/204Pb of 17.28-19.20 and 207Pb/204 Pb of 15.51-16.27, and these Pb isotopic compositions overlap with those of Mesozoic Group-2 kimberlites from the Kaapvaal craton. Our results show that eclogites reside at ~85 km depth beneath the central Kaapvaal craton as part of a layer that corresponds to an approximately 50 km thick seismically-detected mid-lithospheric discontinuity. Mid-lithospheric discontinuities have been interpreted as metasomatic fronts formed by focussed crystallization of hydrous mineral phases from enriched volatile-bearing melts, and as such the strongly overprinted amphibole-bearing eclogite xenoliths from Palmietfontein may represent a physical expression of such seismically anomalous metasomatic layer at mid-lithospheric depth. Our Pb isotope data suggest that the focussed metasomatism can be attributed to volatile-rich melts reminiscent of potassic Group-2 kimberlites, which have been invoked in MARID-style metasomatic overprinting of the lower lithospheric mantle beneath the western Kaapvaal craton. However, the relatively low fO2 recorded by the Palmietfontein eclogites (minimum FMQ-4.5) suggests that the metasomatism at mid-lithospheric depth was less protracted compared to the more intensive and oxidizing metasomatism typically observed near the base of cratonic mantle roots. While it is possible that Proterozoic magmatic events were responsible for the focussed mid-lithospheric metasomatism of the Kaapvaal mantle, on the basis of the Pb isotope constraints the Palmietfontein eclogites were most likely overprinted during ca. 120 Ma Group-2 kimberlite magmatism.
Earth and Planetary Science Letters, Vol. 572, 1, 117118
Africa, South Africa
deposit - Premier, Roberts Victor, Jagersfontein
Abstract: Multiple sulphur isotopic compositions of sulphides from Kaapvaal craton mantle eclogites allow to elucidate the recycling of sulphur into the deep Earth and to differentiate between recycled crust and mantle origins of eclogite-hosted sulphides, including the precious metals that they capture. We present multiple sulphur isotope ratio measurements by secondary ion mass spectrometry for sulphides from a collection of mantle-derived eclogite xenoliths from Proterozoic and Mesozoic kimberlite occurrences in South Africa (Premier, Roberts Victor, Jagersfontein). Previous work established that the host eclogites have elemental and oxygen isotopic compositions in support of seawater-altered oceanic lithosphere protoliths, and for many of these xenolith suites Archean ages have been suggested. The eclogite-hosted sulphides have values from ?5.7 to ‰, with the upper end of this wide range representing the highest-ever recorded composition of material derived from the Earth's mantle. The values range from ?0.29 to ‰ and do not record significant mass-independent sulphur isotope fractionation, i.e., there is no compelling S-MIF signature. Most of the sulphide grains have values that fall within a range between ?6 and ‰, and they probably retain an isotopic record of sulphides that formed originally within altered oceanic crust. In contrast, the highly positive values from +13 to ‰ detected in sulphide grains from a single eclogite xenolith are similar to those of marine sulphates, which were probably a minor sulphur component of the oceanic crustal protolith. The lack of a significant S-MIF signature in the eclogitic sulphides that show evidence for a recycled crust origin implies that this sulphur component stems from a post-Archean surficial reservoir. This finding suggests that the cratonic mantle eclogites may have formed from post-Archean oceanic crust (e.g., Paleoproterozoic eclogite protoliths), or - as is preferred here - the ‘surficial’ sulphur was introduced into the cratonic root during relatively young metasomatic events and is thus unrelated to eclogite petrogenesis and Archean continent formation.
Abstract: The cratonic lithosphere-asthenosphere boundary is commonly invoked as the site of sheared peridotite and megacryst formation, a well-recognized petrological assemblage whose genetic relationships—if any—remain poorly understood. We have undertaken a comprehensive petrology and Sr-Nd-Hf-Ca isotope study of sheared peridotite xenoliths and clinopyroxene megacrysts from the c. 1150 Ma Premier kimberlite pipe on the central Kaapvaal craton in South Africa. New textural and mineral trace element evidence suggests that strong tectonic and magmatic overprinting affected the lower cratonic mantle over a vertical distance of ?50 km from the lithosphere-asthenosphere boundary located at ?200-225 km depth. Although modification of the central Kaapvaal cratonic mantle is commonly linked to the c. 2056 Ma Bushveld large igneous event, our thermobarometry, mantle redox, and Sr-Nd-Hf-Ca isotope data support a model in which volatile-rich low-volume melts and associated high-density fluids refertilized the lithosphere base shortly before or during asthenosphere-derived kimberlite and carbonatite magmatism at around 1150 Ma. This episode of lithospheric mantle enrichment was facilitated by exceptionally strong shear movements, as are recorded in the plastically deformed peridotites. We argue that stress-driven segregation of percolating carbonated melts contributed to megacryst formation along, or in close proximity to, shear zones within the cratonic mantle lithosphere. Integration of our results from the Kaapvaal craton and modern petrological concepts allows for the identification of a lithosphere-asthenosphere transition zone between ?150 and 225 km depth. This horizon is defined by intersections of the ?40-42 mW m-2 Premier paleogeotherm with (1) CO2-H2O-present solidus curves for peridotite (upper bound), and (2) typical mantle adiabats with potential temperatures between 1315 and 1420 °C (lower bound). At Premier, the most strongly deformed sheared peridotites occur mainly between ?160 and 185 km depth, firmly within the lithosphere-asthenosphere transition zone. Contrary to many previous models, we suggest that sheared peridotite formation occurs in localized deformation zones spaced out across the entire width of the lithosphere-asthenosphere transition zone, rather than being restricted to a single thin layer at the craton base where mantle flow causes viscous drag. Hence, plate-tectonic stresses acting on the lower cratonic lithosphere may be accommodated by extensive networks of shear zones, which provide transient pathways and sinks for percolating volatile-rich melts, linking the formation of megacrysts and sheared peridotites.
Earth and Planetary Science Letters, Vol. 572, 13p. Pdf
Mantle
eclogites
Abstract: Multiple sulphur isotopic compositions of sulphides from Kaapvaal craton mantle eclogites allow to elucidate the recycling of sulphur into the deep Earth and to differentiate between recycled crust and mantle origins of eclogite-hosted sulphides, including the precious metals that they capture. We present multiple sulphur isotope ratio measurements by secondary ion mass spectrometry for sulphides from a collection of mantle-derived eclogite xenoliths from Proterozoic and Mesozoic kimberlite occurrences in South Africa (Premier, Roberts Victor, Jagersfontein). Previous work established that the host eclogites have elemental and oxygen isotopic compositions in support of seawater-altered oceanic lithosphere protoliths, and for many of these xenolith suites Archean ages have been suggested. The eclogite-hosted sulphides have ?34S values from -5.7 to + 29 ‰, with the upper end of this wide range representing the highest-ever recorded ?34S composition of material derived from the Earth's mantle. The ?33S values range from -0.29 to + 0.18 ‰ and do not record significant mass-independent sulphur isotope fractionation, i.e., there is no compelling S-MIF signature. Most of the sulphide grains have ?34S values that fall within a range between -6 and + 4 ‰, and they probably retain an isotopic record of sulphides that formed originally within altered oceanic crust. In contrast, the highly positive ?34S values from +13 to + 29 ‰ detected in sulphide grains from a single eclogite xenolith are similar to those of marine sulphates, which were probably a minor sulphur component of the oceanic crustal protolith. The lack of a significant S-MIF signature in the eclogitic sulphides that show ?34S evidence for a recycled crust origin implies that this sulphur component stems from a < 2.4Ga post-Archean surficial reservoir. This finding suggests that the cratonic mantle eclogites may have formed from post-Archean oceanic crust (e.g., Paleoproterozoic eclogite protoliths), or - as is preferred here - the 'surficial' sulphur was introduced into the cratonic root during relatively young metasomatic events and is thus unrelated to eclogite petrogenesis and Archean continent formation.
Tappe, S., Heaman, L.M., Smart, K.A., Muehlenbachs, K., Simonetti, A.
First results from Greenland eclogite xenoliths: evidence for an ultra depleted peridotitic component within the North Atlantic craton mantle lithosphere.
GAC/MAC/AGU Meeting held May 23-27 Toronto, Abstract only
Diamond growth from oxidized carbon sources beneath the Northern Slave Craton, Canada: A delta 13 C-N study of eclogite hosted diamonds from the Jericho kimberlite.
Geochimica et Cosmochimica Acta, Vol. 75, pp. 6027-6047.
Smart, K.A., Chacko, T., Simonetti, A., Sharp, Z.D., Heaman, L.M.
A record of Paleoproterozoic subduction preserved in the northern Slave cratonic mantle: Sr-Pb-O isotope and trace element investigations of eclogite xenoliths from the Jericho and Muskox kimberlites.
Tappe, S., Smart, K.A., Stracke, A., Romer, R.L., Prelevic, D., van den Bogaard, P.
Melt evolution beneath a rifted carton edge: 40Ar/39/Ar geochronology and Sr-Nd-Hf-Pb isotope systematics of primitive alkaline basalts and lamprophyres from the SW Baltic Shield.
Geochimica et Cosmochimica Acta, Vol. 173, pp. 1-36.
Abstract: Plate tectonics plays a vital role in the evolution of our planet. Geochemical analysis of Earth’s oldest continental crust suggests that subduction may have begun episodically about 3.8 to 3.2 billion years ago, during the early Archaean or perhaps more than 3.8 billion years ago, during the Hadean. Yet, mantle rocks record evidence for modern-style plate tectonics beginning only in the late Archaean, about 3 billion years ago. Here we analyse the nitrogen abundance, as well as the nitrogen and carbon isotopic signatures of Archaean placer diamonds from the Kaapvaal craton, South Africa, which formed in the upper mantle 3.1 to 3.5 billion years ago. We find that the diamonds have enriched nitrogen contents and isotopic compositions compared with typical mantle values. This nitrogen geochemical fingerprint could have been caused by contamination of the mantle by nitrogen-rich Archaean sediments. Furthermore, the carbon isotopic signature suggests that the diamonds formed by reduction of an oxidized fluid or melt. Assuming that the Archaean mantle was more reduced than the modern mantle, we argue that the oxidized components were introduced to the mantle by crustal recycling at subduction zones. We conclude, on the basis of evidence from mantle-derived diamonds, that modern-style plate tectonics operated as early as 3.5 billion years ago.
Geochimica et Cosmochimica Acta, Vol. 173, pp. 1-36.
Europe
Geochronology
Abstract: A new high-precision 40Ar/39Ar anorthoclase feldspar age of 176.7 ± 0.5 Ma (2-sigma) reveals that small-volume alkaline basaltic magmatism occurred at the rifted SW margin of the Baltic Shield in Scania (southern Sweden), at a time of global plate reorganization associated with the inception of Pangea supercontinent break-up. Our combined elemental and Sr-Nd-Hf-Pb isotope dataset for representative basanite and nephelinite samples (>8 wt.% MgO) from 16 subvolcanic necks of the 30 by 40 km large Jurassic volcanic field suggests magma derivation from a moderately depleted mantle source (87Sr/86Sri = 0.7034-0.7048; ?Ndi = +4.4 to +5.2; ?Hfi = +4.7 to +8.1; 206Pb/204Pbi = 18.8-19.5). The mafic alkaline melts segregated from mixed peridotite-pyroxenite mantle with a potential temperature of ?1400 °C at 2.7-4.2 GPa (?90-120 km depths), which places ultimate melt generation within the convecting upper mantle, provided that the lithosphere-asthenosphere boundary beneath the southern Baltic Shield margin was at ?100 km depth during Mesozoic-Cenozoic rifting. Isotopic shifts and incompatible element enrichment relative to Depleted Mantle reflect involvement of at least 20% recycled oceanic lithosphere component (i.e., pyroxenite) with some minor continent-derived sediment during partial melting of well-stirred convecting upper mantle peridotite. Although pargasitic amphibole-rich metasomatized lithospheric mantle is excluded as the main source of the Jurassic magmas from Scania, hydrous ultramafic veins (i.e., hornblendite) may have caused subtle modifications to the compositions of passing sublithospheric melts. For example, modeling suggests that the more radiogenic Hf (?Hfi = +6.3 to +8.1) and Pb (206Pb/204Pbi = 18.9-19.5) isotopic compositions of the more sodic and H2O-rich nephelinites, compared with relatively homogenous basanites (?Hfi = +4.7 to +6.1; 206Pb/204Pbi = 18.8-18.9), originate from minor interactions between rising asthenospheric melts and amphibole-rich metasomatic components. The metasomatic components were likely introduced to the lithospheric mantle beneath the southern Baltic Shield margin during extensive Permo-Carboniferous magmatic activity, a scenario that is supported by the geochemical and isotope compositions of ca. 286 Ma lamprophyres from Scania (87Sr/86Sri = 0.7040-0.7054; ?Ndi = +2.0 to +3.1; ?Hfi = +6.1 to +9.0; 206Pb/204Pbi = 17.8-18.2). Strong variations in lithosphere thickness and thermal structure across the southern Baltic Shield margin may have caused transient small-scale mantle convection. This resulted in relatively fast and focused upwellings and lateral flow beneath the thinned lithosphere, where mafic alkaline magmas formed by low degrees of decompression melting of sublithospheric mantle. Such a geodynamic scenario would allow for enriched recycled components with low melting points to be preferentially sampled from the more depleted and refractory convecting upper mantle when channeled along a destabilizing craton edge. Similar to the ‘lid effect’ in oceanic island volcanic provinces, lithospheric architecture may exert strong control on the mantle melting regime, and thus offer a simple explanation for the geochemical resemblance of continental and oceanic intraplate mafic alkaline magmas of high Na/K affinity.
Geochimica et Cosmochimica Acta, Vol. 206, pp. 312-342.
Europe, Finland
Deposit - Lahtojoki
Abstract: A collection of 61 xenocrystic and 12 eclogite xenolith-derived diamonds from the 600 Ma Lahtojoki kimberlite in central Finland has been investigated. Calculated pressure and temperature conditions for the diamondiferous eclogites are in excess of 5.5 GPa and 1300 °C, suggesting residence depths greater than 180 km, near the base of the Karelian cratonic mantle lithosphere. Geochemically, the eclogite xenoliths have gabbroic compositions showing positive Eu and Sr anomalies, relatively low ?REE and elevated Al2O3 contents, yet garnets have ambiguous ?18O values of 5.7‰ and 5.9‰. Gabbroic eclogite formation could therefore be linked to either subduction processes during the 1.9 Ga Svecofennian orogeny or to cumulate processes during 2.1 Ga rift-induced magmatism. Determination of the oxygen fugacity of Lahtojoki eclogite xenoliths from both this work and previous studies suggests that diamond-bearing eclogites may be more reduced (?FMQ-3.5) compared to barren eclogites (?FMQ-1.7). While recycled oceanic crust protoliths for the eclogites remain a possibility, the carbon isotopic compositions and nitrogen abundances of the Lahtojoki diamonds indicate mantle-derived volatile sources. All diamonds (i.e., loose and eclogite xenolith-derived) display a restricted range of ?13C values from ?7.8‰ to ?3.7‰ that overlaps with the carbon isotopic composition of Earth’s mantle. The Lahtojoki diamond ?13C values form a negatively skewed distribution, indicating diamond growth from reduced mantle-derived carbon sources such as methane- (CH4) bearing fluids. Nitrogen contents of the Lahtojoki diamonds range from 40 to 1830 atomic ppm with a mean of ?670 atomic ppm; these elevated nitrogen contents combined with the close association to eclogites suggest an eclogitic or crustal volatile source. However, the Karelian craton was periodically intruded by ultramafic alkaline magmas since at least 1.8 Ga, noting in particular the occurrence of phlogopite-rich kimberlites and olivine lamproites between 1200 and 700 Ma. We argue that this punctuated volatile-rich magmatism simultaneously metasomatised the cratonic mantle lithosphere, forming nitrogen enriched phlogopite-bearing metasomes. We propose that reduced, carbon-bearing and nitrogen-rich fluids were remobilized to form the Lahtojoki diamonds. The diamond-forming event(s) most probably occurred during or shortly prior to the entraining kimberlite magmatism as indicated by the diamond nitrogen aggregation systematics. Involvement of reduced diamond-forming fluids is supported by both the negative skewness of Lahtojoki diamond ?13C values and the more reduced nature of the diamondiferous Lahtojoki eclogites compared with their more oxidized barren counterparts. Our results from the diamondiferous eclogites derived from the deepest parts of the Karelian cratonic mantle root are in support of methane being the stable carbon volatile species at the base of thick continental lithosphere.
Earth and Planetary science Letters, Vol. 466, pp. 152-167.
Mantle
Metasomatism, magma, carbonatite
Abstract: Kimberlite and carbonatite magmas that intrude cratonic lithosphere are among the deepest probes of the terrestrial carbon cycle. Their co-existence on thick continental shields is commonly attributed to continuous partial melting sequences of carbonated peridotite at >150 km depths, possibly as deep as the mantle transition zone. At Tikiusaaq on the North Atlantic craton in West Greenland, approximately 160 Ma old ultrafresh kimberlite dykes and carbonatite sheets provide a rare opportunity to study the origin and evolution of carbonate-rich melts beneath cratons. Although their Sr-Nd-Hf-Pb-Li isotopic compositions suggest a common convecting upper mantle source that includes depleted and recycled oceanic crust components (e.g., negative ??Hf??Hf coupled with View the MathML source>+5‰?7Li), incompatible trace element modelling identifies only the kimberlites as near-primary low-degree partial melts (0.05-3%) of carbonated peridotite. In contrast, the trace element systematics of the carbonatites are difficult to reproduce by partial melting of carbonated peridotite, and the heavy carbon isotopic signatures (?3.6 to View the MathML source?2.4‰?13C for carbonatites versus ?5.7 to View the MathML source?3.6‰?13C for kimberlites) require open-system fractionation at magmatic temperatures.
Given that the oxidation state of Earth's mantle at >150 km depth is too reduced to enable larger volumes of ‘pure’ carbonate melt to migrate, it is reasonable to speculate that percolating near-solidus melts of carbonated peridotite must be silicate-dominated with only dilute carbonate contents, similar to the Tikiusaaq kimberlite compositions (e.g., 16-33 wt.% SiO2). This concept is supported by our findings from the North Atlantic craton where kimberlite and other deeply derived carbonated silicate melts, such as aillikites, exsolve their carbonate components within the shallow lithosphere en route to the Earth's surface, thereby producing carbonatite magmas. The relative abundances of trace elements of such highly differentiated ‘cratonic carbonatites’ have only little in common with those of metasomatic agents that act on the deeper lithosphere. Consequently, carbonatite trace element systematics should only be used with caution when constraining carbon mobility and metasomatism at mantle depths. Regardless of the exact nature of carbonate-bearing melts within the mantle lithosphere, they play an important role in enrichment processes, thereby decreasing the stability of buoyant cratons and promoting rift initiation - as exemplified by the Mesozoic-Cenozoic breakup of the North Atlantic craton.
Abstract: Mantle-derived eclogite and pyroxenite xenoliths from the Jurassic Voyageur kimberlite on the northern Slave craton in Arctic Canada were studied for garnet and clinopyroxene major and trace element compositions, clinopyroxene Pb and garnet O isotopic compositions, and garnet Fe3 +/?Fe contents. The Voyageur xenoliths record a wide range of pressures, but are cooler compared to mantle xenoliths derived from the nearby, coeval Jericho kimberlite. The CaO, TiO2 and Zr contents of Voyageur eclogites increase with depth, which is also observed in northern Slave peridotite xenoliths, demonstrating ‘bottom-up’ metasomatic processes within cratonic mantle lithosphere. The Voyageur eclogites have positive Eu anomalies, flat HREEN patterns, and major element compositions that are consistent with ultimate origins from basaltic and gabbroic protoliths within oceanic lithosphere. Clinopyroxene Pb isotope ratios intercept the Stacey-Kramers two-stage terrestrial Pb evolution curve at ca. 2.1 Ga, and form an array towards the host kimberlite, indicating isotopic mixing. The 2.1 Ga eclogite formation age broadly overlaps with known Paleoproterozoic subduction and collision events that occurred along the western margin of the Slave craton. Unlike the eclogites, the Voyageur pyroxenites contain garnet with distinctive fractionated HREEN, sinusoidal REE patterns of calculated bulk rocks, and clinopyroxene with 206Pb/204Pb ratios that intercept the Stacey-Kramers curve at 1.8 Ga. This suggests a distinct origin as Paleoproterozoic high-pressure mantle cumulates. However, the pyroxenite Pb isotope ratios fall within the eclogite array and could also be explained by protoliths formation at ca. 2.1 Ga followed by minor isotopic mixing during mantle metasomatism. Thus, an alternative scenario involves pyroxenite formation within the mantle section of Paleoproterozoic oceanic lithosphere followed by variable metasomatism after incorporation into cratonic mantle lithosphere. This model allows for a linked petrogenesis of the Voyageur eclogites (crust) and pyroxenites (mantle) as part of the same subducting oceanic slab. Oxygen fugacity determinations for one pyroxenite and ten eclogite xenoliths show a range of 3 log units, from ? 4.6 to ? 1.6 ?FMQ, similar to the range observed for nearby Jericho and Muskox eclogites (?FMQ ? 4.2 to ? 1.5). Importantly, the northern Slave eclogite and pyroxenite mantle components are highly heterogeneous in terms of redox state provided that they range from reduced to oxidized relative to Slave peridotite xenoliths. Moreover, the Voyageur eclogites do not exhibit any trend between oxidation state and equilibration depth, which contrasts with the downward decrease in fO2 shown by Slave and worldwide cratonic peridotite xenoliths. Our investigation of mantle eclogite and pyroxenite fO2 reinforces the important influence of recycled mafic components in upper mantle processes, because their high and variable redox buffering capacity strongly controls volatile speciation and melting relations under upper mantle conditions.
Abstract: Diamond xenocrysts and eclogite-hosted diamonds from the Lahtojoki kimberlite (Karelian craton, Finland) indicate metasomatism of the deep lithosphere by N-rich, relatively reduced fluids. P-T-fO2 constraints show that all eclogites were derived from near the base of the lithospheric mantle (>5 GPa), but only the diamond-bearing samples are relatively reduced (?FMQ-3.5 vs. -1.7 for barren eclogites). The Lahtojoki diamonds show evidence of formation from reduced mantle-derived carbon, based on the restricted range of ?13C values (-3 and -7.8 ‰; n = 67) that form a negativelyskewed distribution. This reduced CHO fluid was also anomalously N-rich, based on the diamond N contents that range up to 1830 at. ppm. While N-rich sources for eclogiteassociated diamonds are often linked to recycled crustal materials, in this case we prefer derivation from K-rich cratonic mantle metasomes due to lack of firm crustal geochemical signatures in the eclogites (?18O = 5.7 - 5.9 ‰), in addition to the magmatic history of the Karelian craton. The Karelian craton has been periodically intruded by Krich alkaline lamprophyres, Group-2 kimberlites and olivine lamproites from 1800 to 700 Ma. Such K-rich ultramafic alkaline magmatism is likely linked to phlogopite-rich metasomes, which may represent significant repositories of N (NH4+ substitution for K+). Because the Lahtojoki eclogites resided near the base of the lithospheric mantle, they would have been susceptible to interaction with ascending asthenosphere-derived C-bearing fluids/melts, which were reducing. Following ingress into and interaction with the Krich metasomatised Karelian mantle lithosphere, the increasingly N-enriched, CH4-bearing fluids precipitated diamond during interaction with relatively oxidized eclogite wall rock. In contrast to the prevalent oxidizing effects of mantle metasomatism as identified within cratonic lithosphere-derived samples from worldwide locations, the eclogite-hosted diamonds at Lahtojoki represent a natural example of metasomatic overprinting that was highly reducing.
Abstract: Eclogite mantle xenoliths from various kimberlite occurrences on the Kaapvaal craton show evidence for depth- and redox-dependent metasomatic events that led to variable base metal sulphide and incompatible element enrichments. Eclogite xenoliths from the Roberts Victor, Jagersfontein, Kimberley (Kamfersdam) and Premier kimberlites were investigated for their silicate and base metal sulphide geochemistry, stable oxygen isotope compositions and oxybarometry. The variably metasomatised eclogites had basaltic, picritic and gabbroic protolith compositions and have garnet ?18O values that range from +3.3 to +7.9‰, which, when coupled with the trace element characteristics, indicate oceanic lithosphere protoliths that had undergone variable degrees of seawater alteration. The deepest equilibrated eclogites (175220?km depth) from near the base of the Kaapvaal craton lithosphere are the most refractory and feature significant light rare earth element (LREE) depletions. They show the most oxidised redox compositions with ?logƒO2 values of FMQ-3.9 to FMQ-1.5. Subtle metasomatic overprinting of these eclogites resulted in base metal sulphide formation with relatively depleted and highly fractionated HSE compositions. These deepest eclogites and their included base metal sulphides suggest interaction with relatively oxidised melts or fluids, which, based on their HSE characteristics, could be related to precursor kimberlite metasomatism that was widespread within the Kaapvaal craton mantle lithosphere. In contrast, eclogites that reside at shallower, “mid-lithospheric” depths (140180?km) have been enriched in LREE and secondary diopside/phlogopite. Importantly, they host abundant metasomatic base metal sulphides, which have higher HSE contents than those in the deeper eclogites at the lithosphere base. The mid-lithospheric eclogites have more reducing redox compositions (?logfO2?=?FMQ-5.3 ? FMQ-3.3) than the eclogites from the lowermost Kaapvaal lithosphere. The compositional overprint of the shallower mantle eclogites resembles basaltic rather than kimberlitic/carbonatitic metasomatism, which is also supported by their relatively reducing redox state. Base metal sulphides from the mid-lithospheric eclogites have HSE abundances and distributions that are similar to Karoo flood basalts from southern Africa, suggesting a link between the identified shallow mantle metasomatism of the Kaapvaal cratonic lithosphere and the Karoo large igneous event during the Mesozoic. The sulphide-hosted platinum group element abundances of the mid-lithospheric eclogites are higher compared with their analogues from the deeper lithospheric eclogites, which in combination with their contrasting oxidation states, may imply redox-controlled HSE mobility during sulphur-rich metasomatism of continental mantle lithosphere.
deposit - Roberts Victor, Jagersfontein, Kimberley, Kamfersdam, Premier
Abstract: Eclogite mantle xenoliths from various kimberlite occurrences on the Kaapvaal craton show evidence for depth- and redox-dependent metasomatic events that led to variable base metal sulphide and incompatible element enrichments. Eclogite xenoliths from the Roberts Victor, Jagersfontein, Kimberley (Kamfersdam) and Premier kimberlites were investigated for their silicate and base metal sulphide geochemistry, stable oxygen isotope compositions and oxybarometry. The variably metasomatised eclogites had basaltic, picritic and gabbroic protolith compositions and have garnet ?18O values that range from +3.3 to +7.9‰, which, when coupled with the trace element characteristics, indicate oceanic lithosphere protoliths that had undergone variable degrees of seawater alteration. The deepest equilibrated eclogites (175-220 km depth) from near the base of the Kaapvaal craton lithosphere are the most refractory and feature significant light rare earth element (LREE) depletions. They show the most oxidised redox compositions with ?logƒO2 values of FMQ-3.9 to FMQ-1.5. Subtle metasomatic overprinting of these eclogites resulted in base metal sulphide formation with relatively depleted and highly fractionated HSE compositions. These deepest eclogites and their included base metal sulphides suggest interaction with relatively oxidised melts or fluids, which, based on their HSE characteristics, could be related to precursor kimberlite metasomatism that was widespread within the Kaapvaal craton mantle lithosphere. In contrast, eclogites that reside at shallower, “mid-lithospheric” depths (140-180 km) have been enriched in LREE and secondary diopside/phlogopite. Importantly, they host abundant metasomatic base metal sulphides, which have higher HSE contents than those in the deeper eclogites at the lithosphere base. The mid-lithospheric eclogites have more reducing redox compositions (?logfO2 = FMQ-5.3 ? FMQ-3.3) than the eclogites from the lowermost Kaapvaal lithosphere. The compositional overprint of the shallower mantle eclogites resembles basaltic rather than kimberlitic/carbonatitic metasomatism, which is also supported by their relatively reducing redox state. Base metal sulphides from the mid-lithospheric eclogites have HSE abundances and distributions that are similar to Karoo flood basalts from southern Africa, suggesting a link between the identified shallow mantle metasomatism of the Kaapvaal cratonic lithosphere and the Karoo large igneous event during the Mesozoic. The sulphide-hosted platinum group element abundances of the mid-lithospheric eclogites are higher compared with their analogues from the deeper lithospheric eclogites, which in combination with their contrasting oxidation states, may imply redox-controlled HSE mobility during sulphur-rich metasomatism of continental mantle lithosphere.
Earth and Planetary Science Letters, doi.org/10.1016/ j.epsl.2020. 116720 19p. Pdf
Africa, South Africa
deposit - Bellsbank
Abstract: The nature of the deep calcium geochemical cycle through time is unresolved, in part due to the dearth of information about the calcium isotope composition of Archean recycled oceanic crust. Remnants of such ancient oceanic crust are preserved in the form of cratonic mantle eclogites, brought to surface as xenoliths in kimberlite magma eruptions. The ? 44 / 40Ca of fresh mantle-derived eclogite xenoliths (i.e., garnet and omphacite mineral separates) from the Bellsbank kimberlite on the Kaapvaal craton in South Africa are presented here in combination with their trace element compositions, garnet Fe3+ contents and ?18O values. The studied Bellsbank eclogite xenoliths have geochemical compositions that indicate oceanic crustal protoliths, with bulk Al2O3 from 15 to 27 wt.%, Eu anomalies from 0.8 to 2.6 and, significantly, garnet ?18O values from +2.7 to +6.2‰. Garnet Fe3+/?Fe contents yield logfO2(?FMQ) values between -4.0 and -1.2 for a depth range of 110-180 km, recording strong redox heterogeneity of the eclogite component within the Archean Kaapvaal mantle lithosphere. Reconstructed bulk eclogite MgO contents correlate negatively with fO2, suggesting that the redox compositions are related to magmatic differentiation during oceanic crust formation, excluding secondary metasomatic overprints. These data may thus emphasize that Archean basaltic oceanic crust had a similarly variable redox composition to modern MORB-type crust. Reconstructed bulk ? 44 / 40Ca values for the Bellsbank eclogites range from +0.28 to +1.56‰. Although some of the xenoliths have ? 44 / 40Ca values that overlap with the average mantle composition and modern MORB (+0.94 ± 0.1 and +0.83 ± 0.05‰), half of our dataset shows excursions to more extreme Ca isotopic compositions. Both higher and lower ? 44 / 40Ca relative to mantle compositions are recorded by the eclogites, with a general negative correlation with ?18O suggestive of seawater-alteration of oceanic crust. The combined low ? 44 / 40Ca (+0.28‰) and ?18O (+3.4‰) measured for one eclogite xenolith may record a subtle imprint by carbonate-rich mantle melts, which are known to contain isotopically light calcium contributed by recycled sediments. In contrast, the high ? 44 / 40Ca of up to +1.56‰ for some eclogite xenoliths, coupled with strong LREE depletion, can be explained by calcium isotope fractionation during partial melting. The protracted history of recycled oceanic crust as probed by cratonic mantle eclogites is recorded by their highly variable ? 44 / 40Ca-?18O-fO2 signatures. Whereas some of this heterogeneity can be linked to processes that operated on the Archean ocean floor such as seawater-alteration of basaltic crust, other sources of compositional variability are introduced by loss and addition of melts during subduction recycling and mantle residence. The observed ? 44 / 40Ca complexity of ancient recycled oceanic crust components at the scale of a single mantle-derived eclogite xenolith suite implies that mantle plume sourced intraplate magmas should reveal similarly strong calcium isotope variations contributed by apparently essential recycled crust components - as observed in the global oceanic island basalt record.
Tappe, S., Massuyeau, M. , Smart, K.A., Woodland, A.B., Gussone, N., Milne, S., Stracke, A.
Sheared peridotite and megacryst formation beneath the Kaapvaal Craton: a snapshot of tectonomagmetic processes across the lithosphere-asthenosphere transition.
Abstract: The cratonic lithosphere-asthenosphere boundary is commonly invoked as the site of sheared peridotite and megacryst formation, a well-recognized petrological assemblage whose genetic relationships—if any—remain poorly understood. We have undertaken a comprehensive petrology and Sr-Nd-Hf-Ca isotope study of sheared peridotite xenoliths and clinopyroxene megacrysts from the c. 1150 Ma Premier kimberlite pipe on the central Kaapvaal craton in South Africa. New textural and mineral trace element evidence suggests that strong tectonic and magmatic overprinting affected the lower cratonic mantle over a vertical distance of ?50 km from the lithosphere-asthenosphere boundary located at ?200-225 km depth. Although modification of the central Kaapvaal cratonic mantle is commonly linked to the c. 2056 Ma Bushveld large igneous event, our thermobarometry, mantle redox, and Sr-Nd-Hf-Ca isotope data support a model in which volatile-rich low-volume melts and associated high-density fluids refertilized the lithosphere base shortly before or during asthenosphere-derived kimberlite and carbonatite magmatism at around 1150 Ma. This episode of lithospheric mantle enrichment was facilitated by exceptionally strong shear movements, as are recorded in the plastically deformed peridotites. We argue that stress-driven segregation of percolating carbonated melts contributed to megacryst formation along, or in close proximity to, shear zones within the cratonic mantle lithosphere. Integration of our results from the Kaapvaal craton and modern petrological concepts allows for the identification of a lithosphere-asthenosphere transition zone between ?150 and 225 km depth. This horizon is defined by intersections of the ?40-42 mW m-2 Premier paleogeotherm with (1) CO2-H2O-present solidus curves for peridotite (upper bound), and (2) typical mantle adiabats with potential temperatures between 1315 and 1420 °C (lower bound). At Premier, the most strongly deformed sheared peridotites occur mainly between ?160 and 185 km depth, firmly within the lithosphere-asthenosphere transition zone. Contrary to many previous models, we suggest that sheared peridotite formation occurs in localized deformation zones spaced out across the entire width of the lithosphere-asthenosphere transition zone, rather than being restricted to a single thin layer at the craton base where mantle flow causes viscous drag. Hence, plate-tectonic stresses acting on the lower cratonic lithosphere may be accommodated by extensive networks of shear zones, which provide transient pathways and sinks for percolating volatile-rich melts, linking the formation of megacrysts and sheared peridotites.
The age and localization of kimberlite magmatism in the Yakutian kimberlite Province: constraints from isotope geochronology - an overview.
Proceedings of the 10th. International Kimberlite Conference, Vol. 1, Special Issue of the Journal of the Geological Society of India,, Vol. 1, pp. 225-234.
Re-Os dating of sulphide inclusions zonally distributed in single Yakutian diamonds: evidence for multiple episodes of Proterozoic formation and protracted timescales of diamond growth.
Geochimica et Cosmochimica Acta, Vol. 120, pp. 363-394.
Viola, G., Henderson, I.H.C., Bingen, B., Thomas, R.J., Smethurst, M.A., De Azavedo, S.
Growth and collapse of a deeply eroded orogen: insights from structural, geophysical, and geochronological constraints on Pan-African evolution of NE Mozambique.
Journal of Geophysical Research: Solid Earth, Vol. 123, 8, pp. 6195-6214.
Canada, Ontario
geochronology
Abstract: Similar to a magnetic tape, rocks can retain the direction of ancient Earth's magnetic field. Scientists use this record (known as paleomagnetism) to reconstruct past positions of continents and to decipher the geological history of our planet. We investigated paleomagnetism and chemical composition of the ~1.14 Ga?old intrusive rocks called lamprophyres exposed in Northwestern Ontario (Canada). We found that the paleomagnetic field directions recorded in lamprophyres are indistinguishable from those recorded by another similar age suite of basaltic intrusions called the Abitibi dikes, from the same area. The combined data from these rocks allowed us to constrain the position of an ancient supercontinent called Laurentia at ~1.14 billions of years ago more accurately than it was possible before. Our results convincingly show that, during that time, Laurentia moved with a velocity comparable to present?day plate velocities, before switching to an extremely rapid motion approximately 35 millions of years later. The lamprophyre and Abitibi rocks also share similar chemical signatures, close to those observed for ocean island basalts (e.g., Hawaii). These observations support the hypothesis that a failed ocean opening attempt called the North American Midcontinent Rift was instigated by the arrival of a hot mantle material upwelling to the Earth surface.
Abstract: The original connections of Archean cratons are becoming traceable due to an increasing amount of paleomagnetic data and refined magmatic barcodes. The Uauá block of the northern São Francisco craton may represent a fragment of a major Archean craton. Here, we report new paleomagnetic data from the 2.62 Ga Uauá tholeiitic mafic dyke swarm of the Uauá block in the northern São Francisco craton, Eastern Brazil. Our paleomagnetic results confirm the earlier results for these units, but our interpretation differs. We suggest that the obtained characteristic remanent magnetization for the 2.62 Ga swarm is of primary origin, supported by a provisionally-positive baked contact test. The corresponding paleomagnetic pole (25.2°N, 330.5°E, A95 = 8.1° N = 20) takes the present northern part of the São Francisco craton to moderate latitudes. Based on the comparison of the paleolatitudes of cratons with high-quality paleomagnetic data and magmatic barcodes, we suggest that the northern part of the São Francisco craton could have been part of the proposed Supervaalbara supercraton during the Archean. Supervaalbara is proposed as including (but not limited to) the part of the São Francisco craton as well as the Superior, Wyoming, Kola + Karelia, Zimbabwe, Kaapvaal, Tanzania, Yilgarn, and Pilbara cratons.
Research in fluid inclusions in minerals: current state and future outlook. Third biennial conference on fluid inclusions held Sept. 2010. discussion of papers...
Abstract: The results of geochronological, mineralogical, petrographical, and geochemical study of the Ilbokich ultramafic lamprophyre are reported. The specific features in the mineral and chemical compositions of the studied ultramafic lamprophyre indicate that it can be regarded as a variety similar to aillikite, while other differences dominated by K-feldspar can be referred to damtjernite. According to Rb-Sr analysis, ultramafic lamprophyre dikes intruded at the turn of the Early and Middle Devonian, about 392 Ma ago. This directly proves the existence of Early Paleozoic alkali-ultramafic magmatism in the northern part of the southwest Siberian Platform. A finding of Devonian alkali-ultramafic lamprophyre is of dual predictive importance. On the one hand, it is indicative of the low probability of finding large diamond-bearing deposits in close association with aillikite. On the other hand, it can be indicative of a possible large Devonian diamond province in the studied territory, where diamondiferous kimberlite is structurally separated from aillikite.
Contributions to Mineralogy and Petrology, 10.1007/ s00410-018- 1480-3, 27p.
Russia, Siberia
kimberlite
Abstract: We studied olivines from the Devonian pre-trap (the Ilbokich occurrence) and the Triassic post-trap (the Chadobets occurrence) carbonate-rich ultramafic lamprophyres (UMLs) in the southwestern portion of the Siberian craton. On the basis of detailed investigations of major, minor, and trace-element distributions, we have reconstructed the main processes that control the origins of these olivines. These include fractional crystallisation from melt, assimilation, and fractional crystallisation processes with orthopyroxene assimilation, melt-reaction diffusive re-equilibration, alkali enrichment, and CO2 degassing of the melt. Furthermore, we inferred the composition of the sources of the primary UML melt and their possible correlations with proto-kimberlitic melts, as well as the influence of the Triassic Siberian plume on the composition of the lithospheric mantle. The main differences between olivines from the Ilbokich and the Chadobets aillikites were that the olivines from the former had more magnesium-rich cores (Mg# = 89.2 ± 0.2), had Mg- and Cr-rich transition zones (Mg# = 89.7 ± 0.2 and 300-500 ppm Cr), had lower Ni (up to 3100 ppm) and Li (1.4-1.5 ppm), and had higher B (0.8-2.6 ppm) contents, all at higher Fo values (90-86), relative to the olivines from the latter (Mg# = 88-75; 200-300 ppm Cr; up to 3400 ppm Ni; 1.4-2.4 ppm Li; 0.4-2.2 ppm B). The Siberian aillikite sources contained a significant amount of metasomatic material. Phlogopite-rich MARID-type veins provided the likely metasomatic component in the pre-trap Devonian Ilbokich aillikite source, whereas the Triassic Chadobets aillikitic post-trap melts were derived from a source with a significant carbonate component. A comparison of UML olivines with olivines from the pre-trap and post-trap Siberian kimberlites shows a striking similarity. This suggests that the carbonate component in the aillikitic source could have been produced by evolved kimberlite melts. The differences in the lithospheric metasomatic component that contributed to pre-trap and post-trap aillikitic melts can be interpreted as reflections of the thermal impact of the Siberian Traps, which reduced phlogopite-bearing metasomes within the southwestern Siberian sub-continental lithospheric mantle.
Geological Society of London Special Publication Supercontinent Cycles through Earth History., Vol. 424, pp. 167-190.
South America, Brazil
Supercontinents
Abstract: Moderate to high palaeolatitudes recorded in mafic dykes, exposed along the coast of Bahia, Brazil, are partly responsible for some interpretations that the São Francisco/Congo craton was separate from the low-latitude Rodinia supercontinent at about 1050 Ma. We report new palaeomagnetic data that replicate the previous results. However, we obtain substantially younger U-Pb baddeleyite ages from five dykes previously thought to be 1.02- 1.01 Ga according to the 40 Ar/ 39 Ar method. Specifically, the so-called 'A-normal' remanence direction from Salva-dor is dated at 924.2 + 3.8 Ma, within error of the age for the 'C' remanence direction at 921.5 + 4.3 Ma. An 'A-normal' dyke at Ilhéus is dated at 926.1 + 4.6 Ma, and two 'A-normal' dykes at Olivença have indistinguishable ages with best estimate of emplacement at 918.2 + 6.7 Ma. We attribute the palaeomagnetic variance of the 'A-normal' and 'C' directions to lack of averaging of geomagnetic palaeosecular variation in some regions. Our results render previous 40 Ar/ 39 Ar ages from the dykes suspect, leaving late Mesoproterozoic palaeolatitudes of the São Francisco/Congo craton unconstrained. The combined 'A-normal' palaeomagnetic pole from coastal Bahia places the São Francisco/Congo craton in moderate to high palaeolatitudes at c. 920 Ma, allowing various possible positions of that block within Rodinia. Despite more than two decades of intense global research, the configuration of Neoproterozoic supercontinent Rodinia remains enigmatic. Following the first global synthesis by Hoffman (1991), most models include a central location for Laurentia, flanked by 'East' Gondwana-Land cra-tons along its proto-Cordilleran margin and 'West'
Geochemical processes in peridotite xenoliths from the Premier diamond mine, South Africa: evidence -depletion and refertilization of subcratonic lithosphere.
Trace element chemistry of mineral inclusions in eclogitic diamonds from the Premier ( Cullinan) and Finsch kimberlites: implications for evolution mantle
Abstract: Mechanisms of Precambrian orogeny and their contribution to the origin of ultrahigh temperature granulites, granite-greenstone terranes and net crustal growth remain debatable. Here, we use 2D numerical models with 150 °C higher mantle temperatures compared to present day conditions to investigate physical and petrological controls of Precambrian orogeny during forced continental plates convergence. Numerical experiments show that convergence between two relatively thin blocks of continental lithosphere with fertile mantle creates a short-lived cold collisional belt that later becomes absorbed by a long-lived thick and flat ultra-hot accretionary orogen with Moho temperatures of 700–1100 °C. The orogen underlain by hot partially molten depleted asthenospheric mantle spreads with plate tectonic rates towards the incoming lithospheric block. The accretionary orogeny is driven by delamination of incoming lithospheric mantle with attached mafic lower crust and invasion of the hot partially molten asthenospheric wedge under the accreted crust. A very fast convective cell forms atop the subducting slab, in which hot asthenospheric mantle rises against the motion of the slab and transports heat towards the moving orogenic front. Juvenile crustal growth during the orogeny is accompanied by net crustal loss due to the lower crust subduction. Stability of an ultra-hot orogeny is critically dependent on the presence of relatively thin and warm continental lithosphere with thin crust and dense fertile mantle roots subjected to plate convergence. Increased thickness of the continental crust and subcontinental lithospheric mantle, pronounced buoyancy of the lithospheric roots, and decreased mantle and continental Moho temperature favor colder and more collision-like orogenic styles with thick crust, reduced magmatic activity, lowered metamorphic temperatures, and decreased degree of crustal modification. Our numerical modeling results thus indicate that different types of orogens (cold, mixed-hot and ultra-hot) could be created at the same time in the Early Earth, depending on compositional and thermal structures of interacting continental blocks.
Abstract: Mechanisms of Precambrian orogeny and their contribution to the origin of ultrahigh temperature granulites, granite-greenstone terranes and net crustal growth remain debatable. Here, we use 2D numerical models with 150 °C higher mantle temperatures compared to present day conditions to investigate physical and petrological controls of Precambrian orogeny during forced continental plates convergence. Numerical experiments show that convergence between two relatively thin blocks of continental lithosphere with fertile mantle creates a short-lived cold collisional belt that later becomes absorbed by a long-lived thick and flat ultra-hot accretionary orogen with Moho temperatures of 700-1100 °C. The orogen underlain by hot partially molten depleted asthenospheric mantle spreads with plate tectonic rates towards the incoming lithospheric block. The accretionary orogeny is driven by delamination of incoming lithospheric mantle with attached mafic lower crust and invasion of the hot partially molten asthenospheric wedge under the accreted crust. A very fast convective cell forms atop the subducting slab, in which hot asthenospheric mantle rises against the motion of the slab and transports heat towards the moving orogenic front. Juvenile crustal growth during the orogeny is accompanied by net crustal loss due to the lower crust subduction. Stability of an ultra-hot orogeny is critically dependent on the presence of relatively thin and warm continental lithosphere with thin crust and dense fertile mantle roots subjected to plate convergence. Increased thickness of the continental crust and subcontinental lithospheric mantle, pronounced buoyancy of the lithospheric roots, and decreased mantle and continental Moho temperature favor colder and more collision-like orogenic styles with thick crust, reduced magmatic activity, lowered metamorphic temperatures, and decreased degree of crustal modification. Our numerical modeling results thus indicate that different types of orogens (cold, mixed-hot and ultra-hot) could be created at the same time in the Early Earth, depending on compositional and thermal structures of interacting continental blocks.
Abstract: The term craton has a complex and confused etymology. Despite originally specifying only strength and stability - of the crust - the term craton, within the context of diamond exploration, has widely come to refer to a region characterised by crustal basement older than 2.5 Ga, despite the fact that some such “cratons” no longer possess their deep lithospheric root. This definition often precluded regions with deep lithospheric roots but basement younger than 2-2.5 Ga. Viscous, buoyant lithospheric mantle roots are key to the survival and stability of continental crust. Here we use a revised craton definition (Pearson et al., 2021, in press), that includes the requirement of a deep (~150 km or greater) and intact lithospheric root, to re-examine the link between cratons and diamonds. The revised definition has a nominal requirement for tectonic stability since ~ 1 Ga and recognises that some regions are “modified cratons” - having lost their deep roots, i.e., they may have behaved like cratons for an extended period but subsequently lost much of their stabilising mantle roots during major tectono-thermal events. In other words, despite being long-lived features, cratons are not all permanent. The 150 km lithospheric thickness cut-off provides an optimal match to crustal terranes with 1 Ga timescale stability. In terms of regional diamond exploration, for a given area, the crucial criterion is when a deep mantle root was extant, i.e., over what period was the lithospheric geotherm suitable for diamond formation, stability and sampling? A thick lithospheric root is key to the formation of deep-seated magmas such as olivine lamproites and to the evolution of sub-lithospheric sourced proto-kimberlites, all capable of carrying and preserving diamonds to Earth's surface. This criterion appears essential even for sub-lithospheric diamonds, that still require a diamond transport mechanism capable of preserving the high-pressure carbon polymorph via facilitating rapid transport of volatile-charged magma to the surface, without dilution from additional melting that takes place beneath thinner (<120 km) lithospheric "lids". Seismology can help to define the lateral extent of today's cratons, but a detailed understanding of the regional geological history, kimberlite eruption ages and geothermal conditions is required to evaluate periods of past diamond potential, no-longer evident today. This revised craton concept broadens the target terranes for diamond exploration away from only the Archean cores of cratons and an associated mentality that "the exception proves the rule". The revised definition is compatible with numerous occurrences of diamond in Proterozoic terranes or Archean terranes underpinned by Proterozoic mantle.
New dat a on the petrology of olivine lamproites of Western australia From the results of the investigation of magmatic inclusions in olivines.(Russian)
Doklady Academy of Sciences Akademy Nauk SSSR, (Russian), Vol. 284, No. 1, pp. 196-201
Re-Os isotopic composition of peridotitic sulphide inclusions in diamonds from Ellendale, Australia: age constraints on Kimberley cratonic lithosphere.
Geochimica et Cosmochimica Acta, Vol. 74, 11, pp. 3292-3306.
Abstract: Type Ib diamonds contain abundant isolated nitrogen and account for less than 0.1% of natural diamonds. This rarity is because over geological time and at temperatures typical of the cratonic lithosphere, isolated nitrogen aggregates to A centres (N pairs) and B centres (4N around a vacancy). Preservation of isolated nitrogen in natural diamonds requires either short mantle residency times or storage at temperatures <700 °C, whereas most cratonic diamonds are billions of years old and resided >1000 °C. Eclogitic sulphides in Zimmi Ib diamonds (Sierra Leone) have 650 Ma Re-Os ages, whose origin is best explained by rapid tectonic exhumation after continental collision to shallower depths in the keel prior to kimberlite eruption (Smit et al., 2016). Here we present SIMS and spectroscopic data for a new suite of Zimmi sulphide-bearing diamonds. These new data allow us to evaluate the speciation of diamond source fluids, and the defects in these diamonds that are responsible for their distinctive canary yellow colours. The combined dataset establishes the link between the spectroscopic features in Zimmi Ib diamonds and their unusual history. Low ?13C values below -15 ‰ in 3 diamonds result from source fluids that originated as organic carbon in the oceanic crust, and were recycled into the lithosphere during subduction. In particular, a trend of decreasing ?13C and N content from core to rim in a single diamond indicates closed-system growth from CH4-rich subducted fluids. Recycled origins for organic carbon supports the temporal link of Zimmi diamond formation with deep underthrusting during Neoproterozoic continental assembly, recorded in the Rokelide orogen. CL imaging of Zimmi diamonds reveals irregular growth patterns with abundant deformation lines, associated with tectonic exhumation of the diamonds. Vacancies formed by deformation were subsequently annealed to form NV centres, where the negative charge state (637 nm) is more abundant due to isolated nitrogen donating an electron. Fancy brownish-yellow to greenish-yellow colours observed in Zimmi Ib diamonds result from a combination of isolated nitrogen, deformation-related amber centres and NV centres. These colour-forming defects can all be attributed to the unique geological history of Zimmi Ib diamonds and their rapid exhumation after formation.
Abstract: Type Ib diamonds contain abundant isolated nitrogen and account for less than 0.1% of natural diamonds. This rarity is because over geological time and at temperatures typical of the cratonic lithosphere, isolated nitrogen aggregates to A centres (N pairs) and B centres (4N around a vacancy). Preservation of isolated nitrogen in natural diamonds requires either short mantle residency times or storage at temperatures <700 °C, whereas most cratonic diamonds are billions of years old and resided >1000 °C. Eclogitic sulphides in Zimmi Ib diamonds (Sierra Leone) have 650 Ma Re-Os ages, whose origin is best explained by rapid tectonic exhumation after continental collision to shallower depths in the keel prior to kimberlite eruption (Smit et al., 2016). Here we present SIMS and spectroscopic data for a new suite of Zimmi sulphide-bearing diamonds. These new data allow us to evaluate the speciation of diamond source fluids, and the defects in these diamonds that are responsible for their distinctive canary yellow colours. The combined dataset establishes the link between the spectroscopic features in Zimmi Ib diamonds and their unusual history. Low ?13C values below -15 ‰ in 3 diamonds result from source fluids that originated as organic carbon in the oceanic crust, and were recycled into the lithosphere during subduction. In particular, a trend of decreasing ?13C and N content from core to rim in a single diamond indicates closed-system growth from CH4-rich subducted fluids. Recycled origins for organic carbon supports the temporal link of Zimmi diamond formation with deep underthrusting during Neoproterozoic continental assembly, recorded in the Rokelide orogen. CL imaging of Zimmi diamonds reveals irregular growth patterns with abundant deformation lines, associated with tectonic exhumation of the diamonds. Vacancies formed by deformation were subsequently annealed to form NV centres, where the negative charge state (637 nm) is more abundant due to isolated nitrogen donating an electron. Fancy brownish-yellow to greenish-yellow colours observed in Zimmi Ib diamonds result from a combination of isolated nitrogen, deformation-related amber centres and NV centres. These colour-forming defects can all be attributed to the unique geological history of Zimmi Ib diamonds and their rapid exhumation after formation.
Smit, K.V., Shirey, S.B., Stern, R.A., Steele, A., Wang, W.
Diamond growth from C-H-N-O recycled fluids in the lithosphere: Evidence from CH4 micro-inclusions and dleta 13 C-Delta 15 N-N content in Marange mixed-habit diamonds.
European Geosciences Union General Assembly 2017, Vienna April 23-28, 1p. 9187 Abstract
Africa, Zimbabwe, Sierra Leone
Deposit - Marange, Zimmi
Abstract: Traditional models for diamond formation within the lithospheric mantle invoke either carbonate reduction or methane oxidation. Both these mechanisms require some oxygen exchange with the surrounding wall-rock at the site of diamond precipitation. However, peridotite does not have sufficient buffering capacity to allow for diamond formation via these traditional models and instead peridotitic diamonds may form through isochemical cooling of H 2 O-rich CHO fluids [1]. Marange mixed-habit diamonds from eastern Zimbabwe provide the first natural confirmation of this new diamond growth model [2]. Although Marange diamonds do not contain any silicate or sulphide inclusions, they contain Ni-N-vacancy complexes detected through photoluminescence (PL) spectroscopy that suggest the source fluids equilibrated in the Ni-rich depleted peridotitic lithosphere. Cuboid sectors also contain abundant micro-inclusions of CH 4 , the first direct observation of reduced CH 4-rich fluids that are thought to percolate through the lithospheric mantle [2]. In fluid inclusion-free diamonds, core-to-rim trends in ? 13 C and N content are used to infer the speciation of the diamond-forming fluid. Core to rim trends of increasing ? 13 C with decreasing N content are interpreted as diamond growth from oxidized CO 2-or carbonate-bearing fluids. Diamond growth from reduced species should show the opposite trends-decreasing ? 13 C from core to rim with decreasing N content. Within the CH 4-bearing growth sectors of Marange diamonds, however, such a 'reduced' trend is not observed. Rather, ? 13 C increases from core to rim within a homogeneously grown zone [2]. These contradictory observations can be explained through either mixing between CH 4-and CO 2-rich end-members of hydrous fluids [2] or through closed system precipitation from an already mixed CH 4-CO 2 H 2 O-maximum fluid with XCO 2 (CO 2 /[CO 2 +CH 4 ]) between 0.3 and 0.7 [3]. These results demonstrate that Marange diamonds precipitated from cooling CH 4-CO 2-bearing hydrous fluids rather than through redox buffering. As this growth mechanism applies to both the fluid-rich cuboid and gem-like octahedral sectors of Marange diamonds, a non-redox model for diamond formation from mixed CH 4-CO 2 fluids is indicated for a wider range of gem-quality peridotitic diamonds. Indeed, at the redox conditions of global diamond-bearing lithospheric mantle (FMQ-2 to-4; [4]), CHO fluids are strongly water-dominated and contain both CH 4 and CO 2 as dominant carbon species [5]. By contrast diamond formation in eclogitic assemblages, through either redox buffering or cooling of carbon-bearing fluids, is not as well constrained. Zimmi diamonds from the West African craton have eclogitic sulphide inclusions (with low Ni and high Re/Os) and formed at 650 Ma, overlapping with the timing of subduction [6]. In one Zimmi diamond, a core to rim trend of decreasing ? 13 C (-23.4 to-24.5 %¸) and N content is indicative of formation from reduced C 2 H 6 /CH 4-rich fluids, likely derived from oceanic crust recycled during Neoproterozoic subduction. Unlike mixed CH 4-CO 2 fluids near the water maximum, isochemical cooling or ascent of such reduced CHO fluids is not effficient at diamond precipitation. Furthermore, measurable carbon isotopic variations in diamond are not predicted in this model and therefore cannot be reconciled with the ?1 internal variation seen. Consequently, this Zimmi eclogitic diamond likely formed through redox buffering of reduced subduction-related fluids, infiltrating into sulphide-bearing eclogite.
Abstract: The Siberian craton in Russia hosts many of the country's famous diamond mines. The Lomonosov mine, however, occurs within the boundaries of a different craton-the Baltic shield, most of which lies in Europe. Unlike many diamond mines in South Africa, Canada, and Siberia, the Lomonosov deposit is not in a stable Archean geologic setting. Similar to the Argyle diamond mine in Australia, Lomonosov is in a younger Proterozoic orogenic (or mountain-building) region. Fancy pink diamonds at both these localities likely relate to these Proterozoic tectonic processes. Along with other diamond mines in Proterozoic geologic regions, the Lomonosov deposit (and its fancy-color diamond inventory) demonstrates that the diamond potential of these regions should not be overlooked.
Mineralogy and Petrology, in press available, 12p.
Canada, Ontario, Attawapiskat
deposit - Victor
Abstract: The Jurassic Victor kimberlite (Attawapiskat Field) was emplaced into an area of the central Superior Craton that was affected by a lithosphere-scale thermal event at ~1.1 Ga. Victor diamonds formed ca. 400 million years after this event, in a lithospheric mantle characterized by an unusually cool model geotherm (37-38 mW/m2; Hasterok and Chapman 2011). The bulk of Victor diamonds derives from a thin (<10 km thick) layer that is located at about 180 km depth and represents lherzolitic substrates (for 85% of diamonds). Geothermobarometric calculations (average pressure and temperature at the 1 sigma level are 57?±?2 kbar and 1129?±?16 °C) coupled with typical fluid metasomatism-associated trace element patterns for garnet inclusions indicate diamond precipitation under sub-solidus (lherzolite + H2O) conditions. This conclusion links the presence of a diamond-rich lherzolitic layer in the lithospheric mantle, just above the depth where ascending melts would freeze, to the unusually low paleogeotherm beneath Attawapiskat, because along an average cratonic geotherm (40 mW/m2) lherzolite in the presence of hydrous fluid would melt at depths >140 km.
Mineralogy and Petrology, doi.org/10.1007/ s00710-018- 0587-6 16p.
Africa, Sierra Leone
deposit - Zimmi
Abstract: Zimmi diamonds (Sierra Leone) have 500 million year mantle residency times whose origin is best explained by rapid tectonic exhumation to shallower depths in the mantle, associated with continental collision but prior to kimberlite eruption. Here we present spectroscopic data for a new suite of Zimmi sulphide-bearing diamonds that allow us to evaluate the link between their spectroscopic features and their unusual geological history. Cathodoluminesence (CL) imaging of these diamonds revealed irregular patterns with abundant deformation lamellae, associated with the diamonds' tectonic exhumation. Vacancies formed during deformation were subsequently naturally annealed to form vacancy clusters, NV0/- centres and H3 (NVN0). The brownish-yellow to greenish-yellow colours observed in Zimmi Ib-IaA diamonds result from visible absorption by a combination of isolated substitutional nitrogen ( {N}S^0 ) and deformation-related vacancy clusters. Colour-forming centres and other spectroscopic features can all be attributed to the unique geological history of Zimmi Ib-IaA diamonds and their rapid exhumation after formation.
Abstract: This study investigates the color origin of 40 natural Fancy Dark brown-black round brilliant diamonds from the Marange alluvial deposits in eastern Zimbabwe. Visual observations show that the dark appearance of the Marange diamonds is due to a combination of graphite micro-inclusions (associated with methane), graphite needles, and dark brown radiation stains that occur along internal fractures. The GR1 (V0) defect, typically formed during natural and artificial irradiation, is observed in the optical spectra of 43% of the diamonds, al- though its intensity is too low to significantly impact the bodycolor. Natural irradiation in these diamonds is likely related to their billion-year residence in the Umkondo conglomerate, which is known to contain radioac- tive minerals such as zircon. Aside from radiation staining, irradiation-damaged diamond appears non-lumines- cent in DiamondView images and shows a weaker, broader diamond peak (at 1332 cm?1) in Raman spectroscopy. Brown coloration of the radiation stains is due to heating of the diamonds during later regional metamorphism, which also facilitated the formation of the H3 (NVN0) and NiN complexes.
Abstract: Water is carried down into Earth at subduction zones by the process of plate tectonics. Much of the water escapes close behind the subduction zone, promoting melting of the mantle and giving rise to the volcanic chains in the Pacific Ocean basin known as the Ring of Fire, and many other volcanoes elsewhere. But can water be carried even further into the mantle? How would we even know? Why is it important, and what are the effects of such deep water storage? Diamonds can give us the answers to these questions. Recent discoveries of water-containing mineral inclusions and even free water held at high pressures in diamonds tell us that water is carried into Earth’s deep interior—perhaps as deep as 700 km.
Gems & Gemology, Sixth International Gemological Symposium Vol. 54, 3, 1p. Abstract p. 307.
Africa, Sierra Leone
deposit - zimmi
Abstract: Type Ib diamonds from Zimmi, Sierra Leone, have 500 My mantle residency times whose origin is best explained by rapid tectonic exhumation after continental collision to shallower depths in the mantle prior to kimberlite eruption (Smit et al., 2016). Here we present spectroscopic data for a new suite of Zimmi sulfide-bearing type Ib diamonds that allow us to evaluate the link between their rare Fancy yellow colors, the distribution of their spectroscopic features, and their unusual geological history. Cathodoluminesence (CL) imaging revealed irregular patterns with abundant deformation lamellae, associated with the diamonds’ tectonic exhumation (Smit et al., 2018). Vacancies formed during deformation were subsequently naturally annealed to form vacancy clusters, NV0/? centers, and H3 (NVN0). The brownish yellow to greenish yellow colors observed in Zimmi type Ib diamonds result from visible absorption by a combination of isolated nitrogen and deformation-related vacancy clusters (Smit et al., 2018). Color-forming centers and other spectroscopic features can all be attributed to the unique geological history of Zimmi type Ib diamonds and their rapid exhumation after formation.
Abstract: Diamond is one of Earth’s most extraordinary materials. It represents the pinnacle for several material and physical properties. As a gem, however, it is the near-perfect examples—diamonds attaining the D-Flawless distinction—and those with imperfections resulting in a vibrant or surprising color that create the most enduring impressions. Fancy-color natural diamonds are among the most highly valued gemstones due to their attractiveness and great rarity. The 18.96 ct Winston Pink Legacy, with a color grade of Fancy Vivid pink, recently made history by selling at over $50 million, its $2.6 million per carat price an all-time high for a pink diamond (Christie’s, 2018).
Abstract: Carbon is one of the most important elements on our planet, which led the Geological Society of London to name 2019 the Year of Carbon. Diamonds are a main host for carbon in the deep earth and also have a deeper origin than all other gemstones. Whereas ruby, sapphire, and emerald form in the earth’s crust, diamonds form many hundreds of kilometers deep in the earth’s mantle. Colored gemstones tell scientists about the crust; gem diamonds tell scientists about the mantle. This makes diamonds unique among gemstones: Not only do they have great beauty, but they can also help scientists understand carbon processes deep in the earth. Indeed, diamonds are some of the only direct samples we have of the earth’s mantle. But how do diamonds grow in the mantle? While Hollywood’s depiction of Superman squeezing coal captured the public’s imagination, in reality this does not work. Coal is a crustal compound and is not found at mantle pressures. Also, we now know that diamond does not prefer to form through direct conversion of solid carbon, even though the pressure and temperature conditions under which diamond forms have traditionally been studied experimentally as the reaction of graphite to diamond. Generally, two conditions are needed for diamond formation:?Carbon must be present in a mantle fluid or melt in sufficient quantity, and the melt or fluid must become reduced enough so that oxygen does not combine with carbon (see below). But do diamonds all grow by the same mechanism? What does their origin reveal about their growth medium and their mantle host rock? Surprisingly, diamonds do not all form in the same way, but rather they form in various environments and through varying mechanisms. Through decades of study, we now understand that diamonds such as the rare blue Hope, the large colorless Cullinan, and the more common yellow “cape” diamonds all have very different origins within the deep earth.
Abstract: The age of something is fundamental. Humans, animals, wine, cars, and antiques are viewed and understood in the context of their age. So it is with rocks and minerals. A geologist needs to know the age of rocks to construct the geologic history of an area. In the field, relative ages can be determined by cross-cutting relationships (the younger rock “cuts” across the older rock) or superposition (the younger rock overlies the older rock). To determine the absolute ages of rocks and minerals such as diamond, scientists measure naturally occurring radioactively decaying elements. Absolute ages are free of any knowledge of relative age relations to any other geological material. This is known as the science of geochronology...(no abstract, full article)
Diamond and Related Materials, in press available 33p.
Global
DiaMap
Abstract: Type IIb diamonds are those that contain more boron than nitrogen. The presence of this uncompensated boron gives rise to absorption in the infrared part of the electromagnetic spectrum, extending into the visible region and often resulting in blue colouration. Here we report on the expansion of the DiaMap freeware (for the automated spectral deconvolution of Type I [nitrogen containing] diamonds) to work on Type IIb diamonds, returning concentrations from three boron-related absorption bands, and determining which band provides the most reliable value. The program uses the calibration coefficients of Collins (2010), which show good relative agreement between the three bands, but might require some further study to confirm their absolute accuracy to the uncompensated boron concentration. The methodology of DiaMap_IIb is applicable to all Type IIb diamonds, both natural and synthetic. Analysis of high-resolution Fourier-transform infrared (FTIR) maps of two high-pressure high-temperature (HPHT) synthetic diamonds using DiaMap_IIb, confirm the growth sector dependence of the boron incorporation. Partitioning of boron strongly favours the octahedral {111} sectors.
Abstract: he science of studying diamond inclusions for understanding Earth history has developed significantly over the past decades, with new instrumentation and techniques applied to diamond sample archives revealing the stories contained within diamond inclusions. This chapter reviews what diamonds can tell us about the deep carbon cycle over the course of Earth’s history. It reviews how the geochemistry of diamonds and their inclusions inform us about the deep carbon cycle, the origin of the diamonds in Earth’s mantle, and the evolution of diamonds through time.
IN: Deep carbon: past to present, Orcutt, Daniel, Dasgupta eds., pp. 89-128.
Mantle
geodynamics
Abstract: The science of studying diamond inclusions for understanding Earth history has developed significantly over the past decades, with new instrumentation and techniques applied to diamond sample archives revealing the stories contained within diamond inclusions. This chapter reviews what diamonds can tell us about the deep carbon cycle over the course of Earth’s history. It reviews how the geochemistry of diamonds and their inclusions inform us about the deep carbon cycle, the origin of the diamonds in Earth’s mantle, and the evolution of diamonds through time.
IN: Deep Carbon: past to present. Editors Orcutt, Danielle, Dasgupta, pp. 89-128.
Mantle
geodynamics
Abstract: The science of studying diamond inclusions for understanding Earth history has developed significantly over the past decades, with new instrumentation and techniques applied to diamond sample archives revealing the stories contained within diamond inclusions. This chapter reviews what diamonds can tell us about the deep carbon cycle over the course of Earth’s history. It reviews how the geochemistry of diamonds and their inclusions inform us about the deep carbon cycle, the origin of the diamonds in Earth’s mantle, and the evolution of diamonds through time.
Geochimica et Cosmochimica Acta, Vol. 275, pp. 99-122.
Mantle
carbon
Abstract: Diamonds are unrivalled in their ability to record the mantle carbon cycle and mantle fO2 over a vast portion of Earth’s history. Diamonds’ inertness and antiquity means their carbon isotopic characteristics directly reflect their growth environment within the mantle as far back as ?3.5 Ga. This paper reports the results of a thorough secondary ion mass spectrometry (SIMS) carbon isotope and nitrogen concentration study, carried out on fragments of 144 diamond samples from various locations, from ?3.5 to 1.4 Ga for P [peridotitic]-type diamonds and 3.0 to 1.0 Ga for E [eclogitic]-type diamonds. The majority of the studied samples were from diamonds used to establish formation ages and thus provide a direct connection between the carbon isotope values, nitrogen contents and the formation ages. In total, 908 carbon isotope and nitrogen concentration measurements were obtained. The total ?¹³C data range from ?17.1 to ?1.9 ‰ (P = ?8.4 to ?1.9 ‰; E = ?17.1 to ?2.1‰) and N contents range from 0 to 3073 at. ppm (P = 0 to 3073 at. ppm; E = 1 to 2661 at. ppm). In general, there is no systematic variation with time in the mantle carbon isotope record since > 3 Ga. The mode in ?¹³C of peridotitic diamonds has been at ?5 (±2) ‰ since the earliest diamond growth ?3.5 Ga, and this mode is also observed in the eclogitic diamond record since ?3 Ga. The skewness of eclogitic diamonds’ ?¹³C distributions to more negative values, which the data establishes began around 3 Ga, is also consistent through time, with no global trends apparent. No isotopic and concentration trends were recorded within individual samples, indicating that, firstly, closed system fractionation trends are rare. This implies that diamonds typically grow in systems with high excess of carbon in the fluid (i.e. relative to the mass of the growing diamond). Any minerals included into diamond during the growth process are more likely to be isotopically reset at the time of diamond formation, meaning inclusion ages would be representative of the diamond growth event irrespective of whether they are syngenetic or protogenetic. Secondly, the lack of significant variation seen in the peridotitic diamonds studied is in keeping with modeling of Rayleigh isotopic fractionation in multicomponent systems (RIFMS) during isochemical diamond precipitation in harzburgitic mantle. The RIFMS model not only showed that in water-maximum fluids at constant depths along a geotherm, fractionation can only account for variations of <1‰, but also that the principal ?¹³C mode of ?5 ± 1‰ in the global harzburgitic diamond record occurs if the variation in fO2 is only 0.4 log units. Due to the wide age distribution of P-type diamonds, this leads to the conclusion that the speciation and oxygen fugacity of diamond forming fluids has been relatively consistent. The deep mantle has therefore generated fluids with near constant carbon speciation for 3.5 Ga.
Diamonds & Related Materials, In press available, 30p. Pdf
Global
synthetics
Abstract: Type IIb diamonds are those that contain more boron than nitrogen. The presence of this uncompensated boron gives rise to absorption in the infrared part of the electromagnetic spectrum, extending into the visible region and often resulting in blue colouration. Here we report on the expansion of the DiaMap freeware (for the automated spectral deconvolution of Type I [nitrogen containing] diamonds) to work on Type IIb diamonds, returning concentrations from three boron-related absorption bands, and determining which band provides the most reliable value. The program uses the calibration coefficients of Collins (2010), which show good relative agreement between the three bands, but might require some further study to confirm their absolute accuracy to the uncompensated boron concentration. The methodology of DiaMap_IIb is applicable to all Type IIb diamonds, both natural and synthetic. Analysis of high-resolution Fourier-transform infrared (FTIR) maps of two high-pressure high-temperature (HPHT) synthetic diamonds using DiaMap_IIb, confirm the growth sector dependence of the boron incorporation. Partitioning of boron strongly favours the octahedral {111} sectors.
Abstract: The Precambrian is marked by the stabilization of subcontinental mantle lithosphere and associated crystallization of lithospheric diamonds from slab-derived carbon [1,2]. These features and higher nitrogen contents are consistent with diamond fluid delivery from the crustal (eclogitic) part of the slab and keel growth by lateral accretion/advective thickening [e.g. 3-5] in shallow and reducing mantle wedge settings. Such diamonds are rare to non-existent in the Phanerozoic. Sublithospheric diamonds are also slab-derived but from nitrogen-poor fluids/melts. These diamond fluids were delivered from deeper carbonated crustal or serpentinized mantle portions of cold slabs that subducted into the mantle transition zone regions and warmed up. While the age of such sublithospheric diamonds is poorly known, current mantle tomogrpahy shows that these conditions are a feature of the modern Earth and are consistent with the few ages that show these diamonds are younger. Aside from depth differences, the conditions for the crystallization of slab-associated lithospheric vs sublithospheric diamonds are fundamentally different in slab temperature, fluid composition, and fluid source within the slab source-rock. We hypothesize that these differences between lithospheric and sublithospheric diamonds may also be of temporal significance. If so, slab-derived diamond petrogenesis could be a key to understanding why cratonic keel formation is prevalent in the early Precambrian. Slabderived diamonds provide evidence for a transition from Precambrian conditions of shallow-devolatilization and warmer, more buoyant plates, that would facilitate lithosphere thickening to Phanerozoic conditions of deeperdevolatilization, cooler, and less buoyant plates, that are less conducive to lithosphere thickening.
Abstract: Marange diamonds (Zimbabwe) contain both fluid-poor (gem-quality) and fluid-bearing growth zones with abundant CH4. As such, they provide the unique opportunity to compare trace element compositions of CH4-bearing diamonds with those of carbonatitic and saline high density fluid (HDF)-bearing diamonds (gem-quality and fibrous) to obtain an overview of mantle source fluids for diamond growth. HDF’s in fibrous diamonds and some gem-quality diamonds have been linked to subduction of surficial material, consistent with the global link between diamond age and collisional tectonic events. Even though Marange diamonds have +?15N indicative of surficial recycling, they do not display the expected Eu or Sr anomalies. Fibrous diamonds have the most fractionated REE patterns, with negligible HREE and high (La/Yb)N ? 100- 10000. Gem-quality diamonds have highly variable (La/Yb)N; the most unfractionated HDF’s are in Victor and Cullinan diamonds with low (La/Yb)N <76. HDF’s in Marange diamonds are intermediate between these two extremes, with (La/Yb)N = 23-240. Differences in (La/Yb)N between different diamond suites relate either to varying initial compositions (where low (La/Yb)N reflects derivation during higher degrees of melting) or to the increasing interaction of HDF’s in fibrous diamonds with mantle rocks during fluid infiltration. Marange diamonds have rare +Ce anomalies, that have so far only been reported for Victor and Brazil (sub-lithospheric) gem-quality diamonds. The oxidation state of Ce (Ce4+ vs Ce3+) and development of Ce anomalies could be attributed to ƒO2, melt/fluid composition, and PT conditions. In Marange, Victor and Brazil diamonds, Ce4+ substitution for Zr4+ does not appear to be a factor since we find no correlation between Zr content and Ce anomalies. However, in Marange diamonds, CH4-bearing zones have less variable Ce anomalies compared to the CH4-free zones, which may suggest Ce anomalies are indicative of fluid oxidation state.
Abstract: Before cutting and polishing, diamonds have highly variable surface features rarely, if ever, seen by the jewelry wearer. These features can tell an interesting story of diamond’s geological history deep within Earth-both in the mantle rocks where diamonds grew and during their subsequent volcanic transport. Our previous column showed that volcanic eruptions of kimberlite are how diamonds make their way from depth in the mantle to Earth’s surface. But this violent process does not leave the rough diamond unscathed. These early histories are rarely considered once the diamond has been faceted and set into jewelry, but they raise interesting and geologically important questions: Why do rough diamonds look so different from each other, and what might this tell us about their geological history? What effect does the kimberlite magma have on the diamond cargo? How can we see through this later stage of the diamond’s history to its millions and billions of years of mantle storage?
Americam Geophysical Union Fall meeting, 1p. Abstract
Europe, Norway
eclogites, peridotites
Abstract: The preservation of Archean cratons is typically attributed to the presence of a highly-depleted and buoyant sub-continental lithospheric mantle (SCLM) that is equally old or older than its overlying crust. Time constraints on the formation and petrological evolution of the SCLM are key to investigating its long-term evolution and role in the formation and preservation of the continental crust. Nevertheless, such constraints are difficult to obtain as well-preserved samples of the SCLM are rare and typically lack conventional chronometric minerals. The history of SCLM rocks is typically inferred on the basis of model ages, many of which indicate an Archean origin; however, these dates are difficult to link to specific mineral assemblages or chemical signatures, and the petrological and dynamic processes that these represent. Garnet Lu-Hf geochronology is one of the few chronometers that could overcome this limitation. In this study, a refined method in Lu-Hf garnet chronology was applied to fragments of the Laurentian SCLM that are now exposed as orogenic peridotites in the ultrahigh-pressure domains of the Western Gneiss Complex, Norway. The peridotite bodies comprise a variety of unusually well-preserved rock types-from dunites that record decompression and melting at >350 km depth to fertile lithologies produced by melting and fluid metasomatism. Our internal isochron results from pyrope (after exsolution from majorite) in dunite samples yielded identical Neoarchean ages; these are the first-ever obtained for mantle garnet. The ages coincide with a time interval during which there was voluminous juvenile crust formation, indicating a link between this global process and the deeply sourced mantle upwellings that these samples represent. Internal isochrons from websterite-and clinopyroxenite-hosted pyrope yielded Meso-to Neoproterozoic ages that exactly match two distinct supercontinent break-up events in the overlying continental crust. Together, the new Lu-Hf results indicate that since its extraction during a period of widespread Archean crustal growth, the Laurentian SCLM appears to have largely been at petro-physical and chemical stasis and evolved only during short pulses that ran in sync with the supercontinent cycle.
Journal of Metamorphic Geology, Vol. 38, pp. 593-627.
Australia
geochronology
Abstract: The final assembly of the Mesoproterozoic supercontinent Nuna was marked by the collision of Laurentia and Australia at 1.60 Ga, which is recorded in the Georgetown Inlier of NE Australia. Here, we decipher the metamorphic evolution of this final Nuna collisional event using petrostructural analysis, major and trace element compositions of key minerals, thermodynamic modelling, and multi?method geochronology. The Georgetown Inlier is characterised by deformed and metamorphosed 1.70-1.62 Ga sedimentary and mafic rocks, which were intruded by c. 1.56 Ga old S?type granites. Garnet Lu-Hf and monazite U-Pb isotopic analyses distinguish two major metamorphic events (M1 at c. 1.60 Ga and M2 at c. 1.55 Ga), which allows at least two composite fabrics to be identified at the regional scale—c. 1.60 Ga S1 (consisting in fabrics S1a and S1b) and c. 1.55 Ga S2 (including fabrics S2a and S2b). Also, three tectono?metamorphic domains are distinguished: (a) the western domain, with S1 defined by low?P (LP) greenschist facies assemblages; (b) the central domain, where S1 fabric is preserved as medium?P (MP) amphibolite facies relicts, and locally as inclusion trails in garnet wrapped by the regionally dominant low?P amphibolite facies S2 fabric; and (c) the eastern domain dominated by upper amphibolite to granulite facies S2 foliation. In the central domain, 1.60 Ga MP-medium?T (MT) metamorphism (M1) developed within the staurolite-garnet stability field, with conditions ranging from 530-550°C at 6-7 kbar (garnet cores) to 620-650°C at 8-9 kbar (garnet rims), and it is associated with S1 fabric. The onset of 1.55 Ga LP-high?T (HT) metamorphism (M2) is marked by replacement of staurolite by andalusite (M2a/D2a), which was subsequently pseudomorphed by sillimanite (M2b/D2b) where granite and migmatite are abundant. P-T conditions ranged from 600 to 680°C and 4-6 kbar for the M2b sillimanite stage. 1.60 Ga garnet relicts within the S2 foliation highlight the progressive obliteration of the S1 fabric by regional S2 in the central zone during peak M2 metamorphism. In the eastern migmatitic complex, partial melting of paragneiss and amphibolite occurred syn? to post? S2, at 730-770°C and 6-8 kbar, and at 750-790°C and 6 kbar, respectively. The pressure-temperature-deformation-time paths reconstructed for the Georgetown Inlier suggest a c. 1.60 Ga M1/D1 event recorded under greenschist facies conditions in the western domain and under medium?P and medium?T conditions in the central domain. This event was followed by the regional 1.56-1.54 Ga low?P and high?T phase (M2/D2), extensively recorded in the central and eastern domains. Decompression between these two metamorphic events is ascribed to an episode of exhumation. The two?stage evolution supports the previous hypothesis that the Georgetown Inlier preserves continental collisional and subsequent thermal perturbation associated with granite emplacement.
Abstract: The layered agpaitic nepheline syenites (kakortokites) of the Ilímaussaq complex, South Greenland, host voluminous accumulations of eudialyte-group minerals (EGM). These complex Na-Ca-zirconosilicates contain economically attractive levels of Zr, Nb and rare-earth elements (REE), but have commonly undergone extensive autometasomatic/hydrothermal alteration to a variety of secondary mineral assemblages. Three EGM alteration assemblages are recognized, characterized by the secondary zirconosilicates catapleiite, zircon and gittinsite. Theoretical petrogenetic grid models are constructed to assess mineral stabilities in terms of component activities in the late-stage melts and fluids. Widespread alteration of EGM to catapleiite records an overall increase in water activity, and reflects interaction of EGM with late-magmatic Na-, Cl- and F-rich aqueous fluids at the final stages of kakortokite crystallization. Localized alteration of EGM and catapleiite to the rare Ca-Zr silicate gittinsite, previously unidentified at Ilímaussaq, requires an increase in CaO activity and suggests post-magmatic interaction with Ca-Sr bearing aqueous fluids. The pseudomorphic replacement of EGM in the kakortokites was not found to be associated with significant remobilization of the primary Zr, Nb and REE mineralization, regardless of the high concentrations of potential transporting ligands such as F and Cl. We infer that the immobile behaviour essentially reflects the neutral to basic character of the late-magmatic fluids, in which REE-F compounds are insoluble and remobilization of REE as Cl complexes is inhibited by precipitation of nacareniobsite-(Ce) and various Ca-REE silicates. A subsequent decrease in F- activity would furthermore restrict the mobility of Zr as hydroxyl-fluoride complexes, and promote precipitation of the secondary zirconosilicates within the confines of the replaced EGM domains.
Earth and Planetary Science Letters, Vol. 465, pp. 59-69.
Mantle
Geothermometry
Abstract: Crustal foundering is an important mechanism in the differentiation and recycling of continental crust. Nevertheless, little is known about the dynamics of the lower crust, the temporal scale of foundering and its role in the dynamics of active margins and orogens. This particularly applies to active settings where the lower crust is typically still buried and direct access is not possible. Crustal xenoliths derived from mantle depth in the Pamir provide a unique exception to this. The rocks are well-preserved and comprise a diverse set of lithologies, many of which re-equilibrated at high-pressure conditions before being erupted in their ultrapotassic host lavas. In this study, we explore the petrological and chronological record of eclogite and felsic granulite xenoliths. We utilized accessory minerals - zircon, monazite and rutile - for coupled in-situ trace-element analysis and U-(Th-)Pb chronology by laser-ablation (split-stream) inductively coupled plasma mass spectrometry. Each integrated analysis was done on single mineral zones and was performed in-situ in thin section to maintain textural context and the ability to interpret the data in this framework. Rutile thermo-chronology exclusively reflects eruption (View the MathML source11.17±0.06Ma), which demonstrates the reliability of the U-Pb rutile thermo-chronometer and its ability to date magmatic processes. Conversely, zircon and monazite reveal a series of discrete age clusters between 55-11 Ma, with the youngest being identical to the age of eruption. Matching age populations between samples, despite a lack of overlapping ages for different chronometers within samples, exhibit the effectiveness of our multi-mineral approach. The REE systematics and age data for zircon and monazite, and Ti-in-zircon data together track the history of the rocks at a million-year resolution. The data reveal that the rocks resided at 30-40 km depth along a stable continental geotherm at 720-750?°C until 24-20 Ma, and were subsequently melted, densified, and buried to 80-90 km depth - 20 km deeper than the present-day Moho - at View the MathML source930±35°C. The material descended rapidly, accelerating from 0.9-1.7 mm?yr?1 to 4.7-5.8 mm?yr?1 within 10-12 Myr, and continued descending after reaching mantle depth at 14-13 Ma. The data reflect the foundering of differentiated deep-crustal fragments (2.9-3.5 g?cm?3) into a metasomatized and less dense mantle wedge. Through our new approach in constraining the burial history of rocks, we provided the first time-resolved record of this crustal-recycling process. Foundering introduced vestiges of old evolved crust into the mantle wedge over a relatively short period (c. 10 Myr). The recycling process could explain the variability in the degree of crustal contamination of mantle-derived magmatic rocks in the Pamir and neighboring Tibet during the Cenozoic without requiring a change in plate dynamics or source region.
Abstract: Free oxygen began to accumulate in Earth’s surface environments between 3.0 and 2.4 billion years ago. Links between oxygenation and changes in the composition of continental crust during this time are suspected, but have been difficult to demonstrate. Here we constrain the average composition of the exposed continental crust since 3.7 billion years ago by compiling records of the Cr/U ratio of terrigenous sediments. The resulting record is consistent with a predominantly mafic crust prior to 3.0 billion years ago, followed by a 500- to 700-million-year transition to a crust of modern andesitic composition. Olivine and other Mg-rich minerals in the mafic Archaean crust formed serpentine minerals upon hydration, continuously releasing O2-scavenging agents such as dihydrogen, hydrogen sulfide and methane to the environment. Temporally, the decline in mafic crust capable of such process coincides with the first accumulation of O2 in the oceans, and subsequently the atmosphere. We therefore suggest that Earth’s early O2 cycle was ultimately limited by the composition of the exposed upper crust, and remained underdeveloped until modern andesitic continents emerged.
Abstract: The burial and exhumation of continental crust during collisional orogeny exert a strong control on the dynamics of mountain belts and plateaus. Constraining the rates and style of exhumation of deeply buried crust has proven difficult due to complexities in the local geology and thermochronometric methods typically used. To advance this field, we applied trace?element and U?Pb laser ablation inductively coupled plasma mass spectrometry analyses to rutile from eclogite and amphibolite samples from the Western Gneiss Complex of Norway—an archetypal continental (ultra)high?pressure (UHP) terrane. Peak temperature and timing of midcrustal cooling were constrained for samples collected along a subduction? and exhumation?parallel transect, using Zr?in?rutile thermometry and U?Pb rutile geochronology, respectively. Peak temperatures decrease from 830 °C in the UHP domain to 730 °C at the UHP?HP transition, remain constant at 730 °C across most of the terrane, and decrease to 620 °C at the eclogite?out boundary. U?Pb results show that most of the terrane cooled through 500 °C at 380-375 Ma except for the lowest grade region, where cooling occurred approximately 20 million years earlier. The results indicate that exhumation was a two stage process, involving (1) flexural rebound and slab flattening at depth combined with foreland?directed extrusion, followed by (2) synchronous cooling below 500 °C across the, by then, largely flat?lying Western Gneiss Complex. The latter implies and requires relatively homogeneous mass removal across a large area, consistent with erosion of an overlying orogenic plateau. The Caledonides were at near?equatorial latitudes at the time. A Caledonian paleo?plateau thus may represent a so far unrecognized factor in Devonian and Carboniferous atmospheric circulation and climate forcing.
Abstract: The first find of microdiamond in the Nordøyane ultra-high-pressure (UHP) domain of the Western Gneiss Region (WGR) of the Scandinavian Caledonides reshaped tectonic models for the region. Nevertheless, in spite of much progress regarding the meaning and significance of this find, the history of rock that the diamonds were found in is complex and still largely ambiguous. To investigate this, we report U-Pb zircon ages obtained from the exact crushed sample material in which metamorphic diamond was first found. The grains exhibit complicated internal zoning with distinct detrital cores overgrown by metamorphic rims. The cores yielded a range of ages from the Archaean to the late Neoproterozoic / early Cambrian. This detrital zircon age spectrum is broadly similar to detrital signatures recorded by metasedimentary rocks of the Lower and Middle allochthons elsewhere within the orogen. Thus, our dating results support the previously proposed affinity of the studied gneiss to the Seve-Blåhø Nappe of the Middle Allochthon. Metamorphic rims yielded a well-defined peak at 447 ± 2 Ma and a broad population that ranges between c. 437 and 423 Ma. The data reveal a prolonged metamorphic history of the Fjørtoft gneiss that is far more complex then would be expected for a UHP rock that has seen a single burial and exhumation cycle. The data are consistent with a model involving multiple such cycles, which would provide renewed support for the dunk tectonics model that has been postulated for the region.
Earth and Planetary Science letters, Vol. 528, 115820 11p.
Mantle
craton
Abstract: The continental crust and sub-continental lithospheric mantle (SCLM) are co-dependent reservoirs in terms of their geochemistry, tectonics, and long-term evolution. Obtaining insight into the mechanisms of lithosphere formation and differentiation requires robust constraint on the complex petrological history of mantle rocks. This has proven difficult as samples from the deep mantle are rare and, although many may have formed in the Archean, no such age has been obtained directly from mantle-derived silicate minerals. Lutetium-hafnium geochronology of garnet has the potential of overcoming this limitation. In this study, this technique was applied on fragments of the SCLM exposed in the Norwegian Caledonides. The chronologic record of these rocks is rich and extensive, yet it is difficult to interpret and is, in part, inconsistent. Our Lu-Hf results from supersilicic pyrope in dunite provide the first Archean internal isochron ages for mantle rocks. These ages are consistent with a period of juvenile crust formation worldwide and provide a record of deeply sourced mantle upwellings from >350 km depth. Results from fertile rock types indicate that melting and isotope re-equilibration occurred in sync with two Proterozoic supercontinent break-up events that are recorded in the Laurentian and Baltic lithospheres. Together, the results indicate that since its extraction during a period of rapid Archean crustal growth, the SCLM appears to have largely been at petro-physical and chemical stasis, with the exception of major episodes of continental break-up. The evolution of the SCLM is thus, highly punctuated and ultimately controlled by the Wilson cycle.
Journal of Metamorphic Geology, doi:10.1111/jmg.12599
Canada, Quebec
cratons
Abstract: Dating the onset of continental collision is fundamental in defining orogenic cycles and their effects on regional tectonics and geodynamic processes through time. Part of the Palaeoproterozoic Trans?Hudson Orogen, the Southeastern Churchill Province (SECP) is interpreted to result from the amalgamation of Archean to Palaeoproterozoic crustal blocks (amalgamated as the central Core Zone) that diachronically collided with the margins of the North Atlantic and Superior cratons, resulting in two bounding transpressive orogens: the Torngat and New Quebec Orogens. The SECP exposes mainly gneissic middle to lower orogenic crust in which deformation and amphibolite to granulite facies metamorphism and anatexis overprinted the early geological features classically used to constrain the timing of collisional events. To enable improved tectonic models for the development of the SECP, and the Trans?Hudson as a whole, we investigated granulite facies supracrustal sequences from the Tasiuyak Complex (TC) accretionary prism and the western margin of the North Atlantic Craton-that is, Saglek Block (upper plate)-using a multi?chronometer approach coupled with trace element geochemistry. In particular, the use of garnet Lu-Hf geochronology provides an important minimal time constraint for crustal thickening and collision. Garnet growth in the TC is constrained at 1885 ± 12 Ma (Lu-Hf), indistinguishable from U-Pb age of prograde monazite at 1873 ± 5 Ma. Zircon growth during melt crystallization occurred at 1848 ± 12 Ma. Garnet from the overriding Saglek Block is dated at 2567 ± 4.4 Ma (Lu-Hf) and indicates that gneissic rocks from the upper plate did not record the metamorphic imprint of the Torngat Orogeny. The diachronicity of the integrated metamorphic record across the strike of the SECP is explained by the location of terrane boundaries, consistent with the westward growth of the Churchill plate margin through sequential amalgamation of narrow crustal blocks during accretionary tectonics from c. 1.9 to 1.8 Ga.
Journal of Metamorphic Geology, Vol. 39, 8, 31p. Pdf
Canada
geochronology
Abstract: Dating the onset of continental collision is fundamental in defining orogenic cycles and their effects on regional tectonics and geodynamic processes through time. Part of the Palaeoproterozoic Trans-Hudson Orogen, the Southeastern Churchill Province (SECP) is interpreted to result from the amalgamation of Archean to Palaeoproterozoic crustal blocks (amalgamated as the central Core Zone) that diachronically collided with the margins of the North Atlantic and Superior cratons, resulting in two bounding transpressive orogens: the Torngat and New Quebec Orogens. The SECP exposes mainly gneissic middle to lower orogenic crust in which deformation and amphibolite to granulite facies metamorphism and anatexis overprinted the early geological features classically used to constrain the timing of collisional events. To enable improved tectonic models for the development of the SECP, and the Trans-Hudson as a whole, we investigated granulite facies supracrustal sequences from the Tasiuyak Complex (TC) accretionary prism and the western margin of the North Atlantic Craton—that is, Saglek Block (upper plate)—using a multi-chronometer approach coupled with trace element geochemistry. In particular, the use of garnet Lu-Hf geochronology provides an important minimal time constraint for crustal thickening and collision. Garnet growth in the TC is constrained at 1885 ± 12 Ma (Lu-Hf), indistinguishable from U-Pb age of prograde monazite at 1873 ± 5 Ma. Zircon growth during melt crystallization occurred at 1848 ± 12 Ma. Garnet from the overriding Saglek Block is dated at 2567 ± 4.4 Ma (Lu-Hf) and indicates that gneissic rocks from the upper plate did not record the metamorphic imprint of the Torngat Orogeny. The diachronicity of the integrated metamorphic record across the strike of the SECP is explained by the location of terrane boundaries, consistent with the westward growth of the Churchill plate margin through sequential amalgamation of narrow crustal blocks during accretionary tectonics from c. 1.9 to 1.8 Ga.
Abstract: The powerpoint of the presentation made by Wiehan Smit at the SAIMM July 2019 Grade Control School has been made available by the author as a pdf file.
Earth and Planetary Science Letters, Vol. 451, pp. 241-250.
Europe, Greenland
Aillikite
Abstract: Mantle-derived CO2-rich magma ascends rapidly through the lithospheric column, supporting upward transport of large mantle-xenoliths and xenocryst (>30 vol%) loads to the (sub-)surface within days. The regional magmatism during which such pulses occur is typically well characterized in terms of general duration and regional compositional trends. In contrast, the time-resolved evolution of individual ultramafic dyke and pipe systems is largely unknown. To investigate this evolution, we performed a geochemical and speedometric analysis of xenoliths from ultramafic (aillikite) dykes in two Neoproterozoic alkaline provinces in West Greenland: 1) Sarfartôq, which overlies Archean ultra-depleted SCLM and yielded ultra-deep mineral indicators, and 2) Sisimiut, where the SCLM is refertilized and deep xenoliths (>120 km) are lacking. We focused on the rare and understudied crustal xenoliths, which preserve a rich record of melt injection. The xenoliths are derived from 25-36 km depth and were transported to the sub-surface within View the MathML source4±1h (Fe-in-rutile speedometry), during which they were exposed to the magmatic temperature of View the MathML source1,015±50°C (Zr-in-rutile thermometry). Garnet major-element speedometry shows that before the xenolith-ascent stage the lower crust had already been exposed to a variety of magmas for 700 (Sarfartôq) and 7,100 (Sisimiut) years. The Sisimiut samples contain exotic carbonate- and sulfide-rich assemblages, which occurred during the early stages of melt infiltration. Absence of such exotic assemblages and the faster magmatic development at Sarfartôq are tentatively linked to higher decarbonation kinetics in the more depleted SCLM at this location. The data reveal the so far unrecognized pre-eruptive development of ultramafic systems. This stage involves non-steady state melt-silicate interaction between ascending magmas and the immediate SCLM wall-rock, during which the composition of both is modified. The progress and duration of this interaction is strongly influenced by the composition of the SCLM. Kinetics factors describing this interaction could thus be used to model the chemistry of aillikite and similar ultramafic magmas.
A Short Sketch of the African Diamond Mine. with Tables For calculating Prices of Precious Stones and As certaining Their Distinguishing Characteristics.
South African Journal of Geology, Vol. 123, 4, pp. 597-614. pdf
Africa, South Africa
alkaline rocks
Abstract: Numerous Mesoproterozoic alkaline intrusions belonging to the Pilanesberg Alkaline Province are present within the Transvaal sub-basin of the Kaapvaal Craton. The Pilanesberg Complex is the best-known example; it represents one of the world’s largest alkaline complexes, and is associated with a northwest-southeast trending dyke swarm that extends from Botswana to the southwest of Johannesburg. This paper documents the results of a petrological and geochemical study of a thin mafic sill (here referred to as an alkaline igneous body, AIB), which intrudes the ca. 2 200 Ma Silverton Formation close to the southernmost part of the Pilanesberg dyke swarm. The AIB has only been observed in cores from a borehole drilled close to Carletonville. It is hypocrystalline, containing randomly oriented elongated skeletal kaersutite crystals and 6 to 8 mm varioles mainly composed of radially oriented acicular plagioclase. These two textures are related to undercooling, probably linked to the limited thickness (70 cm) of the AIB coupled with a probable shallow emplacement depth. Ar-Ar dating of the kaersutite gives an age of ca. 1 400 Ma, similar to the age of Pilanesberg Complex. However, the AIB is an alkaline basaltic andesite and is thus notably less differentiated than the Pilanesberg Complex and some of its associated dykes, such as the Maanhaarrand dyke, for which we provide whole-rock geochemical data. Literature data indicate that the Pilanesberg dyke swarm also contains mafic hypabyssal rocks suggesting a link between the dyke swarm and the AIB. The AIB is characterized by strongly negative ?Nd and ?Hf, that cannot be related to crustal contamination, as shown by positive Ti and P anomalies, and the absence of negative Nb-Ta anomalies in mantle-normalised trace element diagrams. The AIB magma is interpreted to have been derived from a long-lived enriched, probably lithospheric mantle reservoir. The AIB thus provides important information on the magma source of the Pilanesberg Alkaline Province.
South African Journal of Geology, Vol. 121, pp. 227-236.
Africa, South Africa
geomorphology
Abstract: Rocky reaches of the southeast African coastline are characterized mainly by log-spiral and headland-bound bays. Extensive fieldwork was carried out to investigate both documented and new exposures of Cretaceous beds on the southern KwaZulu-Natal and upper Eastern Cape (Transkei) coasts. Our results suggest that geological inheritance plays an important role in the contemporary rocky coast geomorphology. We offer evidence that post-Gondwana break-up mass flow channels play an important role in the present southeast African coastline morphology. Mass flow channels contain fills of incompetent Cretaceous rocks which are being preferentially eroded by prevailing marine and fluvial processes to form headland-bound embayment landforms. This study has identified an important geomorphic process for the development of the current southeast African coastline.
Abstract: Several interstellar environments produce 'anomalous microwave emission', with brightness-peaks at tens-of-gigahertz frequencies. The emission's origins are uncertain - rapidly-spinning nano-particles could emit electric-dipole radiation, but polycyclic aromatic hydrocarbons proposed as the carrier are now found not to correlate with Galactic signals. The difficulty is to identify co-spatial sources over long lines of sight. Here we identify anomalous microwave emission in three proto-planetary discs. These are the only known systems that host hydrogenated nano-diamonds, in contrast to very common detection of polycyclic aromatic hydrocarbons. Spectroscopy locates the nano-diamonds close to the host-stars, at physically-constrained temperatures. Developing disc models, we reproduce the emission with diamonds 0.75-1.1 nanometres in radius, holding less than or equal to 1-2 per cent of the carbon budget. The microwave-emission:stellar-luminosity ratios are approximately constant, allowing nano-diamonds to be ubiquitous but emitting below detection thresholds in many star-systems. This can unify the findings with similar-sized diamonds found within solar system meteorites. As nano-diamond spectral absorption is seen in interstellar sightlines, these particles are also a candidate for generating galaxy-scale anomalous microwave emission.
European Geosciences Union General Assembly 2017, Vienna April 23-28, 1p. 16438 Abstract
Africa, Zimbabwe, Australia, South America, Brazil
Deposit - Murowa, Argyle, Machado River
Abstract: Fourier Transform Infrared (FTIR) spectroscopy is a commonly-used technique for investigating diamonds. It gives the most useful information if spatially-resolved measurements are used [1]. In this contribution we discuss the best way to acquire and present FTIR data from diamonds, using examples from Murowa (Zimbabwe), Argyle (Australia) and Machado River (Brazil). Examples of FTIR core-to-rim line scans, maps with high spatial resolution and maps with high spectral resolution that are fitted to extract the spatial variation of different nitrogen and hydrogen defects are presented. Model mantle residence temperatures are calculated from the concentration of A and B nitrogen-containing defects in the diamonds using known times of annealing in the mantle. A new, two-stage thermal annealing model is presented that better constrains the thermal history of the diamond and that of the mantle lithosphere in which the diamond resided. The effect of heterogeneity within the analysed FTIR volume is quantitatively assessed and errors in model temperatures that can be introduced by studying whole diamonds instead of thin plates are discussed. The kinetics of platelet growth and degradation will be discussed and the potential for two separate, kinetically-controlled defect reactions to be used to constrain a full thermal history of the diamond will be assessed. [1] Kohn, S.C., Speich, L., Smith, C.B. and Bulanova, G.P., 2016. FTIR thermochronometry of natural diamonds: A closer look.
The Discovery and Evaluation of the Ellendale and Argyle Lamproite Diamond Deposits, Kimberley, Western Australia.
Society for Mining, Metallurgy and Exploration (SME)-American Institute of Mining, Metallurgical, and Petroleum Engineers (AIME)., SYMPOSIUM OUTLINE FALL MEETING DENVER OCTOBER 26TH. No. 84-3
An integrated petrological, geochemical and Re-Os isotope study of peridotite xenoliths from the Argyle lamproite, western Australia and implications for
Mineral inclusions in sublithospheric diamonds from Collier 4 kimberlite pipe, Juina, Brazil: subducted protoliths, carbonated melts and primary kimberlite ..
Contributions to Mineralogy and Petrology, Vol. 160, 4, pp. 489-50.
Smith, C.B., Haggerty, S.E., Chatterjee, B., Beard, A., Townend, R.
Kimberlite, lamproite, ultramafic lamprophyre, and carbonatite relationships on the Dharwar Craton, India: an example from the Khaderpet pipe, a Diamondiferous ultramafic with associated carbonatite intrusion.
Smith, C.B., Haggerty, S.E., Chatterjee, B., Beard, A., Townend, R.
Kimberlite, lamproite, ultramafic lamprophyre, carbonatite relationships on the Dharwar Craton, India; and example from the Khaderpet pipe, a Diamondiferous ultramafic with associated carbonatite intrusion.
Earth and Planetary Science Letters, Vol. 432, pp. 374-380.
South America, Brazil
Deposit - Juina-5, Collier-4, Machado River
Abstract: Sub-lithospheric diamonds from the Juina-5 and Collier-4 kimberlites and the Machado River alluvial deposit in Brazil have carbon isotopic compositions that co-vary with the oxygen isotopic compositions of their inclusions, which implies that they formed by a mixing process. The proposed model for this mixing process, based on interaction of slab-derived carbonate melt with reduced (carbide- or metal-bearing) ambient mantle, explains these isotopic observations. It is also consistent with the observed trace element chemistries of diamond inclusions from these localities and with the experimental phase relations of carbonated subducted crust. The 18O-enriched nature of the inclusions demonstrates that they incorporate material from crustal protoliths that previously interacted with seawater, thus confirming the subduction-related origin of superdeep diamonds. These samples also provide direct evidence of an isotopically anomalous reservoir in the deep (?350 km) mantle.
Abstract: Diamonds from the Machado River alluvial deposit have been characterised on the basis of external morphology, internal textures, carbon isotopic composition, nitrogen concentration and aggregation state and mineral inclusion chemistry. Variations in morphology and features of abrasion suggest some diamonds have been derived directly from local kimberlites, whereas others have been through extensive sedimentary recycling. On the basis of mineral inclusion compositions, both lithospheric and sublithospheric diamonds are present at the deposit. The lithospheric diamonds have clear layer-by-layer octahedral and/or cuboid internal growth zonation, contain measurable nitrogen and indicate a heterogeneous lithospheric mantle beneath the region. The sublithospheric diamonds show a lack of regular sharp zonation, do not contain detectable nitrogen, are isotopically heavy (?13CPDB predominantly ? 0.7 to ? 5.5) and contain inclusions of ferropericlase, former bridgmanite, majoritic garnet and former CaSiO3-perovskite. This suggests source lithologies that are Mg- and Ca-rich, probably including carbonates and serpentinites, subducted to lower mantle depths. The studied suite of sublithospheric diamonds has many similarities to the alluvial diamonds from Kankan, Guinea, but has more extreme variations in mineral inclusion chemistry. Of all superdeep diamond suites yet discovered, Machado River represents an end-member in terms of either the compositional range of materials being subducted to Transition Zone and lower mantle or the process by which materials are transferred from the subducted slab to the diamond-forming region.
Abstract: In this study, 660 diamonds from Igarapé Lajes Diggings (Roosevelt and Aripuanã Park indigenous areas), in Amazonian craton, Rondônia State, Brazil, were investigated. Their morphological, optical and surface characteristics were described using optical and scanning electron microscopy (SEM), cathodoluminescence (CL) and infrared spectroscopy (FTIR). The results demonstrated a predominance of resorbed crystals with many surface corrosion features, generally colorless, and led to the identification of four distinct groups: G1, G2, G3 and G4. Group G1 presents features of secondary sources while G2 and G4 show only primary features, some of which are not described in literature. Group G3 is similar to the other groups, however, is composed of less resorbed specimens with primary octahedral morphology relatively well preserved, indicating shorter time of exposure to dissolution effects. Cathodoluminescence in G2 is attributed to features of plastic deformation and to low contents of nitrogen (< 100 ppm, Type II) and high aggregation (IaB). G4 shows homogeneous blue CL, high contents of nitrogen (700 to 1000 ppm) and intermediate aggregation (IaAB). G1 presents luminescence influenced by radiation effects and populations with N contents and aggregation in the same ranges of G2 and G4, suggesting that the primary sources of the three groups can be the same. The relationship of nitrogen content versus aggregation state indicates higher temperatures of formation for G2 and lower for G4. The obtained data suggests that diamonds of G2 originated in sublithospheric mantle as has also been reported in nearby deposits (Machado River and Juína). The employed techniques were also effective in distinguishing diamonds from Roosevelt Reserve and from other localities, indicating that they could be used for improvement of certification procedures of diamonds of unknown origin.
Abstract: The trace element compositions of inclusions in sub-lithospheric diamonds from the Juina-5 kimberlite, Brazil, are presented. Literature data for mineral/melt partition coefficients were collated, refitted and employed to interpret inclusion compositions. As part of this process an updated empirical model for predicting the partitioning behaviour of trivalent cations for garnet-melt equilibrium calibrated using data from 73 garnet-melt pairs is presented. High levels of trace element enrichment in inclusions interpreted as former calcium silicate perovskite and majoritic garnet preclude their origin as fragments of an ambient deep mantle assemblage. Inclusions believed to represent former bridgmanite minerals also display a modest degree of enrichment relative to mantle phases. The trace element compositions of ‘NAL’ and ‘CF phase’ minerals are also reported. Negative Eu, Ce, and Y/Ho anomalies alongside depletions of Sr, Hf and Zr in many inclusions are suggestive of formation from a low-degree carbonatitic melt of subducted oceanic crust. Observed enrichments in garnet and ‘calcium perovskite’ inclusions limit depths of melting to less than ~ 600 km, prior to calcium perovskite saturation in subducting assemblages. Less enriched inclusions in sub-lithospheric diamonds from other global localities may represent deeper diamond formation. Modelled source rock compositions that are capable of producing melts in equilibrium with Juina-5 ‘calcium perovskite’ and majorite inclusions are consistent with subducted MORB. Global majorite inclusion compositions suggest a common process is responsible for the formation of many superdeep diamonds, irrespective of geographic locality. Global transition zone inclusion compositions are reproduced by fractional crystallisation from a single parent melt, suggesting that they record the crystallisation sequence and melt evolution during this interaction of slab melts with ambient mantle. All observations are consistent with the previous hypothesis that many superdeep diamonds are created as slab-derived carbonatites interact with peridotitic mantle in the transition zone.
Africa, Zimbabwe, Australia, South America, Brazil
Deposit - Murowa, Argyle, Machado River
Abstract: Fourier Transform Infrared (FTIR) spectroscopy is a commonly-used technique for investigating diamonds, that gives the most useful information if spatially-resolved measurements are used. In this paper we discuss the best way to acquire and present FTIR data from diamonds, using examples from Murowa (Zimbabwe), Argyle (Australia) and Machado River (Brazil). Examples of FTIR core-to-rim line scans, maps with high spatial resolution and maps with high spectral resolution that are fitted to extract the spatial variation of different nitrogen and hydrogen defects are presented. Model mantle residence temperatures are calculated from the concentration of A and B nitrogen-containing defects in the diamonds using known times of annealing in the mantle. A new, two-stage thermal annealing model is presented that better constrains the thermal history of the diamond and that of the mantle lithosphere in which the diamond resided. The effect of heterogeneity within the analysed FTIR volume is quantitatively assessed and errors in model temperatures that can be introduced by studying whole diamonds instead of thin plates are discussed. The spatial distribution of VN3H hydrogen defects associated with the 3107 cm? 1 vibration does not follow the same pattern as nitrogen defects, and an enrichment of VN3H hydrogen at the boundary between pre-existing diamond and diamond overgrowths is observed. There are several possible explanations for this observation including a change in chemical composition of diamond forming fluid during growth or kinetically controlled uptake of hydrogen.
Abstract: Diamonds from Dachine, French Guiana, are unique among worldwide diamond populations. The diamonds were transported to the surface in an unusual ultramafic extrusive magma with an affinity to boninite or komatiite, which was emplaced within an arc geological setting at ~ 2.2 Ga. Dachine diamonds have internal and external morphologies indicative of relatively rapid growth from carbon oversaturated fluids or melts, and exhibit internal features consistent with residence in a high-strain environment. On the basis of nitrogen (N) defects the diamonds are categorized as Type Ib-IaA. The unusually low aggregation state of N places severe constraints on the thermal history of the diamonds, effectively ruling out derivation in convecting mantle. The carbon and N isotopic compositions of Dachine diamonds are consistent with a sedimentary source of carbon, with the majority of diamonds having ?13C values < ? 25‰ and ?15N values > + 4‰. The primary carbon was presumably deposited on an early Proterozoic seafloor. Sulphide inclusions have low Ni and Cr and are comparable to lithospheric eclogitic-type sulphide inclusions. Three garnet and one clinopyroxene inclusion are also eclogitic in composition, and one garnet inclusion has a majorite component indicating an origin around 250 km depth. The silicate inclusions are highly depleted in many incompatible trace elements (e.g. LREE, Nb, Hf, Zr), and modelling indicates an eclogitic source lithology that contained a LREE-enriched trace phase such as epidote or allanite, and an HFSE-rich phase such as rutile. Four of the five inclusions are unusually enriched in Mn, as well as Ni and Co, and modelling indicates a protolith with the bulk composition of subducted normal MORB plus about 10% ferromanganese crust component. We suggest a model wherein Dachine diamonds precipitated from remobilized sedimentary carbon at the slab-mantle interface from liquids derived ultimately by deserpentinization of slab peridotite at depths of ~ 200 to 250 km. These fluids may also trigger melting in wedge peridotite, resulting in a volatile-rich ultramafic melt that transports the diamonds rapidly to the surface. The process of diamond formation and exhumation from the slab mantle interface likely occurred in a Paleoproterozoic subduction zone and over a very limited timespan, likely less than a million years.
Abstract: Platelets in diamond are extended planar defects that are thought to be generated during the nitrogen aggregation process in type Ia diamonds. They were subjected to intensive research during the 1980s and 1990s but the techniques used for observation of defects in diamond have improved since that time and new insights can be gained by further study. This study combines high resolution Fourier Transform Infrared (FTIR) analysis, with an emphasis on the main platelet peak, and transmission electron microscopic (TEM) imaging. By performing TEM and FTIR analyses on volumes of diamond that were closely spatially related it is shown that the average platelet diameter, D, follows the relationship D=ax?b where x is the position of the platelet peak in the infrared spectrum, a is a constant and b is the minimum position of the platelet peak. The best fit to the data is obtained if a value of b=1360cm?1 is used, giving a fitted value of a=221. The observed variation in infrared (IR) peak width can also be explained in terms of this relationship. Additionally, platelet morphology was found to vary according to diameter with large platelets being more elongated. The tendency to become more elongated can be described by the empirical equation AR=11.9D+19.6+0.4 where AR is the aspect ratio. Using the relationships established here, it will be possible to study platelet abundance and size as a function of parameters such as nitrogen concentration, nitrogen aggregation and diamond residence time in the mantle. This work therefore will open up new methods for constraining the geological history of diamonds of different parageneses and from different localities.
Africa, Zimbabwe. Australia, Canada, Northwest Territories, South Africa, Botswana
deposit - Murowa, Argyle, Diavik, Venetia, Orapa
Abstract: FTIR maps of diamond plates, cut through the centre of growth, contain abundant information about changing defect concentrations from core to rim. These data can, in principle, be interpreted in terms of the variation in conditions of diamond growth and the temperatures experienced by the diamond during the period of mantle residence between growth and exhumation. Many diamonds show multiple growth zones that can be observed by cathodoluminescence. Importantly, the combination of nitrogen concentration and nitrogen aggregation measured by FTIR can be used to determine whether the growth zones are of similar or very different ages (Kohn et al., 2016). In this study, we use automated fitting of several thousand individual spectra within each FTIR map to define a model temperature for each pixel using the Python program, QUIDDIT. We then use a two-stage aggregation model to constrain potential temperature-time histories for each diamond. To take full advantage of the temperature history recorded by zoned diamonds, radiometric ages of inclusions are required. If the growth ages of each zone and the date of exhumation are well-known, then a model temperature can be calculated for each zone. The combination of zone-specific ages and improved quality and processing of FTIR spectra is able to provide unique new insights into the thermal history of diamondbearing lithospheric mantle. For the first time we will be able to use the N defects in diamonds to work out whether a particular location in the lithosphere has heated or cooled over long periods of geological time. The implications for the mechanism of formation of lithosphere will be discussed. We will illustrate the approach using examples of zoned diamonds from Murowa (Zimbabwe), Argyle (Australia), Diavik (Canada), Venetia (South Africa) and Orapa (Botswana).
Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0625-4 13p.
Australia, Western Australia
deposit - Argyle
Abstract: Underground mining and deep drilling of the richly diamondiferous ~1.2 Ga Argyle lamproite in Western Australia has prompted a re-evaluation of the geology of the pipe. Argyle is considered to be a composite pipe that formed by the coalescence of several diatremes and has been offset and elongated by post-emplacement faulting. Recent geological studies have recognised at least five distinct volcaniclastic lamproite lithofacies with differing diamond grades. The new data suggest that the centre of the southern (main) diatreme is occupied by well-bedded, olivine lamproite lapilli tuff with very high diamond grades (>10 ct/t). Characteristic features include a clast-supported fabric and high modal abundance of densely packed lamproite lapilli and coarse-grained, likely mantle-derived olivine now replaced by serpentine and/or talc. The persistence of small-scale graded and cross-bedding in this lithofacies to depths of ~1.5 km below the original surface prior to erosion suggests phreatomagmatic volcanism forming the diatreme was syn-eruptively accompanied by subsidence of the tephra, maintaining a steep-walled diatreme in the water-saturated country rock sediments.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 425-
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 119-144.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 223-236.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 379-402.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 403-424.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 89-118.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 359-378.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 49-64.
Society of Economic Geology Geoscience and Exploration of the Argyle, Bunder, Diavik, and Murowa Diamond Deposits, Special Publication no. 20, pp. 237-252.
Contributions to Mineralogy and Petrology, Vol. 173, pp. 39-
Global
FTIR
Abstract: Platelets are one of the most common defects occurring in natural diamonds but their behaviour has not previously been well understood. Recent technical advances, and a much improved understanding of the correct interpretation of the main infrared (IR) feature associated with platelets (Speich et al. 2017), facilitated a systematic study of platelets in 40 natural diamonds. Three different types of platelet behaviour were identified here. Regular diamonds show linear correlations between both B-centre concentrations and platelet density and also between platelet size and platelet density. Irregular diamonds display reduced platelet density due to platelet breakdown, anomalously large or small platelets and a larger platelet size distribution. These features are indicative of high mantle storage temperatures. Finally, a previously unreported category of subregular diamonds is defined. These diamonds experienced low mantle residence temperatures and show smaller than expected platelets. Combining the systematic variation in platelet density with temperatures of mantle storage, determined by nitrogen aggregation, we can demonstrate that platelet degradation proceeds at a predictable rate. Thus, in platelet-bearing diamonds where N aggregation is complete, an estimate of annealing temperature can now be made for the first time.
Abstract: He-Ne-Ar compositions were determined in diamonds from the Argyle lamproite, Western Australia, to assess whether subducted material affects the noble gas budget and composition of stable old sub-continental lithospheric mantle (SCLM). Twenty diamonds (both peridotitic and eclogitic) were characterized for their carbon isotopic compositions and N abundance and aggregation from which 10 eclogitic growth zones and 5 peridotitic growth zones were analysed for their He-Ne-Ar compositions. The eclogitic diamonds have ?13C values of ?4.7 to ?16.6‰ indicating a subduction signature, whereas the peridotitic diamonds have mantle-like compositions of ?4.0 to ?7.8‰. Mantle residence temperatures based on N-in-diamond thermometry showed that the eclogitic diamonds were mainly formed at 1260-1270?°C or above 1300?°C near the base of the lithosphere, whereas the peridotitic diamonds generally formed at lower temperatures (mostly 1135-1230?°C). A noble gas subduction signature is present to various extents in the eclogitic diamonds and is inferred from a hyperbolic mixing relationship between R/Ra and 4He and ?13C values concentrations with a predominance of low R/Ra values (<0.5; R/Ra?=?3He/4Hesample/3He/4Heair). In addition, low 40Ar/4He and 40Ar/36Ar ratios, high nucleogenic 21Ne/4He and low 3He/22Ne ratios are characteristic of subducted material and were found in the eclogitic diamonds. The peridotitic diamonds show generally higher R/Ra values (median 1.1?±?1.1) and lower 4He/40Ar ratios compared to eclogitic diamonds (median 0.1?±?0.8 R/Ra; with 7/10 samples having an average of 0.13?±?0.14 R/Ra). The studied peridotitic diamond growth zones showed a negative correlation between R/Ra and 4He concentrations over 2 orders of magnitude and limited variation in 3He, that can be largely explained by radiogenic 4He ingrowth. At low 4He concentrations the R/Ra value is around 2.8 for both paragenesis of diamonds and is significantly lower than present-day SCLM values, suggesting (1) a more radiogenic helium isotope composition beneath the Halls Creek Orogen than those for typical SCLM from other cratons and/or (2) that the peridotitic diamonds are formed from fluids that also had a subduction input. The high mantle residence temperature and low R/Ra value in the core and low temperature and higher R/Ra value in the rim of a single peridotitic diamond indicate multiple growth events and that part of the lherzolitic diamond population may be genetically related to the eclogitic diamonds. Combining the diamond mantle residence temperatures with noble gas compositions shows that noble gas subduction signatures are present at the base of the lithosphere below 180?km depth beneath Argyle and that fluid migration and interaction with the SCLM occurred over scales of at least 15?km, between 180 and 165?km depth.
Abstract: Isotope compositions of basalts provide information about the chemical reservoirs in Earth’s interior and play a critical role in defining models of Earth’s structure. However, the helium isotope signature of the mantle below depths of a few hundred kilometers has been difficult to measure directly. This information is a vital baseline for understanding helium isotopes in erupted basalts. We measured He-Sr-Pb isotope ratios in superdeep diamond fluid inclusions from the transition zone (depth of 410 to 660 kilometers) unaffected by degassing and shallow crustal contamination. We found extreme He-C-Pb-Sr isotope variability, with high 3He/4He ratios related to higher helium concentrations. This indicates that a less degassed, high-3He/4He deep mantle source infiltrates the transition zone, where it interacts with recycled material, creating the diverse compositions recorded in ocean island basalts.
American Institute of Mining, Metallurgical, and Petroleum Engineers (AIME) Preprint, Annual Meeting held Phoenix Arizona Feb. 24-27th. 1992, Preprint No. 92-102, 4p
Antigorite peridotite, metaserpentinite, and other inclusions within diatremes on the Colorado Plateau, SW USA: implications for the mantle wedge during low angle
Lithos, doi.org/10.101016/j. lithos.2020.105460, 55p. Pdf
United States, Colorado
subduction
Abstract: The zonation of trace elements in Cr-pyrope has been analyzed to investigate histories recorded by garnet in cool mantle and implications for processes in the mantle wedge during low-angle subduction. The garnets are from the Navajo Volcanic Field (NVF) of the Colorado Plateau in the southwestern United States. Their host rocks were emplaced between 30 and 24 Ma, not long after low-angle subduction of the Farallon plate and the Laramide orogeny. Twenty-seven of the 31 garnets are discrete fragments from diatremes of serpentinized ultramafic microbreccia (SUM). Many Ni and Mn values in those grains yield temperatures in and below the range 800 °C to 600 °C, consistent with inclusions of chlorite and other hydrous minerals. Gradients of Na, Ti, Mn, Ni, Y, REE, and other elements are common in the discrete grains. Diffusion calculations constrain possible histories of a garnet with growth zonation of Y and REE and retrograde zonation of Mn and Ni. The garnet must have formed and resided at temperatures below about 900 °C, and that zonation is unlikely to have been preserved from the Proterozoic. The Mn gradient is consistent with cooling during the time period of low-angle Farallon subduction. Many of the discrete garnets grew from sources metasomatically enriched in Li, Na, Ti, and Zr, and they have distinctive high Li/Na. The high Li/Na is a likely consequence of Li metasomatism in the mantle wedge. Nb values in the Cr-pyrope fragments from northern SUM diatremes are lower than those of most garnets from kimberlites, but the low values are similar to and lower than those of pyrope in peridotite emplaced in orogenic belts; those northern diatremes also host lawsonite eclogite and garnetite. Most but not all relatively Cr-rich discrete garnets (4 to 8 wt% Cr2O3) record enrichment in LREE but little enrichment in Ti and Zr; LREE enrichment by an aqueous fluid is consistent with chlorite inclusions in two of these garnets. Oriented lamellae of rutile and other phases are common, and one texture may record fluid interactions associated with interface-coupled dissolution-reprecipitation. Garnets from the four minette-hosted peridotites record markedly hotter temperatures than do the SUM-hosted grains, and they lack the high Li/Na and low Nb. Gradients of trace elements in minette-hosted garnets record metasomatism shortly before crustal emplacement, but that metasomatism resulted in a decrease of Nb and had little effect on Li/Na. The minette-hosted garnet peridotites may represent mantle residual from Proterozoic accretion of the Colorado Plateau. In contrast, at least some of the SUM-hosted garnets probably grew in rock eroded from the forearc wedge by low-angle subduction and emplaced below the NVF.
Abstract: Mg2GeO4 is important as an analog for the ultrahigh-pressure behavior of Mg2SiO4, a major component of planetary interiors. In this study, we have investigated magnesium germanate to 275 GPa and over 2,000 K using a laser-heated diamond anvil cell combined with in situ synchrotron X-ray diffraction and density functional theory (DFT) computations. The experimental results are consistent with the formation of a phase with disordered Mg and Ge, in which germanium adopts eightfold coordination with oxygen: the cubic, Th3P4-type structure. DFT computations suggest partial Mg-Ge order, resulting in a tetragonal I4¯2d structure indistinguishable from I4¯3d Th3P4 in our experiments. If applicable to silicates, the formation of this highly coordinated and intrinsically disordered phase may have important implications for the interior mineralogy of large, rocky extrasolar planets.
A New Occurrence of Garnet-ultra basite in the Caledonides; A Chromium Rich Chromite Garnet Lherzolite from Tvaerdalen, Liverpool Land, East Greenland.
Terra Cognita., Vol. 1, No. 1, P. 74. (abstract.).
Perraki, M., Korsakov, A.V., Smith, D.C., Mposkos, E.
Raman spectroscopic and microscopic criteria for the distinction of microdiamonds in ultrahigh-pressure metamorphic rocks from diamonds in sample preparation materials.
Godard, G., Frizzotti, M-L., Palmeri, R., Smith, D.C.
Origin of high pressure disordered metastable phases ( Lonsdaleite and incipiently amorphized quartz) in metamorphic rocks: geodynamic shock or crystal-scale overpressure?
In: Ultrahigh Pressure Metamorphism: 25 years after discovery of coesite and diamond. Eds. Dobrzhinetskaya, L., Cuthbert, S., Faryad, W., Elsevier Publ. Pp. 125-148.
Computer assisted retrieval of gem localities and associated data
Geological Association of Canada (GAC)/Mineralogical Association of Canada (MAC)/SEG Annual Meeting May 27-29. Toronto, Ontario, Abstract, Vol. 16, p. A93. Abstract
Zhao, D., Smith, D.G.W. Smith, Zhou, M., Jang, J., Deng, C., Huang, Y.
Yinniugou lamproites in Datong, northern Shanxi Province, Chin a: first occurrence in the North Chin a craton.
Mid-continent diamonds Geological Association of Canada (GAC)-Mineralogical Association of Canada (MAC) Symposium ABSTRACT volume, held Edmonton May, pp. 133-140.
Nature Communications, doi.org/10.1038/s41467-019-11065-4 pdf 10p.
Mantle
subduction
Abstract: Ore deposits are loci on Earth where energy and mass flux are greatly enhanced and focussed, acting as magnifying lenses into metal transport, fractionation and concentration mechanisms through the lithosphere. Here we show that the metallogenic architecture of the lithosphere is illuminated by the geochemical signatures of metasomatised mantle rocks and post-subduction magmatic-hydrothermal mineral systems. Our data reveal that anomalously gold and tellurium rich magmatic sulfides in mantle-derived magmas emplaced in the lower crust share a common metallogenic signature with upper crustal porphyry-epithermal ore systems. We propose that a trans-lithospheric continuum exists whereby post-subduction magmas transporting metal-rich sulfide cargoes play a fundamental role in fluxing metals into the crust from metasomatised lithospheric mantle. Therefore, ore deposits are not merely associated with isolated zones where serendipitous happenstance has produced mineralisation. Rather, they are depositional points along the mantle-to-upper crust pathway of magmas and hydrothermal fluids, synthesising the concentrated metallogenic budget available.
Abstract: The Ashram Zone, which is host to the Ashram Rare Earth Element (REE) Deposit, occurs within the Eldor Carbonatite Complex, Québec, Canada. The complex is located within the Paleoproterozoic New Québec Orogen (Labrador Trough), and has been subjected to greenschist metamorphism and folding during the Hudsonian Orogeny at 1.75 Ga. To date, consanguineous undersaturated alkaline rocks have not been recognized within or adjacent to the complex. It is evident that the bulk compositions of the rocks, essentially magnesiocarbonatites and ferrocarbonatites, do not represent those of liquid compositions, as many are complex breccias which have been subjected to later hydrothermal activity. The Ashram Zone is dominated by diverse textural varieties of carbonatite which include: fluorite-rich schlieren carbonatites; coarse-to-medium grained granular carbonatites; fine grained, commonly mosaic-textured, quartz-bearing carbonatites; and colloform carbonatites. Compositional and textural data are provided for the minerals present in the carbonatites. The major rock-forming minerals are diverse Ca-Mg-Fe carbonates, fluorite, and quartz. The carbonates range in their compositional evolution from rare dolomite through ferrodolomite and magnesian siderite to siderite. The principal REE-bearing minerals of the Ashram Deposit are monazite-(Ce) and monazite-(Nd), with lesser amounts of bastnaesite-(Ce) and bastnaesite-(Nd). The minor and accessory mineral suite is characterized by the presence of apatite, phlogopite, xenotime, diverse Sc- and sn-bearing Nb-Ti-minerals (niobian rutile, nioboaeschynite, samarskite), barite, sphalerite, several uncommon, but here relatively abundant, Ba- and Ba-Be minerals (bafertisite, magbasite, barylite, betrandite, sanbornite, cebaite), yangzhumingite, cassiterite, galena, pyrite, and rare magnetite and potassium feldspar. Pyrochlore is absent and the Nb-Ti oxide assemblage is similar to that found in NYF-pegmatites associated with F-rich, A-type granitoids. The mineralogy of the Ashram Deposit, compared to that of other carbonatites associated with undersaturated silicate rocks is unique, especially with respect to the abundance of fluorite and monazite (commonly with Nd-enrichment), Ba-Be-enrichment, the NYF-type Nb-Ti oxide assemblage (especially xenotime, Y-Nb-aeschynite, samarskite), phlogopite-potassium feldspar quartz-rich residua with granitoid characteristics, paucity of magnetite, pyrochlore, and Sr-bearing carbonates. The Ashram Deposit is considered to be a late-magmatic-to-hydrothermal F-REE magnesio-to-ferrocarbonatite derived from as yet unknown consanguineous antecedents.
Abstract: Oceanic crust is created by the extraction of molten rock from underlying mantle at the seafloor ‘spreading centres’ found between diverging tectonic plates. Modelling studies have suggested that mantle melting can occur through decompression as the mantle flows upwards beneath spreading centres, but direct observation of this process is difficult beneath the oceans. Continental rifts, however—which are also associated with mantle melt production—are amenable to detailed measurements of their short-term kinematics using geodetic techniques. Here we show that such data can provide evidence for an upwelling mantle flow, as well as information on the dimensions and timescale of mantle melting. For North Island, New Zealand, around ten years of campaign and continuous GPS measurements in the continental rift system known as the Taupo volcanic zone reveal that it is extending at a rate of 6-15?millimetres per year. However, a roughly 70-kilometre-long segment of the rift axis is associated with strong horizontal contraction and rapid subsidence, and is flanked by regions of extension and uplift. These features fit a simple model that involves flexure of an elastic upper crust, which is pulled downwards or pushed upwards along the rift axis by a driving force located at a depth greater than 15?kilometres. We propose that flexure is caused by melt-induced episodic changes in the vertical flow forces that are generated by upwelling mantle beneath the rift axis, triggering a transient lower-crustal flow. A drop in the melt fraction owing to melt extraction raises the mantle flow viscosity and drives subsidence, whereas melt accumulation reduces viscosity and allows uplift—processes that are also likely to occur in oceanic spreading centres.
Abstract: Geological pathways for the recycling of Earth’s surface materials into the mantle are both driven and obscured by plate tectonics1,2,3. Gauging the extent of this recycling is difficult because subducted crustal components are often released at relatively shallow depths, below arc volcanoes4,5,6,7. The conspicuous existence of blue boron-bearing diamonds (type IIb)8,9 reveals that boron, an element abundant in the continental and oceanic crust, is present in certain diamond-forming fluids at mantle depths. However, both the provenance of the boron and the geological setting of diamond crystallization were unknown. Here we show that boron-bearing diamonds carry previously unrecognized mineral assemblages whose high-pressure precursors were stable in metamorphosed oceanic lithospheric slabs at depths reaching the lower mantle. We propose that some of the boron in seawater-serpentinized oceanic lithosphere is subducted into the deep mantle, where it is released with hydrous fluids that enable diamond growth10. Type IIb diamonds are thus among the deepest diamonds ever found and indicate a viable pathway for the deep-mantle recycling of crustal elements.
Abstract: Type IIb diamonds, those defined as having trace amounts of substitutional boron, are prized for their blue colors. The famous Hope diamond is a perfect example. Besides their boron content, these rare diamonds are also characterized by their general lack of nitrogen. Little is known about how type IIb diamonds form, but they are especially intriguing because boron is often regarded as a crustal element whose presence in mantle-derived diamonds is unexpected. Despite interest in type IIb diamonds as a potential geochemical tracer of mantle processes, minimal research progress has been made to date. They are simply so rare and their color so highly valued that sample access is problematic. Even when access to type IIb diamonds is granted, these diamonds are typically free of mineral or fluid inclusions that might illuminate their geological significance (e.g. Gaillou et al. 2012; King et al. 1998).
Abstract: Natural diamonds crystallize at great depths, far deeper than we can dig or drill into the Earth. So how is it that diamonds can be found among us? The answer lies in rare and unusual volcanoes called kimberlites. These deeply-seated volcanic eruptions can sometimes pick up diamonds, along with other minerals and rock fragments, and blast them to the top. Think of kimberlites as elevators that diamonds use to ride up to Earth’s surface! Tune in as GIA Research Scientist Dr. Evan Smith digs deeper into these super-charged volcanoes and uncovers the role they play, not just in transporting gem diamonds, but in revealing the geological workings of the Earth.
Abstract: Subducting tectonic plates carry water and other surficial components into Earth’s interior. Previous studies suggest that serpentinized peridotite is a key part of deep recycling, but this geochemical pathway has not been directly traced. Here, we report Fe-Ni-rich metallic inclusions in sublithospheric diamonds from a depth of 360 to 750 km with isotopically heavy iron (?56Fe = 0.79 to 0.90‰) and unradiogenic osmium (187Os/188Os = 0.111). These iron values lie outside the range of known mantle compositions or expected reaction products at depth. This signature represents subducted iron from magnetite and/or Fe-Ni alloys precipitated during serpentinization of oceanic peridotite, a lithology known to carry unradiogenic osmium inherited from prior convection and melt depletion. These diamond-hosted inclusions trace serpentinite subduction into the mantle transition zone. We propose that iron-rich phases from serpentinite contribute a labile heavy iron component to the heterogeneous convecting mantle eventually sampled by oceanic basalts.
Abstract: Do you know your diamond’s origin? Join GIA Research Scientist Dr. Evan Smith and GIA Global Business Development Director Matt Tratner as they explain why diamond origin is important in today's marketplace, some of the challenges that exist in identifying a diamond's country of origin, and how GIA uses the scientific matching process to confirm a diamond's origin.
In: Mantle Convection and Surface Expressions, Geophysical Monograph, editors Marquarte, H., Ballmer, M., Vottaar, S., Konter, J., no. 263, 14p. Pdf
Mantle
Super-deep diamonds
Abstract: Some rare diamonds originate below the lithosphere, from depths of 300-800 km and perhaps deeper. Ongoing sublithospheric or super-deep diamond research is providing new insight into the mantle and the hidden consequences of plate tectonics. Here we highlight several advances in the past decade, stemming from the discovery of inclusions from oceanic crust at lower mantle depths; inclusions having geochemical imprints of low-degree car-bonatitic melt, possibly from subducted slabs; hydrous ringwoodite and other signs of deep water; major mantle minerals preserved in their original crystal structure, including ringwoodite and CaSiO 3-perovskite; additional diamond varieties with a super-deep origin (CLIPPIR and type IIb diamonds), greatly increasing the known prevalence and diversity of super-deep diamonds; and consistent, recurring Fe-Ni-C-S metallic melt inclusions from depths of 360-750 km. Redox freezing of oxidized, slab-derived fluid/melt upon interaction with ambient metal-saturated mantle appears to be a phenomenon broadly recorded by many super-deep diamonds. Melting of car-bonate, as well as dehydration reactions, from subducted slabs are relevant mechanisms that may generate fluid/ melt contributing to diamond growth. Fe-Ni metal, with dissolved carbon, sulfur, and other elements is also indicated as a possible diamond-forming melt. These mobile and dynamic phases are agents of chemical mass-transfer in the deep mantle.
Abstract: Large, high-quality type IIa diamonds such as the Cullinan and the Koh-i-Noor are among the most elusive of mined gem diamonds. These are called CLIPPIR diamonds, an acronym reflecting the distinguishing physical characteristics of this variety of diamonds (Cullinan-like, Large, Inclusion Poor, Pure, Irregular, Resorbed) [1]. There is currently no reliable method to predict the occurrence of CLIPPIR diamonds in a deposit, which remains a hurdle for exploration and mining [2]. Mineral inclusions reveal that these are sublithospheric diamonds [1], which explains why their occurrence is effectively independent from more common eclogitic and peridotitic lithospheric diamonds and their associated indicator minerals. More recently, an analysis of iron isotopes in the metallic inclusions sometimes found in CLIPPIR diamonds has provided additional insight into their formation, which may provide clues for exploration. Three measurements of metallic Fe-Ni-C-S inclusions from two diamonds from the Letseng mine, Lesotho reveal remarkably heavy iron isotopic compositions, ?56Fe = 0.79-0.90‰ [3]. These measurements lie far outside the range of known mantle compositions (near 0‰) or expected reaction products at depth. Instead, the heavy signature is ascribed to subducted iron sourced from magnetite and/or Fe-Ni alloys precipitated during seafloor serpentinization of oceanic peridotite. These metallic inclusions provide physical evidence that traces serpentinite subduction into the mantle transition zone. This finding is a step toward a genetic model for CLIPPIR diamonds. Their formation requires input from deeply subducted serpentinized peridotite. Furthermore, this input may come specifically from cold subducting slabs, whose serpentinized mantle portions can bypass the shallow sub-arc dehydration activity and instead transport serpentinite-derived components such as hydrous minerals and iron-rich phases to the transition zone/uppermost lower mantle [4]. The results suggest that geochemical signatures related to deeply subducted serpentinites may eventually provide a basis for targeting CLIPPIR diamonds in volcanic deposits at surface.
A sublithospheric mantle, metallic liquid origin for the world's largest gem-quality diamonds.
GSA Annual Meeting, Abstract, 1p.
Technology
Type II diamonds
Abstract: Many of the world’s largest and most valuable diamonds (e.g. Cullinan, Lesedi La Rona, Star of Sierra Leone, Lesotho Promise, Koh-i-Noor) have an unusual set of physical characteristics, suggesting they may form by a unique and common mechanism. The most often noted characteristic is their nitrogen-deficient character, classifying them as Type II. In addition, these large diamonds are generally inclusion poor, irregularly shaped, and highly resorbed. The famous 3106 carat Cullinan diamond, discovered in 1905, is a prime example. These Cullinan-like Type II diamonds are especially valuable as gemstones and difficult to access for research. Furthermore, they very rarely contain any inclusions that might shed light on their geological origin. For these reasons the paragenesis of such diamonds has long remained so enigmatic that they have not been connected to the processes that form more common Type I diamonds or even any other Type II diamonds. Here we report the findings of a systematic search for inclusions among thousands of high-quality Type II diamonds, both polished gemstones and offcuts. Not only was the search successful in finding inclusions in 70 diamonds, it also revealed a recurring set of inclusions that are distinct from those of more familiar lithospheric/sublithospheric diamonds. The most abundant inclusion encountered was a metallic, Fe-Ni-C-S multi-phase assemblage, which was observed in 35 diamonds. The second most abundant inclusion type is former CaSiO3 perovskite, now retrogressed to lower-pressure minerals. The CaSiO3 phases constrain the depth of formation to deeper than 300 km. Two additional Cullinan-like Type IIa diamonds were found to have inclusions of low-Cr majoritic garnet, also indicative of a sublithospheric origin. Overall, the inclusions suggest that Cullinan-like, large, high-quality diamonds belong to a unique paragenesis with an intimate link to Fe-Ni metal in the deep mantle.
Geochemistry, Geophysics, Geosystems: G3, Vol. 16, 2, pp. 366-379.
United States, Colorado Plateau
Convection
Abstract: Although volcanism in the southwestern United States has been studied extensively, its origin remains controversial. Various mechanisms such as mantle plumes, upwelling in response to slab sinking, and small-scale convective processes have been proposed, but have not been evaluated within the context of rapidly shearing asthenosphere that is thought to underlie this region. Using geodynamic models that include this shear, we here explore spatiotemporal patterns of mantle melting and volcanism near the Colorado Plateau. We show that the presence of viscosity heterogeneity within an environment of asthenospheric shearing can give rise to decompression melting along the margins of the Colorado Plateau. Our models indicate that eastward shear flow can advect pockets of anomalously low viscosity toward the edges of thickened lithosphere beneath the plateau, where they can induce decompression melting in two ways. First, the arrival of the pockets critically changes the effective viscosity near the plateau to trigger small-scale edge-driven convection. Second, they can excite shear-driven upwelling (SDU), in which horizontal shear flow becomes redirected upward as it is focused within the low-viscosity pocket. We find that a combination of “triggered” edge-driven convection and SDU can explain volcanism along the margins of the Colorado Plateau, its encroachment toward the plateau's southwestern edge, and the association of volcanism with slow seismic anomalies in the asthenosphere. Geographic patterns of intraplate volcanism in regions of vigorous asthenospheric shearing may thus directly mirror viscosity heterogeneity of the sublithospheric mantle.
Abstract: Many of the world’s largest and most valuable diamonds (e.g. Cullinan, Lesedi La Rona, Star of Sierra Leone, Lesotho Promise, Koh-i-Noor) have an unusual set of physical characteristics, suggesting they may form by a unique and common mechanism. The most often noted characteristic is their nitrogen-deficient character, classifying them as Type II. In addition, these large diamonds are generally inclusion poor, irregularly shaped, and highly resorbed. The famous 3106 carat Cullinan diamond, discovered in 1905, is a prime example. These Cullinan-like Type II diamonds are especially valuable as gemstones and difficult to access for research. Furthermore, they very rarely contain any inclusions that might shed light on their geological origin. For these reasons the paragenesis of such diamonds has long remained so enigmatic that they have not been connected to the processes that form more common Type I diamonds or even any other Type II diamonds. Here we report the findings of a systematic search for inclusions among thousands of high-quality Type II diamonds, both polished gemstones and offcuts. Not only was the search successful in finding inclusions in 70 diamonds, it also revealed a recurring set of inclusions that are distinct from those of more familiar lithospheric/sublithospheric diamonds. The most abundant inclusion encountered was a metallic, Fe-Ni-C-S multi-phase assemblage, which was observed in 35 diamonds. The second most abundant inclusion type is former CaSiO3 perovskite, now retrogressed to lower-pressure minerals. The CaSiO3 phases constrain the depth of formation to deeper than 300 km. Two additional Cullinan-like Type IIa diamonds were found to have inclusions of low-Cr majoritic garnet, also indicative of a sublithospheric origin. Overall, the inclusions suggest that Cullinan-like, large, high-quality diamonds belong to a unique paragenesis with an intimate link to Fe-Ni metal in the deep mantle.
Abstract: The redox state of Earth’s convecting mantle, masked by the lithospheric plates and basaltic magmatism of plate tectonics, is a key unknown in the evolutionary history of our planet. Here we report that large, exceptional gem diamonds like the Cullinan, Constellation, and Koh-i-Noor carry direct evidence of crystallization from a redox-sensitive metallic liquid phase in the deep mantle. These sublithospheric diamonds contain inclusions of solidified iron-nickel-carbon-sulfur melt, accompanied by a thin fluid layer of methane ± hydrogen, and sometimes majoritic garnet or former calcium silicate perovskite. The metal-dominated mineral assemblages and reduced volatiles in large gem diamonds indicate formation under metal-saturated conditions. We verify previous predictions that Earth has highly reducing deep mantle regions capable of precipitating a metallic iron phase that contains dissolved carbon and hydrogen.
Abstract: “Super-deep” diamonds are thought to have a sub-lithospheric origin (i.e., below ~300 km depth) because some of the mineral phases entrapped within them as inclusions are considered to be the products of retrograde transformation from lower-mantle or transition-zone precursors. CaSiO3-walstromite, the most abundant Ca-bearing mineral inclusion found in super-deep diamonds, is believed to derive from CaSiO3-perovskite, which is stable only below ~600 km depth, although its real depth of origin is controversial. The remnant pressure (Pinc) retained by an inclusion, combined with the thermoelastic parameters of the mineral inclusion and the diamond host, allows calculation of the entrapment pressure of the diamond-inclusion pair. Raman spectroscopy, together with X-ray diffraction, is the most commonly used method for measuring the Pinc without damaging the diamond host. In the present study we provide, for the first time, a calibration curve to determine the Pinc of a CaSiO3-walstromite inclusion by means of Raman spectroscopy without breaking the diamond. To do so, we performed high-pressure micro-Raman investigations on a CaSiO3-walstromite crystal under hydrostatic stress conditions within a diamond-anvil cell. We additionally calculated the Raman spectrum of CaSiO3-walstromite by ab initio methods both under hydrostatic and non-hydrostatic stress conditions to avoid misinterpretation of the results caused by the possible presence of deviatoric stresses causing anomalous shift of CaSiO3-walstromite Raman peaks. Last, we applied single-inclusion elastic barometry to estimate the minimum entrapment pressure of a CaSiO3-walstromite inclusion trapped in a natural diamond, which is ~9 GPa (~260 km) at 1800 K. These results suggest that the diamond investigated is certainly sub-lithospheric and endorse the hypothesis that the presence of CaSiO3-walstromite is a strong indication of super-deep origin.
Abstract: Large and relatively pure diamonds like the historic 3,106 ct Cullinan, found in South Africa in 1905, have long been regarded as unusual based on their physical characteristics. For example, they often exhibit exceptional color and clarity, while routinely qualifying as type IIa, a rare designation of chemical purity. A new research discovery about these Cullinan-like diamonds is that they contain heretofore unknown, deeply derived inclusions that originate below the continental mantle keel and are thus known as "superdeep" diamonds (Smith et al., 2016). Originating from a depth between 360 and 750 km, they reveal information about the conditions within the convecting mantle, beneath the earth’s rigid tectonic plates. Here we review the previously published findings, compare the Cullinan-like diamonds to the more abundant lithospheric diamond population, and offer evidence from some additional diamond samples that further verifies their superdeep origin. Cullinan-like diamonds contain minute and rare silicate and iron-rich metallic inclusions surrounded by a fluid jacket composed of methane and hydrogen. The inclusion compositions suggest that this deep mantle environment contains small pockets of oxygen-deficient metallic liquid out of which the diamonds crystallized. This new and unexpected observation made on the world’s most expensive diamonds is important for understanding the chemical reactions between mineral assemblages in the deep earth. It shows that deep regions of the mantle contain metallic iron, as opposed to the shallower, more oxidized mantle rocks actively participating in plate tectonics and its associated volcanism.
Abstract: Facets that are nearly parallel to a diamond’s octahedral crystal plane often develop a wavy, rippled appearance called "lizard skin" during polishing (e.g., J.I. Koivula, The MicroWorld of Diamonds, Gemworld International, Northbrook, Illinois, 2000, p. 63). The term is also used more broadly to describe any bumpy, uneven surface texture that develops on polished diamond facets. It is often attributed to polishing off-grain. Recently, GIA’s New York lab encountered a 2.67 ct type IIa diamond (figure 1, left) with especially prominent lizard skin texture on multiple facets (figure 1, center and right). In this case, the texture appears to have developed due to a preexisting deformation fabric or structure inherent to the diamond itself, rather than merely as a consequence of poor polishing technique.
Abstract: Type IIb diamonds, such as the Hope diamond, contain trace amounts of boron and are prized for their blue colors. Since boron is a quintessential crustal element, it is completely unexpected in diamond-forming fluids at mantle depths. Despite the mineralogical/geochemical interest in type IIb diamonds, almost nothing is known about how they form chiefly because of their rarity (?0.02% of all diamonds) and high gem value. To investigate the type of mantle host rock, the depth of origin (lithospheric vs. convecting mantle), and the source of boron, the high-volume diamond grading stream of the Gemological Institute of America was systematically screened to find type IIb diamonds with inclusions. Over a period of about two years, 46 prospective samples were identified and examined optical microscopy, X-ray diffraction, and infrared/Raman spectroscopy; a few diamonds were also analyzed for carbon isotopic composition and polished for electron probe microanalysis of inclusions. The examined inclusions represent retrogressed highpressure minerals, from metabasic to metaperidotitic hosts in the lowermost mantle transition zone (MTZ) to lower mantle (LM). These include former CaSiO3-perovskite, majorite, bridgmanite, stishovite, calcium-ferrite-type phase, and ferropericlase. The variably light carbon isotope compositions and inclusion mineralogy indicate diamond growth in deeply subducted oceanic lithosphere (crust and mantle). Some inclusions are found to have coexisting fluid (CH4 ± H2) that suggests the original high-pressure minerals interacted with hydrous media. We propose that the boron resided in serpentinized oceanic lithosphere. During subduction, the serpentine was metamorphosed to dense hydrous magnesium silicates (DHMS) that retained some boron. Upon breakdown in the MTZ/LM, these DHMS yielded boron-bearing hydrous fluids conducive to diamond growth.
Gems & Gemology, Sixth International Gemological Symposium Vol. 54, 3, 1p. Abstract p. 274.
Africa, South Africa, Angola
deposit - Cullinan, Lulo
Abstract: Many of the world’s largest and most valuable gem diamonds exhibit an unusual set of physical characteristics. For example, in addition to their conspicuously low nitrogen concentrations, diamonds such as the 3,106 ct Cullinan (type IIa) and the Hope (type IIb, boron bearing) tend to have very few or no inclusions, and in their rough state they are found as irregular shapes rather than as sharp octahedral crystals. It has long been suspected that type IIa and IIb diamonds form in a different way than most other diamonds. Over the past two years, systematic investigation of both type IIa and IIb diamonds at GIA has revealed that they sometimes contain rare inclusions from unique geological origins. Examination of more than 130 inclusion-bearing samples has established recurring sets of inclusions that clearly show many of these diamonds originate in the sublithospheric mantle, much deeper in the earth than more common diamonds from the cratonic lithosphere. We now recognize that type IIa diamonds, or more specifically, diamonds with characteristics akin to the historic Cullinan diamond (dubbed CLIPPIR diamonds), are distinguished by the occurrence of ironrich metallic inclusions. Less frequently, CLIPPIR diamonds also contain inclusions of majoritic garnet and former CaSiO3perovskite that constrain the depth of formation to within 360–750 km. The inclusions suggest that CLIPPIR diamonds belong to a unique paragenesis with an intimate link to metallic iron in the deep mantle (Smith et al., 2016, 2017). Similarly, findings from type IIb diamonds also place them in a “superdeep” sublithospheric mantle setting, with inclusions of former CaSiO3 perovskite and other high-pressure minerals, although the iron-rich metallic inclusions are generally absent (Smith et al., 2018). Altogether, these findings show that high-quality type II gem diamonds are predominantly sourced from the sublithospheric mantle, a surprising result that has refuted the notion that all superdeep diamonds are small and nongem quality. Valuable information about the composition and behavior of the deep mantle is cryptically recorded in these diamonds. CLIPPIR diamonds (figure 1) confirm that the deep mantle contains metallic iron, while type IIb diamonds suggest that boron and perhaps water can be carried from the earth’s surface down into the lower mantle by plate tectonic processes. In addition to being gemstones of great beauty, diamonds carry tremendous scientific value in their unique ability to convey information about the interior of our planet.
Abstract: In the past few years, two new diamond varieties have been characterized as sublithospheric, or super-deep, in origin. Ongoing studies of new inclusion-bearing specimens continue to improve our understanding of type IIa (more specifically, CLIPPIR) and type IIb diamonds. CLIPPIR diamonds are a variety epitomized by large and high quality type IIa gem diamonds, such as the 3106 carat Cullinan diamond [1]. Among their inclusions are examples of majoritic garnet and inferred CaSiO3-perovskite, suggesting a formation depth in the range of 360 to 750 km [1, 2]. Type IIb diamonds (boron-bearing) host inclusions of ferropericlase as well as retrogressed majoritic garnet, CaSiO3-perovskite, CF-type phase, stishovite, and bridgmanite [3]. The mineral assemblage suggests an origin deeper than 360 km, likely in the transition zone to uppermost lower mantle. The relationship between these two similar diamond varieties remains somewhat unclear. Studies to date have left open the possibility that CLIPPIR diamonds might be formed at distinctly shallower depths than type IIb’s, without any overlap. An additional large (>100 carats) rough CLIPPIR diamond has now been examined that contains inclusions of retrogressed aluminous bridgmanite. This is the first evidence of CLIPPIR diamond growth in the lower mantle, meaning there must be some overlap between the depth of formation for CLIPPIR and type IIb diamonds. A related issue concerning depth of formation, for type IIb diamonds [4], has also been addressed by examination of a new specimen. A large (>10 ct) type IIb diamond has been found to contain former bridgmanite, which helps to dissolve the apparent dichotomy between inclusions in larger (>2ct) and smaller (<2ct) type IIb diamonds [4, 5]. These recently examined specimens are helping to build a clearer picture of the paragenesis and geochemical implciations of these exquisite gem diamonds.
Abstract: Crowningshieldite is the natural analog of the synthetic compound ?-NiS. It has a NiAs-type structure and is the high-temperature polymorph relative to millerite (?-NiS), with an inversion temperature of 379 °C. Crowningshieldite is hexagonal, space group P63/mmc, with a = 3.44(1) Å, c = 5.36(1) Å, V = 55.0(2) Å3, and Z = 2. It has an empirical formula (Ni0.90Fe0.10)S and dcalc = 5.47(1) g/cm3. The five strongest lines in the powder X-ray diffraction data are [dmeas in angstroms (I) (hkl)]: 1.992 (100) (102), 1.718 (55) (110), 2.978 (53) (100), 2.608 (35) (101), and 1.304 (17) (202). Crowningshieldite was found as part of a multiphase inclusion in a gem-quality, colorless, type IIa (containing less than ~5 ppm N) diamond from the Letseng mine, Lesotho. The inclusion contains crowningshieldite along with magnetite-magnesioferrite, hematite, and graphite. A fracture was observed that extended from the inclusion to the diamond exterior, meaning that fluids, possibly kimberlite-related, could have penetrated into this fracture and altered the inclusion. Originally, the inclusion might have been a more reduced, metallic Fe-Ni-C-S mixture made up of cohenite, Fe-Ni alloy, and pyrrhotite, akin to the other fracture-free, pristine inclusions within the same diamond. Such metallic Fe-Ni-C-S primary inclusions are a notable recurring feature of similar type IIa diamonds from Letseng and elsewhere that have been shown to originate from the sublithospheric mantle. The discovery of crowningshieldite confirms that the ?-NiS polymorph occurs in nature. In this case, the reason for its preservation is unclear, but the relatively iron-rich composition [Fe/(Fe+Ni) = 0.1] or the confining pressure of the diamond host are potential factors impeding its transformation to millerite. The new mineral name honors G. Robert Crowningshield (1919-2006) (IMA2018-072).
Mantle Convection and Surface Expressions, Geophysical Monograph, No. 263, Chapter 7, pp. 179- 14p. Pdf
Mantle
inclusions, subduction, CLIPPER
Abstract: Some rare diamonds originate below the lithosphere, from depths of 300-800 km and perhaps deeper. Ongoing sublithospheric or super-deep diamond research is providing new insight into the mantle and the hidden consequences of plate tectonics. Here we highlight several advances in the past decade, stemming from the discovery of inclusions from oceanic crust at lower mantle depths; inclusions having geochemical imprints of low-degree car-bonatitic melt, possibly from subducted slabs; hydrous ringwoodite and other signs of deep water; major mantle minerals preserved in their original crystal structure, including ringwoodite and CaSiO 3-perovskite; additional diamond varieties with a super-deep origin (CLIPPIR and type IIb diamonds), greatly increasing the known prevalence and diversity of super-deep diamonds; and consistent, recurring Fe-Ni-C-S metallic melt inclusions from depths of 360-750 km. Redox freezing of oxidized, slab-derived fluid/melt upon interaction with ambient metal-saturated mantle appears to be a phenomenon broadly recorded by many super-deep diamonds. Melting of car-bonate, as well as dehydration reactions, from subducted slabs are relevant mechanisms that may generate fluid/ melt contributing to diamond growth. Fe-Ni metal, with dissolved carbon, sulfur, and other elements is also indicated as a possible diamond-forming melt. These mobile and dynamic phases are agents of chemical mass-transfer in the deep mantle.
Relative Abundance, Compositions and P-t Histories of Ultramafic Xenoliths, Green Knobs, New Mexico and Implications For the Mantle Below the Colorado Plateau.
Geological Society of America (GSA), Vol.7, No. 7, P. 1275.
Cr- Rich Spinel and Garnet in Two Peridotite Xenoliths From the Frank Smith Mine South Africa: Significance of Al and Chromium Distribution between Spinel and Garnet.
Metasomatised and veined upper mantle xenoliths from Pello Hill, Tanzania: evidence for anomalously light mantle beneath the Tanzanian sectorof the East African
Mineralogy and Petrology, Vol. 100, No. 4, pp. 510-527
The Diavik waste rock project: geochemical and microbiological characterization of drainage from low sulfide waste rock: active zone field experiments.
Abstract: Two experimental waste-rock piles (test piles), each 15 m in height × 60 m × 50 m, were constructed at the Diavik diamond mine in Northern Canada to study the behavior of low-sulfide content waste rock, with a similarly low acid-neutralization potential, in a continuous permafrost region. One test pile with an average of 0.035 wt.% S (<50 mm fraction; referred to as Type I) and a second test pile with an average of 0.053 wt.% S (<50 mm fraction; referred to as Type III) were constructed in 2006. The average carbon content in the <50 mm fraction of waste rock in the Type I test pile was 0.031 wt.% as C and in the Type III test pile was 0.030 wt.% as C. The NP:AP ratio, based on the arithmetic mean of particle-size weighted NP and AP values, for the Type I test pile was 12.2, suggesting this test pile was non-acid generating and for the Type III test pile was 2.2, suggesting an uncertain acid-generating potential. The Type I test pile maintained near-neutral pH for the 4-year duration of the study. Sulfate and dissolved metal concentrations were low, with the exception of Ni, Zn, Cd, and Co in the fourth year following construction. The pore water in the Type III test pile contained higher concentrations of SO42? and dissolved metals, with a decrease in pH to <4.7 and an annual depletion of alkalinity. Maximum concentrations of dissolved metals (20 mg L?1 Ni, 2.3 mg L?1 Cu, 3.7 mg L?1 Zn, 35 ?g L?1 Cd, and 3.8 mg L?1 Co) corresponded to decreases in flow rate, which were observed at the end of each field season when the contribution of the total outflow from the central portion of the test pile was greatest. Bacteria were present each year in spite of annual freeze/thaw cycles. The microbial community within the Type I test pile included a population of neutrophilic S-oxidizing bacteria. Each year, changes in the water quality of the Type III test-pile effluent were accompanied by changes in the microbial populations. Populations of acidophilic S-oxidizing bacteria and Fe-oxidizing bacteria became more abundant as the pH decreased and internal test pile temperatures increased. Irrespective of the cold-climate conditions and low S content of the waste rock, the geochemical and microbiological results of this study are consistent with other acid mine drainage studies; indicating that a series of mineral dissolution-precipitation reactions controls pH and metal mobility, and transport is controlled by matrix-dominated flow and internal temperatures.
Abstract: Two experimental waste-rock piles (test piles), each 15 m in height × 60 m × 50 m, were constructed at the Diavik diamond mine in Northern Canada to study the behavior of low-sulfide content waste rock, with a similarly low acid-neutralization potential, in a continuous permafrost region. One test pile with an average of 0.035 wt.% S (<50 mm fraction; referred to as Type I) and a second test pile with an average of 0.053 wt.% S (<50 mm fraction; referred to as Type III) were constructed in 2006. The average carbon content in the <50 mm fraction of waste rock in the Type I test pile was 0.031 wt.% as C and in the Type III test pile was 0.030 wt.% as C. The NP:AP ratio, based on the arithmetic mean of particle-size weighted NP and AP values, for the Type I test pile was 12.2, suggesting this test pile was non-acid generating and for the Type III test pile was 2.2, suggesting an uncertain acid-generating potential. The Type I test pile maintained near-neutral pH for the 4-year duration of the study. Sulfate and dissolved metal concentrations were low, with the exception of Ni, Zn, Cd, and Co in the fourth year following construction. The pore water in the Type III test pile contained higher concentrations of SO42? and dissolved metals, with a decrease in pH to <4.7 and an annual depletion of alkalinity. Maximum concentrations of dissolved metals (20 mg L?1 Ni, 2.3 mg L?1 Cu, 3.7 mg L?1 Zn, 35 ?g L?1 Cd, and 3.8 mg L?1 Co) corresponded to decreases in flow rate, which were observed at the end of each field season when the contribution of the total outflow from the central portion of the test pile was greatest. Bacteria were present each year in spite of annual freeze/thaw cycles. The microbial community within the Type I test pile included a population of neutrophilic S-oxidizing bacteria. Each year, changes in the water quality of the Type III test-pile effluent were accompanied by changes in the microbial populations. Populations of acidophilic S-oxidizing bacteria and Fe-oxidizing bacteria became more abundant as the pH decreased and internal test pile temperatures increased. Irrespective of the cold-climate conditions and low S content of the waste rock, the geochemical and microbiological results of this study are consistent with other acid mine drainage studies; indicating that a series of mineral dissolution-precipitation reactions controls pH and metal mobility, and transport is controlled by matrix-dominated flow and internal temperatures.
Abstract: The Diavik Waste Rock Project consists of laboratory and field experiments developed for the investigation and scale-up of the geochemical evolution of sulfidic mine wastes. As part of this project, humidity cell experiments were conducted to assess the long-term geochemical evolution of a low-sulfide waste rock. Reactive transport modelling was used to assess the significant geochemical processes controlling oxidation of sulfide minerals and their dependence on temperature and sulfide mineral content. The geochemical evolution of effluent from waste rock with a sulfide content of 0.16 wt.% and 0.02 wt.% in humidity cells was simulated with the reactive transport model MIN3P, based on a conceptual model that included constant water flow, sulfide mineral content, sulfide oxidation controlled by the availability of oxidants, and subsequent neutralization reactions with carbonate and aluminosilicate minerals. Concentrations of Ni, Co, Cu, Zn, and SO4 in the humidity cell effluent were simulated using the shrinking core model, which represented the control of oxidant diffusion to the unreacted particle surface in the sulfide oxidation process. The influence of temperature was accounted for using the Arrhenius relation and appropriate activation energy values. Comparison of the experiment results, consisting of waste rock differentiated by sulfide mineral content and temperature, indicated surface area and temperature play important roles in rates of sulfide oxidation and release of sulfate and metals. After the model was calibrated to fit the effluent data from the higher sulfide content cells, subsequent simulations were conducted by adjusting only measured parameters, including sulfide mineral content and surface area.
Abstract: The Diavik Waste Rock Project, located in a region of continuous permafrost in northern Canada, includes complementary field and laboratory experiments with the purpose of investigating scale-up techniques for the assessment of the geochemical evolution of mine waste rock at a large scale. As part of the Diavik project, medium-scale field experiments (?1.5?m high active zone lysimeters) were conducted to assess the long term geochemical evolution and drainage of a low-sulfide waste rock under a relatively simple (i.e. constrained by the container) flow regime while exposed to atmospheric conditions. A conceptual model, including the most significant processes controlling the sulfide-mineral oxidation and weathering of the associated host minerals as observed in a laboratory humidity cell experiment, was developed as part of a previous modelling study. The current study investigated the efficacy of scaling the calibrated humidity cell model to simulate the geochemical evolution of the active zone lysimeter experiments. The humidity cell model was used to simulate the geochemical evolution of low-sulfide waste rock with S content of 0.053?wt.% and 0.035?wt.% (primarily pyrrhotite) in the active zone lysimeter experiments using the reactive transport code MIN3P. Water flow through the lysimeters was simulated using temporally variable infiltration estimated from precipitation measurements made within 200?m of the lysimeters. Flow parameters and physical properties determined during previous studies at Diavik were incorporated into the simulations to reproduce the flow regime. The geochemical evolution of the waste-rock system was simulated by adjustment of the sulfide-mineral content to reflect the values measured at the lysimeters. The temperature dependence of the geochemical system was considered using temperature measurements taken daily, adjacent to the lysimeters, to correct weathering rates according to the Arrhenius equation. The lysimeter simulations indicated that a model developed from simulations of laboratory humidity cell experiments, incorporating detailed representations of temporally variable temperature and water infiltration, can be scaled to provide a reasonable assessment of geochemical evolution of the medium-scale field experiments.
Abstract: The geochemical evolution of mine-waste rock often includes concurrent acid generation and neutralization processes. Deposition of mine-waste rock in large, oxygenated, and partially saturated piles can result in release of metals and decreased pH from weathering of sulfide minerals. Acid neutralization processes can often mitigate metals and pH impacts associated with sulfide oxidation. The Diavik Waste Rock Project included large field experiments (test piles built in 2006) conducted to characterize weathering of sulfide waste rock at a scale representative of full size waste-rock piles. Water samples from the unsaturated interior of one of the test piles, constructed of waste rock with ~0.05 wt.% S, were collected using soil water solution samplers and drains at the base of the pile. Field observations indicated pH decreased throughout the depth of the pile during 2008 and 2009 and that carbonate mineral buffering was entirely depleted by 2011 or 2012. Carbonate mineral exhaustion was accompanied by increased concentrations of dissolved Al and Fe in effluent samples collected at the basal drains. These results suggest that dissolution of Al and Fe(oxy)hydroxides occurred after the depletion of carbonate minerals following an acid neutralization sequence that is similar to observations made by previous researchers. A conceptual model of acid neutralization proceses within the pile, developed using physical and geochemical measurements conducted from 2008 to 2012, was used to inform reactive transport simulations conducted in 2017 to quantify the dominant acid neutralization processes within the test pile interior. Reactive transport simulations indicate that the conceptual model developed using the results of field samples provides a reasonable assessment of the evolution of the acid neutralization sequence.
Environmental Science and Technology, Vol. 49, 13, pp. 7589-7596.
Canada, Northwest Territories
Deposit - Diavik
Abstract: Mining-related perchlorate [ClO4(-)] in the receiving environment was investigated at the operating open-pit and underground Diavik diamond mine, Northwest Territories, Canada. Samples were collected over four years and ClO4(-) was measured in various mine waters, the 560 km(2) ultraoligotrophic receiving lake, background lake water and snow distal from the mine. Groundwaters from the underground mine had variable ClO4(-) concentrations, up to 157 ?g L(-1), and were typically an order of magnitude higher than concentrations in combined mine waters prior to treatment and discharge to the lake. Snow core samples had a mean ClO4(-) concentration of 0.021 ?g L(-1) (n=16). Snow and lake water Cl(-)/ClO4(-) ratios suggest evapoconcentration was not an important process affecting lake ClO4(-) concentrations. The multiyear mean ClO4(-) concentrations in the lake were 0.30 ?g L(-1) (n = 114) in open water and 0.24 ?g L(-1) (n = 107) under ice, much below the Canadian drinking water guideline of 6 ?g L(-1). Receiving lake concentrations of ClO4(-) generally decreased year over year and ClO4(-) was not likely [biogeo]chemically attenuated within the receiving lake. The discharge of treated mine water was shown to contribute mining-related ClO4(-) to the lake and the low concentrations after 12 years of mining were attributed to the large volume of the receiving lake.
Abstract: The silico?carbonatite dykes of the Huanglongpu area, Lesser Qinling, China, are unusual in that they are quartz-bearing, Mo-mineralised and enriched in the heavy rare earth elements (HREE) relative to typical carbonatites. The textures of REE minerals indicate crystallisation of monazite-(Ce), bastnäsite-(Ce), parisite-(Ce) and aeschynite-(Ce) as magmatic phases. Burbankite was also potentially an early crystallising phase. Monazite-(Ce) was subsequently altered to produce a second generation of apatite, which was in turn replaced and overgrown by britholite-(Ce), accompanied by the formation of allanite-(Ce). Bastnäsite and parisite where replaced by synchysite-(Ce) and röntgenite-(Ce). Aeschynite-(Ce) was altered to uranopyrochlore and then pyrochlore with uraninite inclusions. The mineralogical evolution reflects the evolution from magmatic carbonatite, to more silica-rich conditions during early hydrothermal processes, to fully hydrothermal conditions accompanied by the formation of sulphate minerals. Each alteration stage resulted in the preferential leaching of the LREE and enrichment in the HREE. Mass balance considerations indicate hydrothermal fluids must have contributed HREE to the mineralisation. The evolution of the fluorcarbonate mineral assemblage requires an increase in aCa2+ and aCO32? in the metasomatic fluid (where a is activity), and breakdown of HREE-enriched calcite may have been the HREE source. Leaching in the presence of strong, LREE-selective ligands (Cl?) may account for the depletion in late stage minerals in the LREE, but cannot account for subsequent preferential HREE addition. Fluid inclusion data indicate the presence of sulphate-rich brines during alteration, and hence sulphate complexation may have been important for preferential HREE transport. Alongside HREE-enriched magmatic sources, and enrichment during magmatic processes, late stage alteration with non-LREE-selective ligands may be critical in forming HREE-enriched carbonatites.
Reacyion relationships in the Bayan Obo rare earth elements (REE) niobium deposit, Inner Mongolia: implications for stability rare earth elements (REE)
Contributions to Mineralogy and Petrology, Vol. 134, No. 2-3, pp. 294-310.
China, Mongolia
Carbonates, phosphates, rare earths, Deposit - Bayan Obo
Abstract: The unique, giant, rare earth element (REE) deposit at Bayan Obo, northern China, is the world’s largest REE deposit. It is geologically complex, and its genesis is still debated. Here, we report in situ Th-Pb dating and Nd isotope ratios for monazite and Sr isotope ratios for dolomite and apatite from fresh drill cores. The measured monazite ages (361-913 Ma) and previously reported whole-rock Sm-Nd data show a linear relationship with the initial Nd isotope ratio, suggesting a single-stage evolution from a Sm-Nd source that was formed before 913 Ma. All monazites show consistent ?Nd(1.3Ga) values (0.3 ± 0.6) close to those of the adjacent 1.3 Ga carbonatite and mafic dikes. The primary dolomite and apatite show lower 87Sr/86Sr ratios (0.7024-0.7030) than the recrystallized dolomite (0.7038-0.7097). The REE ores at Bayan Obo are interpreted to have originally formed as products of ca. 1.3 Ga carbonatitic magmatism and to have undergone subsequent thermal perturbations induced by Sr-rich, but REE-poor, metamorphic fluids derived from nearby sedimentary rocks.
Abstract: Sulfur-bearing monazite-(Ce) occurs in silicified carbonatite at Eureka, Namibia, forming rims up to ~0.5 mm thick on earlier-formed monazite-(Ce) megacrysts. We present X-ray photoelectron spectroscopy data demonstrating that sulfur is accommodated predominantly in monazite-(Ce) as sulfate, via a clino-anhydrite-type coupled substitution mechanism. Minor sulfide and sulfite peaks in the X-ray photoelectron spectra, however, also indicate that more complex substitution mechanisms incorporating S2 and S4+ are possible. Incorporation of S6+ through clino-anhydrite-type substitution results in an excess of M2+ cations, which previous workers have suggested is accommodated by auxiliary substitution of OH for O2. However, Raman data show no indication of OH, and instead we suggest charge imbalance is accommodated through F substituting for O2. The accommodation of S in the monazite-(Ce) results in considerable structural distortion that may account for relatively high contents of ions with radii beyond those normally found in monazite-(Ce), such as the heavy rare earth elements, Mo, Zr and V. In contrast to S-bearing monazite-(Ce) in other carbonatites, S-bearing monazite-(Ce) at Eureka formed via a dissolutionprecipitation mechanism during prolonged weathering, with S derived from an aeolian source. While large S-bearing monazite-(Ce) grains are likely to be rare in the geological record, formation of secondary S-bearing monazite-(Ce) in these conditions may be a feasible mineral for dating palaeo-weathering horizons.
The Great Gold Lands of South Africa. a Vacation in the Cape Colony, Natal, the Orange Free State and the Transvaal. Visiting the Diamond Fields and the Goldfields.
Abstract: Limited field studies and sparse chronological constraints in the southwestern Great Slave Lake area creates uncertainties about the Laurentide Ice Sheet (LIS) flow history and deglacial chronology. Improved understanding of the western LIS ice-margin morphology and retreat history is required to refine larger ice-sheet interpretations and timing for northwest drainage of glacial Lake McConnell. Using new field observations and geochronology we establish ice-flow history and better constrain regional deglaciation. Paleo-ice flow indicators (n = 66) show an oldest southwestern flow (230°), an intermediate northwesterly flow (305°), and a youngest westerly flow (250°). Till samples bulk sediment and matrix properties (n = 160) allowed identification of two till units. A lower grey till sourced mainly from local Paleozoic sediments produced clast fabrics indicating a southwesterly flow direction, overlain by a brown till that contained an increased Canadian Shield content with lodged elongate boulders a-axes and boulder-top striation orientations indicating a west to northwest ice-flow direction. Ice-flow results show a clockwise shift in direction interpreted as evidence for ice-divide migration followed by topographically controlled deglacial westward flow influenced by the Mackenzie River valley. Minimum deglacial timing estimates were constrained through optical dating of fine-sand deposits in a well-developed strandline (n = 2) and seven aeolian dunes; ages range from 9.9 ± 0.6 to 10.8 ± 0.7 ka BP. These ages are from dunes located below glacial Lake McConnell maximum water level and may thus provide new local lake level age constraints. Ice retreat is informed by a newly-mapped segment of the Snake River moraine, which is an understudied feature in the region. New ice-flow history and ice-margin retreat interpretations will be integrated into the larger body of work on the western LIS providing more confident conclusions on ice-sheet evolution and meltwater drainage pathways, specifically in the southwestern Great Slave Lake area.
Abstract: Fieldwork conducted since 2010 by the Geological Survey of Canada under the GEM programs has revealed a more complex glacial history of the southern Great Slave Lake region of the Northwest Territories than was previously reported. New reconstructions of the Laurentide Ice Sheet paleo-ice flow history have been established from field observations of erosional and/or depositional ice-flow indicators (e.g. striae, bedrock grooves, till clast fabrics, and streamlined landforms), new geochronological constraints, and interpretations of glacial stratigraphy. Three distinct ice-flow phases are consistently observed in areas proximal to the western margin of the Canadian Shield between the Slave River near Fort Smith and Hay River further west. These phases are: 1) an oldest southwest flow; 2) a long-term sustained ice flow to the northwest; and, 3) a youngest west-southwest flow during Late Wisconsin deglaciation, which includes extensions of the Great Slave Lake and Hay River ice streams further east than previous mapped. At Hay River approaching the eastern limit of soft Cretaceous bedrock of the Western Canada Sedimentary Basin, the ice flow pattern no longer shows the aforementioned consistent chronology. From Hay River to the Liard River, near the zone where the Laurentide and Cordilleran ice sheet coalesced, a thinning ice profile, topographic highlands such as the Cameron Hills and Horn Plateau, and the deep basin that Great Slave Lake currently occupies, played a significant role on the dynamics of the Laurentide Ice Sheet during early ice advance, retreat during Marine Isotope Stage 3, Late Wisconsin advance and deglaciation. Other factors, such as increased sediment supply and clay content from Cretaceous shale bedrock were also significant in influencing ice-sheet behaviour. The role of elevated porewater pressures over subglacial clay-rich sediments controlled the extent and dynamics of several discordant ice streams in upland and lowland regions within the study area.
Nano Letters, doi.10.1021/acs/ nanolett.Oc0556 10p. Pdf
Global
nanodiamond
Abstract: The search for new nanostructural topologies composed of elemental carbon is driven by technological opportunities as well as the need to understand the structure and evolution of carbon materials formed by planetary shock impact events and in laboratory syntheses. We describe two new families of diamond-graphene (diaphite) phases constructed from layered and bonded sp3 and sp2 nanostructural units and provide a framework for classifying the members of this new class of materials. The nanocomposite structures are identified within both natural impact diamonds and laboratory-shocked samples and possess diffraction features that have previously been assigned to lonsdaleite and postgraphite phases. The diaphite nanocomposites represent a new class of high-performance carbon materials that are predicted to combine the superhard qualities of diamond with high fracture toughness and ductility enabled by the graphitic units and the atomically defined interfaces between the sp3- and sp2-bonded nanodomains.
Nature Scientific Reports, doi.org/10.1038/ s41598-019-46556-3 8p. Pdf
Global
diamond morphology, impact craters
Abstract: Diamond is a material of immense technological importance and an ancient signifier for wealth and societal status. In geology, diamond forms as part of the deep carbon cycle and typically displays a highly ordered cubic crystal structure. Impact diamonds, however, often exhibit structural disorder in the form of complex combinations of cubic and hexagonal stacking motifs. The structural characterization of such diamonds remains a challenge. Here, impact diamonds from the Popigai crater were characterized with a range of techniques. Using the MCDIFFaX approach for analysing X-ray diffraction data, hexagonality indices up to 40% were found. The effects of increasing amounts of hexagonal stacking on the Raman spectra of diamond were investigated computationally and found to be in excellent agreement with trends in the experimental spectra. Electron microscopy revealed nanoscale twinning within the cubic diamond structure. Our analyses lead us to propose a systematic protocol for assigning specific hexagonality attributes to the mineral designated as lonsdaleite among natural and synthetic samples.
Abstract: Diamond is a material of immense technological importance and an ancient signifier for wealth and societal status. In geology, diamond forms as part of the deep carbon cycle and typically displays a highly ordered cubic crystal structure. Impact diamonds, however, often exhibit structural disorder in the form of complex combinations of cubic and hexagonal stacking motifs. The structural characterization of such diamonds remains a challenge. Here, impact diamonds from the Popigai crater were characterized with a range of techniques. Using the MCDIFFaX approach for analysing X-ray diffraction data, hexagonality indices up to 40% were found. The effects of increasing amounts of hexagonal stacking on the Raman spectra of diamond were investigated computationally and found to be in excellent agreement with trends in the experimental spectra. Electron microscopy revealed nanoscale twinning within the cubic diamond structure. Our analyses lead us to propose a systematic protocol for assigning specific hexagonality attributes to the mineral designated as lonsdaleite among natural and synthetic samples.
Origins of bimodal leucogranite-lamprophyre suites, Climax and Red Mountain porphyry molydenum systems, Colorado: petrologic and strontium isotopicevidence
Colorado School of Mines Quarterly, Vol. 83, No. 2, Summer pp. 1-24
Abstract: Earth’s oldest evolved (felsic) rocks, the 4.02-billion-year-old Idiwhaa gneisses of the Acasta Gneiss Complex, northwest Canada, have compositions that are distinct from the felsic rocks that typify Earth’s ancient continental nuclei, implying that they formed through a different process. Using phase equilibria and trace element modelling, we show that the Idiwhaa gneisses were produced by partial melting of iron-rich hydrated basaltic rocks (amphibolites) at very low pressures, equating to the uppermost ~3?km of a Hadean crust that was dominantly mafic in composition. The heat required for partial melting at such shallow levels is most easily explained through meteorite impacts. Hydrodynamic impact modelling shows not only that this scenario is physically plausible, but also that the region of shallow partial melting appropriate to formation of the Idiwhaa gneisses would have been widespread. Given the predicted high flux of meteorites in the late Hadean, impact melting may have been the predominant mechanism that generated Hadean felsic rocks.
Earth and planetary Science Letters, Vol. 579, 117343, 11p. Pdf
Australia
geophysics- seismics
Abstract: Plate tectonics, including rifting, subduction, and collision processes, was likely to have been different in the past due to the secular cooling of the Earth. The northeastern part of the West Australian Craton (WAC) has a complex Archean and Paleoproterozoic tectonic history; therefore, it provides an opportunity to study how subduction and collision processes evolved during the emergence of plate tectonics, particularly regarding the assembly of Earth's first supercontinent, Columbia. Because the northeastern boundary of the WAC and the southwestern boundary of the North Australian Craton (NAC) are covered by the Phanerozoic Canning Basin, the regional tectonic evolution has remained enigmatic, including how many tectonic elements were assembled and what may have driven rifting and subsequent collision events. Here, we use new passive-source seismic modeling to identify a seismically distinct segment of the lithosphere, the Percival Lakes Province, which lies east of the Pilbara Craton and is separated by two previously unknown southeast-trending lithosphere scale Paleoproterozoic sutures. We interpret that the northeastern suture, separates the Percival Lakes Province from the NAC, records the amalgamation of the WAC with the NAC. The southwestern suture separates the PLP from the reworked northeastern margin of the Pilbara Craton, including the East Pilbara Terrane and the Rudall Province. A significant upper mantle dipping structure was identified in the southwestern suture, and we interpret it to be a relic of subduction that records a previously unknown Paleoproterozoic collision that pre-dated the amalgamation of the WAC and NAC. By comparing our findings with previously documented dipping features, we show that the Paleoproterozoic collisions are seismically distinguishable from their Phanerozoic counterparts.
Abstract: The geodynamic environment in which Earth’s first continents formed and were stabilized remains controversial1. Most exposed continental crust that can be dated back to the Archaean eon (4 billion to 2.5 billion years ago) comprises tonalite-trondhjemite-granodiorite rocks (TTGs) that were formed through partial melting of hydrated low-magnesium basaltic rocks2; notably, these TTGs have ‘arc-like’ signatures of trace elements and thus resemble the continental crust produced in modern subduction settings3. In the East Pilbara Terrane, Western Australia, low-magnesium basalts of the Coucal Formation at the base of the Pilbara Supergroup have trace-element compositions that are consistent with these being source rocks for TTGs. These basalts may be the remnants of a thick (more than 35?kilometres thick), ancient (more than 3.5 billion years old) basaltic crust4, 5 that is predicted to have existed if Archaean mantle temperatures were much hotter than today’s6, 7, 8. Here, using phase equilibria modelling of the Coucal basalts, we confirm their suitability as TTG ‘parents’, and suggest that TTGs were produced by around 20 per cent to 30 per cent melting of the Coucal basalts along high geothermal gradients (of more than 700 degrees Celsius per gigapascal). We also analyse the trace-element composition of the Coucal basalts, and propose that these rocks were themselves derived from an earlier generation of high-magnesium basaltic rocks, suggesting that the arc-like signature in Archaean TTGs was inherited from an ancestral source lineage. This protracted, multistage process for the production and stabilization of the first continents—coupled with the high geothermal gradients—is incompatible with modern-style plate tectonics, and favours instead the formation of TTGs near the base of thick, plateau-like basaltic crust9. Thus subduction was not required to produce TTGs in the early Archaean eon.
Abstract: Earth’s oldest felsic rocks, the 4.02 billion-year-old Idiwhaa gneisses of the Acasta Gneiss Complex, northwest Canada, have compositions that are distinct from the felsic rocks that typify Earth’s ancient continental nuclei, implying they formed through a different process. Using phase equilibria and trace element modelling, we show that the Idiwhaa gneisses were produced by partial melting of ironrich amphibolite host rocks at very low pressures, equating to the uppermost ~3 km of mafic crust. The heat required for such shallow melting is most easily explained through meteorite impacts. Hydrodynamic impact modelling shows that, not only is this scenario physically plausible, but the region of shallow melting appropriate to formation of the Idiwhaa gneisses would have been widespread. Given the predicted high flux of meteorites during the late Hadean, impact melting may have been the predominant mechanism that generated Hadean felsic rocks.
Earth and Planetary Science Letters, Vol. 505, pp. 65-75.
Mantle
geothermometry
Abstract: It is estimated that around three quarters of Earth's first generation continental crust had been produced by the end of the Archaean Eon, 2.5 billion years ago. This ancient continental crust is mostly composed of variably deformed and metamorphosed magmatic rocks of the tonalite-trondhjemite-granodiorite (TTG) suite that formed by partial melting of hydrated mafic rocks. However, the geodynamic regime under which TTG magmas formed is a matter of ongoing debate. Using a filtered global geochemical dataset of 563 samples with ages ranging from the Eoarchaean to Neoarchaean (4.0-2.5 Ga), we interrogate the bulk rock major oxide and trace element composition of TTGs to assess evidence for secular change. Despite a high degree of scatter in the data, the concentrations or ratios of several key major oxides and trace elements show statistically significant trends that indicate maxima, minima and/or transitions in the interval 3.3-3.0 Ga. Importantly, a change point analysis of K2O/Na2O, Sr/Y and LaN/YbN demonstrates a statistically significant (>99% confidence) change during this 300 Ma period. These shifts may be linked to a fundamental change in geodynamic regime around the peak in upper mantle temperatures from one dominated by non-uniformitarian, deformable stagnant lid processes to another dominated by the emergence of global mobile lid or plate tectonic processes by the end of the Archaean. A notable change is also evident at 2.8-2.7 Ga that coincides with a major jump in the rate of survival of metamorphic rocks with contrasting thermal gradients, which may relate to the emergence of more potassic continental arc magmas and an increased preservation potential during collisional orogenesis. In many cases, the chemical composition of TTGs shows an increasing spread through the Archaean, reflecting the irreversible differentiation of the lithosphere.
Abstract: Much of the present-day volume of Earth’s continental crust had formed by the end of the Archean Eon, 2.5 billion years ago, through the conversion of basaltic (mafic) crust into sodic granite of tonalite, trondhjemite and granodiorite (TTG) composition. Distinctive chemical signatures in a small proportion of these rocks, the so-called high-pressure TTG, are interpreted to indicate partial melting of hydrated crust at pressures above 1.5?GPa (>50?km depth), pressures typically not reached in post-Archean continental crust. These interpretations significantly influence views on early crustal evolution and the onset of plate tectonics. Here we show that high-pressure TTG did not form through melting of crust, but through fractionation of melts derived from metasomatically enriched lithospheric mantle. Although the remaining, and dominant, group of Archean TTG did form through melting of hydrated mafic crust, there is no evidence that this occurred at depths significantly greater than the ~40?km average thickness of modern continental crust.
Abstract: A large compilation of quality-curated major and trace element data has been assembled to investigate how trace element patterns of mafic and ultramafic magmas have varied with time through particular settings from the Archean to the Phanerozoic, the primary objective being to recognise at what times particular patterns of variation emerge, and how similar these are to baseline data sets representing tectonic settings in the modern Earth. The most informative element combinations involve Nb, Th and the REE, where REE are represented by ‘lambda’ parameters describing slope and shape of patterns. Combinations of the ratios of Th, Nb, La and lambda values from Archean and early Proterozoic basalts and komatiites reveal a distinctive pattern that is common in most well-sampled terranes, defining a roughly linear trend in multi-dimensional space from compositions intermediate between modern n-MORB and primitive mantle at one end, towards compositions approximating middle-to-upper continental crust at the other. We ascribe this ‘Variable Th/Nb’ trend in most instances to varying degrees of crustal contamination of magmas with similar compositions to modern oceanic plateau basalts. Komatiites had slightly more depleted sources than basalts, consistent with the hypothesis of derivation from plume tails and heads, respectively. The most significant difference between Precambrian and Phanerozoic plume-derived basalts is that the distinctive OIB-like enriched source component appears to be largely missing from the Archean and Proterozoic geologic record, although isolated examples of OIB-like trace element characteristics are evident in datasets from even the oldest preserved greenstones. Phanerozoic intra-cratonic LIPs, such as the 260?Ma Emeishan LIP in China, have fundamentally different geochemical characteristics to Archean and Paleoproterozoic assemblages; the oldest Proterozoic LIP we have identified that has this type of ‘modern’ signal is the Midcontinent Rift at 1100?Ma. The data are consistent with plume tail sources having changed from being dominantly depleted in the Archean Earth to dominantly enriched in the Phanerozoic Earth, while plume head sources have hardly changed at all. Trace element patterns considered to be diagnostic of subduction are locally present but rare in Archean terranes and become more prevalent through the Proterozoic, although this conclusion is tempered by the large degree of overlap in compositional space between continental arc magmas and continental flood basalts. This overlap reflects the difficulty of distinguishing the effects of supra-subduction metasomatizm and flux melting from those of crustal contamination. Additional factors must also be borne in mind, particularly that trace element partitioning systematics may have been different in all environments in a hotter planet, and large-scale asthenospheric overturns might have been predominant over modern-style plumes in the Archean Earth. Some basaltic suites in particular Archean terranes, notably the western parts of both the Yilgarn and Pilbara cratons in Western Australia and parts of the Superior Craton, have restricted, but locally predominant, suites of basalts with characteristics akin to modern oceanic arcs, suggesting that some process similar to modern subduction was preserved in these particular belts. Ferropicrite magmas with distinctive characteristics typical of modern OIBs and some continental LIPs (notably Emeishan) are rare but locally predominant in some Archean and early Proterozoic terranes, implying that plume sources were beginning to be fertilised by enriched, probably subducted, components as far back as the Mesoarchean. We see no evidence for discontinuous secular changes in mantle-derived magmatism with time that could be ascribed to major mantle reorganisation events. The Archean-Proterozoic transition appears to be entirely gradational from this standpoint. The transition from Archean-style to Phanerozoic-style plume magmatism took place somewhere between 1900?Ma (age of the Circum-Superior komatiitic basalt suites) and 1100?Ma (the age of the Midcontinent Rift LIP).
Earth and planetary Science Letters, Vol. 578, 117319, 9p. Pdf
Mantle
geochronolgy
Abstract: The formation of stable buoyant continental crust during the Archaean Eon was fundamental in establishing the planet's geochemical reservoirs. However, the processes that created Earth's first continents and the timescales over which they formed are debated. Here, we report the Pb isotope compositions of K-feldspar grains from 52 Paleoarchaean to Neoarchaean granites from the Pilbara Craton in Western Australia, one of the world's oldest and best-preserved granite-greenstone terranes. The Pb isotope composition of the Pilbara K-feldspars is variable, implying the granites were derived from crustal precursors of different age and/or variable time-integrated 238U/204Pb and 232Th/204Pb compositions. Trends to sub-mantle 207Pb/206Pb ratios preclude the influence of 4.3 Ga crustal precursors. In order to estimate crustal residence times we derive equations to calculate source model ages in a linearized Pb isotope evolution system. The best agreement between the feldspar Pb two-stage source model ages and those derived from zircon initial Hf isotope compositions requires crustal precursors that separated from a chondritic mantle source between 3.2 and 3.8 Ga, and rapidly differentiated to continental crust with 238U/204Pb and 232Th/238U ratios of ?14 and 4.2-4.5, respectively. The preservation of Pb isotope variability in the Pilbara Paleoarchaean granites indicates their early continental source rocks were preserved for up to 500 Ma after their formation. The apparent longevity of these early continental nuclei is consistent with the incipient development of buoyant melt-depleted cratonic lithosphere during the Eoarchaean to Paleoarchaean.
De Wit, M., Bhebhe, Z., Davidson, J., Haggerty, S.E., Hundt, P., Jacob, J., Lynn, M., Marshall, T.R., Skinner, C., Smithson, K., Stiefenhofer, J., Robert, M., Revitt, A., Spaggiari, R., Ward, J.
Abstract: From the discovery of diamonds in South Africa in 1866 until the end of 2013, Africa is estimated to have produced almost 3.2 Bct out of a total global production of 5.03 Bct, or 63.6% of all diamonds that have ever been mined. In 2013 African countries ranked 2nd (Botswana), 3rd (DRC), 6th (Zimbabwe), 7th (Angola), 8th (South Africa), and 9th (Namibia), in terms of carat production and 1st (Botswana), 4th (Namibia), 5th (Angola), 6th (South Africa), 7th (Zimbabwe), and 9th (DRC), in terms of value of the diamonds produced. In 2013 Africa produced 70.6 Mct out of a global total of 130.5 Mct or 54.1%, which was valued at US$ 8.7 billion representing 61.5% of the global value of US$ 14.1 billion.
Abstract: The Man Craton region of West Africa has a rich history of diamonds since they were first discovered in the 1930’s.They are primarily alluvial in source with currently only one kimberlite mine in operation at Koidu in Sierra Leone. The total diamond production from Guinea, Liberia and Sierra Leone over the past 10 years is recorded by the Kimberley Process at around 12.2 million carats with a value of $1.9 billion. The two main producing countries during this period are Guinea, which has yielded 6.7 million carats at an average of $52 per carat, and Sierra Leone where production has reached 5 million carats at a higher value of $277 per carat. Liberia is the smallest producer with 0.4 million carats but these have a high average value of $383 per carat. There are two known age provenances of kimberlites in the Man Craton. The larger, Jurassic age provenance comprises six main clusters of small (generally 10 ha) kimberlite pipes and dykes ranging from the older Bounoudou kimberlites in Guinea, at 153 Ma, through to the younger Tongo kimberlites in Sierra Leone dated at 140 Ma. A single, neo-Proterozoic cluster is known in the Weasua area in Liberia and is dated at 800 Ma. The Jurassic age kimberlites are classified as phlogopite-rich kimberlites with abundant groundmass opaque minerals. The older Weasua kimberlites typically contain less phlogopite and groundmass opaque minerals. Although remnants of diatreme facies are present in some pipes, notably the Banankoro, Koidu and Weasua kimberlites, hypabyssal and transitional facies tend to predominate which would indicate that these kimberlites have been eroded down to the interface between the root and diatreme zones. This suggests potential erosion of up to 2 km over the Man Craton; however geomorphological evidence suggests a lesser amount of erosion has taken place (Skinner et al., 2004). Alluvial diamonds are prevalent throughout the Man Craton and are not restricted to the known kimberlite clusters. This would argue for a wide dispersion of diamonds in the alluvial system as a result of significant landmass uplift and weathering since the time of intrusion. It could also indicate that there are diamondiferous kimberlites yet to be discovered, which is supported by the limited exploration data. It is therefore concluded that there are certain areas of the Man Craton which remain highly prospective for diamondiferous kimberlites.
Abstract: Scientists provide new evidence that modern plate tectonics, a defining feature of Earth and its unique ability to support life, emerged roughly 3.6 billion years ago. The study uses zircons, the oldest minerals ever found on Earth, to peer back into the planet's ancient past.
Abstract: Comprehensive research of ore-bearing differentiated intrusions of the Keulik-Kenirim structural unit, which represents a fragment of the Paleoproterozoic Pechenga-Varzuga Belt, has been carried out for the first time. The intrusions are subvolcanic by type and lenticular in shape, nearly conformable and steeply dipping. They are made up of peridotite, olivine and plagioclase pyroxenites, and gabbro metamorphosed under amphibolite facies conditions along with host basic volcanics. All intrusive rocks are enriched in TiO2 and FeO. Sulfide Cu-Ni mineralization is represented by disseminated, pocket, and stringer-disseminated types, which are clustered in the peridotitic zone as hanging units and bottom lodes. The Ni content in disseminated ore is estimated at 0.45-0.55 wt % and 1.15-3.32 wt % in ore pockets; the Cu grades are 0.17-0.20 and 0.46-5.65 wt %, respectively. To determine the age of intrusions and metamorphism of intrusive and volcanic rocks, various isotopic systems have been used: Sm-Nd (TIMS) in rock and U-Pb (SIMS SHRIMP) and Lu-Hf (LA-ICP-MS) in zircon. Conclusions on the origin of zircons are based on concentrations of trace elements including REE therein and Hf-Nd correlation in zircons and rocks. The U-Pb system of zircons reflects episodes of igneous rock formation (1982 ± 12 Ma) and their postmagmatic transformation (1938 ± 20 Ma). The last disturbance of the U-Pb isotopic system occurred 700 and 425 Ma. Xenogenic zircons dated from 3.17 to 2.65 Ga have been revealed in the studied samples. These zircons were captured by magma from the Archean basement during its ascent. The intrusions were emplaced synchronously with economic ore formation in the Pechenga ore field (1985 ± 10 Ma). The peak metamorphism of intrusive rocks under amphibolite facies conditions is recorded at 40 Ma later. The differentiated intrusions of the Keulik-Kenirim structural unit are close in their internal structure, mineralogy, and geochemistry, as well as in age and features of related Cu-Ni mineralization to ore-bearing intrusions of the Pechenga ore field, which are derivatives of ferropicritic (ferriferous) magmatism.
Lithos, doi 10.1016/j.lithos.2019.105215, 75p. Pdf
Europe, Spain
deposit - Ronda
Abstract: We present a detailed study of the water geochemistry, mineralogy and textures in serpentinization-related hyperalkaline springs in the Ronda peridotites. Ronda waters can be classified into hyperalkaline fluids and river waters that are broadly similar to Ca2+-OH- and Mg2+-HCO3- water types described in serpentinite-hosted alkaline springs elsewhere. At the discharge sites of the fluids (fractures or human made outlets) and ponds along the fluid flow paths, the fluids are hyperalkaline (10.9 < pH < 12) and characterized by low Mg and high Na, K, Ca, and Cl concentrations. River waters, occurring near the spring sites, are mildly alkaline (8.5 < pH < 8.9) and enriched in Mg and DIC compared to Na, K, Ca and Cl. The chemistry of Ronda Mg-HCO3 river waters is likely due to the hydrolysis of ferromagnesian peridotite minerals in equilibrium with the atmosphere by infiltrated meteoric water and shallow groundwater in the serpentinized peridotite. The Ronda Ca-OH hyperalkaline fluids are generated by the combination of low temperature serpentinization reactions from infiltrated surface Mg-HCO3 river waters —or Ca-HCO3 waters from near karst aquifers— and deep carbonate precipitation isolated from atmospheric CO2. Mass balance calculations indicate that the weathering of Ca-bearing peridotite silicates such as diopside is a feasible source of Ca in Ronda Ca-OH hyperalkaline fluids; however, it requires steady-state dissolution rates substantially greater than those determined experimentally. Travertine, crystalline crusts and sediment deposits are the main types of solid precipitates observed in Ronda hyperalkaline spring sites. Calcite and aragonite, minor dolomite and Mg-Al-rich clays are the main minerals in the spring sites. As illustrated in the Baños del Puerto spring site, (i) calcite-dominated precipitation is due to hyperalkaline fluid uptake of atmospheric CO2 during discharge, and (ii) aragonite-dominated precipitation is due to mixing of Ca-OH hyperalkaline fluids with Mg- HCO3 river waters. Aragonite and dolomite contents increase away from the springs and toward the river waters that uniquely reflects the effect of Mg ions on the precipitation of aragonite versus calcite. Other potential factors controlling the precipitation of these CaCO3 polymorphs are the Mg/Ca ratio, the CO2 content, and the temperature of the fluids. Dolomite forms during lithification of travertine due to periodic flooding of river water combined with subsequent evaporation.
Earth and Planetary Science Letters, Vol. 471, pp. 65-73.
Mantle
geochemistry, water cycle
Abstract: Subduction of hydrous and carbonated oceanic lithosphere replenishes the mantle volatile inventory. Substantial uncertainties exist on the magnitudes of the recycled volatile fluxes and it is unclear whether Earth surface reservoirs are undergoing net-loss or net-gain of H2O and CO2. Here, we use noble gases as tracers for deep volatile cycling. Specifically, we construct and apply a kinetic model to estimate the effect of subduction zone metamorphism on the elemental composition of noble gases in amphibole - a common constituent of altered oceanic crust. We show that progressive dehydration of the slab leads to the extraction of noble gases, linking noble gas recycling to H2O. Noble gases are strongly fractionated within hot subduction zones, whereas minimal fractionation occurs along colder subduction geotherms. In the context of our modelling, this implies that the mantle heavy noble gas inventory is dominated by the injection of noble gases through cold subduction zones. For cold subduction zones, we estimate a present-day bulk recycling efficiency, past the depth of amphibole breakdown, of 5-35% and 60-80% for 36Ar and H2O bound within oceanic crust, respectively. Given that hotter subduction dominates over geologic history, this result highlights the importance of cooler subduction zones in regassing the mantle and in affecting the modern volatile budget of Earth's interior.
Abstract: Simultaneous acquisition of detrital zircon Pb-Pb ages and trace element abundances from grains collected across the Indian craton, spanning ?3 b.y., reveals prominent shifts in Eu/Eu* and light and middle to heavy rare earth element ratios. These shifts correspond to a ca. 3.0-2.2 Ga interval of crustal thickening during Indian craton formation, followed by a period wherein arc magmatism occurred along thinner craton margins from ca. 1.9 to 1.0 Ga, with arc magmatism concentrated along attenuated continental margins after ca. 1.0 Ga. Similar temporal shifts in trace element concentrations are recognized in global whole-rock compilations. We propose that the post-1.0 Ga increase in juvenile magmatism reflects a switch to lateral arc terrane accretion as the primary style of continental growth over the past billion years.
Abstract: The Pikoo kimberlites of east-central Saskatchewan are a relatively recent discovery, comprising at least ten discreet bodies thought to erupt through the Sask Craton, a small Archean microcontinent enclosed within the Paleoproterozoic Trans-Hudson Orogen. Since the Sask Craton also plays host to the 70+ bodies of the diamondiferous Cretaceous Fort à la Corne kimberlites, which are among the largest kimberlites in the world, significant interest lay in unraveling the genesis of the Pikoo bodies. This study presents the first detailed examination of the petrology and geochronology of the Pikoo kimberlites. A combination of detailed petrography, major and minor element chemistry analyzed by EPMA, and trace element determinations measured via LA-ICP-MS was employed to characterize the Pikoo samples as archetypal coherent (hypabyssal) kimberlite. Traditional criteria for diamond preservation potential were applied to the Pikoo ilmenite by assessing their Fe2O3 and MgO contents. The results indicated high MgO and low Fe2O3 within the grain interiors and rims with elevated MgO and MnO in PK150, PK151, PK314, and variably in PK312. The high-Fe mineral compositions of PK346 contradict the trends of the other intrusions, suggesting PK346 formed from an oxidized, high-carbonate late pulse of previously fractionated magma. The differences in magma evolution can explain the striking petrographic and chemical distinctions highlighted between the two most significant intrusions of PK150 and PK346, as well as the notably less favourable microdiamond results North Arrow reported for PK346. A robust U-Pb age of 417 ± 14 Ma was determined from PK150 perovskite analyzed in situ via LA-ICP-MS. The data were processed using two approaches to confirm the perovskite represented a single population with a uniform common Pb composition. This age is distinctly different from the nearby FALC kimberlites but overlaps with occurrences in the Slave Craton, the United States, Russia, and Namibia. This may suggest more widespread diamond-bearing kimberlite activity in circa Silurian times. Tracer isotopes were also measured in situ via LA-MC-ICP-MS on PK150 perovskite. The dominant range in ?Ndi (+1.8 to -2.0) is near chondritic, suggesting a deep mantle source isolated from contamination.
International Geology Review, Vol. 58, 3, pp. 263-276.
Mantle
Diamond genesis
Abstract: Earth is a water planet, but how much water exists on and in the Earth? Is the water limited to the Earth’s surface and limited depths of our planet (molecular water of the hydrosphere), or do deep reservoirs of hydrogen and oxygen really exist as proposed in recent works but not yet proven? Due to the importance of H2O for life and geological processes on the Earth, these questions are among the most significant in all of the Earth sciences. Water must be present in the deep Earth as plate tectonics could not work without water as a major driving force that lowers both viscosity and density of the solid mineral phases of the interior and controls the onset of melting. On subduction, water is returned to the hydrosphere first by dewatering of hydrous phases and second by melting and arc magmatism in and above the subducting slab. The mantle is composed of oxygen minerals, and the extent to which hydrogen is dissolved in them constitutes the true reservoir of the planet’s water. Are ‘deep water and diamonds’ intimately related as indicated in the title of the present article? What is the connection between these two important terrestrial materials? The necessity to review this issue arises from the recent discovery of a strongly hydrous ringwoodite in a Brazilian diamond. As ringwoodite constitutes 60% or more of the lower part of the transition zone, between 525 and 660 km depth, this could correspond to a huge amount of water in this region, comparable or greater in mass to all of Earth’s hydrosphere. If the water found in this ringwoodite is representative of the water concentrations of the transition zone, then estimates of Earth’s total water reservoir are in need of major revision. This work is an attempt at such a revision.
Journal of Geophysical Research,, Vol. 120, 12, pp. 8259-8280.
Mantle
Ringwoodite
Abstract: Review of recent mineral physics literature shows consistent trends for the influence of Fe and H2O on the bulk modulus (K0) of wadsleyite and ringwoodite, the major phases of Earth's mantle transition zone (410-660?km). However, there is little consensus on the first pressure derivative, K0??=?(dK/dP)P=0, which ranges from about 4 to >5 across experimental studies and compositions. Here we demonstrate the importance of K0? in evaluating the bulk sound velocity of the transition zone in terms of water content and provide new constraints on the effect of H2O on K0? for wadsleyite and ringwoodite by conducting a comparative compressibility study. In the experiment, multiple crystals of hydrous Fo90 wadsleyite containing 2.0 and 0.25?wt?% H2O were loaded into the same diamond anvil cell, along with hydrous ringwoodite containing 1.4?wt?% H2O. By measuring their pressure-volume evolution simultaneously up to 32?GPa, we constrain the difference in K0? independent of the pressure scale, finding that H2O has no effect on K0?, whereas the effect of H2O on K0 is significant. The fitted K0? values of hydrous wadsleyite (0.25 and 2.0?wt?% H2O) and hydrous ringwoodite (1.4?wt?% H2O) examined in this study were found to be identical within uncertainty, with K0? ~3.7(2). New secondary-ion mass spectrometry measurements of the H2O content of these and previously investigated wadsleyite samples shows the bulk modulus of wadsleyite is reduced by 7.0(5)?GPa/wt?% H2O, independent of Fe content for upper mantle compositions. Because K0? is unaffected by H2O, the reduction of bulk sound velocity in very hydrous regions of transition zone is expected to be on the order of 1.6%, which is potentially detectible in high-resolution, regional seismology studies.
Abstract: As the most abundant solid phase at depths of 410-525 km, wadsleyite constitutes a large geochemical reservoir in the Earth. To better understand the implications of minor element substitution and cation ordering in wadsleyite, we have synthesized wadsleyites coexisting with pyroxenes with 2-3 wt% of either TiO2, Cr2O3, V2O3, CoO, NiO, or ZnO under hydrous conditions in separate experiments at 1300 °C and 15 GPa. We have refined the crystal structures of these wadsleyites by single-crystal X-ray diffraction, analyzed the compositions by electron microprobe, and estimated M3 vacancy concentration from b/a cell-parameter ratios. According to the crystal structure refinements, Cr and V show strong preferences for M3 over M1 and M2 sites and significant substitution up to 2.9 at% at the tetrahedral site (T site). Ni, Co, and Zn show site preferences similar to those of Fe with M1? M3 > M2 > T. The avoidance of Ni, Co, and Fe for the M2 site in both wadsleyite and olivine appears to be partially controlled by crystal field stabilization energy (CFSE). The estimated CFSE values of Ni2+, Co2+, and Zn2+ at three distinct octahedral sites show a positive correlation with octahedral occupancy ratios [M2/(M1+M3)]. Ti substitutes primarily into the M3 octahedron, rather than M1, M2, or T sites. Ti, Cr, and V each have greater solubility in wadsleyite than in olivine. Therefore these transition metal cations may be enriched in a melt or an accessory phase if hydrous melting occurs on upward convection across the wadsleyite-olivine boundary and may be useful as indicators of high-pressure origin.
Contributions to Mineralogy and Petrology, 10.1007/ s00410-018-1478-x 10p.
Mantle
melting
Abstract: Ni, Co, and Zn are widely distributed in the Earth’s mantle as significant minor elements that may offer insights into the chemistry of melting in the mantle. To better understand the distribution of Ni2+, Co2+, and Zn2+ in the most abundant silicate phases in the transition zone and the upper mantle, we have analyzed the crystal chemistry of wadsleyite (Mg2SiO4), ringwoodite (Mg2SiO4), forsterite (Mg2SiO4), and clinoenstatite (Mg2Si2O6) synthesized at 12-20 GPa and 1200-1400 °C with 1.5-3 wt% of either NiO, CoO, or ZnO in starting materials. Single-crystal X-ray diffraction analyses demonstrate that significant amounts of Ni, Co, and Zn are incorporated in octahedral sites in wadsleyite (up to 7.1 at%), ringwoodite (up to 11.3 at%), olivine (up to 2.0 at%), and clinoenstatite (up to 3.2 at%). Crystal structure refinements indicate that crystal field stabilization energy (CFSE) controls both cation ordering and transition metal partitioning in coexisting minerals. According to electron microprobe analyses, Ni and Co partition preferentially into forsterite and wadsleyite relative to coexisting clinoenstatite. Ni strongly prefers ringwoodite over coexisting wadsleyite with DRw/WdNi?=?4.13. Due to decreasing metal-oxygen distances with rising pressure, crystal field effect on distribution of divalent metal ions in magnesium silicates is more critical in the transition zone relative to the upper mantle. Analyses of Ni partitioning between the major upper-mantle phases implies that Ni-rich olivine in ultramafic rocks can be indicative of near-primary magmas.
